Determination of 4-tert-octylphenol, 4-nonylphenol and bisphenol A in surface waters from the Haihe River in Tianjin by gas chromatography-mass spectrometry with selected ion monitoring.
The estrogenic pollutants 4-tert-octylphenol (OP), 4-nonylphenol (NP) and bisphenol A (BPA) were determined in surface water samples from the Haihe River, Tianjin, China. The analytes were extracted and concentrated from 300 ml acidified water samples by liquid-liquid extractions using dichloromethane, derivatized with trifluoroacetic anhydride, and quantified by gas chromatography-mass spectrometry (GC-MS) with selected ion monitoring (SIM). Among the samples collected from 14 sampling sites, only one sample was found to have a relatively high concentration of BPA (8.30 microgl(-1)) and NP (0.55 microgl(-1)). The concentrations of OP, NP and BPA in the other samples were in the range of 18.0-20.2, 106-296 and 19.1-106 ngl(-1), respectively. Recoveries for OP, NP and BPA in the spiked water samples were all over 80%.
College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China.
Xinglong
X
Jin
Guibin
G
Jiang
Guolan
G
Huang
Jingfu
J
Liu
Qunfang
Q
Zhou
D001559:Benzhydryl Compounds; D002681:China; D004784:Environmental Monitoring / Q000379:methods*; D004968:Estrogens, Non-Steroidal / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry; D010636:Phenols / Q000032:analysis*; D045483:Rivers; D013501:Surface-Active Agents / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis*; D000098826:Bisphenol A Compounds
D001559:Benzhydryl Compounds; D004968:Estrogens, Non-Steroidal; D010636:Phenols; D013501:Surface-Active Agents; D014874:Water Pollutants, Chemical; C025256:nonylphenol; C105260:4-tert-octylphenol; C006780:bisphenol A; D000098826:Bisphenol A Compounds