[PtMe(iPr3P)2]+: a Pt(II) complex with an agostic interaction that undergoes C-H activation.
The T-shaped Pt(II) complex [PtMe(iPr3P)2][1-H-closo-CB11Me11], which is stabilised by an agostic interaction, undergoes acid-catalysed intramolecular C-H activation in the presence of THF to afford cyclometallated [Pt(THF)(iPr3P)(iPr2PCHMeCH2)][1-H-closo-CB11Me11].
Ingleson
Michael J
MJ
Department of Chemistry, University of Bath, Bath, UK BA2 7AY.
Mahon
Mary F
MF
Weller
Andrew S
AS
D000143:Acids / Q000737:chemistry; D002384:Catalysis; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*
D000143:Acids; D009942:Organometallic Compounds; D010984:Platinum