Polarization effects on the hyper-Raman spectra of carbon tetrachloride: a joint experimental-theoretical study.
Hyper-Raman spectra of pure carbon tetrachloride in the liquid phase are recorded for different combinations of the polarizations of the incident and scattered lights and are compared to ab initio time-dependent Hartree-Fock simulations. Both the calculated intensities of the Raman and hyper-Raman spectra give indeed a quite satisfactory agreement with polarized experimental spectra.
Quinet
Olivier
O
Laboratoire de Chimie Theorique Appliquee, Facultes Universitaires Notre-Dame de la Paix, rue de Bruxelles, 61, B-5000 Namur, Belgium.
Champagne
Benoit
B
Rodriguez
Vincent
V