A two-dimensional azido-based topologic ferrimagnet.
The reported Mn(II)-azide system is the first example of a two-dimensional homometallic ferrimagnet, in which the magnetic properties are due exclusively to topological reasons related with the coordination mode of the bridging ligands; it is also the first case in which a system of this kind exhibits long range order comparable to the classical heterospin ferrimagnets.
Escuer
Albert
A
Departament de Química Inorgànica, Universitat de Barcelona, Martí Franqués 1-11, 08028 Barcelona, Spain. albert.escuer@qi.ub.es
Mautner
Franz A
FA
Goher
Mohamed A S
MA
Abu-Youssef
Morsy A M
MA
Vicente
Ramon
R