Momentum representation of the solute/bath interaction in the dynamic theory of chemical processes in condensed phase.
For the system consisting of the chemically reactive solute immersed in the oscillator bath, we consider an approach based on the solute/medium interaction expressed in terms of momenta rather than coordinates. In the adiabatic representation the medium reorganization effects are suppressed, being hidden in the solute renormalized potential and new spectral density function. The advantage proposed by the bilinear interaction in momentum representation is its spatial uniformity important for approximate dynamical treatments. The procedure of explicit transforming a standard spectral density (coordinate representation of interaction) into the spectral density in adiabatic representation (momentum representation of interaction) is the main new result of the present study. Illustrative calculations for several types of spectral functions are performed. Special discussion is devoted to clarifying the nature of the slow diffusion coordinate, to which the present approach is mainly addressed.
Basilevsky
M V
MV
Karpov Institute of Physical Chemistry, ul. Vorontsovo Pole 10, 105064 Moscow, Russia.
Davidovich
G V
GV
Voronin
A I
AI