Intramolecular reduction of the nitro group into phosphoraneimine mediated by a rhenium(v) complex. Synthesis and structure of the novel phosphoraneimine oxorhenium(v) complex [ReOCl[o-(PPh3=N)C6H4(NCH2CH2N(CH2CO2H)CH2CO2]].
The title compound was synthesised via an unexpected intramolecular reduction of a nitro group in the oxo-Re(v) coordination sphere.
Laboratoire de Chimie Inorganique, Université P. Sabatier, 31062 Toulouse, France.
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M
Allali
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Benoist
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M
Gressier
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Jaud
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N
Habbadi
A
A
Souizi
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M
Dartiguenave