Tetranuclear copper(II) complex with glucose-1-phosphate and its phosphate ester exchange with ATP.
The novel tetranuclear copper(II) complexes with alpha-d-glucose-1-phosphates, [Cu(4)(mu-OH)(alpha-d-Glc-1P)(2)(L)(4)(H(2)O)(2)](NO(3))(3) (L = bpy (1), phen (2)), were prepared and characterized by X-ray crystallography. Complex 1 was further transformed into the ATP stabilized tetracopper(II) complex of [Cu(4)(ATP)(2)(bpy)(4)] (4), where ATP is adenosine 5'-triphosphate.
Kato
Merii
M
Department of Chemistry, Faculty of Science, Nara Women's University, Kitauoya-higashi-machi, Nara 630-8285, Japan.
Tanase
Tomoaki
T
D000255:Adenosine Triphosphate / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005958:Glucosephosphates / Q000737:chemistry*; D008956:Models, Chemical; D008968:Molecular Conformation; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis*
D005958:Glucosephosphates; D009942:Organometallic Compounds; D003300:Copper; D000255:Adenosine Triphosphate; C031590:glucose-1-phosphate