Hierarchical self-assembly of supramolecular spintronic modules into 1D- and 2D-architectures with emergence of magnetic properties.
Hierarchical self-assembly of complex supramolecular architectures allows for the emergence of novel properties at each level of complexity. The reaction of the ligand components A and B with Fe(II) cations generates the [2x2] grid-type functional building modules 1 and 2, presenting spin-transition properties and preorganizing an array of coordination sites that sets the stage for a second assembly step. Indeed, binding of La(III) ions to 1 and of Ag(I) ions to 2 leads to a 1D columnar superstructure 3 and to a wall-like 2D layer 4, respectively, with concomitant modulation of the magnetic properties of 1 and 2. Thus, to each of the two levels of structural complexity generated by the two sequential self-assembly steps corresponds the emergence of novel functional features.
Ruben
Mario
M
ISIS, 8 Allée Gaspard Monge, 67000 Strasbourg, France.
Ziener
Ulrich
U
Lehn
Jean-Marie
JM
Ksenofontov
Vadim
V
Gütlich
Philipp
P
Vaughan
Gavin B M
GB