title: Groundwater salinization in the Saloum (Senegal) delta aquifer: minor elements and isotopic indicators.
abstract: The hydrochemistry of minor elements bromide (Br), boron (B), strontium (Sr), environmental stable isotopes (18O and 2H) together with major-ion chemistry (chloride, sodium, calcium) has been used to constrain the source(s), relative age, and processes of salinization in the Continental Terminal (CT) aquifer in the Saloum (mid-west Senegal) region. Seventy-one groundwater wells which include 24 wells contaminated by saltwater and three sites along the hypersaline Saloum River were sampled to obtain additional information on the hydrochemical characteristics of the groundwater defined in previous studies. Use of Br against Cl confirms the Saloum River saline water intrusion up to a contribution of 7% into the aquifer. In addition to this recent intrusion, a relatively ancient intrusion of the Saloum River water which had reached at least as far as 20 km south from the source was evidenced. The high molar ratio values of Sr/Cl and Sr/Ca indicate an additional input of strontium presumably derived from carbonate precipitation/dissolution reactions and also via adsorption reactions. The variable B concentrations (7-650 microg/L) found in the groundwater samples were tested against the binary mixing model to evaluate the processes of salinization which are responsible for the investigated system. Sorption of B and depletion of Na occur as the Saloum river water intrudes the aquifer (salinization) in the northern part of the region, whereas B desorption and Na enrichment occur as the fresh groundwater flushing displaces the saline waters in the coastal strip (refreshening). In the central zone where ancient intrusion prevailed, the process of freshening of the saline groundwater is indicated by the changes in major-ion chemistry as well as B desorption and Na enrichment. In addition to these processes, stable isotopes reveal that mixing with recently infiltrating waters and evaporation contribute to the changes in isotopic signature.
authors.affiliation: Geology Department, Faculty of Sciences and Techniques, University Cheikh Anta Diop (UCAD)-Dakar, P.O. Box 5005, Senegal.
authors.forename: Serigne
authors.initials: S
authors.lastname: Faye
authors.forename: Piotr
authors.initials: P
authors.lastname: Maloszewski
authors.forename: Willibald
authors.initials: W
authors.lastname: Stichler
authors.forename: Peter
authors.initials: P
authors.lastname: Trimborn
authors.forename: Seynabou
authors.initials: S
authors.lastname: Cissé Faye
authors.forename: Cheikh
authors.initials: C
authors.lastname: Bécaye Gaye
mesh_terms: D004784:Environmental Monitoring; D005618:Fresh Water / Q000737:chemistry*; D055593:Geological Phenomena; D005844:Geology; D007554:Isotopes / Q000032:analysis; D045483:Rivers / Q000737:chemistry; D012675:Senegal; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D007554:Isotopes; D014874:Water Pollutants, Chemical