Formation of a supramolecular hyperbranched polymer from self-organization of an AB2 monomer containing a crown ether and two paraquat moieties.
An AB2 monomer containing a bis(m-phenylene)-32-crown-10 and two paraquat moieties was designed and prepared. It self-organized to form a supramolecular hyperbranched polymer in solution.
Huang
Feihe
F
Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061-0212, USA.
Gibson
Harry W
HW
D043844:Crown Ethers / Q000737:chemistry*; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy; D010269:Paraquat / Q000031:analogs & derivatives* / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
D043844:Crown Ethers; D011108:Polymers; D010269:Paraquat