Asymmetric catalytic coupling of organoboranes, alkynes, and imines with a removable (trialkylsilyloxy)ethyl group--direct access to enantiomerically pure primary allylic amines.
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
Sejal J
SJ
Patel
Timothy F
TF
Jamison
D000480:Alkynes / Q000737:chemistry; D000588:Amines / Q000138:chemical synthesis*; D001880:Boranes / Q000737:chemistry; D002384:Catalysis; D007097:Imines / Q000737:chemistry; D013237:Stereoisomerism; D014297:Trimethylsilyl Compounds / Q000737:chemistry
D000480:Alkynes; D000588:Amines; D001880:Boranes; D007097:Imines; D014297:Trimethylsilyl Compounds