Direct syntheses of S-alkylthio-D-galactono-, D-mannono-1,4-lactones, S-alkylthio-L-galactitols and D-mannitols displaying amphiphilic and mesophasic properties.
Alkylthio-L-galactitols and D-mannitols were obtained in good yields (70-81%) by reduction, with NaBH4, of the corresponding 6-S-alkyl-6-thio-D-hexono-1,4-lactones.
Chaveriat
Ludovic
L
Laboratoire des Glucides (FRE 2779), Université de Picardie Jules Verne, 33 Rue Saint-Leu, F-80039 Amiens, France.
Stasik
Imane
I
Demailly
Gilles
G
Beaupère
Daniel
D
D002236:Carbohydrate Conformation; D002241:Carbohydrates / Q000737:chemistry; D005690:Galactose / Q000737:chemistry*; D007783:Lactones / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008353:Mannitol / Q000737:chemistry*; D008956:Models, Chemical; D013053:Spectrophotometry; D013438:Sulfhydryl Compounds / Q000737:chemistry; D013696:Temperature; D014466:Ultraviolet Rays
D002241:Carbohydrates; D007783:Lactones; D013438:Sulfhydryl Compounds; D008353:Mannitol; D005690:Galactose