title: Enantioselective allylation of aldehydes catalyzed by chiral indium(III) complexes immobilized in ionic liquids.
abstract: In the presence of chiral catalytic complexes prepared from In(OTf)3 and chiral PYBOX ligands, allytributylstannane reacted with aldehydes in ionic liquids to afford the corresponding homoallylic alcohols in high enantioselectivities (86-94% ee) and good yields (68-89%); the chiral catalysts immobilized in ionic liquids could be reused with comparable enantioselectivities and yields.
authors.affiliation: Key Lab. of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering of Suzhou University, Suzhou, 215006, China. shunjun@suda.edu.cn
authors.forename: Jun
authors.initials: J
authors.lastname: Lu
authors.forename: Shun-Jun
authors.initials: SJ
authors.lastname: Ji
authors.forename: Teck-Peng
authors.initials: TP
authors.lastname: Loh
mesh_terms: D000438:Alcohols / Q000138:chemical synthesis*; D000447:Aldehydes / Q000138:chemical synthesis* / Q000737:chemistry; D000478:Alkylation; D002384:Catalysis; D007204:Indium / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D009947:Organotin Compounds / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000438:Alcohols; D000447:Aldehydes; D052578:Ionic Liquids; D009942:Organometallic Compounds; D009947:Organotin Compounds; D007204:Indium