Nickel catalysed asymmetric cycloisomerisation of diethyl diallylmalonate.
Cationic nickel catalysts with monodentate phosphoramidites and Wilke's azaphospholene as ligands are highly regio- and enantioselective catalysts for the cycloisomerisation of diethyl diallylmalonate.
Böing
Christian
C
Institut für Technische und Makromolekulare Chemie, Aachen, Germany.
Franciò
Giancarlo
G
Leitner
Walter
W
D002384:Catalysis; D003500:Cyclization; D008024:Ligands; D008314:Malonates / Q000737:chemistry*; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry; D013237:Stereoisomerism
D008024:Ligands; D008314:Malonates; D009943:Organophosphorus Compounds; C429244:diethyl diallylmalonate; C434331:phosphoramidite; D009532:Nickel