Preparation and characterisation of palladium, platinum and manganese di(organo)carbene complexes from quinolinone and quinolinium precursors.
A series of palladium, platinum and manganese di(organo)carbene complexes have been prepared from 4-chloro-N-methylquinolinone by processes that involve alkylation before or after attachment to the metal unit; the nucleophilic heteroatoms are separated from the C-donor atom by three bonds.
Meyer
Wolfgang H
WH
Department of Chemistry, P/Bag X1, Matieland, 7602, Stellenbosch, South Africa.
Deetlefs
Maggel
M
Pohlmann
Michael
M
Scholz
Roland
R
Esterhuysen
Matthias W
MW
Julius
Gerrit R
GR
Raubenheimer
Helgard G
HG
D018360:Crystallography, X-Ray; D006838:Hydrocarbons; D008345:Manganese / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D015363:Quinolones / Q000737:chemistry*
D006838:Hydrocarbons; D009942:Organometallic Compounds; D015363:Quinolones; C030011:carbene; D008345:Manganese; D010984:Platinum; D010165:Palladium; D008697:Methane