title: First transition-metal complexes of S=P(NHBu t)3.
abstract: The first transition-metal (Rh(I), Mo(VI), Ni(II)) complexes of S[double bond, length as m-dash]P(NHBu(t))(3) have been synthesized via metathetical reactions of mono-lithiated and [Rh(CO)(2)Cl](2), (Bu(t)N)(2)MoCl(2)(dme) and NiBr(2)(dme). Surprisingly in the molecular structure of the Ni(II)-complex both hard-soft (N,S) and hard-hard (N,N[prime or minute]) chelation modes of are realized.
authors.affiliation: Institut fur Chemie, Humboldt Universitat zu Berlin, Brook-Taylor-Strasse 2, D-12489 Berlin, Germany. k_rufanov@gmx.net
authors.forename: Konstantin A
authors.initials: KA
authors.lastname: Rufanov
authors.forename: Burkhard
authors.initials: B
authors.lastname: Ziemer
authors.forename: Manfred
authors.initials: M
authors.lastname: Meisel