title: On-line analysis of diesel engine exhaust gases by selected ion flow tube mass spectrometry.
abstract: Selected ion flow tube mass spectrometry (SIFT-MS) has been used to analyse on-line and in real time the exhaust gas emissions from a Caterpillar 3304 diesel engine under different conditions of load (idle and 50% of rated load) and speed (910, 1500 and 2200 rpm) using three types of fuel: an ultra-low-sulphur diesel, a rapeseed methyl ester and gas oil. SIFT-MS analyses of the alkanes, alkenes and aromatic hydrocarbons in the headspace of these fuels were also performed, but the headspace of the rapeseed methyl ester consists mainly of methanol and a compound with the molecular formula C4H8O. The exhaust gases were analysed for NO and NO2 using O2+* reagent ions and for HNO2 using H3O+ reagent ions. The following aldehydes and ketones in the exhaust gases were quantified by using the combination of H3O+ and NO+ reagent ions: formaldehyde, acetaldehyde, propenal, propanal, acetone, butanal, pentanal, butanone and pentanone. Formaldehyde, acetaldehyde and pentenal, all known respiratory irritants associated with sensitisation to asthma of workers exposed to diesel exhaust, are variously present within the range 100-2000 ppb. Hydrocarbons in the exhaust gases accessible to SIFT-MS analyses were also quantified as total concentrations of the various isomers of C3H4, C3H6, C4H6, C5H8, C5H10, C6H8, C6H10, C7H14, C6H6, C7H8, C8H10 and C9H12.
authors.affiliation: Institute of Science and Technology in Medicine, School of Medicine, Keele University, Thornburrow Drive, Hartshill, Stoke-on-Trent ST4 7QB, UK. d.smith@bemp.keele.ac.uk
authors.forename: David
authors.initials: D
authors.lastname: Smith
authors.forename: Patrik
authors.initials: P
authors.lastname: Spanĕl
authors.forename: David
authors.initials: D
authors.lastname: Dabill
authors.forename: John
authors.initials: J
authors.lastname: Cocker
authors.forename: Bob
authors.initials: B
authors.lastname: Rajan
mesh_terms: D000395:Air Pollutants, Occupational / Q000032:analysis*; D004784:Environmental Monitoring / Q000379:methods; D013058:Mass Spectrometry / Q000295:instrumentation* / Q000379:methods*; D016273:Occupational Exposure; D009862:Online Systems; D006113:United Kingdom; D001335:Vehicle Emissions / Q000032:analysis*
chemical_list: D000395:Air Pollutants, Occupational; D001335:Vehicle Emissions