Binuclear Cu2+ complex mediated discrimination between L-glutamate and L-aspartate in water.
L-glutamate and L-aspartate selectivity is achieved by the action of two Cu2+ metal ions rightly disposed in a cyclophane-type macrocyclic framework; electrochemical sensing of glutamate has been achieved by adsorption of the copper complexes on graphite electrodes.
Verdejo
Begoña
B
Instituto de Ciencia Molecular, Departamentos de Química Inorgánica y Orgánica, Universidad de Valencia, 46100 Burjassot (Valencia), Spain.
Aguilar
Juan
J
Doménech
Antonio
A
Miranda
Carlos
C
Navarro
Pilar
P
Jiménez
Hermás R
HR
Soriano
Conxa
C
García-España
Enrique
E
D001224:Aspartic Acid / Q000032:analysis*; D003300:Copper; D004563:Electrochemistry; D018698:Glutamic Acid / Q000032:analysis*; D009942:Organometallic Compounds / Q000737:chemistry*; D014867:Water
D009942:Organometallic Compounds; D014867:Water; D001224:Aspartic Acid; D018698:Glutamic Acid; D003300:Copper