Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution.
A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.
Sastri
Chivukula V
CV
Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womens University, Seoul 120-750, Korea.
Sook Seo
Mi
M
Joo Park
Mi
M
Mook Kim
Kwan
K
Nam
Wonwoo
W
D006863:Hydrogen-Ion Concentration; D007501:Iron / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry; D019159:Nonheme Iron Proteins / Q000737:chemistry*; D010084:Oxidation-Reduction; D012996:Solutions / Q000737:chemistry; D013440:Sulfides / Q000737:chemistry*; D014867:Water / Q000737:chemistry
D019159:Nonheme Iron Proteins; D012996:Solutions; D013440:Sulfides; D014867:Water; C066317:ferryl iron; D007501:Iron; D009584:Nitrogen