Cooperative recognition of C60-ammonium substrates by a ditopic oligophenylenevinylene/crown ether host.
A new fullerene derivative with an ammonium subunit has been prepared. Its ability to form supramolecular complexes with oligophenylenevinylene derivatives bearing one or two crown ether moieties has been evidenced by electrospray mass spectrometry, and UV-visible and luminescence spectroscopy experiments. Interestingly, the assembly of the C60-ammonium cation with the oligophenylenevinylene derivative bearing two crown ether moieties leads to the cooperative formation of the 2:1 complex owing to intramolecular fullerene-fullerene interactions.
Elhabiri
Mourad
M
Laboratoire de Physico-Chimie Bioinorganique, Université Louis Pasteur et CNRS (UMR 7509), Ecole Européenne de Chimie, Polymères et Matériaux (ECPM), Strasbourg, France.
Trabolsi
Ali
A
Cardinali
François
F
Hahn
Uwe
U
Albrecht-Gary
Anne-Marie
AM
Nierengarten
Jean-François
JF