Iron porphyrins anchored to a thermosensitive polymeric core-shell nanosphere as a thermotropic catalyst.
A thermosensitive nanocatalyst was prepared in the reaction of water-soluble iron(III) porphyrins and thermosensitive polymeric nanospheres with a core-shell structure; its catalytic activity in cyclohexene oxidation by iodosylbenzene was dependent markedly on reaction temperatures in aqueous solution.
Choi
Bo Gyu
BG
Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womans University, Seoul 120-750, Korea.
Song
Rita
R
Nam
Wonwoo
W
Jeong
Byeongmoon
B