Platinum catalysed 3,4- and 1,4-diboration of alpha,beta-unsaturated carbonyl compounds using bis-pinacolatodiboron.
Bis-pinacolatodiboron reacts with [small alpha],[small beta]-unsaturated carbonyl compounds to give 1,4- and unprecedented 3,4-additions in the presence of a second generation Pt(0) catalyst at ambient temperature.
Bell
Nathan J
NJ
Department of Chemistry, University Science Laboratories, Durham University, South Road, Durham, UK.
Cox
Andrew J
AJ
Cameron
Neil R
NR
Evans
John S O
JS
Marder
Todd B
TB
Duin
Marcel A
MA
Elsevier
Cornelis J
CJ
Baucherel
Xavier
X
Tulloch
Arran A D
AA
Tooze
Robert P
RP