Metal-metal interactions in platinum(II)/gold(I) or platinum(II)/silver(I) salts containing planar cations and linear anions.
The salts [Pt{C(NHMe)(2)}(4)][Au(CN)(2)](2), [Pt{C(NHMe)(2)}(4)][Ag(2)(CN)(3)][Ag(CN)(2)], [Pt(en)(2)][Au(CN)(2)](2), [Pt(en)(2)][Ag(CN)(2)](2), and [Pt(bipy)(2)][Au(CN)(2)](2) have been prepared by mixing solutions of salts containing the appropriate cation with solutions of K[Au(CN)(2)] or K[Ag(CN)(2)]. Because the platinum atom in the cation is sterically protected, the structures of [Pt{C(NHMe)(2)}(4)][Au(CN)(2)](2) and [Pt{C(NHMe)(2)}(4)][Ag(2)(CN)(3)][Ag(CN)(2)] reveal no close metal-metal interactions. Colorless crystals of [Pt(en)(2)][Au(CN)(2)](2) and [Pt(en)(2)][Ag(CN)(2)](2) are isostructural and involve extended chains of alternating cations and anions that run parallel to the crystallographic a axis, along with isolated anions. In the chains, the metal-metal separations are relatively short: Pt...Au, 3.1799(3) Angstroms; Pt...Ag, 3.1949(2) Angstroms. In [Pt(bipy)(2)][Au(CN)(2)](2), each cation has axial interactions with the anions through close Pt...Au contacts [3.1735(6) Angstroms]. In addition, the anions are weakly linked through Au...Au contacts of 3.5978(9) Angstroms. Unlike the previously reported Pt/Au complex [Pt(NH(3))(4)][Au(CN)(2)](2).1.5H(2)O, which is luminescent, none of the salts reported here luminesce.
Stork
Jay R
JR
Department of Chemistry, University of California, Davis, 95616, USA.
Rios
Daniel
D
Pham
David
D
Bicocca
Vincent
V
Olmstead
Marilyn M
MM
Balch
Alan L
AL
D000838:Anions / Q000737:chemistry; D002412:Cations / Q000737:chemistry; D018360:Crystallography, X-Ray; D006046:Gold / Q000737:chemistry*; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010984:Platinum / Q000737:chemistry*; D012492:Salts / Q000138:chemical synthesis; D012834:Silver / Q000737:chemistry*
D000838:Anions; D002412:Cations; D009942:Organometallic Compounds; D012492:Salts; D012834:Silver; D010984:Platinum; D006046:Gold