title: Preparation and characterisation of palladium, platinum and manganese di(organo)carbene complexes from quinolinone and quinolinium precursors.
abstract: A series of palladium, platinum and manganese di(organo)carbene complexes have been prepared from 4-chloro-N-methylquinolinone by processes that involve alkylation before or after attachment to the metal unit; the nucleophilic heteroatoms are separated from the C-donor atom by three bonds.
authors.affiliation: Department of Chemistry, P/Bag X1, Matieland, 7602, Stellenbosch, South Africa.
authors.forename: Wolfgang H
authors.initials: WH
authors.lastname: Meyer
authors.forename: Maggel
authors.initials: M
authors.lastname: Deetlefs
authors.forename: Michael
authors.initials: M
authors.lastname: Pohlmann
authors.forename: Roland
authors.initials: R
authors.lastname: Scholz
authors.forename: Matthias W
authors.initials: MW
authors.lastname: Esterhuysen
authors.forename: Gerrit R
authors.initials: GR
authors.lastname: Julius
authors.forename: Helgard G
authors.initials: HG
authors.lastname: Raubenheimer
mesh_terms: D018360:Crystallography, X-Ray; D006838:Hydrocarbons; D008345:Manganese / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D015363:Quinolones / Q000737:chemistry*
chemical_list: D006838:Hydrocarbons; D009942:Organometallic Compounds; D015363:Quinolones; C030011:carbene; D008345:Manganese; D010984:Platinum; D010165:Palladium; D008697:Methane