title: Giant extended pi-conjugated dendrimers containing the 10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene chromophore: synthesis, NMR behaviors, optical properties, and electroluminescence.
abstract: This paper reports the facile synthetic strategy of a series of novel pi-conjugated dendrimers (G0 and G1) based on 10,15-dihydro-5H-diindeno[1,2-a;1',2'-c]fluorene (truxene) in which the benzene cores are generated "in-situ" from acetyl aromatics by the acid-promoted cyclotrimerizations. The unique NMR behaviors, physical properties, and electroluminescence device applications are also presented. Besides the purity, the structure, and the confirmation of the successful formation and isolation of desired compounds by clear assignments of every molecule by (1)H and (13)C and 2D NMR characterizations, several astonishing NMR behaviors have been observed in various solvents. For 1, chemical shift values belonging to H-2' of hexyl substituents move to the most upfield; however, such chemical shift values move from 0.48 to 0.85 ppm when pyridine-d(5) or benzene-d(6) is used as solvent. Our dendrimers as the emissive layers in organic light-emitting diodes gave blue-green light with an external quantum efficiency up to 0.16% both for G0 and for G1 in nitrogen, respectively, which exhibit unique electroluminescence spectra in comparison with their corresponding photoluminescence ones.
authors.affiliation: The Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University Healthy Science Centre, Peking University, Beijing 100871, China.
authors.forename: Xiao-Yu
authors.initials: XY
authors.lastname: Cao
authors.forename: Xue-Hui
authors.initials: XH
authors.lastname: Liu
authors.forename: Xing-Hua
authors.initials: XH
authors.lastname: Zhou
authors.forename: Yong
authors.initials: Y
authors.lastname: Zhang
authors.forename: Yang
authors.initials: Y
authors.lastname: Jiang
authors.forename: Yong
authors.initials: Y
authors.lastname: Cao
authors.forename: Yu-Xin
authors.initials: YX
authors.lastname: Cui
authors.forename: Jian
authors.initials: J
authors.lastname: Pei