Molecular wire formation from viologen assemblies.
The adsorption behavior of viologen alpha,omega-dithiols (viologen dithiols) on gold has been investigated. At short exposures, a low-coverage phase consisting of flat-lying molecules has been determined by STM and IR spectroscopy. In contrast, multilayer films are formed after long adsorption times. Single molecular wires could be formed between a gold STM tip and a surface with a low coverage of the adsorbed dithiols, and their electrical behavior was investigated. Molecular conductivity was determined either by the repeated measurement of I(s) curves or by recording I-V curves for different tip-sample separations. These methods concurred in producing a value of (0.5 +/- 0.1) nS for the single-molecule conductivity of the alpha,omega-viologen dithiol molecule HS-6V6-SH. The high conductivity of HS-6V6-SH, as compared to that of HS-C12-SH, may be related to the low-lying LUMO, which provides a barrier indentation for electron transport in a two-step electron-transfer mechanism.
Centre for Nanoscale Science, Chemistry Department, University of Liverpool, Liverpool L69 7ZD, UK.
Wolfgang
W
Haiss
Harm
H
van Zalinge
Horst
H
Höbenreich
Donald
D
Bethell
David J
DJ
Schiffrin
Simon J
SJ
Higgins
Richard J
RJ
Nichols