Inorganic-organic hybrid molecular architectures of cyanometalate host and organic guest systems: specific behavior of the guests.
Molecular architectures built of inorganic cyanometalate building blocks provide variegated host structures with several organic guest molecules. The strategies to derive novel structures are presented briefly. The formation of a charge-transfer (CT) complex as the guest inside the cavity and the photochemistry of the CT complexes are discussed. The chemical pressure that the guest experiences inside the cavity is also discussed based on the vibrational spectroscopic results.
Nishikiori
Shin-ichi
S
Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo, Komaba, Meguro, Tokyo 153-8902, Japan.
Yoshikawa
Hirofumi
H
Sano
Yuriko
Y
Iwamoto
Toschitake
T