Structural evolution of a two-component organogel.
Dry reverse micelles of AOT in isooctane spontaneously undergo a microstructural transition to an organogel upon the addition of a phenolic dopant, p-chlorophenol. This microstructural evolution has been studied through a combination of light scattering, small-angle neutron scattering (SANS), NMR, and rheology. Several equilibrium stages between the system of dry reverse micelles of AOT and a 1:1 AOT/p-chlorophenol (molar ratio) gel in isooctane have been examined. To achieve this, p-chlorophenol is added progressively to the dilute solutions of AOT in isooctane, and this concentration series is then analyzed. The dry micelles of AOT in isooctane do not undergo any detectable structural change up to a certain p-chlorophenol concentration. Upon a very small increment in the concentration of p-chlorophenol beyond this "threshold" concentration, large strandlike aggregates are observed which then evolve to the three-dimensional gel network.
Singh
Mohit
M
Department of Chemical and Biomolecular Engineering, Tulane University, New Orleans, Louisiana 70118, USA.
Tan
Grace
G
Agarwal
Vivek
V
Fritz
Gerhard
G
Maskos
Karol
K
Bose
Arijit
A
John
Vijay
V
McPherson
Gary
G
D002733:Chlorophenols / Q000737:chemistry; D004143:Dioctyl Sulfosuccinic Acid / Q000737:chemistry*; D005782:Gels / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008823:Micelles; D018625:Microscopy, Atomic Force; D009795:Octanes / Q000737:chemistry; D009930:Organic Chemicals / Q000737:chemistry*; D012212:Rheology; D012542:Scattering, Radiation; D013501:Surface-Active Agents / Q000737:chemistry*
D002733:Chlorophenols; D005782:Gels; D008823:Micelles; D009795:Octanes; D009930:Organic Chemicals; D013501:Surface-Active Agents; D004143:Dioctyl Sulfosuccinic Acid; C029107:4-chlorophenol; C045798:2,2,4-trimethylpentane