Enantioselective synthesis of chiral sulfinates using chiral diamines.
The reaction of p-toluenesulfinyl chloride with alcohols in the presence of chiral diamines was examined. Chiral sulfinates were obtained in good yields with enantioselectivity up to 76% ee.
Nakamura
Shuichi
S
Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya 466-8555, Japan.
Tateyama
Motoaki
M
Sugimoto
Hideki
H
Nakagawa
Masaya
M
Watanabe
Yoshihiko
Y
Shibata
Norio
N
Toru
Takeshi
T