First detection of a selenenyl fluoride ArSe-F by NMR spectroscopy: the nature of Ar2Se2/XeF2 and ArSe-SiMe3/XeF2 reagents.
Arylselenenyl fluorides ArSeF are obtained from diselenides Ar2Se2 or arylselenotrimethylsilanes ArSe-SiMe3, and XeF2. They are detected by low-temperature 19F and 77Se NMR spectroscopy. Substitution in the ortho position of the aromatic ring to provide electronic or steric protection is a requirement for their formation. ArSe--F compounds decompose according to 3 ArSe-F-->[ArSe-SeF2Ar]+ArSe-F-->ArSeF3+Ar2Se2. Reaction energies for this disproportionation as well as that of the sulfur and tellurium homologues have been calculated with MP2, CCSD(T,) and B3 LYP methods. They were found to be increasingly exothermic in the sequence S<Se<Te. For selected Se-C and Se-F compounds the 77Se and 19F chemical shifts have been calculated by GIAO-MP2 and GIAO-B3 LYP methods and are in good agreement with experimental values.
Poleschner
Helmut
H
Freie Universität Berlin, Institut für Chemie, Anorganische und Analytische Chemie, Fabeckstrasse 34-36, 14195 Berlin, Germany. hpol@chemie.fu-berlin.de
Seppelt
Konrad
K