Self-assembled monolayers of optically active Co(III) complexes: a new promoter electrode recognizing the electron transfer site in cytochrome c.
A new-class of promoter electrode bearing a molecular recognition ability has been constructed; the chirality and/or orientation of promoter on the Au electrode surface have affected the electron transfer rate of cytochrome c.
Takahashi
Isao
I
Department of Applied Chemistry, Nagoya Institute of Technology, Nagoya 466-8555, Japan.
Inomata
Tomohiko
T
Funahashi
Yasuhiro
Y
Ozawa
Tomohiro
T
Jitsukawa
Koichiro
K
Masuda
Hideki
H
D000818:Animals; D015374:Biosensing Techniques; D003035:Cobalt / Q000737:chemistry*; D045304:Cytochromes c / Q000032:analysis*; D004563:Electrochemistry; D004566:Electrodes; D004579:Electron Transport; D006046:Gold / Q000737:chemistry; D006736:Horses; D015394:Molecular Structure; D009206:Myocardium / Q000378:metabolism
D003035:Cobalt; D006046:Gold; D045304:Cytochromes c