Application of chiral lanthanide shift reagents for assignment of absolute configuration of alcohols.
[structure: see text] The absolute configuration of secondary and tertiary alcohols can be predicted from analysis of the chemical shift behaviors of the CX- and CY-carbons in the presence of (R)- and (S)-Pr(tfc)3 as formulated in the boxes.
Ghosh
Indranath
I
Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.
Zeng
Hongbo
H
Kishi
Yoshito
Y
D000438:Alcohols / Q000737:chemistry*; D007202:Indicators and Reagents / Q000737:chemistry; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D013237:Stereoisomerism
D000438:Alcohols; D007202:Indicators and Reagents; D028581:Lanthanoid Series Elements