Novel aggregation of [Ni(thiolato)2(amine)2]-type square planes assisted by silver(I) ions.
Treatment of [Ni(L)][L =((-)SCH(2)CH(2)NH[double bond, length as m-dash]C(CH(3))-)(2)] with Ag(+) in water gave a pinwheel-like S-bridged Ni(II)(3)Ag(I)(2) structure in [Ag(2)[Ni(L)](3)](2+), which further reacted with [Ni(L)] to produce a Ni(II)(4)Ag(I)(2) structure in [Ag(2)[Ni(L)](4)](2+) and a Ni(II)(7)Ag(I)(4) structure in [Ag(4)[Ni(L)](7)](4+).
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan. konno@ch.wani.osaka-u.ac.jp.
Takumi
T
Konno
Masafumi
M
Usami
Masakazu
M
Hirotsu
Takashi
T
Yoshimura
Tatsuya
T
Kawamoto