A micromethod for the stereochemical analysis of fatty acid desaturase-mediated sulfoxidation reactions.
The stereochemistry of fatty acid desaturase-mediated sulfoxidation can be evaluated at micromolar concentrations of analyte using (19)F NMR in combination with a chiral shift reagent: (S)-(+)-MPAA.
Lao
Kim Y Y
KY
Ottawa-Carleton Chemistry Institute, Department of Chemistry, Carleton University, Ottawa, Ontario, Canada.
Hodgson
Derek J
DJ
Dawson
Brian
B
Buist
Peter H
PH
D044943:Fatty Acid Desaturases / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013237:Stereoisomerism; D013454:Sulfoxides / Q000737:chemistry*
D013454:Sulfoxides; D044943:Fatty Acid Desaturases