Preconcentration of mercury using duolite GT-73 in the analysis of water samples by inductively coupled plasma atomic emission spectrometry.
Duolite GT-73 resin was used for the preconcentration of Hg(II) from hydrochloric acid media as well as separation of the analyte from diversity of the co-existing metal ions (Al, Ca, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, Pb and Zn) in off-line column operation. Due to the high affinity of the resin to the transition metals, Hg was adsorbed alongside with the foreign metals investigated. A complete release of the concomitant metals from the resin without the desorption of Hg was carried out using solutions of HCl and HNO3. A quantitative recovery of Hg was obtained by digestion of the resin using a H2SO4 and H2O2 mixture in an open-vessel system. An enrichment factor of 40 was achieved. The devised procedure was applied for the determination of Hg(II) in tap-water samples.
Wroclaw University of Technology, Institute of Inorganic Chemistry and Metallurgy of Rare Elements, Wybrzeze Wyspianskiego 27, 50-370 Wroclaw, Poland. pawel.pohl@pwr.wroc.pl
Pawel
P
Pohl
Bartlomiej
B
Prusisz