Solvent tuned excited state configuration mixing in a pi-conjugated metal-organic oligomer.
The photophysical properties of a pi-conjugated metal-organic oligomer vary smoothly with solvent composition. The variation is believed to arise from solvent-tuned configuration mixing of 3pi,pi* and 3MLCT levels.
Liu
Shengxia
S
Department of Chemistry, University of Florida, Gainesville, FL 32611-7200, USA.
Schanze
Kirk S
KS