title: Thermal decomposition kinetics of the Pb0.25Ba0.75(TNR).H2O complex.
abstract: Studies of the non-isothermal decomposition of Pb(0.25)Ba(0.75)(TNR).H(2)O (TNR=2,4,6-trinitro-1,3-dihydroxy-benzene) were carried out by means of TG-DTA, DSC and IR techniques. The thermal decomposition mechanism and the associated kinetics have been investigated. The kinetic parameters were obtained from the analysis of the DSC curves by integral and differential methods. The most probable kinetic model function of the dehydration reaction of Pb(0.25)Ba(0.75)(TNR).H(2)O were suggested by comparison of the kinetic parameters.
authors.affiliation: Xian Modern Chemistry Research Institute, Xian 710065, China. hurongzu@public.xa.sn.cn
authors.forename: Rongzu
authors.initials: R
authors.lastname: Hu
authors.forename: Sanping
authors.initials: S
authors.lastname: Chen
authors.forename: Shengli
authors.initials: S
authors.lastname: Gao
authors.forename: Fengqi
authors.initials: F
authors.lastname: Zhao
authors.forename: Yang
authors.initials: Y
authors.lastname: Luo
authors.forename: Hongxu
authors.initials: H
authors.lastname: Gao
authors.forename: Qizhen
authors.initials: Q
authors.lastname: Shi
authors.forename: Hongan
authors.initials: H
authors.lastname: Zhao
authors.forename: Pu
authors.initials: P
authors.lastname: Yao
authors.forename: Jing
authors.initials: J
authors.lastname: Li
mesh_terms: D017609:Barium Compounds / Q000737:chemistry; D001555:Benzene Derivatives / Q000737:chemistry; D045424:Complex Mixtures / Q000737:chemistry*; D015386:Hazardous Substances / Q000032:analysis*; D007700:Kinetics; D007854:Lead / Q000737:chemistry; D009574:Nitro Compounds / Q000737:chemistry; D013696:Temperature; D014867:Water / Q000737:chemistry
chemical_list: D017609:Barium Compounds; D001555:Benzene Derivatives; D045424:Complex Mixtures; D015386:Hazardous Substances; D009574:Nitro Compounds; D014867:Water; D007854:Lead