[Synthesis and spectral properties of L-amino acid tailed porphyrin and their zinc(II) complexes].
Three new L-amino acid tailed porphyrins and their zinc(II) complexes were synthesized by L-amino acid and 5-[o-(bromnoethoxyl)phenyl]-10,15,20-triphenyl prophyrin. FABMS, UV-Vis, IR, elemental analysis and chemical analysis were used to determine the structures of these porphyrins and their zinc complexes. The FTIR spectra (4000-400 cm(-1)) of L-amino acid tailed porphyrin and its zinc(II) complexes were measured and investigated. The major bands have been empirically assigned in comparison with L- amino acid tailed porphyrin and its zinc(II) complexes.
Luo
Guo-tian
GT
Department of Chemistry and Life Science, Gannan Teachers' College, Ganzhou 341000, China.
Teng
Li-li
LL
Lai
Xiao-qi
XQ
Li
Lei
L
D000596:Amino Acids / Q000737:chemistry; D004563:Electrochemistry / Q000379:methods; D011166:Porphyrins / Q000138:chemical synthesis / Q000737:chemistry*; D013055:Spectrophotometry, Infrared / Q000379:methods*; D013056:Spectrophotometry, Ultraviolet / Q000379:methods*; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods; D015032:Zinc / Q000737:chemistry*
D000596:Amino Acids; D011166:Porphyrins; D015032:Zinc