Ir-catalyzed C-H activation in the synthesis of borylated ferrocenes and half sandwich compounds.
The complex generated from 1/2[Ir(OMe)(cod)]2 and 4,4'-di-tert-butyl-2,2'-bipyridine catalyzes the regioselective borylation of ferrocenes, CpMn(CO)3 and CpMo(CO)3CH3 with a stoichiometric amount of B2pin2.
Datta
Anupama
A
Institut für Anorganische Chemie, TU Darmstadt, Petersenstr. 18, 64287 Darmstadt, Germany.
Köllhofer
Axel
A
Plenio
Herbert
H