Rationalisation of weak ferromagnetism in manganese(III) chains: the relation between structure and ordering phenomena.
The synthesis, structure and magnetic properties of the one-dimensional chain compounds [Mn(cyclam)(SO4)]ClO4.H2O (1) and [Mn(cyclam)(HCOO)](CF3SO3)(ClO4) (2) are reported. Cyclam is the cyclic tetradentate ligand 1,4,7,11-tetraazacyclotetradecane. Both chain compounds exhibit antiferromagnetic interactions within the chains. A magnetic ordering phase transition at 5.5 K in (1) is investigated by magnetisation measurements along the three principal crystallographic axes of a single crystal and the results show unambiguously that the ferromagnetic ordering is only taking place along one crystallographic axis. The spin structure of the magnetic ordered phase and the magnitude of the ferromagnetic moment are correlated with the crystal structure and symmetry of the compound.
Mossin
Susanne
S
Department of Chemistry, University of Copenhagen, Denmark.
Weihe
Høgni
H
Sørensen
Henning Osholm
HO
Lima
Nicola
N
Sessoli
Roberta
R
D018360:Crystallography, X-Ray; D006571:Heterocyclic Compounds / Q000737:chemistry; D008280:Magnetics; D017895:Manganese Compounds / Q000737:chemistry*; D008958:Models, Molecular; D013696:Temperature
D006571:Heterocyclic Compounds; D017895:Manganese Compounds