Fe-Ga multiple bonding? Synthesis, spectroscopic and structural characterization of a transition metal complex containing a cationic two-coordinate gallium centre.
This communication reports the synthesis and characterization of the cationic iron complex [((eta5-C5Me5)Fe(CO)2))2Ga]+[BAr(f)4]- [Ar(f) = C6H3(CF3)2-3,5] containing a symmetrically bridging two-coordinate gallium atom and a delocalised Fe-Ga-Fe pi system incorporating partial Fe-Ga multiple bond character.
Centre for Fundamental and Applied Main Group Chemistry, School of Chemistry, Cardiff University, PO Box 912, Park Place, Cardiff, Wales CF10 3TB, UK.
Natalie R
NR
Bunn
Simon
S
Aldridge
Deborah L
DL
Coombs
Andrea
A
Rossin
David J
DJ
Willock
Cameron
C
Jones
Li-ling
LL
Ooi