The substituent-dependent base-treatment chemistry of (eta5-C5H5)Fe(CO)2SiR2SiR2Cl: formation of 1,2-disila-3-metallacyclobutanes, their ring-opened polymers, migrations and substitutions.
We report the formation of disilametallacycles, high molecular weight polymers or simple substitution products from the reactions of 1-(cyclopentadienyliron dicarbonyl)-2-chlorodisilanes with bases, LDA or n-BuLi.
Sharma
Hemant K
HK
Department of Chemistry, University of Texas at El Paso, 79968-0513, USA.
Pannell
Keith H
KH
D003503:Cyclobutanes / Q000138:chemical synthesis*; D008956:Models, Chemical; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D011108:Polymers / Q000138:chemical synthesis*; D012821:Silanes / Q000737:chemistry*
D003503:Cyclobutanes; D009942:Organometallic Compounds; D011108:Polymers; D012821:Silanes