[Raman spectra study on the GeS2-Ga2S3-KCl system glasses].
Raman spectra of GeS2 -Ga2S3-KCl pseudo-ternary system glasses at room temperature in the air were probed systematically in the region of 150-500 cm(-1). Based on the results of Raman spectra and preparing procedure in pseudo-binary systems GeS2 -KCl and Ga2S3 -KCl, the sole interaction of Ga2S3 and KCl was identified and new units GaS3/2 Cl were produced in GeS2 -Ga2S3-KCl glasses. That K+ ions in the form of Cl as the nearest coordination were homogeneously dispersed in the polymeric network was confirmed by the Raman spectra evolution of samples on the serials I and Ill. Raman spectral evolution of three composition serials can be successfully interpreted using a localized model considering the effect of K+ ions on the structural units GaS3/2 Cl and Ga2 S4 Cl2.
Tao
Hai-Zheng
HZ
Wuhan University of Technology, Wuhan, China.
Zhao
Xiu-Jian
XJ
Jing
Cheng-Bin
CB
Tong
Wei
W
D000465:Algorithms; D002712:Chlorides / Q000737:chemistry; D005708:Gallium / Q000737:chemistry*; D005857:Germanium / Q000737:chemistry*; D005898:Glass / Q000737:chemistry*; D008956:Models, Chemical; D011188:Potassium / Q000737:chemistry*; D013059:Spectrum Analysis, Raman; D013696:Temperature
D002712:Chlorides; D005857:Germanium; D005708:Gallium; D011188:Potassium