The reaction of RhCp*(CH3)2(L)(L = pyridine, dmso) with GaCp* and AlCp*: a new type of carbon-carbon bond activation reaction.
Reaction of RhCp*(L)(CH(3))(2)(L = pyridine, dmso) with equimolar amounts of GaCp* at 60 degrees C quantitatively leads to the zwitterionic species [Cp*Rh(CpMe(4)GaMe(3))]. [Cp*Rh(CH(3))(2)(GaCp*)] could be isolated and identified as an intermediate in this reaction.
Cadenbach
Thomas
T
Anorganische Chemie II, Ruhr Universität Bochum, 44780 Bochum, Germany.
Gemel
Christian
C
Schmid
Rochus
R
Block
Stefan
S
Fischer
Roland A
RA