Synthesis of new 2-C-(2,3:5,6-di-O-isopropylidene)-beta-D-mannofuranosyldithioacetate derivatives.
Various new C-glycosides have been synthesized through the thioacylation reaction of different amines by a 2-C-mannofuranosyldithioacetate. Amino acids, di- and polyamines (putresceine, spermine, spermidine) and one amino alcohol were in particular used to generate glycothiopeptidic or precursors of "bola" structures.
Dominguez
Zaira J
ZJ
Unidad de Servicios de Apoyo en Resoluciòn Analitica, Universidad Veracruzana. Xalapa Ver., Mexico.
Marchand
Patrice
P
Gulea
Mihaela
M
Masson
Serge
S
D000215:Acylation; D000588:Amines / Q000737:chemistry; D000596:Amino Acids / Q000737:chemistry; D002240:Carbohydrate Sequence; D004952:Esters / Q000737:chemistry; D006027:Glycosides / Q000138:chemical synthesis*; D006868:Hydrolysis; D008358:Mannose / Q000031:analogs & derivatives* / Q000737:chemistry; D015394:Molecular Structure; D010455:Peptides / Q000138:chemical synthesis; D011073:Polyamines / Q000737:chemistry; D013329:Structure-Activity Relationship; D013455:Sulfur / Q000737:chemistry
D000588:Amines; D000596:Amino Acids; D004952:Esters; D006027:Glycosides; D010455:Peptides; D011073:Polyamines; D013455:Sulfur; D008358:Mannose