title: An evaluation of arsenic release from monolithic solids using a modified semi-dynamic leaching test.
abstract: Quicklime and quicklime-fly ash-based stabilization/solidification (S/S) effectiveness was evaluated by performing semi-dynamic leaching tests (American Nuclear Society 16.1). Artificial soil samples, contaminated with arsenic trioxide (As2O3) as well as field soil samples contaminated with arsenic (As) were tested. The artificial soils were prepared by mixing amounts of kaolinite or montmorillonite with fine quartz sand. The S/S effectiveness was evaluated by measuring effective diffusion coefficients (De) and leachability indices (LX). Treatment was most effective in kaolinite-based artificial soils treated with quicklime and in quicklime-fly ash treated field soils. The experimental results indicate that De values were lowered as a result of S/S treatment. Upon treatment LX values were higher than 9, suggesting that S/S treated soils are acceptable for "controlled utilization". Based on a model developed by de Groot and van der Sloot [G.J. de Groot, H.A. van der Sloot, in: T.M. Gilliam, C.C. Wiles (Eds.), Stabilization and Solidification of Hazardous, Radioactive, and Mixed Wastes, vol. 2, ASTM STP 1123, ASTM, PA, 1992, p. 149], the leaching mechanism for all of the treated soils was found to be controlled by diffusion. The effect of soluble silica (Si) on As leachability was also evaluated. When soluble Si concentration was less than 1 ppm, As leachability was the lowest. The controlling mechanism of As immobilization whether sorption, precipitation, or inclusion was also evaluated. It was determined that precipitation was the dominant mechanism.
authors.affiliation: WM Keck Geoenvironmental Laboratory, Center for Environmental Systems, Department of Civil, Environmental and Ocean Engineering, Stevens Institute of Technology, Hoboken, NJ 07030, USA.
authors.forename: Dimitris
authors.initials: D
authors.lastname: Dermatas
authors.forename: Deok Hyun
authors.initials: DH
authors.lastname: Moon
authors.forename: Nektaria
authors.initials: N
authors.lastname: Menounou
authors.forename: Xiaoguang
authors.initials: X
authors.lastname: Meng
authors.forename: Richard
authors.initials: R
authors.lastname: Hires
mesh_terms: D001151:Arsenic / Q000032:analysis* / Q000737:chemistry; D017610:Calcium Compounds / Q000737:chemistry; D002244:Carbon / Q000737:chemistry; D011232:Chemical Precipitation; D060729:Coal Ash; D004058:Diffusion; D004784:Environmental Monitoring / Q000379:methods; D010087:Oxides / Q000737:chemistry; D052638:Particulate Matter; D012989:Soil Pollutants / Q000032:analysis*; D012995:Solubility
chemical_list: D017610:Calcium Compounds; D060729:Coal Ash; D010087:Oxides; D052638:Particulate Matter; D012989:Soil Pollutants; D002244:Carbon; C016538:lime; D001151:Arsenic