Chronoamperometric study of the films formed by 4,4'-bipyridyl cation radical salts on mercury in the presence of iodide ions: consecutive two-dimensional phase transitions.
This paper reports a new mathematical model for consecutive two-dimensional phase transitions that accounts for the chronoamperometric behavior observed in the formation of electrochemical phases by 4,4'-bipyridyl cation radical (BpyH(2)(*)(+)) on mercury in aqueous iodide solutions. Also, a new interpretation for the induction time is proposed.
Gómez
L
L
Departamento de Química Física y Termodinámica Aplicada, Universidad de Córdoba, Campus de Rabanales, Edificio C3, E-14014 Córdoba, Spain.
Ruiz
J J
JJ
Camacho
L
L
Rodríguez-Amaro
R
R