Rhodium-catalyzed reaction of thiols with polychloroalkanes in the presence of triethylamine.
[reaction: see text] RhCl(PPh(3))(3) catalyzes a reaction of thiols with polychloroalkanes in the presence of triethylamine. This reaction serves as a convenient new method to produce formaldehyde dithioacetals, ethylenedithioethers, thioformates, and dithiocarbonic esters under mild conditions.
Tanaka
Ken
K
Department of Applied Chemistry, Graduate School of Engineering, Tokyo University of Agriculture and Technology, Koganei, Tokyo 184-8588, Japan. tanaka-k@cc.tuat.ac.jp
Ajiki
Kaori
K