title: Dibenzo[a,d]cycloheptenyl dibenzophosphole palladium dichloride: synthesis, X-ray-crystal structure and application in the Suzuki-Miyaura coupling.
abstract: A highly rigid dibenzo[a,d]cycloheptenyl dibenzophosphole with a pre-organized concave shaped binding site acts as an efficient ligand in the palladium catalyzed Suzuki-Miyaura coupling process between halogenoaromatics and phenylboronic acid.
authors.affiliation: Department of Chemistry, Laboratory Hétéroéléments et Coordination UMR CNRS 7653, Ecole Polytechnique, 91128, Palaiseau cedex, France.
authors.forename: Claire
authors.initials: C
authors.lastname: Thoumazet
authors.forename: Louis
authors.initials: L
authors.lastname: Ricard
authors.forename: Hansjorg
authors.initials: H
authors.lastname: Grützmacher
authors.forename: Pascal
authors.initials: P
authors.lastname: Le Floch