[Photoluminescence and UV-VIS absorption spectra characteristics of complexes of ruthenium (II) with 1,10-phenanthroline and 4,7-diphnyl-1,10-phenanthroline].
The preparation and spectroscopic characteristics of the tris (1,10-phenanthroline) and tris (4,7-diphenyl-1,10-phenalthroline) complex ions of rathenium (II) are reported. Under the coordinate field with the property of D3 group, the splitting of the 4d state of Ru2+ is discussed. The transitions which give rise to the UV-VIS absorption spectra and emission spectra of the complexes are assigned. The influence of the coordinate substance on the absorptivity and red-shift is discussed as well.
Lu
W
W
Departement of Polymer Science and Engineering, USTC, 230026 Hefei.
Shi
J
J
Wang
H
H