Efficient immobilisation of Rh-MonoPhos on the aluminosilicate AlTUD-1.
Rhodium-MonoPhos was successfully immobilised by ionic interactions on aluminosilicate AlTUD-1. The resulting new heterogeneous catalyst can be used in water and showed excellent enantioselectivity and activity in the asymmetric hydrogenation of methyl-2-acetamidoacrylate.
Simons
Chretien
C
Laboratory for Applied Organic Chemistry and Catalysis, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands.
Hanefeld
Ulf
U
Arends
Isabel W C E
IW
Minnaard
Adriaan J
AJ
Maschmeyer
Thomas
T
Sheldon
Roger A
RA