Structural inversion in 3-D hexagonal organization of coil-rod-coil molecule.
We report an unusual example of supramolecular structural inversion in coil-rod-coil molecules, from organized coil perforations in a rod layers to organized discrete rod-bundles in a coil matrix, while maintaining a 3-D hexagonal superlattice.
Jin
Long Yi
LY
Center for Supramolecular Nano-Assembly and Department of Chemistry, Yonsei University, Seoul 120-749, Korea.
Bae
Jinyoung
J
Ahn
Jong-Hyun
JH
Lee
Myongsoo
M
D003460:Crystallization; D008958:Models, Molecular; D015394:Molecular Structure; D014961:X-Ray Diffraction / Q000379:methods