title: A study of ignition of metal impregnated carbons: the influence of oxygen content in the activated carbon matrix.
abstract: A study of the reason for the early ignition of coconut-based impregnated carbon in comparison with the peat-based impregnated carbon was conducted. The surface features of carbons were evaluated using various physicochemical methods. The metal analysis of the initial carbon indicated that the content of potassium was higher in the coconut-based carbon. The surface functional group analysis revealed the presence of similar surface species; however, the peat-based carbon was more acidic in its chemical nature. Since the oxygen content was higher in the peat-based carbon, the early ignition of the coconut-based material was attributed to its higher affinity to chemisorb oxygen, which leads to exothermic effects. This conclusion was confirmed by performing oxidation of coconut-based carbon prior to impregnation. This process increased the ignition temperature for Cu/Cr impregnated coconut-based material from 186 to 289 degrees C and for the Cu/Zn/Mo impregnated carbon from 235 to 324 degrees C.
authors.affiliation: Protechnik Laboratories (Pty) Ltd., PO Box 8854, Pretoria 0001, South Africa. martinm@protechnik.co.za
authors.forename: M M
authors.initials: MM
authors.lastname: van der Merwe
authors.forename: T J
authors.initials: TJ
authors.lastname: Bandosz
mesh_terms: D002244:Carbon / Q000737:chemistry*; D003059:Cocos / Q000737:chemistry; D005390:Fires / Q000517:prevention & control*; D008670:Metals / Q000737:chemistry*; D010100:Oxygen / Q000032:analysis* / Q000737:chemistry; D012987:Soil; D013696:Temperature
chemical_list: D008670:Metals; D012987:Soil; D002244:Carbon; D010100:Oxygen