title: A promising enantioselective Diels-Alder dienophile by computer-assisted rational design: 2,5-diphenyl-1-vinyl-borolane.
abstract: Several chiral vinylboranes have been theoretically evaluated as enantioselective Diels-Alder dienophiles. Theoretical results suggest that optically pure 2,5-diphenyl-1-vinyl-borolane should be the reagent of choice for performing such transformations efficiently.
authors.affiliation: Instituto de Química Orgánica y de Síntesis (CONICET), Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario, Suipacha 531, Rosario (2000), Argentina. spellegr@fbioyf.unr.edu.ar
authors.forename: Silvina C
authors.initials: SC
authors.lastname: Pellegrinet
authors.forename: María A
authors.initials: MA
authors.lastname: Silva
authors.forename: Jonathan M
authors.initials: JM
authors.lastname: Goodman
mesh_terms: D001896:Boron Compounds / Q000737:chemistry*; D017076:Computer-Aided Design; D007202:Indicators and Reagents / Q000737:chemistry*; D008958:Models, Molecular; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000737:chemistry*
chemical_list: C498349:2,5-diphenyl-1-vinylborolane; D001896:Boron Compounds; D007202:Indicators and Reagents; D014753:Vinyl Compounds