Complexation of thorium(IV) with acetate at variable temperatures.
The complexation between Th(IV) and acetate in 1.05 mol kg(-1) NaClO4 was studied at variable temperatures (10, 25, 40, 55 and 70 degrees C). The formation constants of five successive complexes, Th(Ac)j(4-j)+ where Ac = CH3COO- and j = 1-5, and the molar enthalpies of complexation were determined by potentiometry and calorimetry. Extended X-ray absorption fine structure spectroscopy (EXAFS) provided additional information on the complexes in solution. The effect of temperature on the stability of the complexes is discussed in terms of the electrostatic model.
Rao
Linfeng
L
Glenn T. Seaborg Center, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA. LRao@lbl.gov
Zhang
Zhicheng
Z
Zanonato
PierLuigi
P
Di Bernardo
Plinio
P
Bismondo
Arturo
A
Clark
Sue B
SB