Synthesis and reactivity of triethylborane adduct of N-heterocyclic carbene: versatile synthons for synthesis of N-heterocyclic carbene complexes.
The reaction of an imidazolium salt with LiBEt(3)H afforded triethylborane adduct of imidazol-2-ylidene, which can act as a carbene precursor for the synthesis of a transition metal complex as well as a main group element complex.
Yamaguchi
Yoshitaka
Y
Department of Materials Chemistry, Graduate School of Engineering, Yokohama National University, Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan.
Kashiwabara
Taigo
T
Ogata
Kenichi
K
Miura
Yumiko
Y
Nakamura
Yoshiyuki
Y
Kobayashi
Kimiko
K
Ito
Takashi
T