Migration of trimellitic acid from epoxy anhydride can coatings into foods.
The migration of trimellitic acid and its esters from epoxy anhydride coatings was determined in simulants as well as in canned foods. The most appropriate simulant was a combination of EC simulants B and C: 2% acetic acid/10% ethanol in water. The average migration into food was 900 microg kg(-1). This far exceeds the 50 microg kg(-1) for which the safety of trimellitic acid and its anhydride is ensured and the Swiss legal limit (QM(T) of 5 mg kg(-1) coating). Furthermore, much trimellitic acid migrated as (unidentified) esters, i.e. toxicological testing of free trimellitic acid is inadequate for the material that in reality migrates.
Fankhauser-Noti
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Official Food Control Authority of the Canton of Zurich, Switzerland.
Grob
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D002849:Chromatography, Gas / Q000379:methods; D002851:Chromatography, High Pressure Liquid / Q000379:methods; D004852:Epoxy Compounds; D004952:Esters / Q000032:analysis; D005506:Food Contamination / Q000032:analysis*; D018857:Food Packaging / Q000379:methods*; D027845:Malus / Q000737:chemistry; D008745:Methylation; D018532:Pisum sativum / Q000737:chemistry; D012015:Reference Standards; D014233:Tricarboxylic Acids / Q000032:analysis* / Q000737:chemistry
D004852:Epoxy Compounds; D004952:Esters; D014233:Tricarboxylic Acids; C014871:trimellitic acid