Operation of the quartz crystal microbalance in liquids: derivation of the elastic compliance of a film from the ratio of bandwidth shift and frequency shift.
For a thin viscoelastic film deposited on a quartz crystal microbalance in a liquid environment, the change in dissipation induced by the presence of a film is proportional to the film's elastic compliance, Jf'. This surprising result is a consequence of the fact that the film is "clamped" by a viscous fluid.
Du
Binyang
B
Institute of Physical Chemistry, Technical University of Clausthal, Arnold-Sommerfeld-Strasse 4, D-38678 Clausthal-Zellerfeld, Germany.
Johannsmann
Diethelm
D