Synthesis of 1,10-N,N'-phenanthroline dioxides using HOF.CH(3)CN complex.
[reaction: see text] HOF.CH(3)CN, a very efficient oxygen-transfer agent, made readily from F(2), H(2)O, and CH(3)CN, was reacted with various 1,10-phenanthroline derivatives to form the corresponding N,N'-dioxides in good yields and short reaction times.
Carmeli
Mira
M
School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel-Aviv University, Tel-Aviv 69978, Israel.
Rozen
Shlomo
S
D000097:Acetonitriles / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D015394:Molecular Structure; D010087:Oxides / Q000138:chemical synthesis*; D010618:Phenanthrolines / Q000138:chemical synthesis*
D000097:Acetonitriles; D010087:Oxides; D010618:Phenanthrolines; D005461:Fluorine; D006859:Hydrogen