Surfactant-free synthesis of amphiphilic diblock copolymer nanoparticles via nitroxide-mediated emulsion polymerization.
Amphiphilic hairy nanoparticles are prepared in a one step, batch, heterogeneous polymerization of styrene or n-butyl acrylate, using a water-soluble poly(sodium acrylate) alkoxyamine macroinitiator based on the SG1 nitroxide.
Delaittre
Guillaume
G
Laboratoire de Chimie des Polymères, CNRS UMR7610, Université Pierre et Marie Curie, 75252 Paris cedex 05, France.
Nicolas
Julien
J
Lefay
Catherine
C
Save
Maud
M
Charleux
Bernadette
B