(mu-2,11-Dithia[3.3]paracyclophane-kappa2S:S')bis[(6-carboxypyridine-2-carboxylato-kappa2N,O6silver(I)]: a mixed-ligand silver-based dinuclear compound.
In the title complex, [Ag2(C7H4NO4)2(C16H16S2)], each Ag(I) atom is trigonally coordinated by one S atom of a 2,11-dithia[3.3]paracyclophane (dtpcp) ligand, and by one N and one O atom of a 6-carboxypyridine-2-carboxylate ligand. Dtpcp acts as a bidentate ligand, bridging two inversion-related AgI atoms to give a dinuclear silver(I) compound. The dinuclear moieties are interconnected via O-H...O hydrogen bonds to form a two-dimensional zigzag sheet. Two such sheets are interwoven via pi-pi interactions between pyridine rings, affording an interwoven bilayer network.
Liu
Shu-Qin
SQ
Department of Chemistry, Dalian University of Technology, Dalian 116012, People's Republic of China.
Konaka
Hisashi
H
Kuroda-Sowa
Takayoshi
T
Ning
Gui-Ling
GL
Munakata
Megumu
M