The determination of nickel(II) after on-line sorbent preconcentration by inductively coupled plasma atomic emission spectrometry using Borassus Flabellifer inflorescence loaded with coniine dithiocarbamate.
A procedure was developed for the determination of nickel(II) in water samples by inductively coupled plasma atomic emission spectrometry (ICP-AES) after preconcentration on coniine dithiocarbamate (CDC) supported by Borassus Flabellifer inflorescence. The sorbed element was subsequently eluted with 0.4M nitric acid and the acid eluates are analysed by ICP-AES. The influence of various parameters such as pH, flow rate of sample, eluent concentration, volume of the sample and volume eluent were investigated. Under the optimal conditions, nickel in aqueous sample was concentrated about 100-fold. Nickel recovery was obtained by the proposed method in range of 98.9-99.9%. This method is also applied for the analysis of spiked and natural water samples. The results provide strong evidence to support the hypothesis of an adsorption mechanism.
Environmental Monitoring Laboratories, Department of Chemistry, S.V. University, Tirupati 517502, AP, India.
K
K
Suvardhan
K Suresh
KS
Kumar
L
L
Krishnaiah
S Prabakhara
SP
Rao
P
P
Chiranjeevi
D000470:Alkaloids / Q000737:chemistry*; D002845:Chromatography / Q000379:methods; D006863:Hydrogen-Ion Concentration; D009532:Nickel / Q000032:analysis*; D017942:Nitric Acid / Q000737:chemistry; D010880:Piperidines / Q000737:chemistry*; D013054:Spectrophotometry, Atomic / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014876:Water Pollution / Q000517:prevention & control
D000470:Alkaloids; D010880:Piperidines; D014874:Water Pollutants, Chemical; D017942:Nitric Acid; D009532:Nickel; C007112:coniine