The cation as a tool to get spin-canted three-dimensional ironIII networks.
Alkyl-substituted ammonium cations (X) allow the preparation of a series of spin-canted oxo- and oxalato-bridged three-dimensional iron(III) networks, exhibiting magnetic ordering at T(c) values ranging from 40 to 56 K. The value of T(c) varies with the cation despite the lack of significant structural modifications.
Armentano
Donatella
D
Dipartimento di Chimica, Università degli Studi della Calabria, 87030 Arcavacata di Rende, Cosenza, Italy.
De Munno
Giovanni
G
Mastropietro
Teresa F
TF
Proserpio
Davide M
DM
Julve
Miguel
M
Lloret
Francesc
F