Influence of surfactant concentration on counter-ion induced solubility of poly(pyridine-2,5-diyl).
Protonating the pyridine rings of poly(pyridine-2,5-diyl) with dodecybenzenesulfonic acid and camphorsulphonic acid produces polymer materials which can be dissolved in chloroform (in contrast to the unprotonated polymer, which can only be dissolved in strong acids such as formic acid) and allows mixing the protonated polymers with other chloroform soluble conjugated polymers for use in electronic devices. The protonating behavior of poly(pyridine-2,5-diyl) with two kinds of surfactants is different in some levels. Dodecybenzenesulfonic acid has higher protonating ability than camphorsulphonic acid.
Imit
Mokhtar
M
School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China. mokhtarjan@sohu.com
Yamamoto
Takakazu
T
Imin
Patigul
P