title: Asphaltenic aggregates are polydisperse oblate cylinders.
abstract: Small-angle neutron scattering (SANS) has proven to be very useful for deducing the sizes and morphologies of asphaltenic aggregates in solution. A wide variety of intra-particle structure factors have previously been applied to SANS scattering spectra, but the studies often provided limited information concerning the quality of the fits and the Q range over which the models were applied. Selection of an appropriate form factor that closely approximates the structure of asphaltenic aggregates is important for determining the properties of asphaltenic aggregates, such as the radius of gyration (R(G)), molar mass, and apparent fractal dimension. This study evaluates various mono- and polydisperse intra-particle structure factor models as applied to four asphaltene scattering spectra. Agreement of the model fit parameters (I(0) and R(G)) with those obtained from Guinier analyses suggests that such a form factor model is physically reasonable. Reduced chi2 values for each non-linear least squares fit indicates how well a given model fits to the entire Q range studied for the scattering intensity distribution. In the polydispersity analyses, an analytical function is introduced to model the scattering behavior of oblate cylinders with a Schultz distribution of radii. Results indicate that the polydisperse radius oblate cylinder model best approximates the shape of asphaltenic aggregates.
authors.affiliation: Department of Chemical Engineering, North Carolina State University, Raleigh, NC 27965-7905, USA.
authors.forename: Keith L
authors.initials: KL
authors.lastname: Gawrys
authors.forename: Peter K
authors.initials: PK
authors.lastname: Kilpatrick