title: Organic phase stabilization of rhodium nanoparticle catalyst by direct phase transfer from aqueous solution to room temperature ionic liquid based on surfactant counter anion exchange.
abstract: We describe the organic phase transfer of surfactant-stabilized rhodium nanoparticles previously synthesized in an aqueous solution of N,N-dimethyl-N-dodecyl-N-(2-hydroxyethyl)ammonium chloride (HEA12Cl); the addition of LiN(Tf)2 to the aqueous suspension of Rh-HEA12Cl transferred the hydrosol nanoparticles to an ionic liquid phase.
authors.affiliation: UMR CNRS 6052 Syntheses et Activations de Biomolecules, Ecole Nationale Superieure de Chimie de Rennes, Institut de Chimie de Rennes, Avenue du General Leclerc, 35700, Rennes, France.
authors.forename: Vincent
authors.initials: V
authors.lastname: Mévellec
authors.forename: Bastien
authors.initials: B
authors.lastname: Leger
authors.forename: Marc
authors.initials: M
authors.lastname: Mauduit
authors.forename: Alain
authors.initials: A
authors.lastname: Roucoux
mesh_terms: D002384:Catalysis; D002625:Chemistry, Organic; D007474:Ion Exchange; D007477:Ions / Q000737:chemistry; D046529:Microscopy, Electron, Transmission; D015394:Molecular Structure; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D055601:Organic Chemistry Phenomena; D012238:Rhodium / Q000737:chemistry*; D012996:Solutions / Q000737:chemistry; D013501:Surface-Active Agents / Q000737:chemistry*; D013696:Temperature; D014867:Water / Q000737:chemistry
chemical_list: D007477:Ions; D012996:Solutions; D013501:Surface-Active Agents; D014867:Water; D012238:Rhodium