Synthesis of nearly monodisperse embedded nanoparticles by separating nucleation and growth in ion implantation.
We investigate the formation of nanoparticles of Au in SiO(2) by multiple ion implantation steps and intermediate anneals to isolate nucleation and growth, thereby producing a narrow particle size distribution. We discuss the effects of varying the initial nucleation dose and the growth temperature and establish guidelines for synthesizing nanoparticles with improved size uniformity. By this method, we have obtained a standard deviation of 16% on an average diameter of 1.68 nm, compared to 28% when no attempt is made to isolate nucleation and growth.
Ramaswamy
Vidya
V
Division of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts, USA.
Haynes
Tony E
TE
White
C Woody
CW
MoberlyChan
Warren J
WJ
Roorda
Sjoerd
S
Aziz
Michael J
MJ
D003460:Crystallization / Q000379:methods*; D006046:Gold / Q000737:chemistry*; D007477:Ions; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods*; D010316:Particle Size; D012822:Silicon Dioxide / Q000737:chemistry*; D013696:Temperature
D007477:Ions; D006046:Gold; D012822:Silicon Dioxide