The first bipodal thiocarbamic acid ester, O,O'-diethyl N,N'-(p-phenylenedicarbonyl)bis(thiocarbamate).
The title compound, C(14)H(16)N(2)O(4)S(2), is the first reported X-ray crystallographic structure determination of a bipodal O-alkyl N-benzoylthiocarbamate. This compound crystallizes in a cis-S,O orientation (Z,Z' configuration), with the two S/O moieties anti relative to one another, as indicated by the twofold rotation axis located at the center of the benzene ring.
Blewett
Gavin
G
Department of Chemistry, University of Stellenbosch, Private Bag X1, Matieland 7602, South Africa.
Esterhuysen
Catharine
C
Bredenkamp
Martin W
MW
Koch
Klaus R
KR