title: (Salen)tin complexes: syntheses, characterization, crystal structures, and catalytic activity in the formation of propylene carbonate from CO(2) and propylene oxide.
abstract: A series of (salen)tin(II) and (salen)tin(IV) complexes was synthesized. The (salen)tin(IV) complexes, (salen)SnX(2) (X = Br and I), were prepared in good yields via the direct oxidation reaction of (salen)tin(II) complexes with Br(2) or I(2). (Salen)SnX(2) successfully underwent the anion-exchange reaction with AgOTf (OTf = trifluoromethanesulfonate) to form (salen)Sn(OTf)(2) and (salen)Sn(X)(OTf) (X = Br). The (salen)Sn(OTf)(2) complex was easily converted to any of the dihalide (salen)SnX(2) compounds using halide salts. All complexes were fully characterized by (1)H NMR spectroscopy, mass spectrometry, and elemental analysis, while some were characterized by (13)C, (19)F, and (119)Sn NMR spectroscopy. Several crystal structures of (salen)tin(II) and (salen)tin(IV) were also determined. Finally, both (salen)tin(II) and (salen)tin(IV) complexes were shown to efficiently catalyze the formation of propylene carbonate from propylene oxide and CO(2). Of the series, (3,3',5,5'-Br(4)-salen)SnBr(2), 3i, was found to be the most effective catalyst (TOF = 524 h(-)(1)).
authors.affiliation: Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
authors.forename: Huanwang
authors.initials: H
authors.lastname: Jing
authors.forename: Smita K
authors.initials: SK
authors.lastname: Edulji
authors.forename: Julianne M
authors.initials: JM
authors.lastname: Gibbs
authors.forename: Charlotte L
authors.initials: CL
authors.lastname: Stern
authors.forename: Hongying
authors.initials: H
authors.lastname: Zhou
authors.forename: SonBinh T
authors.initials: ST
authors.lastname: Nguyen