Microwave synthesis and characterization of Co-ferrite nanoparticles.
Stable CoFe(2)O(4) nanoparticles have been obtained by co-precipitation using a microwave heating system. Transmission electron microscopy images analysis shows an agglomeration of particles with an average size of about 5 nm, and X-ray diffraction reveals the presence of a pure ferrite nanocrystalline phase. X-ray photoelectron spectroscopy and thermal gravimetric analysis show the presence of organic matter in the range of about 16 wt%. The magnetic response in DC fields is typical for an assembly of single-domain particles. The measured saturation magnetization is slightly larger than the bulk value, probably due to the presence of small amounts of Co and Fe. AC magnetization data indicate the presence of magnetic interactions between the nanoparticles.
Institute of Chemical Process and Environmental Technology, National Research Council of Canada, 200 Montreal Rd., M-12, Ottawa, Ontario K1A 0R6, Canada. farid.bensebaa@nrc.ca
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D003035:Cobalt / Q000737:chemistry*; D005290:Ferric Compounds / Q000138:chemical synthesis*; D046529:Microscopy, Electron, Transmission / Q000379:methods; D008872:Microwaves; D049329:Nanostructures / Q000737:chemistry*; D013499:Surface Properties; D013696:Temperature
D005290:Ferric Compounds; C001215:ferrite; D003035:Cobalt