Tris(thioacetals) from benzene hexathiol: towards covalent self-assembly.
Mixtures of isomers are available from the reaction of benzene hexathiol with three equivalents of p-tolualdehyde and kinetic traps avoided under the reported catalytic conditions, establishing tris(thioacetals) as potential building blocks for covalently self-assembled complex structures.
Institut fur Organische Chemie, Universitat Erlangen-Nurnberg, Henkestrasse 42, D-91054 Erlangen, Germany. l_r_sutton@yahoo.co.uk
Liam R
LR
Sutton
Wolfgang A
WA
Donaubauer
Frank
F
Hampel
Andreas
A
Hirsch