Platinum(IV) oxide catalyzed H-D exchange reactions in arylsilanes.
[reaction: see text] Arylsilanes were regioselectively labeled with deuterium by treatment with platinum(IV) oxide and deuterium oxide under hydrothermal conditions. Arylsilanols were also labeled with regioselectively under the same conditions.
Yamamoto
Mitsuru
M
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoudai-katsura, Nishikyo, Kyoto 615-8510, Japan.
Oshima
Koichiro
K
Matsubara
Seijiro
S
D002384:Catalysis; D041961:Deuterium Exchange Measurement; D017666:Deuterium Oxide / Q000737:chemistry; D008872:Microwaves; D015394:Molecular Structure; D017646:Organosilicon Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D017671:Platinum Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D017646:Organosilicon Compounds; D017671:Platinum Compounds; D017666:Deuterium Oxide