Amino acid-derived iodobenzene dicarboxylates: reagents for oxidative conversion of alkenes to amino acid esters.
[reaction: see text] New amino acid-derived iodobenzene dicarboxylates were prepared by the reaction of (diacetoxyiodo)benzene with N-protected natural amino acids. These compounds in the presence of iodide anion can be used as reagents for beta-iodocarboxylation of alkenes leading to the respective amino acid esters.
Koposov
Alexey Y
AY
Department of Chemistry, University of Minnesota--Duluth, Duluth, Minnesota 55812, USA.
Boyarskikh
Vyacheslav V
VV
Zhdankin
Viktor V
VV
D000475:Alkenes / Q000737:chemistry*; D000596:Amino Acids / Q000737:chemistry*; D002384:Catalysis; D003998:Dicarboxylic Acids / Q000138:chemical synthesis* / Q000737:chemistry; D004952:Esters / Q000138:chemical synthesis; D007202:Indicators and Reagents; D007462:Iodobenzenes / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013237:Stereoisomerism
D000475:Alkenes; D000596:Amino Acids; D003998:Dicarboxylic Acids; D004952:Esters; D007202:Indicators and Reagents; D007462:Iodobenzenes