A novel method for calculating rate constants of diffusion-influenced reactions.
In the present work we suggest a method for calculating rate constants of chemical processes affected by mobility of reactants. The method is based on the encounter theory. Unlike the widely accepted model of collision complexes it provides a general formal solution for practically arbitrary reaction scheme.
Ivanov
Konstantin L
KL
International Tomography Center, Novosibirsk 630090, Russia. ivanov@tomo.nsc.ru
Lukzen
Nikita N
NN