Opening the 'black box': oscillations in organocuprate conjugate addition reactions.
Under the conditions of a rapid injection experiment, the conjugate addition reactions of butyl Gilman reagents with 2-cyclohexenone undergo oscillations of a complex nature.
Murphy
Michael D
MD
Department of Chemistry, University of North Carolina-Charlotte, Charlotte, NC 28223, USA.
Ogle
Craig A
CA
Bertz
Steven H
SH
D003300:Copper / Q000737:chemistry*; D003512:Cyclohexanones / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D013997:Time Factors
D003512:Cyclohexanones; D009942:Organometallic Compounds; C028215:2-cyclohexen-1-one; D003300:Copper