title: Hydrolysis of CpTiCl2(TEMPO) and its application on one-pot syntheses of CpTiCl(OR)2 complexes.
abstract: The eta1-hydroxylamido half-titanocene complex, CpTiCl2(TEMPO) 1, hydrolyzes extremely efficiently to generate (CpTiClO)4 and the protonated hydroxylamine. The efficient hydrolysis chemistry provides selective syntheses of CpTi dialkoxide and diaryloxide complexes.
authors.affiliation: Department of Chemistry, Stanford University, Stanford, CA 94305, USA.
authors.forename: Kuo-Wei
authors.initials: KW
authors.lastname: Huang
authors.forename: Robert M
authors.initials: RM
authors.lastname: Waymouth
mesh_terms: D003497:Cyclic N-Oxides / Q000737:chemistry; D003517:Cyclopentanes / Q000737:chemistry; D006868:Hydrolysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D014025:Titanium / Q000737:chemistry*
chemical_list: D003497:Cyclic N-Oxides; D003517:Cyclopentanes; D009942:Organometallic Compounds; D014025:Titanium; C003959:TEMPO