Novel alpha-functionally substituted amino acids: diphenylphosphinoglycines.
The three-component one-pot reaction of glyoxalic acid hydrate with P-H and N-H compounds allows a convenient access to phosphinoglycines. The molecular structure of , determined by X-ray crystallography, some reactions and an alternative formation of phosphinoglycolates are reported.
Heinicke
Joachim
J
Institut für Chemie und Biochemie, Ernst-Moritz-Arndt-Universität Greifswald, 17487, Greifswald, Germany. heinicke@uni-greifswald.de
Peulecke
Normen
N
Jones
Peter G
PG
D005998:Glycine / Q000031:analogs & derivatives* / Q000737:chemistry*; D006038:Glyoxylates / Q000737:chemistry; D008956:Models, Chemical; D008958:Models, Molecular; D015394:Molecular Structure
D006038:Glyoxylates; D005998:Glycine