Leaching from solid waste incineration ashes used in cement-treated base layers for pavements.
Waste incineration bottom ash and treated flue gas cleaning products mixed with 2.5% of cement (50 kg/m3) were tested in the laboratory in terms of compressive strength and tank leaching tests over a 64-day period. Although the material displayed lower mechanical strength than a reference concrete, the strength still was sufficient for use as a base layer for roads. The metal content in the incineration-residue-based specimens was up to 100 times higher than in the reference concrete, suggesting that the mixed waste incineration residue should be used only for dedicated purposes. The leaching of Cl and Na was increased by a factor of 20-100 from the incineration-residue-based specimens as compared to the reference, while the leaching of K, Ca and SO4 was increased by a factor of 2-10. The leaching of heavy metals was also higher from the incineration-residue-based specimens than from the reference with respect to Cu (50 times), Cd, Pb and Zn (5 times), but not with respect to Cr and Ni. The leaching curves did only allow for a closer evaluation of the leaching process in a few cases. The physical retention of the constituents seemed to be the same in the reference as in the incineration-residue-based specimens. Heavy metal leaching was limited by enhanced chemical retention in the incineration-residue-specimens as compared to the reference. Since no quality criteria in terms of leaching from a monolithic material are currently available, the leaching issue must be evaluated case by case.
Cai
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Environment & Resources DTU, Technical University of Denmark, Building 115, DK-2800 Lyngby, Denmark.
Bager
Dirch H
DH
Christensen
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TH
D002244:Carbon; D060729:Coal Ash; D003252:Construction Materials; D017745:Incineration; D008422:Materials Testing; D019216:Metals, Heavy / Q000032:analysis*; D052638:Particulate Matter; D012989:Soil Pollutants / Q000032:analysis*; D018505:Waste Management / Q000379:methods; D014873:Water Pollutants / Q000032:analysis*
D060729:Coal Ash; D019216:Metals, Heavy; D052638:Particulate Matter; D012989:Soil Pollutants; D014873:Water Pollutants; D002244:Carbon