title: Synchronous, time resolved, diffuse reflectance FT-IR, energy dispersive EXAFS (EDE) and mass spectrometric investigation of the behaviour of Rh catalysts during NO reduction by CO.
abstract: Synchronous, time resolved, infra-red, XAFS, and mass spectroscopies are simultaneously applied in situ to the investigation of the dynamic behaviour of Rh/Al2O3 catalysts during NO reduction by CO; NO conversion, and its kinetic character are closely correlated to the conversion of Rh(I)(predominantly RhI(CO)2) to Rh(0).
authors.affiliation: School of Chemistry, University of Southampton, Highfield, Southampton, UK SO17 1BJ. m.a.newton@soton.ac.uk
authors.forename: Mark A
authors.initials: MA
authors.lastname: Newton
authors.forename: Bhrat
authors.initials: B
authors.lastname: Jyoti
authors.forename: Andrew J
authors.initials: AJ
authors.lastname: Dent
authors.forename: Steven G
authors.initials: SG
authors.lastname: Fiddy
authors.forename: John
authors.initials: J
authors.lastname: Evans
mesh_terms: D002248:Carbon Monoxide / Q000737:chemistry*; D002384:Catalysis; D013058:Mass Spectrometry / Q000379:methods; D009569:Nitric Oxide / Q000737:chemistry*; D010084:Oxidation-Reduction; D012238:Rhodium / Q000737:chemistry*; D013052:Spectrometry, X-Ray Emission / Q000379:methods; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods; D013696:Temperature; D013997:Time Factors
chemical_list: D009569:Nitric Oxide; D002248:Carbon Monoxide; D012238:Rhodium