Axial coordination of carboxylate activates the non-heme FeIV=O unit.
Rohde
Jan-Uwe
JU
Department of Chemistry and Center for Metals in Biocatalysis, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA.
Que
Lawrence
L
D002264:Carboxylic Acids / Q000737:chemistry*; D006418:Heme / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D019159:Nonheme Iron Proteins / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*; D013757:Tetraethylammonium Compounds / Q000737:chemistry; D014269:Trifluoroacetic Acid / Q000737:chemistry
D002264:Carboxylic Acids; D008024:Ligands; D019159:Nonheme Iron Proteins; D009942:Organometallic Compounds; D013757:Tetraethylammonium Compounds; C066317:ferryl iron; D006418:Heme; D007501:Iron; D014269:Trifluoroacetic Acid; D010100:Oxygen