Step structures on III-V phosphide (001) surfaces: how do steps and Sb affect CuPt ordering of GaInP2?
The observation of III-V phosphide (001)-(2 x 2) surfaces makes it possible to solve a long standing mystery of step structures. First-principles calculations show that a bulklike type-B step on a hydrogenated 2 x 2 surface is more stable than a rebonded one by 1.1 eV/unit step. In contrast, this energy difference for a H-free beta(2 x 4) surface is only 0.5 eV/unit step. The large difference explains why the CuPt ordering of GaInP is stronger in metal-organic chemical vapor deposition than in molecular beam epitaxy. However, a minute amount of Sb will preferentially attach to the 2 x 2 surface steps and induce additional step structures that cause ordering disruption.
Batyrev
Iskander G
IG
National Renewable Energy Laboratory, Golden, Colorado 80401, USA.
McMahon
W E
WE
Zhang
S B
SB
Olson
J M
JM
Wei
Su-Huai
SH