title: Advanced method using microwaves and solid-phase microextraction coupled with gas chromatography-mass spectrometry for the determination of pyrethroid residues in strawberries.
abstract: A microwave-assisted desorption method was developed and coupled with solid-phase microextraction and GC-MS for the analysis of pyrethroid residues in strawberries. In the first step, pyrethroid analytes were desorbed from the whole fruits in an aqueous acetonitrile solution at 50% under microwave assistance, so preventing these compounds to be captured with strong matrix effects by endogenous constituents. Then, the 100 microm poly(dimethylsiloxane)-coated fibre was exposed for 30 min in the obtained extracting solution. Calibration curves, realised from blank strawberries spiked at different concentrations with standards, showed a linear range between 1 microg/kg and 250 microg/kg with r2 > 0.992 and variation coefficients below 15%. Limits of detection and quantitation were found lower than 14 microg/kg and 40 microg/kg, respectively. Observed analysis results by using this method and relative to field incurred strawberry samples were also compared to those obtained by two accredited trading laboratories using traditional methods.
authors.affiliation: Equipe Périgourdine de Chimie Appliquée, Laboratoire de Pysico et Toxico-Chimie des Systèmes Naturels, UMR 5472 CNRS, Université Bordeaux I, BP 1043, 24001 Perigueux Cedex, France.
authors.forename: Astrid
authors.initials: A
authors.lastname: Sanusi
authors.forename: Valérie
authors.initials: V
authors.lastname: Guillet
authors.forename: Michel
authors.initials: M
authors.lastname: Montury
mesh_terms: D000327:Adsorption; D031985:Fragaria / Q000737:chemistry*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods*; D008872:Microwaves; D010573:Pesticide Residues / Q000032:analysis*; D011722:Pyrethrins / Q000032:analysis*; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity
chemical_list: D010573:Pesticide Residues; D011722:Pyrethrins