title: Salicylate poly(vinyl chloride) membrane electrode based on (2-[(E)-2-(4-nitrophenyl) hydrazono]-1-phenyl-2-(2-quinolyl)-1-ethanone) Cu(II).
abstract: A new salicylate-selective electrode based on the complex of (2-[(E)-2-(4-nitrophenyl)hydrazono]-1-phenyl-2-(2-quinolyl)-1-ethanone) Cu(II) as the membrane carrier was developed. The electrode exhibited a good Nernstian slope of -59.6+/-1.0 mV/decade and a linear range of 1.0 x 10(-6) to 1.0M for salicylate. The limit of detection was 5.0 x 10(-7) M. The electrode had a fast response time of 10 s and can be used for more than 3 months. The selective coefficients were determined by the fixed interference method and could be used in the pH range of 4.0 to 10.5. The electrode was employed as an indicator electrode for direct determination of salicylate in pharmaceutical and biological samples.
authors.affiliation: Department of Chemistry, Faculty of Science, Yazd University, Yazd, Iran. mazloum@yazduni.ac.ir
authors.forename: M Mazloum
authors.initials: MM
authors.lastname: Ardakani
authors.forename: M S
authors.initials: MS
authors.lastname: Jalayer
authors.forename: J
authors.initials: J
authors.lastname: Safari
authors.forename: Z
authors.initials: Z
authors.lastname: Sadeghi
authors.forename: H R
authors.initials: HR
authors.lastname: Zare
mesh_terms: D004566:Electrodes; D006835:Hydrazones / Q000737:chemistry*; D008567:Membranes, Artificial; D009942:Organometallic Compounds / Q000737:chemistry*; D011143:Polyvinyl Chloride / Q000737:chemistry*; D011199:Potentiometry / Q000379:methods*; D020156:Salicylic Acid / Q000032:analysis*
chemical_list: C504342:(2-(2-(4-nitrophenyl)hydrazono)-1-phenyl-2-(2-quinolyl)-1-ethanone)copper(II); D006835:Hydrazones; D008567:Membranes, Artificial; D009942:Organometallic Compounds; D011143:Polyvinyl Chloride; D020156:Salicylic Acid