Four-color hole burning spectra of phenol/ammonia 1:3 and 1:4 clusters.
The hole burning spectra of phenol/ammonia (1:3 and 1:4) clusters were measured by a newly developed four-color (UV-near-IR-UV-UV) hole burning spectroscopy, which is a kind of population labeling spectroscopy. From the hole burning spectra, it was found that single species is observed in an n = 3 cluster, while three isomers are observed simultaneously for n = 4. A possibility was suggested that the reaction efficiency of the hydrogen transfer from the electronically excited phenol/ammonia clusters, which was measured by a comparison with the action spectra of the corresponding cluster, depends on the initial vibronic levels.
Ishiuchi
Shun-Ichi
S
Chemical Resources Laboratory, Tokyo Institute of Technology/PRESTO-JST, Nagatsuta-cho, Midoriku, Yokohama 226-8503, Japan.
Daigoku
Kota
K
Hashimoto
Kenro
K
Fujii
Masaaki
M