Model studies toward the synthesis of kirkine.
In model studies towards the synthesis of kirkine, the carbon skeleton was constructed using a radical cascade reaction. Two different approaches towards the synthesis have been examined as well as the regioselectivity of the radical cyclisation.
Barclay
Gillian L
GL
Laboratoire de Synthèse Organique associée au CNRS, Ecole Polytechnique, 91128, Palaiseau, France.
Quiclet-Sire
Béatrice
B
Sanchez-Jimenez
Graciela
G
Zard
Samir Z
SZ
D003500:Cyclization; D006576:Heterocyclic Compounds, 4 or More Rings / Q000138:chemical synthesis / Q000737:chemistry; D007536:Isomerism; D008956:Models, Chemical; D015394:Molecular Structure; D009414:Nerve Growth Factors / Q000138:chemical synthesis / Q000737:chemistry; D014315:Triterpenes / Q000138:chemical synthesis* / Q000737:chemistry
D006576:Heterocyclic Compounds, 4 or More Rings; D009414:Nerve Growth Factors; D014315:Triterpenes; C417923:kirkinine