Development of pressurized liquid extraction and cleanup procedures for determination of organochlorine pesticides in soils.
The scope of this work is the development of a rapid, reliable and sensitive method for the analysis of organochlorine pesticides from soils by pressurized liquid extraction (PLE). The effect of four parameters (temperature, pressure, static time and cell volume) on the extraction efficiency was studied. The great extracting power of the PLE causes the extraction of numerous interfering substances, so a more efficient purification of this extract was necessary. In this work several sorbents have also been assayed to carry out the purification of soil samples: Florisil, silica, alumina, carbon, as well as combinations of them. Finally, the proposed analytical method was validated using a certified reference soil material (CRM804-050) and the results were compared with those obtained by other extraction techniques (Soxhlet and microwave-assisted extraction).
Concha-Graña
E
E
Department of Analytical Chemistry, Faculty of Sciences, University of A Coruña, Campus da Zapateira, E-15071 A Coruña, Spain.
Turnes-Carou
M I
MI
Muniategui-Lorenzo
S
S
López-Mahía
P
P
Fernández-Fernández
E
E
Prada-Rodríguez
D
D
D000818:Animals; D010575:Pesticides / Q000032:analysis*; D011312:Pressure; D015203:Reproducibility of Results; D012989:Soil Pollutants / Q000032:analysis* / Q000302:isolation & purification
D010575:Pesticides; D012989:Soil Pollutants