title: A 3-D noninterpenetrating diamondoid network of a decanuclear copper(I) complex.
abstract: The solvothermal reaction of CuCl(2).2H(2)O with pyridine-4-thiol and ethanol yielded a novel photoluminescent 3-D polymeric complex with an interesting decorated diamondoid network that is constructed of decanuclear copper(I) cluster units and mu(4)-Cl ligands. The in situ generation of CuSO(4).5H(2)O implies the spontaneous occurrence of desulfurization and redox reactions in the present system.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China.
authors.forename: Jian-Kai
authors.initials: JK
authors.lastname: Cheng
authors.forename: Yu-Biao
authors.initials: YB
authors.lastname: Chen
authors.forename: Ling
authors.initials: L
authors.lastname: Wu
authors.forename: Jian
authors.initials: J
authors.lastname: Zhang
authors.forename: Yi-Hang
authors.initials: YH
authors.lastname: Wen
authors.forename: Zhao-Ji
authors.initials: ZJ
authors.lastname: Li
authors.forename: Yuan-Gen
authors.initials: YG
authors.lastname: Yao