Studies on synthesis, infrared and fluorescence spectra of new europium (III) and terbium (III) complexes with an beta-diketonate-type ligand.
A new beta-diketonate-type ligand, N-(2-amino-6-methyl-pyridinyl)ketoacetamide (L) and its complexes with europium (III) and terbium (III) were synthesized. The complexes were characterized by elemental analysis, infrared spectra and conductivity. The europium (III) and terbium (III)-ions were found to coordinate to the CO oxygen atoms and pyridine nitrogen atoms. The fluorescence properties of these complexes in solid, DMF and CH3OH were studied. The solvent factors influencing the fluorescent intensity are discussed.
Tai
Xi-Shi
XS
Department of Chemistry, Weifang University, Weifang 261061, PR China. taixishi@lzu.edu.cn
Tan
Min-Yu
MY
D002244:Carbon / Q000737:chemistry; D005063:Europium / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry; D007477:Ions; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008956:Models, Chemical; D008968:Molecular Conformation; D009584:Nitrogen / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry; D013050:Spectrometry, Fluorescence / Q000379:methods*; D013053:Spectrophotometry; D013055:Spectrophotometry, Infrared; D013725:Terbium / Q000737:chemistry*
D007477:Ions; D008024:Ligands; D013725:Terbium; D005063:Europium; D002244:Carbon; D006859:Hydrogen; D009584:Nitrogen; D010100:Oxygen