title: Sorption and desorption of perchlorate and U(VI) by strong-base anion-exchange resins.
abstract: This study investigated the sorption affinity and capacity of six strong-base anion-exchange (SBA) resins for both uranium [U(VI)] and perchlorate (ClO4-) in simulated groundwater containing varying concentrations of sulfate (SO4(2-)). Additionally, desorption of U(VI) from spent resins was studied to separate U(VI) from resins with sorbed ClO4- for waste segregation and minimization. Results indicate that all SBA resins investigated in this study strongly sorb U(VI). The gel-type polyacrylic resin (Purolite A850) showed the highest sorption affinity and capacityfor U(VI) butwasthe least effective in sorbing ClO4-. The presence of SO4(2-) had little impact on the sorption of U(VI) but significantly affected the sorption of ClO4-, particularly on monofunctional SBA resins. A dilute acid wash was found to be effective in desorbing U(VI) but ineffective in desorbing ClO4- from bifunctional resins (Purolite A530E and WBR109). A single wash removed approximately 75% of sorbed U(VI) but only approximately 0.1% of sorbed ClO4- from the bifunctional resins. On the other hand, only 21.4% of sorbed U(VI) but approximately 34% of sorbed ClO4- was desorbed from the Purolite A850 resin. This study concludes that bifunctional resins could be used effectively to treatwater contaminated with ClO4- and traces of U(VI), and dilute acid washes could minimize hazardous wastes by separating sorbed U(VI) from ClO4- prior to the regeneration of the spent resin loaded with ClO4-.
authors.affiliation: Environmental Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, USA. gub1@ornl.gov
authors.forename: Baohua
authors.initials: B
authors.lastname: Gu
authors.forename: Yee-Kyoung
authors.initials: YK
authors.lastname: Ku
authors.forename: Gilbert M
authors.initials: GM
authors.lastname: Brown
mesh_terms: D000837:Anion Exchange Resins; D006863:Hydrogen-Ion Concentration; D010472:Perchlorates / Q000737:chemistry* / Q000302:isolation & purification*; D014865:Waste Disposal, Fluid; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods
chemical_list: D000837:Anion Exchange Resins; D010472:Perchlorates; D014874:Water Pollutants, Chemical; C494474:perchlorate