Activated carbon and tungsten oxide supported on activated carbon catalysts for toluene catalytic combustion.
We have used activated carbon (AC) prepared from almond shells as a support for tungsten oxide to develop a series of WOx/AC catalysts for the catalytic combustion of toluene. We conducted the reaction between 300 and 350 degrees C, using a flow of 500 ppm of toluene in air and space velocity (GHSV) in the range 4000-7000 h(-1). Results show that AC used as a support is an appropriate material for removing toluene from dilute streams. By decreasing the GHSV and increasing the reaction temperature AC becomes a specific catalyst for the total toluene oxidation (SCO2 = 100%), but in less favorable conditions CO appears as reaction product and toluene-derivative compounds are retained inside the pores. WOx/AC catalysts are more selective to CO2 than AC due to the strong acidity of this oxide; this behavior improves with increased metal loading and reaction temperature and contact time. The catalytic performance depends on the nonstoichiometric tungsten oxide obtained during the pretreatment. In comparison with other supports the WOx/AC catalysts present, at low reaction temperatures, higher activity and selectivity than WO, supported on SiO2, TiO2, Al2O3, or Y zeolite. This is due to the hydrophobic character of the AC surface which prevents the adsorption of water produced from toluene combustion thus avoiding the deactivation of the active centers. However, the use of WOx/AC system is always restricted by its gasification temperature (around 400 degrees C), which limits the ability to increase the conversion values by increasing reaction temperatures.
Alvarez-Merino
M A
MA
Departamento Química Inorgánica y Orgánica, Facultad de Ciencias Experimentales, Universidad de Jaén, 23071, Jaén, Spain.
Ribeiro
M F
MF
Silva
J M
JM
Carrasco-Marín
F
F
Maldonado-Hódar
F J
FJ
D000397:Air Pollution / Q000517:prevention & control*; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D002606:Charcoal / Q000737:chemistry; D017745:Incineration / Q000379:methods; D010084:Oxidation-Reduction; D012997:Solvents / Q000737:chemistry*; D014050:Toluene / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*
D012997:Solvents; D017973:Tungsten Compounds; D002606:Charcoal; D014050:Toluene; D002244:Carbon