3,6-Dihydroxy-2-(11-phenylundecanoyl)cyclohex-2-en-1-one from Virola venosa bark.
The structure of the title compound, C23H32O4, an arylalkanone isolated from the petroleum ether fraction of the ethanol extract of the bark of Virola venosa, has been established by NMR spectroscopy and, for the first time, by X-ray structure analysis. Two independent molecules of the same enantiomer are present in the unit cell. Both molecules exhibit an intramolecular hydrogen bond, which can be correlated with a rare signal observed at 18.28 p.p.m. in the 1H NMR spectrum. The packing, in space group P1, is determined by a pseudo-center of symmetry leading to a short intermolecular contact, which is present in one molecule but does not occur in the other. As a consequence, the O-C-C-O torsion angles [-16.9 (3) and -12.7 (3) degrees ] through the ketone and its adjacent hydroxy group are significantly different in the two molecules.
Castro
Ernesto
E
Department of Chemistry, Universidad Nacional de Colombia, 14490 Bogota.
Cuca Suarez
Luis E
LE
Siengalewicz
Peter
P
Gutmann
Rene
R
Czermak
Georg
G
Brueggeller
Peter
P
D000473:Alkanes / Q000737:chemistry* / Q000302:isolation & purification; D018360:Crystallography, X-Ray; D003510:Cyclohexanes / Q000737:chemistry; D003512:Cyclohexanones / Q000737:chemistry* / Q000302:isolation & purification; D053138:Cyclohexenes; D015394:Molecular Structure; D026324:Myristicaceae / Q000737:chemistry*; D019906:Nuclear Magnetic Resonance, Biomolecular; D024301:Plant Bark / Q000737:chemistry; D010936:Plant Extracts / Q000737:chemistry / Q000302:isolation & purification
C496382:3,6-dihydroxy-2-(11-phenylundecanoyl)cyclohex-2-en-1-one; D000473:Alkanes; D003510:Cyclohexanes; D003512:Cyclohexanones; D053138:Cyclohexenes; D010936:Plant Extracts; C052568:cyclohexene