Enhancement of alpha-oxygen formation and N2O decomposition on Fe/ZSM-5 catalysts by extraframework Al.
The concentration of alpha-oxygen which can oxidize methane to methanol and benzene to phenol at RT, increases linearly with the amount of introduced extraframework Al on Fe/ZSM-5 catalysts prepared by solid-state exchange of FeCl3 and AlCl3 with H-ZSM-5.
Sun
Keqiang
K
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Zhang
Haidong
H
Xia
Haian
H
Lian
Yuxiang
Y
Li
Ying
Y
Feng
Zhaochi
Z
Ying
Pinliang
P
Li
Can
C
D000077410:Aluminum Chloride; D017607:Aluminum Compounds / Q000737:chemistry*; D002384:Catalysis; D002712:Chlorides / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D009609:Nitrous Oxide / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D013696:Temperature; D017641:Zeolites / Q000737:chemistry*
D017607:Aluminum Compounds; D002712:Chlorides; D005290:Ferric Compounds; D017641:Zeolites; D000077410:Aluminum Chloride; D007501:Iron; D009609:Nitrous Oxide; D010100:Oxygen; C024555:ferric chloride