title: Aqueous solubility and alkaline hydrolysis of the novel high explosive hexanitrohexaazaisowurtzitane (CL-20).
abstract: The recently developed polycyclic nitramine CL-20 is considered as a possible replacement for the monocyclic nitramines RDX and HMX. The present study reports aqueous solubility data for CL-20, as well as the kinetic parameters for its alkaline hydrolysis with sodium hydroxide below and above its solubility limits. Aqueous solubility of CL-20 was measured in the temperature range of 4-69 degrees C and the data were fitted to a generalized solubility model. Alkaline hydrolysis experiments were conducted at 15, 20, 30 and 40 degrees C, with hydroxide concentrations ranging from 0.25 to 300 mM. Like RDX and HMX, alkaline hydrolysis of CL-20 follows second-order kinetics. CL-20 alkaline hydrolysis was found to proceed at a significantly faster rate than RDX. The temperature dependency of the second-order rate constants was evaluated using the Arrhenius model. The activation energy for CL-20 was found to be within close range of the activation energies reported for RDX and HMX.
authors.affiliation: Center for Environmental Systems, Stevens Institute of Technology, Castle Point on Hudson, Hoboken, NJ 07030, USA.
authors.forename: Pelin
authors.initials: P
authors.lastname: Karakaya
authors.forename: Mohammed
authors.initials: M
authors.lastname: Sidhoum
authors.forename: Christos
authors.initials: C
authors.lastname: Christodoulatos
authors.forename: Steve
authors.initials: S
authors.lastname: Nicolich
authors.forename: Wendy
authors.initials: W
authors.lastname: Balas
mesh_terms: D001952:Bridged-Ring Compounds / Q000737:chemistry*; D006868:Hydrolysis; D007700:Kinetics; D008962:Models, Theoretical; D009574:Nitro Compounds / Q000737:chemistry*; D012995:Solubility; D014865:Waste Disposal, Fluid / Q000379:methods*
chemical_list: D001952:Bridged-Ring Compounds; D009574:Nitro Compounds; C083639:hexanitrohexaazaisowurzitane