Molybdenum-catalyzed hydrostannations of allenylcarbinols.
Allenylcarbinols undergo regioselective hydrostannation in the presence of MoBl3, a catalyst which was developed for the hydrostannation of propargyl alcohols and derivatives; allylstannanes are formed preferentially, which can easily be converted into allyl iodides.
Kazmaier
Uli
U
Universität des Saarlandes, Institut für Organische Chemie, D-66123, Saarbrücken, Germany. u.kazmaier@mx.uni-saarland.de
Klein
Manuela
M