Thioureas as ligands in the pd-catalyzed intramolecular Pauson-Khand reaction.
[reaction: see text] The thiourea-Pd complex was established as a novel type of catalyst in the PKR of allylpropargylamine, and the demonstrated chemistry may prove to be valuable for developing thiuorea as a ligand for the Pd-catalyzed Pauson-Khand reaction.
Tang
Yefeng
Y
Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Beijing 100871, China.
Deng
Lujiang
L
Zhang
Yangdong
Y
Dong
Guangbin
G
Chen
Jiahua
J
Yang
Zhen
Z
D002384:Catalysis; D006574:Heterocyclic Compounds, 2-Ring / Q000138:chemical synthesis*; D008024:Ligands; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D011437:Propylamines / Q000737:chemistry; D013890:Thiourea / Q000737:chemistry*
D006574:Heterocyclic Compounds, 2-Ring; D008024:Ligands; D011437:Propylamines; D010165:Palladium; D013890:Thiourea