On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction.
The formation and reactivity of surface intermediates in the reverse water-gas-shift reaction on a Pt/CeO2 catalyst are critically dependent on the reaction conditions so that conclusions regarding the reaction mechanism cannot be inferred using ex operando conditions.
Tibiletti
Daniele
D
CenTACat, School of Chemistry, Queen's University Belfast, Belfast, Northern Ireland BT41 1PB.
Goguet
Alexandre
A
Meunier
Frederic C
FC
Breen
John P
JP
Burch
Robbie
R