Mild and efficient oxidation of alcohols with sodium periodate catalyzed by polystyrene-bound Mn(III)porphyrin.
Mild and efficient oxidation of primary and secondary alcohols with sodium periodate catalyzed by Mn(TPyP), [manganese(III)tetra(4-pyridyl)porphyrin], supported on chloromethylated polystyrene, [Mn(TPyP)-CMP], at room temperature were reported. This catalyst can be reused consecutively four times in the oxidation of 4-chlorobenzyl alcohol in 97% yield without significant loss of its activity.
Moghadam
Majid
M
Department of Chemistry, Yasouj University, Yasouj 75914-353, Iran. moghadamm@mail.yu.ac.ir
Tangestaninejad
Shahram
S
Mirkhani
Valiollah
V
Mohammadpoor-Baltork
Iraj
I
Kargar
Hadi
H
D000438:Alcohols / Q000138:chemical synthesis / Q000737:chemistry*; D002384:Catalysis; D008345:Manganese / Q000737:chemistry*; D008665:Metalloporphyrins / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010504:Periodic Acid / Q000737:chemistry*; D011137:Polystyrenes / Q000737:chemistry*
D000438:Alcohols; D008665:Metalloporphyrins; D011137:Polystyrenes; D010504:Periodic Acid; D008345:Manganese; C009288:metaperiodate