title: Controlled low-temperature molecular manipulation of sexiphenyl molecules on Ag111 using scanning tunneling microscopy.
abstract: A novel scanning tunneling microscope manipulation scheme for a controlled molecular transport of weakly adsorbed molecules is demonstrated. Single sexiphenyl molecules adsorbed on a Ag(111) surface at 6 K are shot towards single silver atoms by excitation with the tip. To achieve atomically straight shooting paths, an electron resonator consisting of linear standing-wave fronts is constructed. The sexiphenyl manipulation signals reveal a pi ring flipping as the molecule moves from the hcp to fcc site. Ab initio calculations show an incorporation of the Ag atom below the center of a pi ring.
authors.affiliation: Physics & Astronomy Department, Ohio University, Nanoscale and Quantum Phenomena Institute, Athens, Ohio 45701, USA. hla@ohio.edu
authors.forename: Saw-Wai
authors.initials: SW
authors.lastname: Hla
authors.forename: Kai-Felix
authors.initials: KF
authors.lastname: Braun
authors.forename: Bernhard
authors.initials: B
authors.lastname: Wassermann
authors.forename: Karl-Heinz
authors.initials: KH
authors.lastname: Rieder