One-dimensional void-space arrays constructed from a coordination polymer with bowl-like frameworks of cavitands.
A one-dimensional coordination polymer of [Mn(II)(hfac)2] bridged by new bowl-like ligands of cavitands was prepared and the crystal structure was determined by X-ray crystal analysis. Ethyl acetate molecules are necessarily included as guest molecules in each of the void-space cavities of the cavitands, and then are held by weak interaction forces.
Tadokoro
Makoto
M
Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan. tadokoro@sci.osaka-cu.ac.jp
Mizugaki
Shin
S
Kozaki
Masatoshi
M
Okada
Keiji
K