Site-specific ligation of anthracene-1,8-dicarboxylates to an Mn12 core: a route to the controlled functionalisation of single-molecule magnets.
A novel single-molecule magnet of the Mn12 family, [Mn12O12(O2CC6H5)8(L)4(H2O)4].8CH2Cl2, has been synthesised by site-specific ligand exchange using a tailor-made dicarboxylate (L2-), which leads to selective occupation of axial binding sites.
Pacchioni
Mirko
M
Dipartimento di Chimica, INSTM and Università di Modena e Reggio Emilia, Italy.
Cornia
Andrea
A
Fabretti
Antonio C
AC
Zobbi
Laura
L
Bonacchi
Daniele
D
Caneschi
Andrea
A
Chastanet
Guillaume
G
Gatteschi
Dante
D
Sessoli
Roberta
R