A 3-D noninterpenetrating diamondoid network of a decanuclear copper(I) complex.
The solvothermal reaction of CuCl(2).2H(2)O with pyridine-4-thiol and ethanol yielded a novel photoluminescent 3-D polymeric complex with an interesting decorated diamondoid network that is constructed of decanuclear copper(I) cluster units and mu(4)-Cl ligands. The in situ generation of CuSO(4).5H(2)O implies the spontaneous occurrence of desulfurization and redox reactions in the present system.
Cheng
Jian-Kai
JK
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China.
Chen
Yu-Biao
YB
Wu
Ling
L
Zhang
Jian
J
Wen
Yi-Hang
YH
Li
Zhao-Ji
ZJ
Yao
Yuan-Gen
YG