Synthesis of the tetracyclic core of the tetrapetalones through transannular oxidative [4+3] cyclization.
Wang
Xiang
X
Department of Chemistry and Center for Chemical Methodology and Library Development, Boston University, 590 Commonwealth Avenue, Boston, MA 02215, USA.
Porco
John A
JA
D000215:Acylation; D003500:Cyclization; D006027:Glycosides / Q000138:chemical synthesis / Q000737:chemistry*; D006576:Heterocyclic Compounds, 4 or More Rings / Q000138:chemical synthesis / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013302:Streptomyces / Q000201:enzymology
D006027:Glycosides; D006576:Heterocyclic Compounds, 4 or More Rings; D047028:Macrocyclic Compounds; C492598:tetrapetalone A