Selective O2 oxidation of air-sensitive lanthanocene thiolates and thioether chelate.
Two unusual regioselective O2 oxidation reactions of air-sensitive lanthanocene thiolates and a thioether chelate are described, revealing a novel oxygenation pattern of thiolate ligands.
Zhou
Xigeng
X
Department of Chemistry, Molecular Catalysis and Innovative Material Laboratory, Fudan University, Shanghai 200433, People's Republic of China. xgzhou@fudan.edu.cn
Zhu
Ming
M
Zhang
Libei
L
Zhu
Zhenyu
Z
Pi
Chengfu
C
Pang
Zhen
Z
Weng
Linhong
L
Cai
Ruifang
R
D000388:Air; D002614:Chelating Agents / Q000737:chemistry*; D018360:Crystallography, X-Ray; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013440:Sulfides / Q000737:chemistry*
D002614:Chelating Agents; D028581:Lanthanoid Series Elements; D008024:Ligands; D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D013440:Sulfides; D010100:Oxygen