Enantioselective catalytic diamination of alkenes with a bisimidoosmium oxidant.
A first example of an enantioselective catalytic diamination of olefins has been developed which employs enantiopure titanium complexes as catalysts and bis(tbutylimido)dioxoosmium(VIII) as nitrogen source.
Muñiz
Kilian
K
Kekulé-Institut für Organische Chemie und Biochemie, Gerhard-Domagk-Str. 1, D-53121 Bonn, Germany. kilian.muniz@uni-bonn.de
Nieger
Martin
M