Studies on 1H NMR, infrared and fluorescence spectra of rare earth complexes with a new binaphthylamide.
Solid complexes of lanthanide picrates with N,N-dibenzyl-2-[2'-[(dibenzylcarbamoyl)-methoxy]-[1,1']binaphthalenyl-2-yloxy]-acetamide (L), [Ln(pic)(3)L] (Ln = La, Nd, Eu, Gd, Tb, Dy, Y), have been prepared and characterized by elemental analysis, IR, 1H NMR, UV-Vis spectra and conductivity measurements. The fluorescence property of the europium complex in solid state and in CHCl(3), acetone, AcOEt and DMF was studied.
Department of Chemistry and National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, PR China.
Ya-Wen
YW
Wang
Wei-Sheng
WS
Liu
Ning
N
Tang
Min-Yu
MY
Tan
D000081:Acetamides / Q000737:chemistry*; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D013050:Spectrometry, Fluorescence; D013055:Spectrophotometry, Infrared
D000081:Acetamides; D028581:Lanthanoid Series Elements; D008024:Ligands