title: LEED, STM, and TDS studies of ordered thin films of the rhombus-shaped polycondensed aromatic hydrocarbon C54H22, on MoS2, GeS, and graphite.
abstract: Low-energy electron diffraction (LEED), scanning tunneling microscopy (STM), and thermal desorption spectroscopy (TDS) are used to study vacuum vapor-deposited molecular thin films of the rhombus-shaped polycondensed aromatic hydrocarbon "rhombus-C54", C54H22, on MoS2 and graphite (0001) and on GeS (010) substrates. It is found that this compound forms well-ordered incommensurate superstructures of the closest packed flat-lying molecules in well-defined azimuthal orientations to the substrate. These films are thermally remarkably stable. By TDS, a monolayer binding energy on graphite of 2.3 eV was derived, whereas the molecules in the second layer were found to be less strongly bound (1.9 eV). This difference allows the preparation of monolayers by desorbing multilayers at the appropriate temperature. Apparently, this molecule is a promising candidate for further studies aiming at applications in organic electronics such as organic field effect transistors or light emitting displays.
authors.affiliation: Physikalisches Institut, Universität Stuttgart, D-70550 Stuttgart, Germany.
authors.forename: Christian
authors.initials: C
authors.lastname: Günther
authors.forename: Norbert
authors.initials: N
authors.lastname: Karl
authors.forename: Jens
authors.initials: J
authors.lastname: Pflaum
authors.forename: Rainer
authors.initials: R
authors.lastname: Strohmaier
authors.forename: Bruno
authors.initials: B
authors.lastname: Gompf
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Eisenmenger
authors.forename: Markus
authors.initials: M
authors.lastname: Müller
authors.forename: Klaus
authors.initials: K
authors.lastname: Müllen