Reversible O-O bond cleavage and formation of a peroxo moiety of a peroxocarbonate ligand mediated by an iron(III) complex.
A mononuclear iron(III) complex containing a peroxocarbonate ligand, [Fe(qn)2(O2C(O)O)]- (qn = quinaldinate), underwent the reversible O-O bond cleavage and reformation of the peroxo group via the formation of FeIV=O or FeV=O species, which was confirmed by the resonance Raman and ESI-TOF/MS measurements.
Furutachi
Hideki
H
Department of Chemistry, Faculty of Science, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
Hashimoto
Koji
K
Nagatomo
Shigenori
S
Endo
Taichi
T
Fujinami
Shuhei
S
Watanabe
Yoshihito
Y
Kitagawa
Teizo
T
Suzuki
Masatatsu
M