Sorption-desorption behavior of bispyrazolato-copper(II) 1D coordination polymers.
A new polycrystalline vapochromic polymorph of the one-dimensional copper bispyrazolate polymer reversibly and selectively absorbs a number of small molecules; the crystal structures of the anhydrous and fully hydrated species, determined by powder diffraction methods, are markedly different despite their simple, fast, and reversible interconversion.
Cingolani
Augusto
A
Dipartimento di Scienze Chimiche, Università di Camerino, via S. Agostino 1, I-62032 Camerino (MC), Italy.
Galli
Simona
S
Masciocchi
Norberto
N
Pandolfo
Luciano
L
Pettinari
Claudio
C
Sironi
Angelo
A