Confusion approach to porphyrinoid chemistry.
N-confused porphyrin (NCP) is a porphyrin isomer that is different largely from the parent porphyrin, particularly in the physical, chemical, structural, and coordination properties. Introduction of the confused pyrrole into the normal and expanded porphyrins leads to generation of the confused porphyrinoids having rich structural diversity. In this Account, we introduce a series of N-confused porphyrinoids recently synthesized and highlight their properties such as fusion, peripheral N coordination, supramolecular assemblies, anion binding, and singlet-oxygen sensitization.
Srinivasan
Alagar
A
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 812-8581, Japan.
Furuta
Hiroyuki
H
D000838:Anions; D018360:Crystallography, X-Ray; D019281:Dimerization; D006860:Hydrogen Bonding; D007536:Isomerism; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry; D010777:Photochemistry; D011166:Porphyrins / Q000138:chemical synthesis*; D011485:Protein Binding; D011758:Pyrroles / Q000737:chemistry; D026082:Singlet Oxygen / Q000737:chemistry
D000838:Anions; D009942:Organometallic Compounds; D011166:Porphyrins; D011758:Pyrroles; D026082:Singlet Oxygen