title: [N,N'-Bis(3-carboxysalicylidene)-1,2-diphenyl-(RR,SS)-1,2-ethanediyldiaminato-O,N,N',O'](methanol-O)oxovanadium(IV) and [N,N'-bis(3-carboxysalicylidene)-2,3-dimethyl-2,3-butanediyldiaminato-O,N,N',O']oxovanadium(IV) monohydrate.
abstract: The two title mononuclear oxovanadium (IV) complexes, [VO(C(30)H(22)N(2)O(6))(CH(3)OH)] and [VO(C(22)H(22)N(2)O(6))].H(2)O, respectively, have distorted square-pyramidal coordination and the 3-carboxy groups form intramolecular hydrogen bonds with the coordinated salicyl O atoms. In (I), methanol coordinates to the vanadium atom trans with respect to the oxo ligand.
authors.affiliation: Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, Yokohama 223-8522, Japan.
authors.forename: R
authors.initials: R
authors.lastname: Uemura
authors.forename: M
authors.initials: M
authors.lastname: Tsuchimoto
authors.forename: S
authors.initials: S
authors.lastname: Ohba