Titanium-mediated alkylative coupling of N-acylpyrroles.
[reaction: see text]. Inter- and intramolecular titanium-mediated coupling reactions of N-acylpyrroles are reported for convenient functionalization of terminal olefins. Comparison with the Kulinkovich reaction of esters and other carboxylic acid derivatives is also included.
Epstein
Oleg L
OL
Department of Chemistry, Wayne State University, 5101 Cass Avenue, Detroit, Michigan 48202, USA.
Seo
Jung Min
JM
Masalov
Nikolai
N
Cha
Jin Kun
JK
D000475:Alkenes / Q000737:chemistry; D000478:Alkylation; D002384:Catalysis; D007202:Indicators and Reagents; D015394:Molecular Structure; D011758:Pyrroles / Q000138:chemical synthesis* / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*
D000475:Alkenes; D007202:Indicators and Reagents; D011758:Pyrroles; D014025:Titanium