The exo and endo isomers of [N,N'-bis(salicylidene)-1,2-diphenyl-(RS,SR)-1,2-ethanediyldiaminato]oxovanadium(IV).
The title complexes, exo- and endo-[VO(C(28)H(22)N(2)O(2))], show monomeric structures with a distorted square-pyramidal coordination. The two phenyl groups on the five-membered N,N'-chelate ring are both on the same side as the oxo ligand for the exo isomer and on opposite sides for the endo isomer.
Hoshina
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Department of Chemistry, Faculty of Science and Technology, Keio University, Hiyoshi 3-14-1, Kohoku-ku, Yokohama 223-8522, Japan.
Tsuchimoto
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Ohba
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