Photodecarbonylation of ruthenium carbonyl octaethylporphyrin via stepwise two-photon absorption of visible light.
The photoinduced decarbonylation of a ruthenium(II) carbonyl octaethylporphyrin (RuOEP(CO)(Py)) complex has been shown to occur upon nanosecond pulse laser irradiation as a visible light excitation source, which is reasonably interpreted by a stepwise two-photon absorption process.
Ishii
Kazuyuki
K
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
Hoshino
Shun-ichi
S
Kobayashi
Nagao
N
D008665:Metalloporphyrins / Q000138:chemical synthesis / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010777:Photochemistry; D017319:Photosensitizing Agents / Q000138:chemical synthesis / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*
D008665:Metalloporphyrins; D009942:Organometallic Compounds; D017319:Photosensitizing Agents; D012428:Ruthenium