title: Vertical fluxes and accumulation of PCBs in coastal sediments of the Río de la Plata estuary, Argentina.
abstract: Settling particles and underlying sediments collected at 1, 2.5 and 4 km along offshore transects in the urbanized sector of the Río de la Plata were analyzed to evaluate the sources and accumulation of PCBs. Total PCB concentrations range from <0.1 to 100 ng g(-1) and include variability associated to North-South and offshore gradients reflecting the impact of coastal discharges. Highest concentrations were recorded in the industrialized Central area close to Buenos Aires (61+/-37 ng g(-1) at 1 km) relative to cleaner northern stations (3.6+/-2.2 ng g(-1)) and southward sites (37+/-2.8 ng g(-1)), affected by transport of particulate PCBs by coastal currents. Sediment traps deployed in the Central area revealed large depositional fluxes of total matter (361+/-124 gm(-2)day(-1)) and PCBs (26+/-19 microg m(-2)day(-1)) and high sedimentation rates (5.0+/-1.7 cm yr(-1)). Uniform PCB concentrations (66-89 ng g(-1)) down to 20 cm in sediment cores suggest continued PCB discharges during the last 4 years. PCB composition was dominated by hexa (43+/-6.4%), hepta (23+/-5.1%) and pentachlorobiphenyls (21+/-5.5%) with lower proportions tri-tetra (7.4+/-5.4%) and higher chlorinated congeners (5.1+/-3.3%). A consistent weathering pattern with loss of 3-5 chlorobiphenyls and enrichment in higher chlorinated PCBs corresponding to a shift from a 1:1 to a 1:3 1254:1260 Aroclor mixture, was observed offshore. A principal component analysis performed with the relative contribution of PCB congener classes confirmed the offshore weathering pattern indicating that transformer oils containing Aroclor 1254-1260 are the most probable sources. Sediment inventories, sediment trap fluxes and Fugacity II calculations indicate an accumulation approximately 500-800 kg PCB in superficial sediments of this coastal environment.
authors.affiliation: Laboratorio de Química Ambiental y Biogeoquímica, Facultad de Ciencias Naturales y Museo, Universidad Nacional de La Plata, Av. Calchaqui km 23500 (1888) Florencio Varela, Buenos Aires, Argentina. laqab@intervar.com.ar
authors.forename: J C
authors.initials: JC
authors.lastname: Colombo
authors.forename: N
authors.initials: N
authors.lastname: Cappelletti
authors.forename: A
authors.initials: A
authors.lastname: Barreda
authors.forename: M C
authors.initials: MC
authors.lastname: Migoya
authors.forename: C N
authors.initials: CN
authors.lastname: Skorupka
mesh_terms: D001118:Argentina; D002947:Cities; D004784:Environmental Monitoring; D004785:Environmental Pollutants / Q000032:analysis*; D019015:Geologic Sediments / Q000737:chemistry*; D011078:Polychlorinated Biphenyls / Q000032:analysis*; D025341:Principal Component Analysis
chemical_list: D004785:Environmental Pollutants; D011078:Polychlorinated Biphenyls