title: Example of an organic reaction in a Langmuir film: reduction of an amphiphilic ketone by NaBH4.
abstract: Langmuir monolayers of an amphiphilic ketone 1 have been studied on pure water and on aqueous subphases containing sodium borohydride. Changes in the compression isotherm and in the monolayer morphology were observed when the concentration of NaBH4 or the delay between spreading and compression was increased. These modifications were specific to NaBH4 and suggested that a chemical reaction is taking place along the monolayer. Modifications in the IR spectrum of the corresponding Langmuir-Blodgett film confirmed the reduction of the ketone group of 1 when spread on aqueous subphases of sodium borohydride. Analysis of the compression isotherms demonstrated that this reaction occurred for all surface pressures and therefore indicated that the ketone group of 1 is accessible to the borohydride whatever the compression state of the monolayer.
authors.affiliation: Laboratoire des Interactions Moléculaires et Réactivité Chimique et Photochimique, CNRS UMR 5623, Université Paul Sabatier, 118 Route de Narbonne, 31062 Toulouse Cedex 4, France.
authors.forename: Ignacio
authors.initials: I
authors.lastname: Gascon
authors.forename: Cosmin
authors.initials: C
authors.lastname: Patrascu
authors.forename: Jean-Daniel
authors.initials: JD
authors.lastname: Marty
authors.forename: Christophe
authors.initials: C
authors.lastname: Mingotaud
mesh_terms: D001894:Borohydrides / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis / Q000737:chemistry*; D008567:Membranes, Artificial; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010316:Particle Size; D013499:Surface Properties; D014867:Water / Q000737:chemistry
chemical_list: D001894:Borohydrides; D007659:Ketones; D008567:Membranes, Artificial; D014867:Water; C025364:sodium borohydride