A resonance-mediated non-adiabatic reaction: F*(2P1/2) + HD --> HF(v' = 3) + D.
The reaction of F(2P3/2,1/2) + HD --> HF(v' = 3) + D was investigated in a rotating-source, crossed-beam machine. The high translational energy resolution afforded by the Doppler-selected time-of-flight technique enabled us to distinguish the differential attributes of the HF(v' = 3) + D products of the ground state (2P3/2) reaction from those due to the spin-orbit excited (2P1/2) one. It was found that the F*(2P1/2) reactivity is significantly smaller than that for F(2P3/2), and the two state-to-state angular distributions exhibit remarkable similarities, though some differences were noted. Comparing the results with those concluded previously, we assert that both the adiabatic (F(2P3/2) + HD) and, in particular, the non-adiabatic (F*(2P1/2) + HD) reactions are predominantly mediated by a resonance mechanism for the formation of the HF(v' = 3) + D channel.
Institute of Atomic and Molecular Sciences, Academia Sinica, Taipei, Taiwan 106.
Shih-Huang
SH
Lee
Feng
F
Dong
Kopin
K
Liu