Mechanical properties of HDPE/UHMWPE blends: effect of filler loading and filler treatment.
Various blend ratios of high-density polyethylene (HDPE) and ultra high molecular weight polyethylene (UHMWPE) were prepared with the objective of determining their suitability as biomaterials. In the unfilled state, a blend of 50/50 (HDPE/UHMWPE) ratio by weight was found to yield optimum properties in terms of processability and mechanical properties. Hydroxyapatite (HA) was compounded with the optimum blend ratio. The effects of HA loading, varied from 0 to 50wt% for both filled and unfilled blends were tested for mechanical properties. It was found that the inclusion of HA in the blend led to a remarkable improvement of mechanical properties compared to the unfilled blend. In order to improve the bonding between the polymer blend and the filler, the HA used was chemically treated with a coupling agent known as 3-(trimethoxysiyl) propyl methacrylate and the treated HA was mixed into the blend. The effect of mixing the blend with silane-treated HA also led to an overall improvement of mechanical properties.
Lai
K L K
KL
Polymer Engineering Division, School of Materials and Mineral Resources Engineering, University Science of Malaysia.
Roziyanna
A
A
Ogunniyi
D S
DS
Zainal
Arifin M I
AM
Azlan
Ariffin A
AA
D001672:Biocompatible Materials / Q000032:analysis / Q000138:chemical synthesis*; D001696:Biomechanical Phenomena; D017886:Durapatite / Q000032:analysis / Q000138:chemical synthesis*; D006801:Humans; D008422:Materials Testing; D020959:Polyethylene / Q000032:analysis / Q000138:chemical synthesis*; D011095:Polyethylenes / Q000032:analysis / Q000138:chemical synthesis*; D013329:Structure-Activity Relationship
D001672:Biocompatible Materials; D011095:Polyethylenes; C111601:ultra-high molecular weight polyethylene; D020959:Polyethylene; D017886:Durapatite