C-Glycosides of 2-amino-2-deoxy sugars. beta-C-Glycosides and 1,1-disubstituted variants.
[reaction: see text] C(1)-Substituted anomeric selenides, derived from azidoselenation of C(1)-methylated glycals, provide access to anomeric radical reactivity that has been used to generate beta-C-glycosides and 1,1-disubstituted C-glycosides based on galacto, gluco, and manno variants of N-acetyl-2-amino sugars.
Liu
Yan
Y
School of Chemistry, University of Bristol, Bristol BS8 1TS, UK.
Gallagher
Timothy
T
D000606:Amino Sugars / Q000737:chemistry*; D002384:Catalysis; D006027:Glycosides / Q000138:chemical synthesis / Q000737:chemistry*; D007202:Indicators and Reagents; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012643:Selenium / Q000737:chemistry*; D013237:Stereoisomerism
D000606:Amino Sugars; D006027:Glycosides; D007202:Indicators and Reagents; D009942:Organometallic Compounds; D012643:Selenium