Statistical mechanics of a colloidal suspension in contact with a fluctuating membrane.
Surface effects are generally prevailing in confined colloidal systems. Here we report on dispersed nanoparticles close to a fluid membrane. Exact results regarding the static organization are derived for a dilute solution of nonadhesive colloids. It is shown that thermal fluctuations of the membrane broaden the density profile, but on average colloids are neither accumulated nor depleted near the surface. The radial correlation function is also evaluated, from which we obtain the effective pair potential between colloids. This entropically driven interaction shares many similarities with the familiar depletion interaction. It is shown to be always attractive with range controlled by the membrane correlation length. The depth of the potential well is comparable to the thermal energy, but depends only indirectly upon membrane rigidity. Consequences for the stability of the suspension are also discussed.
Bickel
T
T
Centre de Physique Moléculaire Optique et Hertzienne, Université Bordeaux 1, CNRS-UMR 5798, 351 cours de la Libération, 33405 Talence, France. th.bickel@cpmoh.u-bordeaux1.fr
Benhamou
M
M
Kaïdi
H
H
D003102:Colloids / Q000737:chemistry*; D003198:Computer Simulation; D046911:Macromolecular Substances / Q000737:chemistry; D019563:Mechanics; D008563:Membrane Lipids / Q000737:chemistry*; D008567:Membranes, Artificial; D008956:Models, Chemical; D015233:Models, Statistical; D013499:Surface Properties; D013696:Temperature
D003102:Colloids; D046911:Macromolecular Substances; D008563:Membrane Lipids; D008567:Membranes, Artificial