title: Tris[bis[hydrotris(1-pyrazolyl)borato-kappa3N2,N2',N2"]iron(III)] hexaisothiocyanatoiron(III).
abstract: The title compound, [Fe(C(9)H(10)BN(6))(2)](3)[Fe(NCS)(6)] or [Fe(III)(Tp)(2)](3)[Fe(III)(NCS)(6)] [Tp is hydrotris(1-pyrazolyl)borate], crystallizes in space group R-3; the asymmetric unit comprises one-half of an [Fe(Tp)(2)](+) cation, with its Fe atom on a crystallographic inversion centre, and one-sixth of an [Fe(NCS)(6)](3-) anion, on a site of -3 symmetry. The anions and cations are stacked into a three-dimensional supramolecular aggregate via two distinct types of weak C-H.pi interactions.
authors.affiliation: Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, People's Republic of China.
authors.forename: Shi
authors.initials: S
authors.lastname: Wang
authors.forename: Yi-Zhi
authors.initials: YZ
authors.lastname: Li
authors.forename: Jing-Lin
authors.initials: JL
authors.lastname: Zuo
authors.forename: Cheng-Hui
authors.initials: CH
authors.lastname: Li
authors.forename: Xiao-Zeng
authors.initials: XZ
authors.lastname: You