Mixed metal bis(mu-oxo) complexes with [CuM(mu-O)2]n+(M = Ni(III) or Pd(II)) cores.
Two highly reactive heterodinuclear bis(mu-oxo) complexes were prepared by combining mononuclear peroxo species with reduced metal precursors at -80 degrees C and were identified by UV-vis, EPR/NMR, and resonance Raman spectroscopy, with corroboration in the case of the CuPd system from density functional calculations.
Department of Chemistry, Center for Metals in Biocatalysis, Supercomputer Institute, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA.
Nermeen W
NW
Aboelella
John T
JT
York
Anne M
AM
Reynolds
Koyu
K
Fujita
Christopher R
CR
Kinsinger
Christopher J
CJ
Cramer
Charles G
CG
Riordan
William B
WB
Tolman
D003300:Copper / Q000737:chemistry*; D006861:Hydrogen Peroxide; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*
D009942:Organometallic Compounds; D010165:Palladium; D003300:Copper; D009532:Nickel; D006861:Hydrogen Peroxide