Trinuclear coordinatively labile Cu(II) complex of 4,6-O-ethylidene-beta-D-glucopyranosylamine derived Schiff base ligand and its reactivity towards primary alcohols and amines.
A novel neutral trinuclear Cu(II) complex of a Schiff base ligand derived from D-glucose has been synthesised and structurally characterised, which exhibits excellent alcohol binding affinity and activates the C-Cl bond of chloroform in the presence of primary amine.
Sah
Ajay K
AK
Department of Chemistry, Faculty of Science, Nara Women's University, Kitauoya-higashi-machi, Nara 630-8285, Japan.
Kato
Merii
M
Tanase
Tomoaki
T
D000438:Alcohols / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D005944:Glucosamine / Q000031:analogs & derivatives* / Q000737:chemistry; D006574:Heterocyclic Compounds, 2-Ring / Q000737:chemistry*; D006860:Hydrogen Bonding; D008024:Ligands; D008956:Models, Chemical; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012545:Schiff Bases / Q000737:chemistry*
C439754:4,6-O-ethylideneglucopyranosylamine; D000438:Alcohols; D000588:Amines; D006574:Heterocyclic Compounds, 2-Ring; D008024:Ligands; D009942:Organometallic Compounds; D012545:Schiff Bases; D003300:Copper; D005944:Glucosamine