title: Validated sampling strategy for assessing contaminants in soil stockpiles.
abstract: Dutch legislation on the reuse of soil requires a sampling strategy to determine the degree of contamination. This sampling strategy was developed in three stages. Its main aim is to obtain a single analytical result, representative of the true mean concentration of the soil stockpile. The development process started with an investigation into how sample pre-treatment could be used to obtain representative results from composite samples of heterogeneous soil stockpiles. Combining a large number of random increments allows stockpile heterogeneity to be fully represented in the sample. The resulting pre-treatment method was then combined with a theoretical approach to determine the necessary number of increments per composite sample. At the second stage, the sampling strategy was evaluated using computerised models of contaminant heterogeneity in soil stockpiles. The now theoretically based sampling strategy was implemented by the Netherlands Centre for Soil Treatment in 1995. It was applied to all types of soil stockpiles, ranging from clean to heavily contaminated, over a period of four years. This resulted in a database containing the analytical results of 2570 soil stockpiles. At the final stage these results were used for a thorough validation of the sampling strategy. It was concluded that the model approach has indeed resulted in a sampling strategy that achieves analytical results representative of the mean concentration of soil stockpiles.
authors.affiliation: Netherlands Institute of Applied Geoscience TNO, P.O. Box 80015, 3500 TA Utrecht, The Netherlands. f.lame@nitg.tno.nl
authors.forename: Frank
authors.initials: F
authors.lastname: Lamé
authors.forename: Ton
authors.initials: T
authors.lastname: Honders
authors.forename: Giljam
authors.initials: G
authors.lastname: Derksen
authors.forename: Michiel
authors.initials: M
authors.lastname: Gadella
mesh_terms: D004784:Environmental Monitoring / Q000379:methods* / Q000706:statistics & numerical data*; D006256:Hazardous Waste; D006801:Humans; D007854:Lead / Q000032:analysis; D012989:Soil Pollutants / Q000032:analysis*
chemical_list: D006256:Hazardous Waste; D012989:Soil Pollutants; D007854:Lead