Isolation and characterization of the first circular single-stranded polymetallic lanthanide-containing helicate.
A thorough examination of the disassembly of bimetallic triple-stranded lanthanide helicates [Ln2(Li)3]6+ (stoichiometry S = m/n = 2/3 = 0.67, global complexity GC = m + n = 2 + 3 = 5) in excess of metals shows the competitive formation of standard linear bimetallic complexes [Ln2(Li)2]6+ (S= 1.0, GC = 4), and circular trimetallic single-stranded helicates [Ln3(Li)3]9+ (S= 1.0, GC = 6).
Senegas
Jean-Michel
JM
Department of Inorganic Chemistry, University of Geneva, 30 quai E. Ansermet, CH-1211 Geneva 4, Switzerland.
Koeller
Sylvain
S
Bernardinelli
Gerald
G
Piguet
Claude
C
D018360:Crystallography, X-Ray; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry* / Q000302:isolation & purification*; D012680:Sensitivity and Specificity; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
D028581:Lanthanoid Series Elements; D008024:Ligands; D009942:Organometallic Compounds