title: [Synthesis and spectral properties of tailed sercine tetraphenylporphyrin cobalt complex].
abstract: A new tailed sercine tetraphenylporphinatozinc, 5-(p-butoxyphenyl-10,15,20-trichlorophenyl)porphine and cobalt complex (Co[Ser-TPP]) was synthesized and characterized by elementary analysis, UV, IR, 1HNMR and Raman spectra. The electronic absorption spectra of axial coordination reactions of Co[Ser-TPP] with pyridine, 4-methylpyridine, 4-aminopyridine, 4,4-bipyridine, imidazole, 1-methylimidazole and 2-methylimidazole were inverstigated. The results showed that the changes of electronic absorption spectra of Co[Ser-TPP] could be attributed to the axial coordination reactions of Co[Ser-TPP] with pyridine and imidazole series.
authors.affiliation: College of Chemistry and Life Science, Three Gorges University, Yichang 443003, China.
authors.forename: Chun-lin
authors.initials: CL
authors.lastname: Ni
authors.forename: Chun-qiong
authors.initials: CQ
authors.lastname: Zhou
authors.forename: Yu
authors.initials: Y
authors.lastname: Zhou
authors.forename: Zhi-ke
authors.initials: ZK
authors.lastname: He
authors.forename: Liang-jie
authors.initials: LJ
authors.lastname: Yuan
mesh_terms: D003035:Cobalt / Q000737:chemistry*; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D013057:Spectrum Analysis
chemical_list: D011166:Porphyrins; C409084:tetraphenylporphyrin; D003035:Cobalt