title: A new synthetic method for an indolizidine skeleton by C-N bond formation via a pi-allylpalladium complex.
abstract: Pd(0)-catalyzed intramolecular cyclic reaction via a pi-allylpalladium complex provided an indolizidine skeleton in satisfactory high and reproducible yields by using allylic compound having an acetoxyl group as a leaving group. These results must be available for syntheses of various functional indolizidine alkaloids.
authors.affiliation: School of Pharmaceutical Sciences, Kitasato University, Minato-ku, Tokyo 108-8641, Japan. konday@pharm.kitasato-u.ac.jp
authors.forename: Yaeko
authors.initials: Y
authors.lastname: Yamada
authors.forename: Wakako
authors.initials: W
authors.lastname: Takahashi
authors.forename: Yoshihisa
authors.initials: Y
authors.lastname: Asada
authors.forename: Junko
authors.initials: J
authors.lastname: Holiuchi
authors.forename: Kazuyoshi
authors.initials: K
authors.lastname: Takeda
authors.forename: Yoshihiro
authors.initials: Y
authors.lastname: Harigaya
mesh_terms: D000470:Alkaloids / Q000138:chemical synthesis; D002384:Catalysis; D003500:Cyclization; D007212:Indolizines / Q000138:chemical synthesis*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D010165:Palladium / Q000737:chemistry*
chemical_list: D000470:Alkaloids; D007212:Indolizines; D009942:Organometallic Compounds; D010165:Palladium