Use of a chiral praseodymium shift reagent in predicting the complete stereostructure of glisoprenin A.
[structure: see text] The complete stereostructure of glisoprenin A has been predicted via analysis of the 13C NMR behaviors in the presence of (R)- and (S)-Pr(tfc)3.
Ghosh
Indranath
I
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.
Kishi
Yoshito
Y
Tomoda
Hiroshi
H
Omura
Satoshi
S
D005233:Fatty Alcohols / Q000737:chemistry*; D007202:Indicators and Reagents / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D011221:Praseodymium / Q000737:chemistry*; D013237:Stereoisomerism
D005233:Fatty Alcohols; D007202:Indicators and Reagents; C077321:glisoprenin A; D011221:Praseodymium