title: Efficient, near-complete removal of DNAPL from three-dimensional, heterogeneous porous media using a novel combination of treatment technologies.
abstract: Remediation of porous media containing an entrapped dense nonaqueous phase liquid (DNAPL) is extremely difficult due to the heterogeneity and three-dimensional spatial nature of typical natural systems. A novel treatment technology based on surfactant- and gravity-induced mobilization, dense brine containment and collection, and a vapor-phase extraction polishing step is proposed as a means to remediate such systems. Laboratory experiments are performed using the suggested methodology applied to three-dimensional, heterogeneous systems, which are packed based upon a realization from a correlated random field. Entrapped DNAPL is effectively removed as a result of each component of the technology. Following vapor extraction, less than 1% of the original DNAPL mass remained in the system. While these results are very promising, several open issues must be resolved before this technology can be considered mature; both the investigation of some of these issues and a summary of remaining needs are addressed.
authors.affiliation: Department of Environmental Sciences and Engineering, University of North Carolina, Chapel Hill, North Carolina 27599-7431, USA.
authors.forename: D N
authors.initials: DN
authors.lastname: Johnson
authors.forename: J A
authors.initials: JA
authors.lastname: Pedit
authors.forename: C T
authors.initials: CT
authors.lastname: Miller
mesh_terms: D006112:Gravitation; D008962:Models, Theoretical; D016062:Porosity; D012989:Soil Pollutants / Q000302:isolation & purification*; D012995:Solubility; D013501:Surface-Active Agents / Q000737:chemistry*; D014835:Volatilization
chemical_list: D012989:Soil Pollutants; D013501:Surface-Active Agents