Cyclopentathiadiazines, new heterocyclic materials from cyclic enaminonitriles.
Indene and cyclopentene enaminonitriles were reacted with SCl2, iBu3N and NCS to give the first cyclopenta[1,2,6]thiadiazines that showed unusual characteristics, one as a NIR dye and another as a liquid crystal.
Macho
Sonia
S
Departamento de Química, Facultad de Ciencias, Universidad de Burgos, 09001 Burgos, Spain.
Miguel
Daniel
D
Neo
Ana G
AG
Rodriguez
Teresa
T
Torroba
Tomás
T
D006571:Heterocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry*; D013829:Thiadiazines / Q000138:chemical synthesis* / Q000737:chemistry; D014961:X-Ray Diffraction
D006571:Heterocyclic Compounds; D009570:Nitriles; D013829:Thiadiazines