Synthesis of (+)-6beta-isovaleryloxylabda- 8,13-diene-7alpha,15-diol, a metabolite from Trismusculus reticulatus.
[structures: see text] A seven-step synthesis of (+)-6beta-isovaleryloxylabda-8,13-diene-7alpha,15-diol has been achieved starting from (+)-larixol; this allowed determination of the absolute configuration of the metabolite isolated from the mucus of Trimusculus reticulatus.
Pathak
Arunendra
A
LEDSS-UMR 5616 (ICMG- IFR 2607), Bâtiment 52 Chimie recherches, Université Joseph Fourier, BP 53X, F-38041 Grenoble Cedex 9, France.
Aslaoui
Jamila
J
Morin
Christophe
C
D000818:Animals; D008974:Mollusca / Q000378:metabolism*; D009093:Mucus / Q000737:chemistry; D009281:Naphthalenes / Q000138:chemical synthesis* / Q000737:chemistry; D010421:Pentanoic Acids / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
C503012:6beta-isovaleryloxylabda- 8,13-diene-7alpha,15-diol; D009281:Naphthalenes; D010421:Pentanoic Acids