title: Efficient protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds using tetrabutylammonium fluoride.
abstract: [reaction: see text] The protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds proceeds efficiently by treatment with tetrabutylammonium fluoride in wet DMF or THF via isolable dimethylsilanol intermediates.
authors.affiliation: Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055, USA.
authors.forename: Cheryl L
authors.initials: CL
authors.lastname: Heitzman
authors.forename: William T
authors.initials: WT
authors.lastname: Lambert
authors.forename: Eric
authors.initials: E
authors.lastname: Mertz
authors.forename: J Brad
authors.initials: JB
authors.lastname: Shotwell
authors.forename: Jennifer M
authors.initials: JM
authors.lastname: Tinsley
authors.forename: Porino
authors.initials: P
authors.lastname: Va
authors.forename: William R
authors.initials: WR
authors.lastname: Roush
mesh_terms: D005663:Furans / Q000737:chemistry*; D015394:Molecular Structure; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D013329:Structure-Activity Relationship
chemical_list: D005663:Furans; D000644:Quaternary Ammonium Compounds; D012821:Silanes; C082343:silanol; C009405:tetrabutylammonium