[High temperature Raman spectra and structure character study of BSO crystal].
The structure character of BSO crystal at room temperature was generalized. The main Raman shifts of lattice vibration at room temperature were interpreted. The Raman spectra of BSO crystal were measured in a temperature range from 293 K to 1123 K with high temperature Raman spectroscopy and time-resolved detection techniques. Temperature-dependence character of the Raman spectra of the crystal was investigated. The vibration mode of the longest bond Bi-O(1) in crystal shifts from 542 cm(-1) to 512 cm(-1) with the temperature increasing from room temperature to 1123 K. It can be attributed to the fact that oxygen atoms are electrostatic bond to Bi atoms. The intensity of 88 cm(-1) modes, which belongs to combination mode of bending and stretching in Bi3O4 unit, changes not so noticeably as other modes, and even the 58 cm(-1) mode of Bi atoms motions in crystal lattice decreases rapidly when the temperature is higher than 873 K, which indicates that the framework structure of the crystal is broken down at high temperature, while the Bi3O4 unit still exists.
Qiu
Huai-li
HL
Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China.
Wang
Ai-hua
AH
You
Jing-lin
JL
Liu
Xiao-jing
XJ
Chen
Hui
H
Yin
Shao-tang
ST
D001729:Bismuth / Q000737:chemistry*; D003460:Crystallization; D006358:Hot Temperature; D008958:Models, Molecular; D010087:Oxides / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry; D017655:Silicon Compounds / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry; D013059:Spectrum Analysis, Raman / Q000379:methods*
D010087:Oxides; D017655:Silicon Compounds; D012822:Silicon Dioxide; C033301:bismuth oxide; D010100:Oxygen; D001729:Bismuth