title: A new scaffold for the stereoselective synthesis of alpha-O-linked glycopeptide mimetics.
abstract: alpha-O-Linked glycohomoglutamates are obtained as diastereomerically pure compounds by chemo-, regio-, and stereoselective cycloadditions between glycals and aspartic acid derivatives. The latter constitute orthogonally functionalized scaffolds for glycopeptide mimetics.
authors.affiliation: Dipartimento di Chimica Organica Ugo Schiff, Università di Firenze, via della Lastruccia, 13 I-50019 Sesto Fiorentino (FI), Italy.
authors.forename: Francesca
authors.initials: F
authors.lastname: Venturi
authors.forename: Chiara
authors.initials: C
authors.lastname: Venturi
authors.forename: Francesca
authors.initials: F
authors.lastname: Liguori
authors.forename: Martina
authors.initials: M
authors.lastname: Cacciarini
authors.forename: Monica
authors.initials: M
authors.lastname: Montalbano
authors.forename: Cristina
authors.initials: C
authors.lastname: Nativi
mesh_terms: D006020:Glycopeptides / Q000138:chemical synthesis* / Q000737:chemistry; D018716:Molecular Mimicry; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D006020:Glycopeptides