Al(OPr i)3-catalysed halogen exchange processes of relevance to atom transfer radical polymerization: the effect depends on the metal electronic structure.
Whether or not tri(isopropoxo)aluminium catalyses halogen exchange for an ATRP catalyst depends on the number of valence electrons.
Stoffelbach
François
F
Laboratoire de Chimie de Coordination, UPR CNRS 8241, 205 Route de Narbonne, 31077 Toulouse Cedex, France.
Poli
Rinaldo
R