The cation as a tool to get spin-canted three-dimensional ironIII networks.
Alkyl-substituted ammonium cations (X) allow the preparation of a series of spin-canted oxo- and oxalato-bridged three-dimensional iron(III) networks, exhibiting magnetic ordering at T(c) values ranging from 40 to 56 K. The value of T(c) varies with the cation despite the lack of significant structural modifications.
Dipartimento di Chimica, Università degli Studi della Calabria, 87030 Arcavacata di Rende, Cosenza, Italy.
Donatella
D
Armentano
Giovanni
G
De Munno
Teresa F
TF
Mastropietro
Davide M
DM
Proserpio
Miguel
M
Julve
Francesc
F
Lloret