[Synthesis and spectral properties of tailed sercine tetraphenylporphyrin cobalt complex].
A new tailed sercine tetraphenylporphinatozinc, 5-(p-butoxyphenyl-10,15,20-trichlorophenyl)porphine and cobalt complex (Co[Ser-TPP]) was synthesized and characterized by elementary analysis, UV, IR, 1HNMR and Raman spectra. The electronic absorption spectra of axial coordination reactions of Co[Ser-TPP] with pyridine, 4-methylpyridine, 4-aminopyridine, 4,4-bipyridine, imidazole, 1-methylimidazole and 2-methylimidazole were inverstigated. The results showed that the changes of electronic absorption spectra of Co[Ser-TPP] could be attributed to the axial coordination reactions of Co[Ser-TPP] with pyridine and imidazole series.
Ni
Chun-lin
CL
College of Chemistry and Life Science, Three Gorges University, Yichang 443003, China.
Zhou
Chun-qiong
CQ
Zhou
Yu
Y
He
Zhi-ke
ZK
Yuan
Liang-jie
LJ
D003035:Cobalt / Q000737:chemistry*; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D013057:Spectrum Analysis
D011166:Porphyrins; C409084:tetraphenylporphyrin; D003035:Cobalt