European survey on post-consumer poly(ethylene terephthalate) (PET) materials to determine contamination levels and maximum consumer exposure from food packages made from recycled PET.
Typical contamination and the frequency of misuse of poly(ethylene terephthalate) (PET) bottles are crucial parameters in the risk assessment of post-consumer recycled (PCR) PET intended for bottle-to-bottle recycling for direct food contact applications. Owing to the fact that misuse of PET bottles is a rare event, sustainable knowledge about the average concentration of hazardous compounds in PCR PET is accessible only by the screening of large numbers of samples. In order to establish average levels of contaminants in PET source materials for recycling, PET flakes from commercial washing plants (689 samples), reprocessed pellets (38) and super-clean pellets (217) were collected from 12 European countries between 1997 and 2001. Analysis of these materials by headspace gas chromatography revealed average and maximum levels in PCR PET of 18.6 and 86.0 mg kg-1 for acetaldehyde and 2.9 and 20 mg kg-1 for limonene, respectively. Acetaldehyde and limonene are typical compounds derived from PET itself and from prior PET bottle contents (flavouring components), respectively. Maximum levels in PCR PET of real contaminants such as misuse chemicals like solvents ranged from 1.4 to 2.7 mg kg-1, and statistically were shown to result from 0.03 to 0.04% of recollected PET bottles that had been misused. Based on a principal component analysis of the experimental data, the impact of the recollecting system and the European Union Member State where the post-consumer PET bottles had been collected on the nature and extent of adventitious contaminants was not significant. Under consideration of the cleaning efficiency of super-clean processes as well as migration from the bottle wall into food, it can be concluded that the consumer will be exposed at maximum to levels < 50 ng total misuse chemicals day-1. Therefore, PCR PET materials and articles produced by modern superclean technologies can be considered to be safe in direct food applications in the same way as virgin food-grade PET.
Franz
R
R
Fraunhofer Institute for Process Engineering and Packaging (IVV), Giggenhauser Strasse 35, D-85354 Freising, Germany.
Mauer
A
A
Welle
F
F
D000079:Acetaldehyde / Q000032:analysis; D002273:Carcinogens / Q000032:analysis; D003247:Conservation of Natural Resources; D053138:Cyclohexenes; D017743:Equipment Reuse; D005060:Europe; D005410:Flame Ionization / Q000379:methods; D005506:Food Contamination / Q000517:prevention & control*; D018857:Food Packaging; D015386:Hazardous Substances / Q000032:analysis; D006801:Humans; D000077222:Limonene; D008452:Maximum Allowable Concentration; D008970:Molecular Weight; D011093:Polyethylene Terephthalates / Q000032:analysis*; D012997:Solvents / Q000032:analysis; D013729:Terpenes / Q000032:analysis
D002273:Carcinogens; D053138:Cyclohexenes; D015386:Hazardous Substances; D011093:Polyethylene Terephthalates; D012997:Solvents; D013729:Terpenes; D000077222:Limonene; D000079:Acetaldehyde