title: Platinum(IV) oxide catalyzed H-D exchange reactions in arylsilanes.
abstract: [reaction: see text] Arylsilanes were regioselectively labeled with deuterium by treatment with platinum(IV) oxide and deuterium oxide under hydrothermal conditions. Arylsilanols were also labeled with regioselectively under the same conditions.
authors.affiliation: Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoudai-katsura, Nishikyo, Kyoto 615-8510, Japan.
authors.forename: Mitsuru
authors.initials: M
authors.lastname: Yamamoto
authors.forename: Koichiro
authors.initials: K
authors.lastname: Oshima
authors.forename: Seijiro
authors.initials: S
authors.lastname: Matsubara
mesh_terms: D002384:Catalysis; D041961:Deuterium Exchange Measurement; D017666:Deuterium Oxide / Q000737:chemistry; D008872:Microwaves; D015394:Molecular Structure; D017646:Organosilicon Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D017671:Platinum Compounds / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D017646:Organosilicon Compounds; D017671:Platinum Compounds; D017666:Deuterium Oxide