title: A new layered zinc phosphate templated by protonated isonicotinate, [Zn2(C6H5NO2)2(HPO4)2].
abstract: An organic-inorganic hybrid compound, poly[bis[(pyridine-4-carboxylato)zinc(II)]-di-mu3-phosphato], [Zn2(C6H5NO2)2(HPO4)2], has been hydrothermally synthesized and structurally characterized. The crystal structure consists of two types of two-dimensional layers of zinc hydrogenphosphate templated by protonated isonicotinate (ina) (or 4-pyridinecarboxylic acid), which contain two crystallographically independent centrosymmetric [Zn2(ina)2(HPO4)2] dimers as basic building units. The layers are interconnected via hydrogen-bonding and heterocyclic ring interactions.
authors.affiliation: Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, New Jersey 08854, USA.
authors.forename: Guang Sheng
authors.initials: GS
authors.lastname: Guo
authors.forename: Yong Ge
authors.initials: YG
authors.lastname: Wei
authors.forename: Jing
authors.initials: J
authors.lastname: Li
authors.forename: Ying
authors.initials: Y
authors.lastname: Wang
authors.forename: Hong You
authors.initials: HY
authors.lastname: Guo
mesh_terms: D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D007539:Isonicotinic Acids / Q000737:chemistry*; D008968:Molecular Conformation; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010710:Phosphates / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*; D017967:Zinc Compounds / Q000737:chemistry*
chemical_list: D007539:Isonicotinic Acids; D009942:Organometallic Compounds; D010710:Phosphates; D017967:Zinc Compounds; C043952:zinc phosphate; D015032:Zinc