Diethyl [(Z)-1-iodo-2-phenyl-1-hexenyl]phosphonate.
The crystal structure of the title compound, C16H24IO3P, is composed of independent molecules, in which one of the phosphonate ethoxy groups is disordered over two positions. The other ethoxy group lies sandwiched between two phenyl rings and, as a result, is ordered. This constrained environment also leads to two C-H...centroid interactions, one intra- and one intermolecular. Examination of the extended structure reveals the presence of chains of molecules held together by I...O interactions.
Mbianda
Xavier Y
XY
Faculty of Engineering, School of Applied Sciences, Department of Analytical Chemistry, Technikon Witwatersrand (University of Johannesburg), PO Box 17011, Doornfontein 2028, South Africa. xavimba@twr.ac.za
Fernandes
Manuel A
MA
D001555:Benzene Derivatives / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008958:Models, Molecular; D008968:Molecular Conformation; D063065:Organophosphonates / Q000737:chemistry*; D014753:Vinyl Compounds / Q000737:chemistry*
D001555:Benzene Derivatives; D063065:Organophosphonates; D014753:Vinyl Compounds