Synthesis of fagopyritols A1 and B1 from D-chiro-inositol.
Fagopyritol A1 (3-O-alpha-d-galactopyranosyl-d-chiro-inositol) and fagopyritol B1 (2-O-alpha-d-galactopyranosyl-d-chiro-inositol) have been synthesized by glycosylation of the diequatorial diol 1,4,5,6-tetra-O-benzoyl-d-chiro-inositol, readily obtained from d-chiro-inositol, with 2,3,4,6-tetra-O-benzyl-d-galactopyranosyl trichloroacetimidate.
Cid
M Belén
MB
Grupo de Carbohidratos, Instituto de Investigaciones Quimicas, CSIC, Américo Vespucio s/n, Isla de La Cartuja, 41092 Sevilla, Spain.
Alfonso
Francisco
F
Martín-Lomas
Manuel
M
D002236:Carbohydrate Conformation; D004187:Disaccharides / Q000138:chemical synthesis* / Q000737:chemistry; D007202:Indicators and Reagents; D007294:Inositol; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular
D004187:Disaccharides; D007202:Indicators and Reagents; C424842:fagopyritol A1; C112483:fagopyritol B1; D007294:Inositol