Development of a total analytical system by interfacing membrane extraction, pervaporation and high-performance liquid chromatography.
This paper discusses the interfacing of continuous membrane extraction, pervaporation and on-line HPLC-UV detection into a total analytical system (TAS). Organics from a water sample were extracted into an organic solvent, and then concentrated via pervaporation prior to HPLC-UV detection. Factors affecting the system performance were studied. With optimized experimental parameters enrichment factors as high as 192 were obtained, the method detection limits were at low ng/mL levels, and the precisions were better than 5%.
Wang
Xiaoyan
X
Department of Chemistry and Environmental Science, New Jersey Institute of Technology, University Heights, Newark, NJ 07102, USA.
Mitra
Somenath
S
D001331:Automation / Q000295:instrumentation; D001713:Biphenyl Compounds / Q000302:isolation & purification; D002851:Chromatography, High Pressure Liquid / Q000295:instrumentation / Q000379:methods*; D008567:Membranes, Artificial; D009281:Naphthalenes / Q000302:isolation & purification; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D013056:Spectrophotometry, Ultraviolet; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
D001713:Biphenyl Compounds; D008567:Membranes, Artificial; D009281:Naphthalenes; D014874:Water Pollutants, Chemical; C031721:naphthalene; C010574:biphenyl