Phase behavior and critical properties of size-asymmetric, primitive-model electrolytes.
The theory of J. Jiang et al. [J. Chem. Phys. 116, 7977 (2002)] for size-symmetric electrolytes is extended to size-asymmetric electrolytes. When compared to molecular-simulation results, this extension gives the correct trend of critical properties with size asymmetry.
Qin
Yuan
Y
Department of Chemical Engineering, University of California, Berkeley 94720, USA.
Prausnitz
John M
JM