A 2D honeycomb-shaped network based on a starburst cluster: [Ag4(micro3-Cl)(PPh2(CH2)2PPh2)1.5{S2P(OR)2}3](R = Et, Pri).
The first 2D metal-organic framework utilizing PPh2(CH2)2PPh2 (dppe) units as the linkers and tetranuclear silver clusters, [Ag4(micro3)-Cl){S2P(OR)2}3], as the network nodes in the formation of the honeycomb-shaped layer structure is reported.
Liu
C W
CW
Department of Chemistry, National Dong Hwa University, Hualien, Taiwan 974. chenwei@mail.ndhu.edu.tw
Liaw
Ben-Jie
BJ
Liou
Lin-Shou
LS
Wang
Ju-Chun
JC