Fractional revivals in the rovibrational motion of I2.
Motivated by pump-probe experiments of I(2) in a room-temperature sample, the detection of fractional revivals is investigated using full-dimensional quantum wave packet calculations. It is shown that the structures observed in the pump-probe signal depend sensitively on the probe parameters employed and that the observed signal reflects a particular phase effect between fractional revivals.
Institut für Physikalische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany.
T
T
Lohmüller
V
V
Engel
J A
JA
Beswick
C
C
Meier