Syntheses of alkenylated carbohydrate derivatives toward the preparation of monolayers on silicon surfaces.
This note describes the synthesis of different alkenylated carbohydrate derivatives suitable for direct attachment to hydrogen-terminated silicon surfaces. The derivatives were alkenylated at the C-1 position, while the remaining hydroxyl groups were protected. The development of such new carbohydrate-based sensing elements opens the access to new classes of biosensors.
de Smet
Louis C P M
LC
Laboratory of Organic Chemistry, Wageningen University, Dreijenplein 8, 6703 HB Wageningen, The Netherlands.
Pukin
Aliaksei V
AV
Stork
Gerrit A
GA
Ric de Vos
C H
CH
Visser
Gerben M
GM
Zuilhof
Han
H
Sudhölter
Ernst J R
EJ
D000475:Alkenes / Q000138:chemical synthesis; D015374:Biosensing Techniques; D002241:Carbohydrates / Q000138:chemical synthesis*; D012825:Silicon; D013499:Surface Properties
D000475:Alkenes; D002241:Carbohydrates; D012825:Silicon