Synthesis, structure, and reactivity of a dinuclear metal complex with linear M-H-M bonding.
Reaction of two equiv of 1-adamantylzinc bromide with (dippm)NiBr2 (dippm = bis(di-isopropylphosphino)methane) led to a dinuclear metal complex containing a unique linear bridging hydride ligand. The hydride was characterized by neutron diffraction methods, which confirmed a linear bonding mode. Preliminary reactivity studies of this unusual dimer are reported.
Vicic
David A
DA
Department of Chemistry and Biochemistry, University of Arkansas, Fayetteville, AR 72701, USA. dvicic@uark.edu
Anderson
Thomas J
TJ
Cowan
John A
JA
Schultz
Arthur J
AJ
D001952:Bridged-Ring Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D006860:Hydrogen Bonding; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D001952:Bridged-Ring Compounds; D009942:Organometallic Compounds; D009532:Nickel