A chiral layered Co(II) coordination polymer with helical chains from achiral materials.
A layered coordination polymer Co(PDC)(H2O)2.H2O containing two helical chains was synthesized, and the resultant crystals were not racemic as evidenced by the observation of strong signals in vibrational circular dichroism (VCD) spectra.
Tian
Ge
G
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Department of Chemistry, Jilin University, Changchun, 130012, China.
Zhu
Guangshan
G
Yang
Xiaoyu
X
Fang
Qianrong
Q
Xue
Ming
M
Sun
Jinyu
J
Wei
Yan
Y
Qiu
Shilun
S
D002942:Circular Dichroism; D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008956:Models, Chemical; D015394:Molecular Structure; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism
D011108:Polymers; D003035:Cobalt