Barium divanadium(V) tellurite(IV).
A new three-dimensional bimetallic tellurite, BaV2TeO8, was synthesized by the hydrothermal reaction of Ba(OH)2, TeO2 and V2O5, and characterized by single-crystal X-ray diffraction. The three-dimensional framework is built up from anionic [V2TeO8]n(2n-) layers parallel to (101) and connected via Ba-O bonds. The anionic layers are formed by three types of polyhedra, namely VO5 tetragonal pyramids, VO(4) tetrahedra and TeO(4+2) 'folded square' polyhedra.
Hou
Ju Ying
JY
Department of Chemistry and Key Laboratory of Chemistry of Solid Materials, Fuzhou University, Fuzhou, Fujian 350002, People's Republic of China.
Huang
Chang Cang
CC
Zhang
Han Hui
HH
Yang
Qi Yu
QY
Chen
Yi Ping
YP
Xu
Jian Fu
JF