Evaluation of a microwave-assisted extraction technique for determination of water-soluble inorganic species in urban airborne particulate matter.
A simple and rapid microwave-assisted extraction (MAE) technique has been developed for the determination of water-soluble inorganic species (cations: Na+, NH4+, K+, Ca2+ and Mg2+ and anions: F-, Cl-, NO3-, PO4(3-) and SO4(2-)) in airborne particulate matter. The analytes were extracted under different treatment conditions such as microwave power and extraction time. They were quantified using ion chromatography. The observed concentrations and recovery yields obtained under different conditions were compared. The results of a comparison between this MAE and sonication using NIST SRM 1648 are also given in this paper. The optimized MAE technique gave results in good agreement with the values obtained by the sonication. For some ions, for example Mg2+ and K+, recovery was low with both techniques. The results demonstrated that the optimized MAE is fast and efficient compared with conventional ultrasonic extraction. Urban airborne particles were collected and subjected to the MAE followed by the IC analysis to determine the relative proportions of different water-soluble inorganic species. These results are briefly discussed.
Sathrugnan
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K
Department of Chemical and Biomolecular Engineering, National University of Singapore, Block E5 4 Engineering Drive 4, Singapore 117576.
Balasubramanian
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R