[Ru(eta3-2-C3H4Me)(CO)(dppf)][SbF6]: a mononuclear 16e - ruthenium(II) catalyst for propargylic substitution and isomerization of HC[triple bond]CCPh2(OH).
The 16e(-) derivative [Ru(eta3-2-C3H4Me)(CO)(dppf)][SbF6] catalyzes: (i) the propargylic substitution reaction of 1,1-diphenyl-2-propyn-1-ol with alcohols to produce propargylic ethers, and (ii) the formal isomerization of 1,1-diphenyl-2-propyn-1-ol into 3,3-diphenyl-2-propenal.
Cadierno
Victorio
V
Departamento de Quimica Organica e Inorganica, I.U.Q.O.E.M. (Unidad Asociada al CSIC), Facultad de Quimica, Universidad de Oviedo, E-33071 Oviedo, Spain. vcm@uniovi.es
Díez
Josefina
J
García-Garrido
Sergio E
SE
Gimeno
José
J