Complex morphology of melt-spun nylon-6 fibres investigated by 1H double-quantum-filtered NMR spin-diffusion experiments.
The complex morphology of high-speed melt-spun nylon-6 fibres hydrated with D2O was investigated using 1H double-quantum-filtered spin-diffusion NMR experiments. The magnetisation exchange from selected crystalline domains along the fibrils and interfibrils was simulated with the help of a three-dimensional solution of a spin-diffusion equation approximated by a product of one-dimensional analytical NMR signals, which correspond to a lamellar morphology. This allows to measure the sizes of crystalline and less-mobile amorphous domains along the fibrils, as well as the diameter of the fibrils and interfibril distances. A series of nylon-6 fibres with extreme values of winding speed and draw ratio was investigated. The changes detected in the domain size along the fibrils and interfibrils show the same trend in the data obtained from wide-angle X-ray diffraction and small-angle X-ray scattering.
Buda
A
A
Institut für Technische Chemie und Makromolekulare Chemie, Rheinisch-Westfälische Technische Hochschule, Worringer Weg 1 52056 Aachen, Germany. abuda@mc.rwth-aachen.de
Demco
D E
DE
Blümich
B
B
Litvinov
V M
VM
Penning
J P
JP
D002209:Caprolactam / Q000031:analogs & derivatives* / Q000737:chemistry*; D004058:Diffusion; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008956:Models, Chemical; D011108:Polymers / Q000737:chemistry*; D011522:Protons; D013113:Spin Labels
D011108:Polymers; D011522:Protons; D013113:Spin Labels; C009916:nylon 6; D002209:Caprolactam