Selective synthesis of isomeric heterodinuclear complexes with switched metal arrangements via proton-induced reversible metal migration.
Pairs of isomeric heterodinuclear complexes, [(cod)Ir(mu-PNNN)M(L)]BF4 and [(L)M(mu-PNNN)Ir(cod)]BF4, with switched metal arrangements are prepared in a specific manner by simply changing the addition order of the reagents.
Dubs
Christian
C
Chemical Resources Laboratory, Tokyo Institute of Technology, R1-27, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan.
Inagaki
Akiko
A
Akita
Munetaka
M