Heteronuclear polarization transfer by symmetry-based recoupling sequences in solid-state NMR.
We demonstrate a new set of methods for transferring spin polarization between different nuclear isotopes in magic-angle-spinning solid-state NMR. The technique employs symmetry-based recoupling sequences on one irradiation channel and a simple sequence of between one and three strong radiofrequency pulses on the second channel. A phase shift of the recoupling sequences is applied at the same time as a pi/2 pulse on the second channel. The trajectory of the transferred polarization may be used to estimate heteronuclear distances. The method is particularly attractive for nuclei with low gyromagnetic ratios or for those experiencing strong anisotropic spin interactions, where conventional Hartmann-Hahn cross-polarization is difficult to apply. We demonstrate the method on 1H-13C, 1H-15N and 19F-109Ag systems.
Chemistry Department, Southampton University, Highfield, Southampton SO17 1BJ, UK.
Xin
X
Zhao
Wilfried
W
Hoffbauer
Jörn
J
Schmedt auf der Günne
M H Malcolm H
MH
Levitt
D000465:Algorithms; D002244:Carbon / Q000032:analysis*; D005240:Feasibility Studies; D019906:Nuclear Magnetic Resonance, Biomolecular / Q000379:methods*; D011522:Protons; D012399:Rotation; D012815:Signal Processing, Computer-Assisted; D013113:Spin Labels
D011522:Protons; D013113:Spin Labels; D002244:Carbon