title: [Assay of three kinds of aluminum fractions (Al(a), Al(b) and Al(c)) in polynuclear aluminum solutions by Al-Ferron timed spectrophotometry and demarcation of their time limits].
abstract: Al-Ferron timed spectrophotometry assay is a basic method in the study on the formation of polynuclear hydroxyl aluminum species and their transformation laws in aqueous systems. In actual working process, this methodology has some dogmatism and arbitrariness in the time limits demarcation of the three kinds of aluminum fractions (Al(a), Al(b) and Al(c)) in polynuclear aluminum solutions, which makes this kind of classification rougher, and the experimental results non-reproducible. The reason for this difference is that the specific species within Al(a), Al(b) and Al(c) have different reaction mechanism and dynamics, and that specific species of Al(b) having different OH/Al ratios have different reaction rates with ferron. In this paper, the ExpAssoc distribution was applied to quantitatively fit the Al-Ferron reaction dynamics curve, and the extrapolation method was used to survey the 1 min measured value [Al(a)] of monomeric Al, which is hard to obtain in manual manipulation. The time demarcation between Al(b) and Al(c) should reach the point of the experimental data curve up to horizontal platform. The microwave-radiated technology was used to fast assay the total aluminum concentration [Al(T)]. With these methods, the contents of monomeric Al(a), polynuclear Al(b) and gel Al(c) can be conveniently and quantitatively measured. It offers a novel method for surmounting the arbitrariness in the measurement of the three kinds of aluminum fractions and the repetitive calculation of Al(a) and Al(b).
authors.affiliation: Department of Chemistry, Nanjing University, Nanjing 210093, China.
authors.forename: Chen-yi
authors.initials: CY
authors.lastname: Wang
authors.forename: Cai-hua
authors.initials: CH
authors.lastname: Zhang
authors.forename: Shu-ping
authors.initials: SP
authors.lastname: Bi
authors.forename: Zhen-chao
authors.initials: ZC
authors.lastname: Zhang
authors.forename: Wei-hua
authors.initials: WH
authors.lastname: Yang
mesh_terms: D000535:Aluminum / Q000032:analysis* / Q000737:chemistry; D006912:Hydroxyquinolines / Q000032:analysis* / Q000737:chemistry; D007700:Kinetics; D008956:Models, Chemical; D009941:Organomercury Compounds / Q000032:analysis* / Q000737:chemistry; D012996:Solutions; D013053:Spectrophotometry / Q000379:methods*; D013997:Time Factors
chemical_list: D006912:Hydroxyquinolines; D009941:Organomercury Compounds; D012996:Solutions; C002833:8-hydroxy-7-iodo-5-quinolinesulfonic acid; D000535:Aluminum