title: An alternate route for the synthesis of hybrid mesoporous organosilica with crystal-like pore walls from allylorganosilane precursors.
abstract: The bridged allylorganosilanes 1,4-bis(diallylethoxysilyl)benzene and 1,4-bis(triallylsilyl)benzene are presented as new precursors for the surfactant-assisted synthesis of ordered mesoporous organosilica with pore walls having crystal-like molecular-scale periodicity. This approach provides a new route to the formation of periodic mesostructures with crystal-like pore walls. The synthesis method presented is applicable to the preparation of mesoporous organosilica with bulky organic groups, the precursors of which are typically impossible to obtain in high purity.
authors.affiliation: Toyota Central R and D Laboratories, Inc., Nagakute, Aichi 480-1192, Japan.
authors.forename: Mahendra P
authors.initials: MP
authors.lastname: Kapoor
authors.forename: Shinji
authors.initials: S
authors.lastname: Inagaki
authors.forename: Shushiro
authors.initials: S
authors.lastname: Ikeda
authors.forename: Kiyomi
authors.initials: K
authors.lastname: Kakiuchi
authors.forename: Masahiko
authors.initials: M
authors.lastname: Suda
authors.forename: Toyoshi
authors.initials: T
authors.lastname: Shimada