title: NaI-catalyzed highly regioselective ring-opening [1 + 2] cycloaddition reaction of cyclopropenes with imines: highly stereoselective synthesis of cis-vinylic aziridines.
abstract: cis-Vinylic aziridines were prepared highly stereoselectively via a NaI-catalyzed regioselective ring-opening [1 + 2] cycloaddition reaction of cyclopropenes with imines.
authors.affiliation: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, P. R. China. masm@mail.sioc.ac.cn
authors.forename: Shengming
authors.initials: S
authors.lastname: Ma
authors.forename: Junliang
authors.initials: J
authors.lastname: Zhang
authors.forename: Lianghua
authors.initials: L
authors.lastname: Lu
authors.forename: Xin
authors.initials: X
authors.lastname: Jin
authors.forename: Yangjun
authors.initials: Y
authors.lastname: Cai
authors.forename: Hairong
authors.initials: H
authors.lastname: Hou
mesh_terms: D001388:Aziridines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D018360:Crystallography, X-Ray; D003500:Cyclization; D003521:Cyclopropanes / Q000737:chemistry*; D007097:Imines / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D012974:Sodium Iodide / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001388:Aziridines; D003521:Cyclopropanes; D007097:Imines; C021985:cyclopropene; D012974:Sodium Iodide