title: Simple synthesis of an allenylidene heptavalent rhenium(d0) complex.
abstract: This paper reports a simple way to synthesize an allenylidene rhenium(VII) complex. The diimido adamantyl-thiolato allenylidene rhenium(VII) complex 2 was obtained through a metathetical reaction of phosphonioalkylidyne rhenium complex 1 with diphenylketene and also structurally analyzed with X-ray diffraction. Complex 2 is the first d0 allenylidene complex with structure information.
authors.affiliation: Fachbereich Chemie der Philipps-Universitaet Marburg, Hans-Meerwein-Strasse, 35032 Marburg, Germany. xli63@sdu.edu.cn
authors.forename: Xiaoyan
authors.initials: X
authors.lastname: Li
authors.forename: Markus
authors.initials: M
authors.lastname: Schopf
authors.forename: Jürgen
authors.initials: J
authors.lastname: Stephan
authors.forename: Jennifer
authors.initials: J
authors.lastname: Kippe
authors.forename: Klaus
authors.initials: K
authors.lastname: Harms
authors.forename: Jörg
authors.initials: J
authors.lastname: Sundermeyer