title: Routes to N,N'-unsymmetrically substituted 1,3-diketimines.
abstract: [reaction: see text] A series of novel N,N'-unsymmetrically substituted 1,3-diketimines (3, 12, and 27) have been synthesized from the reaction of exocyclic enaminoketones 8 with amines or metalloenamines (from 13 or 14) with imidoyl thioether 25 or 26.
authors.affiliation: Materials Science and Engineering, Central Research and Development, DuPont, Experimental Station, Wilmington, Delaware 19880-0328, USA.
authors.forename: Kyung-Ho
authors.initials: KH
authors.lastname: Park
authors.forename: Will J
authors.initials: WJ
authors.lastname: Marshall
mesh_terms: D000588:Amines / Q000737:chemistry; D018360:Crystallography, X-Ray; D007097:Imines / Q000138:chemical synthesis*; D008956:Models, Chemical; D015394:Molecular Structure
chemical_list: D000588:Amines; D007097:Imines