title: Microemulsion-mediated solvothermal synthesis of SrCO3 nanostructures.
abstract: The controlled synthesis of SrCO3 nanostructures with different morphologies, such as rodlike, whiskerlike, ellipsoidlike, and spherelike, were successfully achieved by the cationic surfactant-CTAB-microemulsion-mediated solvothermal method. Various comparison experiments showed that fundamental experimental parameters, such as the molar ratio of H2O to CTAB and the concentration of reactants, played important roles in the morphological control of SrCO3 nanostructures. A lower molar ratio of H2O to CTAB favors rodlike products, whereas a higher molar ratio generally leads to the formation of spherical products. A rational mechanism based on fusion, aggregate, and coalescence of microemulsion droplets is proposed for the selective formation of various morphologies. X-ray powder diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED), and field-emission scanning electron microscope (FE-SEM) were used to characterize the products.
authors.affiliation: Institute of Polyoxometalate Chemistry, Northeast Normal University, Changchun, P. R. China 130024.
authors.forename: Minhua
authors.initials: M
authors.lastname: Cao
authors.forename: Xinglong
authors.initials: X
authors.lastname: Wu
authors.forename: Xiaoyan
authors.initials: X
authors.lastname: He
authors.forename: Changwen
authors.initials: C
authors.lastname: Hu