Silyl methallylsulfinates: efficient and powerful agents for the chemoselective silylation of alcohols, polyols, phenols and carboxylic acids.
Alcohols, phenols and carboxylic acids are silylated with very good yields in the presence of silyl methallylsulfinates under non-basic conditions and with the formation of volatile co-products.
Huang
Xiaogen
X
Laboratoire de Glycochimie et de Synthèse Asymétrique, Ecole Polytechnique Fédérale de Lausanne, (EPFL), BCH, CH-1015, Lausanne, Suisse.
Craita
Cotinica
C
Awad
Loay
L
Vogel
Pierre
P
D000438:Alcohols / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D004952:Esters / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010636:Phenols / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D013237:Stereoisomerism; D013457:Sulfur Compounds / Q000737:chemistry*
D000438:Alcohols; D002264:Carboxylic Acids; D004952:Esters; D010636:Phenols; D011108:Polymers; D012821:Silanes; D013457:Sulfur Compounds; C024617:polyol