title: catena-Poly[1,4-diazoniabicyclo[2.2.2]octane [silver(I)-tri-mu-thiocyanato-kappa6S:S]].
abstract: The title compound, [(C6H14N2)[Ag(NCS)3]]n, is a polymeric silver(I) complex. The Ag(I) atom is hexacoordinated by the S atoms of six thiocyanate anions, with each thiocyanate S atom acting in a bridging mode to link the Ag atoms together. The unique Ag(I) atom lies at a cell origin and has crystallographically imposed 3 symmetry. The diazonia[2.2.2]octane molecule lies about a site with 6 imposed symmetry with the unique N atom on a threefold axis. The S and N atoms of the thiocyanate ligands sit on a mirror plane and a threefold axis, respectively. The crystal structure consists of one-dimensional chains, which are stabilized by N-H...N hydrogen bonds to form a three-dimensional network.
authors.affiliation: Department of Chemistry, Fuyang Normal College, Fuyang, Anhui 236041, People's Republic of China.
authors.forename: Zhao-Di
authors.initials: ZD
authors.lastname: Liu
authors.forename: Ying
authors.initials: Y
authors.lastname: Zou
authors.forename: Min-Yu
authors.initials: MY
authors.lastname: Tan
authors.forename: Hai-Liang
authors.initials: HL
authors.lastname: Zhu