Inclusion of C60 into an adjustable porphyrin dimer generated by dynamic disulfide chemistry.
A new, highly flexible porphyrin dimer was isolated in preparative scale from a dynamic disulfide library; this receptor adjusts to fit guests with a wide range of steric requirements and, whilst C60 proved to be an unsuitable template for this library, a new C60-porphyrin complex was isolated and characterised.
Kieran
Amy L
AL
Department of Chemistry, University of Cambridge, Lensfield Rd, Cambridge, UK CB2 1EW.
Pascu
Sofia I
SI
Jarrosson
Thibaut
T
Sanders
Jeremy K M
JK
D020650:Combinatorial Chemistry Techniques / Q000379:methods; D018360:Crystallography, X-Ray; D019281:Dimerization; D004220:Disulfides / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry* / Q000302:isolation & purification; D011166:Porphyrins / Q000737:chemistry*; D012680:Sensitivity and Specificity; D015032:Zinc / Q000737:chemistry*
D004220:Disulfides; D037741:Fullerenes; D009942:Organometallic Compounds; D011166:Porphyrins; D015032:Zinc; C069837:fullerene C60