Investigation of the diastereoselectivity of tricyclo(5.2.1.0(2,6))decan-10-ones: controversies and agreements.
The diastereoselectivities of tricyclo(5.2.1.0(2,6))decan-10-one and its derivatives are controlled by antiperiplanar and vicinal sigma --> piC=O interactions rather than the hyperconjugation effects as reported previously.
Yadav
Veejendra K
VK
Contribution from the Department of Chemistry, Indian Institute of Technology, Kanpur 208016, India. vijendra@iitk.ac.in
Singh
Latika
L