High-resolution solid-state 73Ge NMR spectra of hexacoordinated germanium compounds.
High-resolution solid-state magic angle spinning 73Ge NMR spectra of hexavalent germanium compounds, i.e. diiodogermylene (1a) and bis(1-pyrrolyl)(meso-tetraphenylporphyrinato)germanium (3a), were determined. To the best of our knowledge, this is the first example of high-resolution solid-state 73Ge NMR spectra of hexacoordinated germanium nuclei. The symmetry requirement for observation of high-resolution solid-state 73Ge NMR spectra is discussed.
Takeuchi
Yoshito
Y
Department of Chemistry, Faculty of Science, Kanagawa University, 2946 Tsuchiya, Hiratsuka-shi 259-1293, Japan. yoshito@chem.kanagawa-u.ac.jp
Nishikawa
Miki
M
Yamamoto
Hiroshi
H