title: Release dynamic process identification for a cement based material in various leaching conditions. Part I. Influence of leaching conditions on the release amount.
abstract: In this paper we investigate at laboratory scale the influence of the liquid/solid leaching conditions on the release of different chemical species from a reference porous material obtained by solidification of PbO and CdO with Portland cement. The pH influence on the dissolution of pollutants and the initial pore solution composition (target elements: Na(+), K(+), Ca(2+), Pb(2+), Cd(2+), SO(4)(2-)) were assessed by applying a methodology consisting of two equilibrium leaching tests, the Acid Neutralization Capacity (ANC) and the Pore Water (PW) tests and geochemical modelling. Samples of the same material were submitted in parallel to four different dynamic leaching tests in order to determine the influence of the sample shape (monolithic or granular) and eluate hydrodynamics (instantaneous L/S ratio, eluate renewal) on the leaching of the target elements. The comparison criteria were the eluate saturation state, the cumulative release and the released flux. Generally, the eluates obtained in the tests applied on granular material were more concentrated, even saturated for the eluate pH value with respect to Ca(2+), Pb(2+) and SO(4)(2-). The consequence of the eluate saturation is the slowing down effect on the dynamic release. The highest released flux was observed for the Monolith Leaching Test (MLT) involving the highest instantaneous L/S ratio and the lowest solid/liquid exchange surface and for which no saturation was observed, except Pb(2+) and SO(4)(2-) in some eluates. The maximum cumulative released-mass was obtained for the Column Leaching Test (CLT) applied on granular material having the highest exchange surface, the lowest instantaneous L/S and a continuous input flow of the leachant. The experimental results demonstrate the significance of the liquid/solid contact type which is also a scenario specific parameter.
authors.affiliation: Ecole des Mines d'Albi, F-81013 Albi, France.
authors.forename: Radu
authors.initials: R
authors.lastname: Barna
authors.forename: Zoltan
authors.initials: Z
authors.lastname: Rethy
authors.forename: Ligia
authors.initials: L
authors.lastname: Tiruta-Barna
mesh_terms: D002118:Calcium / Q000032:analysis; D003252:Construction Materials; D004058:Diffusion; D005374:Filtration; D006863:Hydrogen-Ion Concentration; D007477:Ions; D007854:Lead / Q000032:analysis; D008670:Metals / Q000032:analysis; D016062:Porosity; D012037:Refuse Disposal; D012212:Rheology; D013431:Sulfates / Q000032:analysis; D013997:Time Factors; D014865:Waste Disposal, Fluid / Q000379:methods*; D014867:Water / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D007477:Ions; D008670:Metals; D013431:Sulfates; D014874:Water Pollutants, Chemical; D014867:Water; D007854:Lead; D002118:Calcium