[Study of the circular dichroism for tribasic complex of amine derivative of beta-cyclodextrindien-Cu2+ -benzoic acid].
The circular dichroism spectra of beta-cyclodextrindien, beta-cyclodextrindien-Cu2+ complex, beta-cyclodextrindien-benzoic acid complex, tribasic complex of beta-cyclodextrindien-Cu2+ -benzoic acid were determined by using JASCO J-20C automatic recording spectropolarimeter. The attribution of the bands obtained were made according to the order of orbit energy of Cu2+ complex and benzoic acid, and the coordination structure of tribasic complex of amine derivative of beta-cyclodextrindien-Cu2+ -benzoic acid were decided acording to the structure character of Cu2+ complex and KAJART sector rule of inclusion complex of beta-cyclodextrindien with aromatic compounds.
Hu
J
J
Lanzhou Institute of Chemical Physics, Academia Sinica, 730000 Lanzhou.
Zhang
H
H
Shen
B
B
D000588:Amines / Q000737:chemistry*; D019817:Benzoic Acid / Q000737:chemistry*; D002942:Circular Dichroism; D003300:Copper / Q000737:chemistry*; D047392:beta-Cyclodextrins / Q000737:chemistry*
D000588:Amines; D047392:beta-Cyclodextrins; D003300:Copper; D019817:Benzoic Acid; C031215:betadex