A neutral tungsten-eta2-alkyne-1-thio ligand forming a homoleptic Werner type complex with Cu(I).
The 1-thio-eta2-alkyne-complex [Tp'(CO)2W(BnSCCS)][Tp'= hydrotris(3,5-dimethylpyrazolyl)borate; Bn = benzyl], which was obtained by reductive removal of the benzyl group at the alkyne complex [Tp'(CO)2W(BnSCCSBn)]PF(6), has been established as a ligand in a combined organometallic/Werner type heterobimetallic complex with Cu(I).
Seidel
Wolfram W
WW
Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstra[Gernam sz ligature]e 36, 48149, Münster, Germany. seidelww@uni-muenster.de
Ibarra Arias
Maria D
MD
Schaffrath
Markus
M
Bergander
Klaus
K