Novel cerium(IV) heteropolyoxotungstate containing two types of lacunary Keggin anions.
A novel V-shaped polyoxotungstate is formed when Ce(IV) metal centres bridge monolacunary [PW(11)O(39)](7-) anions to an unusual 1,4-bilacunary [PW(10)O(38)](11-) anion which appears with an unprecedented bridging structural motif.
Sousa
Filipa L
FL
Department of Chemistry, CICECO, University of Aveiro, 3810-193 Aveiro, Portugal.
Almeida Paz
Filipe A
FA
Cavaleiro
Ana M V
AM
Klinowski
Jacek
J
Nogueira
Helena I S
HI