title: Polycyclooctatetraeneoxy alkane polyanionic polyradicals.
abstract: The room temperature potassium reduction of 1,2,3-triscyclooctatetraeneoxypropane, in hexamethylphosphoramide (HMPA), yields an anion radical, which disproportionates so strongly to the dianion diradical that the anion radical cannot be observed via EPR. The dianion diradical has one unpaired electron in a primary and one in a secondary ring system, and it can be readily reduced to the corresponding trianion triradical. An analogous reduction of 1,2,3,4-tetrakiscyclooctatetraeneoxybutane does produce an observable anion radical, but it also is readily reduced to the system corresponding to one electron per eight-membered ring (the tetraanion tetraradical). These results and those obtained from systems containing two cyclooctatetraene (COT) moieties are explained in terms of the geometry changes COT undergoes upon one-electron reduction, the interactions between reduced and adjacent unreduced ring systems, and the electron- electron repulsion present in the polyanion polyradicals.
authors.affiliation: Department of Chemistry, Illinois State University, Normal, Illinois 61790-4160, USA. cdsteve@ilstu.edu
authors.forename: Cheryl D
authors.initials: CD
authors.lastname: Stevenson
authors.forename: Richard C
authors.initials: RC
authors.lastname: Reiter
authors.forename: Lisa F
authors.initials: LF
authors.lastname: Szczepura
authors.forename: Steven J
authors.initials: SJ
authors.lastname: Peters