title: A study of 2-azido-3,5-dichlorobiphenyl by nano- and picosecond laser flash photolysis and computational methods.
abstract: The dynamics of singlet 3,5-dichloro-2-biphenylnitrene and the products of its rearrangement were monitored by pico- and nanosecond laser flash photolysis and the results were consistent with the predictions of DFT and ab initio molecular orbital calculations.
authors.affiliation: Department of Chemistry, The Ohio State University, Columbus, Ohio 43210, USA. gritsan@kinetics.nsc.ru
authors.forename: Nina P
authors.initials: NP
authors.lastname: Gritsan
authors.forename: Dmitrii A
authors.initials: DA
authors.lastname: Polshakov
authors.forename: Meng-Lin
authors.initials: ML
authors.lastname: Tsao
authors.forename: Matthew S
authors.initials: MS
authors.lastname: Platz
mesh_terms: D001386:Azides / Q000032:analysis* / Q000737:chemistry*; D001713:Biphenyl Compounds / Q000737:chemistry*; D003198:Computer Simulation; D007834:Lasers; D015394:Molecular Structure; D010777:Photochemistry; D010782:Photolysis; D011078:Polychlorinated Biphenyls / Q000032:analysis* / Q000737:chemistry; D013696:Temperature; D013997:Time Factors; D014466:Ultraviolet Rays
chemical_list: C499981:2-azido-3,5-dichlorobiphenyl; D001386:Azides; D001713:Biphenyl Compounds; D011078:Polychlorinated Biphenyls; C029904:3,5-dichlorobiphenyl