Crystal structures of dicarboxy-2,2'-bipyridyl complexes: the role of hydrogen bonding and stacking interactions.
The crystal structures of three complexes of dicarboxy-2,2'-bipyridyl ligands, 5,5'-dicarboxy-2,2'-bipyridyl (1) and 4,4'-dicarboxy-2,2'-bipyridyl (2) are reported. [Rh(1H)3] shows two interpenetrating, homochiral rhombohedral networks linked by short carboxylate-carboxylic acid hydrogen bonds, in which each complex acts as a node for six hydrogen bonds. [Ru(1H2)(1H)2] forms only four such hydrogen bonds, leading to the formation of heterochiral chains held together by stacking between bipyridyls. [Co(2H)3] can in principle form six hydrogen bonds, but in practice forms only four in a layer structure where stacking interactions are important. This is attributed to differences in molecular shape.
Matthews
Craig J
CJ
Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, 30 quai Ernest Ansermet, CH 1211 Geneva 4, Switzerland.
Elsegood
Mark R J
MR
Bernardinelli
Gérald
G
Clegg
William
W
Williams
Alan F
AF
D015082:2,2'-Dipyridyl / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D012428:Ruthenium / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D003035:Cobalt; D015082:2,2'-Dipyridyl; D012428:Ruthenium