A neutron scattering study of the structure and water partitioning of selectively deuterated copolymer micelles.
We present a scattering study of a selectively deuterated micelle-forming diblock copolymer. The copolymer comprises a partially deuterated polystyrene (d,h-PS) block and an imidazolium-functionalized PS (IL) block. In toluene solutions, the copolymers assemble into elongated micelles where the IL block forms the micelle core. Through dynamic light scattering (DLS) measurements, we obtain the overall size of the micelles. In our small-angle neutron scattering (SANS) studies, we use contrast matching to characterize the IL core and the PS shell of the micelles independently. The PS block forming the micelle shell exhibits either a starlike or brushlike conformation depending upon the size of the core to which it is tethered. We find the IL block to be in an extended conformation, driving the formation of slightly elongated and relatively stiff micelle cores. The elongated micelle core cross-sectional radius and length depend linearly on the length of the IL block. We find that the micelles can sequester a few water molecules for each IL repeat unit; the addition of water slightly increases the cross section of the elongated micelles.
Stancik
Cheryl M
CM
Department of Chemical Engineering, Stanford University, Stanford, California 94305, USA.
Lavoie
Adrien R
AR
Achurra
Paulina A
PA
Waymouth
Robert M
RM
Gast
Alice P
AP
D003903:Deuterium / Q000737:chemistry; D007093:Imidazoles / Q000737:chemistry*; D008823:Micelles; D015394:Molecular Structure; D033363:Neutron Diffraction / Q000379:methods*; D010316:Particle Size; D011137:Polystyrenes / Q000138:chemical synthesis / Q000737:chemistry*; D013499:Surface Properties; D014867:Water / Q000737:chemistry
D007093:Imidazoles; D008823:Micelles; D011137:Polystyrenes; D014867:Water; D003903:Deuterium