N-[(R)-1-(2-hydroxy-5-methylphenyl)ethyl]-N-[(R)-1-(2-methoxy-5-methylphenyl)-2-phenylethyl]aminium chloride.
The title compound, C25H30NO2+.Cl-, has been synthesized, and the crystal structure shows that it is mainly stabilized through intermolecular N-H...Cl and O-H...Cl and intramolecular N-H...O hydrogen bonds. The absolute configuration of the new stereogenic center (the C atom adjacent to the N atom on the phenol side) was determined to have an R configuration.
Yang
Xiao-Feng
XF
Department of Chemical Engineering, Jinan University, Jinan Shandong Province 250022, People's Republic of China. jn_yangxiaofeng@hotmail.com
Zhang
Guang-You
GY
Zhang
Yan
Y
Zhao
Jin-Yan
JY
Wang
Xiang-Bo
XB
D000627:Aminophenols / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D015394:Molecular Structure
D000627:Aminophenols