title: Straightforward detection of the secondary ionisation of the phosphate group and pK determinations by high-resolution solid-state 31P NMR.
abstract: The suitability of high-resolution solid-state 31P NMR for a straightforward determination of the protonation state of phosphate groups as well as of their pK2 values extracted from solid state mono : dianionic ratios has been demonstrated.
authors.affiliation: UMR CNRS 7565, Universite Henri Poincare, Nancy 1, 54506 Vandoeuvre-les-Nancy, France.
authors.forename: Carole
authors.initials: C
authors.lastname: Gardiennet
authors.forename: Bernard
authors.initials: B
authors.lastname: Henry
authors.forename: Paul
authors.initials: P
authors.lastname: Kuad
authors.forename: Bernard
authors.initials: B
authors.lastname: Spiess
authors.forename: Piotr
authors.initials: P
authors.lastname: Tekely
mesh_terms: D000249:Adenosine Monophosphate / Q000737:chemistry / Q000378:metabolism; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D010710:Phosphates / Q000737:chemistry*; D012680:Sensitivity and Specificity
chemical_list: D010710:Phosphates; D000249:Adenosine Monophosphate