A wave packet based statistical approach to complex-forming reactions.
A wave packet based statistical model is suggested for complex-forming reactions. This model assumes statistical formation and decay of the long-lived reaction complex and computes reaction cross sections and their energy dependence from capture probabilities. This model is very efficient and reasonably accurate for reactions dominated by long-lived resonances, as confirmed by its application to the C((1)D)+H(2) reaction.
Department of Chemistry, University of New Mexico, Albuquerque, NM 87131, USA.
Shi Ying
SY
Lin
Hua
H
Guo