title: [In situ raman spectroscopic study on the oxidation of HCHO on a roughened platinum electrode].
abstract: The electrooxidation behavior of HCHO on a roughened platinum electrode was studied by cyclic voltammetry. Two factors that influence the electrooxidation behavior of HCHO, i.e. the concentration of the supporting electrolyte and the structure of the electrode surface were taken into account. The dissociative adsorption behavior of HCHO on a roughened platinum electrode was investigated by confocal microprobe Raman spectroscopy in-situ, and the spontaneous dissociative adsorption behavior of HCHO on a roughened platinum electrode was found by CV and was confirmed at the molecule level by in-situ Raman spectra.
authors.affiliation: Department of Science, Tianjin University of Science and Technology, Tianjin, China.
authors.forename: Xiao-cong
authors.initials: XC
authors.lastname: Wang
authors.forename: Xiao-qiong
authors.initials: XQ
authors.lastname: Su
authors.forename: Qi-ling
authors.initials: QL
authors.lastname: Zhong
authors.forename: Xi-gen
authors.initials: XG
authors.lastname: Huang
authors.forename: Bin
authors.initials: B
authors.lastname: Ren
authors.forename: Juan
authors.initials: J
authors.lastname: Xiang
authors.forename: Zhong-qun
authors.initials: ZQ
authors.lastname: Tian
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D004566:Electrodes; D008027:Light; D010084:Oxidation-Reduction; D010984:Platinum / Q000737:chemistry*; D013059:Spectrum Analysis, Raman / Q000379:methods*
chemical_list: D000447:Aldehydes; D010984:Platinum