Molecularly imprinted solid-phase extraction of naphthalene sulfonates from water.
A new polymeric sorbent synthesised by exploiting molecular imprinting technology has been used to selectively extract naphthalene sulfonates (NSs) directly from aqueous samples. In the non-covalent molecular imprinting approach used to prepare this polymer, 1-naphthalene sulfonic acid (1-NS) and 4-vinylpyridine (4-VP) were used as a template molecule and functional monomer, respectively, and both dissolved in a mixture of methanol/water (4:1) as porogen together with the cross-linker ethylene glycol dimethacrylate. The new non-covalent molecularly imprinted polymer (MIP) prepared in aqueous environment was used as a sorbent in solid-phase extraction (SPE) to selectively extract a group of naphthalene mono- and disulfonates. When one litre of a standard aqueous solution, which contained a mixture of eight NSs, was percolated through the SPE cartridge, all the NSs were retained on the MIP because of the cross-reactivity of the polymer. Recoveries were higher than 80% for all the compounds even after a clean-up step with methanol (MeOH). The MIP was also used to analyse water from the Ebro river.
Caro
Ester
E
Departament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili, Imperial Tarraco 1, 43005 Tarragona, Spain.
Marcé
Rosa M
RM
Cormack
Peter A G
PA
Sherrington
David C
DC
Borrull
Francesc
F
D009282:Naphthalenesulfonates / Q000737:chemistry*; D014867:Water / Q000737:chemistry*
D009282:Naphthalenesulfonates; D014867:Water