Spinodal and ideal glass limits for metastable liquids.
A spinodal line provides a high-temperature limit to the stability of a superheated liquid and a line of ideal glass transitions may provide a low-temperature limit for a supercooled liquid. For models in which the thermodynamic properties depend on only one independent external variable the line of ideal glass transition can be viewed as a second-order transition between two equilibrated phases and it meets the spinodal with the same slope at the maximum tension a stretched liquid can sustain. For real materials there are two independent external variables, temperature and pressure; the line of ideal glass transitions cannot be viewed as a second-order phase transition and the two lines need not have the same slope where they meet.
Speedy
Robin J
RJ
Apartment 504, 120 Courtenay Place, Wellington, New Zealand. robin.speedy@clear.net.nz