title: Periodic mesoporous phenylenesilicas with ether or sulfide hinge groups--a new class of PMOs with ligand channels.
abstract: A new class of periodic mesoporous organosilicas (PMOs) with 4-phenyl ether and 4-phenyl sulfide bridge-bonded silsesquioxanes integrated into the pore walls to create ligand channels have been synthesized using inorganic salt-assisted self-assembly directed by a supramolecular polyoxyethylene (10) stearyl ether (Brij 76) template.
authors.affiliation: Materials Chemistry Research Group, Department of Chemsitry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6.
authors.forename: William J
authors.initials: WJ
authors.lastname: Hunks
authors.forename: Geoffrey A
authors.initials: GA
authors.lastname: Ozin
mesh_terms: D004987:Ethers / Q000737:chemistry*; D008024:Ligands; D017646:Organosilicon Compounds / Q000138:chemical synthesis* / Q000737:chemistry / Q000145:classification*; D016062:Porosity; D013440:Sulfides / Q000737:chemistry*
chemical_list: D004987:Ethers; D008024:Ligands; D017646:Organosilicon Compounds; D013440:Sulfides