title: Theoretical aspects of fluoride air contaminant formation in aluminium smelter potrooms.
abstract: The amount of particulate fluorides evolved from aluminium electrolysis cells is not entirely accounted for by the fluorides entrained in the anode gas. The largest additional source of particulate fluoride formation is by direct evaporation of fluorides into the anode gas stream and subsequent condensation on the drops of electrolyte generated in the process of bubble burst. A theoretical model was used for the calculation of the main physical parameters responsible for the formation of particle nuclei when the hot anode-gas is mixed with ambient air. The results of these calculations are in agreement with experimental observations reported in the literature. In particular, the size distribution, composition and morphology of the nano-particles support the theory of a vapour condensation mechanism under conditions of extreme supersaturation, but further studies are necessary.
authors.affiliation: Department of Analytical Chemistry, St Petersburg State Polytechnic University, Politekhnicheskaya ul. 29, 195251, St Petersburg, Russia.
authors.forename: Boris V
authors.initials: BV
authors.lastname: L'vov
authors.forename: Leonid K
authors.initials: LK
authors.lastname: Polzik
authors.forename: Stephan
authors.initials: S
authors.lastname: Weinbruch
authors.forename: Dag G
authors.initials: DG
authors.lastname: Ellingsen
authors.forename: Yngvar
authors.initials: Y
authors.lastname: Thomassen
mesh_terms: D016902:Air Pollution, Indoor / Q000032:analysis*; D000535:Aluminum / Q000737:chemistry; D004572:Electrolysis; D005459:Fluorides / Q000032:analysis*; D005740:Gases; D008669:Metallurgy; D008962:Models, Theoretical; D010316:Particle Size
chemical_list: D005740:Gases; D000535:Aluminum; D005459:Fluorides