Leaching of CCA-treated wood: implications for waste disposal.
Leaching of arsenic, chromium, and copper from chromated copper arsenate (CCA)-treated wood poses possible environmental risk when disposed. Samples of un-weathered CCA-treated wood were tested using a variety of the US regulatory leaching procedures, including the toxicity characteristic leaching procedure (TCLP), synthetic precipitation leaching procedure (SPLP), extraction procedure toxicity method (EPTOX), waste extraction test (WET), multiple extraction procedure (MEP), and modifications of these procedures which utilized actual MSW landfill leachates, a construction and demolition (C and D) debris leachate, and a concrete enhanced leachate. Additional experiments were conducted to assess factors affecting leaching, such as particle size, pH, and leaching contact time. Results from the regulatory leaching tests provided similar results with the exception of the WET, which extracted greater quantities of metals. Experiments conducted using actual MSW leachate, C and D debris leachate, and concrete enhanced leachate provided results that were within the same order of magnitude as results obtained from TCLP, SPLP, and EPTOX. Eleven of 13 samples of CCA-treated dimensional lumber exceeded the US EPA's toxicity characteristic (TC) threshold for arsenic (5 mg/L). If un-weathered arsenic-treated wood were not otherwise excluded from the definition of hazardous waste, it frequently would require management as such. When extracted with simulated rainwater (SPLP), 9 of the 13 samples leached arsenic at concentrations above 5 mg/L. Metal leachability tended to increase with decreasing particle size and at pH extremes. All three metals leached above the drinking water standards thus possibly posing a potential risk to groundwater. Arsenic is a major concern from a disposal point of view with respect to ground water quality.
Townsend
Timothy
T
Department of Environmental Engineering Sciences, University of Florida, Gainesville, FL 32611-6450, USA. ttown@ufl.edu
Tolaymat
Thabet
T
Solo-Gabriele
Helena
H
Dubey
Brajesh
B
Stook
Kristin
K
Wadanambi
Lakmini
L
D001149:Arsenates / Q000032:analysis / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D010316:Particle Size; D012037:Refuse Disposal; D012995:Solubility; D012996:Solutions; D013048:Specimen Handling; D014481:United States; D014484:United States Environmental Protection Agency; D014865:Waste Disposal, Fluid; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000592:standards; D014877:Water Pollution, Chemical / Q000331:legislation & jurisprudence; D014934:Wood
D001149:Arsenates; D012996:Solutions; D014874:Water Pollutants, Chemical; C040890:chromated copper arsenate