Adsorption of a multicomponent mixture of gases with multisite occupancy.
In this paper, we present a study of the adsorption of multicomponent mixtures with multisite occupancy. The transfer-matrix technique is used to analyze the one-dimensional binary mixtures for interacting systems. A general expression for the characteristic polynomial is derived. Extension of the treatment to a higher dimension is also presented by using the mean-field Bragg-Williams approximation, transfer-matrix calculations, and Monte Carlo simulation. Partial and total isotherms are obtained for the dimer-trimer mixture where a different order appears.
Manzi
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Departamento de Física, Laboratorio de Ciencias de Superficie y Medios Porosos, Universidad Nacional de San Luis, CONICET, Chacabuco 917, 5700 San Luis, Argentina.
Mas
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Belardinelli
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Pereyra
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