Preparation of enolate-homoenolate species as (Z)-gamma-siloxyallylmetal equivalents: sequential 1,4-addition of bis(iodozincio)methane to 1,4-dicarbonylbutenes and cyclopropanation.
Hirayama
Takaharu
T
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoutodaigaku-Katsura, Nishikyo, Kyoto 615-8501, Japan.
Oshima
Koichiro
K
Matsubara
Seijiro
S
D000475:Alkenes / Q000138:chemical synthesis / Q000737:chemistry*; D000605:Amino Alcohols / Q000737:chemistry*; D002073:Butanes / Q000737:chemistry*; D003500:Cyclization; D003521:Cyclopropanes / Q000138:chemical synthesis* / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D017646:Organosilicon Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D015032:Zinc / Q000737:chemistry*
D000475:Alkenes; D000605:Amino Alcohols; D002073:Butanes; D003521:Cyclopropanes; D017646:Organosilicon Compounds; C513531:bis(iodozincio)methane; D015032:Zinc; D008697:Methane