Direct two-step spin-crossover through [HS-HS]...[LS-LS] at the plateau in dinuclear diiron(II) complex [{Fe(NCBH3)(4phpy)}2(mu-bpypz)2].
The variable temperature magnetic susceptibility, X-ray crystallography, and IR and Raman spectra of a new dinuclear complex [{Fe(II)(NCBH(3))(4-phpy)}(2) mu-bpypz)(2)] demonstrated the first two-step spin-crossover associated with a 1 : 1 mixture of high-spin pair [HS-HS] and low-spin pair [LS-LS] at the plateau.
Nakano
Keisaku
K
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka Osaka, 560-0043, Japan.
Kawata
Satoshi
S
Yoneda
Ko
K
Fuyuhiro
Akira
A
Yagi
Takashi
T
Nasu
Saburo
S
Morimoto
Syotaro
S
Kaizaki
Sumio
S