title: The first example of solvothermally synthesized thioantimonates(V) with ethylenediamine coordinated lanthanide(III): [Sm(en)4]SbS4 x 0.5en and [Sm(en)3(H2O)(micro-SbS4)]infinity.
abstract: Under mild solvothermal conditions two novel thioantimonates(V) [Sm(en)4]SbS4 x 0.5en (1) and [Sm(en)3(H2O)(micro-SbS4)]infinity (2) were synthesized; the structure of 1 contains discrete [Sm(en)4]3+ and [SbS4]3 ions, while 2 consists of neutral [Sm(en)3(H2O) (micro-SbS4)] one-dimensional chains.
authors.affiliation: Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, P R China.
authors.forename: Ding-xian
authors.initials: DX
authors.lastname: Jia
authors.forename: Qin-Yu
authors.initials: QY
authors.lastname: Zhu
authors.forename: Jie
authors.initials: J
authors.lastname: Dai
authors.forename: Wen
authors.initials: W
authors.lastname: Lu
authors.forename: Wen-Juan
authors.initials: WJ
authors.lastname: Guo