[2,6-Bis[(dimethylamino)methyl]pyridine-kappa3N](2,2-methylenediphenolato-kappa2O,O')dioxouranium(VI) acetone solvate.
In the title compound, [UO(2)(C(13)H(10)O(2))(C(11)H(19)N(3))].C(3)H(6)O, the U atom is in a pentagonal-bipyramidal environment, with the three N atoms of the 2,6-bis[(dimethylamino)methyl]pyridine ligand and the two O atoms of the dianionic 2,2'-methylenediphenolate ligand in the equatorial plane. The geometry is compared with that of previously reported 1:2 uranyl-diphenoxide complexes.
Masci
Bernardo
B
Dipartimento di Chimica and IMC-CNR Sezione Meccanismi di Reazione, Università La Sapienza, Box 34, Roma 62, P.le Aldo Moro 5, 00185 Roma, Italy. bernardo.masci@uniroma1.it
Thuéry
Pierre
P