Homogeneous and heterogenized Au(III) Schiff base-complexes as selective and general catalysts for self-coupling of aryl boronic acids.
A series of homogeneous and heterogenized gold metal complexes show high activity and selectivity for the homocoupling of a large variety of aryl boronic acids, being of general utility for the synthesis of C2-symmetric biaryls.
González-Arellano
C
C
Instituto de Química Orgánica General, CSIC, Madrid, Spain.
Corma
A
A
Iglesias
M
M
Sánchez
F
F
D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D003432:Cross-Linking Reagents / Q000737:chemistry; D006046:Gold / Q000737:chemistry*; D015394:Molecular Structure; D012545:Schiff Bases / Q000737:chemistry*
D001897:Boronic Acids; D003432:Cross-Linking Reagents; D012545:Schiff Bases; D006046:Gold