Poly[bis(N-methylformamide)tetra-mu-thiocyanato-manganese(II)mercury(II)].
The title complex, [MnHg(NCS)4(C2H5NO)2]n, consists of slightly distorted MnN4O2 octahedra and HgS4 tetrahedra. Each Mn(II) cation is bound to four N atoms of the NCS groups and two O atoms of the N-methylformamide (NMF) ligands in a cis configuration. Each Hg(II) cation is coordinated to four S atoms of NCS groups. Each pair of Mn(II) and Hg(II) cations is connected by an -NCS- bridge, forming an infinite three-dimensional -Mn-NCS-Hg- network.
Wang
Xin Qiang
XQ
State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University, Jinan 250100, People's Republic of China. xqwang@icm.sdu.edu.cn
Yu
Wen Tao
WT
Xu
Dong
D
Zhang
Guang Hui
GH
Geng
Yan Ling
YL
D017895:Manganese Compounds / Q000737:chemistry*; D017669:Mercury Compounds / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*
D017895:Manganese Compounds; D017669:Mercury Compounds; D009942:Organometallic Compounds; C515463:poly(bis(N-methylformamide)tetra-mu-thiocyanato-manganese(II)mercury(II))