Synthesis and characterisation of two monomeric crystalline thallium(I) beta-diketiminates.
Treatment of the appropriate sodium beta-diketiminate NaL or NaL' with an equivalent portion of TlCl in thf under mild conditions furnishes in good yield the first structurally characterised thallium beta-diketiminates: the monomeric, orange, crystalline Tl(I) complexes TlL and TlL' [L = {N(SiMe3)C(Ph)}2CH, L' = {N(C6H3Pr(i)(2)-2,6)C(H)}2CPh].
Cheng
Yanxiang
Y
Chemistry Department, University of Sussex, Brighton, BN1 9QJ, UK.
Hitchcock
Peter B
PB
Lappert
Michael F
MF
Zhou
Meisu
M