Porphyrin supermolecules: synthesis and self-assembly features of zinc-5-(3'-pyridyl)-10,15,20-tris(4'-hydroxyphenyl)porphyrin.
Targeted synthesis of the title compound, with one converging coordination site and three diverging H-bonding sites, has led to the formation of multiporphyrin oligomers by directed intermolecular coordination, without resorting to external auxiliaries. A uniquely structured cyclic tetraporphyrin supermolecule was detected in solution, isolated in the solid state, and characterized in detail by X-ray diffraction.
Vinodu
Mikki
M
School of Chemistry, Sackler Faculty of Exact Sciences, Tel-Aviv University, 69978 Ramat-Aviv, Tel-Aviv, Israel.
Stein
Zafra
Z
Goldberg
Israel
I
D018360:Crystallography, X-Ray; D008665:Metalloporphyrins / Q000138:chemical synthesis* / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; D015032:Zinc / Q000737:chemistry*
D008665:Metalloporphyrins; C494955:zinc-5-(3'-pyridyl)-10,15,20-tris(4'-hydroxyphenyl)porphyrin; D015032:Zinc