Ca[Ag2(SCN)4].2H2O.
Calcium tetrathiocyanatodiargentate(I) dihydrate, Ca[Ag(2)(SCN)(4)].2H(2)O, contains eight-membered Ag(4)S(4) rings bonded together through shared atoms to form layers parallel to (100). The thiocyanate groups link the layers to Ca-O chains running parallel to the c axis. The Ca atom is located on a twofold rotation axis parallel to b and is surrounded by four water molecules of crystallization and four thiocyanate N atoms in a distorted square antiprism.
Günes
Minna
M
Department of Chemistry, University of Jyväskylä, PO Box 35, FIN-40014 University of Jyväskylä, Finland. minna.gunes@lut.fi
Valkonen
Jussi
J