On the mechanism of nanopore filling of SAPO-5 molecular sieve by nitrogen molecules.
SAPO-5 molecular sieve was synthesized according to patent literature and characterized with X-ray diffraction, electron microscopy (SEM, TEM), and solid state magic angle spinning NMR spectroscopy. The material of particles in the micrometer region was found to consist of ca. 20 nm microcrystallites packed in mostly parallel orientation to ca. 200 nm sized agglomerates. The nitrogen adsorption isotherm was measured at 77.6 K over ca. 7 decades of pressure up to pore saturation. The course of the isotherm is interpreted to consist of filling of the nanopores (diameter, 0.73 nm) up to 2N(2)/unit cell, subsequent multilayer adsorption on the outer surface of the agglomerates, and, finally, pore condensation in the interparticle adsorption space. The nanopore adsorption can be quantitatively reproduced with the statistical mechanical model of a quasi one-dimensional lattice gas taking intermolecular interactions into account. The evaluated energy parameters are of physically reasonable magnitude and agree with literature data. The multilayer part of the adsorption isotherm can be well represented by the Brunauer-Emmett-Teller model yielding a specific outer space area (63 m(2) g(-)(1)) which is consistent with estimated geometrical and pore size analysis data.
Boddenberg
Bruno
B
University of Dortmund, Department of Chemistry, Physical Chemistry II, Otto-Hahn Strasse 6, D-44227 Dortmund, Germany. bruno.boddenberg@physicalchemistry.net
Radha Rani
V
V
Grosse
Reiner
R
D000327:Adsorption; D049329:Nanostructures / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010316:Particle Size; D016062:Porosity; D033362:Powder Diffraction; D017655:Silicon Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013499:Surface Properties
D009943:Organophosphorus Compounds; D017655:Silicon Compounds; D009584:Nitrogen