Synthesis of primary amines by the electrophilic amination of Grignard reagents with 1,3-dioxolan-2-one O-sulfonyloxime.
Primary amines are prepared by the electrophilic amination of Grignard reagents with 4,4,5,5-tetramethyl-1,3-dioxolan-2-one O-phenylsulfonyloxime and the acidic hydrolysis of the resulting imines. [reaction: see text]
Kitamura
Mitsuru
M
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Suga
Takahiro
T
Chiba
Shunsuke
S
Narasaka
Koichi
K