title: Cytochrome P-450 dependent monooxygenases model system: rapid and efficient oxidation of primary aromatic amines to azo derivatives with sodium periodate catalyzed by manganese(III) Schiff base complexes.
abstract: Rapid and efficient oxidation of primary aromatic amines was investigated. Mn(III)-salophen catalyst can catalyze the oxidation of primary aromatic amines to azo derivatives with sodium periodate. The ability of various Schiff base complexes in this oxidation system was also investigated.
authors.affiliation: Department of Chemistry, Isfahan University, Isfahan 81746-73441, Iran. mirkhani@sci.ui.ac.ir
authors.forename: Valiollah
authors.initials: V
authors.lastname: Mirkhani
authors.forename: Shahram
authors.initials: S
authors.lastname: Tangestaninejad
authors.forename: Majid
authors.initials: M
authors.lastname: Moghadam
authors.forename: Maryam
authors.initials: M
authors.lastname: Moghbel
mesh_terms: D000588:Amines / Q000737:chemistry*; D000818:Animals; D001391:Azo Compounds / Q000737:chemistry*; D002384:Catalysis; D003577:Cytochrome P-450 Enzyme System / Q000378:metabolism; D008345:Manganese / Q000737:chemistry*; D010084:Oxidation-Reduction; D010105:Oxygenases / Q000378:metabolism*; D010504:Periodic Acid / Q000737:chemistry; D012545:Schiff Bases / Q000737:chemistry*; D013053:Spectrophotometry
chemical_list: D000588:Amines; D001391:Azo Compounds; D012545:Schiff Bases; D010504:Periodic Acid; D008345:Manganese; D003577:Cytochrome P-450 Enzyme System; C009288:metaperiodate; D010105:Oxygenases