Structural evolution of a two-component organogel.
Dry reverse micelles of AOT in isooctane spontaneously undergo a microstructural transition to an organogel upon the addition of a phenolic dopant, p-chlorophenol. This microstructural evolution has been studied through a combination of light scattering, small-angle neutron scattering (SANS), NMR, and rheology. Several equilibrium stages between the system of dry reverse micelles of AOT and a 1:1 AOT/p-chlorophenol (molar ratio) gel in isooctane have been examined. To achieve this, p-chlorophenol is added progressively to the dilute solutions of AOT in isooctane, and this concentration series is then analyzed. The dry micelles of AOT in isooctane do not undergo any detectable structural change up to a certain p-chlorophenol concentration. Upon a very small increment in the concentration of p-chlorophenol beyond this "threshold" concentration, large strandlike aggregates are observed which then evolve to the three-dimensional gel network.
Department of Chemical and Biomolecular Engineering, Tulane University, New Orleans, Louisiana 70118, USA.
Mohit
M
Singh
Grace
G
Tan
Vivek
V
Agarwal
Gerhard
G
Fritz
Karol
K
Maskos
Arijit
A
Bose
Vijay
V
John
Gary
G
McPherson
D002733:Chlorophenols / Q000737:chemistry; D004143:Dioctyl Sulfosuccinic Acid / Q000737:chemistry*; D005782:Gels / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008823:Micelles; D018625:Microscopy, Atomic Force; D009795:Octanes / Q000737:chemistry; D009930:Organic Chemicals / Q000737:chemistry*; D012212:Rheology; D012542:Scattering, Radiation; D013501:Surface-Active Agents / Q000737:chemistry*
D002733:Chlorophenols; D005782:Gels; D008823:Micelles; D009795:Octanes; D009930:Organic Chemicals; D013501:Surface-Active Agents; D004143:Dioctyl Sulfosuccinic Acid; C029107:4-chlorophenol; C045798:2,2,4-trimethylpentane