title: Total synthesis of syringalide B, a phenylpropanoid glycoside.
abstract: The first total synthesis of syringalide B, 2-(4-hydroxyphenyl)ethyl 4-O-[(E)-feruloyl]-beta-D-glucopyranoside, is described. The hydroxyl groups were protected with allyloxycarbonyl (Aoc) and allyl groups, which successfully prevent the migration of the feruloyl group during the deblocking procedure.
authors.affiliation: Department of Chemical Biology, School of Pharmaceutical Sciences, Peking University, Health Sciences Center, Beijing 100083, PR China.
authors.forename: Qing
authors.initials: Q
authors.lastname: Li
authors.forename: Shu-Chun
authors.initials: SC
authors.lastname: Li
authors.forename: Hui
authors.initials: H
authors.lastname: Li
authors.forename: Meng-Shen
authors.initials: MS
authors.lastname: Cai
authors.forename: Zhong-Jun
authors.initials: ZJ
authors.lastname: Li
mesh_terms: D002109:Caffeic Acids / Q000138:chemical synthesis* / Q000737:chemistry; D002240:Carbohydrate Sequence; D005960:Glucosides / Q000138:chemical synthesis* / Q000737:chemistry; D006027:Glycosides / Q000138:chemical synthesis*; D008969:Molecular Sequence Data; D020005:Propanols / Q000737:chemistry
chemical_list: C504009:2-(4-hydroxyphenyl)ethyl 4-O-feruloylglucopyranoside; D002109:Caffeic Acids; D005960:Glucosides; D006027:Glycosides; D020005:Propanols; C439395:1-phenylpropanol