Molecular study of thermal immobilization of chromium(VI) with clay.
Clay that contains kaolinite has been used extensively as a raw material for manufacturing of bricks and china at 900-1100 degrees C. This study used clay to stabilize the contaminant chromium(VI) [Cr(VI)] through a heating process at 500-1100 degrees C. X-ray absorption spectroscopic results indicated that the 500-900 degrees C heating process transformed hazardous Cr(VI) to nontoxic Cr(III); Cr2O3 was the species detected as most abundant. The 1100 degrees C heating process caused the formation of Cr2SiO5, which was not detected in the samples heated at 500-900 degrees C. Fourier transformed extended X-ray absorption fine structure spectra were fitted by use of WinXAS software. Phase shifts and backscatter(ing) amplitudes for specific atom pairs, based on the crystallographic data for CrO3 and Cr2O3, were theoretically calculated with the FEFF software. The processed XAS data show that the first shell coordination numbers were similar to each other as the temperature was increased from 500 to 900 degrees C and 1100 degrees C, implying that their Cr(III) crystallite size was relatively similar. The interatomic distance between the target center element and the first shell for the 500-1100 degrees C samples was 1.98 A. The Debye-Waller factor for the 1100 degrees C sample was increased compared with the 500 and 900 degrees C samples and probably indicates the formation of Cr2SiO5.
Wei
Yu-Ling
YL
Department of Environmental Science, Tunghai University, Taichung, Taiwan, Republic of China.
Hsieh
Huei-Fang
HF
Yang
Yao-Wen
YW
Lee
Jyh-Fu
JF
Liang
Wei-Shun
WS
D000327:Adsorption; D000538:Aluminum Silicates; D002274:Carcinogens, Environmental / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry*; D000077215:Clay; D004787:Environmental Pollution / Q000517:prevention & control; D012995:Solubility; D013696:Temperature
D000538:Aluminum Silicates; D002274:Carcinogens, Environmental; D002857:Chromium; C074702:chromium hexavalent ion; D000077215:Clay