Electronic structure of cis-Mo(P)(NO)2, where P is a porphyrin: an organometallic perspective of metalloporphyrin-NO complexes.
This study presents a first MO analysis of the stereochemistry of cis-Mo(P)(NO)(2), where the Mo(NO)(2) unit eclipses a pair of opposite Mo-N bonds and also adopts a remarkable horseshoe-like conformation. In addition, we have uncovered a number of analogies--in terms of commonalities of metal-ligand orbital interactions--between the dinitrosylmetalloporphyrins, Fe(P)(NO)(2) and Mo(P)(NO)(2), and the two dialkylmetalloporphyrins, Ru(P)(CH(3))(2), and Zr(P)(CH(3))(2).
Tangen
Espen
E
Department of Chemistry, University of Tromsø, Breivika, N-9037 Tromsø, Norway.
Ghosh
Abhik
A
D008024:Ligands; D008665:Metalloporphyrins / Q000737:chemistry*; D008697:Methane / Q000737:chemistry; D008958:Models, Molecular; D008982:Molybdenum / Q000737:chemistry*; D009569:Nitric Oxide / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry; D013237:Stereoisomerism; D015040:Zirconium / Q000737:chemistry
D008024:Ligands; D008665:Metalloporphyrins; D009942:Organometallic Compounds; D009569:Nitric Oxide; D012428:Ruthenium; D008982:Molybdenum; D015040:Zirconium; D008697:Methane