Synthesis of 2,3-unsaturated C-glycosides by HClO4-SiO2 catalyzed Ferrier rearrangement of glycals.
Alkyl 2,3-unsaturated C-glycopyranosides have been prepared by Ferrier rearrangement of acyl or alkyl protected glycals catalyzed by HClO(4)-SiO(2).
Tiwari
Pallavi
P
Division of Medicinal and Process Chemistry, Central Drug Research Institute (CDRI), Chattar Manzil Palace, Lucknow 226 001, India.
Agnihotri
Geetanjali
G
Misra
Anup Kumar
AK
D002384:Catalysis; D006027:Glycosides / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D010472:Perchlorates / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry*
D006027:Glycosides; D010472:Perchlorates; D012822:Silicon Dioxide