Inclusion complexes of trivalent lutetium cations with an acidic derivative of per(3,6-anhydro)-alpha-cyclodextrin.
The cyclodextrin derivative (hexakis (2-O-carboxymethyl-3,6-anhydro)-alpha-cyclodextrin) forms mono- and bimetallic complexes with lutetium(III) in aqueous solution; the X-ray structure of the binuclear complex [Lu2(ACX)(H2O)2] is the first example of a lanthanide-cyclodextrin inclusion complex.
Bonnet
Célia
C
Laboratoire de Reconnaissance Ionique, SCIB, CEA/DSM/DRFMC, CEA-Grenoble, 17 rue des Martyrs, 38054 Grenoble Cedex 9, France.
Gadelle
Andrée
A
Pécaut
Jacques
J
Fries
Pascal H
PH
Delangle
Pascale
P
D000143:Acids / Q000737:chemistry; D002412:Cations; D018360:Crystallography, X-Ray; D008187:Lutetium / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D047391:alpha-Cyclodextrins / Q000737:chemistry*
D000143:Acids; D002412:Cations; D009942:Organometallic Compounds; D047391:alpha-Cyclodextrins; C110521:per(3,6-anhydro)-alpha-cyclodextrin; D008187:Lutetium