(Acetonitrile-N)(o-benzoquinone diimine-N,N')chloro-trans-bis(triphenylphosphine-P)ruthenium(II) hexafluorophosphate 0.25-hydrate.
The Ru atom in the title compound, [RuCl(CH(3)CN){P(C(6)H(5))(3)}(2){C(6)H(4)(NH)(2)}]PF(6).0.25H(2)O, has a six-coordinate octahedral geometry, with a trans arrangement of the triphenylphosphine groups. The asymmetric unit contains two complex molecules and a partially occupied water site. Principal dimensions include Ru-N 1.958 (4)-2.044 (5), Ru-P 2.3897 (16)-2.4092 (15), and Ru-Cl 2.4280 (15) and 2.4295 (16) A
Venegas-Yazigi
Diego
D
Departamento de Química, Facultad de Ciencias, Universidad de Chile, Las Palmeras 3425, Nunoa, Santiago, Chile, and Departamento de Química, Fac. Cs. Nat., Mat. y del M. Amb., Universidad Tecnológica Metropolitana, Av. J. P. Alessandri 1242, Nunoa, Santiago, Chile.
Mirza
Hameed
H
Lever
A. B. P.
AB
Lough
Alan J.
AJ
Costamagna
Juan
J
Latorre
Ramón
R