title: Release behavior of triazine residues in stabilised contaminated soils.
abstract: This paper reports the release behavior of two triazines (atrazine and simazine) in stabilised soils from a pesticide-contaminated site in South Australia. The soils were contaminated with a range of pesticides, especially with triazine herbicides. With multiple extractions of each soil sample with deionised water (eight in total), 15% of atrazine and 4% of simazine residues were recovered, resulting in very high concentrations of the two herbicides in leachate. The presence of small fractions of surfactants was found to further enhance the release of the residues. Methanol content up to 10% did not substantially influence the concentration of simazine and atrazine released. The study demonstrated that while the stabilisation of contaminated soil with particulate activated carbon (5%) and cement mix (15%) was effective in locking the residues of some pesticides, it failed to immobilise triazine herbicides residues completely. Given the higher water solubility of these herbicides than other compounds more effective strategies to immobilise their residues is needed.
authors.affiliation: CSIRO Land and Water, Adelaide Laboratory, PMB No 2, Glen Osmond, SA 5064, Australia. guang.guo.ying@csiro.au
authors.forename: G G
authors.initials: GG
authors.lastname: Ying
authors.forename: R S
authors.initials: RS
authors.lastname: Kookana
authors.forename: M
authors.initials: M
authors.lastname: Mallavarpu
mesh_terms: D004784:Environmental Monitoring / Q000379:methods; D010573:Pesticide Residues / Q000737:chemistry*; D010940:Plant Proteins / Q000737:chemistry*; D011955:Receptors, Drug / Q000737:chemistry*; D012989:Soil Pollutants; D013021:South Australia; D018505:Waste Management
chemical_list: D010573:Pesticide Residues; D010940:Plant Proteins; D011955:Receptors, Drug; D012989:Soil Pollutants; C030708:triazine herbicide receptor