Radical addition to "cation pool". Reverse process of radical cation fragmentation.
The reaction of an N-acyliminium ion with an alkyl iodide and hexabutyldistannane took place to give the alkylation product. A mechanism involving the addition of an alkyl radical to an N-acyliminium ion to produce the corresponding radical cation has been suggested.
Maruyama
Tomokazu
T
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Japan.
Suga
Seiji
S
Yoshida
Jun-ichi
J