title: Palladium-catalyzed N-vinylation of sulfoximines.
abstract: New previously unavailable N-vinyl sulfoximines have been synthesized by intermolecular palladium-catalyzed coupling between sulfoximines and vinyl bromides in excellent yield. Hydrogenation of the vinyl moiety opens a novel way to alpha-branched N-alkyl sulfoximines.
authors.affiliation: Institut für Organische Chemie der RWTH Aachen, Professor-Pirlet-Str. 1, D-52056 Aachen, Germany.
authors.forename: Juan R
authors.initials: JR
authors.lastname: Dehli
authors.forename: Carsten
authors.initials: C
authors.lastname: Bolm
mesh_terms: D001965:Bromides / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D013449:Sulfonamides / Q000138:chemical synthesis* / Q000737:chemistry; D014753:Vinyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D001965:Bromides; D013449:Sulfonamides; D014753:Vinyl Compounds; D010165:Palladium