title: Achiral ligands dramatically enhance rate and enantioselectivity in the Rh/phosphoramidite-catalyzed hydrogenation of alpha,beta-disubstituted unsaturated acids.
authors.affiliation: Department of Organic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.
authors.forename: Rob
authors.initials: R
authors.lastname: Hoen
authors.forename: Jeroen A F
authors.initials: JA
authors.lastname: Boogers
authors.forename: Heiko
authors.initials: H
authors.lastname: Bernsmann
authors.forename: Adriaan J
authors.initials: AJ
authors.lastname: Minnaard
authors.forename: Auke
authors.initials: A
authors.lastname: Meetsma
authors.forename: Theodora D
authors.initials: TD
authors.lastname: Tiemersma-Wegman
authors.forename: André H M
authors.initials: AH
authors.lastname: de Vries
authors.forename: Johannes G
authors.initials: JG
authors.lastname: de Vries
authors.forename: Ben L
authors.initials: BL
authors.lastname: Feringa
mesh_terms: D000143:Acids / Q000737:chemistry*; D000179:Acrylates / Q000737:chemistry; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D008024:Ligands; D008689:Methacrylates / Q000737:chemistry; D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010666:Phenylpropionates / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000143:Acids; D000179:Acrylates; D008024:Ligands; D008689:Methacrylates; D009943:Organophosphorus Compounds; D010666:Phenylpropionates; C510582:alpha-methylcinnamic acid; C434331:phosphoramidite; D006859:Hydrogen; D012238:Rhodium; C036658:acrylic acid