Efficient protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds using tetrabutylammonium fluoride.
[reaction: see text] The protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds proceeds efficiently by treatment with tetrabutylammonium fluoride in wet DMF or THF via isolable dimethylsilanol intermediates.
Heitzman
Cheryl L
CL
Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109-1055, USA.
Lambert
William T
WT
Mertz
Eric
E
Shotwell
J Brad
JB
Tinsley
Jennifer M
JM
Va
Porino
P
Roush
William R
WR
D005663:Furans / Q000737:chemistry*; D015394:Molecular Structure; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D013329:Structure-Activity Relationship
D005663:Furans; D000644:Quaternary Ammonium Compounds; D012821:Silanes; C082343:silanol; C009405:tetrabutylammonium