Core-shell nanostructures from single poly(N-vinylcaprolactam) macromolecules: stabilization and visualization.
Formation of core-shell poly(N-vinylcaprolactam) (PVCL) single-molecule nanostructures due to interaction of PVCL with metal ions was studied using transmission electron microscopy, 13C NMR, and light scattering. This study demonstrates that addition of CoCl2 to PVCL in its globular conformation yields unimolecular core-shell polymer particles with the core decorated with Co(II) ions. The crucial condition for formation of well-defined unimolecular nanostructures is the presence of stable globular aggregates in aqueous solution. Moreover, the metal ions should have a sufficiently high coordination number (higher than 2) to provide a cross-linking and stabilization of the core.
Bronstein
Lyudmila M
LM
Deparment of Chemistry, Indiana University, Bloomington, Indiana 47405, USA. lybronst@indiana.edu
Kostylev
Maxim
M
Tsvetkova
Irina
I
Tomaszewski
John
J
Stein
Barry
B
Makhaeva
Elena E
EE
Okhapkin
Ivan
I
Khokhlov
Alexei R
AR
D002209:Caprolactam / Q000031:analogs & derivatives* / Q000737:chemistry; D003102:Colloids / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D046529:Microscopy, Electron, Transmission; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D011108:Polymers / Q000737:chemistry*; D012996:Solutions; D013696:Temperature; D014867:Water / Q000737:chemistry
D003102:Colloids; D011108:Polymers; D012996:Solutions; D014867:Water; C086861:poly-N-vinylcaprolactam; D002209:Caprolactam