One teflon-like channelled nanoporous polymer with a chiral and new uninodal 4-connected net: sorption and catalytic properties.
Zn(C17H8F6O4) is the first example of a fluoro-lined nanotube organo-inorganic 3D polymeric chiral structure, which possesses two different types of isolated channels, one of them being laid out with a double spiral of CF3-groups from the ligand molecule; the structure is a new uninodal 4-connected net that only exists when bent ligands connect the centres, and the compound exhibits selective sorption and catalytic chiral recognition properties.
Monge
Angeles
A
Instituto de Ciencia de Materiales de Madrid (CSIC) Cantoblanco, 28049 Madrid, Spain. amonge@icmm.csic.es
Snejko
Natalia
N
Gutiérrez-Puebla
Enrique
E
Medina
Manuela
M
Cascales
Concepción
C
Ruiz-Valero
Caridad
C
Iglesias
Marta
M
Gómez-Lor
Berta
B
D000327:Adsorption; D002384:Catalysis; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D033362:Powder Diffraction; D015032:Zinc / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D011108:Polymers; D015032:Zinc