Catalytic metathesis of carbon dioxide with heterocumulenes mediated by titanium isopropoxide.
The insertion of an isopropoxide ligand of titanium isopropoxide into heterocumulenes gives a product that carries out metathesis at elevated temperatures by undergoing insertion of a second heterocumulene in a head to head fashion, followed by an extrusion reaction.
Ghosh
Rajshekhar
R
Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012, India.
Samuelson
Ashoka G
AG