[Flotation spectrophotometric determination of copper on isochromatic dye ion pair with crystal violet and bromopnenol blue].
Bromophenol blue (BPB) was produced and entered into the aqueous phase when NaOH solution of pH = 10 was added to Cu(biq)2BPB by trichloromethane and isoamyl alcohol (20:1) extractive. And then CV x BPB was floated by crystal violet (CV) with benzene solution. The flotation was dissolved in ethanol and the absorbance of the solution measured at 590 nm. The sensitivity was raised because of the two dyes assistant effect. The molar absorptivity was 1.45 x 10(5) L x mol(-1) x cm(-1). Copper in the sample was separated first by extracting the Cu(biq)2BPB complex with trichloromethane and isoamyl alcohol, thus achieving a high selectivity. Beer's law was obeyd in the range of 0-0. 4 mg/L with a relative standard deviation of 3.6%. For 4.8 x 10(-8) g/mL copper solution, the recoveries were 97.8%-101.7%.
Liu
B
B
Research Centre of Physical and Chemical Analysis, Hebei University, 071002 Baoding.
Chen
C
C
Zuo
B
B
D001978:Bromphenol Blue / Q000032:analysis; D004396:Coloring Agents / Q000032:analysis*; D003300:Copper / Q000032:analysis*; D005840:Gentian Violet / Q000032:analysis*; D013053:Spectrophotometry / Q000379:methods*; D014873:Water Pollutants / Q000032:analysis*
D004396:Coloring Agents; D014873:Water Pollutants; D001978:Bromphenol Blue; D003300:Copper; D005840:Gentian Violet