A mixed-valence bis(diarylamino)stilbene: crystal structure and comparison of electronic coupling with biphenyl and tolane analogues.
The E-4,4'-bis[di(p-anisyl)amino]stilbene cation is a class-III mixed-valence species with electronic coupling comparable to that in its biphenyl-bridged analogue, whereas its tolane-bridged analogue belongs to class II.
Barlow
Stephen
S
School of Chemistry and Biochemistry and Center for Organic Photonics and Electronics, Georgia Institute of Technology, Atlanta, GA 30332-0400, USA. stephen.barlow@chemistry.gatech.edu
Risko
Chad
C
Coropceanu
Veaceslav
V
Tucker
Neil M
NM
Jones
Simon C
SC
Levi
Zerubba
Z
Khrustalev
Viktor N
VN
Antipin
Mikhail Yu
MY
Kinnibrugh
Tiffany L
TL
Timofeeva
Tatiana
T
Marder
Seth R
SR
Brédas
Jean-Luc
JL