title: Formation of radical cations of aziridines generated by laser flash photolysis.
abstract: The radical cations of 1-butyl-trans-2,3-diphenyl aziridine (1), 1-butyl-2-phenyl aziridine (2), 1,2-diphenyl aziridine (3) and 1-(p-methoxyphenyl)-2-phenyl aziridine (4) were generated upon laser flash photolysis in aqueous and aqueous acetonitrile solutions by direct photoionisation as indicated by the broad absorption band of the solvated electron above 550 nm as well.
authors.affiliation: Organische Chemie I, Universitat Bielefeld, Universitatsstrasse 25, D-33615, Bielefeld, Germany.
authors.forename: Carsten
authors.initials: C
authors.lastname: Gaebert
authors.forename: Christian
authors.initials: C
authors.lastname: Siegner
authors.forename: Jochen
authors.initials: J
authors.lastname: Mattay
authors.forename: Marion
authors.initials: M
authors.lastname: Toubartz
authors.forename: Steen
authors.initials: S
authors.lastname: Steenken
mesh_terms: D001388:Aziridines / Q000737:chemistry* / Q000528:radiation effects*; D002412:Cations; D005609:Free Radicals; D010782:Photolysis
chemical_list: D001388:Aziridines; D002412:Cations; D005609:Free Radicals