Synthesis and co-polymerization of an unsaturated 1,5-anhydro-D-fructose derivative.
An unsaturated derivative, 3,6-di-O-acetyl-1,5-anhydro-4-deoxy-D-glycero-hex-3-enopyranos-2-ulose (3), was obtained via regioselective elimination and acetylation of monohydrated 1,5-anhydro-D-fructose (1) in a single step reaction. High yield (80%) was achieved without any dimeric by-products. Its co-polymerization to saccharide polymers was investigated with different commercial vinyl co-monomers. Co-polymers were obtained and characterized.
Deppe
Olaf
O
Institute for Technical Chemistry, Department of Carbohydrate Technology, Technical University of Braunschweig, Langer Kamp 5, 38106 Braunschweig, Germany. o.deppe@tu-bs.de
Glümer
Anke
A
Yu
Shukun
S
Buchholz
Klaus
K
D002236:Carbohydrate Conformation; D005632:Fructose / Q000031:analogs & derivatives* / Q000138:chemical synthesis* / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013055:Spectrophotometry, Infrared
D005632:Fructose