Bis(mu-phenyl 2-pyridyl ketone N4,N4-butane-1,4-diylthiosemicarbazonato)bis[chlorocopper(II)].
The title compound, [Cu2(C17H17N4S)2Cl2], exhibits a dimeric structure related by a centre of symmetry. The monomers are linked to each other by the longest Cu-S apical distance observed to date among Cu(II) square-pyramidal complexes of N4-substituted thiosemicarbazones. Each Cu(II) atom deviates from the coordination square plane, which contains the pyridyl and imine N atoms, the thiolate S atom and the Cl- anion, towards the S atom of the adjacent monomer. The dimers pack in a zigzag manner through the crystal.
Sreekanth
A
A
Department of Applied Chemistry, Cochin University of Science and Technology, Kochi 682 022, Kerala, India.
Suni
V
V
John
Rohith P
RP
Nethaji
Munirathinam
M
Kurup
M R Prathapachandra
MR
D003460:Crystallization; D009942:Organometallic Compounds / Q000737:chemistry*
D009942:Organometallic Compounds; C515464:bis(mu-phenyl 2-pyridyl ketone N4,N4-butane-1,4-diylthiosemicarbazonato)bis(chlorocopper(II))