title: Sorption, degradation, and leaching of tebuthiuron and diuron in soil columns.
abstract: A study in small outdoor lysimeters was carried out to determine the leaching of the herbicides tebuthiuron and diuron in different soil types, using undisturbed soil columns. Soil sorption and degradation for both herbicides were also studied in the laboratory. The multi-layered AF (Attenuation Factor) model was evaluated for predicting the herbicides leaching in undisturbed soil columns. Tebuthiuron leached in greater amounts than diuron in both soils. Sorption was well represented by linear and Freundlich equations, however parameters from the linear equations were used in the AF model. In general, both herbicides presented very low sorption, with diuron presenting lower values of sorption coefficient than tebuthiuron in the two soils. Chromatographic data indicated rapid late degradation of diuron and tebuthiuron in both soil types at two different depths. Simple exponential equation was not able to represent degradation, thus a bi-exponential equation was used, and some model adjusting was needed. Average measured amounts of each herbicide were compared with amounts predicted by the multi-layered-soil AF model. The AF model was able to predict leaching amounts in the sandy soil, especially for diuron, however it did not perform well in the clayey soil.
authors.affiliation: Centro Experimental Central do Instituto Biológico, Campinas, São Paulo, Brazil. matallo@biologico.sp.gov.br
authors.forename: Marcus B
authors.initials: MB
authors.lastname: Matallo
authors.forename: Claudio A
authors.initials: CA
authors.lastname: Spadotto
authors.forename: Luiz C
authors.initials: LC
authors.lastname: Luchini
authors.forename: Marco A F
authors.initials: MA
authors.lastname: Gomes
mesh_terms: D000327:Adsorption; D000538:Aluminum Silicates; D000077215:Clay; D004237:Diuron / Q000737:chemistry*; D005544:Forecasting; D006540:Herbicides / Q000737:chemistry*; D008782:Methylurea Compounds / Q000737:chemistry*; D008962:Models, Theoretical; D018570:Risk Assessment; D012822:Silicon Dioxide; D012989:Soil Pollutants / Q000032:analysis*; D012995:Solubility
chemical_list: D000538:Aluminum Silicates; D006540:Herbicides; D008782:Methylurea Compounds; D012989:Soil Pollutants; D012822:Silicon Dioxide; D004237:Diuron; C010346:tebuthiuron; D000077215:Clay