Highly enantioselective hydrogenation of enol ester phosphonates catalyzed by rhodium phosphine-phosphite complexes.
Chiral phosphine-phosphites provide versatile catalysts for the highly enantioselective hydrogenation of alpha-acyloxy alpha, beta-unsaturated phosphonates.
Rubio
Miguel
M
Instituto de Investigaciones Quimicas, Consejo Superior de Investigaciones Cientificas-Universidad de Sevilla, Avda Americo Vespucio s/n, Isla de la Cartuja, 41092 Sevilla, Spain.
Suárez
Andrés
A
Alvarez
Eleuterio
E
Pizzano
Antonio
A
D002384:Catalysis; D004952:Esters / Q000737:chemistry*; D006865:Hydrogenation; D015394:Molecular Structure; D063065:Organophosphonates / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D017905:Phosphites / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
D004952:Esters; D063065:Organophosphonates; D010720:Phosphines; D017905:Phosphites; D012238:Rhodium