3-Germyl-3,3-dimethylpropionic acid derivatives.
The crystal structures of 3,3-dimethyl-3-(trichlorogermyl)propionic acid, [Ge(C5H9O2)Cl3], 3,3-dimethyl-3-(triphenylgermyl)propionic acid, [Ge(C6H5)3(C5H9O2)], and 3,3-dimethyl-3-(tri-p-tolylgermyl)propionic acid, [Ge(C7H7)3(C5H9O2)], have slightly distorted tetrahedral geometries about the Ge atoms. All the structures form dimers via strong O-H...O hydrogen bonds, resulting in eight-membered rings that can be best described in terms of graph-set notation R2(2) (8).
Parvez
Masood
M
Department of Chemistry, The University of Calgary, 2500 University Drive NW, Calgary, Alberta, Canada T2N 1N4. parvez@ucalgary.ca
Khosa
Kaleem M
KM
Mazhar
Muhammad
M
Ali
Saqib
S
Sohail
Manzar
M
D018360:Crystallography, X-Ray; D005857:Germanium / Q000737:chemistry*; D006860:Hydrogen Bonding; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011422:Propionates / Q000737:chemistry*
D009942:Organometallic Compounds; D011422:Propionates; D005857:Germanium