Highly diastereo- and enantioselective reactions of enecarbamates with ethyl glyoxylate to give optically active syn and anti alpha-alkyl-beta-hydroxy imines and ketones.
Matsubara
Ryosuke
R
Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Nakamura
Yoshitaka
Y
Kobayashi
Shū
S
D002219:Carbamates / Q000138:chemical synthesis / Q000737:chemistry*; D006038:Glyoxylates / Q000138:chemical synthesis / Q000737:chemistry*; D007097:Imines / Q000138:chemical synthesis* / Q000737:chemistry; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry; D013237:Stereoisomerism
D002219:Carbamates; D006038:Glyoxylates; D007097:Imines; D007659:Ketones; D009942:Organometallic Compounds