Neutral and ionic dissociation patterns in hexacoordinate silicon chelates: a model nucleophilic substitution at pentacoordinate silicon.
A model nucleophilic-displacement reaction coordinate at pentacoordinate silicon is demonstrated by neutral and ionic dissociation equilibria through a stable hexacoordinate complex.
Gostevskii
Boris
B
Department of Chemistry, Ben-Gurion University, Beer-Sheva 84105, Israel.
Adear
Keren
K
Sivaramakrishna
Akella
A
Silbert
Gilad
G
Stalke
Dietmar
D
Kocher
Nikolaus
N
Kalikhman
Inna
I
Kost
Daniel
D