Synthesis, structure, and reactivity of a eta(3)-1-hydroxyallyl complex: protonation of an alpha,beta-unsaturated carbonyl compound bound to palladium(0) and platinum(0).
The direct addition of a proton to a carbonyl oxygen in an eta2-enone complex of palladium and platinum led to the quantitative formation of eta3-1-hydroxyallyl complexes of palladium and platinum, of which X-ray diffraction analysis showed typical eta3-allyl structure.
Ogoshi
Sensuke
S
Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
Morita
Masaki
M
Kurosawa
Hideo
H