Thiostannylation of arynes with stannyl sulfides: synthesis and reaction of 2-(arylthio)arylstannanes.
Arynes were found to insert into a sulfur-tin sigma-bond of stannyl sulfides to give a variety of 2-(arylthio)arylstannanes, whose carbon-tin bonds were applicable to further transformations.
Yoshida
Hiroto
H
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan. yhiroto@hiroshima-u.ac.jp
Terayama
Tsuguaki
T
Ohshita
Joji
J
Kunai
Atsutaka
A