title: Stereoselection in radical cyclization of beta-alkoxyvinyl sulfoxides: synthesis of tetrahydrofuranyl allyl carbinols.
abstract: [reaction: see text] Tetrahydrofuranyl allyl carbinols may be prepared stereoselectively via radical cyclization of beta-alkoxyvinyl sulfoxides, Pummerer rearrangement, and reaction with allylstannane.
authors.affiliation: School of Chemistry and Molecular Engineering, Seoul National University, Seoul 151-747, Korea.
authors.forename: Gyochang
authors.initials: G
authors.lastname: Keum
authors.forename: Soon Bang
authors.initials: SB
authors.lastname: Kang
authors.forename: Youseung
authors.initials: Y
authors.lastname: Kim
authors.forename: Eun
authors.initials: E
authors.lastname: Lee
mesh_terms: D000498:Allyl Compounds / Q000138:chemical synthesis*; D003500:Cyclization; D005609:Free Radicals / Q000737:chemistry; D005663:Furans / Q000138:chemical synthesis*; D000432:Methanol / Q000138:chemical synthesis*; D008968:Molecular Conformation; D013237:Stereoisomerism; D013454:Sulfoxides / Q000737:chemistry*; D014753:Vinyl Compounds / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D005609:Free Radicals; D005663:Furans; D013454:Sulfoxides; D014753:Vinyl Compounds; D000432:Methanol