Rational synthesis of a two-dimensional honeycomb structure based on a paramagnetic paddlewheel diruthenium complex.
A novel 2-D coordination polymer with honeycomb (6,3) net topology is constructed from a paramagnetic paddlewheel diruthenium tetrabenzoate, [RuII2(O2CPh)4], as a linear linker motif and triazine as a three-connected node; the RuII2 cores are positioned on nodes of a 2-D Kagome lattice.
Furukawa
Shuhei
S
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Ohba
Masaaki
M
Kitagawa
Susumu
S
D018360:Crystallography, X-Ray; D008280:Magnetics; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry*; D013696:Temperature
D009942:Organometallic Compounds; D012428:Ruthenium