title: Isomer-selective adsorption of amino acids by components of natural sediments.
abstract: We present evidence that under circumstances of low pH and organic-free surfaces an ordinary estuarine sediment can exhibit strong optical isomer selectivity in its absorption of a number of amino acids. This selectivity can also be seen to a lesser degree in the minerals quartz, montmorillonite, and kaolin. Adsorption reactions were performed with racemic amino acid mixtures, and after equilibrium, deviations from a D/L ratio of 1 were measured and in many cases were found to be significant. This was particularly pronounced at pH 4.0, where selective removal of the L isomers by adsorption onto sedimentfractions was almosttotal. Changes in both the nature and degree of selectivity were also observable in different sediment size fractions. While we are at this stage unable to identify the mode of primary selectivity, adsorption experiments with these candidate sediment components, quartz, kaolin, and montmorillonite do exhibit some selective behavior. We believe that the existence of natural chirally selective components in sediment may indicate a new approach to the development of chiral catalysis and synthesis.
authors.affiliation: Department of Earth and Ocean Sciences, University of Liverpool, Liverpool L69 3GP, United Kingdom.
authors.forename: M
authors.initials: M
authors.lastname: Wedyan
authors.forename: M R
authors.initials: MR
authors.lastname: Preston
mesh_terms: D000327:Adsorption; D000596:Amino Acids / Q000737:chemistry*; D001546:Bentonite / Q000737:chemistry; D002851:Chromatography, High Pressure Liquid; D019015:Geologic Sediments / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007536:Isomerism; D007616:Kaolin / Q000737:chemistry
chemical_list: D000596:Amino Acids; D001546:Bentonite; D007616:Kaolin