Simple synthesis of an allenylidene heptavalent rhenium(d0) complex.
This paper reports a simple way to synthesize an allenylidene rhenium(VII) complex. The diimido adamantyl-thiolato allenylidene rhenium(VII) complex 2 was obtained through a metathetical reaction of phosphonioalkylidyne rhenium complex 1 with diphenylketene and also structurally analyzed with X-ray diffraction. Complex 2 is the first d0 allenylidene complex with structure information.
Li
Xiaoyan
X
Fachbereich Chemie der Philipps-Universitaet Marburg, Hans-Meerwein-Strasse, 35032 Marburg, Germany. xli63@sdu.edu.cn
Schopf
Markus
M
Stephan
Jürgen
J
Kippe
Jennifer
J
Harms
Klaus
K
Sundermeyer
Jörg
J