Mineralization of polyethylene glycol in aqueous solution by hydrogen peroxide with basic oxygen furnace slag.
This study evaluated the dissolution behavior of basic oxygen furnace slag (BOF slag) and the performance of H2O2 with BOF slag denoted as H2O2/BOF slag process to degrade polyethylene glycol (PEG) in the aqueous solution. The concentration of total organic carbon (TOC) was chosen as a mineralization index of the degradation of PEG by the H2O2/BOF slag process. A first-order kinetic model with respect to TOC was adopted to represent the mineralization of PEG by H2O2/BOF slag process. The experimental results in this study suggested that dosages with 3.98 x 10(-4) mole min(-1) l(-1) H2O2 and 15 g l(-1) BOF slag loading in the solution at pH 2 provided the optimal operation conditions for the mineralization of PEG yielding a 75.5% treatment efficiency at 100 min reaction time. The H2O2/Fe2+ ratio was then determined to be 13.5:1.
Chiou
C S
CS
Graduate Institute of Environmental Engineering, National Taiwan University, Taipei 106, Taiwan.
Chang
C F
CF
Chang
C Y
CY
Wu
Y P
YP
Chang
C T
CT
Li
Y S
YS
Chen
Y H
YH
D002244:Carbon / Q000032:analysis; D002384:Catalysis; D006861:Hydrogen Peroxide / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste; D007501:Iron; D016877:Oxidants / Q000737:chemistry*; D011092:Polyethylene Glycols / Q000737:chemistry*; D012996:Solutions; D013232:Steel; D018505:Waste Management / Q000379:methods*
D007220:Industrial Waste; D016877:Oxidants; D012996:Solutions; D013232:Steel; D011092:Polyethylene Glycols; D002244:Carbon; D006861:Hydrogen Peroxide; D007501:Iron