Unexpected ligand substitutions in the cluster core {Re6Se8}: synthesis and structure of the novel cluster compound Cs11(H3O)[Re6Se4(O)4Cl6]3.4H2O.
The compound Cs11(H3O)[Re6Se4(O)4Cl6]3.4H2O containing a novel cluster core {Re6Se4(O)4} with ordered ligands, where the 4 positions of one face of a Se4(O)4 cube are occupied exclusively by Se atoms and 4 O atoms lie in the opposite face was synthesized via the interaction of solid Re6Se8Br2 with molten KOH.
Yarovoi
S S
SS
Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, 3, Lavrentiev Av., 630090 Novosibirsk, Russia.
Mironov
Y V
YV
Solodovnikov
S F
SF
Naumov
D Y
DY
Moroz
N K
NK
Kozlova
S G
SG
Simon
A
A
Fedorov
V E
VE