On the structure of aqueous LiCl solutions.
The structure of highly concentrated aqueous lithium chloride solutions was investigated by the Reverse Monte Carlo method. Two total structure factors, obtained from neutron and x-ray diffraction experiments, were applied as input information. From the resulting particle configurations, partial pair correlation functions, coordination numbers and cosine distributions of bond angles have been determined. It was found that, in accordance with common-sense expectations, the hydrogen bonded network of water molecules is breaking up continuously as the concentration of the electrolyte increases. The hydration shell of the cations becomes more and more distorted as concentration grows whereas the hydration structure of the anions appears to be nearly invariant. Ion-pairing was not detected even at the highest salt concentration.
Harsányi
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Research Institute for Solid State Physics and Optics, Hungarian Academy of Sciences, P. O. Box 49, Budapest 1525, Hungary. i_harsanyi@hotmail.com
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