title: The effect of resin/crosslinker ratio on the mechanical properties and fungal deterioration of a maxillofacial silicone elastomer.
abstract: Variation of the crosslinker/resin ratio of a room temperature condensation cure maxillofacial silicone elastomer has caused considerable changes in the mechanical properties and deterioration by Candida albicans. Increasing the crosslinker/resin ratio caused a decrease in the tensile strength and stiffness of the elastomer. However, tear strength appeared to show an optimum value at the recommended crosslinker/resin ratio. These effects were due to the low molar mass silicone polymer that acts as a carrier for the actual crosslinking additive. The general decrease in mechanical properties was accompanied by an increase in the hexane extractables content and an increase in the Si-H content of the elastomer. The unbound polymer (extractable material) content of the elastomer was found to influence the colonization of the material by C. albicans. An increase in the unbound polymer content corresponded to an increasing number of hyphae and blastospores observed penetrating into the elastomer. The data obtained in this study have significant implications concerning the degree of control of elastomer formulation and the deterioration of maxillofacial appliances.
authors.affiliation: The Manchester Metropolitan University, Department of Chemistry and Materials, John Dalton Building, Chester Street, Manchester, M1 5GD, UK. r.taylor@mmu.ac.uk
authors.forename: R L
authors.initials: RL
authors.lastname: Taylor
authors.forename: C M
authors.initials: CM
authors.lastname: Liauw
authors.forename: C
authors.initials: C
authors.lastname: Maryan