Mixed carboxylate-bridged dimanganese(II/III) compounds prepared by an O2-dependent oxidative cleavage of ketones.
The structure of an O(2)-sensitive Mn(II)-Mn(II) complex with an unsymmetrical perchlorate bridge is reported. This complex promotes an O(2)-dependent oxidative cleavage of ketones giving mixed carboxylate complexes.
Jensen
Kenneth Bendix
KB
Department of Chemistry, University of Southern Denmark, Odense, 5230 Odense M, Denmark.
Johansen
Edel
E
Larsen
Frank Bartnik
FB
McKenzie
Christine J
CJ