[Resonance Raman spectra of transition metal Mn(III), Fe(III), Rh(III), Pd(II) porphyrin complexes].
The resonance Raman spectra of Mn(III), Rh(III), Fe(III), Pd(II) protoporphyrin IX-dimethylester (PP) and tetra-phenylporphyrin (TPP) complexes were reported. The difference of their structure-sensitive band frequency was a result of the interaction of different metal ions' outer d electrons with the electrons of the porphyrin ring. As well the effects of different porphyrin rings and their substituts on the structure-sensitive bands were discussed in this paper.
Lei
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Institute of Zhongyuan Pharmaceutical Factory, 450066 Zhengzhou.
Jiang
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Gao
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D007501:Iron / Q000737:chemistry; D008345:Manganese / Q000737:chemistry; D008665:Metalloporphyrins / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry; D011166:Porphyrins / Q000737:chemistry; D011524:Protoporphyrins / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry; D013059:Spectrum Analysis, Raman; D028561:Transition Elements / Q000737:chemistry*
D008665:Metalloporphyrins; D011166:Porphyrins; D011524:Protoporphyrins; D028561:Transition Elements; C409084:tetraphenylporphyrin; D008345:Manganese; D010165:Palladium; D012238:Rhodium; D007501:Iron