title: Large deformation compression induced crystallinity degradation of conventional and highly crosslinked UHMWPEs.
abstract: The effect of a large compressive plastic deformation on the melt temperature (Tm), lamellar thickness, crystallinity, and density of four UHMWPEs (two conventional and two highly crosslinked) was examined. The materials were prepared from a single batch of medical grade GUR 1050 resin (Ticona, Bayport, TX, USA). The two conventional UHMWPEs were as-received (virgin) and gamma radiation sterilized at 30 kGy in a nitrogen atmosphere (radiation sterilized). The two highly crosslinked UHMWPEs were each irradiated at 100 kGy and then post-processed with one of either two thermal treatments: annealing, which was done below the melt transition temperature (Tm), at 110 degrees C for 2h (110 degrees C-annealed); and, remelting, which was done above Tm, at 150 degrees C (150 degrees C-remelted). Differences in changes upon compression between the materials were examined using ANCOVA analyses. The 150 degrees C-remelted material showed a significant change in Tm and lamellar thickness upon compressive plastic deformation whereas the other three UHMWPE materials did not. However, all of the materials showed significantly decreased crystallinity and density upon compressive deformation. The findings of this study support that microstructural evolution during compressive deformation is a function of UHMWPE formulation, as affected by irradiation and post-irradiation heat treatment.
authors.affiliation: Department of Mechanical and Aerospace Engineering, Case Western Reserve University, 620 Glennan Building, Cleveland, OH, USA.
authors.forename: Michael C
authors.initials: MC
authors.lastname: Sobieraj
authors.forename: Steven M
authors.initials: SM
authors.lastname: Kurtz
authors.forename: Clare M
authors.initials: CM
authors.lastname: Rimnac
mesh_terms: D001672:Biocompatible Materials / Q000737:chemistry; D001696:Biomechanical Phenomena; D002152:Calorimetry, Differential Scanning; D003432:Cross-Linking Reagents / Q000494:pharmacology; D003460:Crystallization; D005720:Gamma Rays; D006244:Hardness; D006245:Hardness Tests; D008422:Materials Testing; D008855:Microscopy, Electron, Scanning; D009584:Nitrogen; D011095:Polyethylenes / Q000737:chemistry*; D013314:Stress, Mechanical; D013499:Surface Properties; D013696:Temperature; D013718:Tensile Strength; D013997:Time Factors
chemical_list: D001672:Biocompatible Materials; D003432:Cross-Linking Reagents; D011095:Polyethylenes; C111601:ultra-high molecular weight polyethylene; D009584:Nitrogen