title: The formation, role and removal of NO3-N during corona discharge in air for phenol removal.
abstract: Pulsed corona discharge carried out in the gas phase has been shown to be a low cost solution for wastewater treatment. In this study, the results show that the nitrogen dissociated during corona discharge in the gas phase formed nitric acid in solution, which resulted in a drop in solution pH. The phenol removal could be described in accordance with a first-order reaction in a basic buffer solution, but not in initial neutral and basic non-buffered solutions. This indicates that basic conditions facilitate phenol removal, whilst the formation of nitric acid in solution resulted in decrease in the phenol removal rate. This study also shows that most of the oxidants used for phenol removal came mainly from the dissociation of water molecules at the surface of the liquid phase and/or the gas phase very close to the liquid surface in discharging conditions, not from the gas dissociation in the bulk gas phase, and therefore, it is more effective to keep the solution basic than to change the component of gas in the reactor when removing phenol from water using corona discharge.
authors.affiliation: School of Environmental Science and Engineering, Shanghai Jiaotong University, Shanghai 200240, China.
authors.forename: Z
authors.initials: Z
authors.lastname: He
authors.forename: B
authors.initials: B
authors.lastname: Zhang
authors.forename: W
authors.initials: W
authors.lastname: Cai
authors.forename: B
authors.initials: B
authors.lastname: Zhou
mesh_terms: D003363:Cost Control; D006863:Hydrogen-Ion Concentration; D017942:Nitric Acid / Q000737:chemistry / Q000302:isolation & purification*; D016877:Oxidants / Q000737:chemistry; D010084:Oxidation-Reduction; D019800:Phenol / Q000302:isolation & purification*; D014865:Waste Disposal, Fluid / Q000379:methods*
chemical_list: D016877:Oxidants; D019800:Phenol; D017942:Nitric Acid