Mixed metal bis(mu-oxo) complexes with [CuM(mu-O)2]n+(M = Ni(III) or Pd(II)) cores.
Two highly reactive heterodinuclear bis(mu-oxo) complexes were prepared by combining mononuclear peroxo species with reduced metal precursors at -80 degrees C and were identified by UV-vis, EPR/NMR, and resonance Raman spectroscopy, with corroboration in the case of the CuPd system from density functional calculations.
Aboelella
Nermeen W
NW
Department of Chemistry, Center for Metals in Biocatalysis, Supercomputer Institute, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA.
York
John T
JT
Reynolds
Anne M
AM
Fujita
Koyu
K
Kinsinger
Christopher R
CR
Cramer
Christopher J
CJ
Riordan
Charles G
CG
Tolman
William B
WB
D003300:Copper / Q000737:chemistry*; D006861:Hydrogen Peroxide; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*
D009942:Organometallic Compounds; D010165:Palladium; D003300:Copper; D009532:Nickel; D006861:Hydrogen Peroxide