title: Amorphous silicon exhibits a glass transition.
abstract: Amorphous silicon is a semiconductor with a lower density than the metallic silicon liquid. It is widely believed that the amorphous-liquid transition is a first-order melting transition. In contrast to this, recent computer simulations and the experimental observation of pressure-induced amorphization of nanoporous silicon have revived the idea of an underlying liquid-liquid phase transition implying the existence of a low-density liquid and its glass transition to the amorphous solid. Here we demonstrate that during irradiation with high-energy heavy ions amorphous silicon deforms plastically in the same way as conventional glasses. This behaviour provides experimental evidence for the existence of the low-density liquid. The glass transition temperature for a timescale of 10 picoseconds is estimated to be about 1,000 K. Our results support the idea of liquid polymorphism as a general phenomenon in tetrahedral networks.
authors.affiliation: Institut für Festkörperphysik, Friedrich-Schiller-Universität Jena, Max-Wien-Platz 1, D-07743 Jena, Germany. Hedler@pinet.uni-jena.de
authors.forename: André
authors.initials: A
authors.lastname: Hedler
authors.forename: Siegfried Ludwig
authors.initials: SL
authors.lastname: Klaumünzer
authors.forename: Werner
authors.initials: W
authors.lastname: Wesch
mesh_terms: D005898:Glass; D006358:Hot Temperature; D012825:Silicon / Q000737:chemistry*
chemical_list: D012825:Silicon