title: Regioselective Lewis acid-mediated [1,3] rearrangement of allylvinyl ethers.
abstract: [reaction: see text]. Aluminum and copper Lewis acids were implemented to effect a regioselective [1,3] rearrangement of allylvinyl ethers in moderate to good yields. The use of trisubstituted alkenes leads to depressed levels of Claisen products.
authors.affiliation: Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
authors.forename: Christopher G
authors.initials: CG
authors.lastname: Nasveschuk
authors.forename: Tomislav
authors.initials: T
authors.lastname: Rovis
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000535:Aluminum / Q000737:chemistry; D002384:Catalysis; D003300:Copper / Q000737:chemistry; D004987:Ethers / Q000737:chemistry*; D007202:Indicators and Reagents; D015394:Molecular Structure; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000737:chemistry*
chemical_list: D000475:Alkenes; D004987:Ethers; D007202:Indicators and Reagents; D014753:Vinyl Compounds; C100195:vinyl ether; D003300:Copper; D000535:Aluminum