Reactions of meso-hydroxyhemes with carbon monoxide and reducing agents in search of the elusive species responsible for the g = 2.006 resonance of carbon monoxide-treated heme oxygenase. Isolation of diamagnetic iron(II) complexes of octaethyl-meso-hydroxyporphyrin.
Rath
Sankar Prasad
SP
Department of Chemistry, University of California, Davis, California 95616, USA.
Olmstead
Marilyn M
MM
Balch
Alan L
AL
D002248:Carbon Monoxide / Q000737:chemistry*; D004578:Electron Spin Resonance Spectroscopy / Q000379:methods; D005296:Ferrous Compounds / Q000737:chemistry / Q000302:isolation & purification; D006418:Heme / Q000031:analogs & derivatives / Q000737:chemistry*; D006419:Heme Oxygenase (Decyclizing) / Q000737:chemistry*; D008280:Magnetics; D008665:Metalloporphyrins / Q000737:chemistry* / Q000302:isolation & purification; D008956:Models, Chemical; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry* / Q000302:isolation & purification; D019163:Reducing Agents / Q000737:chemistry*
D005296:Ferrous Compounds; D008665:Metalloporphyrins; D009942:Organometallic Compounds; D019163:Reducing Agents; D006418:Heme; D002248:Carbon Monoxide; D006419:Heme Oxygenase (Decyclizing)