title: Structural and spectroscopic characterization of (mu-hydroxo or mu-oxo)(mu-peroxo)diiron(III) complexes: models for peroxo intermediates of non-heme diiron proteins.
abstract: (mu-Hydroxo or oxo)(mu-1,2-peroxo)diiron(III) complexes having a tetradentate tripodal ligand (L) containing a carboxylate sidearm [Fe2(mu-OH or mu-O)(mu-O2)(L)2]n+ were synthesized as models for peroxo-intermediates of non-heme diiron proteins and characterized by various physicochemical measurements including X-ray analysis, which provide fundamental structural and spectroscopic insights into the peroxodiiron(III) complexes.
authors.affiliation: Department of Chemistry, Faculty of Science, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
authors.forename: Xi
authors.initials: X
authors.lastname: Zhang
authors.forename: Hideki
authors.initials: H
authors.lastname: Furutachi
authors.forename: Shuhei
authors.initials: S
authors.lastname: Fujinami
authors.forename: Shigenori
authors.initials: S
authors.lastname: Nagatomo
authors.forename: Yonezo
authors.initials: Y
authors.lastname: Maeda
authors.forename: Yoshihito
authors.initials: Y
authors.lastname: Watanabe
authors.forename: Teizo
authors.initials: T
authors.lastname: Kitagawa
authors.forename: Masatatsu
authors.initials: M
authors.lastname: Suzuki
mesh_terms: D040761:Biomimetic Materials / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D019159:Nonheme Iron Proteins / Q000737:chemistry*; D015204:Spectroscopy, Mossbauer; D013059:Spectrum Analysis, Raman
chemical_list: D005290:Ferric Compounds; D019159:Nonheme Iron Proteins