Removal of chlorophenols from aquatic systems using the dried and dead fungus Pleurotus sajor caju.
In this study, the potential use of the fungus Pleurotus sajor caju to remove phenols (i.e., phenol, o-chlorophenol, p-chlorophenol and 2,4,6-trichlorophenol) from aqueous solutions was evaluated. Biosorption of phenol or chlorophenols reached equilibrium in 4 h. The maximum adsorptions of phenol and chlorophenols onto the Pleurotus sajor caju were 0.95 mmol/g for phenol, 1.24 mmol/g for o-chlorophenol, 1.47 mmol/g for p-chlorophenol and 1.89 mmol/g for 2,4,6-trichlorophenol. The affinity order was as follows: 2,4,6-trichlorophenol> p-chlorophenol> o-chlorophenol>phenol. Phenol and chlorophenols bindings onto Pleurotus sajor caju were clearly pH dependent. The adsorption of phenol and chlorophenols increased with increasing pH. Desorption was achieved using methanol solution (30%, v/v). Pleurotus sajor caju biomass is suitable for reuse for more than five cycles without noticeable loss of adsorption capacity.
Denizli
Adil
A
Department of Chemistry, Hacettepe University, Biochemistry Division, Beytepe, Ankara, Turkey. denizli@hacettepe.edu.tr
Cihangir
Nilüfer
N
Tüzmen
Nalan
N
Alsancak
Güleren
G
D000327:Adsorption; D002733:Chlorophenols / Q000737:chemistry / Q000302:isolation & purification*; D002851:Chromatography, High Pressure Liquid; D006863:Hydrogen-Ion Concentration; D000432:Methanol; D020076:Pleurotus / Q000737:chemistry*; D013997:Time Factors; D014865:Waste Disposal, Fluid / Q000379:methods*; D018508:Water Purification / Q000379:methods*
D002733:Chlorophenols; D000432:Methanol