Landau-de Gennes model for nonuniform configurations in nematic liquid crystalline elastomers.
Through a mean field theory, an elastic free energy describing the nonuniform elastic textures observed in nematic elastomers, is proposed. To construct it, an order parameter that describes the nematic-isotropic phase transition through the change of the elastic properties of the strain tensor at the transition point is introduced. The resulting elastic free energy can be written in a form that resembles the Frank free energy of the usual nematic liquid crystals, becoming equivalent to it when the size of the elastic nematic domains is a fixed constant along the whole sample. Using this approach, a model for nonhomogeneous deformations found by Macromolecules 33, 7675 (2000)] in elastomeric thin films of urethane/urea is proposed.
Simões
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Departamento de Física, Universidade Estadual de Londrina, Campus Universitário, 86051-990 - Londrina (PR), Brazil. simoes@uel.br
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