title: Synthesis, characterization, physicochemical, and photophysical studies of redox switchable NIR dye derived from a ruthenium-dioxolene-porphyrin system.
abstract: Newly synthesized semi-quinone derivatives of the ruthenium polypyridyl, covalently linked to a porphyrin core, show very high epsilon values (59,000-83,500 M(-1)cm(-1)) for the absorption band in the near infrared (NIR) region of the spectrum. Further, complexes 1-4 show an interesting reversible electrochromic behavior as a function of the redox state of the coordinated dioxolene functionality, and a switching phenomenon between bleaching and the restoration of the NIR peak could be achieved electrochemically. Thus, complexes 1-4 could be ideal candidate materials for NIR-active electrochromic devices. Ultrafast studies on 1 and its mononuclear components, 5-(3,4-dihydroxyphenyl)-10,15,20-triphenyl-21H,23H-porphyrin (H2L1) and Ru(bpy)2(bsq)+, reveal that there is no electron or energy transfer from the porphyrin to the Ru(bpy)2sq+ (bpy is 2,2'-bipyridine and sq is the deprotonated species of a substituted semi-quinone fragment) fragment or vice versa in 1. The observed decrease in the luminescence quantum yield for 1 compared to that of H2L1 can be ascribed to the increased nonradiative pathway due to higher vibronic coupling because of the direct linkage of the metal center to the porphyrin moiety.
authors.affiliation: Central Salt and Marine Chemicals Research Institute, Bhavnagar 364 002, Gujarat, India.
authors.forename: D Amilan
authors.initials: DA
authors.lastname: Jose
authors.forename: Atindra D
authors.initials: AD
authors.lastname: Shukla
authors.forename: D Krishna
authors.initials: DK
authors.lastname: Kumar
authors.forename: Bishwajit
authors.initials: B
authors.lastname: Ganguly
authors.forename: Amitava
authors.initials: A
authors.lastname: Das
authors.forename: G
authors.initials: G
authors.lastname: Ramakrishna
authors.forename: Dipak K
authors.initials: DK
authors.lastname: Palit
authors.forename: Hirendra N
authors.initials: HN
authors.lastname: Ghosh