Biomimetic oxidation of Hantzsch 1,4-dihydropyridines with tetra-n-butylammonium periodate catalyzed by tetraphenylporphyrinatomanganese(III) chloride [Mn(TPP)Cl].
Efficient oxidation of Hantzsch 1,4-dihydropyridines to their corresponding pyridine derivatives with (Bu(4)N)IO(4) catalyzed by tetraphenylporphyrinatomanganese(III) chloride [Mn(TPP)Cl] is reported. This catalytic system shows high efficiency in the oxidation of 1,4-dihydropyridines at room temperature in the presence of imidazole.
Nasr-Esfahani
Masoud
M
Department of Chemistry, Yasouj University, Yasouj 75914-353, Iran.
Moghadam
Majid
M
Tangestaninejad
Shahram
S
Mirkhani
Valiollah
V
D032701:Biomimetics; D002384:Catalysis; D004095:Dihydropyridines / Q000737:chemistry*; D008665:Metalloporphyrins / Q000737:chemistry; D010084:Oxidation-Reduction; D010504:Periodic Acid / Q000737:chemistry
D004095:Dihydropyridines; D008665:Metalloporphyrins; D010504:Periodic Acid; C041471:manganese tetraphenylporphyrin; C038806:1,4-dihydropyridine; C009288:metaperiodate