Molecular salts with diquat-based electron acceptors for nonlinear optics.
We have used several techniques, including Stark spectroscopy and MO calculations, to investigate the optical and electronic properties of two new dipolar chromophoric cations containing diquat-based electron acceptor groups. Both the Stark data and the calculated parameters show that the strong electron-accepting properties of a diquat unit lead to static first hyperpolarizabilities beta0 which are considerably larger than those of a related stilbazolium chromophore. In addition, one compound has a strongly 2D quadratic NLO response, providing a very rare example of a charged molecule displaying such behavior.
Coe
Benjamin J
BJ
School of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK. b.coe@man.ac.uk
Harris
James A
JA
Brunschwig
Bruce S
BS
Garín
Javier
J
Orduna
Jesús
J