Self-assembly of supramolecular chiral insulated molecular wire.
Supramolecular chiral insulated molecular wire was constructed by self-assembly of a neutral one-dimensional schizophyllan host and a water-soluble polythiophene guest. The work presented here will not only open a door to a new application of polysaccharides but also provide an important clue to prepare stable supramolecular insulated molecular wires with one-handed helical structure.
Li
Chun
C
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 812-8581, Japan.
Numata
Munenori
M
Bae
Ah-Hyun
AH
Sakurai
Kazuo
K
Shinkai
Seiji
S
D002240:Carbohydrate Sequence; D018625:Microscopy, Atomic Force; D008958:Models, Molecular; D008969:Molecular Sequence Data; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*; D012566:Sizofiran / Q000138:chemical synthesis / Q000737:chemistry*; D012995:Solubility; D013237:Stereoisomerism; D013876:Thiophenes / Q000138:chemical synthesis / Q000737:chemistry*; D014867:Water / Q000737:chemistry
D011108:Polymers; D013876:Thiophenes; D014867:Water; C066730:polythiophene; D012566:Sizofiran