Dependence of irradiation temperature in the response of iron salts.
A potential dosimeter based on aqueous frozen solutions and solid-state salt are presented for the evaluation of the energy transferred during the interaction of high-energy radiation with matter at low temperature. The foundation of these dosimeters, both the solid state and the frozen solutions, is based on the measurement of the change of the iron oxidation state. The systems were irradiated with gamma radiation at different doses (up to 10 MGy), and at different temperatures (from 77 to 298 K). The irradiated samples were analysed by UV-spectroscopy and Mössbauer spectroscopy. A theoretical model was developed for the chemical reactions system. This model reproduces the experimental effects produced by the irradiation in aqueous solutions of ferrous salt. The results showed that the response of the dosimeters depends on the irradiation temperature. At low-radiation doses, the response was linear. In particular, this work can be applied to low-temperature dosimetry can be specially applied to simulation experiments of extraterrestrial bodies, as well as in general to space research.
Martínez
T
T
Facultad de Química, UNAM, Ciudad Universitaria, México DF, Mexico.
Lartigue
J
J
Frias
D
D
Sanchez-Mejorada
G
G
Negrón-Mendoza
A
A
Ramos-Bernal
S
S
D003080:Cold Temperature; D004735:Energy Transfer; D005118:Extraterrestrial Environment; D005296:Ferrous Compounds / Q000528:radiation effects*; D005615:Freezing; D008956:Models, Chemical; D011829:Radiation Dosage; D011834:Radiation Monitoring / Q000379:methods*; D013696:Temperature
D005296:Ferrous Compounds; C020748:ferrous sulfate