Catalytic formation of C-O bonds by alkene activation: Lewis acid-cycloisomerisation of olefinic alcohols.
Tin(IV) trifluoromethanesulfonate has been found to be an excellent catalyst for the cycloisomerisation of non-activated and differently substituted olefinic alcohols to cyclic ethers.
Coulombel
Lydie
L
Laboratoire Arômes, Synthèses et Interactions, Université de Nice-Sophia Antipolis, Nice, France.
Favier
Isabelle
I
Duñach
Elisabet
E
D000475:Alkenes / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D003500:Cyclization; D004988:Ethers, Cyclic / Q000138:chemical synthesis* / Q000737:chemistry; D005233:Fatty Alcohols / Q000737:chemistry*; D019216:Metals, Heavy / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry; D013237:Stereoisomerism
D000475:Alkenes; D004988:Ethers, Cyclic; D005233:Fatty Alcohols; D019216:Metals, Heavy; D009942:Organometallic Compounds; D002244:Carbon; D010100:Oxygen