Porous lanthanide-organic framework with zeolite-like topology.
Two novel isomorphous porous frameworks of Ln(III), {[Ln2(imidc)2(H2O)3](H2O)}n, [Ln = Gd(III) (1) and Er(III) (2)] have been synthesized hydrothermally using multifunctional 4,5-imidazoledicarboxylic acid (imidc) as a connector; they have a zeolite-like network topology which can provide another form upon dehydration, and exhibit selective adsorption properties for H2O over N2, CO2 and MeOH.
Maji
Tapas Kumar
TK
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishigyo-ku, Kyoto 615-8510, Japan.
Mostafa
Golam
G
Chang
Ho-Chol
HC
Kitagawa
Susumu
S