4-Connected metal-organic assemblies mediated via heterochelation and bridging of single metal ions: Kagome lattice and the M6L12 octahedron.
Single-metal-ion-based rigid molecular building blocks (MBBs) have been utilized to design and synthesize novel metal-organic assemblies. Reaction between In(NO3)3.2H2O and 2,5-pyridinedicarboxylic acid (2,5-H2PDC) has permitted the assembly of two supramolecular isomers, a Kagomé lattice and an unprecedented M6L12 discrete octahedron.
Liu
Yunling
Y
Department of Chemistry, University of South Florida, Tampa, 33620, USA.
Kravtsov
Victor Ch
VCh
Beauchamp
Derek A
DA
Eubank
Jarrod F
JF
Eddaoudi
Mohamed
M