[Synthesis and molecular recognition study of 6-Cs-beta-CD].
The reagents 6-Cs-beta-CD with molecular recognition function were synthesized and confirmed. Both basic condition and enough illumination were necessary for obtaining stable and strong fluorescence. With 6-Cs-beta-CD as the host, cyclohexanol, cyclohexene, cyclohexane and bromocyclohexane as the guest, the recognition properties were studied. The affinity of 6-Cs-beta-CD and the guest is distinct with different hydrophobicity of the guest.
Zhao
Y
Y
Department of Chemistry, Tsinghua University, 100084 Beijing.
Li
L
L
Tong
A
A
D057927:Hydrophobic and Hydrophilic Interactions; D013050:Spectrometry, Fluorescence; D013816:Thermodynamics; D047392:beta-Cyclodextrins / Q000138:chemical synthesis* / Q000737:chemistry*
D047392:beta-Cyclodextrins; C031215:betadex