Difference in icosahedral short-range order in early and late transition metal liquids.
New short-range order data are presented for equilibrium and undercooled liquids of Ti and Ni. These were obtained from in situ synchrotron x-ray diffraction measurements of electrostatically levitated droplets. While the short-range order of liquid Ni is icosahedral, consistent with Frank's hypothesis, significantly distorted icosahedral order is observed in liquid Ti. This is the first experimental observation of distorted icosahedral short-range order in any liquid, although this has been predicted by theoretical studies on atomic clusters.
Lee
G W
GW
Department of Physics, Washington University, St. Louis, Missouri 63130, USA.
Gangopadhyay
A K
AK
Kelton
K F
KF
Hyers
R W
RW
Rathz
T J
TJ
Rogers
J R
JR
Robinson
D S
DS