Adsorption of poly(N-isopropylacrylamide) on glass substrata.
The adsorption of poly(N-isopropylacrylamide) (PNIPAAM), a well known thermosensitive polymer, on glass was investigated by X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM). The polymer was dissolved in water at low (0.02 g/L) and high (2 g/L) concentration and the tested temperatures were below (25 degrees C) and above (50 degrees C) the lower critical solubility temperature (LCST). Whatever the conditions, a smooth layer of adsorbed molecules spread along the surface was observed. The thickness was about twice higher for high concentration compared to low concentration. The cohesion in the adsorbed layer, as revealed by scraping tests performed by AFM, was higher above the LCST than below the LCST. On top of this adsorbed layer, single-chain coils, globules, or aggregates were present, depending on concentration and temperature. The observation of these additional adsorbed entities was poorly reproducible, presumably due to the lack of shear control upon rinsing. These results emphasize the importance of the characterization of surface morphology to interpret amounts of adsorbed polymers.
Callewaert
M
M
Unité de Chime des Interfaces, Université Catholique de Louvain, Croix du Sud 2/18, 1348 Louvain-la-Neuve, Belgium.
Grandfils
Ch
Ch
Boulangé-Petermann
L
L
Rouxhet
P G
PG
D000180:Acrylic Resins / Q000737:chemistry*; D000327:Adsorption; D005898:Glass / Q000737:chemistry*; D018625:Microscopy, Atomic Force; D012995:Solubility; D013499:Surface Properties; D013696:Temperature
D000180:Acrylic Resins; C052970:poly-N-isopropylacrylamide