Synthesis and characterization of titania-coated silver nanoparticles.
Silver particles of 70 +/- 10 nm mean diameter were coated with uniform layers of amorphous titania by the hydrolysis and polycondensation process using titanium(IV) n-butoxide in aqueous solution. Because of the large dielectric function of titania, a shift to the longer wavelengths was observed for the plasmon resonance maximum of coated silver nanoparticles. By changing the alkoxide to particles ratio in the reaction mixture, thickness ranging from 5 to 20 nm was obtained. Hydrothermal treatment performed on coated particles at 350 degrees C for 4 h converted amorphous titania to the anatase crystalline form. The anatase form was confirmed by X-ray powder diffraction. More red shift of the plasmon resonance was observed for the hydrothermally treated samples compared with the particles coated with amorphous titania.
Kumbhar
Amar
A
Department of Chemistry, Clemson University, Clemson, South Carolina, USA.
Chumanov
George
G
D020099:Coated Materials, Biocompatible / Q000138:chemical synthesis / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D008422:Materials Testing; D008968:Molecular Conformation; D036103:Nanotechnology / Q000379:methods*; D043942:Nanotubes / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D044367:Phase Transition; D012834:Silver / Q000032:analysis / Q000737:chemistry*; D013499:Surface Properties; D014025:Titanium / Q000032:analysis / Q000737:chemistry*
D020099:Coated Materials, Biocompatible; C009495:titanium dioxide; D012834:Silver; D014025:Titanium