title: Vibrational and electronic circular dichroism of delta-TRISPHAT [tris(tetrachlorobenzenediolato)phosphate(V)] anion.
abstract: Herein is reported an experimental and theoretical study of the circular dichroism properties of TRISPHAT (1) anion. ECD analysis of the [tetramethylammonium][delta-1] salt confirms the absolute configuration assignment obtained through X-ray crystallographic analysis of the parent cinchonidium salt. The structure, infrared, and vibrational circular dichroism (VCD) spectra derived from density functional theory (DFT) calculations are compared with experimental data.
authors.affiliation: Département de Chimie Organique, Université de Genève, Genève, Switzerland.
authors.forename: Delphine
authors.initials: D
authors.lastname: Bas
authors.forename: Thomas
authors.initials: T
authors.lastname: Bürgi
authors.forename: Jérôme
authors.initials: J
authors.lastname: Lacour
authors.forename: Jérôme
authors.initials: J
authors.lastname: Vachon
authors.forename: Jacques
authors.initials: J
authors.lastname: Weber