Molecular tectonics: design of luminescent H-bonded molecular networks.
Using bis-amidinium dications as tetra H-bond donor tectons and Au(CN)(2)(-) anion, neutral 1-D networks based on a bis monohapto mode of H-bonding are obtained. Owing to the short metal-metal distance within the network, luminescent crystals are obtained. The emission phenomena may be tuned by the nature of the spacer connecting the two cyclic amidinium groups.
Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université Louis Pasteur, Strabourg, France.
Carmen
C
Paraschiv
Sylvie
S
Ferlay
Mir Wais
MW
Hosseini
Véronique
V
Bulach
Jean-Marc
JM
Planeix