Octahedral metal clusters as building units in a neutral layered honeycomb network, [Zn(en)]2[Nb6Cl12(CN)6].
A polymeric hybrid cluster-based compound with a double-layered honeycomb framework built of octahedral niobium cyanochloride clusters and [Zn(en)]2+ metal complexes was designed and synthesized at room temperature, and structurally characterized by single crystal X-ray diffraction.
Yan
Bangbo
B
Department of Chemistry, Wake Forest University, Winston-Salem, NC 27109, USA.
Day
Cynthia S
CS
Lachgar
Abdessadek
A
D008958:Models, Molecular; D009556:Niobium / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D014961:X-Ray Diffraction; D015032:Zinc / Q000737:chemistry*
D009942:Organometallic Compounds; D009556:Niobium; D015032:Zinc