Mechanism of 4,6-O-benzylidene-directed beta-mannosylation as determined by alpha-deuterium kinetic isotope effects.
Department of Chemistry, University of Illinois at Chicago, 845 West Taylor Street, Chicago, IL 60607-7061, USA. dcrich@uic.edu
David
D
Crich
N Susantha
NS
Chandrasekera
D001597:Benzylidene Compounds / Q000737:chemistry*; D003903:Deuterium / Q000737:chemistry*; D006031:Glycosylation; D007553:Isotope Labeling; D007554:Isotopes / Q000737:chemistry*; D007700:Kinetics; D008358:Mannose / Q000737:chemistry*; D008956:Models, Chemical; D013865:Thioglycosides / Q000138:chemical synthesis
D001597:Benzylidene Compounds; D007554:Isotopes; D013865:Thioglycosides; D003903:Deuterium; D008358:Mannose