Tetrakis-heteroleptic complexation at porphyrins: a convenient route to diversely functionalized aggregates.
[structure: see text] Using a novel tetraphenanthrolinated porphyrin building block and heteroleptic bisphenanthroline complexation, copper-instructed multicomponent assemblies exhibiting distinct electrochemical and photoactive behavior were accessed.
Schmittel
Michael
M
Center of Micro and Nanochemistry and Engineering, Organic Chemistry I, Universität Siegen, Adolf-Reichwein-Strasse, D-5708 Siegen, Germany. schmittel@chemie.uni-siegen.de
Kishore
R S K
RS
D003300:Copper / Q000737:chemistry; D004563:Electrochemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D010618:Phenanthrolines / Q000138:chemical synthesis*; D010777:Photochemistry; D011166:Porphyrins / Q000138:chemical synthesis / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
D009942:Organometallic Compounds; D010618:Phenanthrolines; D011166:Porphyrins; D003300:Copper; D015032:Zinc