Structure and magnetic properties of a novel copper halide framework {[tBuNH3]2[Cu3(mu3-OH)(mu2-H2O)Cl7]}n synthesized via in situ templation.
The use of the tris(alkylamido)phosphate OP[N(H)tBu]3 as an in situ source of the templating agent [tBuNH3]+ produces the copper halide chain {[tBuNH3]2[Cu3(mu3-OH)(mu2-H2O)Cl7]}n (1) in a solvothermal process; the novel antiferromagnetically coupled trinuclear fragment Cu3(OH)(H2O)Cl7 is the building block in the polymeric anion in .
Chivers
Tristram
T
Department of Chemistry, University of Calgary, Calgary, Alberta, Canada. chivers@ucalgary.ca
Fu
Zhiyong
Z
Thompson
Laurence K
LK
D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006863:Hydrogen-Ion Concentration; D008280:Magnetics; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry*; D013696:Temperature
D009942:Organometallic Compounds; D011108:Polymers; D003300:Copper