Cytochrome P-450 dependent monooxygenases model system: rapid and efficient oxidation of primary aromatic amines to azo derivatives with sodium periodate catalyzed by manganese(III) Schiff base complexes.
Rapid and efficient oxidation of primary aromatic amines was investigated. Mn(III)-salophen catalyst can catalyze the oxidation of primary aromatic amines to azo derivatives with sodium periodate. The ability of various Schiff base complexes in this oxidation system was also investigated.
Mirkhani
Valiollah
V
Department of Chemistry, Isfahan University, Isfahan 81746-73441, Iran. mirkhani@sci.ui.ac.ir
Tangestaninejad
Shahram
S
Moghadam
Majid
M
Moghbel
Maryam
M
D000588:Amines / Q000737:chemistry*; D000818:Animals; D001391:Azo Compounds / Q000737:chemistry*; D002384:Catalysis; D003577:Cytochrome P-450 Enzyme System / Q000378:metabolism; D008345:Manganese / Q000737:chemistry*; D010084:Oxidation-Reduction; D010105:Oxygenases / Q000378:metabolism*; D010504:Periodic Acid / Q000737:chemistry; D012545:Schiff Bases / Q000737:chemistry*; D013053:Spectrophotometry
D000588:Amines; D001391:Azo Compounds; D012545:Schiff Bases; D010504:Periodic Acid; D008345:Manganese; D003577:Cytochrome P-450 Enzyme System; C009288:metaperiodate; D010105:Oxygenases