Platinum catalysed 3,4- and 1,4-diboration of alpha,beta-unsaturated carbonyl compounds using bis-pinacolatodiboron.
Bis-pinacolatodiboron reacts with [small alpha],[small beta]-unsaturated carbonyl compounds to give 1,4- and unprecedented 3,4-additions in the presence of a second generation Pt(0) catalyst at ambient temperature.
Department of Chemistry, University Science Laboratories, Durham University, South Road, Durham, UK.
Nathan J
NJ
Bell
Andrew J
AJ
Cox
Neil R
NR
Cameron
John S O
JS
Evans
Todd B
TB
Marder
Marcel A
MA
Duin
Cornelis J
CJ
Elsevier
Xavier
X
Baucherel
Arran A D
AA
Tulloch
Robert P
RP
Tooze