title: Bis(acesulfamato-kappa2N3,O4)bis(2-aminopyrimidine-kappaN1)copper(II).
abstract: In the crystal structure of the title compound, bis(2-aminopyrimidine-kappaN1)bis[6-methyl-1,2,3-oxathiazin-4(3H)-one 2,2-dioxide(1-)-kappa2N3,O4]copper(II), [Cu(C4H4NO4S)2(C4H5N3)2], the first mixed-ligand complex of acesulfame, the CuII centre resides on a centre of symmetry and has an octahedral geometry that is distorted both by the presence of four-membered chelate rings and by the Jahn-Teller effect. The equatorial plane is formed by the N atoms of two aminopyrimidine (ampym) ligands and by the weakly basic carbonyl O atoms of the acesulfamate ligands, while the more basic deprotonated N atoms of these ligands are in the elongated axial positions with a strong misdirected valence. The crystal is stabilized by pyrimidine ring stacking and by intermolecular hydrogen bonding involving the NH2 moiety of the ampym ligand and the carbonyl O atom of the acesulfamate moiety.
authors.affiliation: Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayís University, TR-55139 Kurupelit Samsun, Turkey. abulut@omu.edu.tr
authors.forename: Ahmet
authors.initials: A
authors.lastname: Bulut
authors.forename: Hasan
authors.initials: H
authors.lastname: Içbudak
authors.forename: Gözde
authors.initials: G
authors.lastname: Sezer
authors.forename: Canan
authors.initials: C
authors.lastname: Kazak