Synthesis of dialkyl 2,5-dihydro-5-oxo-1,2-azaphosphole-3,4-dicarboxylates.
The adducts produced in the reaction between triphenylphosphine and dialkyl acetylenedicarboxylates were trapped by arylsulfonyl isocyanates to produce dialkyl 2,5-dihydro-5-oxo-1,2-azaphosphole-3,4-dicarboxylates in good yields.
Yavari
Issa
I
Department of Chemistry, University of Tarbiat Modarres, Tehran, Iran. isayavar@yahoo.com
Alizadeh
Abdolali
A
Anary-Abbasinejad
Mohammad
M
D000478:Alkylation; D001391:Azo Compounds / Q000138:chemical synthesis / Q000737:chemistry; D003460:Crystallization; D003998:Dicarboxylic Acids / Q000138:chemical synthesis* / Q000737:chemistry; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D015394:Molecular Structure
D001391:Azo Compounds; D003998:Dicarboxylic Acids; D007202:Indicators and Reagents