Spin-state rationale for the peroxo-stabilizing role of the thiolate ligand in superoxide reductase.
Bukowski
Michael R
MR
Center for Metals in Biocatalysis and Department of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA.
Halfen
Heather L
HL
van den Berg
Tieme A
TA
Halfen
Jason A
JA
Que
Lawrence
L
D008024:Ligands; D008958:Models, Molecular; D010088:Oxidoreductases / Q000737:chemistry*; D010545:Peroxides / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D013059:Spectrum Analysis, Raman; D013438:Sulfhydryl Compounds / Q000737:chemistry*
D008024:Ligands; D010545:Peroxides; D013438:Sulfhydryl Compounds; D010088:Oxidoreductases; C121849:superoxide reductase