title: Investigation of the reactivity of arylamines, organo-hydrazines and tolylisocyanate towards [PW12-xMxO40]n- Keggin anions.
abstract: Reaction of K7[A,alpha-PW9Mo2O39] with Na2MoO4.2H2O in a mixture of water/dioxane/hydrochloric acid and further precipitation with (Bu4N)Br provided (Bu4N)3[A,alpha-PW9Mo3O40](3). Analogous reaction with K7-xNax[alpha-PW11O39] is an alternative to the synthesis of (Bu4N)3[alpha-PW11O39{MoVIO}]2. Multinuclear NMR and ESI mass spectrometry have been used to interpret the reaction of (Bu4N)x[alpha-PW11O39{ReO}](x=3 1; x=4 1I), (Bu4N)x[alpha-PW11O39{MoO}](x=3 2; x=4 2I) and (Bu4N)3[A,alpha-PW9Mo3O40]3 by organohydrazines, arylamines, tolylisocyanate and tetraphenylphosphine imide.
authors.affiliation: Laboratoire de Chimie Inorganique et Materiaux Moleculaires, UMR CNRS 7071, Universite Pierre et Marie Curie, 4 Place Jussieu, 75252, Paris Cedex 05, France.
authors.forename: C
authors.initials: C
authors.lastname: Dablemont
authors.forename: A
authors.initials: A
authors.lastname: Proust
authors.forename: R
authors.initials: R
authors.lastname: Thouvenot
authors.forename: C
authors.initials: C
authors.lastname: Afonso
authors.forename: F
authors.initials: F
authors.lastname: Fournier
authors.forename: J-C
authors.initials: JC
authors.lastname: Tabet
mesh_terms: D004578:Electron Spin Resonance Spectroscopy; D006834:Hydrazines / Q000737:chemistry*; D017953:Isocyanates / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D000071228:Polyelectrolytes; D011108:Polymers / Q000737:chemistry; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D021241:Spectrometry, Mass, Electrospray Ionization; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D017973:Tungsten Compounds / Q000737:chemistry*
chemical_list: D006834:Hydrazines; D017953:Isocyanates; D000071228:Polyelectrolytes; D011108:Polymers; D000644:Quaternary Ammonium Compounds; D017973:Tungsten Compounds; C009405:tetrabutylammonium