title: A novel diastereoselective synthesis of (Z)-fluoroalkenes via a Nozaki-Hiyama-Kishi-type reaction.
abstract: A highly diastereoselective and straightforward synthesis for (Z)-2-fluoroallylic alcohols via a Nozaki-Hiyama-Kishi-type reaction with the corresponding bromofluoroolefins was developed, providing an easy access to highly interesting fluorinated synthons.
authors.affiliation: INSA de ROUEN, IRCOF, UMR CNRS6014, 1 rue Tesnière, 76131 Mont Saint-Aignan, France.
authors.forename: Guillaume
authors.initials: G
authors.lastname: Dutheuil
authors.forename: Xinsheng
authors.initials: X
authors.lastname: Lei
authors.forename: Xavier
authors.initials: X
authors.lastname: Pannecoucke
authors.forename: Jean-Charles
authors.initials: JC
authors.lastname: Quirion
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D006845:Hydrocarbons, Fluorinated