Significant viscosity dependent deviations from classical van Deemter theory in liquid chromatography with porous silica monolithic columns.
Significant deviations from classical van Deemter behaviour, indicative of turbulent flow liquid chromatography, has been recorded for mobile phases of varying viscosity on porous silica monolithic columns at elevated mobile phase flow rates.
Nesterenko
Pavel N
PN
Department of Chemstry, M.V. Lomonosov Moscow State University, 119899 Moscow, Russian Federation. PavelN@analyt.chem..msu.ru
Rybalko
Marina A
MA
Paull
Brett
B
D002853:Chromatography, Liquid / Q000295:instrumentation*; D012212:Rheology; D012822:Silicon Dioxide / Q000737:chemistry; D014783:Viscosity
D012822:Silicon Dioxide