title: Self-assembled tin-based bridged hybrid materials.
abstract: Hybrid materials where layers of tin oxide alternate with layers of hydrophobic organic chains were prepared by the hydrolysis of distannylated compounds containing an organic chain alpha,omega-disubstituted by tripropynylstannyl groups. In the case of an aliphatic chain, hydrolysis under microemulsion conditions led to the organization of the corresponding hybrid. These hydrolysis conditions also induced a high surface area and a defined mesoporosity in the hybrid. When a mixed aromatic-aliphatic spacer was used, weak hydrophobic interactions between the spacers were sufficient to generate the same type of organization in the corresponding material.
authors.affiliation: Laboratoire de Chimie Organique et Organométallique, UMR 5802, Université Bordeaux 1, 351 cours de la Libération, 33405 Talence, France.
authors.forename: Hicham
authors.initials: H
authors.lastname: Elhamzaoui
authors.forename: Bernard
authors.initials: B
authors.lastname: Jousseaume
authors.forename: Hocine
authors.initials: H
authors.lastname: Riague
authors.forename: Thierry
authors.initials: T
authors.lastname: Toupance
authors.forename: Philippe
authors.initials: P
authors.lastname: Dieudonné
authors.forename: Cécile
authors.initials: C
authors.lastname: Zakri
authors.forename: Maryse
authors.initials: M
authors.lastname: Maugey
authors.forename: Hassan
authors.initials: H
authors.lastname: Allouchi