A samarium cyclooctatetraene complex as catalyst for hydroamination/cyclisation catalysis.
The cyclooctatetraene-bis(phosphinimino)methanide complex [[CH(PPh2NSiMe3)2]Sm(eta8-C8H8)] has been prepared; although this compound has no alkyl or amide ligand it shows moderate activity as a catalyst for the hydroamination/cyclisation reaction.
Zulys
Agustino
A
Institut für Chemie, Freie Universität Berlin, Germany.
Panda
Tarun K
TK
Gamer
Michael T
MT
Roesky
Peter W
PW