title: Spatial and temporal variations of the inherent and apparent optical properties in a shallow coastal lake.
abstract: Apparent and inherent optical properties in the coastal lagoon of Fogliano were measured in three seasonal surveys in 2002. Irradiance data from in situ measurements of ultraviolet and visible wavebands permitted to estimate the related attenuation coefficients. Laboratory extinction measurements on filtered (0.22 microm) and unfiltered water samples were also performed. The integrated approach between in situ and laboratory measurements allowed the determination of the role of the suspended and dissolved matter in the attenuation and extinction of ultraviolet and visible radiation within the water column. As noted, the impact of the suspended and dissolved matter on the lake optical quality was influenced by wind resuspension of particulate matter: the relative role of dissolved matter in the absorption of UV and visible radiation was prevailing at low wind velocity conditions (less than 2.2 m s(-1)), while at high wind velocities (3.9 m s(-1)), particulate matter resuspension strongly influenced the attenuation and the extinction measurements. The extinction in the analyzed wavelengths of filtered and unfiltered water samples and the in situ irradiance measurements allowed us to define new optical parameters and important correlations with limnological and classical optical measurements. By sampling at high spatial resolution (18 stations in 4 km2), it was possible to evidence a spatial gradient of the optical and limnological properties, these distributions showed a consistent pattern in all three surveys, and were important for the characterization of the chromophoric dissolved organic matter that was estimated with the spectral slope of the extinction curve spectra. A relatively higher spectral slope was found in the southern basin with respect to the northern, where the maximum values of the attenuation coefficients and limnological parameters were found. These results suggest different sources of dissolved organic matter and/or a different level of photobleaching.
authors.affiliation: Dipartimento di Scienze e Tecnologie Chimiche e dei Biosistemi, Università di Siena, Via A. Moro 2 53100, Siena, Italy. bracchini@unisi.it
authors.forename: Luca
authors.initials: L
authors.lastname: Bracchini
authors.forename: Arduino Massimo
authors.initials: AM
authors.lastname: Dattilo
authors.forename: Margherita
authors.initials: M
authors.lastname: Falcucci
authors.forename: Steven Arthur
authors.initials: SA
authors.lastname: Loiselle
authors.forename: Vincent
authors.initials: V
authors.lastname: Hull
authors.forename: Carmen
authors.initials: C
authors.lastname: Arena
authors.forename: Claudio
authors.initials: C
authors.lastname: Rossi
mesh_terms: D005618:Fresh Water / Q000032:analysis* / Q000737:chemistry; D007558:Italy; D012621:Seasons; D013472:Sunlight; D014466:Ultraviolet Rays; D014919:Wind