A cyclic tetra-nuclear dinitrosyl iron complex [Fe(NO)2(imidazolate)]4: synthesis, structure and stability.
A novel cyclic tetra-nuclear dinitrosyl iron complex [Fe(NO)2(Im-H)]4 was isolated and characterized by X-ray crystallography, and in donor solvents this fragments into 17 e- monomeric units that give EPR spectra analogous to the g= 2.03 species seen in mammalian biology.
Wang
Ximeng
X
Department of Chemistry and Biochemistry, California State University, Long Beach, CA 90840, USA.
Sundberg
Eric B
EB
Li
Lijuan
L
Kantardjieff
Katherine A
KA
Herron
Steven R
SR
Lim
Mark
M
Ford
Peter C
PC
D018360:Crystallography, X-Ray; D003500:Cyclization; D004355:Drug Stability; D005296:Ferrous Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D007093:Imidazoles / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D005296:Ferrous Compounds; D007093:Imidazoles; D009942:Organometallic Compounds; C511189:tetra(dinitrosyl(imidazolate))iron