TiCl4-catalyzed intermolecular hydroamination reactions of norbornene.
[reaction: see text] An intermolecular hydroamination reaction of norbornene is presented that uses catalytic amounts of user-friendly TiCl(4) and tolerates a variety of functional groups. In addition, a secondary amine is converted using this methodology.
Ackermann
Lutz
L
Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13, D-81377 München, Germany. lutz.ackermann@cup.uni-muenchen.de
Kaspar
Ludwig T
LT
Gschrei
Christian J
CJ