Highly stable olefin-Cu(I) coordination oligomers and polymers.
Highly stable Cu(I)-olefin coordination oligomers and polymers have been successfully prepared and applied to construct metal-organic frameworks (MOFs) with interesting physical and chemical functions in recent years. In this review, we present the olefin-Cu(I) coordination oligomers and polymers and their novel physical properties. From structure to functions, particular emphasis is placed on the coordination and organometallic chemistry of olefin-Cu(I) coordination oligomers and polymers, their structures and potential applications as solids possessing unusual physical functional properties such as electrochemical, chiral separation, fluorescent sensing and ferroelectricity.
Ye
Qiong
Q
Coordination Chemistry Institute, The State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, P. R. China.
Wang
Xi-Sen
XS
Zhao
Hong
H
Xiong
Ren-Gen
RG
D000475:Alkenes / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D004563:Electrochemistry; D008956:Models, Chemical; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D013050:Spectrometry, Fluorescence; D013237:Stereoisomerism
D000475:Alkenes; D009942:Organometallic Compounds; D011108:Polymers; D003300:Copper