A new layered zinc phosphate templated by protonated isonicotinate, [Zn2(C6H5NO2)2(HPO4)2].
An organic-inorganic hybrid compound, poly[bis[(pyridine-4-carboxylato)zinc(II)]-di-mu3-phosphato], [Zn2(C6H5NO2)2(HPO4)2], has been hydrothermally synthesized and structurally characterized. The crystal structure consists of two types of two-dimensional layers of zinc hydrogenphosphate templated by protonated isonicotinate (ina) (or 4-pyridinecarboxylic acid), which contain two crystallographically independent centrosymmetric [Zn2(ina)2(HPO4)2] dimers as basic building units. The layers are interconnected via hydrogen-bonding and heterocyclic ring interactions.
Guo
Guang Sheng
GS
Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, New Jersey 08854, USA.
Wei
Yong Ge
YG
Li
Jing
J
Wang
Ying
Y
Guo
Hong You
HY
D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D007539:Isonicotinic Acids / Q000737:chemistry*; D008968:Molecular Conformation; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010710:Phosphates / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*; D017967:Zinc Compounds / Q000737:chemistry*
D007539:Isonicotinic Acids; D009942:Organometallic Compounds; D010710:Phosphates; D017967:Zinc Compounds; C043952:zinc phosphate; D015032:Zinc