Glycosylation with glycosyl benzyl phthalates as a new type of glycosyl donor.
A glucopyranosyl benzyl phthalate, two mannopyranosyl benzyl phthalates, and a 2-deoxyglucopyranosyl benzyl phthalate, which were prepared from the corresponding 1-hydroxy sugars and benzyl hydrogen phthalate, were found to be efficient glycosyl donors in the glycosylations of various glycosyl acceptors using TMSOTf as a promoter.
Centre for Bioactive Molecular Hybrids and Department of Chemistry, Yonsei University, Seoul, 120-749, Korea. kwan@yonsei.ac.kr
Kwan Soo
KS
Kim
Yong Joo
YJ
Lee
Hye Young
HY
Kim
Sung Soo
SS
Kang
Soon Young
SY
Kwon
D006027:Glycosides / Q000138:chemical synthesis / Q000737:chemistry*; D006031:Glycosylation; D008968:Molecular Conformation; D010795:Phthalic Acids / Q000138:chemical synthesis / Q000737:chemistry*
D006027:Glycosides; D010795:Phthalic Acids