catena-Poly[[heptakis(dimethylformamide-kappaO)di-mu4-oxo-tetra-mu3-oxo-hexadeca-mu2-oxo-tetraoxolanthanum(III)octamolybdenum(IV)]-mu-sodium(I)].
The title compound, [NaLaMo(8)O(26)(C(3)H(7)NO)(7)](n), contains infinite chains of [Mo(8)O(26)](4-) units supporting dimethylformamide-coordinated La(III) cations and linked by Na(+) cations. The lanthanum center adopts a nine-coordinate geometry and the Na atom is sandwiched between two beta-[Mo(8)O(26)](4-) units.
Chen
Shu-Mei
SM
The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, National Center for Nanoscience and Nanotechnology, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China.
Lu
Can-Zhong
CZ
Yu
Ya-Qin
YQ
Zhang
Quan-Zheng
QZ
He
Xiang
X