"Cation pool" method based on C-C bond dissociation. Effective generation of monocations and dications.
The "cation pools" of alkoxyarylcarbenium ions were effectively generated by the oxidative C-C bond dissociation using low temperature electrolysis. The present method is especially effective for the generation and accumulation of dications, which react with carbon nucleophiles.
Okajima
Masayuki
M
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan.
Suga
Seiji
S
Itami
Kenichiro
K
Yoshida
Jun-ichi
J