A portable automated system for trace gas sampling in the field and stable isotope analysis in the laboratory.
A computer-controllable mobile system is presented which enables the automatic collection of 33 air samples in the field and the subsequent analysis for delta13C and delta18O stable isotope ratios of a carbon-containing trace gas in the laboratory, e.g. CO2, CO or CH4. The system includes a manifold gas source input for profile sampling and an infrared gas analyzer for in situ CO2 concentration measurements. Measurements of delta13C and delta18O of all 33 samples can run unattended and take less than six hours for CO2. Laboratory tests with three gases (compressed air with different pCO2 and stable isotope compositions) showed a measurement precision of 0.03 per thousand for delta13C and 0.02 per thousand for delta18O of CO2 (standard error (SE), n = 11). A field test of our system, in which 66 air samples were collected within a 24-hour period above grassland, showed a correlation of 0.99 (r2) between the inverse of pCO2 and delta13C of CO2. Storage of samples until analysis is possible for about 1 week; this can be an important factor for sampling in remote areas. A wider range of applications in the field is open with our system, since sampling and analysis of CO and CH4 for stable isotope composition is also possible. Samples of compressed air had a measurement precision (SE, n = 33) of 0.03 per thousand for delta13C and of 0.04 per thousand for delta18O on CO and of 0.07 per thousand for delta13C on CH4. Our system should therefore further facilitate research of trace gases in the context of the carbon cycle in the field, and opens many other possible applications with carbon- and possibly non-carbon-containing trace gases.
Paul Scherrer Institute, Laboratory of Atmospheric Chemistry, 5232 Villigen, Switzerland.
Daniel E
DE
Theis
Matthias
M
Saurer
Herbert
H
Blum
Emmanuel
E
Frossard
Rolf T W
RT
Siegwolf
D002245:Carbon Dioxide / Q000032:analysis / Q000737:chemistry; D002247:Carbon Isotopes / Q000032:analysis* / Q000737:chemistry; D002248:Carbon Monoxide / Q000032:analysis / Q000737:chemistry; D004784:Environmental Monitoring / Q000295:instrumentation* / Q000379:methods; D004867:Equipment Design; D019544:Equipment Failure Analysis; D017022:Flow Injection Analysis / Q000295:instrumentation* / Q000379:methods; D005740:Gases / Q000032:analysis* / Q000737:chemistry; D013058:Mass Spectrometry / Q000295:instrumentation* / Q000379:methods; D008697:Methane / Q000032:analysis / Q000737:chemistry; D008832:Microchemistry / Q000295:instrumentation* / Q000379:methods; D008904:Miniaturization; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity
D002247:Carbon Isotopes; D005740:Gases; D002245:Carbon Dioxide; D002248:Carbon Monoxide; D008697:Methane