Syntheses and molecular structures of eta3-[(eta5-Cp*)(CO)2Fe-AsPC(SiMe3)2]M(CO)2(eta5-Cp)(M = Mo, W): the first complexes featuring eta3-arsaphosphaallyl ligands.
Reaction of (eta5-Cp)(CO)2M=P=C(SiMe3)2 4a (M = Mo) and 4b (M = W) with (eta5-Cp*)(CO)2Fe-As=C(NMe2)2 5 affords the eta3-1-arsa-2-phosphaallyl complexes [(eta5-Cp*)(CO)2Fe-AsPC(SiMe3)2]M(CO)2(eta5-Cp) 6a and 6b, the molecular structures of which were determined by X-ray analyses.
Weber
Lothar
L
Fakultät für Chemie der Universität Bielefeld, Universitätsstr. 25, D-33615, Bielefeld, Germany. lothar.weber@uni-bielefeld.de
Bayer
Philipp
P
Stammler
Hans-Georg
HG
Neumann
Beate
B