title: Emission of PCDD/Fs and dioxin-like PCBs from metallurgy industries in S. Korea.
abstract: The metallurgy industry and municipal waste incinerators are considered the main sources of polychlorinated dibenzo-p-dioxin and dibenzofurans (PCDD/Fs) in many countries. This study investigated the emission factors and total emissions of PCDD/Fs and dioxin-like polychlorinated biphenyls (PCBs) emitted from metallurgy industries (including ferrous and nonferrous foundries) in Korea. The toxic equivalency (TEQ) emission factor of PCDD/Fs was the highest for secondary copper production, at 24451 ng I-TEQ/ton. The total estimated emissions of PCDD/Fs from these sources were 35.259 g I-TEQ/yr, comprising 0.088 g I-TEQ/yr from ferrous foundries, 31.713 g I-TEQ/yr from copper production, 1.716 g I-TEQ/yr from lead production, 0.111 g I-TEQ/yr from zinc production, and 1.631 g I-TEQ/yr from aluminum production. The total estimated annual amounts of dioxin-like PCBs emitted from these sources were 13.260 g WHO-TEQ/yr, comprising 0.014 g WHO-TEQ/yr from ferrous foundries, 12.675 g WHO-TEQ/yr from copper production, 0.170 g WHO-TEQ/yr from lead production, 0.017 g WHO-TEQ/yr from zinc production, and 0.384 g WHO-TEQ/yr from aluminum production. The highest emission factor was found for secondary copper smelting, at 9770 ng WHO-TEQ/ton.
authors.affiliation: School of Environmental Science and Engineering, Pohang University of Science and Technology, Pohang 790-784, Republic of Korea.
authors.forename: Byeong-Woon
authors.initials: BW
authors.lastname: Yu
authors.forename: Guang-Zhu
authors.initials: GZ
authors.lastname: Jin
authors.forename: Young-Hoon
authors.initials: YH
authors.lastname: Moon
authors.forename: Min-Kwan
authors.initials: MK
authors.lastname: Kim
authors.forename: Jong-Dai
authors.initials: JD
authors.lastname: Kyoung
authors.forename: Yoon-Seok
authors.initials: YS
authors.lastname: Chang
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D001572:Benzofurans / Q000032:analysis*; D000072338:Dibenzofurans, Polychlorinated; D004784:Environmental Monitoring; D007723:Korea; D008669:Metallurgy; D011078:Polychlorinated Biphenyls / Q000032:analysis*; D000072317:Polychlorinated Dibenzodioxins / Q000031:analogs & derivatives* / Q000032:analysis
chemical_list: D000393:Air Pollutants; D001572:Benzofurans; D000072338:Dibenzofurans, Polychlorinated; D000072317:Polychlorinated Dibenzodioxins; D011078:Polychlorinated Biphenyls