title: Total synthesis of (+)-brasilenyne. Application of an intramolecular silicon-assisted cross-coupling reaction.
authors.affiliation: Roger Adams Laboratory, Department of Chemistry, University of Illinois, Urbana, Illinois 61801, USA. denmark@scs.uiuc.edu
authors.forename: Scott E
authors.initials: SE
authors.lastname: Denmark
authors.forename: Shyh-Ming
authors.initials: SM
authors.lastname: Yang
mesh_terms: D000480:Alkynes / Q000737:chemistry; D003035:Cobalt / Q000737:chemistry; D018360:Crystallography, X-Ray; D004148:Dioxolanes / Q000737:chemistry; D004987:Ethers / Q000737:chemistry; D004988:Ethers, Cyclic / Q000138:chemical synthesis* / Q000737:chemistry; D008293:Malates / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry; D012825:Silicon / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000480:Alkynes; D004148:Dioxolanes; D004987:Ethers; D004988:Ethers, Cyclic; D008293:Malates; D009942:Organometallic Compounds; D003035:Cobalt; C471861:brasilenyne; C030298:malic acid; C031133:ethylene carbonate; D012825:Silicon