2-Phosphinophenolate complexes: formation and crystal structure of a novel trinuclear mu-O nickel(II)-tris(P(intersection)O-chelate).
A novel linear trinuclear mu-O-bridging 2-phosphinophenolate nickel(II) complex with fac-tris(P(intersection)O- chelates) in the terminal positions and the three oxygen atoms each facing the central nickel(II) cation was synthesized and structurally characterized by X-ray crystallography. To the best of our knowledge, this is the first example of an octahedral Ni(II) tris(P(intersection)O- chelate).
Heinicke
Joachim
J
Institut für Chemie und Biochemie, Ernst-Moritz-Arndt-Universität Greifswald, D-17487 Greifswald, Germany. heinicke@uni-greifswald.de
Peulecke
Normen
N
Karaghiosoff
Konstantin
K
Mayer
Peter
P