Tunneling-induced spin alignment at low and zero field.
The transfer of rotational to spin angular momentum of CH3 groups according to the Haupt effect is shown to be independent of magnetic field strength, including zero field. Haupt enhanced pulsed nuclear resonance signals of gamma-picoline have been observed at fields below 50 mT with a sensitivity enhancement of more than 3 orders of magnitude over thermally polarized experiments.
Physical Chemistry, ETH-Zurich, CH-8093 Zurich, Switzerland. mato@nmr.phys.chem.ethz.ch
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