The observation of superparamagnetic behavior in molecular nanowires.
Using the anionic precursor [(Tp)Fe(CN)3]-, a new one-dimensional Ising cyanide-bridged chain, [(Tp)2FeIII2(CN)6Cu(CH3OH).2CH3OH]n, has been prepared. The crystal structure and magnetic studies demonstrate that it is a single-chain magnet and the blocking temperature is ca. 6 K.
Wang
Shi
S
Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China.
Zuo
Jing-Lin
JL
Gao
Song
S
Song
You
Y
Zhou
Hong-Cai
HC
Zhang
Yuan-Zhu
YZ
You
Xiao-Zeng
XZ