[Study on time-resolved fluorimetry of samarium].
In this paper, a simple and highly sensitive laser fluorimetric system is described, and the value of time discrimination for suppressing unwanted signals and decreasing the minimum detectable concentration is demonstrated. It is confirmed that time discrimination is very useful for ultratrale determination of fluorescent complex. This technique is successful with the combined use of a pulsed laser and a pulse-gate signal detection system for samarium complex. The linear range and the detectin limit of the method are 0. 01-10microg/ml and 3.3ng/ml, respectively. The RSD for Sm3+ (0. 5microg/ml) ( n =12) is 3.7%. The method was used to detemine samarium in rare earth mixtures. The recovery was in the range of 90.0-110.0%, and the mean recovery was 101.4% ( n = 6 )
Pan
L
L
Changchun Institute of Applied Chemisty, Academia Sinica, 130022 Changchun.
Wang
S
S
Dong
X
X