title: Removal of selenium and arsenic by animal biopolymers.
abstract: The animal biopolymers prepared from hen eggshell membrane and broiler chicken feathers, which are byproducts of the poultry-processing industry, were evaluated for the removal of the oxyanions selenium [Se(IV) and Se(VI)] and arsenic [As(III) and As(V)] from aqueous solutions. The biopolymers were found to be effective at removing Se(VI) from solution. Optimal Se(IV) and Se(VI) removal was achieved at pH 2.5-3.5. At an initial Se concentration of 100 mg/L (1.3 mM), the eggshell membrane removed approx 90% Se(VI) from the solution. Arsenic was removed less effectively than Se, but the chemical modification of biopolymer carboxyl groups dramatically enhanced the As(V) sorption capacity. Se(VI) and As(V) sorption isotherms were developed at optimal conditions and sorption equilibrium data fitted the Langmuir isotherm model. The maximum uptakes by the Langmuir model were about 37.0 mg/g and 20.7 mg/g of Se(VI) and 24.2 mg/g and 21.7 mg/g of As(V) for eggshell membrane and chicken feathers, respectively.
authors.affiliation: Faculty of Animal Science, School of Veterinary Medicine and Animal Sciences, Kitasato University, Towada, Aomori 034-8628, Japan.
authors.forename: Shin-ichi
authors.initials: S
authors.lastname: Ishikawa
authors.forename: Shiho
authors.initials: S
authors.lastname: Sekine
authors.forename: Noriko
authors.initials: N
authors.lastname: Miura
authors.forename: Kyozo
authors.initials: K
authors.lastname: Suyama
authors.forename: Keizo
authors.initials: K
authors.lastname: Arihara
authors.forename: Makoto
authors.initials: M
authors.lastname: Itoh
mesh_terms: D000588:Amines / Q000737:chemistry; D000818:Animals; D001151:Arsenic / Q000302:isolation & purification*; D001704:Biopolymers / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry; D002645:Chickens; D004220:Disulfides / Q000737:chemistry; D004528:Egg Shell / Q000648:ultrastructure; D005241:Feathers / Q000648:ultrastructure; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008566:Membranes; D008855:Microscopy, Electron, Scanning; D012643:Selenium / Q000302:isolation & purification*; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
chemical_list: D000588:Amines; D001704:Biopolymers; D002264:Carboxylic Acids; D004220:Disulfides; D014874:Water Pollutants, Chemical; D012643:Selenium; D001151:Arsenic