Self-organisation in P-substituted guanidines leading to solution-state isomerisation.
Different isomeric forms of the amidine unit have been identified in Ph2P(E)C[NR'][NHR'] (E = S, Se; R' = iPr, Cy), using both solid- and solution-state techniques.
Grundy
Joanna
J
Department of Chemistry, School of Life Sciences, University of Sussex, Falmer, Brighton, UK BN1 9QJ.
Coles
Martyn P
MP
Avent
Anthony G
AG
Hitchcock
Peter B
PB
D006146:Guanidines / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry; D010758:Phosphorus / Q000737:chemistry*; D012643:Selenium / Q000737:chemistry; D013237:Stereoisomerism
D006146:Guanidines; D009942:Organometallic Compounds; D010758:Phosphorus; D012643:Selenium