Potentiometric discrimination of neutral forms of nitrophenol isomers by liquid membrane electrodes incorporated with corroles.
The results of studies on the use of corrole derivatives as a host ligand in the PVC liquid membrane electrodes and their ability for the potentiometric high-throughput discrimination of nitrophenol guests have been presented. The significance of parameters which govern the mechanism of generation of potentiometric signals such as the attachment of substituents in the corrole structure, acidity and lipophilicity of the guests, and pH of the aqueous solutions has been discussed in details. Supramolecular recognition processes between corroles and para-nitrophenol molecules have been confirmed by independent NMR measurements.
Radecki
Jerzy
J
Institute of Animal Reproduction & Food Research, Polish Academy of Sciences, Tuwima 10, PL-10-747 Olsztyn, Poland. radecki@pan.olsztyn.pl
Stenka
Iwona
I
Dolusic
Eddy
E
Dehaen
Wim
W
Plavec
Janez
J
D004566:Electrodes; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy; D008567:Membranes, Artificial; D009596:Nitrophenols / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D011199:Potentiometry
D008567:Membranes, Artificial; D009596:Nitrophenols; D011166:Porphyrins