title: Electrically anisotropic thin films consisting of polymeric and metallic nanolayers from self-assembled lamellae of diblock copolymers.
abstract: We demonstrated the fabrication of electrically anisotropic thin films of alternating polymeric layers and metallic layers in nanometer thickness by utilizing self-assembled nanodomains of symmetric diblock copolymers. Nanometer-thick metal layers macroscopically parallel to the film plane were synthesized by electroless Ag deposition on Au nanoparticles selectively in one of the blocks. Every Ag/Au layer was completely separated by nanometer-thick polymer layers in the direction perpendicular to the film plane. Therefore, the conductivity of the film was highly anisotropic, differing by at least 8 orders of magnitude in directions parallel and perpendicular to the film plane, even though the in-plane conductivity (2.8 x10(-6) S/cm) was in the range of semiconductors. If self-assembled nanodomains of diblock copolymers were not employed, a serial layer-by-layer process for each layer would be required to fabricate such an electrically anisotropic thin film.
authors.affiliation: Department of Materials Science and Engineering, Pohang University of Science and Technology, Pohang 790-784, Korea.
authors.forename: Sang-Hyun
authors.initials: SH
authors.lastname: Yun
authors.forename: Seong Min
authors.initials: SM
authors.lastname: Yoo
authors.forename: Byeong-Hyeok
authors.initials: BH
authors.lastname: Sohn
authors.forename: Jin Chul
authors.initials: JC
authors.lastname: Jung
authors.forename: Wang-Cheol
authors.initials: WC
authors.lastname: Zin
authors.forename: Seung-Yeop
authors.initials: SY
authors.lastname: Kwak
authors.forename: Taek Seung
authors.initials: TS
authors.lastname: Lee