Absorption spectrometric and thermodynamic study of charge transfer complexes of menadione (Vitamin K3) with a series of phenols.
The electron donor-acceptor (EDA) interactions between menadione (i.e., 2-methyl-1,4-naphthoquinone, which is also called 'Vitamin K3') and a series of phenols (viz., phenol, resorcinol and p-quinol) have been studied in CCl4 medium. In all the cases, charge transfer (CT) bands have been located. The CT transition energies (h nu(CT)) of the complexes are found to change systematically with change in the number and position of the -OH groups in the aromatic ring of the phenol moiety. From the trends in the h nu(CT) values, the Hückel parameters (h(O) and k(C-O)) for the -OH group have been obtained. The CT transition energies are well correlated with the ionisation potentials of the phenols. From an analysis of this variation the electron affinity of Vitamin K3 has been found to be 2.28 eV. The stoichiometry of the complexes in each case has been found to be 1(menadione):2 (phenol). Formation constants of the complexes have been determined at four different temperatures from which the enthalpies and entropies of formation of the complexes have been estimated.
Pal
Purnendu
P
Department of Chemistry, University College of Science, University of Calcutta, Kolkata 700009, India.
Bhattacharya
Sumanta
S
Mukherjee
Asok K
AK
Mukherjee
Dulal C
DC
D003627:Data Interpretation, Statistical; D007700:Kinetics; D010636:Phenols / Q000737:chemistry*; D013057:Spectrum Analysis; D013816:Thermodynamics; D024483:Vitamin K 3 / Q000737:chemistry*
D010636:Phenols; D024483:Vitamin K 3