[Study on cleavage mechanisms of dimer (t-Bu)2NO in several solvent phases].
In this paper, we studied the cleavage products of dimer t-BuNO in aqueous and organic solutions using method of 1HNMR and UV-Vis, analyzed the reactive kinetics, put forward that dimer (t-Bu)2NO homolytically cleavaged in nonpolar organic solution, and that dimer (t-Bu)2NO homolytically and heterolyticall cleavaged in a competitive manner in polar aqueous solution.
Ma
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Cancer Research Institute, Hunan Medical University, Changsha.
Tang
J
J