Fluoroaryl-substituted aminoalane dimers: syntheses and structures.
Six dimeric aminoalanes of formula [Me(2)Al-mu-N(H)Ar(F)](2)(Ar(F)= 4-C(6)H(4)F (1), 2-C(6)H(4)F (2), 3,5-C(6)H(3)F(2)(3), 2,3,4,5-C(6)HF(4)(4), 2,3,5,6-C(6)HF(4)(5) and C(6)F(5)(6)) have been prepared by treatment of the appropriate fluoroaniline with AlMe(3) in toluene solution at 25 degrees C. The structures of 1-6 were determined by X-ray crystallography.
Shukla
Piyush
P
Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, TX 78712, USA. cowley@mail.utexas.edu
Cowley
Alan H
AH
Jones
Jamie N
JN
Gordon
John C
JC
Scott
Brian L
BL
D000535:Aluminum / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*
D006845:Hydrocarbons, Fluorinated; D009942:Organometallic Compounds; D000535:Aluminum