title: Soybean oil based greases: influence of composition on thermo-oxidative and tribochemical behavior.
abstract: The biodegradable properties and lubricating ability of greases depend on both the base oil and the thickener. Mineral oils are the most widely used lubricant base fluids due to their inherent lubricity and low cost, but recent environmental awareness has forced consideration of the use of biodegradable fluids such as vegetable oils and certain synthetic fluids in grease formulations. This study presents data on the thermo-oxidation behavior and tribology of biodegradable greases formulated with soybean oil and different compositions of metal soap thickener. The composition of thickener has been varied by using fatty acids with different degrees of unsaturation and fatty acids of different chain lengths. The improvement of thermo-oxidation and tribological properties as a result of changing thickener/base oil ratio and the antioxidative effect of some suitable additives have also been evaluated.
authors.affiliation: Department of Chemical Engineering, Pennsylvania State University, University Park, Pennsylvania 16802, USA.
authors.forename: Brajendra K
authors.initials: BK
authors.lastname: Sharma
authors.forename: Atanu
authors.initials: A
authors.lastname: Adhvaryu
authors.forename: Joseph M
authors.initials: JM
authors.lastname: Perez
authors.forename: Sevim Z
authors.initials: SZ
authors.lastname: Erhan
mesh_terms: D002152:Calorimetry, Differential Scanning; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D004355:Drug Stability; D005227:Fatty Acids / Q000737:chemistry; D006358:Hot Temperature; D010084:Oxidation-Reduction; D013024:Soybean Oil / Q000737:chemistry*
chemical_list: D005227:Fatty Acids; D013024:Soybean Oil