Surface properties and catalytic performance of La(1-x)Sr(x)FeO(3) perovskite-type oxides for methane combustion.
La(1-x)Sr(x)FeO(3) (x=0.0-1.0) perovskites were prepared and tested for the combustion of methane. X-ray diffraction (XRD) patterns revealed the presence of a single perovskite structure for substitutions 0x0.3, however Fe(2)O(3), SrCO(3) and SrFeO(3) phases were observed for substitutions x>0.3. The results of activity test indicate that with La(1-x)Sr(x)FeO(3) as the catalyst, the combustion of methane can take place at low temperatures around 400 degrees C. Partial substitution of La with Sr increases the activity and an optimal substitution fraction (x=0.5) exists in the La(1-x)Sr(x)FeO(3) catalysts. Catalyst activity can be well correlated to the product of the specific surface area and atomic ratio of Fe to La+Sr on the catalyst surface. Experimental results of O(2)-TPD and CH(4)-TPD in the range of 350-500 degrees C indicate that the amount of oxygen desorbed from the La(1-x)Sr(x)FeO(3) catalysts is far larger than that of methane. Therefore, it can be proposed that the catalytic oxidation of CH(4) over these catalysts proceeds with the surface reaction between CH(4) in the gas phase and the adsorbed O(2). Addition of water vapor or CO(2) to the feed inhibited catalyst activity, but the inhibition was reversible and became negligible at high reaction temperature.
Wang
Ching-Huei
CH
Department of Biochemical Engineering, Kao Yuan Institute of Technology, Kaohsiung 821, Taiwan.
Chen
Chun-Liang
CL
Weng
Hung-Shan
HS
D017610:Calcium Compounds / Q000737:chemistry; D002384:Catalysis; D005290:Ferric Compounds / Q000737:chemistry*; D007811:Lanthanum / Q000737:chemistry; D008697:Methane / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry; D013324:Strontium / Q000737:chemistry; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry; D014961:X-Ray Diffraction
D017610:Calcium Compounds; D005290:Ferric Compounds; D010087:Oxides; C059910:perovskite; D007811:Lanthanum; D014025:Titanium; D008697:Methane; D013324:Strontium