New catalytic route to functionalized vinylboronates.
Vinylsubstituted boronates i.e. vinyldioxaborolane and vinyldioxaborinane react regioselectively with olefins in the presence of RuHCl(CO)(PCy3)2 with the formation of functionalized vinylboron derivatives. The reaction opens a new catalytic route for preparation of organoboranes.
Marciniec
Bogdan
B
Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland. marcinb@amu.edu.pl
Jankowska
Magdalena
M
Pietraszuk
Cezary
C