Strain-dependent localization, microscopic deformations, and macroscopic normal tensions in model polymer networks.
We use molecular dynamics simulations to investigate the microscopic and macroscopic response of model polymer networks to uniaxial elongations. By studying networks with strand lengths ranging from N(s)=20 to 200 we cover the full crossover from cross-link to entanglement dominated behavior. Our results support a recent version of the tube model which accounts for the different strain dependence of chain localization due to chemical cross-links and entanglements.
Svaneborg
Carsten
C
Max-Planck-Institut für Polymerforschung, Postfach 3148, D-55021 Mainz, Germany. zqex@mpipks-dresden.mpg.de
Grest
Gary S
GS
Everaers
Ralf
R
D003198:Computer Simulation; D004548:Elasticity; D008956:Models, Chemical; D008958:Models, Molecular; D015233:Models, Statistical; D011108:Polymers / Q000737:chemistry*; D013314:Stress, Mechanical; D013500:Surface Tension
D011108:Polymers