Quenched disorder in a liquid-crystal biosensor: adsorbed nanoparticles at confining walls.
We analyze the response of a nematic liquid-crystal film, confined between parallel walls, to the presence of nanoscopic particles adsorbed at the walls. This is done for a variety of patterns of adsorption (random and periodic) and operational conditions of the system that can be controlled in experimental liquid-crystal-based devices. We compute simulated optical textures and the total optical output of the sensor between crossed polars, as well as the correlation function for the liquid-crystal tensor order parameter; we use these observables to discuss the gradual destruction of the original uniform orientation. For large concentrations of particles adsorbed in random patterns, the liquid crystal at the center of the sensor adopts a multidomain state, characterized by a small correlation length of the tensor order parameter, and also by a loss of optical anisotropy under observation through crossed polars. In contrast, for particles adsorbed in periodic patterns, the nematic at the center of the cell can remain in a monodomain orientation state, provided the patterns in opposite walls are synchronized.
Guzmán
O
O
Department of Chemical and Biological Engineering, University of Wisconsin, Madison, Wisconsin 53706-1691, USA. orlando@che.wisc.edu
Abbott
N L
NL
de Pablo
J J
JJ
D000327:Adsorption; D016880:Anisotropy; D015374:Biosensing Techniques; D002627:Chemistry, Physical / Q000379:methods*; D003460:Crystallization; D007700:Kinetics; D050866:Liquid Crystals; D015233:Models, Statistical; D008962:Models, Theoretical; D053758:Nanoparticles / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry; D012984:Software; D013997:Time Factors