High temperature removal of hydrogen sulfide using an N-150 sorbent.
In this study, an N-150 sorbent was used as a high temperature desulfurization sorbent for the removal of hydrogen sulfide from coal gas in a fixed bed reactor. The results indicate that the N-150 sorbent could be used for H(2)S removal in the tested temperature ranges. Regeneration test also reveals that utilization of the N-150 sorbent maintains up to 85% compared to the fresh sorbent. No significant degeneration occurs on the N-150 sorbent. In addition, various concentrations of H(2)S, H(2) and CO were also considered in the performance test of the N-150 sorbent. Except for H(2)S, H(2) and CO act the important roles in the high temperature desulfurization. By increasing the H(2) concentration, the sulfur capacity of the sorbent decreases and an adverse result is observed in the case of increasing CO concentration. This can be explained via water-shift reaction. On the basis of the instrument analysis, X-ray powder diffraction determination and SEM images with EDS spectrum characterization, residual sulfur is found in the regenerated N-150 sorbent and this sulfur species is sulfate which resulted by incomplete regeneration. The sulfate formation and sintering effect are major reasons to cause activity loss in the sulfidation/regeneration cycles.
Ko
T H
TH
Department of Environmental Engineering, National Cheng Kung University, 1 University Road, Tainan 70101, Taiwan.
Chu
H
H
Chaung
L K
LK
Tseng
T K
TK
D000042:Absorption; D000395:Air Pollutants, Occupational / Q000032:analysis*; D003031:Coal; D005290:Ferric Compounds / Q000737:chemistry*; D006358:Hot Temperature; D006862:Hydrogen Sulfide / Q000737:chemistry*; D017895:Manganese Compounds / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D010087:Oxides / Q000737:chemistry*; D016062:Porosity; D013455:Sulfur / Q000032:analysis; D013499:Surface Properties; D013696:Temperature; D014961:X-Ray Diffraction
D000395:Air Pollutants, Occupational; D003031:Coal; D005290:Ferric Compounds; D017895:Manganese Compounds; C497490:N-150 sorbent; D010087:Oxides; D013455:Sulfur; D006862:Hydrogen Sulfide