Unexpected formation of a novel macrocyclic tetraphosphine: (RSSR)-1,9-dibenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-tetraphosphacyclohexadecane.
The title compound was synthesised in moderate yield via stereoselective self-assembly of two bisphosphine, four formaldehyde and two primary amine molecules.
Naumov
Roman N
RN
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Kazan Scientific Center, Arbuzov str. 8, Kazan, Russian Federation, 420088.
Karasik
Andrey A
AA
Sinyashin
Oleg G
OG
Lönnecke
Peter
P
Hey-Hawkins
Evamarie
E
D018360:Crystallography, X-Ray; D047028:Macrocyclic Compounds / Q000138:chemical synthesis*; D008958:Models, Molecular; D015394:Molecular Structure; D010720:Phosphines / Q000138:chemical synthesis*
C500566:(RSSR)-1,9-dibenzyl-3,7,11,15-tetramesityl-1,9-diaza-3,7,11,15-tetraphosphacyclohexadecane; D047028:Macrocyclic Compounds; D010720:Phosphines