Absorption line CW EPR using an amplitude modulated longitudinal field.
In standard continuous wave electron paramagnetic resonance (CW-EPR) experiments, the first derivative of absorption lines is detected. This type of a line shape is caused by the magnetic field modulation and is usually an undesired feature, since the sensitivity of CW-EPR drastically decreases with increasing linewidth. A new approach is introduced, which allows for the measurement of absorption line EPR spectra in systems with broad inhomogeneous lines. The method makes use of multiple-photon transitions that are induced in spin systems when a transverse microwave and a longitudinal radio frequency field are simultaneously applied. The absorption lines are obtained by using amplitude modulation of the radio frequency field and slight saturation of the spectral lines. The basics of the new approach are discussed and experimental examples are given.
Fedin
Matvey
M
Physical Chemistry Laboratory, Department of Chemistry and Applied Biosciences, ETH-Hönggerberg, 8093 Zürich, Switzerland. fedin@esr.phys.chem.ethz.ch
Gromov
Igor
I
Schweiger
Arthur
A