Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes.
The eta1-hydroxylamido half-titanocene complex, CpTiCl2(TEMPO) 1, hydrolyzes extremely efficiently to generate (CpTiClO)4 and the protonated hydroxylamine. The efficient hydrolysis chemistry provides selective syntheses of CpTi dialkoxide and diaryloxide complexes.
Huang
Kuo-Wei
KW
Department of Chemistry, Stanford University, Stanford, CA 94305, USA.
Waymouth
Robert M
RM
D003497:Cyclic N-Oxides / Q000737:chemistry; D003517:Cyclopentanes / Q000737:chemistry; D006868:Hydrolysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D014025:Titanium / Q000737:chemistry*
D003497:Cyclic N-Oxides; D003517:Cyclopentanes; D009942:Organometallic Compounds; D014025:Titanium; C003959:TEMPO