Residue analysis and dissipation of monosulfuron in soil and wheat.
HPL-UV residue analytical method for monosulfuron [N-[(4'-methyl) pyrimidin-2'yl]-2-nitrophenylsulfonyl urea] in soil and wheat was developed. Monosulfuron residues were recovered by solvent extraction, followed by liquid-liquid partition, and C18 cartrige clean-up. Excellent method recoveries ranging from 95%-104% for both fortified soil and wheat grain were obtained with coefficients of variation 1.5%-11.8%. The minimum detectable quantities in soil and wheat were both 4 ng, the limit of detection was 0.02 mg/kg. When monosulfuron was applied according to double dosage of maximum recommended use direction(120 g ai/hm2 of 10% monosulfuron wettable powder sprayed for once during development of wheat) in field studies conducted in Shandong Province and near Beijing, monosulfuron residues was not detected in soil and wheat samples collected 75 d after application. Laboratory soil degradation studies showed that monosulfuron degraded faster in acidic soil and strong alkaline soil than in neutral or weak alkaline soil. Half lives in Jiangxi soil, Shijiazhuang soil, Jiangsu soil and Heilongjiang soil were 41, 48, 87 and 84 d respectively. Monosulfuron residues dissipated rapidly in Shandong and Beijing field test sites with half-lives of less than 14 d.
Fan
Zhi-Jin
ZJ
National Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China. fanzj@nakai.edu.cn
Hu
Ji-Ye
JY
Ai
Ying-Wei
YW
Qian
Chuan-Fan
CF
Yu
Wei-Qiang
WQ
Li
Zheng-Ming
ZM
D000383:Agriculture; D002681:China; D002851:Chromatography, High Pressure Liquid; D006207:Half-Life; D010573:Pesticide Residues / Q000737:chemistry* / Q000302:isolation & purification; D011743:Pyrimidines / Q000737:chemistry* / Q000302:isolation & purification; D012987:Soil / Q000032:analysis*; D013453:Sulfonylurea Compounds / Q000737:chemistry* / Q000302:isolation & purification; D014908:Triticum / Q000378:metabolism*
D010573:Pesticide Residues; D011743:Pyrimidines; D012987:Soil; D013453:Sulfonylurea Compounds; C495688:monosulfuron