title: Spontaneous resolution in a halogen bonded supramolecular architecture.
abstract: The halogen bonding driven self-assembly of 1,8-diiodoperfluorooctane and N,N,N',N'-tetramethyl-p-phenylenediamine induces the formation of a chiral and enantiopure co-crystal wherein the fluorinated chains adopt an unusual gauche arrangement.
authors.affiliation: NFMLab-Department of Chemistry, Materials and Chemical Engineering G. Natta, Polytechnic of Milan, Via L. Mancinelli 7, 20131, Milan, Italy.
authors.forename: Hannes
authors.initials: H
authors.lastname: Neukirch
authors.forename: Emanuela
authors.initials: E
authors.lastname: Guido
authors.forename: Rosalba
authors.initials: R
authors.lastname: Liantonio
authors.forename: Pierangelo
authors.initials: P
authors.lastname: Metrangolo
authors.forename: Tullio
authors.initials: T
authors.lastname: Pilati
authors.forename: Giuseppe
authors.initials: G
authors.lastname: Resnati