A novel diastereoselective synthesis of (Z)-fluoroalkenes via a Nozaki-Hiyama-Kishi-type reaction.
A highly diastereoselective and straightforward synthesis for (Z)-2-fluoroallylic alcohols via a Nozaki-Hiyama-Kishi-type reaction with the corresponding bromofluoroolefins was developed, providing an easy access to highly interesting fluorinated synthons.
Dutheuil
Guillaume
G
INSA de ROUEN, IRCOF, UMR CNRS6014, 1 rue Tesnière, 76131 Mont Saint-Aignan, France.
Lei
Xinsheng
X
Pannecoucke
Xavier
X
Quirion
Jean-Charles
JC
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D013237:Stereoisomerism
D000475:Alkenes; D006845:Hydrocarbons, Fluorinated