Mononuclear nitrogen/sulfur-ligated cobalt(II) methoxide complexes: structural, EPR, paramagnetic 1H NMR, and electrochemical investigations.
The first examples of mononuclear nitrogen/sulfur-ligated Co(II) alkoxide complexes, species of relevance to a reactive intermediate observed for Co(II)-substituted liver alcohol dehydrogenase, have been isolated and characterized by multiple methods including X-ray crystallography, EPR, paramagnetic (1)H NMR, and cyclic voltammetry.
Department of Chemistry and Biochemistry, Utah State University, 0300 Old Main Hill, Logan, UT 84322-0300, USA.
Kyle J
KJ
Tubbs
Ewa
E
Szajna
Brian
B
Bennett
Jason A
JA
Halfen
Rex W
RW
Watkins
Atta M
AM
Arif
Lisa M
LM
Berreau
D000426:Alcohol Dehydrogenase / Q000737:chemistry; D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004563:Electrochemistry; D004578:Electron Spin Resonance Spectroscopy; D008099:Liver / Q000201:enzymology; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D009584:Nitrogen / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry*
D003035:Cobalt; D013455:Sulfur; D000426:Alcohol Dehydrogenase; D009584:Nitrogen