Poly[diaquahexakis(dimethyl sulfoxide-kappaO)cerium [(mu(2)-hexacosaoxooctamolybdate)sodium]].
The title compound, {[Ce(C2H6OS)6(H2O)2][NaMo8O26]}n, contains an infinite chain of beta-octamolybdate moieties linked by Na+ ions, and further linked into a two-dimensional network by [Ce(DMSO)6(H2O)2]3+ (DMSO is dimethyl sulfoxide) groups via hydrogen-bond interactions. The Ce and Na atoms are located on a twofold axis and an inversion centre, respectively.
Chen
Li Juan
LJ
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Fuzhou, Fujian 350002, People's Republic of China.
Lu
Can Zhong
CZ
Zhang
Quan Zheng
QZ
Chen
Shu Mei
SM