The first rhodaboratrane: [RhCl(PPh3){B(mt)3}](Rh-->B)(mt = methimazolyl).
The reaction of [Rh(C6H5)Cl2(PPh3)2] with Na[HB(mt)3](mt = methimazolyl) provides [RhCl(PPh3){B(mt)3}](Rh-->B) the first authentic example of a compound with a rhodium-boron dative bond.
Crossley
Ian R
IR
Research School of Chemistry, Institute of Advanced Studies, Australian National University, Canberra, ACT Australia.
Foreman
Mark R St-J
MR
Hill
Anthony F
AF
White
Andrew J P
AJ
Williams
David J
DJ