A new self-assembling capsule via metal coordination.
A new octadentate cavitand forms a stable dimeric molecular capsule via metal-coordination, creating a large and elaborate three-dimensional cavity in which large aromatic guests are accommodated to form supramolecular complexes.
Haino
Takeharu
T
Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima, 739-8526, Japan. haino@sci.hiroshima-u.ac.jp
Kobayashi
Mutsumi
M
Chikaraishi
Midori
M
Fukazawa
Yoshimasa
Y
D019281:Dimerization; D009682:Magnetic Resonance Spectroscopy / Q000379:methods / Q000592:standards; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012015:Reference Standards; D012680:Sensitivity and Specificity; D012834:Silver / Q000737:chemistry*; D013237:Stereoisomerism
D009942:Organometallic Compounds; D012834:Silver