Isotropic-liquid crystalline phase diagram of a CdSe nanorod solution.
We report the isotropic-liquid crystalline phase diagram of 3.0 nm x 60 nm CdSe nanorods dispersed in anhydrous cyclohexane. The coexistence concentrations of both phases are found to be lower and the biphasic region wider than the results predicted by the hard rod model, indicating that the attractive interaction between the nanorods may be important in the formation of the liquid crystalline phase in this system.
Li
Liang-Shi
LS
Department of Chemistry, University of California at Berkeley and Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA. alivis@uclink4.berkeley.edu
Marjanska
Malgorzata
M
Park
Gregory H J
GH
Pines
Alexander
A
Alivisatos
A Paul
AP