The step-wise assembly of an undecanuclear heterotrimetallic cyanide cluster.
The step-wise assembly of the high nuclearity cluster, {[Ni(II)(H2O)5]6[Co(III)(tmphen)2]3[Fe(II)(CN)6]2}13+, is achieved by treating {[Co(tmphen)2]3[Fe(CN)6]2} with six equivalents of Ni(ClO4)2 in aqueous MeOH.
Berlinguette
Curtis P
CP
Department of Chemistry, Texas A&M University, College Station, TX, USA.
Dunbar
Kim R
KR