A new and efficient method for o-quinone methide intermediate generation: application to the biomimetic synthesis of (+/-)-Alboatrin.
[reaction: see text] A new and efficient method for o-quinone methide intermediate generation from o-methyleneacetoxy-phenols has been developed and applied to the biomimetic synthesis of (+/-)-Alboatrin.
Rodriguez
Raphaël
R
Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford OX1 3TA, United Kingdom.
Adlington
Robert M
RM
Moses
John E
JE
Cowley
Andrew
A
Baldwin
Jack E
JE
D001685:Biological Factors / Q000138:chemical synthesis*; D032701:Biomimetics; D020650:Combinatorial Chemistry Techniques; D045563:Indolequinones / Q000138:chemical synthesis*; D015394:Molecular Structure; D011809:Quinones / Q000138:chemical synthesis*; D013237:Stereoisomerism
D001685:Biological Factors; D045563:Indolequinones; D011809:Quinones; C504944:alboatrin; C068040:quinone methide