Preparation of activated carbon using low temperature carbonisation and physical activation of high ash raw bagasse for acid dye adsorption.
Activated carbons were prepared from bagasse through a low temperature (160 degrees C) chemical carbonisation treatment and gasification with carbon dioxide at 900 degrees C. The merit of low temperature chemical carbonisation in preparing chars for activation was assessed by comparing the physical and chemical properties of activated carbons developed by this technique to conventional methods involving the use of thermal and vacuum pyrolysis of bagasse. In addition, the adsorption properties (acid blue dye) of these bagasse activated carbons were also compared with a commercial activated carbon. The results suggest that despite the high ash content of the precursor, high surface areas (614-1433 m2 g(-1)) and microporous (median pore size from 0.45 to 1.2 nm) activated carbons can be generated through chemical carbonisation and gasification. The micropore area of the activated carbon developed from chars prepared by the low temperature chemical carbonisation provides favourable adsorption sites to acid blue dye (391 mg g(-1) of carbon). The alkalinity of the carbon surface and total surface area were shown to have complementary effects in promoting the adsorption of acid blue dye. Adsorption of the anionic coloured component of the acid dye was shown to be promoted in carbon exhibiting alkaline or positively charged surfaces. This study demonstrates that activated carbons with high acid dye adsorption capacities can be prepared from high ash bagasse based on low temperature chemical carbonisation and gasification.
Valix
M
M
Department of Chemical Engineering, University of Sydney, Bldg. J01, Sydney NSW 2006, Australia. mvalix@chem.eng.usyd.edu.au
Cheung
W H
WH
McKay
G
G
D000327:Adsorption; D000880:Anthraquinones / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry; D002482:Cellulose / Q000737:chemistry*; D002606:Charcoal / Q000138:chemical synthesis* / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D010316:Particle Size; D013696:Temperature
D000880:Anthraquinones; D002245:Carbon Dioxide; D002606:Charcoal; D002482:Cellulose; C027433:bagasse; C433873:acid blue 80