One-pot sequential synthesis of acetoxylated [60]fullerene derivatives.
[reaction: see text] The reaction of [60]fullerene with 4-substituted phenylhydrazine hydrochlorides in refluxing chlorobenzene under aerobic conditions afforded 1-(4-substituted phenyl)-1,2-dihydro[60]fullerenes, which could be subsequently oxidized to 1-acetoxyl-4-aryl-1,4-dihydro[60]fullerenes by manganese(III) acetate dihydrate in one pot. The transformation of ArC(60)-H to ArC(60)-OAc has been realized with Mn(OAc)(3).2H(2)O for the first time.
Chen
Zhong-Xiu
ZX
Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
Wang
Guan-Wu
GW
D019342:Acetic Acid / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D017895:Manganese Compounds / Q000737:chemistry; D008968:Molecular Conformation
D037741:Fullerenes; D017895:Manganese Compounds; C069837:fullerene C60; D019342:Acetic Acid