title: Development of highly active and selective novel Pd based acetoxylation catalysts and prevention of catalyst deactivation by Bi modification.
abstract: A first approach to successful prevention of catalyst deactivation while simultaneously achieving extremely high selectivity of benzyl acetate (> or = 95%) at significantly high toluene conversion (> 70%) by gas phase acetoxylation over novel Pd-Sb-Bi/TiO2 catalysts.
authors.affiliation: Institut für Angewandte Chemie Berlin-Adlershof e.V., Berlin, Germany.
authors.forename: A
authors.initials: A
authors.lastname: Benhmid
authors.forename: K V
authors.initials: KV
authors.lastname: Narayana
authors.forename: A
authors.initials: A
authors.lastname: Martin
authors.forename: B
authors.initials: B
authors.lastname: Lucke
authors.forename: M-M
authors.initials: MM
authors.lastname: Pohl
mesh_terms: D000965:Antimony / Q000737:chemistry; D001593:Benzyl Compounds / Q000138:chemical synthesis*; D001729:Bismuth / Q000737:chemistry*; D002384:Catalysis; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*; D010316:Particle Size; D013997:Time Factors; D014025:Titanium / Q000737:chemistry; D014050:Toluene / Q000737:chemistry*
chemical_list: D001593:Benzyl Compounds; C046412:benzyl acetate; C009495:titanium dioxide; D014050:Toluene; D010165:Palladium; D000965:Antimony; D014025:Titanium; D001729:Bismuth