Vibrational spectra and ab initio analysis of tert-butyl, trimethylsilyl, and trimethylgermyl derivatives of 3,3-dimethylcyclopropene. VI: Application of observed trends to stannyl derivatives.
The effects of substitution of X = C by Si or Ge in X(CH(3))(3) moieties attached to the formal double bond of 3,3-dimethylcyclopropene are examined. Regularities in observed trends of vibrational frequencies implicating the moieties containing the X atom, as the X atomic mass is increased, are extrapolated to X = Sn. The results of this extrapolation made it possible to assign the known experimental vibrational frequencies of 3,3-dimethyl-1-(trimethylstannyl)cyclopropene and 3,3-dimethyl-1,2-bis(trimethylstannyl)cyclopropene.
Panchenko
Yu N
YN
Laboratory of Molecular Spectroscopy, Division of Physical Chemistry, Department of Chemistry, M.V. Lomonosov Moscow State University, 119899 Moscow, Russia.
De Maré
G R
GR
Abramenkov
A V
AV
Baird
M S
MS
Tverezovsky
V V
VV
Nizovtsev
A V
AV
Bolesov
I G
IG
D003521:Cyclopropanes / Q000737:chemistry*; D005857:Germanium / Q000737:chemistry*; D013057:Spectrum Analysis; D014001:Tin / Q000737:chemistry*; D014297:Trimethylsilyl Compounds / Q000737:chemistry*
D003521:Cyclopropanes; D014297:Trimethylsilyl Compounds; D005857:Germanium; D014001:Tin; C021985:cyclopropene