Single-particle characterization of four "Asian Dust" samples collected in Korea, using low-Z particle electron probe X-ray microanalysis.
A single-particle analytical technique, named low-Z particle electron probe X-ray microanalysis (low-Z particle EPMA), employing an ultrathin window X-ray detector and enabling the quantitative determination of even low-Z elements such as C, N, and O, is applied to characterize "Asian Dust" samples, collected in ChunCheon, Korea, during four Asian Dust storm events on March 7, 2000, April 7, 2000, March 22, 2001, and May 17, 2001. In this study, it is demonstrated that single-particle analysis using the low-Z particle EPMA provides detailed information on various types of chemical species in the samples. The most abundantly encountered particles, both in coarse and fine fractions, are aluminosilicates. The relative abundances of those particles on the basis of their size are different between the four Asian Dust samples. The sample collected on March 7, 2000 did not experience any chemical modification during its transport because the sample does not contain particles of chemical species that result from atmospheric reactions. The sample collected on April 7, 2000 contains both genuine and reacted sea-salt particles. The genuine sea-salts are in the form of a mixture of NaCl and MgCl2 entrained during their passage over the Yellow Sea. The reacted sea-salts particles are encountered very much in fine fraction. The sample collected on March 22, 2001 shows somewhat significant chemical modification both for CaCO3 and sea-salts particles. For this sample, a significant number of reacted CaCO3 and sea-salt particles, such as those containing nitrate and/or sulfate, are encountered, implying that CaCO3 and sea-salts particles have reacted with sulfur or nitrogen oxide species during their long-range transport. The sample collected on May 17, 2001 experienced the most extensive chemical modification during its transport. In addition to the observation of the extensively reacted CaCO3 and sea-salt particles, reacted K2CO3 particles are also extensively encountered in this sample, which implies that K2CO3 species should be regarded as an additional important chemical species in the study of the chemical modification of Asian Dust particles during long-range transport.
Ro
Chul-Un
CU
Department of Chemistry, Inha University, Incheon, 402-751, Korea. curo@inha.ac.kr
Hwang
Heejin
H
Kim
Hyekyeong
H
Chun
Youngsin
Y
Van Grieken
René
R
D000392:Air Movements; D000393:Air Pollutants / Q000032:analysis*; D002119:Calcium Carbonate / Q000032:analysis; D004391:Dust; D004577:Electron Probe Microanalysis; D004784:Environmental Monitoring; D007723:Korea; D012965:Sodium Chloride / Q000032:analysis
D000393:Air Pollutants; D004391:Dust; D012965:Sodium Chloride; D002119:Calcium Carbonate