[Determination of naphthenic acids in distillates of crude oil by gas chromatography/chemical ionization-mass spectrometry].
The petroleum carboxylic acids in 200-420 degrees C distillate of crude oil were separated by the extraction with column chromatography on an anion exchange resin. The effect of the composition and structure of naphthenic acids on separation were studied by the infra-red (IR) spectroscopic techniques. Naphthenic acids and iso-butane reagent gas were introduced into the ion source for chemical ionization, in which the ions represented by [M + C4H9]+ were used to calculate the relative molecular mass for each acid. Based on the mass spectra of pure fatty and naphthenic acids, in combination with the z-series formula CnH(2n + z)O2, the naphthenic acids can be classified into fatty, mono-, bi- ... hexa-cyclic types. The results indicated that the relative molecular mass range of naphthenic acids in this distillates was 170-510, and the carbon number range was C10-C35. The contents of bi-cyclic and tri-cyclic naphthenic acids were higher than others.
Lü
Zhenbo
Z
College of Materials & Metallurgy, Northeastern University, Shenyang 110005, China. lzhb6684708@21cn.com
Tian
Songbai
S
Zhai
Yuchun
Y
Sun
Yanwei
Y
Zhuang
Lihong
L
D000837:Anion Exchange Resins; D002264:Carboxylic Acids / Q000032:analysis* / Q000737:chemistry*; D002849:Chromatography, Gas / Q000379:methods; D002852:Chromatography, Ion Exchange / Q000379:methods; D015394:Molecular Structure; D008970:Molecular Weight; D010578:Petroleum / Q000032:analysis*; D021241:Spectrometry, Mass, Electrospray Ionization / Q000379:methods; D013055:Spectrophotometry, Infrared / Q000379:methods
D000837:Anion Exchange Resins; D002264:Carboxylic Acids; D010578:Petroleum; C046170:naphthenic acid