Headgroup effects on phase behavior and interfacial properties of beta-3,7-dimethyloctylglycoside/water systems.
The aqueous phase behavior and the interfacial properties of alkylglycosides, AGs, with a 3,7-dimethyloctyl (geranyl) chain have been investigated as a function of the number of glucose units, N, in the maltooligosaccharide headgroup. The results can be interpreted in terms of a "helical conformation" of the maltooligosaccharide, where the cross section area increases as N increases.
Minamikawa
Hiroyuki
H
Nanotechnology Research Institute, National Institute of Advanced Industrial Science and Technology, Tsukuba Central-5, Higashi 1-1-1, Tsukuba, Ibaraki 305-8565, Japan. hiroyuki.minamikawa@aist.go.jp
Hato
Masakatsu
M
D002236:Carbohydrate Conformation; D006027:Glycosides / Q000737:chemistry*; D009844:Oligosaccharides / Q000737:chemistry*; D044367:Phase Transition; D012542:Scattering, Radiation; D013729:Terpenes / Q000737:chemistry*; D014965:X-Rays
D006027:Glycosides; D009844:Oligosaccharides; D013729:Terpenes; C021705:maltooligosaccharides