title: Synthesis and efficiency of a spherical macroporous epoxy-polyamide chelating resin for preconcentrating and separating trace noble metal ions.
abstract: The determination of noble metals in various materials usually requires their preconcentration and separation from other elements. In spite of the improvements in analytical instrumentation and the development of new analytical techniques such as ICP-MS, which are capable of detecting metal ions at ppt levels, the interference caused by the sample matrix still exists and is perhaps the most serious problem, making a pre-determination enrichment step necessary. Thus, the search for efficient preconcentration and separation methods is essential. A series of chelating resins that can selectively adsorb noble metal ions from aqueous solutions have been described. Functional groups, such as salicylaldoxime and thiosemicarbazide have been incorporated in cross-linked polymers or porous silica gel. These resins have very high selectivity for one or several types of noble metal ion. However, desorption of noble metals from these resins is usually difficult. Hence, the development of an adsorbent from which noble metals can be easily desorbed is needed. In this paper, a new spherical macroporous epoxy-polyamide chelating resin that met this requirement was synthesized by one step reaction. The synthesis of the resin was safe, rapid and more simple and economical than many report adsorbents. Meanwhile, the resin showed more advantages: better acid and alkali resistance; higher adsorption capacity and lower preconcentration concentrations. A resin column procedure combined with inductively coupled plasma atomic emission spectrometry (ICP-AES) for the determination of trace Rh(III), Ru(III) and Ir(IV) in real samples was established.
authors.affiliation: Department of Chemistry, Lanzhou University, Lanzhou 730000, PR China.
authors.forename: Dong
authors.initials: D
authors.lastname: Yang
authors.forename: Xijun
authors.initials: X
authors.lastname: Chang
authors.forename: Yongwen
authors.initials: Y
authors.lastname: Liu
authors.forename: Sui
authors.initials: S
authors.lastname: Wang
mesh_terms: D002614:Chelating Agents / Q000138:chemical synthesis* / Q000737:chemistry; D004853:Epoxy Resins / Q000138:chemical synthesis* / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007495:Iridium / Q000302:isolation & purification*; D009757:Nylons / Q000138:chemical synthesis* / Q000737:chemistry; D016062:Porosity; D012238:Rhodium / Q000302:isolation & purification*; D012428:Ruthenium / Q000302:isolation & purification*; D012680:Sensitivity and Specificity; D013054:Spectrophotometry, Atomic
chemical_list: D002614:Chelating Agents; D004853:Epoxy Resins; D009757:Nylons; C015461:polyamide epoxy; D007495:Iridium; D012428:Ruthenium; D012238:Rhodium