Polymer-supported manganese porphyrin catalysts--peptide-linker promoted chemoselectivity.
Manganese porphyrin catalysts were tethered to polymer-supports via peptide linkers. The reactivity and chemoselectivity of the catalysts were assessed in the epoxidation of limonene. It was found that the inclusion of a peptide linker incorporating a donor heteroatom which could act as an axial ligand led to a supported manganese porphyrin catalyst with unprecedented selectivity and stability.
Brulé
Emilie
E
Department of Chemistry, Organic Chemistry, Royal Institute of Technology, Stockholm, Sweden.
Hii
King Kuok Mimi
KK
de Miguel
Yolanda R
YR
D002384:Catalysis; D008401:Gas Chromatography-Mass Spectrometry; D009682:Magnetic Resonance Spectroscopy; D008345:Manganese / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared
D011108:Polymers; D011166:Porphyrins; D008345:Manganese