Structurally diverse Rh(I) and Mn(I) complexes derived from the new ambidentate indene ligand, (1-[iPr2P(S)]-2-[NMe2])C9H6.
A new indene-based ligand featuring pendant phosphine sulfide and amine donor fragments has been developed; Rh(I) coordinates to the neutral form of the ligand in a kappa2-[N,S] fashion, while the anionic form of the ligand binds Rh(I) and Mn(I) in kappa2-[C,S] and eta5 modes, respectively.
Wechsler
Dominik
D
Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada, B3H 4J3.
McDonald
Robert
R
Ferguson
Michael J
MJ
Stradiotto
Mark
M
D018360:Crystallography, X-Ray; D007192:Indenes / Q000737:chemistry*; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D012238:Rhodium / Q000737:chemistry*
D007192:Indenes; D008024:Ligands; D009942:Organometallic Compounds; D008345:Manganese; D012238:Rhodium