title: Highly enantioselective hydrogenation of enol ester phosphonates catalyzed by rhodium phosphine-phosphite complexes.
abstract: Chiral phosphine-phosphites provide versatile catalysts for the highly enantioselective hydrogenation of alpha-acyloxy alpha, beta-unsaturated phosphonates.
authors.affiliation: Instituto de Investigaciones Quimicas, Consejo Superior de Investigaciones Cientificas-Universidad de Sevilla, Avda Americo Vespucio s/n, Isla de la Cartuja, 41092 Sevilla, Spain.
authors.forename: Miguel
authors.initials: M
authors.lastname: Rubio
authors.forename: Andrés
authors.initials: A
authors.lastname: Suárez
authors.forename: Eleuterio
authors.initials: E
authors.lastname: Alvarez
authors.forename: Antonio
authors.initials: A
authors.lastname: Pizzano
mesh_terms: D002384:Catalysis; D004952:Esters / Q000737:chemistry*; D006865:Hydrogenation; D015394:Molecular Structure; D063065:Organophosphonates / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D017905:Phosphites / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D004952:Esters; D063065:Organophosphonates; D010720:Phosphines; D017905:Phosphites; D012238:Rhodium