Luminescent homochiral silver(I) lamellar coordination networks built from helical chains.
The reactions of 2,2'-dimethoxy-1,1'-binaphthyl-3,3'-bis(4-vinylpyridine)(L) with AgNO3 or AgClO4 at 70 degrees C gave rise to two novel luminescent homochiral lamellar coordination polymers, AgL2X (X = NO3- for 1 or ClO4- for 2), which are built from linking helical chains by Ag(I) atoms as hinges.
Wu
Chuan-De
CD
Department of Chemistry, CB#3290, University of North Carolina, Chapel Hill, NC 27599, USA.
Ngo
Helen L
HL
Lin
Wenbin
W