Tetraaqua(3,4,7,8-tetramethyl-1,10-phenanthroline-kappa2N,N')zinc(II) thiosulfate.
In the title complex of zinc(II) with 3,4,7,8-tetramethyl-1,10-phenanthroline (tmph), viz. [Zn(C16H16N2)(H2O)4](S2O3), the metal atom has a monomeric octahedral ZnN2O4 complex environment comprising two N-atom donors from the tmph group and four aqua O-atom donors. The complex cation is connected to four thiosulfate anions through a compact hydrogen-bonding network involving all coordinated aqua H-atom donors and all the outer acceptors (O and S) of the anion.
Díaz de Vivar
M Enriqueta
ME
Universidad Nacional de la Patagonia, Sede Puerto Madryn, 9120 Puerto Madryn, Chubut, Argentina.
Baggio
Sergio
S
Ibañez
Andrés
A
Baggio
Ricardo
R
D000894:Anti-Inflammatory Agents, Non-Steroidal / Q000737:chemistry; D018360:Crystallography, X-Ray; D015394:Molecular Structure; D009578:Nitrobenzenes / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010618:Phenanthrolines / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
D000894:Anti-Inflammatory Agents, Non-Steroidal; D009578:Nitrobenzenes; D009942:Organometallic Compounds; D010618:Phenanthrolines; D015032:Zinc