title: Tunneling characteristics of octadecyl derivatives on tin and indium electrodes.
abstract: In this paper we report the tunneling behavior based on the capillary tunnel junctions of n-octadecylmercaptan (C18H37SH), octadecylamine (C18H37NH2), nonadecanoic acid (C17H35COOH), octadecanol (C18H370H), and n-iodooctadecane (C18H37I), sandwiched between tin and indium electrodes utilizing the naturally existing oxide surfaces, respectively. The surfaces of the electrodes were examined by X-ray diffraction (XRD), atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS) methods, and the self-assembled monolayers adsorbed on the electrode surfaces were inspected by contact angle measurements and XPS. The measured characteristic curves on tin electrode indicated a sequence of energy gaps associated with the specimen: deltaC17H35COOH > deltaC18H37OH > deltaC18H37SH > deltaC18H37NH2 > deltaC18lH37I. The results on the energy gaps obtained on indium electrodes displayed similar sequence behavior although with different gap values. The experimental observations indicate that the molecule-electrode contact, including both the functional groups and substrates, could contribute jointly to the overall conductance characteristics of molecular junctions.
authors.affiliation: Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080 China.
authors.forename: Yuhong
authors.initials: Y
authors.lastname: Liu
authors.forename: Xiaolin
authors.initials: X
authors.lastname: Fan
authors.forename: Deliang
authors.initials: D
authors.lastname: Yang
authors.forename: Chen
authors.initials: C
authors.lastname: Wang
authors.forename: Lijun
authors.initials: L
authors.lastname: Wan
authors.forename: Chunli
authors.initials: C
authors.lastname: Bai