New perspectives in hydroformylation: a para-hydrogen study.
NMR studies on the reaction of Ir(CO)(PPh(3))(2)(eta(3)-C(3)H(5)) with para-H(2) and CO enable the complete mapping of the hydroformylation mechanism for an iridium monohydride catalyst via the detection of species which include iridium acyl and alkyl dihydride intermediates.
Godard
Cyril
C
Department of Chemistry, University of York, Heslington, York, UK.
Duckett
Simon B
SB
Henry
Celine
C
Polas
Stacey
S
Toose
Robert
R
Whitwood
Adrian C
AC