One-pot acetalation-acetylation of sugar derivatives employing perchloric acid immobilised on silica.
Perchloric acid immobilised on silica gel has been used as an efficient promoter for per-O-acetylation, and acetalation and subsequent O-acetylation of glycosides and thioglycosides in one-pot using stoichiometric reagents.
Mukhopadhyay
Balaram
B
Centre for Carbohydrate Chemistry, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich NR4 7TJ, UK. a.mukhopadhyay@uea.ac.uk
Russell
David A
DA
Field
Robert A
RA
D000080:Acetals / Q000737:chemistry*; D000107:Acetylation; D000475:Alkenes / Q000737:chemistry; D001597:Benzylidene Compounds / Q000737:chemistry; D002241:Carbohydrates / Q000737:chemistry*; D015394:Molecular Structure; D010472:Perchlorates / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry*
D000080:Acetals; D000475:Alkenes; D001597:Benzylidene Compounds; D002241:Carbohydrates; D010472:Perchlorates; D012822:Silicon Dioxide; C013658:propylene