An effective fluorescent chemosensor for the detection of copper(II).
The fluorescent compound N-substituted 2,6-bis(benzimidazol-2-yl)pyidine (1) has been synthesized. The fluorescent characteristics of the compound 1 and 2,6-bis(benzimidazol-2-yl)pyidine (2) and the complexes formed between the two compounds and different metal ions have also been investigated. The results show that the compound 1 possesses a specific ability to form complex with Cu(2+) ion, but the compound 2 have not such a property. It is proposed that the specific recognition ability of compound 1 to Cu(2+) may be attributed to the cyclic configuration of this compound in polar solvent.
Zhou
Li-Li
LL
Nano-organic Photoelectronic Laboratory, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, China.
Sun
Hao
H
Zhang
Xiao-Hong
XH
Wu
Shi-Kang
SK
D002413:Cations, Divalent / Q000737:chemistry; D003300:Copper / Q000032:analysis* / Q000737:chemistry*; D004126:Dimethylformamide / Q000032:analysis / Q000737:chemistry; D005453:Fluorescence; D005456:Fluorescent Dyes / Q000032:analysis / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D013050:Spectrometry, Fluorescence
D002413:Cations, Divalent; D005456:Fluorescent Dyes; D003300:Copper; D004126:Dimethylformamide