Some characteristics of 3,7-dinitro-, 3,7-dinitroso- and dinitrate compounds derived from 1,3,5,7-tetraazabicyclo[3.3.1]nonane.
The paper presents a set of some literature data and the authors' own experimental results of stability, sensitivity and explosion parameters of energetic Mannich N-bases, 3,7-dinitro-1,3,5,7-tetraazabicyclo[3.3.1]nonane (DPT), 3,7-dinitroso-1,3,5,7-tetraazabicyclo[3.3.1]nonane (DNPT) and hexamethylenetetramine dinitrate (HEXADI). Both their chemical and thermal reactivities are discussed. The results of small-scale cook-off test, determination of initiation ability, detonation velocity, impact sensitivity and performance show that the lowest process safety risks are connected with HEXADI.
Vágenknecht
Jirí
J
Department of Theory and Technology of Explosives (DTTX), University of Pardubice, CZ-53210 Pardubice, Czech Republic. jiri.vagenknecht@upce.cz
Zeman
Svatopluk
S
D000473:Alkanes / Q000737:chemistry*; D005107:Explosions; D009603:Nitroso Compounds / Q000737:chemistry*; D018570:Risk Assessment; D012449:Safety
D000473:Alkanes; D009603:Nitroso Compounds; C017573:nonane