title: Efficient acyclic stereocontrol using the tethered aminohydroxylation reaction.
abstract: [reaction: see text] The tethered aminohydroxylation (TA) of acyclic allylic carbamates has been achieved in a stereospecific and stereoselective manner. Unusually high levels of stereocontrol were observed in the oxidation of 1,1-disubstituted substrates.
authors.affiliation: Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford OX1 3TA, UK. tiothy.donohoe@chem.ox.ac.uk
authors.forename: Timothy J
authors.initials: TJ
authors.lastname: Donohoe
authors.forename: Peter D
authors.initials: PD
authors.lastname: Johnson
authors.forename: Richard J
authors.initials: RJ
authors.lastname: Pye
authors.forename: Martine
authors.initials: M
authors.lastname: Keenan