title: Reduction of 1,4-dichlorobut-2-yne by titanocene to a 1,2,3-butatriene. Formation of a 1-titanacyclopent-3-yne and a 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene.
abstract: The 2,5-dititanabicyclo[2.2.0]hex-1(4)-ene (bis-titanocene-mu-(Z)-1,2,3-butatriene complex)3 is formed starting from [Cp2Ti(eta2-Me3SiC2SiMe3)] by in situ generated titanocene and 1,4-dichlorobut-2-yne via the 1-titanacyclobut-3-yne (2).
authors.affiliation: Leibniz-Institut fur Organische Katalyse an der Universitat Rostock e.V., Buchbinderstr. 5-6, D-18055 Rostock, Germany.
authors.forename: Vladimir V
authors.initials: VV
authors.lastname: Burlakov
authors.forename: Perdita
authors.initials: P
authors.lastname: Arndt
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Baumann
authors.forename: Anke
authors.initials: A
authors.lastname: Spannenberg
authors.forename: Uwe
authors.initials: U
authors.lastname: Rosenthal
authors.forename: Pattiyil
authors.initials: P
authors.lastname: Parameswaran
authors.forename: Eluvathingal D
authors.initials: ED
authors.lastname: Jemmis