title: Structure determination of mycolactone C via total synthesis.
abstract: [structure: see text] By total synthesis, mycolactone C has been established as an approximately 1:1 mixture of Z-Delta4'5'- and E-Delta4'5'-geometric isomers of C12'-deoxymycolactones A and B.
authors.affiliation: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.
authors.forename: Ted C
authors.initials: TC
authors.lastname: Judd
authors.forename: Alexander
authors.initials: A
authors.lastname: Bischoff
authors.forename: Yoshito
authors.initials: Y
authors.lastname: Kishi
authors.forename: Sarojini
authors.initials: S
authors.lastname: Adusumilli
authors.forename: Pamela L C
authors.initials: PL
authors.lastname: Small
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry*; D007783:Lactones / Q000138:chemical synthesis* / Q000737:chemistry*; D018942:Macrolides; D008968:Molecular Conformation; D019911:Mycobacterium ulcerans / Q000737:chemistry*
chemical_list: D000475:Alkenes; D007783:Lactones; D018942:Macrolides; C451488:mycolactone A; C451489:mycolactone B; C510305:mycolactone C