Fluorescent imprinted polymers prepared with 2-acrylamidoquinoline as a signaling monomer.
[structure: see text] A cyclobarbital-selective molecularly imprinted polymer was prepared using a fluorescent functional monomer, 2-acrylamidoquinoline. This monomer was designed to increase in fluorescence intensity upon hydrogen bonding to the cyclobarbital guest. The resultant imprinted polymers exhibited the enhancement of the fluorescence intensity when cyclobarbital was bound. Our results show that this fluorescent responsive imprinting method could be useful in the development of sensors for quantification of nonfluorescent compounds.
Kubo
Hiroyuki
H
Graduate School of Science and Technology, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe 657-8501, Japan.
Yoshioka
Nobuyuki
N
Takeuchi
Toshifumi
T
D000178:Acrylamides / Q000737:chemistry*; D001463:Barbiturates / Q000737:chemistry; D005456:Fluorescent Dyes / Q000737:chemistry*; D006860:Hydrogen Bonding; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D011108:Polymers; D011804:Quinolines / Q000737:chemistry*; D013050:Spectrometry, Fluorescence; D013816:Thermodynamics
C510251:2-acrylamidoquinoline; D000178:Acrylamides; D001463:Barbiturates; D005456:Fluorescent Dyes; D007202:Indicators and Reagents; D011108:Polymers; D011804:Quinolines; C084639:cyclobarbital