Incommensurate nature of the multilayered molecular ferromagnetic metals based on bis(ethylenedithio)tetrathiafulvalene and bimetallic oxalate complexes.
The salt [ET]x[MnRh(ox)(3)].CH(2)Cl(2) (x = 2.526(1)) has been obtained and characterized. This paramagnetic metal is essentially isostructural to the ferromagnetic metal [ET]y[MnCr(ox)(3)].CH(2)Cl(2) (y approximately equal to 3) and provides a definite answer on the origin of the structural disorder present on such systems. As in the ferromagnetic analogue, this material shows high electrical conductivity at room temperature (13 S.cm(-1)) and metallic behavior.
Coronado
Eugenio
E
Instituto de Ciencia Molecular, Universidad de Valencia, Dr. Moliner, 50. E46100-Burjasot, Spain. eugenio.coronado@uv.es
Galán-Mascarós
José R
JR
Gómez-García
Carlos J
CJ
Martínez-Ferrero
Eugenia
E
van Smaalen
Sander
S