Synthesis of a hafnocene disilene complex.
Reaction of the magnesium transmetalation product of a 1,2-dipotassiodisilane with hafnocene dichloride gives a disilene hafnocene complex. X-ray crystallography of the respective trimethylphosphane adduct provides structural proof for this assignment.
Fischer
Roland
R
Institut für Anorganische Chemie, Technische Universität Graz, A-8010 Graz, Stremayrgasse 16/IV, Austria.
Zirngast
Michaela
M
Flock
Michaela
M
Baumgartner
Judith
J
Marschner
Christoph
C