title: En route to coordination chemistry under confined conditions in a porous capsule: Pr3+ with different coordination shells.
abstract: The highly charged nanocontainer capsule of the type [pentagon]12[linker]30 identical with [(Mo)Mo5O21(H2O)6]12[Mo2O4(SO4)]30 with 20 nanosized pores and channels allows the entrance of cations like Pr3+: the latter are positioned at two different sites and have two different coordination shells, corresponding to a coordination chemistry under confined conditions; a fascinating aspect is that capsule encapsulated water shells fixed by hydrogen bonds act formally as polydentate ligands.
authors.affiliation: Fakultat fur Chemie der Universitat, Lehrstuhl fur Anorganische Chemie I, Postfach 100131, D-33501 Bielefeld, Germany. a.mueller@uni-bielefeld.de
authors.forename: Achim
authors.initials: A
authors.lastname: Muller
authors.forename: Yunshan
authors.initials: Y
authors.lastname: Zhou
authors.forename: Lijuan
authors.initials: L
authors.lastname: Zhang
authors.forename: Hartmut
authors.initials: H
authors.lastname: Bogge
authors.forename: Marc
authors.initials: M
authors.lastname: Schmidtmann
authors.forename: Martin
authors.initials: M
authors.lastname: Dressel
authors.forename: Joris
authors.initials: J
authors.lastname: Slageren