Effect of poly-HEMA hydrophilic gel environment on the photo-physical behavior of rhodamine dyes.
The absorption spectra of rhodamine B (RB) chloride, rhodamine 6G (R6G) tetrafluoroborate and rhodamine 6G chloride in poly-2-hydroxyethyl methacrylate hydrogel (PHEMA) matrix were studied using absorption spectroscopy in the visible region. The transport and aggregative properties of these ionic dyes in aqueous solution across the hydrophilic gel were also investigated. The similarities of absorption spectra of RB in aqueous solutions and in hydrogel host suggest that the hydrogel framework has a minor effect in their absorption spectra. In contrast, there is a relatively strong interaction or electrostatic forces between R6G dyes and the hydrogel matrix. The permeability of R6G chloride through hydrogel host is seen to be markedly higher than RB chloride and R6G tetrafluoroborate.
Ghanadzadeh
A
A
Department of Chemistry, Faculty of Science, Gilan University, Namjou Street, Rasht 31345, Iran. aggilani@guilan.ac.ir
Sariri
R
R
Ghanadzadeh
H
H
Zakerhamidi
M S
MS
D002712:Chlorides / Q000737:chemistry; D004305:Dose-Response Relationship, Drug; D005782:Gels; D020136:Hydrogel, Polyethylene Glycol Dimethacrylate / Q000737:chemistry; D008956:Models, Chemical; D011102:Polyhydroxyethyl Methacrylate / Q000737:chemistry*; D011108:Polymers; D012235:Rhodamines / Q000032:analysis / Q000737:chemistry*; D013053:Spectrophotometry; D055672:Static Electricity; D013997:Time Factors
D002712:Chlorides; D005782:Gels; D011108:Polymers; D012235:Rhodamines; C026188:rhodamine 6G; D011102:Polyhydroxyethyl Methacrylate; D020136:Hydrogel, Polyethylene Glycol Dimethacrylate; C029773:rhodamine B