title: Net changes in nutrient concentrations below a point source input in two streams draining catchments with contrasting land uses.
abstract: We examined net changes in ammonium-Nitrogen (NH(4)(+)-N), nitrate-Nitrogen (NO(3)(-)-N), dissolved inorganic nitrogen (DIN), soluble reactive phosphorus (SRP), and dissolved organic carbon (DOC) chloride-corrected ambient concentrations along a reach located below a wastewater treatment plant (WWTP) input in a non-agricultural (12 dates) and an agricultural (6 dates) stream. Based on those net changes, we estimated processing length (Snet) and mass transfer coefficient (Vf) of the cited nutrients. In the agricultural stream, results suggest that diffuse nutrient inputs from adjacent agricultural fields had a greater effect on water chemistry than the WWTP input, and probably overwhelmed the stream capacity to retain and transform nutrients. In the non-agricultural stream we observed consistent longitudinal trends below the WWTP input only for NH(4)(+)-N and NO(3)(-)-N. The tight coupling between longitudinal NH(4)(+)-N decreases and NO(3)(-)-N increases in the non-agricultural stream, and lack of longitudinal trends of DIN on most dates suggest that NH(4)(+)-N from the WWTP input was being nitrified along the reach. These results suggest that WWTP inputs favor conditions to support hot spots for chemoautotrophic activity.
authors.affiliation: Departament d'Ecologia, Facultat de Biologia, Universitat de Barcelona, Av. Diagonal 645, 08028-Barcelona, Spain. merseburger@ceab.csic.es
authors.forename: Gora C
authors.initials: GC
authors.lastname: Merseburger
authors.forename: Eugènia
authors.initials: E
authors.lastname: Martí
authors.forename: Francesc
authors.initials: F
authors.lastname: Sabater
mesh_terms: D000383:Agriculture; D002244:Carbon / Q000032:analysis; D004784:Environmental Monitoring; D009566:Nitrates / Q000032:analysis; D009584:Nitrogen / Q000032:analysis; D010758:Phosphorus / Q000032:analysis; D000644:Quaternary Ammonium Compounds / Q000032:analysis; D045483:Rivers; D013030:Spain; D014865:Waste Disposal, Fluid; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014881:Water Supply
chemical_list: D009566:Nitrates; D000644:Quaternary Ammonium Compounds; D014874:Water Pollutants, Chemical; D010758:Phosphorus; D002244:Carbon; D009584:Nitrogen