title: A neutral tungsten-eta2-alkyne-1-thio ligand forming a homoleptic Werner type complex with Cu(I).
abstract: The 1-thio-eta2-alkyne-complex [Tp'(CO)2W(BnSCCS)][Tp'= hydrotris(3,5-dimethylpyrazolyl)borate; Bn = benzyl], which was obtained by reductive removal of the benzyl group at the alkyne complex [Tp'(CO)2W(BnSCCSBn)]PF(6), has been established as a ligand in a combined organometallic/Werner type heterobimetallic complex with Cu(I).
authors.affiliation: Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstra[Gernam sz ligature]e 36, 48149, Münster, Germany. seidelww@uni-muenster.de
authors.forename: Wolfram W
authors.initials: WW
authors.lastname: Seidel
authors.forename: Maria D
authors.initials: MD
authors.lastname: Ibarra Arias
authors.forename: Markus
authors.initials: M
authors.lastname: Schaffrath
authors.forename: Klaus
authors.initials: K
authors.lastname: Bergander