Constituents of Crinoidea, 4. Isolation and structure of ceramides and glucocerebrosides from the feather star Comanthus japonica.
Five ceramides, JC-1-JC-5, and four glucocerebrosides, JCer-1-JCer-4, have been isolated from their parent ceramide and glucocerebroside molecular species JC and JCer obtained from the less polar lipid fraction of the chloroform/methanol extract of the feather star Comanthus japonica. The structures of these sphingolipids have been determined on the basis of chemical and spectroscopic evidence. Reversed-phase HPLC was effective at isolating these sphingolipids, revealing very close resemblance in their structures. JC-1, JC-3, JC-4, JC-5 and JCer-2, JCer-4 are newly found ceramides and glucocerebrosides, respectively.
Inagaki
Masanori
M
Faculty of Pharmaceutical Sciences, Kyushu University, 3-1-1 Maidashi, Higashi-ku, Fukuoka 812-8582, Japan.
Oyama
Akemi
A
Arao
Kazuyoshi
K
Higuchi
Ryuichi
R
D000818:Animals; D002518:Ceramides / Q000737:chemistry / Q000302:isolation & purification; D005963:Glucosylceramides / Q000737:chemistry* / Q000302:isolation & purification*; D013215:Starfish
D002518:Ceramides; D005963:Glucosylceramides