Electric-field-induced g/u mixing of the E0g+(3P2) and D0u+(3P2) ion-pair states of jet-cooled I2 observed using optical triple resonance.
Electric-field-induced electronic state g/u mixing of nearly isoenergetic rovibrational levels of the E0g+(3P2) and D0u+(3P2) ion-pair states of I2 has been observed using optical triple resonance combined with resonance ionization. Detectable mixing with applied fields of 1 kV/cm occurs over a range of energy level separations of < or = 0.3 cm(-1).
Sjödin
A Marica
AM
School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh EH9 3JJ, Scotland, United Kingdom.
Ridley
Trevor
T
Lawley
Kenneth P
KP
Donovan
Robert J
RJ