Solvent-equilibrated homoadamantyl chloride ion pairs from chloroformate or oxachlorocarbene fragmentations.
Fragmentations of 3-homoadamantyl chloroformate and 3-homoadamantyloxychlorocarbene produce identical ion pairs as product-determining intermediates.
Moss
Robert A
RA
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903, USA. moss@rutchem.rutgers.edu
Tian
Jingzhi
J
Sauers
Ronald R
RR