title: Selective cleavage of the C-C bonds of aminoethyl groups, via a multistep pathway, by a pincer iridium complex.
abstract: A pincer-ligated iridium complex is found to react with N-ethylamines, HN(Et)R (R = cyclohexyl, tert-butyl, ethyl), to give the corresponding iridium isocyanide complexes (PCP)Ir(CH3)(H)(CNR) (PCP = kappa3-2,6-(tBu2PCH2)2C6H3). This novel, regioselective C-C bond cleavage reaction occurs readily under mild conditions (25-45 degrees C). The reaction is shown to proceed via initial dehydrogenation of the amine to give the corresponding imine (N-ethylidenealkylamine). The ethylidene sp2 C-H bond then undergoes addition to iridium, followed by methyl migration.
authors.affiliation: Department of Chemistry, Rutgers, The State University of New Jersey, Piscataway, NJ 08854, USA.
authors.forename: Xiawei
authors.initials: X
authors.lastname: Zhang
authors.forename: Thomas J
authors.initials: TJ
authors.lastname: Emge
authors.forename: Rajshekhar
authors.initials: R
authors.lastname: Ghosh
authors.forename: Alan S
authors.initials: AS
authors.lastname: Goldman