[Photoacoustic spectroscopy investigation of intramolecular energy transfer in Eu-beta-disketones].
The complex crystals of Eu(III) with AA, HFA and TTA have been synthesized. The absorption intensities of Eu-AA, Eu-HFA and Eu-TTA are different while the photoacoustic (PA) signals of the corresponding solid complexes are almost the same, which shows that the probabilities for nonradiative transition of these chelates are different. The results of the fluorescence spectra are identical. The PA signal was obtained by detecting the heat generated through the nonradiative processes after absorption, and the intramolecular energy transfer processes of Eu-beta-diketones were studied from a new point of view.
Su
Q
Q
Dept. of Appl. Chem., Univ. of Sci. and Tech. of China, 230026 Hefei.
Sun
Y
Y
Zhao
H
H
Zhang
Z
Z