Mixed-metal triangular trinuclear complexes: dimers of gold-silver mixed-metal complexes from gold(I) carbeniates and silver(I) 3,5-diphenylpyrazolates.
Dimers of trinuclear mixed gold-silver compounds are obtained by the reaction of a gold(I) carbeniate, [Au(mu-C(OEt)=NC6H4-p-CH3)]3, with a silver(I) pyrazolate, [Ag(mu-3,5-Ph2pz)]3. The crystalline products are the mixed-metal species Au(carb)Ag2(mu-3,5-Ph2pz)2 and Au2(carb)2Ag(mu-3,5-Ph2pz)CCH2Cl2.
Mohamed
Ahmed A
AA
Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA.
Burini
Alfredo
A
Fackler
John P
JP