title: Removal and pre-concentration of phenolic species onto beta-cyclodextrin modified poly(hydroxyethylmethacrylate-ethyleneglycoldimethacrylate) microbeads.
abstract: Poly(Hydroxyethylmethacrylate-Ethyleneglycoldimethacrylate), poly(HEMA-EGDMA), microbeads with 150-200 microm in size, was prepared by suspension polymerization. Beta-cyclodextrin was modified onto the polymeric microbeads using glutaraldahyde activation in an acidic medium at pH=2.5. FT-IR and TGA were used for the characterization of modified polymers and the determination of the nature of the interaction between phenolic compounds and the modified polymeric microbeads. Plain and beta-cyclodextrin modified microbeads were used in adsorption-desorption studies of phenolic species in single solution. Adsorption capacities of the phenolic species onto the plain microbeads were found to be 28.2, 17.0, 14.3, 9.8, and 1.92 mg/g polymer for o-chloro phenol, p-nitro phenol, p-chloro phenol, o-nitro phenol, and phenol, respectively. However, for beta-cyclodextrin modified microbeads, adsorption capacity of phenolic species was determined as 274, 365, 128, 182, and 87 mg/g for phenol, o-nitro phenol, p-nitro phenol, o-chloro phenol, and p-chloro phenol, respectively. Desorption ratio for the phenolic species was more than 90%, except for o-nitro phenol. Detection limits of the phenolic species were improved at least 500-fold for UV-Vis spectrophotometric detection, after the pre-concentration of all phenolic species used in this study. Adsorption time for the phenolic species onto beta-cyclodextrin-modified poly(HEMA-EGDMA) microbeads was found to be reasonable short (10-60 min) and suitable for the applications. Also, synthesized microbeads were useful for the repeated use for the removal and pre-concentration of phenolic species.
authors.affiliation: Department of Chemistry, Hacettepe University, Beytepe, 06532 Ankara, Turkey.
authors.forename: Ismail
authors.initials: I
authors.lastname: Abay
authors.forename: Adil
authors.initials: A
authors.lastname: Denizli
authors.forename: Erhan
authors.initials: E
authors.lastname: Bişkin
authors.forename: Bekir
authors.initials: B
authors.lastname: Salih
mesh_terms: D000327:Adsorption; D010316:Particle Size; D010636:Phenols / Q000737:chemistry* / Q000302:isolation & purification*; D011109:Polymethacrylic Acids / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification; D047392:beta-Cyclodextrins
chemical_list: D010636:Phenols; D011109:Polymethacrylic Acids; D014874:Water Pollutants, Chemical; D047392:beta-Cyclodextrins; C107571:poly(ethyleneglycol dimethacrylate-2-hydroxyethylmethacrylate)