Synthesis of the C11-C23 fragment of spirastrellolide A. A ketal-tethered RCM approach to the construction of spiroketals.
[reaction: see text]. The synthesis of the C11-C23 fragment in spirastrellolide A is described here featuring a ketal-tethered RCM as an alternative approach to the construction of spiroketals.
Liu
Jia
J
Department of Chemistry, University of Minnesota, Minneapolis, Minnesota 55455, USA.
Hsung
Richard P
RP
D000818:Animals; D002384:Catalysis; D007202:Indicators and Reagents; D018942:Macrolides / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D011161:Porifera / Q000737:chemistry; D013141:Spiro Compounds
D007202:Indicators and Reagents; D018942:Macrolides; D013141:Spiro Compounds; C475125:spirastrellolide A