title: Enantioselective intramolecular alkene hydroaminations catalyzed by yttrium complexes of axially chiral bis(thiolate) ligands.
abstract: [structure: see text] A yttrium(III) complex derived from proligand 7c has been shown to be a superior catalyst for enantioselective intramolecular alkene hydroaminations that provide cyclic amines with ee's ranging from 69% to 89%.
authors.affiliation: Department of Chemistry, Montana State University, Bozeman, Montana 59717, USA.
authors.forename: Joon Young
authors.initials: JY
authors.lastname: Kim
authors.forename: Tom
authors.initials: T
authors.lastname: Livinghouse
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000586:Amination; D002384:Catalysis; D007202:Indicators and Reagents; D008024:Ligands; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D015019:Yttrium / Q000737:chemistry*
chemical_list: D000475:Alkenes; D007202:Indicators and Reagents; D008024:Ligands; D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D015019:Yttrium