title: Oxygen-promoted palladium(II) catalysis: facile C(sp2)-C(sp2) bond formation via cross-coupling of alkenylboronic compounds and olefins.
abstract: [reaction: see text] Oxygen-promoted Pd(II) catalysis facilitated the synthesis of conjugated dienes by cross-coupling of alkenylboronic compounds and various olefins including highly substituted alkenes and cyclohexenone. Under mild conditions, these versatile reactions were efficient and highly stereoselective.
authors.affiliation: Department of Chemistry, University of South Florida (SCA 400), 4202 East Fowler Avenue, Tampa, Florida 33620, USA.
authors.forename: Cheol Hwan
authors.initials: CH
authors.lastname: Yoon
authors.forename: Kyung Soo
authors.initials: KS
authors.lastname: Yoo
authors.forename: Sung Wook
authors.initials: SW
authors.lastname: Yi
authors.forename: Rajesh K
authors.initials: RK
authors.lastname: Mishra
authors.forename: Kyung Woon
authors.initials: KW
authors.lastname: Jung
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry*; D002384:Catalysis; D002413:Cations, Divalent; D003432:Cross-Linking Reagents / Q000737:chemistry; D003512:Cyclohexanones / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D001896:Boron Compounds; D002413:Cations, Divalent; D003432:Cross-Linking Reagents; D003512:Cyclohexanones; D010165:Palladium; D010100:Oxygen