One-pot assembly of tricyclo[6.2.1.0(1,6)]undecan-4-one and related polycyclic compounds by tandem electroreductive cyclization.
[reaction: see text] Electroreductive tandem cyclization of 4-allyl-4-(2-bromoprop-2-en-1-yl)cyclohex-2-en-1-one to tricyclo[6.2.1.0(1,6)]undecan-4-one has been demonstrated. This protocol represents an attractive alternative to conventional tandem radical cyclization.
Toyota
Masahiro
M
Department of Organic Chemistry, Graduate School of Pharmaceutical Sciences, Tohoku University, Aobayama, Sendai 980-8578, Japan.
Ilangovan
Andivelu
A
Kashiwagi
Yoshitomo
Y
Ihara
Masataka
M