Kinetics of chalcone oxidation by peroxide anion catalysed by poly-l-leucine.
An insight into the kinetics, mechanism and optimum reaction conditions of the Julia-Colonna epoxidation has been gained using a soluble polyleucine catalyst.
Carrea
Giacomo
G
Istituto di Chimica del Riconoscimento Moleculare, CNR, Via Mario Bianco 9, 20131 Milano, Italy.
Colonna
Stefano
S
Meek
Alastair D
AD
Ottolina
Gianluca
G
Roberts
Stanley M
SM
D000838:Anions; D002384:Catalysis; D002599:Chalcone / Q000737:chemistry*; D004852:Epoxy Compounds / Q000737:chemistry; D007700:Kinetics; D008956:Models, Chemical; D009842:Oligopeptides / Q000737:chemistry*; D010084:Oxidation-Reduction; D010455:Peptides / Q000737:chemistry*; D010545:Peroxides / Q000737:chemistry*
D000838:Anions; D004852:Epoxy Compounds; D009842:Oligopeptides; D010455:Peptides; D010545:Peroxides; C027819:polyleucine; D002599:Chalcone