Synthesis and molecular structure of the first rhodium(I) complex containing a tetra-tert-butylcyclopentaphosphanide ligand.
Na[cyclo-(P(5)(t)Bu(4))] (1) reacts with [RhCl(PPh(3))(3)] (1:1) to give the first rhodium(I) complex with a tetra-tert-butylcyclopentaphosphanide ligand, [Rh{cyclo-(P(5)(t)Bu(4))}(PPh(3))(2)] (2). 2 was characterized by NMR ((1)H, (13)C, (31)P), MS, IR, and X-ray structure determination.
Schisler
Andrea
A
Institut für Anorganische Chemie der Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany.
Lönnecke
Peter
P
Hey-Hawkins
Evamarie
E