title: Missing first points and phase artifact mutually entangled in FT NMR data--noniterative solution.
abstract: Even moderate distortion at the beginning of the NMR signal contributes significantly to the baseline in the reciprocal domain, when the FID-type experiment is considered. If constant phase artifact is also involved, the net problem cannot be resolved accurately, according to its constituents considered in separation. This issue is particularly severe for powder patterns in solids, featuring complex broadband spectra, which substantially mask the baseline behavior. The complete correction procedure should intrinsically deal with both artifacts, due to the mutual dependency. The aim of this work is to indicate the possibility for the exact treatment of baseline and constant phase artifacts together, providing precise measure whether the correction is successful. We have found the analytical, noniterative solution for this coupled problem in the closed form. In this paper, we introduce the correction efficiency concept in order to have the measure for the correction reliability of the resulting spectrum. Relevant efficiency parameter eta is the subject for quantitative analysis resulting in certain constraints for the measurement. We have determined exemplar trends for this parameter as a function of experimental variables such as signal-to-noise ratio and missing points number. The method is model-free and drawn from the origin of the baseline artifact; therefore has potential to work for a broad range of applications.
authors.affiliation: Department of Physics, MRI Center, University of New Brunswick, P.O. Box 4400, Fredericton, E3B 5A3, Canada. stoch@unb.ca
authors.forename: Grzegorz
authors.initials: G
authors.lastname: Stoch
authors.forename: Zbigniew
authors.initials: Z
authors.lastname: Olejniczak