title: [Ru(eta3-2-C3H4Me)(CO)(dppf)][SbF6]: a mononuclear 16e - ruthenium(II) catalyst for propargylic substitution and isomerization of HC[triple bond]CCPh2(OH).
abstract: The 16e(-) derivative [Ru(eta3-2-C3H4Me)(CO)(dppf)][SbF6] catalyzes: (i) the propargylic substitution reaction of 1,1-diphenyl-2-propyn-1-ol with alcohols to produce propargylic ethers, and (ii) the formal isomerization of 1,1-diphenyl-2-propyn-1-ol into 3,3-diphenyl-2-propenal.
authors.affiliation: Departamento de Quimica Organica e Inorganica, I.U.Q.O.E.M. (Unidad Asociada al CSIC), Facultad de Quimica, Universidad de Oviedo, E-33071 Oviedo, Spain. vcm@uniovi.es
authors.forename: Victorio
authors.initials: V
authors.lastname: Cadierno
authors.forename: Josefina
authors.initials: J
authors.lastname: Díez
authors.forename: Sergio E
authors.initials: SE
authors.lastname: García-Garrido
authors.forename: José
authors.initials: J
authors.lastname: Gimeno