[Re6Te8(CN)6][(Ir(CO)(PPh3)2)6](OTf)2 : a new Re6 cluster-supported iridium(I) compound.
A new hexanuclear rhenium cluster encapsulated by six iridium complexes, [Re6Te8(CN)6][(Ir(CO)(PPh3)2)6](OTf)2 (3), which is effective in catalyzing the hydrogenation of p-CH3C6H4C[triple bond]CH to p-CH3C6H4CH=CH2 has been prepared.
Department of Chemistry/Division of Nano Sciences, Ewha Womans University, Seoul 120-750, Korea. sjkim@ewha.ac.kr
Youngmee
Y
Kim
Sehye
S
Kim
Sung-Jin
SJ
Kim
Myung Ki
MK
Lee
Mieock
M
Kim
Hyungeui
H
Lee
Chong Shik
CS
Chin