Oxygen-promoted palladium(II) catalysis: facile C(sp2)-C(sp2) bond formation via cross-coupling of alkenylboronic compounds and olefins.
[reaction: see text] Oxygen-promoted Pd(II) catalysis facilitated the synthesis of conjugated dienes by cross-coupling of alkenylboronic compounds and various olefins including highly substituted alkenes and cyclohexenone. Under mild conditions, these versatile reactions were efficient and highly stereoselective.
Yoon
Cheol Hwan
CH
Department of Chemistry, University of South Florida (SCA 400), 4202 East Fowler Avenue, Tampa, Florida 33620, USA.
Yoo
Kyung Soo
KS
Yi
Sung Wook
SW
Mishra
Rajesh K
RK
Jung
Kyung Woon
KW
D000475:Alkenes / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry*; D002384:Catalysis; D002413:Cations, Divalent; D003432:Cross-Linking Reagents / Q000737:chemistry; D003512:Cyclohexanones / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
D000475:Alkenes; D001896:Boron Compounds; D002413:Cations, Divalent; D003432:Cross-Linking Reagents; D003512:Cyclohexanones; D010165:Palladium; D010100:Oxygen