Temperature and volume effects on the change of dynamics in propylene carbonate.
Dielectric relaxation and PVT measurements were carried out on propylene carbonate. From these, we show that thermal energy exerts a stronger influence than volume on the temperature dependence of the dynamic properties. Data obtained at all temperatures and pressures superimpose, when expressed as a function of T-1 V-3.7 . The scaling exponent is consistent with more thermally governed dynamics, and can be interpreted as a reflection of the soft nature of the potential. The change of dynamics observed in the conductivity and relaxation data transpires at a fixed value of either quantity, independent of temperature and pressure.
Pawlus
S
S
Institute of Physics, University of Silesia, Uniwersytecka 4, 40-007 Katowice, Poland.
Casalini
R
R
Roland
C M
CM
Paluch
M
M
Rzoska
S J
SJ
Ziolo
J
J