Vibrational spectra and chemical quantum calculations for 2-adamantylamino-5-nitropyridine crystals--a novel material for laser Raman converters.
Polycrystalline infrared and polarized FT-Raman spectra have been measured for 2-adamantylamino-5-nitropyridine, a novel organic material for laser Raman converters. The assignment of IR and Raman bands is given on the basis of DFT calculations. The spectroscopic studies have not indicated the presence of any significant intermolecular interactions in the crystal structure of this compound. The lines observed in the stimulated Raman spectrum of this crystal are assigned to the respective molecular vibrations.
Lorenc
J
J
Department of Bioorganic Chemistry, Faculty of Engineering and Economics, University of Economics, Wrocław, Poland.
Hanuza
Jerzy
J
Maczka
Mirosław
M
Kucharska
Edyta
E
Kaminskii
Alexander A
AA
Kaino
Toshikuni
T
Yaima
Tetsuya
T
Yokoo
Atsushi
A
D000218:Adamantane / Q000031:analogs & derivatives* / Q000737:chemistry*; D003460:Crystallization; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D008968:Molecular Conformation; D009569:Nitric Oxide / Q000737:chemistry; D016011:Normal Distribution; D011725:Pyridines / Q000737:chemistry*; D011789:Quantum Theory; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods*; D013059:Spectrum Analysis, Raman / Q000379:methods*; D013223:Statistics as Topic / Q000379:methods
C501723:2-adamantylamino-5-nitropyridine; D011725:Pyridines; D009569:Nitric Oxide; C023666:pyridine; D000218:Adamantane