title: Dynamic in-stream fate modeling of xenobiotic organic compounds: a case study of linear alkylbenzene sulfonates in the Lambro River, Italy.
abstract: Using a conceptual hydraulic model, a one-dimensional dynamic river water quality model has been developed to assess the short-term fate of linear alkylbenzene sulfonates (LAS) in the river compartments water and benthic sediment. The model assumes local equilibrium sorption and that both dissolved and sorbed chemical are available for biodegradation. To investigate the interaction of nutrient dynamics and organic contaminant fate, the model is coupled with a basic water quality model. On the basis of the Lambro River (Italy) as a case study, the result shows that the model predictions agree well with the measured data set. The model output sensitivity to model parameters has been tested, and the results depict that the model is highly sensitive to the biodegrading parameters. Also, a comparison of a steady state with a dynamic simulation and the effect of nutrient dynamics on the LAS fate in the Lambro River as a scenario analysis are presented. The results indicate the usefulness of the proposed model for the short-term simulation of organic contaminant fate in unsteady environmental conditions.
authors.affiliation: Ghent University-BIOMATH, Coupure Links 653, B-9000 Ghent, Belgium. tolessa@biomath.ugent.be
authors.forename: Tolessa
authors.initials: T
authors.lastname: Deksissa
authors.forename: Dirk
authors.initials: D
authors.lastname: De Pauw
authors.forename: Peter A
authors.initials: PA
authors.lastname: Vanrolleghem
mesh_terms: D017738:Alkanesulfonic Acids / Q000032:analysis*; D001673:Biodegradation, Environmental; D003198:Computer Simulation; D005544:Forecasting; D019015:Geologic Sediments / Q000032:analysis; D007558:Italy; D008962:Models, Theoretical; D015203:Reproducibility of Results; D045483:Rivers / Q000737:chemistry*; D013501:Surface-Active Agents / Q000032:analysis*; D014865:Waste Disposal, Fluid / Q000706:statistics & numerical data; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000032:analysis*; D015262:Xenobiotics / Q000032:analysis*
chemical_list: D017738:Alkanesulfonic Acids; D013501:Surface-Active Agents; D014874:Water Pollutants, Chemical; D015262:Xenobiotics; C030641:alkylbenzyl sulfonic acid