title: Synthesis, structure, and reactivity of a eta(3)-1-hydroxyallyl complex: protonation of an alpha,beta-unsaturated carbonyl compound bound to palladium(0) and platinum(0).
abstract: The direct addition of a proton to a carbonyl oxygen in an eta2-enone complex of palladium and platinum led to the quantitative formation of eta3-1-hydroxyallyl complexes of palladium and platinum, of which X-ray diffraction analysis showed typical eta3-allyl structure.
authors.affiliation: Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
authors.forename: Sensuke
authors.initials: S
authors.lastname: Ogoshi
authors.forename: Masaki
authors.initials: M
authors.lastname: Morita
authors.forename: Hideo
authors.initials: H
authors.lastname: Kurosawa