Hydrogen bond mediated open-frame networks in coordination polymers: supramolecular assemblies of Pr(III) and 3,5-dinitro-4-methylbenzoic acid with aza-donor compounds.
A coordination assembly of 3,5-dinitro-4-methylbenzoic acid and Pr(III), synthesized by hydrothermal methods forms a host structure, which is stable up to 300 [degree]C, through C-HO hydrogen bonds and accommodates different types of guest species varying from simple molecules like water to larger molecules like trans-1,2-bis(4-pyridyl)ethene.
Varughese
Sunil
S
Division of Organic Chemistry, National Chemical Laboratory, Dr. Homi Bhabha Road, Pune 411 008, India. pediredi@ems.ncl.res.in.
Pedireddi
V R
VR