True square planar [M{N(SePiPr2)2-Se,Se'}2][M = Sn, Se] complexes. An extraordinary geometrical arrangement for well known centers [Sn(II), Se(II)].
The syntheses and molecular structures of [M{N(SeP(i)Pr2)2-Se,Se'}2][M = Sn(2), Se(3)] are described, these complexes consist of discrete, monomeric molecules featuring MSe4 cores that comprise true square-planar geometries.
Cea-Olivares
Raymundo
R
Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México, 04510 DF México. cea@servidor.unam.mx
Moya-Cabrera
Mónica
M
García-Montalvo
Verónica
V
Castro-Blanco
Rafael
R
Toscano
Rubén A
RA
Hernández-Ortega
Simón
S