title: Transient 2H-phospholes as powerful synthetic intermediates in organophosphorus chemistry.
abstract: Transient 2H-phospholes are easily obtained from 1-R-1H-phospholes by a [1,5]-shift of the R-substituent from phosphorus to the alpha-carbons of the ring. They display cyclopentadiene-like chemistry: [4+2]-cycloaddition reactions with alkenes, alkynes, conjugated dienes and aldehydes, deprotonation to give the aromatic phospholide ions, and reaction with transition metal derivatives to give eta(5)-phospholyl complexes. The resulting products have found some use in homogeneous and asymmetric catalysis and show some promise in the field of electroconducting polymers.
authors.affiliation: Department of Chemistry, University of California-Riverside, Riverside, CA 92521-0403, USA.
authors.forename: François
authors.initials: F
authors.lastname: Mathey