Synthesis, reactivity, and ligand properties of a stable alkyl carbene.
Stable tert-butyl diisopropylamino carbene is more nucleophilic but also more electrophilic than diamino carbenes; it undergoes cyclopropanation reactions and easily binds to metal fragments.
Lavallo
Vincent
V
UCR-CNRS Joint Research Chemistry Laboratory (UMR 2282), Department of Chemistry, University of California, Riverside, California 92521-0403, USA.
Mafhouz
John
J
Canac
Yves
Y
Donnadieu
Bruno
B
Schoeller
Wolfgand W
WW
Bertrand
Guy
G