Spontaneous resolution in a halogen bonded supramolecular architecture.
The halogen bonding driven self-assembly of 1,8-diiodoperfluorooctane and N,N,N',N'-tetramethyl-p-phenylenediamine induces the formation of a chiral and enantiopure co-crystal wherein the fluorinated chains adopt an unusual gauche arrangement.
Neukirch
Hannes
H
NFMLab-Department of Chemistry, Materials and Chemical Engineering G. Natta, Polytechnic of Milan, Via L. Mancinelli 7, 20131, Milan, Italy.
Guido
Emanuela
E
Liantonio
Rosalba
R
Metrangolo
Pierangelo
P
Pilati
Tullio
T
Resnati
Giuseppe
G