Nuclear magnetic shielding and chirality IV. The odd and even character of the shielding response to a chiral potential.
We investigate the odd and even character of the shielding response in a chiral molecule (modeled by a Ne8 helix) when subjected to a chiral potential. We establish that the diastereomeric splittings are a measure of odd powers of Vodd. Implications for diastereomeric, splittings of Xe in handed cages with handed tethers are discussed.
Department of Chemistry M/C-111, University of Illinois at Chicago, Chicago, Illinois 60607-7061, USA.
Devin N
DN
Sears
Cynthia J
CJ
Jameson
Robert A
RA
Harris