Interactions of different types of localized corrosion in surgical implants.
Surgical implants often show different types of localized corrosion such as corrosion fatigue cracking, pitting and crevice corrosion on the same part. Interactions of these different corrosion phenomena were investigated. This was done by cyclic loading of electropolished tensile specimens at different constant and changing potentials. Material investigated was a surgical implant steel X2CrNiMo18-15-3 which was immersed in physiological NaCl solution. Pitting and repassivation potentials were determined. Samples with and without artificial cracks as well as masked specimens were tested. Incubation period for first damage, density and size of pits by coulometric and volumetric method were determined. The fracture surfaces were then investigated by SEM. Results show that not in all cases pitting corrosion was the cause for corrosion fatigue cracking. Also pitting is favoured by crack formation. Density of pits increases by a factor of 5 without any change to pitting potential. There are primary pits formed prior to crack initiation and secondary pits formed after crack initiation. At samples without crack there is almost no difference between the optically measured value of total pit volume and the coulometrically determined value. At samples with cracks coulometric volume of pits is much larger than optical one. This proves that there is a significant amount of crevice corrosion in the crack. The corrosion current density in the crack increases by two orders of magnitude when comparing it to electropolished surface of the sample. Results of laboratory experiments are confirmed by failure of a real implant.
Mori
G
G
Department of General and Analytical Chemistry, University of Leoben, Austria. gregor.mori@notes.unileoben.ac.at
Dösinger
H
H
D003343:Corrosion; D006801:Humans; D066298:In Vitro Techniques; D008422:Materials Testing; D008855:Microscopy, Electron, Scanning; D011199:Potentiometry; D019736:Prostheses and Implants; D011475:Prosthesis Failure; D013499:Surface Properties; D013718:Tensile Strength