Model systems for flavoenzyme activity: a tuneable intramolecularly hydrogen bonded flavin-diamidopyridine complex.
We report the electrochemically tuneable intramolecular hydrogen bonding interactions between a covalently linked flavin-diamidopyridine unit.
Boyd
Alan S F
AS
Centre for Biomimetic Design & Synthesis, Chemistry, William H. Perkin Building, School of Engineering & Physical Sciences, Heriot-Watt University, Riccarton, Edinburgh, UK.
Carroll
Joseph B
JB
Cooke
Graeme
G
Garety
James F
JF
Jordan
Brian J
BJ
Mabruk
Suhil
S
Rosair
Georgina
G
Rotello
Vincent M
VM
D002942:Circular Dichroism; D018360:Crystallography, X-Ray; D004563:Electrochemistry; D005415:Flavins / Q000737:chemistry*; D006860:Hydrogen Bonding; D007202:Indicators and Reagents; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D008958:Models, Molecular
D005415:Flavins; D007202:Indicators and Reagents