Syntheses of metallabenzynes from an allenylcarbene complex.
Treatment of the allenylcarbene complex OsCl2(=CPh-CH=C=CHPh)(PPh3)2 with (PPh3)AuCCR in the presence of HNEt3Cl in CH2Cl2 produces osmabenzynes Os(CC(R)=C(CH2Ph)CH=CPh)Cl2(PPh3)2.
Wen
Ting Bin
TB
Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong.
Hung
Wai Yiu
WY
Sung
Herman H Y
HH
Williams
Ian D
ID
Jia
Guochen
G