Reaction kinetics and mechanics in photo-polymerised networks.
OBJECTIVE
The aim of this paper is to address the relationship, existing in photo-cure composites, between the polymer-network forming reactions, along with their kinetics, and the resultant stress-transmitting micro-mechanical behavior.


METHODS
Photon numbers and energies were calculated and compared for a simple model monomer-composite system. Expressions for light irradiance at depth within materials were computed and the consequences of steady-state assumptions in kinetic models of conversion and shrinkage-strain rate were considered.


RESULTS
The resultant stress-transmitting properties are a complex function of photon-transport, absorption by photo-initiators, possibly non-steady-state free-radical cross-linking, collapse of free-volume and development of an elastic-network displaying non-homogenous structure, viscoelasticity and aging effects.


CONCLUSIONS
Researchers need to be aware of the complexity of these systems, so as to adequately control experimental variables and to develop more sophisticated models and hypotheses for experimental validation.
Watts
David C
DC
Biomaterials Research Group, School of Dentistry, The University of Manchester, Manchester M15 6FH, UK. david.watts@man.ac.uk
D003188:Composite Resins / Q000737:chemistry* / Q000528:radiation effects*; D018772:Dental Marginal Adaptation; D003799:Dental Stress Analysis; D004548:Elasticity; D006244:Hardness; D007700:Kinetics; D008027:Light; D008422:Materials Testing; D044367:Phase Transition; D017785:Photons; D017319:Photosensitizing Agents; D011108:Polymers / Q000737:chemistry; D013314:Stress, Mechanical; D014783:Viscosity
D003188:Composite Resins; D017319:Photosensitizing Agents; D011108:Polymers