Preparation of polyaniline coating on a stainless-steel wire using electroplating and its application to the determination of six aromatic amines using headspace solid-phase microextraction.
A novel polyaniline (PANI) coating was prepared on a stainless-steel wire for solid-phase microextraction by electroplating method. For better mechanical strength, the stainless-steel wire was used instead of the fused silica fiber. The electroplating method had advantages of ease of preparation and simple equipments. The PANI fiber was evaluated by analyzing six aromatic amines (aniline, N,N-dimethylaniline, m-methylaniline, 2,4-dimethylaniline, 2-chloroaniline, 3,4-dichloroaniline) in water. After the analytical procedure was optimized, the linearity was from 4.8 to 2.75 x 10(4) microg L(-1) and the detection limits was from 0.019 to 1.06 microg L(-1). Relative standard deviations were found to be 2.02-6.00%. Good recoveries were obtained when wastewater samples were analyzed.
Research Center for Eco-environmental Science, Chinese Academy of Sciences, Beijing 100085, PR China.
Huang
H
Minjia
Tai
T
Chao
Zhou
Z
Qunfang
Jiang
J
Guibin
D000588:Amines / Q000032:analysis*; D000814:Aniline Compounds / Q000032:analysis* / Q000737:chemistry*; D004595:Electroplating / Q000295:instrumentation / Q000379:methods*; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D013193:Stainless Steel / Q000737:chemistry*
D000588:Amines; D000814:Aniline Compounds; C416807:polyaniline; D013193:Stainless Steel