Synthesis and isolation of cobalt hexacyanoferrate/chromate metal coordination nanopolymers stabilized by alkylamino ligand with metal elemental control.
This Communication describes the novel isolation with metal elemental control of cobalt hexacyanoferrate/chromate metal coordination polymers, stabilized by stearylamine (Co-Fe/Cr-SA) as a protecting coordination ligand in a reverse micelle technique. Each Co-Fe/Cr-SA can be isolated with high uniformity of particle size and elemental composition, and the ratio of the metal component depends on the fundamental characteristics of Co-Fe/Cr-SA: the nanopolymer's shape, color, and magnetism.
School of Materials Science, Japan Advanced Institute of Science and Technology (JAIST), 1-1 Asahidai, Tatsunokuchi-machi, Nomi-gun, Ishikawa 923-1292, Japan. myamada@jaist.ac.jp
Mami
M
Yamada
Masaya
M
Arai
Masato
M
Kurihara
Masatomi
M
Sakamoto
Mikio
M
Miyake