Electrically anisotropic thin films consisting of polymeric and metallic nanolayers from self-assembled lamellae of diblock copolymers.
We demonstrated the fabrication of electrically anisotropic thin films of alternating polymeric layers and metallic layers in nanometer thickness by utilizing self-assembled nanodomains of symmetric diblock copolymers. Nanometer-thick metal layers macroscopically parallel to the film plane were synthesized by electroless Ag deposition on Au nanoparticles selectively in one of the blocks. Every Ag/Au layer was completely separated by nanometer-thick polymer layers in the direction perpendicular to the film plane. Therefore, the conductivity of the film was highly anisotropic, differing by at least 8 orders of magnitude in directions parallel and perpendicular to the film plane, even though the in-plane conductivity (2.8 x10(-6) S/cm) was in the range of semiconductors. If self-assembled nanodomains of diblock copolymers were not employed, a serial layer-by-layer process for each layer would be required to fabricate such an electrically anisotropic thin film.
Yun
Sang-Hyun
SH
Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang 790-784, Korea.
Yoo
Seong Min
SM
Sohn
Byeong-Hyeok
BH
Jung
Jin Chul
JC
Zin
Wang-Cheol
WC
Kwak
Seung-Yeop
SY
Lee
Taek Seung
TS