Depletion interaction in a quasi-two-dimensional colloid assembly.
We address several aspects of the character of the depletion interaction in a quasi-two-dimensional (Q2D) colloid system. First, we consider how, given information concerning the pair and triplet correlation functions, the depletion interaction can be efficiently and accurately determined. For this purpose we introduce a method based on the Born-Green equation using the assumption that for the Q2D binary mixtures of interest to us the depletion interaction is accurately represented as a sum of pair potentials. We then verify, by direct calculation, that three-particle contributions to the depletion interaction are negligibly small in the region of thermodynamic state space of interest to us. Second, we develop a representation of the dependence of the depletion interaction in a Q2D colloid system on the thickness of the confining parallel plates. Third, we report the results of extensive simulations of Q2D binary hard-sphere mixtures for a range of cell thickness, large and small particle number densities, and a ratio of sphere diameters q=0.3 .
Frydel
Derek
D
Department of Chemistry and The James Franck Institute, The University of Chicago, Chicago, Illinois 60637, USA.
Rice
Stuart A
SA