title: Leaching of organic contaminants from storage of reclaimed asphalt pavement.
abstract: Recycling of asphalt has been promoted by rapid increases in both the use and price of petroleum-based bitumen. Semi-volatile organic compounds in leachates from reclaimed asphalt pavement, measured in field samples and in laboratory column test, were analysed through a GC/MS screen-test methodology. Sixteen PAH (polyaromatic hydrocarbons) were also analysed in leachates from the column study. The highest concentrations of semi-volatile compounds, approximately 400 microg l(-1), were measured in field samples from the scarified stockpile. Naphthalene, butylated hydroxytoluene (BHT) and dibutyl phthalate (DBP) were the most dominant of the identified semi-volatiles. The occurrence of these compounds in urban groundwater, also indicate high emission rates and persistent structures of the compounds, making them potentially hazardous. Car exhausts, rubber tires and the asphalt material itself are all probable emission sources, determined from the organic contaminants released from the stockpiles. The major leaching mechanism indicated was dissolution of organic contaminants from the surface of the asphalt gravels. In the laboratory column test, the release of high-molecular weight and more toxic PAH was higher in the leachates after two years than at the commencement of storage. The concentrations of semi-volatiles in leachates, were also several times lower than those from the field stockpile. These results demonstrate the need to follow up laboratory column test with real field measurements.
authors.affiliation: Department of Geology, Chalmers University of Technology, SE-412 96 Göteborg, Sweden.
authors.forename: Malin
authors.initials: M
authors.lastname: Norin
authors.forename: A M
authors.initials: AM
authors.lastname: Strömvall
mesh_terms: D002084:Butylated Hydroxytoluene / Q000032:analysis; D002244:Carbon / Q000032:analysis; D003247:Conservation of Natural Resources; D003993:Dibutyl Phthalate / Q000032:analysis; D004787:Environmental Pollution / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry; D006838:Hydrocarbons / Q000737:chemistry*; D009281:Naphthalenes / Q000032:analysis; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis* / Q000302:isolation & purification; D012408:Rubber; D012989:Soil Pollutants; D001335:Vehicle Emissions; D014835:Volatilization; D014874:Water Pollutants, Chemical
chemical_list: D006838:Hydrocarbons; D009281:Naphthalenes; D011084:Polycyclic Aromatic Hydrocarbons; D012989:Soil Pollutants; D001335:Vehicle Emissions; D014874:Water Pollutants, Chemical; D002084:Butylated Hydroxytoluene; C031721:naphthalene; D003993:Dibutyl Phthalate; D002244:Carbon; C006647:asphalt; D012408:Rubber