title: Chronoamperometric study of the films formed by 4,4'-bipyridyl cation radical salts on mercury in the presence of iodide ions: consecutive two-dimensional phase transitions.
abstract: This paper reports a new mathematical model for consecutive two-dimensional phase transitions that accounts for the chronoamperometric behavior observed in the formation of electrochemical phases by 4,4'-bipyridyl cation radical (BpyH(2)(*)(+)) on mercury in aqueous iodide solutions. Also, a new interpretation for the induction time is proposed.
authors.affiliation: Departamento de Química Física y Termodinámica Aplicada, Universidad de Córdoba, Campus de Rabanales, Edificio C3, E-14014 Córdoba, Spain.
authors.forename: L
authors.initials: L
authors.lastname: Gómez
authors.forename: J J
authors.initials: JJ
authors.lastname: Ruiz
authors.forename: L
authors.initials: L
authors.lastname: Camacho
authors.forename: R
authors.initials: R
authors.lastname: Rodríguez-Amaro