[Calculation for Franck-Condon factors of the two band systems beta(B2pi(r) - X2pi(r)) and gamma(A2sigma+ - X2Pi(r)) of NO in the air at high temperature].
From the nuclear Schrödinger equation of a diatomic molecule with vibration-rotation interaction term involved in it, we derive the wavefunction relevant not only to vibrational quantum number, but also to rotational one. The Franck-Condon factors of the two band systems beta(B2pi(r) - X2pi(r)) and gamma(A2sigma+ - X2Pi(r)) of NO in the air at high temperature are calculated in this paper, using the derived wavefunction. In the calculation, the rotational quantum number J takes values from 0 up to 200. The results apply to both low or high temperature conditions.
Zhang
Z
Z
Department of Physics, Yunnan University, 650091 Kunming.
Pu
X
X
Lin
L
L
Xiong
Y
Y