title: [CoAu2(CN)4(NITpPy)2(H2O)2]n: a new 2-D interdigitating complex containing dicyanoaurate(I) anion, a radical, and cobalt(II) ion incorporating gold...gold and hydrogen bonding interactions.
abstract: A novel complex, [[CoAu2(CN)4(NITpPy)2(H2O)2]]n, 1, containing the cobalt(II) ion, dicyanoaurate(I) anion, and nitronyl nitroxide radical building blocks, has been prepared and structurally characterized by single-crystal X-ray analysis. The structure of complex 1 illustrates that aurophilicity and hydrogen bonding interactions increase dimensionality, generating a 2-D interdigitating system. The spectroscopic and magnetic properties have been investigated.
authors.affiliation: Department of Chemistry, Nankai University, Tianjin 300071, P. R. China.
authors.forename: Hui-Bo
authors.initials: HB
authors.lastname: Zhou
authors.forename: Shu-Ping
authors.initials: SP
authors.lastname: Wang
authors.forename: Wen
authors.initials: W
authors.lastname: Dong
authors.forename: Zhan-Quan
authors.initials: ZQ
authors.lastname: Liu
authors.forename: Qing-Lun
authors.initials: QL
authors.lastname: Wang
authors.forename: Dai-Zheng
authors.initials: DZ
authors.lastname: Liao
authors.forename: Zong-Hui
authors.initials: ZH
authors.lastname: Jiang
authors.forename: Shi-Ping
authors.initials: SP
authors.lastname: Yan
authors.forename: Peng
authors.initials: P
authors.lastname: Cheng