[The study of relation of the retention indices of n-alkenes with their molecular structure].
When the difference values between the retention indices of homologous series of n-alkenes and that of n-alkanes with the same carbon number were plotted with the number of carbon atoms in the molecule, it can be seen that the curve is nearly an exponential curve. We proposed an accurate formula to predict the retention indices of homologous series of n-alkenes. The retention indices of a total of 99 C12-C16 n-alkenes on capillary columns with stationary phase of Squalane, PFE and PEG-4000 were calculated. The standard deviations of the retention indices were +/-0.9-+/-1.5 index units. When the retention indices of n-alkenes with the same carbon numbers and the same geometric structure were plotted with the positions of the double bond in the molecule, it can be seen that the curve is also approximately an exponential curve. Therefore, we put forward an exact formula to predict the retention indices of the n-alkenes. The universality of the formula is demonstrated by predicting a total of 178 retention indices of C15-C18 n-alkenes on capillary columns with stationary phases of C87 hydrocarbon, Apiezonl L, CW-20M. The standard deviations of retention indices were +/-0.9-+/-1.2 index units.
Zhu
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Dalian Institute of Chemical Physics, the Chinese Academy of Sciences, Dalian, 116012.
Zhang
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L
Che
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