From eilatin to isoeilatin: a skeletal rearrangement strongly influences pi-stacking of Ru(II) complex.
The C(1)-symmetrical complex [Ru(bpy)(2)(ieil)][PF(6)](2) exhibits unique electrochemical and photophysical properties, and forms discrete dimers in solution and in the solid state held by weak pi-pi stacking interactions via its isoeilatin ligand, preferentially from one of its faces and in a specific orientation.
Bergman
Sheba D
SD
School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv 69978, Israel.
Reshef
Dvora
D
Frish
Limor
L
Cohen
Yoram
Y
Goldberg
Israel
I
Kol
Moshe
M
D000470:Alkaloids / Q000737:chemistry*; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D009942:Organometallic Compounds / Q000737:chemistry*; D010618:Phenanthrolines / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
D000470:Alkaloids; D009942:Organometallic Compounds; D010618:Phenanthrolines; C097538:eilatine; D012428:Ruthenium