title: Enzymatic reactions involving novel mechanisms of carbanion stabilization.
authors.affiliation: Department of Chemistry and Chemical Biology, Cornell University, Ithaca, New York, NY14853, USA. tpb2@cornell.edu
authors.forename: Tadhg P
authors.initials: TP
authors.lastname: Begley
authors.forename: Steven E
authors.initials: SE
authors.lastname: Ealick
mesh_terms: D000447:Aldehydes / Q000737:chemistry / Q000378:metabolism; D001665:Binding Sites; D002262:Carboxy-Lyases / Q000737:chemistry / Q000378:metabolism*; D002384:Catalysis; D008190:Lyases / Q000737:chemistry / Q000378:metabolism; D015394:Molecular Structure; D009964:Orotidine-5'-Phosphate Decarboxylase / Q000737:chemistry / Q000378:metabolism*; D013438:Sulfhydryl Compounds / Q000737:chemistry / Q000378:metabolism
chemical_list: D000447:Aldehydes; D013438:Sulfhydryl Compounds; D008190:Lyases; D002262:Carboxy-Lyases; C021915:oxalate decarboxylase; D009964:Orotidine-5'-Phosphate Decarboxylase; C022373:Phosphopantothenoyl-cysteine decarboxylase; C050953:alkylmercury lyase