title: Immobilized metal ion-containing ionic liquids: preparation, structure and catalytic performance in Kharasch addition reaction.
abstract: Immobilized metal ion-containing ionic liquid catalysts were prepared by the reaction between silyl-functionalized imidazolium ionic molecules and surface silanol groups of silica, followed by addition of MnCl2, FeCl2, CoCl2, NiCl2, CuCl2, or PdCl2; only the immobilized copper catalyst, which has a sandwiched CuCl4(2-) moiety, was very active for the Kharasch reaction between styrene and CCl4.
authors.affiliation: Department of Chemistry, Graduate School of Science, University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113, Japan.
authors.forename: Takehiko
authors.initials: T
authors.lastname: Sasaki
authors.forename: Chongmin
authors.initials: C
authors.lastname: Zhong
authors.forename: Mizuki
authors.initials: M
authors.lastname: Tada
authors.forename: Yasuhiro
authors.initials: Y
authors.lastname: Iwasawa