title: Field-theoretic simulations of polymer solutions: finite-size and discretization effects.
abstract: In this work we analyze the finite-size and discretization effects that occur in field-theoretic polymer simulations. Following our previous work, we study these effects for a polymer solution in the canonical ensemble confined to a slit (with nonadsorbing walls) of width L, and focus on the behavior of two quantities: the chemical potential mu, and the correlation length xi. Our results show that the finite-size effects disappear for both quantities once the lateral size of the system L is larger than approximately 2xi. On the other hand, the chemical potential is dominated by the lattice discretization Deltax. The origins of this dependence are discussed in detail, and a scheme is proposed in which this effect is avoided. Our results also show that the density profiles do not depend on the lattice discretization if Deltax < approximately xi/4. This implies that the correlation length xi, extracted from the density profiles, is free of lattice size and lattice discretization artifacts once L is > approximately 2xi and Deltax < approximately xi/4.
authors.affiliation: Physics Department, University of California, Santa Barbara, CA 93106, USA.
authors.forename: Alfredo
authors.initials: A
authors.lastname: Alexander-Katz
authors.forename: André G
authors.initials: AG
authors.lastname: Moreira
authors.forename: Scott W
authors.initials: SW
authors.lastname: Sides
authors.forename: Glenn H
authors.initials: GH
authors.lastname: Fredrickson