ipso-nitration of arylboronic acids with chlorotrimethylsilane-nitrate salts.
[reaction: see text] A mixture of nitrate salt and chlorotrimethylsilane is found to be an efficient regioselective nitrating agent for the ipso-nitration of arylboronic acids to produce the corresponding nitroarenes in moderate to excellent yields. High selectivity, simplicity, and convenience are the key features of the reaction.
Prakash
G K Surya
GK
Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, California 90089-1661, USA. gprakash@usc.edu
Panja
Chiradeep
C
Mathew
Thomas
T
Surampudi
Vijayalakshmi
V
Petasis
Nicos A
NA
Olah
George A
GA