title: Fluoroaryl-substituted aminoalane dimers: syntheses and structures.
abstract: Six dimeric aminoalanes of formula [Me(2)Al-mu-N(H)Ar(F)](2)(Ar(F)= 4-C(6)H(4)F (1), 2-C(6)H(4)F (2), 3,5-C(6)H(3)F(2)(3), 2,3,4,5-C(6)HF(4)(4), 2,3,5,6-C(6)HF(4)(5) and C(6)F(5)(6)) have been prepared by treatment of the appropriate fluoroaniline with AlMe(3) in toluene solution at 25 degrees C. The structures of 1-6 were determined by X-ray crystallography.
authors.affiliation: Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, TX 78712, USA. cowley@mail.utexas.edu
authors.forename: Piyush
authors.initials: P
authors.lastname: Shukla
authors.forename: Alan H
authors.initials: AH
authors.lastname: Cowley
authors.forename: Jamie N
authors.initials: JN
authors.lastname: Jones
authors.forename: John C
authors.initials: JC
authors.lastname: Gordon
authors.forename: Brian L
authors.initials: BL
authors.lastname: Scott
mesh_terms: D000535:Aluminum / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*
chemical_list: D006845:Hydrocarbons, Fluorinated; D009942:Organometallic Compounds; D000535:Aluminum