[Detection of radical anion of nitrobenzene in situ on palladium electrode in different solvent].
By means of a highly sensitive electrolytic cell installed in the ESR cavity, radical anion of nitrobenzene in the process of nitrobenzene electroreduction on palladium electrode in different solvent is dectected by flowing electrolytic system. The results show that in different solvent the discrimination of the ESR spectra are different, the solvent has an effect on nitrobenzene radical anion. The nitrobenzene electroreduction on Pd electrode must produce radical anion as an intermediate.
Zhu
X
X
Department of Chemistry, Beijing Normal University, 100875 Beijing.
Wu
Z
Z
Wang
H
H