[Synthesis of 2,3,4-trihydroxyacetophenone hydrazones and study on their spectral properties].
2,3,4-Trihydroxyacetophenone was synthesized with pyrogallol. Benzoylhydrazone and p-hydroxybenzoylhydrazone were synthesized using the reaction of ethyl benzoate and methyl p-hydroxybenzoate with hydrazine hydrate. Three novel 2,3,4-trihydroxyacetophenone hydrazones were synthesized using the reaction of 2,3,4-trihydroxyacetophenone with benzoylhydrazone, p-hydroxybenzoylhydrazone and phenylhydrazine. IR, UV and the fluorescence spectrum of 2,3,4-trihydroxyacetophenone hydrazones were studied.
Liu
Jian-ning
JN
Department of Chemistry, Longdong University, Qingyang 745000, China.
Wu
Bo-wan
BW
Zhang
Bing
B
Yu
Xin-qiao
XQ
D000098:Acetophenones / Q000737:chemistry*; D006835:Hydrazones / Q000138:chemical synthesis* / Q000737:chemistry*; D008956:Models, Chemical; D015394:Molecular Structure; D010659:Phenylhydrazines / Q000737:chemistry; D011748:Pyrogallol / Q000737:chemistry; D013050:Spectrometry, Fluorescence; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D013057:Spectrum Analysis
D000098:Acetophenones; D006835:Hydrazones; D010659:Phenylhydrazines; D011748:Pyrogallol; C030299:phenylhydrazine; C038699:acetophenone