Activated carbons from sewage sludge and discarded tyres: production and optimization.
This is a study about making use of two residual materials such as sludges from a sewage treatment plant and discarded tyres to generate activated carbons and later optimize the production process. H2SO4 and ZnCl2 were used as chemical activating agents. Liquid-phase adsorption tests were made using the produced carbons to retain methylene blue and iodine. The best precursor was sludge activated with ZnCl2. After optimization studies, the best production methodology involved a 1:1 ratio of sludge and ZnCl2, a heating rate of 5 degrees C/min up to 650 degrees C and a residence time of 5 min. The resulting materials adsorbed up to 139.4 mg/g of methylene blue and 1358.5 mg/g of iodine. Nevertheless these carbons may leach Zn while using. To avoid this two treatments were carried out: one consisting of a coating with a polymer and another involving an intensive washing, which was seen to be more efficient.
Rozada
F
F
Department of Chemical Engineering, IRENA-ESTIA, Natural Resources Institute, University of León, Avda. Portugal 41, 24071 León, Spain.
Otero
M
M
Morán
A
A
García
A I
AI
D000327:Adsorption; D002606:Charcoal / Q000138:chemical synthesis* / Q000302:isolation & purification*; D008751:Methylene Blue / Q000737:chemistry; D008956:Models, Chemical; D011108:Polymers / Q000737:chemistry; D012408:Rubber / Q000737:chemistry*; D012722:Sewage / Q000737:chemistry*; D013696:Temperature
D011108:Polymers; D012722:Sewage; D002606:Charcoal; D012408:Rubber; D008751:Methylene Blue