title: [Resonance Raman spectra of transition metal Mn(III), Fe(III), Rh(III), Pd(II) porphyrin complexes].
abstract: The resonance Raman spectra of Mn(III), Rh(III), Fe(III), Pd(II) protoporphyrin IX-dimethylester (PP) and tetra-phenylporphyrin (TPP) complexes were reported. The difference of their structure-sensitive band frequency was a result of the interaction of different metal ions' outer d electrons with the electrons of the porphyrin ring. As well the effects of different porphyrin rings and their substituts on the structure-sensitive bands were discussed in this paper.
authors.affiliation: Institute of Zhongyuan Pharmaceutical Factory, 450066 Zhengzhou.
authors.forename: T
authors.initials: T
authors.lastname: Lei
authors.forename: T
authors.initials: T
authors.lastname: Jiang
authors.forename: L
authors.initials: L
authors.lastname: Gao
mesh_terms: D007501:Iron / Q000737:chemistry; D008345:Manganese / Q000737:chemistry; D008665:Metalloporphyrins / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry; D011166:Porphyrins / Q000737:chemistry; D011524:Protoporphyrins / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry; D013059:Spectrum Analysis, Raman; D028561:Transition Elements / Q000737:chemistry*
chemical_list: D008665:Metalloporphyrins; D011166:Porphyrins; D011524:Protoporphyrins; D028561:Transition Elements; C409084:tetraphenylporphyrin; D008345:Manganese; D010165:Palladium; D012238:Rhodium; D007501:Iron