title: Supramolecular chirality of the hydrogen-bonded complex Langmuir-Blodgett film of achiral barbituric acid and melamine.
abstract: Complex monolayers of barbituric acid and melamine were formed by spreading a chloroform solution of amphiphilic barbituric acid on the subphase of melamine solution. It was confirmed that the complex monolayer was formed through in situ complementary hydrogen bonding at the air-water interface. It was interesting to find that the complex LB films showed supramolecular chirality although both of the molecules were achiral, as verified by the circular dichroism spectral measurements. It was suggested that the pi-pi stacking of the neighboring barbituric acid and melamine group in a helical sense resulted in the chirality of the molecular assemblies. Due to the directionality of the hydrogen bonding, the BA-M film could form regular aligned nanofibers on the AFM images. Increasing the subphase temperature will lead to the decrease of CD intensity and the change of the morphologies. We suggested that the strength of the hydrogen bonding resulted in the difference.
authors.affiliation: CAS Key Laboratory of Colloid and Interface Science, Institute of Chemistry, CAS, 100080, Beijing, People's Republic of China.
authors.forename: Xin
authors.initials: X
authors.lastname: Huang
authors.forename: Chao
authors.initials: C
authors.lastname: Li
authors.forename: Siguang
authors.initials: S
authors.lastname: Jiang
authors.forename: Xuesong
authors.initials: X
authors.lastname: Wang
authors.forename: Baowen
authors.initials: B
authors.lastname: Zhang
authors.forename: Minghua
authors.initials: M
authors.lastname: Liu
mesh_terms: D001463:Barbiturates / Q000737:chemistry*; D002942:Circular Dichroism; D006860:Hydrogen Bonding; D018625:Microscopy, Atomic Force; D011312:Pressure; D013237:Stereoisomerism; D013499:Surface Properties; D014227:Triazines / Q000737:chemistry*
chemical_list: D001463:Barbiturates; D014227:Triazines; C011907:melamine; C032232:barbituric acid