Spectroscopic characterization of copper(II) complexes of indoxyl N(4)-methyl thiosemicarbazone.
New copper(II) complexes of indoxyl thiosemicarbazone (ITSC) of general composition CuL2X2 (where L: ITSC; X: Cl-, NO3-, ClO4-, NCS-) have been synthesized and characterized by elemental analysis, molar conductance, magnetic susceptibility measurements and spectral (electronic, IR, EPR, 1H NMR, Mass) studies. Cyclic voltammetry measurements show quasi-reversible Cu2+/Cu1+ couple. Various physico-chemical techniques suggest a tetragonal structure for these copper(II) complexes.
Chandra
Sulekh
S
Department of Chemistry, Zakir Husain College, University of Delhi, J.L. Nehru Marg, New Delhi 110002, India. schandra_00@yahoo.com
Kumar
Umendra
U
D003300:Copper / Q000737:chemistry*; D004563:Electrochemistry; D004578:Electron Spin Resonance Spectroscopy; D009682:Magnetic Resonance Spectroscopy; D009942:Organometallic Compounds / Q000737:chemistry*; D016339:Spectrometry, Mass, Fast Atom Bombardment; D013055:Spectrophotometry, Infrared; D013882:Thiosemicarbazones / Q000737:chemistry*
D009942:Organometallic Compounds; D013882:Thiosemicarbazones; D003300:Copper