A p-phosphinophenolate ligand for the palladium-catalysed arylation of alkenes.
A triphenylphosphine having a strong electron-donating group, an oxyanion, at the para position of one of the benzene rings was found to show much higher efficiency compared with other structurally related triarylphosphines in the palladium-catalysed arylation of alkenes.
Shirakawa
Eiji
E
Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan. shirakawa@kuchem.kyoto-u.ac.jp
Ishii
Keijiro
K
Tsuchimoto
Teruhisa
T