title: Open, cyclic, and bicyclic compounds of double silylated phosphorus and boron.
abstract: Salt elimination reactions of tris(trimethylsilyl)silyl potassium (1), and two 1,4-dipotassiooligosilanes (3, 5) with 2,2,6,6-tetramethylpiperidinodichloroborane and diethylaminodichlorophosphane have generated open (2), cyclic (4) and bicyclic (6) bora- and phosphaoligosilanes. A monosilylated phosphane and the two five-membered cyclosilanes have been subjected to single crystal X-ray diffraction analysis.
authors.affiliation: Institut für Anorganische Chemie, Technische Universität Graz, Stremayrgasse 16, A-8010, Graz, Austria.
authors.forename: Jelena
authors.initials: J
authors.lastname: Markov
authors.forename: Roland
authors.initials: R
authors.lastname: Fischer
authors.forename: Harald
authors.initials: H
authors.lastname: Wagner
authors.forename: Nadja
authors.initials: N
authors.lastname: Noormofidi
authors.forename: Judith
authors.initials: J
authors.lastname: Baumgartner
authors.forename: Christoph
authors.initials: C
authors.lastname: Marschner