Biomimetic enantioselective total synthesis of (-)-siccanin via the Pd-catalyzed asymmetric allylic alkylation (AAA) and sequential radical cyclizations.
Trost
Barry M
BM
Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA. bmtrost@stanford.edu
Shen
Hong C
HC
Surivet
Jean-Philippe
JP
D000478:Alkylation; D000498:Allyl Compounds / Q000737:chemistry*; D000935:Antifungal Agents / Q000138:chemical synthesis; D040761:Biomimetic Materials / Q000737:chemistry; D002384:Catalysis; D003500:Cyclization; D006375:Helminthosporium / Q000737:chemistry / Q000378:metabolism; D008958:Models, Molecular; D010165:Palladium / Q000737:chemistry; D013237:Stereoisomerism; D014966:Xanthenes / Q000138:chemical synthesis*
D000498:Allyl Compounds; D000935:Antifungal Agents; D014966:Xanthenes; D010165:Palladium; C001795:siccanin