Structural analysis of sonochemically prepared Au/Pd nanoparticles dispersed in porous silica matrix.
Bimetallic Au/Pd nanoparticles supported on a silica matrix were prepared by an ultrasonic technique. The samples heat-treated at 100, 200, 300 and 400 degrees C were examined with techniques of XRD (X-ray diffraction), TEM and XAS (X-ray absorption spectrometry) for studying correlation between their structure and the catalytic activity of hydrogenation of cyclohexene. Even after the heat treatment at 400 degrees C, the particles were smaller than 20 nm and well dispersed in the matrix without agglomeration nor sintering. Results of the XRD, TEM and XAS indicated that the as-prepared particles have a core/shell structure of Au/Pd and transform into a random alloy at 300 degrees C. The catalysis seemed to be deactivated by alloying.
Nakagawa
Takashi
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Department of Nuclear Engineering, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871, Japan. nakagawa@nucl.eng.osaka-u.ac.jp
Nitani
Hiroaki
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Tanabe
Shuji
S
Okitsu
Kenji
K
Seino
Satoshi
S
Mizukoshi
Yoshiteru
Y
Yamamoto
Takao A
TA