title: Mode correlation of product pairs in the reaction OH+CD4-->HOD+CD3.
abstract: The hydrogen abstraction reaction from methane by a hydroxyl radical produces two polyatomic molecules. Each product has several vibrational modes that characterize distinct, concerted motions of the constituent atoms of the molecule. This communication describes the first measurement that maps out the coincident information on how the mode of excitation of one product varies with that of the other co-product. Such information on mode correlation of product pairs is particularly appealing in that it provides intuitively a glimpse of the reaction paths by which the chemical transformation occurs.
authors.affiliation: Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P.O. Box 23-166, Taipei, Taiwan 106.
authors.forename: Bailin
authors.initials: B
authors.lastname: Zhang
authors.forename: Weicheng
authors.initials: W
authors.lastname: Shiu
authors.forename: Jim J
authors.initials: JJ
authors.lastname: Lin
authors.forename: Kopin
authors.initials: K
authors.lastname: Liu