Calorimetric studies of the association of chitin and chitosan with sodium dodecyl sulfate.
The interaction of hydrophobic chitin and chitosan with sodium dodecyl sulfate (SDS) has been studied by titration calorimetry at 298.15K. The nature of interaction of the surfactant and biopolymers was followed by enthalpy interaction profiles. The mixing enthalpy curves were determined by mixing SDS solutions above their critical micelle concentration with chitin and chitosan suspensions in different concentrations. The Gibbs free energy of aggregation values were -23.21, -22.71 and -21.53 kJ mol(-1) for chitin in 0.02, 0.05 and 0.1% concentration, respectively, and 28.30, 24.38 and 24.20 kJ mol(-1) for chitosan in 0.02, 0.05 and 0.1% concentration, respectively. The critical aggregation concentration (cac) obtained by calorimetric data gave 6.32, 7.07 and 9.14 mmol kg(-1) in 0.02, 0.05 and 0.1% concentration, respectively, for chitin and 2.09, 4.91 and 5.11 mmol kg(-1) for chitosan in 0.02, 0.05 and 0.1% concentration, respectively.
Prado
Alexandre G S
AG
Instituto de Química, Universidade de Brasília, Caixa Postal 4478, 70919-970 Brasília, Distrito Federal, Brazil. agsprado@unb.br
Macedo
Julio L
JL
Dias
Sílvia C L
SC
Dias
José A
JA
D002151:Calorimetry / Q000379:methods; D002240:Carbohydrate Sequence; D002686:Chitin / Q000737:chemistry*; D048271:Chitosan / Q000737:chemistry*; D008969:Molecular Sequence Data; D012967:Sodium Dodecyl Sulfate / Q000737:chemistry*; D013816:Thermodynamics
D002686:Chitin; D012967:Sodium Dodecyl Sulfate; D048271:Chitosan