title: Arrested chloride abstraction from trans-RuCl2(DMeOPrPE)2 with TlPF6; formation of a 1-D coordination polymer having unusual octahedral coordination around thallium(I).
abstract: An "arrested" chloride abstraction occurs in the reaction of trans-RuCl(2)(DMeOPrPE)(2) with TlPF(6); the product is a 1-D coordination polymer in which the Tl(I) centers have an unusual octahedral coordination geometry with a stereochemically active 6s(2) lone pair.
authors.affiliation: Department of Chemistry, University of Oregon, Eugene, USA.
authors.forename: Nathaniel K
authors.initials: NK
authors.lastname: Szymczak
authors.forename: Fusen
authors.initials: F
authors.lastname: Han
authors.forename: David R
authors.initials: DR
authors.lastname: Tyler