title: A micromethod for the stereochemical analysis of fatty acid desaturase-mediated sulfoxidation reactions.
abstract: The stereochemistry of fatty acid desaturase-mediated sulfoxidation can be evaluated at micromolar concentrations of analyte using (19)F NMR in combination with a chiral shift reagent: (S)-(+)-MPAA.
authors.affiliation: Ottawa-Carleton Chemistry Institute, Department of Chemistry, Carleton University, Ottawa, Ontario, Canada.
authors.forename: Kim Y Y
authors.initials: KY
authors.lastname: Lao
authors.forename: Derek J
authors.initials: DJ
authors.lastname: Hodgson
authors.forename: Brian
authors.initials: B
authors.lastname: Dawson
authors.forename: Peter H
authors.initials: PH
authors.lastname: Buist
mesh_terms: D044943:Fatty Acid Desaturases / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013237:Stereoisomerism; D013454:Sulfoxides / Q000737:chemistry*
chemical_list: D013454:Sulfoxides; D044943:Fatty Acid Desaturases