title: Influence of ripening on pHstat leaching behaviour of heavy metals from dredged sediments.
abstract: The influence of oxidation and ripening on the kinetics of heavy metal release from anoxic sediments was investigated by means of porewater analysis and pH(stat) leaching tests. During simulated land disposal of an anoxic river sediment, a considerable heavy metal (Cd, Zn and Ni) release into the porewater was observed after 25 days of exposure of the sediment to the air. The release kinetics of Cd and Zn during pH(stat) leaching indicated that their release was related to the oxidation of Cd- and Zn-sulfides. It was not completely clear whether the release of Ni was due to the oxidation of Ni-sulfides or to the introduction of H(+)(generated by the oxidation of sulfides or introduced by titration). The release of Cu seemed to be explained by the oxidation of both Fe-sulfides and Cu-sulfides. As such, pH(stat) experiments provided an indirect way to assess the mineralogy of the anoxic sediment. During ripening of the sediment, the release rate of Zn and Cd in pH(stat) leaching tests increased. For Ni, however, a similar release pattern was observed in the anoxic sediment and in the ripened sediments. Two weeks' drying at 100 degrees C resulted in an increase in the leachability of Cu. Nevertheless, at pH 4 and 6, the thermally treated sediment displayed a slower leaching of Cd and Zn than the ripened sediment. Although thermal treatment is often used to simulate ageing in soils, it cannot be used to simulate ripening of anoxic sediments.
authors.affiliation: Katholieke Universiteit Leuven, Fysico-chemische Geologie, Celestijnenlaan 200C, 3001 Heverlee, Belgium. Valerie.Cappuyns@geo.kuleuven.ac.be
authors.forename: Valerie
authors.initials: V
authors.lastname: Cappuyns
authors.forename: Rudy
authors.initials: R
authors.lastname: Swennen
authors.forename: Anne
authors.initials: A
authors.lastname: Devivier
mesh_terms: D004785:Environmental Pollutants / Q000032:analysis*; D019015:Geologic Sediments / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D019216:Metals, Heavy / Q000032:analysis* / Q000737:chemistry*; D010084:Oxidation-Reduction; D013696:Temperature
chemical_list: D004785:Environmental Pollutants; D019216:Metals, Heavy