Rational design of azide-bridged bimetallic complexes. Crystal structure and magnetic properties of Fe(III)MFe(III) (M = Ni(II) and Cu(II)) trinuclear species.
The first examples of azide-bridged bimetallic trinuclear complexes ([M(cyclam)][FeL(N3)(mu1,5-N3)]2) (H2L = 4,5-dichloro-1,2-bis(pyridine-2-carboxamido) benzene) have been structurally and magnetically characterized.
Colacio
Enrique
E
Departmento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, 18071, Granada, Spain. ecolacio@ugr.es
Costes
Jean-Pierre
JP
Domínguez-Vera
José M
JM
Maimoun
Ikram Ben
IB
Suárez-Varela
José
J