A very large Rh-Rh bond shortening on excitation of the [Rh2(1,8-diisocyano-p-menthane)4]2+ ion by time-resolved synchrotron X-ray diffraction.
A very large Rh-Rh contraction of approximately 0.85 A occurs on excitation of the [Rh(2)(1,8-diisocyano-p-menthane)(4)](2+) ion to its triplet state.
Coppens
Philip
P
Department of Chemistry, SUNY at Buffalo, Buffalo, New York, USA. coppens@acsu.buffalo.edu
Gerlits
Oksana
O
Vorontsov
Ivan I
II
Kovalevsky
Andrey Yu
AY
Chen
Yu-Sheng
YS
Graber
Tim
T
Gembicky
Milan
M
Novozhilova
Irina V
IV