Photodissociation dynamics of N2O at 130 nm: the N2(A 3Sigmau +,B 3Pig)+O(3PJ = 2,1,0) channels.
Oxygen Rydberg time-of-flight spectroscopy was used to study the vacuum ultraviolet photodissociation dynamics of N(2)O near 130 nm. The O((3)P(J)) products were tagged by excitation to high-n Rydberg levels and subsequently field ionized at a detector. In agreement with previous work, we find that O((3)P(J)) formation following excitation to the repulsive N(2)O D((1)Sigma(+)) state produces the first two electronically excited states of the N(2) counterfragment, N(2)(A (3)Sigma(u) (+)) and N(2)(B (3)Pi(g)). The O((3)P(J)) translational energy distribution reveals that the overall branching ratio between N(2)(A (3)Sigma(u) (+)) and N(2)(B (3)Pi(g)) formation is approximately 1.0:1.0 for J = 1 and 2, with slightly less N(2)(B (3)Pi(g)) produced in coincidence with O((3)P(0)). The angular distributions were found to be independent of J and highly anisotropic, with beta = 1.5+/-0.2.
Witinski
Mark F
MF
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853, USA.
Ortiz-Suárez
Marivi
M
Davis
H Floyd
HF
D003198:Computer Simulation; D004307:Dose-Response Relationship, Radiation; D007700:Kinetics; D008027:Light; D008956:Models, Chemical; D008958:Models, Molecular; D009569:Nitric Oxide / Q000737:chemistry* / Q000528:radiation effects; D009584:Nitrogen / Q000737:chemistry* / Q000528:radiation effects; D010100:Oxygen / Q000737:chemistry* / Q000528:radiation effects; D010777:Photochemistry / Q000379:methods*; D011829:Radiation Dosage
D009569:Nitric Oxide; D009584:Nitrogen; D010100:Oxygen