Nature and composition of fat bloom from palm kernel stearin and hydrogenated palm kernel stearin compound chocolates.
Palm kernel stearin and hydrogenated palm kernel stearin can be used to prepare compound chocolate bars or coatings. The objective of this study was to characterize the chemical composition, polymorphism, and melting behavior of the bloom that develops on bars of compound chocolate prepared using these fats. Bars were stored for 1 year at 15, 20, or 25 degrees C. At 15 and 20 degrees C the bloom was enriched in cocoa butter triacylglycerols, with respect to the main fat phase, whereas at 25 degrees C the enrichment was with palm kernel triacylglycerols. The bloom consisted principally of solid fat and was sharper melting than was the fat in the chocolate. Polymorphic transitions from the initial beta' phase to the beta phase accompanied the formation of bloom at all temperatures.
Smith
Kevin W
KW
Life Science, Unilever R&D Colworth, Sharnbrook, Bedfordshire MK44 1LQ, United Kingdom. kevin.w.smith@unilever.com
Cain
Fred W
FW
Talbot
Geoff
G
D002099:Cacao / Q000737:chemistry*; D002152:Calorimetry, Differential Scanning; D004041:Dietary Fats / Q000032:analysis; D005223:Fats / Q000737:chemistry*; D005524:Food Technology; D006865:Hydrogenation; D007850:Lauric Acids / Q000737:chemistry; D000073878:Palm Oil; D010938:Plant Oils / Q000737:chemistry; D013228:Stearates / Q000737:chemistry*; D013696:Temperature; D014280:Triglycerides / Q000032:analysis; D014961:X-Ray Diffraction
D004041:Dietary Fats; D005223:Fats; D007850:Lauric Acids; D010938:Plant Oils; D013228:Stearates; D014280:Triglycerides; C030358:lauric acid; C052387:cocoa butter; D000073878:Palm Oil