Synthesis and phase characterization of a double-tailed pyrrole-containing surfactant: a novel tecton for the production of functional nanostructured materials.
A double-tailed polymerizable (pyrrolylalkyl) ammonium amphiphile has been synthesized, and its interfacial properties and aqueous phase behavior have been studied by polarized optical microscopy and X-ray diffraction. The Krafft temperature is about 27 degrees C, and the critical micelle concentration at 40 degrees C is about 1 mM, as obtained from surface tension measurements, potentiometry, and isothermal titration calorimetry. The lyotropic behavior of the surfactant is found to be of a complex nature. At concentrations higher than the micellar (L1) region, two mesophases have been identified: a second isotropic (L2) phase, which is probably micellar but not fully miscible with water, and a lamellar (L(alpha)) phase, showing interesting alignment properties. Small-angle X-ray scattering analysis of the mesophases has been evaluated in terms of a model of spherical micelles, which describes a mutual arrangement by a structure factor derived from a hard-sphere potential (Percus-Yevick, "PY", approach). Interest in the comprehensive phase behavior of the polymerizable surfactant is based on the desire to integrate the system into a composite material to obtain potentially conducting self-assembled hybrid mesostructures.
Franke
Danielle
D
Max Planck Institute of Colloids and Interfaces, Research Campus Golm, D-14424 Potsdam, Germany.
Egger
Chrystelle C
CC
Smarsly
Bernd
B
Faul
Charl F J
CF
Tiddy
Gordon J T
GJ