title: S-ethyl N-benzoyldithiocarbamate: two independent hydrogen-bonded R(2)2(8) dimers of different symmetry linked into chains by a C-H...pi(arene) interaction.
abstract: The title compound, C10H11NOS2, crystallizes with Z' = 2 in space group C2/c. The molecules are linked by two N-H...S hydrogen bonds [H...S = 2.60 and 2.62 A, N...S = 3.350 (2) and 3.490 (2) A, and N-H...S = 143 and 172 degrees] into two distinct types of R(2)2(8) dimer, viz. one generated by inversion and the other by a twofold rotation axis. A single C-H...pi(arene) hydrogen bond links the two types of dimer into chains.
authors.affiliation: Department of Chemistry, University of Aberdeen, Meston Walk, Old Aberdeen AB24 3UE, Scotland.
authors.forename: John N
authors.initials: JN
authors.lastname: Low
authors.forename: Justo
authors.initials: J
authors.lastname: Cobo
authors.forename: Henry
authors.initials: H
authors.lastname: Insuasty
authors.forename: Martin
authors.initials: M
authors.lastname: Estrada
authors.forename: Edward
authors.initials: E
authors.lastname: Cortés
authors.forename: Christopher
authors.initials: C
authors.lastname: Glidewell