New titanium and zirconium complexes with M-NH2 bonds formed by facile deprotonation of H3N.B(C6F5)3.
Facile deprotonation of H3N.B(C6F5)3 with [M(NMe2)4](M = Zr or Ti) yields the novel amidoborate complexes [Zr(NMe2)3{NH2B(C6F5)3}(HNMe2)] and [Ti(NMe2)3{NH2B(C6F5)3}].
Mountford
Andrew J
AJ
Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK NR4 7TJ.
Clegg
William
W
Harrington
Ross W
RW
Humphrey
Simon M
SM
Lancaster
Simon J
SJ