Novel polyaniline-supported molybdenum-catalyzed aerobic oxidation of alcohols to aldehydes and ketones.
[reaction: see text] Oxidation of alcohols to aldehydes and ketones has been studied in high yields using molecular oxygen and a catalytic amount of 1 in toluene under stirring (ca. 100 degrees C). The reactions of primary alcohols are faster compared to secondary alcohols and the catalyst 1 can be recycled without loss of activity.
Velusamy
Subbarayan
S
Department of Chemistry, Indian Institute of Technology Guwahati, Guwahati 781039, India.
Ahamed
Muneer
M
Punniyamurthy
T
T
D000438:Alcohols / Q000737:chemistry*; D000447:Aldehydes / Q000138:chemical synthesis* / Q000737:chemistry; D000814:Aniline Compounds / Q000737:chemistry*; D002384:Catalysis; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry; D013237:Stereoisomerism; D013997:Time Factors
D000438:Alcohols; D000447:Aldehydes; D000814:Aniline Compounds; D007659:Ketones; D009942:Organometallic Compounds; C416807:polyaniline; D008982:Molybdenum; D010100:Oxygen