title: PS-COD and PS-9-BBN: polymer-supported reagents for solution-phase parallel synthesis.
abstract: 1,5-Cyclooctadiene was deprotonated under LICKOR conditions and reacted with Merrifield resin to afford an immobilized cyclooctadiene in high yield. This polymer is effective as a halogen scavenger, while hydroboration leads to a supported 9-BBN analogue. The latter exhibits similar regioselectivity to 9-BBN in olefin hydroboration. [reaction: see text]
authors.affiliation: Combinatorial Centre for Excellence, School of Chemistry, University of Southampton, Southampton SO17 1BJ, United Kingdom.
authors.forename: Jefferson D
authors.initials: JD
authors.lastname: Revell
authors.forename: Barbara
authors.initials: B
authors.lastname: Dörner
authors.forename: Peter D
authors.initials: PD
authors.lastname: White
authors.forename: A
authors.initials: A
authors.lastname: Ganesan
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry*; D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000138:chemical synthesis*; D002384:Catalysis; D016166:Free Radical Scavengers / Q000138:chemical synthesis*; D006219:Halogens / Q000737:chemistry; D007202:Indicators and Reagents / Q000138:chemical synthesis; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry*
chemical_list: D000475:Alkenes; D001896:Boron Compounds; D019086:Bridged Bicyclo Compounds, Heterocyclic; D016166:Free Radical Scavengers; D006219:Halogens; D007202:Indicators and Reagents; D011108:Polymers; C004267:9-borabicyclo(3,3,1)nonane