Inverse dependency of particle residence times in ponds to the concentration of phosphate, the limiting nutrient.
234Th, a commonly used short-lived particle-reactive tracer in marine systems, was measured in three different holding pond series at the Rocky Flats Environmental Technology Site (RFETS), Colorado, along with its parent nuclide 238U, to determine steady-state residence times of particle-reactive actinides such as Pu, and of particles. Series B ponds, which received industrial effluent that includes ortho-phosphate (PO4) and actinides, differed from series A and C ponds, which did not. This difference was also evident in the calculated particle residence times, which were <1 day for the ponds B4 and B5, where PO4 concentrations were higher (1.4 and 1.8 mg/l), and 3 and 3.4 days for ponds A3 and C2, respectively, where ortho-phosphate concentrations were lower (<0.1 mg/l). Particle residence times thus showed an inverse relationship with the concentration of ortho-phosphate, the limiting nutrient in fresh water systems. The same relationship to the concentration of ortho-phosphate or any of the other nutrient elements was not evident for the residence times of dissolved 234Th, which ranged between 0.1 and 2 days. This can be attributed to higher concentrations of dissolved and particulate ligands with greater binding potential for actinides such as four-valent Th and Pu in ponds with higher ortho-phosphate concentrations. Regardless of actual ortho-phosphate concentration, however, at water residence (holding) times of 1 month in these ponds, particles and associated actinides would be expected to be completely removed from the pond water to sediments.
Roberts
Kimberly A
KA
Laboratory for Oceanographic and Environmental Research (LOER), Texas A&M University, 5007 Ave U, Galveston, TX 77551, USA. robertsk@tamug.tamu.edu
Santschi
Peter H
PH
D000327:Adsorption; D008024:Ligands; D010710:Phosphates / Q000032:analysis*; D013910:Thorium / Q000032:analysis*; D014867:Water / Q000737:chemistry; D014875:Water Pollutants, Radioactive / Q000032:analysis*
D008024:Ligands; D010710:Phosphates; D014875:Water Pollutants, Radioactive; D014867:Water; D013910:Thorium