title: Stereochemical control of the Passerini reaction.
abstract: A catalytic asymmetric Passerini reaction using tridentate indan (pybox) Cu(II) Lewis acid complex 4 with substrates capable of bidentate coordination has been achieved. The reaction occurs via ligand-accelerated catalysis.
authors.affiliation: Howard Hughes Medical Institute, Center for Chemical Methodology and Library Development (CMLD-HU) & Broad Institute of Harvard and MIT, Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, USA.
authors.forename: Peter R
authors.initials: PR
authors.lastname: Andreana
authors.forename: Chang C
authors.initials: CC
authors.lastname: Liu
authors.forename: Stuart L
authors.initials: SL
authors.lastname: Schreiber
mesh_terms: D002384:Catalysis; D007189:Indans / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D007189:Indans; C093582:indan