Long-time relaxation dynamics of langmuir films of a glass-forming polymer: evidence of glasslike dynamics in two dimensions.
We have carried out an experimental study on the mechanical relaxation of Langmuir films of a glass-forming polymer, poly-(4-hydroxystyrene), a good example of a two-dimensional system made of condensed polymer coils (at poor-solvent conditions). This study allows us to explore the response functions of the film and the temperature and density dependencies of the relaxation time. The dynamical properties show glasslike features (non-Debye mechanical response and non-Arrhenius relaxation times) reconcilable within the frame of the mode-coupling model.
Hilles
Hani M
HM
Departamento de Química Física I, Facultad de Química, Universidad Complutense, Ciudad Universitaria s/n, E28040 Madrid, Spain.
Ortega
Francisco
F
Rubio
Ramón G
RG
Monroy
Francisco
F