Covariance for cone and wedge complete filling.
Interfacial phenomena associated with fluid adsorption in two dimensional systems have recently been shown to exhibit hidden symmetries, or covariances, which precisely relate local adsorption properties in different confining geometries. We show that covariance also occurs in three-dimensional systems and is likely to be verifiable experimentally and in Ising model simulations studies. Specifically, we study complete wetting in wedge (W) and cone (C) geometries as bulk coexistence is approached and show that the equilibrium midpoint heights satisfy l(c)(h,alpha)=l(w)(h / 2,alpha), where h measures the partial pressure and alpha is the tilt angle. This covariance is valid for both short-ranged and long-ranged intermolecular forces and identifies both leading and next-to-leading-order critical exponents and amplitudes in the confining geometries.
Rascón
C
C
Grupo Interdisciplinar de Sistemas Complejos (GISC), Departamento de Matemáticas, Universidad Carlos III de Madrid, 28911 Leganés (Madrid), Spain.
Parry
A O
AO