First synthesis of (+/-)-robinlin.
The first synthesis of (+/-)-robinlin (1), a novel homo-monoterpene with strong bioactivity in the brine shrimp lethality test, was achieved by starting from 3-isobutyloxy-2,6,6-trimethyl-2-cyclohexen-1-one (2).
Takikawa
Hirosato
H
Department of Biosystems Science, Graduate School of Science and Technology, Kobe University, Rokkodai, Nada-ku, Japan. takikawa@kobe-u.ac.jp
Hosoe
Shintaro
S
Ueda
Keiko
K
Sasaki
Mitsuru
M
D003510:Cyclohexanes / Q000737:chemistry; D053138:Cyclohexenes; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D039821:Monoterpenes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D003510:Cyclohexanes; D053138:Cyclohexenes; D039821:Monoterpenes; C439164:robinlin; C052568:cyclohexene