Structural and spectroscopic characterization of (mu-hydroxo or mu-oxo)(mu-peroxo)diiron(III) complexes: models for peroxo intermediates of non-heme diiron proteins.
(mu-Hydroxo or oxo)(mu-1,2-peroxo)diiron(III) complexes having a tetradentate tripodal ligand (L) containing a carboxylate sidearm [Fe2(mu-OH or mu-O)(mu-O2)(L)2]n+ were synthesized as models for peroxo-intermediates of non-heme diiron proteins and characterized by various physicochemical measurements including X-ray analysis, which provide fundamental structural and spectroscopic insights into the peroxodiiron(III) complexes.
Zhang
Xi
X
Department of Chemistry, Faculty of Science, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
Furutachi
Hideki
H
Fujinami
Shuhei
S
Nagatomo
Shigenori
S
Maeda
Yonezo
Y
Watanabe
Yoshihito
Y
Kitagawa
Teizo
T
Suzuki
Masatatsu
M
D040761:Biomimetic Materials / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D019159:Nonheme Iron Proteins / Q000737:chemistry*; D015204:Spectroscopy, Mossbauer; D013059:Spectrum Analysis, Raman
D005290:Ferric Compounds; D019159:Nonheme Iron Proteins