Modular synthesis of fluorous trialkylphosphines.
A modular synthetic protocol was developed for the preparation of fluorous trialkylphosphines with a different number of methylene spacers and various lengths of the fluorous ponytails P[(CH(2))(A)R(FX)][(CH(2))(B)R(FY)][(CH(2))(C)R(FZ)] (A, B, C = 3 and 4; X, Y, Z = 4, 6, and 8). [reaction: see text]
Vlád
Gábor
G
Department of Chemical Technology and Environmental Chemistry, Eötvös University, Pázmány Péter sétány 1/A, H-1117 Budapest, Hungary.
Richter
Frank
F
Horváth
István T
IT