title: Stereochemistry of the reaction catalysed by 2-hydroxy-6-keto-6-phenyl-hexa-2,4-dienoic acid 5,6-hydrolase (BphD).
abstract: The stereochemical course of the reaction catalysed by C-C hydrolase BphD from Burkholderia xenovorans LB400 occurs with replacement of a benzoyl group by hydrogen with overall retention of stereochemistry.
authors.affiliation: Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.
authors.forename: Jian-Jun
authors.initials: JJ
authors.lastname: Li
authors.forename: Timothy D H
authors.initials: TD
authors.lastname: Bugg
mesh_terms: D000466:Alkadienes / Q000737:chemistry / Q000378:metabolism*; D001565:Benzoates / Q000737:chemistry; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry; D006867:Hydrolases / Q000737:chemistry / Q000378:metabolism*; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D013237:Stereoisomerism
chemical_list: D000466:Alkadienes; D001565:Benzoates; D006859:Hydrogen; D006867:Hydrolases; C501941:2-hydroxy-6-keto-6-phenylhexa-2,4-dienoic acid 5,6-hydrolase