Bis(ethylenediammonium) decaaquadisodium decavanadate, (C2H10N2)2[Na2(H2O)10][V10O28].
In the title compound, the decavanadate anion, [V(10)O(28)](6-), and the bridged [Na(2)(H(2)O)(10)](2+) dication lie across inversion centers. The charge balance is achieved by ethylenediammonium cations, H(3)NCH(2)CH(2)NH(3)(2+), which are disordered. The decavanadate anions are surrounded by the [Na(2)(H(2)O)(10)](2+) dications, thus forming layers, and the ethylenediammonium cations are located between these layers.
Li
Guo Bao
GB
State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, People's Republic of China. liguobao@pku.edu.cn
Yang
Si Hai
SH
Xiong
Ming
M
Lin
Jian Hua
JH