Cobalt(II), nickel(II) and copper(II) complexes of isoquinoline-3-carboxylate.
The crystal structures of the title complexes, namely trans-bis(isoquinoline-3-carboxylato-kappa2N,O)bis(methanol-kappaO)cobalt(II), [Co(C10H6NO2)2(CH3OH)2], and the corresponding nickel(II) and copper(II) complexes, [Ni(C10H6NO2)2(CH3OH)2] and [Cu(C10H6NO2)2(CH3OH)2], are isomorphous and contain metal ions at centres of inversion. The three compounds have the same distorted octahedral coordination geometry, and each metal ion is bonded by two quinoline N atoms, two carboxylate O atoms and two methanol O atoms. Two isoquinoline-3-carboxylate ligands lie in trans positions, forming the equatorial plane, and the two methanol ligands occupy the axial positions. The complex molecules are linked together by O-H...O hydrogen bonds between the methanol ligands and neighbouring carboxylate groups.
Okabe
Nobuo
N
Faculty of Pharmaceutical Sciences, Kinki University, Kowakae 3-4-1, Higashiosaka, Osaka 577-8502, Japan. okabe@phar.kindai.ac.jp
Muranishi
Yasunori
Y
Odoko
Mamiko
M
D002264:Carboxylic Acids / Q000737:chemistry; D003035:Cobalt / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007546:Isoquinolines / Q000737:chemistry*; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*
D002264:Carboxylic Acids; D007546:Isoquinolines; D009942:Organometallic Compounds; D003035:Cobalt; D003300:Copper; D009532:Nickel