Octacyanometallate-based single-molecule magnets: Co(II)9M(V)6 (M = W, Mo).
Two octacyanometallate-based clusters, {CoII9[WV(CN)8]6.(CH3OH)24}.19H2O (1) and {CoII9[MoV(CN)8]6.(CH3OH)24}.4CH3OH.16H2O (2), have been synthesized. Both complexes show the single-molecule magnet behavior.
Song
You
Y
Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China. yousong@nju.edu.cn
Zhang
Peng
P
Ren
Xiao-Ming
XM
Shen
Xiao-Fei
XF
Li
Yi-Zhi
YZ
You
Xiao-Zeng
XZ