[3 + 3] Cycloadditions and related strategies in alkaloid natural product synthesis.
In this article we describe a strategically unusual approach to piperidines via formal [3 + 3] cycloaddition reactions. The scope and limitations of these processes are outlined and their employment in the synthesis of alkaloid natural products is delineated.
Harrity
Joseph P A
JP
Department of Chemistry, University of Sheffield, UK. j.harrity@sheffield.ac.uk
Provoost
Olivier
O
D000470:Alkaloids / Q000138:chemical synthesis* / Q000737:chemistry; D000478:Alkylation; D000838:Anions / Q000737:chemistry; D001388:Aziridines / Q000737:chemistry; D001688:Biological Products / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D013237:Stereoisomerism
D000470:Alkaloids; D000838:Anions; D001388:Aziridines; D001688:Biological Products