Measurement of anisotropic energy transport in flowing polymers by using a holographic technique.
Almost no experimental data exist to test theories for the nonisothermal flow of complex fluids. To provide quantitative tests for newly proposed theories, we have developed a holographic grating technique to study energy transport in an amorphous polymer melt subject to flow. Polyisobutylene with weight-averaged molecular mass of 85 kDa is sheared at a rate of 10 s(-1), and all nonzero components of the thermal conductivity tensor are measured as a function of time, after cessation. Our results are consistent with proposed generalizations to the energy balance for microstructural fluids, including a generalized Fourier's law for anisotropic media. The data are also consistent with a proposed stress-thermal rule for amorphous polymer melts. Confirmation of the universality of these results would allow numerical modelers to make quantitative predictions for the nonisothermal flow of polymer melts.
Schieber
Jay D
JD
Department of Chemical Engineering, Illinois Institute of Technology, 10 West 33rd Street, Chicago, IL 60616, USA. schieber@iit.edu
Venerus
David C
DC
Bush
Kendall
K
Balasubramanian
Venkat
V
Smoukov
Stoyan
S