title: Indirect determination of uranium by the on-line reduction and fluorimetric detection of cerium(III).
abstract: A novel flow injection method has been developed for the indirect determination of uranium by the on-line reduction and subsequent fluorimetric detection of cerium(III). A sample solution containing uranium(VI), prepared as a sulfuric acid solution, was injected into a sulfuric acid carrier solution and passed through a column packed with metal bismuth to reduce uranium(VI) to uranium(IV). The sample solution was merged with a cerium(IV) solution to oxidize uranium(IV) to uranium(VI) and the cerium(III) generated was then monitored fluorimetricaly. The present method is free from interference from zirconium, lanthanides, and thorium, and has been successfully applied to the determination of uranium in monazite coupled with an anion-exchange separation in a sulfuric acid medium to eliminate iron(III). The sample throughput was 25 per hour and the lowest detectable concentration was 0.0042 mg l(-1).
authors.affiliation: Quality Materials Science, Graduate School of Science and Technology, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan.
authors.forename: Chatchalida
authors.initials: C
authors.lastname: Boonpanaid
authors.forename: Koichi
authors.initials: K
authors.lastname: Oguma