Protonation of a lanthanum phosphide-alkyl occurs at the P-La not the C-La bond: isolation of a cationic lanthanum alkyl complex.
Protonation of the heteroleptic, cyclometalated lanthanum phosphide complex [((Me3Si)2CH)(C6H4-2-CH2NMe2)P]La(THF)[P(C6H4-2-CH2NMe2)(CH(SiMe3)(SiMe2CH2))] with [Et3NH][BPh4] yields the cationic alkyllanthanum complex [(THF)4La[P(C6H4-2-CH2NMe2)(CH(SiMe3)(SiMe2CH2))]][BPh4].
Chemistry, School of Natural Sciences, University of Newcastle, Bedson Building, Newcastle upon Tyne NE1 7RU, UK. k.j.izod@ncl.ac.uk
Keith
K
Izod
Stephen T
ST
Liddle
William
W
Clegg