Dechlorination ability of municipal waste incineration fly ash for polychlorinated phenols.
Pathways of pentachlorophenol dechlorination have been investigated on municipal waste incineration fly ash at 200 degrees C under nitrogen atmosphere. Thermodynamic calculations have been carried out for these dechlorination conditions using the method of total Gibbs energy minimization for the whole system consisting of gaseous components, i.e., chlorinated phenols, phenol, hydrogen chloride and the Cu3Cl3 trimer and of solid Cu2O and CuCl2 components. The effects of water, temperature and of the amounts of the reaction components on the thermodynamic equilibrium have been discussed and the experimental results compared with the calculated thermodynamic data.
Vlková
Leona
L
Institute of Chemical Process Fundamentals, Czech Academy of Sciences, Rozvojová 135, 165 02 Prague 6, Czech Republic.
Pekárek
Vladimír
V
Pacáková
Vera
V
Karban
Jindrich
J
Bures
Michal
M
Stulík
Karel
K
D002244:Carbon / Q000737:chemistry*; D060729:Coal Ash; D008401:Gas Chromatography-Mass Spectrometry; D017745:Incineration; D052638:Particulate Matter; D010416:Pentachlorophenol / Q000032:analysis / Q000737:chemistry*; D013696:Temperature; D013816:Thermodynamics; D014866:Waste Products; D014867:Water / Q000737:chemistry
D060729:Coal Ash; D052638:Particulate Matter; D014866:Waste Products; D014867:Water; D002244:Carbon; D010416:Pentachlorophenol