Regioselective copolymerization of acryl sucrose monomers.
1',2,3,3',4,4',6-Hepta-O-benzyl-sucrose has been prepared and selectively 6'-O-esterified with small alpha,beta-unsaturated acid derivatives. New chiral copolymers containing sucrose have been synthesized by radical polymerization, and some of their physical properties have been determined.
Barros
Maria Teresa
MT
REQUIMTE, CQFB, Departamento de Química, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal. mtbarros@dq.fct.unl.pt
Petrova
Krasimira T
KT
Ramos
Ana Maria
AM
D004951:Esterification; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry*; D013237:Stereoisomerism; D013395:Sucrose / Q000031:analogs & derivatives* / Q000138:chemical synthesis*
D011108:Polymers; D013395:Sucrose