2H T2rho relaxation dynamics and double-quantum filtered NMR studies.
In this study 2H T2rho DQF NMR spectra of water in MCM-41 were measured. The T2rho double-quantum filtered (DQF) NMR signal is generated by applying a radio frequency (RF) field for various durations and then observed after a monitor RF pulse. It was found that the transfer between different quantum coherences by the couplings during long-duration RF fields (i.e., soft pulses) and that residual quadrupolar interaction dominates the signal decay. Knowledge of coherence transfer during long-RF pulses has special significance for the development of sophisticated multi-quantum NMR experiments especially multi-quantum MRI applications.
Hwang
Dennis W
DW
Department of Chemistry, National Taiwan University, Taipei, Taiwan, ROC. dwh@gate.sinica.edu.tw
Jhao
Wei-Jie
WJ
Hwang
Lian-Pin
LP