Effects of pulse strength, width, and sample spinning speed on the spectral spin diffusion of multiquantum coherences of spin-3/2 quadrupolar nuclei.
The effects of radio-frequency pulse strength, width, and sample spinning speed on the spin-diffusion spectrum of half-integer quadrupolar spins in solids have been studied by theoretical, numerical, and experimental investigations. It is revealed that the line shape of the cross peaks changes nonmonotonically with respect to the change of pulse strength, pulse width, or sample spinning speed. It is also found that the sample spinning speed has much more pronounced influence on the spin diffusion spectral line shape. In many cases of practical importance, the effect of sample spinning must be included in spectral analysis, in contrast to the practice of previous studies. Moreover, this effect can be exploited to further improve the precision in the determination of relative orientation of the electric-field gradient tensors of the exchange partners.
Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, China.
Zhihong
Z
Liu
Feng
F
Deng
Shangwu
S
Ding