[Studies on the oxidation reaction of octanol-2 with nitric acid by infrared spectroscopy].
In this paper, the reaction process of oxidation of octanol-2 with nitric acid has been studied by IR spectroscopy. It is found that the main components of non-sapoifiable matter are different in different oxidation degrees. The relation between oxidation products and the amount of nitric acid are investigated,the reaction mechanism has also been studied. Experimental results show that the oxidation process of octanol-2 is as follows: first, octanol-2 is oxidated to octanone-2, or to nitrate, nitrite and nitrile copmpounds, then these compounds are reoxidated to caproic acid in the meantime some by-products, such as valeric, enanthic acids are also found in oxidated products.
Zhang
G
G
Henan Institute of Chemistry, 450003 Zhengzhou.
Zhao
G
G
Wang
Y
Y
Zhang
Q
Q
Zhang
S
S
Lu
F
F