Sensitized effect of beta-cyclodextrin on the fluorescence in the determination of carbaryl.
Based on the significant enhancement of fluorescence intensity of carbaryl in inclusion complex, a spetrofluorimetric method with high sensitivity was developed for the determination of carbaryl in aqueous solution. Under the optimum conditions, the complex had excitation and emission maxima at 278 nm and 332 nm, respectively. The linear range of the method was 7.0 ng/ml-1500 ng/ml with a detection limit of 1.2 ng/ml. The proposed method was successfully used to determine quantitatively of carbaryl in cottonseeds.
Liu
Wen-Li
WL
College of Life Sciences and Medicine Chemical Engineering, Taizhou University, Taizhou 317000, China. liuwenlidy@yahoo.com.cn
Tang
Bo
B
D012721:Carbaryl / Q000032:analysis* / Q000737:chemistry / Q000378:metabolism*; D003369:Cottonseed Oil / Q000032:analysis; D005453:Fluorescence; D006863:Hydrogen-Ion Concentration; D013050:Spectrometry, Fluorescence / Q000379:methods*; D047392:beta-Cyclodextrins / Q000378:metabolism*
D003369:Cottonseed Oil; D047392:beta-Cyclodextrins; C031215:betadex; D012721:Carbaryl