Studies on 1H NMR, infrared and fluorescence spectra of rare earth complexes with a new binaphthylamide.
Solid complexes of lanthanide picrates with N,N-dibenzyl-2-[2'-[(dibenzylcarbamoyl)-methoxy]-[1,1']binaphthalenyl-2-yloxy]-acetamide (L), [Ln(pic)(3)L] (Ln = La, Nd, Eu, Gd, Tb, Dy, Y), have been prepared and characterized by elemental analysis, IR, 1H NMR, UV-Vis spectra and conductivity measurements. The fluorescence property of the europium complex in solid state and in CHCl(3), acetone, AcOEt and DMF was studied.
Wang
Ya-Wen
YW
Department of Chemistry and National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, PR China.
Liu
Wei-Sheng
WS
Tang
Ning
N
Tan
Min-Yu
MY
D000081:Acetamides / Q000737:chemistry*; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D013050:Spectrometry, Fluorescence; D013055:Spectrophotometry, Infrared
D000081:Acetamides; D028581:Lanthanoid Series Elements; D008024:Ligands