Development of highly active and selective novel Pd based acetoxylation catalysts and prevention of catalyst deactivation by Bi modification.
A first approach to successful prevention of catalyst deactivation while simultaneously achieving extremely high selectivity of benzyl acetate (> or = 95%) at significantly high toluene conversion (> 70%) by gas phase acetoxylation over novel Pd-Sb-Bi/TiO2 catalysts.
Benhmid
A
A
Institut für Angewandte Chemie Berlin-Adlershof e.V., Berlin, Germany.
Narayana
K V
KV
Martin
A
A
Lucke
B
B
Pohl
M-M
MM
D000965:Antimony / Q000737:chemistry; D001593:Benzyl Compounds / Q000138:chemical synthesis*; D001729:Bismuth / Q000737:chemistry*; D002384:Catalysis; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*; D010316:Particle Size; D013997:Time Factors; D014025:Titanium / Q000737:chemistry; D014050:Toluene / Q000737:chemistry*
D001593:Benzyl Compounds; C046412:benzyl acetate; C009495:titanium dioxide; D014050:Toluene; D010165:Palladium; D000965:Antimony; D014025:Titanium; D001729:Bismuth