Localization and freezing of a Gaussian chain in a quenched random potential.
The Gaussian chain in a quenched random potential (which is characterized by the disorder strength Delta) is investigated in the d-dimensional space by the replicated variational method. The general expression for the free energy within so-called one-step-replica symmetry breaking (1-RSB) scenario has been systematically derived. We have shown that the replica symmetrical (RS) limit of this expression can describe the chain center-of-mass localization and collapse. The critical disorder when the chain becomes localized scales as Delta(c) approximately b(d)N(-2+d/2) (where b is the length of the Kuhn segment length and N is the chain length) whereas the chain gyration radius R(g) approximately b(b(d)/Delta)(1/(4-d)). The freezing of the internal degrees of freedom follows to the 1-RSB-scenario and is characterized by the beads localization length D(2). It was demonstrated that the solution for D(2) appears as a metastable state at Delta=Delta(A) and behaves similarly to the corresponding frozen states in heteropolymers or in p-spin random spherical model.
Rostiashvili
Vakhtang G
VG
Max Planck Institute for Polymer Research, 10 Ackermannweg, 55128 Mainz, Germany.
Vilgis
Thomas A
TA