title: Reversible O-O bond cleavage and formation of a peroxo moiety of a peroxocarbonate ligand mediated by an iron(III) complex.
abstract: A mononuclear iron(III) complex containing a peroxocarbonate ligand, [Fe(qn)2(O2C(O)O)]- (qn = quinaldinate), underwent the reversible O-O bond cleavage and reformation of the peroxo group via the formation of FeIV=O or FeV=O species, which was confirmed by the resonance Raman and ESI-TOF/MS measurements.
authors.affiliation: Department of Chemistry, Faculty of Science, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
authors.forename: Hideki
authors.initials: H
authors.lastname: Furutachi
authors.forename: Koji
authors.initials: K
authors.lastname: Hashimoto
authors.forename: Shigenori
authors.initials: S
authors.lastname: Nagatomo
authors.forename: Taichi
authors.initials: T
authors.lastname: Endo
authors.forename: Shuhei
authors.initials: S
authors.lastname: Fujinami
authors.forename: Yoshihito
authors.initials: Y
authors.lastname: Watanabe
authors.forename: Teizo
authors.initials: T
authors.lastname: Kitagawa
authors.forename: Masatatsu
authors.initials: M
authors.lastname: Suzuki