title: Ion selective transistor modelling for behavioural simulations.
abstract: Computer aided design and simulation of complex silicon microsystems oriented for environment monitoring requires efficient and accurate models of ion selective sensors, compatible with the existing behavioural simulators. This paper concerns sensors based on the back-side contact Ion Sensitive Field Effect Transistors (ISFETs). The ISFETs with silicon nitride gate are sensitive to hydrogen ion concentration. When the transistor gate is additionally covered with a special ion selective membrane, selectivity to other than hydrogen ions can be achieved. Such sensors are especially suitable for flow analysis of solutions containing various ions. The problem of ion selective sensor modelling is illustrated here on a practical example of an ammonium sensitive membrane. The membrane is investigated in the presence of some interfering ions and appropriate selectivity coefficients are determined. Then, the model of the whole sensor is created and used in subsequent electrical simulations. Providing that appropriate selectivity coefficients are known, the proposed model is applicable for any membrane, and can be straightforwardly implemented for behavioural simulation of water monitoring microsystems. The model has been already applied in a real on-line water pollution monitoring system for detection of various contaminants.
authors.affiliation: Department of Microelectronics & Computer Science, Technical University of Lodz, 93-590 Lodz, Poland. daniel@dmcs.p.lodz.pl
authors.forename: M
authors.initials: M
authors.lastname: Daniel
authors.forename: M
authors.initials: M
authors.lastname: Janicki
authors.forename: W
authors.initials: W
authors.lastname: Wroblewski
authors.forename: A
authors.initials: A
authors.lastname: Dybko
authors.forename: Z
authors.initials: Z
authors.lastname: Brzozka
authors.forename: A
authors.initials: A
authors.lastname: Napieralski
mesh_terms: D003198:Computer Simulation; D006859:Hydrogen; D017736:Ion-Selective Electrodes; D007477:Ions; D015233:Models, Statistical; D008962:Models, Theoretical; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D012815:Signal Processing, Computer-Assisted; D017655:Silicon Compounds / Q000737:chemistry; D014865:Waste Disposal, Fluid / Q000379:methods*; D014867:Water / Q000032:analysis; D014873:Water Pollutants / Q000032:analysis*; D014876:Water Pollution
chemical_list: D007477:Ions; D000644:Quaternary Ammonium Compounds; D017655:Silicon Compounds; D014873:Water Pollutants; D014867:Water; D006859:Hydrogen; C032734:silicon nitride