title: Polyelectrolyte shells of copolymer micelles in aqueous solutions: a Monte Carlo study.
abstract: Multimolecular micelles, formed by polystyrene-block-poly(methacrylic acid) in water, are studied by lattice Monte Carlo method. Electrostatic interactions are calculated in the mean-field approximation by solving the Poisson-Boltzmann equation. The model is parametrized according to available experimental data. The dependence of micellar size on pH and ionic strength is calculated and compared with experimental data. A special attention is devoted to the behavior in solutions with a low ionic strength.
authors.affiliation: Department of Physical and Macromolecular Chemistry, School of Science, Charles University, Albertov 6, 128 43 Praha 2, Czech Republic.
authors.forename: Filip
authors.initials: F
authors.lastname: Uhlík
authors.forename: Zuzana
authors.initials: Z
authors.lastname: Limpouchová
authors.forename: Karel
authors.initials: K
authors.lastname: Jelínek
authors.forename: Karel
authors.initials: K
authors.lastname: Procházka