A luminescent linear trinuclear magnesium complex assembled from a phosphorus-based tris-hydrazone ligand.
A novel linear trinuclear magnesium complex (P(S)[N(CH3)N=CHC6H4-o-O]3)2Mg3 was prepared by the reaction of P(S)[N(CH3))N=CHC6H4-o-OH]3 with MgCl2 x 6H2O in the presence of triethylamine. The trinuclear magnesium complex is fluorescent in solution as well as in the solid-state.
Chandrasekhar
Vadapalli
V
Department of Chemistry, Indian Institute of Technology-Kanpur, Kanpur 208016, India. vc@iitk.ac.in
Azhakar
Ramachandran
R
Bickley
Jamie F
JF
Steiner
Alexander
A
D006835:Hydrazones / Q000737:chemistry*; D008024:Ligands; D049408:Luminescent Agents / Q000138:chemical synthesis* / Q000737:chemistry; D015636:Magnesium Chloride / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D009943:Organophosphorus Compounds / Q000737:chemistry*
D006835:Hydrazones; D008024:Ligands; D049408:Luminescent Agents; D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; D015636:Magnesium Chloride