title: Inhibition of the electrochemistry of ferrocenes by polyamine dendrimers and the key role of hydrogen-bonding with hydroxy groups.
abstract: Commercial DSM polyamine dendrimers inhibit the observation of the cyclic voltammetry (CV) of simple ferrocenes all the more as they are larger (marked dendritic effect); the CV is re-established, however, if a OH-containing group is present in the ferrocene derivative.
authors.affiliation: Nanosciences and Catalysis Group, LCOO, UMR CNRS No 5802, Université Bordeaux I, 33405, Talence Cedex, France.
authors.forename: Marie-Christine
authors.initials: MC
authors.lastname: Daniel
authors.forename: Jaime
authors.initials: J
authors.lastname: Ruiz Aranzaes
authors.forename: Didier
authors.initials: D
authors.lastname: Astruc
mesh_terms: D050091:Dendrimers / Q000737:chemistry*; D004563:Electrochemistry; D005296:Ferrous Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D000075163:Metallocenes; D011073:Polyamines / Q000737:chemistry*
chemical_list: D050091:Dendrimers; D005296:Ferrous Compounds; D000075163:Metallocenes; D011073:Polyamines; C004998:ferrocene