Coordination polymer incorporating maleonitriledithiolate copper clusters: electrocrystallization synthesis and crystal structure of (NPr4)2[Cu(MeCN)]2[Cu8(i-mnt)6].(MeCN)0.5.(THF)0.25.
(NPr4)2[Cu(MeCN)]2[Cu8(i-mnt)6].(MeCN)0.5.(THF)0.25 is prepared by electrocrystallization of a solution of (NPr(4))(4)[Cu(I)(8)(i-mnt)(6)]; the crystal structure consists in bidimensional layers characterised by coordination of copper atoms by the cyano groups of the iso-maleonitriledithiolate ligand of the octa-copper cluster.
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Sandrine
S
Perruchas
Kamal
K
Boubekeur