Routes to N,N'-unsymmetrically substituted 1,3-diketimines.
[reaction: see text] A series of novel N,N'-unsymmetrically substituted 1,3-diketimines (3, 12, and 27) have been synthesized from the reaction of exocyclic enaminoketones 8 with amines or metalloenamines (from 13 or 14) with imidoyl thioether 25 or 26.
Park
Kyung-Ho
KH
Materials Science and Engineering, Central Research and Development, DuPont, Experimental Station, Wilmington, Delaware 19880-0328, USA.
Marshall
Will J
WJ
D000588:Amines / Q000737:chemistry; D018360:Crystallography, X-Ray; D007097:Imines / Q000138:chemical synthesis*; D008956:Models, Chemical; D015394:Molecular Structure
D000588:Amines; D007097:Imines