Shape-controlled synthesis of Prussian blue analogue Co3[Co(CN)6]2 nanocrystals.
Prussian blue analogue Co3[Co(CN)6]2 nanostructures with morphologies of truncated nanocubes (polyhedra), cubes and rods, were synthesized in large quantities by a direct dissociation of the single-source precursor K3[Co(CN)6] in a microemulsion system; the molar ratio of H2O to surfactant and the concentration of K3[Co(CN)6] both played important roles in determining the shape of the product.
Cao
Minhua
M
Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun, PR China.
Wu
Xinglong
X
He
Xiaoyan
X
Hu
Changwen
C
D003035:Cobalt / Q000737:chemistry*; D003460:Crystallization; D003486:Cyanides / Q000737:chemistry; D005295:Ferrocyanides / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010316:Particle Size; D013501:Surface-Active Agents / Q000737:chemistry; D014867:Water / Q000737:chemistry
D003486:Cyanides; D005295:Ferrocyanides; D009942:Organometallic Compounds; D013501:Surface-Active Agents; D014867:Water; D003035:Cobalt; C000170:ferric ferrocyanide