Nonadiabatic transition in the dissociation process from inner valence states of O(2) (+).
In a previous paper we reported a study of the electronic structures of inner valence states of O(2) (+) and the dissociation process, where there remained some questions as to the origins of the dissociation fragment formation of the O+((2)D)+O((3)P) limit in observed spectra. In this paper, we present the results of calculations of the nonadiabatic transition probabilities of the multichannel dissociation process from the inner valence states of O(2) (+) and reproduce the general features of observed spectra previously reported, including fragment formation, using the Zhu-Nakamura theory.
Hirayama
Ryo
R
Yamamoto
Norifumi
N
Miyoshi
Eisaku
E