Crystal synthesis of hybrid organometallic-inorganic hydrogen bonded salts of acid oxoanions.
Partially deprotonated inorganic oxoanions derived from sulfuric and phosphoric acids have been used to assemble organometallic cations in inorganic-organometallic hybrid systems. The organometallic sandwich cations [(eta(5)-C(5)H(5))(2)Co]+, [(eta(5)-C(5)Me(5))(2)Co]+ and [(eta(5)-C(5)Me(5))(2)Fe]+ have been used because they do not interfere with hydrogen bonding formation forcing self-assembling of the inorganic acids anions HSO(4)(-) and H(2)PO(4)(-) into hydrogen bonded mono- and bi-dimensional networks.
Braga
Dario
D
Dipartimento di Chimica G. Ciamician, Universita di Bologna, Via Selmi 2, 40126 Bologna, Italy. dario.braga@unibo.it
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