Molecular tectonics: design of luminescent H-bonded molecular networks.
Using bis-amidinium dications as tetra H-bond donor tectons and Au(CN)(2)(-) anion, neutral 1-D networks based on a bis monohapto mode of H-bonding are obtained. Owing to the short metal-metal distance within the network, luminescent crystals are obtained. The emission phenomena may be tuned by the nature of the spacer connecting the two cyclic amidinium groups.
Paraschiv
Carmen
C
Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université Louis Pasteur, Strabourg, France.
Ferlay
Sylvie
S
Hosseini
Mir Wais
MW
Bulach
Véronique
V
Planeix
Jean-Marc
JM