title: The synthesis of [FeRu(CO)2(mu-CO)2(eta-C5H5)(eta-C5Me5)] and convenient entries to its organometallic chemistry.
abstract: The synthesis, fluxionality and reactivity of the heterobimetallic complex [FeRu(CO)2(mu-CO)2(eta-C5H5)(eta-C5Me5)] are described. Complex exhibits enhanced photolytic reactivity towards alkynes compared to its homometallic analogues, forming the dimetallacyclopentenone complexes [FeRu(CO)(mu-CO){mu-eta]1:eta3-C(O)CR"CR'}eta]-C5H5)(eta-C5Me5)]( R'= R"= H; R'= R"= CO2Me; R'= H, R"= CMe2OH). Prolonged photolysis with diphenylethyne gives the dimetallatetrahedrane complex [FeRu(mu-CO)(mu-eta2:eta2-CPhCPh)(eta-C5H5)(eta-C5Me5)], which contains the first iron-ruthenium double bond. Complexes containing a number of organic fragments can be synthesised using , and . Heating a solution of gave the alkenylidene complex [FeRu(CO)2(mu-CO){mu-eta]1:eta2-C=C(CO2Me)2}(eta-C5H5)(eta-C5Me5)] through an unusual methylcarboxylate migration. Protonation and then addition of hydride to gives the ethylidene complex [FeRu(CO)2(mu-CO)(mu-CHCH3)(eta-C5H5)(eta-C5Me5)] via the ionic vinyl species [FeRu(CO)2(mu-CO)(mu-eta]1:eta2-CH=CH2)(eta-C5H5)(eta-C5Me5)][BF4]. Compound exhibits cis/trans isomerisation at room temperature. Protonation of dimetallacyclopentenone complexes gives the allenyl species [FeRu(CO)2(mu-CO)(mu-eta1:eta2-CH=C=CMe2)(eta-C5H5)(eta-C5Me5)][BF4]. Compound exist as three isomers, two cis and one trans. The two cis isomers are shown to be interconverting by sigma-pi isomerisation. The solid state structures of these compounds were established by X-ray crystallography and are discussed.
authors.affiliation: School of Chemistry, University of Bristol, Bristol, UK S8 1TS.
authors.forename: James N L
authors.initials: JN
authors.lastname: Dennett
authors.forename: Selby A R
authors.initials: SA
authors.lastname: Knox
authors.forename: Kirsty M
authors.initials: KM
authors.lastname: Anderson
authors.forename: Jonathan P H
authors.initials: JP
authors.lastname: Charmant
authors.forename: A Guy
authors.initials: AG
authors.lastname: Orpen