Two-dimensional organization of [ZnGe3S9(H2O)]4- supertetrahedral clusters templated by a metal complex.
Under the structure-directing effect of a metal complex formed in situ, supertetrahedral [ZnGe3S6(H2O)(S3)(1/2)]1- clusters alternate with tetrahedral Zn(H2O)(S3)(1/2)1- units to form a two-dimensional wide bandgap semiconductor that shows photocatalytic activity for H2 production from aqueous solution.
Zheng
Nanfeng
N
Department of Chemistry, University of California, Riverside, California 92521, USA.
Bu
Xianhui
X
Feng
Pingyun
P