title: Unexpected ligand substitutions in the cluster core {Re6Se8}: synthesis and structure of the novel cluster compound Cs11(H3O)[Re6Se4(O)4Cl6]3.4H2O.
abstract: The compound Cs11(H3O)[Re6Se4(O)4Cl6]3.4H2O containing a novel cluster core {Re6Se4(O)4} with ordered ligands, where the 4 positions of one face of a Se4(O)4 cube are occupied exclusively by Se atoms and 4 O atoms lie in the opposite face was synthesized via the interaction of solid Re6Se8Br2 with molten KOH.
authors.affiliation: Nikolaev Institute of Inorganic Chemistry, Russian Academy of Sciences, 3, Lavrentiev Av., 630090 Novosibirsk, Russia.
authors.forename: S S
authors.initials: SS
authors.lastname: Yarovoi
authors.forename: Y V
authors.initials: YV
authors.lastname: Mironov
authors.forename: S F
authors.initials: SF
authors.lastname: Solodovnikov
authors.forename: D Y
authors.initials: DY
authors.lastname: Naumov
authors.forename: N K
authors.initials: NK
authors.lastname: Moroz
authors.forename: S G
authors.initials: SG
authors.lastname: Kozlova
authors.forename: A
authors.initials: A
authors.lastname: Simon
authors.forename: V E
authors.initials: VE
authors.lastname: Fedorov