Eclipsed M2X6 compounds exhibiting very short metal-metal triple bonds.
The preparation, characterization, and electronic structure of homoleptic complexes of molybdenum and tungsten bridged by bis(alkylamido)phenylboranes, M(2)[RN-B(Ph)-NR](3) (M = Mo, R = Et (1), (i)Pr (2); M = W, R = Et (3), (i)Pr (4)), are described. These triple metal-metal bond species (i) exhibit a nearly eclipsed ligand geometry and (ii) possess the shortest metal-metal bonds of neutral dimolybdenum and ditungsten M(2)X(6) complexes observed to date (d(Mo-Mo) = 2.1612(6) A (1); d(W-W) = 2.2351(7) A (4)).
Manke
David R
DR
Department of Chemistry, 6-335, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139-4307, USA.
Loh
Zhi-Heng
ZH
Nocera
Daniel G
DG