Structural characterization and luminescence behavior of a silver(I) 1D polymeric chain constructed via a Bridge with unusual 4,5-diazospirobifluorene and perchlorate.
A new polymeric silver complex, [Ag(2)(L(2))(ClO(4))(2)] (L = 4,5-diazospirobifluorene), has been synthesized and shown to exhibit interesting luminescence properties in a single crystal. Structural analysis reveals a one-dimensional chain, which contains a [Ag(2)(L(2))](2+) dimer bridged with ClO(4)(-). The Ag...Ag distances are 2.776(1) and 4.575(1) A incorporated by two L ligands and by a ClO(4)(-) bridge, respectively.
Department of Chemistry, Soochow University, Taipei, Taiwan 111, R.O.C. ccwang@mail.scu.edu.tw
Chih-Chieh
CC
Wang
Cheng-Han
CH
Yang
Shih-Min
SM
Tseng
Sue-Yi
SY
Lin
Ti-Yu
TY
Wu
Ming-Ren
MR
Fuh
Gene-Hsiang
GH
Lee
Ken-Tsung
KT
Wong
Ruei-Tang
RT
Chen
Yi-Ming
YM
Cheng
Pi-Tai
PT
Chou