Critical phenomenon of nonaqueous microemulsion (AOT/DMA/decane).
The critical phenomenon of nonaqueous microemulsion was studied for the first time. The coexistence curves of (T,n), (T,phi), and (T,psi) (n and phi are refractive index and volume fraction, respectively; psi is defined as psi=phi/[phi+phi(c)(1-phi)/(1-phi(c))]) for a ternary microemulsion [phi (AOT-DMA)+(1-phi) decane] at constant pressure and a constant molar ratio (omega=2.86) of DMA to AOT have been determined within about 7 K from the critical temperature T(c) by measurements of refractive index. The critical exponent beta has been deduced from (T,n), (T,phi), and (T,psi) coexistence curves within 1 K below T(c). They all were 0.329+/-0.005 and were consistent with the 3D Ising value. The experimental results in a temperature range of (T(c)-T)<7 K also have been analyzed to obtain critical amplitudes and the Wegner correction terms, to examine the diameters of the coexistence curves.
Peng
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Department of Chemistry, Lanzhou University, Lanzhou, Gansu 730000, China.
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Shen
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