Topotactic oxidation of TiGaPO-1, a pyridine-templated titanium gallophosphate with a new octahedral-tetrahedral 3-D framework structure containing Ti(III)/Ti(IV).
The first 3-D open-framework TiGaPO complex, constructed from Ti(III)O(6), Ti(IV)O(6), GaO(4), and PO(4) polyhedra, contains pyridinium cations in a 1-D pore network and can be oxidized in air at 543 K with retention of the original framework structure.
Chippindale
Ann M
AM
School of Chemistry, The University of Reading, Whiteknights, Reading, Berks RG6 6AD, UK. a.m.chippindale@rdg.ac.uk
Grimshaw
Mark R
MR
Powell
Anthony V
AV
Cowley
Andrew R
AR