The hydrogen salicylate ion as ligand. Complex formation equilibria with dioxouranium (VI), neodymium (III) and lead (II).
The complexation equilibria of the hydrogen salicylate ion, HL(-), have been studied, at 25 degrees C, by potentiometric measurements with a glass electrode in 1 M NaClO4 for uranyl and Nd(III) ions and in 3 M NaClO4 for Pb(II) ion. The ligand concentration (CL) was varied between 10(-3) and 0.05 M. In the system with U(VI) the concentrations ranged between: 10(-3) < or = [U(VI)] < or = 0.01 M, 0.5 < or = CL /[U(VI)] < or = 10 and 10(-2) < or = [H+] < or = 10(-5) M; for neodymium system: 2 x 10(-3) < or = [Nd(III)] < or = 0.01, 1 < or = CL /[Nd(III)] < or = 10 and 10(-2) < or = [H+] < or = 10(-7) M; for lead system: 10(-3) < or = [Pb(II) < or = 3 x 10(-3), 1 < or = CL /Pb(II)] < or = 2 and 10(-5) < or = [H+] < or = 10(-7.3) M. The experimental data have been explained with the formation of UO2HL+, UO2L, UO2(OH)L(-), (UO2)2(OH)L2(-) UO2(HL)L(-), NdHL(2+), NdL(+), Nd(OH)L, PbHL(+), PbL and PbL2(2-). Equilibrium constants are given for the investigated ionic media and at infinite dilution.
Furia
Emilia
E
Dipartimento di Chimica, Università della Calabria, Via P. Bucci, Arcavacata di Rende, 87036 Rende, CS, Italy.
Porto
Raffaella
R
D006863:Hydrogen-Ion Concentration; D017736:Ion-Selective Electrodes; D007477:Ions / Q000737:chemistry*; D007854:Lead / Q000737:chemistry; D008024:Ligands; D009354:Neodymium / Q000737:chemistry; D010472:Perchlorates / Q000737:chemistry; D011199:Potentiometry / Q000379:methods*; D012459:Salicylates / Q000737:chemistry*; D017670:Sodium Compounds / Q000737:chemistry; D017974:Uranium Compounds / Q000737:chemistry*
D007477:Ions; D008024:Ligands; D010472:Perchlorates; D012459:Salicylates; D017670:Sodium Compounds; D017974:Uranium Compounds; D009354:Neodymium; D007854:Lead; C031068:sodium perchlorate