Formation of radical cations of aziridines generated by laser flash photolysis.
The radical cations of 1-butyl-trans-2,3-diphenyl aziridine (1), 1-butyl-2-phenyl aziridine (2), 1,2-diphenyl aziridine (3) and 1-(p-methoxyphenyl)-2-phenyl aziridine (4) were generated upon laser flash photolysis in aqueous and aqueous acetonitrile solutions by direct photoionisation as indicated by the broad absorption band of the solvated electron above 550 nm as well.
Gaebert
Carsten
C
Organische Chemie I, Universitat Bielefeld, Universitatsstrasse 25, D-33615, Bielefeld, Germany.
Siegner
Christian
C
Mattay
Jochen
J
Toubartz
Marion
M
Steenken
Steen
S
D001388:Aziridines / Q000737:chemistry* / Q000528:radiation effects*; D002412:Cations; D005609:Free Radicals; D010782:Photolysis
D001388:Aziridines; D002412:Cations; D005609:Free Radicals