Synthesis of readily cleavable immobilized 1,10-phenanthroline resins.
1,10-Phenanthroline is derivatized and ultimately immobilized on two different polystyrene/divinylbenzene solid supports using convenient methodology. All syntheses are amenable to semiautomatic processing and are scalable for high-throughput screening. A domino copper-catalyzed coupling-cyclization reaction is used to illustrate applicability in catalytic studies.
Slough
Greg A
GA
Chemistry Department, Kalamazoo College, 1200 Academy Street, Kalamazoo Michigan 49006, USA. gslough@kzoo.edu
Krchnák
Viktor
V
Helquist
Paul
P
Canham
Stephen M
SM