NaI-catalyzed highly regioselective ring-opening [1 + 2] cycloaddition reaction of cyclopropenes with imines: highly stereoselective synthesis of cis-vinylic aziridines.
cis-Vinylic aziridines were prepared highly stereoselectively via a NaI-catalyzed regioselective ring-opening [1 + 2] cycloaddition reaction of cyclopropenes with imines.
Ma
Shengming
S
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, P. R. China. masm@mail.sioc.ac.cn
Zhang
Junliang
J
Lu
Lianghua
L
Jin
Xin
X
Cai
Yangjun
Y
Hou
Hairong
H
D001388:Aziridines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D018360:Crystallography, X-Ray; D003500:Cyclization; D003521:Cyclopropanes / Q000737:chemistry*; D007097:Imines / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D012974:Sodium Iodide / Q000737:chemistry*; D013237:Stereoisomerism
D001388:Aziridines; D003521:Cyclopropanes; D007097:Imines; C021985:cyclopropene; D012974:Sodium Iodide