title: Separated quadrupolar field experiment.
abstract: We describe an NMR experiment that produces spectra correlating the first-order quadrupolar spectrum and the central transition spectrum of half-integer quadrupolar spins, allowing one to separate the quadrupolar parameters in overlapping spectra under both static and magic-angle-spinning conditions. Promising fields of applications include situations where the sample cannot easily be rotated, or where it cannot be rotated at the magic angle.
authors.affiliation: Department of Chemistry, New York University, 100 Washington Square East, New York, NY 10003, USA.
authors.forename: Rajeev
authors.initials: R
authors.lastname: Kumar
authors.forename: Wen
authors.initials: W
authors.lastname: Ling
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Schoefberger
authors.forename: Alexej
authors.initials: A
authors.lastname: Jerschow
mesh_terms: D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008962:Models, Theoretical; D017670:Sodium Compounds / Q000737:chemistry*
chemical_list: D017670:Sodium Compounds