title: Immobilization of Pd(OAc)(2) in ionic liquid on silica: application to sustainable Mizoroki-Heck reaction.
abstract: [reaction: see text] Palladium acetate was supported on amorphous silica with the aid of an ionic liquid, [bmim]PF(6). The immobilized catalyst was highly efficient in promoting the Mizoroki-Heck reaction without a ligand in n-dodecane for at least six reuses, in 89 approximately 98% yields. The TON and TOF reached 68 400 and 8000, respectively.
authors.affiliation: Graduate School of Science and Technology, Niigata University, 8050, 2-Nocho, Ikarashi, Niigata 950-2181, Japan. hagiwara@gs.niigata-u.ac.jp
authors.forename: Hisahiro
authors.initials: H
authors.lastname: Hagiwara
authors.forename: Yoshitaka
authors.initials: Y
authors.lastname: Sugawara
authors.forename: Kohei
authors.initials: K
authors.lastname: Isobe
authors.forename: Takashi
authors.initials: T
authors.lastname: Hoshi
authors.forename: Toshio
authors.initials: T
authors.lastname: Suzuki