Synthesis and crystal structure of a salen-type copper(II) complex derived from 3,5'-O-dimethyl-2',3'-diamino-2',3'-dideoxy-beta-D-xylo-uridine.
We report the synthesis of the first 2',3'-diamino substituted uridine derivative with xylo-configuration, its use as starting material for the synthesis of salen-type ligands and the first structurally characterised copper(II) complex thereof.
Gottschaldt
Michael
M
Institute for Organic and Macromolecular Chemistry, FSU Jena, Humboldtstrasse 10, 07743, Jena, Germany. Michael.Gottschaldt@uni-jena.de
Koth
Daniel
D
Görls
Helmar
H
D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003837:Deoxy Sugars / Q000138:chemical synthesis / Q000737:chemistry*; D005029:Ethylenediamines / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D009941:Organomercury Compounds / Q000138:chemical synthesis / Q000737:chemistry; D014529:Uridine / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry
D003837:Deoxy Sugars; D005029:Ethylenediamines; D009941:Organomercury Compounds; D003300:Copper; C011452:disalicylaldehyde ethylenediamine; D014529:Uridine