Reactivity of phthalimide N-oxyl radical (PINO) toward the phenolic O-H bond. A kinetic study.
The reactivity of the phthalimide N-oxyl radical (PINO) toward the OH bond of a series of substituted phenols was kinetically investigated in CH(3)CN. The reaction selectivity and the deuterium kinetic isotope effect were determined. Information on the kinetic solvent effect was also obtained with phenol as the substrate.
Baciocchi
Enrico
E
Dipartimento di Chimica, Università degli Studi di Roma La Sapienza and Istituto CNR di Metodologie Chimiche (IMC-CNR), Sezione Meccanismi di Reazione, Piazzale A. Moro 5, I-00185 Rome, Italy. enrico.baciocchi@uniroma1.it
Gerini
Maria Francesca
MF
Lanzalunga
Osvaldo
O