Intramolecular reduction of the nitro group into phosphoraneimine mediated by a rhenium(v) complex. Synthesis and structure of the novel phosphoraneimine oxorhenium(v) complex [ReOCl[o-(PPh3=N)C6H4(NCH2CH2N(CH2CO2H)CH2CO2]].
The title compound was synthesised via an unexpected intramolecular reduction of a nitro group in the oxo-Re(v) coordination sphere.
Allali
M
M
Laboratoire de Chimie Inorganique, Université P. Sabatier, 31062 Toulouse, France.
Benoist
E
E
Gressier
M
M
Jaud
J
J
Habbadi
N
N
Souizi
A
A
Dartiguenave
M
M