Syntheses, crystal structures, and luminescent properties of novel layered lanthanide sulfonate-phosphonates.
Hydrothermal reactions of lanthanide metal salts with MeN(CH(2)CO(2)H)(CH(2)PO(3)H(2)) (H(3)L) and 5-sulfoisophthalic acid monosodium salt (NaH(2)BTS) lead to four isomorphous lanthanide carboxylate-phosphonate-sulfonate hybrids, namely, Ln(H(2)L)(HBTS)(H(2)O)(2).H(2)O (Ln = La (1), Pr (2), Nd (3), Gd (4)). Their structures have been established by X-ray single-crystal diffraction. The interconnection of the lanthanide(III) ions by carboxylate-phosphonate ligands results in a 1D double chain; these double chains are further bridged by bidentate bridging carboxylate-sulfonate ligands to form a <011> layer. The luminescent properties of compounds 3 and 4 have also been studied.
Song
Jun-Ling
JL
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou 350002, P. R. China.
Lei
Chong
C
Mao
Jiang-Gao
JG
D000476:Alkanesulfonates / Q000737:chemistry; D018360:Crystallography, X-Ray; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008163:Luminescent Measurements; D008956:Models, Chemical; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D063065:Organophosphonates / Q000737:chemistry*; D013457:Sulfur Compounds / Q000737:chemistry*
D000476:Alkanesulfonates; D028581:Lanthanoid Series Elements; D009942:Organometallic Compounds; D063065:Organophosphonates; D013457:Sulfur Compounds