PtCl(PHCy2)[(PCy2O)2H]: a hydrogen bonded phosphinito complex obtained by direct reaction of molecular oxygen with a terminal phosphido complex.
Exposure of solid trans-[Pt(PHCy2)2(PCy2)Cl] (1) to dry oxygen unexpectedly leads to [PtCl(PHCy2)[(PCy2O)2H]] (2) as the major product, the formation of which has been followed by NOESY 1H NMR techniques.
Mastrorilli
Piero
P
Dipartimento di Ingegneria delle Acque e di Chimica del Politecnico di Bari, via Orabona 4, I-70125 Bari, Italy. p.mastrorilli@poliba.it
Latronico
Mario
M
Nobile
Cosimo Francesco
CF
Suranna
Gian Paolo
GP
Fanizzi
Francesco Paolo
FP
Englert
Ulli
U
Ciccarella
Giuseppe
G