Boron-induced hydrogen localization in the novel metal hydride LaNi(3)BH(x) (x = 2.5-3.0).
The crystal structure and hydrogenation properties of the intermetallic boride LaNi(3)B were investigated. The hydrogen-free compound has a novel structure with orthorhombic symmetry, space group Imma, a = 4.9698(8) A, b = 7.1337(8) A, c = 8.3001(9) A, and V = 294.26(7) A(3). Thermal gravimetrical analysis reveals a hydride phase that forms near ambient conditions within the compositional range LaNi(3)BH(2.5)(-)(3.0). Single-crystal X-ray diffraction on both the alloy and the hydride, using the same crystal, shows an expansion in the a-c plane (by up to approximately 8%) and a contraction along b (by approximately 3%), while the symmetry changes from Imma to Bmmb (Cmcm) and the unit cell doubles along a and b. The cell parameters for the composition of LaNi(3)BD(2.73(4)) are a = 10.7709(7) A, b = 16.0852(10) A, c = 7.6365(5) A, V = 1323.03(15) A(3), and space group Cmcm. Four nearly fully occupied interstitial hydrogen sites were located by neutron powder diffraction on deuterides and found to have tetrahedral, La(2)Ni(2) (D1,D2), trigonal-prismatic, La(3)Ni(3) (D3), and trigonal-bipyramidal, La(2)Ni(3) (D4), metal environments. The structure can also be described in terms of alternating quasi two-dimensional [NiD](-) slabs (Ni-D = 1.62-1.97 A) and La-B sheets for which bond-valence sums suggest the limiting formula La(3+)B(0)[Ni(3)D(3)](3)(-). The La-B planes do not accommodate deuterium; the B-D and D-D interactions appear to be repulsive. The shortest B-D and D-D contacts are 2.52(2) and 2.33(2) A, respectively.
Filinchuk
Yaroslav E
YE
Laboratory of Crystallography, University of Geneva, 24 quai Ernest Ansermet, CH-1211 Geneva, Switzerland. Yaroslav.Filinchuk@cryst.unige.ch
Yvon
Klaus
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