Total synthesis of (+)-brasilenyne. Application of an intramolecular silicon-assisted cross-coupling reaction.
Denmark
Scott E
SE
Roger Adams Laboratory, Department of Chemistry, University of Illinois, Urbana, Illinois 61801, USA. denmark@scs.uiuc.edu
Yang
Shyh-Ming
SM
D000480:Alkynes / Q000737:chemistry; D003035:Cobalt / Q000737:chemistry; D018360:Crystallography, X-Ray; D004148:Dioxolanes / Q000737:chemistry; D004987:Ethers / Q000737:chemistry; D004988:Ethers, Cyclic / Q000138:chemical synthesis* / Q000737:chemistry; D008293:Malates / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry; D012825:Silicon / Q000737:chemistry*; D013237:Stereoisomerism
D000480:Alkynes; D004148:Dioxolanes; D004987:Ethers; D004988:Ethers, Cyclic; D008293:Malates; D009942:Organometallic Compounds; D003035:Cobalt; C471861:brasilenyne; C030298:malic acid; C031133:ethylene carbonate; D012825:Silicon