Accumulation of organochlorine pesticides from water using triolein embedded cellulose acetate membranes.
A new type of composite membrane, triolein embedded cellulose acetate membrane (TECAM), was produced by embedding triolein drops in the matrix of cellulose acetate polymers. The distribution of six organochlorine pesticides (OCPs) between water and TECAM was investigated in a static water system. Its field application was tested in Taihu Lake (China). Results from both laboratory and field experiments indicate that TECAM quickly and efficiently accumulated hydrophobic OCPs from water. Under laboratory conditions, uptake equilibrium was achieved within 24 h for all of the six OCPs. Significant correlations were obtained between log Kp TECAM (TECAM-water partition coefficient) and log Kow (octanol-water partition coefficient); between log Ktw (triolein-water partition coefficient, triolein in TECAM) and log Kow; and between log Ktw and log BCF (bioconcentration factor in rainbow trout calculated from literatures). Triolein in TECAM significantly increased the accumulation of strongly hydrophobic OCPs when compared to the use of cellulose acetate polymers alone. Temperature had only slight effects on the Kp TECAM values of the strongly hydrophobic OCPs. The partition coefficient obtained by measuring OCP concentrations in TECAM under field conditions could be successfully applied to estimate OCPs concentrations in surface water.
Xu
Yiping
Y
State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.
Wang
Zijian
Z
Ke
Runhui
R
Khan
Shahamat U
SU
D000818:Animals; D002482:Cellulose / Q000031:analogs & derivatives* / Q000737:chemistry*; D002681:China; D004784:Environmental Monitoring; D006843:Hydrocarbons, Chlorinated / Q000032:analysis* / Q000378:metabolism; D057927:Hydrophobic and Hydrophilic Interactions; D008567:Membranes, Artificial; D010575:Pesticides / Q000032:analysis* / Q000378:metabolism; D013696:Temperature; D014304:Triolein / Q000737:chemistry*; D014867:Water / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000378:metabolism
D006843:Hydrocarbons, Chlorinated; D008567:Membranes, Artificial; D010575:Pesticides; D014874:Water Pollutants, Chemical; D014867:Water; D014304:Triolein; C005062:acetylcellulose; D002482:Cellulose