title: On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction.
abstract: The formation and reactivity of surface intermediates in the reverse water-gas-shift reaction on a Pt/CeO2 catalyst are critically dependent on the reaction conditions so that conclusions regarding the reaction mechanism cannot be inferred using ex operando conditions.
authors.affiliation: CenTACat, School of Chemistry, Queen's University Belfast, Belfast, Northern Ireland BT41 1PB.
authors.forename: Daniele
authors.initials: D
authors.lastname: Tibiletti
authors.forename: Alexandre
authors.initials: A
authors.lastname: Goguet
authors.forename: Frederic C
authors.initials: FC
authors.lastname: Meunier
authors.forename: John P
authors.initials: JP
authors.lastname: Breen
authors.forename: Robbie
authors.initials: R
authors.lastname: Burch