Vibrational and electronic structure of the dinuclear bis(mu-nitrido) vanadium(v) complex [V(N{N"}2)(mu-N)]2: spectroscopic properties of the M2(mu-N)2 diamond core.
The vibrational and electronic structure of the bis(mu-nitrido) bridged complex [V(N{N"}2)(mu-N)]2 (1) (where [N{N"}2](2-)=[(Me3Si)N{CH(2)CH(2)N(SiMe3)}2](2-)) is analyzed. Assignment of the five modes of the V(2)(mu-N)2 core is based on (15)N isotope shifts and a DFT calculation on the calculated structure I which is an exact reproduction of 1. The three Raman active modes of the planar V(2)(mu-N)2 core are found in the Raman spectrum whereas the two IR allowed vibrations are identified in the infrared spectrum. Furthermore, the electronic structure of is described which complements earlier theoretical studies on the reaction pathway leading to 1(V. M. E. Bates, G. K. B. Clentsmith, F. G. N. Cloke, J. C. Green, H. D. L. Jenkin, Chem. Commun., 2000, 927). Based on the MO scheme of I the UV-vis transitions of 1 are assigned.
Studt
Felix
F
Institut für Anorganische Chemie der Christian Albrechts Universität zu Kiel, 24098 Kiel, Germany.
Lamarche
Vanessa M E
VM
Clentsmith
Guy K B
GK
Cloke
F Geoffrey N
FG
Tuczek
Felix
F
D004583:Electrons; D008024:Ligands; D008956:Models, Chemical; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011789:Quantum Theory; D012680:Sensitivity and Specificity; D013056:Spectrophotometry, Ultraviolet / Q000379:methods; D013059:Spectrum Analysis, Raman / Q000379:methods*; D014639:Vanadium / Q000737:chemistry*; D014732:Vibration
D008024:Ligands; D009942:Organometallic Compounds; D014639:Vanadium