Isolation of a new two-dimensional honeycomb carbonato-bridged copper(II) complex exhibiting long-range ferromagnetic ordering.
Atmospheric CO2 fixation by an aqueous solution containing Cu(ClO4)2.6H2O and 4-aminopyridine (4-apy) yields a novel example of a two-dimensional mu3-CO3 bridged copper(II) complex {[Cu(4-apy)2]3(mu3-CO3)2(ClO4)2.(1/2)CH3OH}n that has been characterized by IR, UV and X-ray crystallography; preliminary magnetic measurements show that complex exhibits long-range ordered ferromagnetic coupling.
Majumder
Arpi
A
Department of Chemistry, Jadavpur University, Kolkata-700 032, India. smitra_2002@yahoo.com
Choudhury
Chirantan Roy
CR
Mitra
Samiran
S
Rosair
Georgina M
GM
El Fallah
M Salah
MS
Ribas
Joan
J
D002254:Carbonates / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008280:Magnetics; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D013696:Temperature
D002254:Carbonates; D009942:Organometallic Compounds; D003300:Copper