Oligomer preparation from hexane by radical polyaddition with bis(alpha-trifluoromethyl-beta,beta-difluorovinyl) terephthalate.
Polymer preparation from hexane as a starting material by radical polyaddition with bis(alpha-trifluoromethyl-beta,beta-difluorovinyl) terephthalate [CF(2)=C(CF(3))OCOC(6)H(4)COO-C(CF(3))=CF(2)] was investigated to afford polymers bearing a molecular weight of as high as 5.5 x 10(3), and the polyaddition mechanism including 1,5-radical shift mechanism was proposed.
Narita
Tadashi
T
Department of Material Science and Engineering, Graduate School of Engineering, Saitma Institute of Technology, 1690 Fusaiji, Okabe, Saitama, 369-0293, Japan. narita@sit.ac.jp.
Hamana
Hiroshi
H
Hattori
Satoshi
S