Persistent (amino)(silyl)carbenes.
(Amino)(silyl)carbenes, prepared by substitution reactions at a carbene center, can survive several days at 0 degrees C. These species are not push-pull carbenes as their phosphino analogues and therefore are excellent ligands for transition-metal centers.
Canac
Yves
Y
UCR-CNRS Joint Research Chemistry Laboratory (UMR 2282), Department of Chemistry, University of California, Riverside, 92521-0403, USA.
Conejero
Salvador
S
Donnadieu
Bruno
B
Schoeller
Wolfgand W
WW
Bertrand
Guy
G