Alpha,beta-unsaturated imines from titanium hydroamination and functionalization by rhodium C-H activation.
Titanium pyrrolyl complexes are effective catalysts for the synthesis of alpha,beta-unsaturated imines, which can be further functionalized using Rh-catalyzed alkene or alkyne insertion into the beta-C-H bond.
Cao
Changsheng
C
Michigan State University, Department of Chemistry, East Lansing, MI 48824, USA.
Li
Yahong
Y
Shi
Yanhui
Y
Odom
Aaron L
AL