The first beta-diketiminate-Ag(I) complexes. Macrocyclic dinuclear and tetranuclear Ag(I)-complexes and linear coordination polymer Ag(I)-complex.
Reactions of Ag(I) and a series of beta-diketiminate ligands have been investigated to demonstrate that unique macrocyclic dinuclear and tetranuclear Ag(I)-complexes and a linear coordination polymer Ag(I)-complex as well as oxidative C-C coupling dimer products of the ligands were obtained depending on the substituents on the carbon framework of beta-diketiminate ligands.
Shimokawa
Chizu
C
Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.
Itoh
Shinobu
S