title: Phaeoside, a novel galactoside of hydroxymanoyl oxide from the gibberellin A1-producing Phaeosphaeria sp. L487.
abstract: Isolation and examination of a diterpene glycoside from the culture filtrate of the gibberellin A(1)-producing Phaeosphaeria sp. L487 allowed us to identify a novel fungal galactoside of hydroxymanoyl oxide together with (-)-ent-13-epi-manoyl oxide. It was designated phaeoside and determined to be 1alpha-hydroxy-ent-13-epi-manoyl oxide 1-O-beta-D-galactopyranoside based on its chemical degradation and spectroscopic methods. This is the first report of the isolation of a diterpene galactoside from fungi.
authors.affiliation: Department of Bioresource Engineering, Faculty of Agriculture, Yamagata University, Tsuruoka, Japan.
authors.forename: Hiromichi
authors.initials: H
authors.lastname: Kenmoku
authors.forename: Tomoharu
authors.initials: T
authors.lastname: Sugai
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Yajima
authors.forename: Takeshi
authors.initials: T
authors.lastname: Sassa
mesh_terms: D001203:Ascomycota / Q000737:chemistry* / Q000378:metabolism; D003470:Culture Media / Q000737:chemistry; D005697:Galactosides / Q000737:chemistry*; D005875:Gibberellins / Q000096:biosynthesis*; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D016339:Spectrometry, Mass, Fast Atom Bombardment; D013729:Terpenes / Q000737:chemistry*
chemical_list: C500715:1-hydroxy-13-manoyl oxide 1-O-galactopyranoside; D003470:Culture Media; D005697:Galactosides; D005875:Gibberellins; D013729:Terpenes; C422660:gibberellin A1