title: Mizoroki-Heck arylation of alpha,beta-unsaturated acids with a hybrid fluorous ether, F-626: facile filtrative separation of products and efficient recycling of a reaction medium containing a catalyst.
abstract: The Mizoroki-Heck reaction was carried out using a fluorous ether F-626 as the solvent and a fluorous Pd carbene complex as the catalyst. When carboxylic acids are the products, separation of both the F-626 and the Pd catalyst from the products can be conveniently carried out by simple filtration. The F-626 filtrates containing the Pd catalyst can be recycled.
authors.affiliation: Department of Chemistry, Faculty of Arts and Sciences, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan.
authors.forename: Takahide
authors.initials: T
authors.lastname: Fukuyama
authors.forename: Masashi
authors.initials: M
authors.lastname: Arai
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Matsubara
authors.forename: Ilhyong
authors.initials: I
authors.lastname: Ryu