Regio- and stereoselective hydrosilylation of terminal alkynes using Grubbs' first-generation olefin-metathesis catalyst.
Grubbs' first-generation, Ru metathesis complex catalyses the hydrosilylation of terminal alkynes. The reaction exhibits an interesting selectivity profile that is dependent on the reaction concentration and more importantly on the silane employed.
Aricó
Caterina S
CS
School of Chemistry, The University of Birmingham, Edgbaston, Birmingham, UK B15 2TT.
Cox
Liam R
LR