The reaction of RhCp*(CH3)2(L)(L = pyridine, dmso) with GaCp* and AlCp*: a new type of carbon-carbon bond activation reaction.
Reaction of RhCp*(L)(CH(3))(2)(L = pyridine, dmso) with equimolar amounts of GaCp* at 60 degrees C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe(4)GaMe(3))]. [Cp*Rh(CH(3))(2)(GaCp*)] could be isolated and identified as an intermediate in this reaction.
Anorganische Chemie II, Ruhr Universität Bochum, 44780 Bochum, Germany.
Thomas
T
Cadenbach
Christian
C
Gemel
Rochus
R
Schmid
Stefan
S
Block
Roland A
RA
Fischer