2-Amino-2-thiazoline and its 1:1 organic salt with 2-naphthoxyacetic acid.
The crystal structures of 2-amino-2-thiazoline, C3H6N2S, and 2-amino-2-thiazolinium 2-naphthoxyacetate, C3H7N2S+.C12H9O3-, are reported. The structure of 2-amino-2-thiazoline consists of two unique molecules that construct a convoluted hydrogen-bonded ribbon involving R(2)2(8) graph-set association via both N-H...N and N-H...S interactions. The organic salt structure consists of the two molecules associated via an R(2)2(8) graph-set dimer through N-H...O interactions, with the hydrogen-bonding network propagated via additional N-H...O three-centre interactions from the second 2-amine H atom.
Lynch
Daniel E
DE
School of Science and the Environment, Coventry University, Coventry CV1 5FB, England. apx106@coventry.ac.uk
D000970:Antineoplastic Agents / Q000737:chemistry; D018360:Crystallography, X-Ray; D006016:Glycolates / Q000737:chemistry*; D006860:Hydrogen Bonding; D015394:Molecular Structure; D013844:Thiazoles / Q000737:chemistry*
D000970:Antineoplastic Agents; D006016:Glycolates; D013844:Thiazoles; C031363:2-aminothiazoline; C008586:2-naphthoxyacetic acid