title: Estimation of apparent rate coefficients for phenanthrene and pentachlorophenol interacting with sediments.
abstract: To gain information on organic pollutants in water-sediment systems, a compartment model was applied to study the sorption course of phenanthrene and pentachlorophenol (PCP) in sediments. The model described the time-dependent interaction of phenanthrene and PCP with operationally defined reversible and irreversible (or slowly reversible) sediment fractions. The interactions between these fractions were described using first order differential equations. By fitting the models to the experimental data, apparent rate constants were obtained using numerical optimization software. The model optimizations showed that the amount of reversible phase increased rapidly in the first 10 d with the sorption time, then decreased after 10 d, while the amount of irreversible phase increased in the total sorption course. That suggested the mass transport between reversible phase and irreversible phase. The extraction efficiency with hot methanol ranged from 36% to 103% for phenanthrene and from 65% to 101% for PCP, with the trend of decreasing with sorption time.
authors.affiliation: Department of Environmental Engineering, Huajiachi Campus, Zhejiang University, Hangzhou 310029, PR China.
authors.forename: Hua-Lin
authors.initials: HL
authors.lastname: Chen
authors.forename: Ying-Xu
authors.initials: YX
authors.lastname: Chen
authors.forename: Yun-Tai
authors.initials: YT
authors.lastname: Xu
authors.forename: Meng-Wei
authors.initials: MW
authors.lastname: Shen
mesh_terms: D055598:Chemical Phenomena; D002627:Chemistry, Physical; D019015:Geologic Sediments / Q000737:chemistry*; D008956:Models, Chemical; D010416:Pentachlorophenol / Q000737:chemistry*; D010616:Phenanthrenes / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D010616:Phenanthrenes; D014874:Water Pollutants, Chemical; C031181:phenanthrene; D010416:Pentachlorophenol