title: Enhancement of alpha-oxygen formation and N2O decomposition on Fe/ZSM-5 catalysts by extraframework Al.
abstract: The concentration of alpha-oxygen which can oxidize methane to methanol and benzene to phenol at RT, increases linearly with the amount of introduced extraframework Al on Fe/ZSM-5 catalysts prepared by solid-state exchange of FeCl3 and AlCl3 with H-ZSM-5.
authors.affiliation: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
authors.forename: Keqiang
authors.initials: K
authors.lastname: Sun
authors.forename: Haidong
authors.initials: H
authors.lastname: Zhang
authors.forename: Haian
authors.initials: H
authors.lastname: Xia
authors.forename: Yuxiang
authors.initials: Y
authors.lastname: Lian
authors.forename: Ying
authors.initials: Y
authors.lastname: Li
authors.forename: Zhaochi
authors.initials: Z
authors.lastname: Feng
authors.forename: Pinliang
authors.initials: P
authors.lastname: Ying
authors.forename: Can
authors.initials: C
authors.lastname: Li
mesh_terms: D000077410:Aluminum Chloride; D017607:Aluminum Compounds / Q000737:chemistry*; D002384:Catalysis; D002712:Chlorides / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D009609:Nitrous Oxide / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D013696:Temperature; D017641:Zeolites / Q000737:chemistry*
chemical_list: D017607:Aluminum Compounds; D002712:Chlorides; D005290:Ferric Compounds; D017641:Zeolites; D000077410:Aluminum Chloride; D007501:Iron; D009609:Nitrous Oxide; D010100:Oxygen; C024555:ferric chloride