Stereodivergent construction of cyclic ethers by a regioselective and enantiospecific rhodium-catalyzed allylic etherification: total synthesis of gaur acid.
Evans
P Andrew
PA
Department of Chemistry, Indiana University, Bloomington 47405, USA. paevans@indiana.edu
Leahy
David K
DK
Andrews
William J
WJ
Uraguchi
Daisuke
D
D000498:Allyl Compounds / Q000138:chemical synthesis*; D002264:Carboxylic Acids / Q000138:chemical synthesis*; D002384:Catalysis; D004988:Ethers, Cyclic / Q000138:chemical synthesis* / Q000737:chemistry*; D008968:Molecular Conformation; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
D000498:Allyl Compounds; D002264:Carboxylic Acids; D004988:Ethers, Cyclic; C502682:gaur acid; D012238:Rhodium