title: Low temperature NO disproportionation by Mn porphyrin. Spectroscopic characterization of the unstable nitrosyl nitrito complex MnIII(TPP)(NO)(ONO).
abstract: Reaction of NO gas with sublimed layers of the Mn(II)TPP (TPP =meso-tetraphenylporphyrinato2-) at low temperature leads to nitric oxide disproportionation. UV-Vis and FTIR spectroscopy with isotopically substituted nitrogen oxides revealed formation of the unstable species identified as trans-Mn(III)(TPP)(NO)(ONO).
authors.affiliation: Armenian Research Institute of Applied Chemistry, Yerevan, Armenia.
authors.forename: Garik G
authors.initials: GG
authors.lastname: Martirosyan
authors.forename: Arsen S
authors.initials: AS
authors.lastname: Azizyan
authors.forename: Tigran S
authors.initials: TS
authors.lastname: Kurtikyan
authors.forename: Peter C
authors.initials: PC
authors.lastname: Ford