title: Synthesis of C-arylglycosides via Ru(II)-catalyzed [2 + 2 + 2] cycloaddition.
abstract: In the presence of catalytic amounts of Cp*RuCl(cod), the cycloaddition of 1,6-diynes with various C-alkynylglycosides proceeded at ambient temperature to afford C-arylglycosides in 46-93% yields.
authors.affiliation: Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa, Nagoya 464-8603, Japan. yamamoto@apchem.nagoya-u.ac.jp
authors.forename: Yoshihiko
authors.initials: Y
authors.lastname: Yamamoto
authors.forename: Tomoaki
authors.initials: T
authors.lastname: Saigoku
authors.forename: Takashige
authors.initials: T
authors.lastname: Ohgai
authors.forename: Hisao
authors.initials: H
authors.lastname: Nishiyama
authors.forename: Kenji
authors.initials: K
authors.lastname: Itoh
mesh_terms: D002384:Catalysis; D006027:Glycosides / Q000138:chemical synthesis*; D009005:Monosaccharides / Q000138:chemical synthesis*; D012428:Ruthenium / Q000737:chemistry
chemical_list: C438934:C-glycoside; D006027:Glycosides; D009005:Monosaccharides; D012428:Ruthenium