Highly selective formation of linear esters from terminal and internal alkenes catalysed by palladium complexes of bis-(di-tert-butylphosphinomethyl)benzene.
The methoxycarbonylation of terminal or internal alkenes catalysed by palladium complexes of bis-(di-tert-butylphosphinomethyl)benzene under mild conditions leads to linear esters in 99% selectivity via a hydride mechanism.
Jimenez Rodriguez
Cristina
C
School of Chemistry, University of St. Andrews, St. Andrews, Fife, Scotland KY16 9ST, UK.
Foster
Douglas F
DF
Eastham
Graham R
GR
Cole-Hamilton
David J
DJ