title: Photodissociation of HCl and small (HCl)m complexes in and on large Ar n clusters.
abstract: Photodissociation experiments were carried out at 193 nm for single HCl molecules which are adsorbed on the surface of large Ar n clusters and small (HCl)m complexes which are embedded in the interior of these clusters. For the surface case the size dependence is measured for the average sizes n=140-1000. No cage exit events are observed in agreement with the substitutional position of the molecule deeply buried in the outermost shell. This result is confirmed by a molecular dynamics simulation of the pickup process under realistic conditions concerning the experiment and the interaction potentials. The calculations of the dissociation process employ the surface hopping model. For the embedded case the average sizes covered are m=3 and 6 and n=8-248. The kinetic energy of the H atom fragments is measured exhibiting peaks at zero and around 2.0 eV which mark completely caged and unperturbed fragments, respectively. The ratio of theses peaks strongly depends on the cluster size and agrees well with theoretical predictions for one and two closed icosahedral shells, in which the nonadiabatic coupling of all states was accounted for.
authors.affiliation: Max-Planck-Institut fur Stromungsforschung, Bunsenstrasse 10, 37073 Gottingen, Germany.
authors.forename: N Hendrik
authors.initials: NH
authors.lastname: Nahler
authors.forename: Michal
authors.initials: M
authors.lastname: Farnik
authors.forename: Udo
authors.initials: U
authors.lastname: Buck
authors.forename: Holger
authors.initials: H
authors.lastname: Vach
authors.forename: R Benny
authors.initials: RB
authors.lastname: Gerber