Diazenide and hydrazide(2-) derivatives of the [Re(CO)3]+ core.
Reaction of [ReBr3(CO)3]2- with aryldiazonium salts gives the Re(iii) diazenide complexes [ReBr2(NNC6H4R-4)(CO)2]-. The attachment of a PhNHCS tethering group to pyridyl hydrazine generates a HYNIC related proligand which gives a stable chelated pyridyliumthiocarbazide(2-) derivative of the [Re(I)(CO)3]+ core.
Alberto
Roger
R
Institute of Inorganic Chemistry, University of Zürich, Winterhurerstrasse 190, Switzerland.
Cowley
Andrew R
AR
Dilworth
Jonathan R
JR
Donnelly
Paul S
PS
Pratt
Jennifer
J
D002248:Carbon Monoxide / Q000737:chemistry; D018360:Crystallography, X-Ray; D006834:Hydrazines / Q000737:chemistry*; D015394:Molecular Structure; D009941:Organomercury Compounds / Q000737:chemistry; D011868:Radioisotopes / Q000737:chemistry; D019275:Radiopharmaceuticals / Q000737:chemistry; D012211:Rhenium / Q000737:chemistry*
D006834:Hydrazines; D009941:Organomercury Compounds; D011868:Radioisotopes; D019275:Radiopharmaceuticals; D012211:Rhenium; D002248:Carbon Monoxide