title: Phenylthiolate as a sigma- and pi- donor ligand: synthesis of a 3-D organometallic coordination polymer [K2Fe(SPh)4]n.
abstract: The synthesis and crystal structure of the first mixed-metal organometallic polymer network containing phenylthiolato ligands, [K2Fe(SPh)4]n, are investigated. The simple phenylthiolate acts as a sigma- and pi-donor ligand to give a 3-D potassium iron coordination polymer with both metal-carbon and metal-sulfur coordination interactions.
authors.affiliation: Department of Chemistry, Fudan University, Shanghai, PR China.
authors.forename: Xiao-Yan
authors.initials: XY
authors.lastname: Yu
authors.forename: Guo-Xin
authors.initials: GX
authors.lastname: Jin
authors.forename: Lin-Hong
authors.initials: LH
authors.lastname: Weng