Synthesis of 1,2-diamino-1,2-dideoxy-myo- inositol-derived ligands for the investigation of metal complex reactivity.
A method for the synthesis of chiral 1,2-diamino-1,2-dideoxy-myo-inositol-based bis-pyridyl ligands 3a and 3b from the corresponding myo-inositol precursor is described. These highly functionalized inosamine-bis-pyridyl ligands are expected to provide a useful platform for exploring the relationship between chiral ligand structure and enantioselective olefin oxidation catalyzed by their metal complexes.
Azev
Viatcheslav N
VN
Department of Chemistry, Tufts University, 62 Talbot Avenue, Medford, Massachusetts 02155, USA.
D'Alarcao
Marc
M
D002384:Catalysis; D007202:Indicators and Reagents; D007294:Inositol / Q000031:analogs & derivatives* / Q000138:chemical synthesis*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D011725:Pyridines / Q000138:chemical synthesis*
D007202:Indicators and Reagents; D008024:Ligands; D009942:Organometallic Compounds; D011725:Pyridines; D007294:Inositol; C023666:pyridine