Anion-assisted trans-cis isomerization of palladium(II) phosphine complexes containing acetanilide functionalities through hydrogen bonding interactions.
The anion-assisted shift of trans-cis isomerization equilibrium of a palladium(II) complex containing acetanilide functionalities brought about by allosteric hydrogen bonding interactions has been established by UV/Vis, 1H NMR, 31P NMR and ESI-MS studies.
Lu
Xiao-Xia
XX
Department of Chemistry, Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, University of Hong Kong, Hong Kong, P. R. China.
Tang
Hau-San
HS
Ko
Chi-Chiu
CC
Wong
Jenny Ka-Yan
JK
Zhu
Nianyong
N
Yam
Vivian Wing-Wah
VW
D000083:Acetanilides / Q000737:chemistry*; D000838:Anions; D006860:Hydrogen Bonding; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry* / Q000378:metabolism; D010720:Phosphines / Q000737:chemistry* / Q000378:metabolism; D013057:Spectrum Analysis; D013237:Stereoisomerism
D000083:Acetanilides; D000838:Anions; D010720:Phosphines; D010165:Palladium; C044646:phosphine; C508827:acetanilide