Two-component dendritic gel: effect of spacer chain length on the supramolecular chiral assembly.
The present study investigates in detail the physical gelation of toluene induced by the addition of simple aliphatic diamines to a dendritic L-lysine-based peptide. The gel-phase material obtained was characterized using differential scanning calorimetry, scanning electron microscopy, small-angle X-ray scattering, circular dichroism, 1H NMR, and X-ray diffraction. When the length of the aliphatic diamine is incrementally increased (C6-C12), the thermally reversible gel-sol transition temperature is dramatically increased (4-105 degrees C). This paper shows that the molecular information preset in the diamine is transcribed into the supramolecular assembly on the microscale and that this, in turn, controls the highly tunable macroscopic materials properties. The results also demonstrate the importance of chirality in the assembly process and highlight the role played by the aliphatic diamine in modulating the transcription of chirality from the molecular to the microscopic level.
Hirst
Andrew R
AR
Department of Chemistry, University of York, Heslington, York, YO10 5DD, United Kingdom.
Smith
David K
DK
Feiters
Martin C
MC
Geurts
Huub P M
HP