Thermal and light induced polymorphism in iron(II) spin crossover compounds.
The spin crossover complexes [Fe[H(2)B(pz)(2)](2)L]([H(2)B(pz)(2)](-)= dihydrobis(pyrazolyl)borate, L = 2,2[prime or minute]-bipyridine (1), bipy and 1,10-phenanthroline, phen (2)) undergo both thermal and light induced spin crossover, but the structure of the low spin and light induced high spin states for are different from that of the thermally induced high spin state and from those of.
Thompson
Amber L
AL
Department of Chemistry, University of Durham, South Road, Durham, UKDH1 3LE.
Goeta
Andres E
AE
Real
Jose A
JA
Galet
Ana
A
Carmen Munoz
M
M