Observation of hysteretic bistability in [Co(III)Cp(2)](+)[Fe(III)I(4)](-).
[Co(III)Cp(2)](+)[Fe(III)I(4)](-) (Cp = cyclopentadienyl) prepared by the double oxidation of FeI(2) and CoCp(2) with iodine exhibits a 30 degrees C thermal hysteresis in magnetic susceptibility between 134 and 164 K that is attributed to a phase transition to a disordered triclinic unit cell from an ordered monoclinic unit cell upon cooling.
Migliori
Jesse M
JM
Department of Chemistry, University of Utah, 315 S. 1400 E. Street, Room 2124, Salt Lake City, Utah 84112-0850, USA.
Reiff
William M
WM
Arif
Atta M
AM
Miller
Joel S
JS