Atomic nanotube welders: boron interstitials triggering connections in double-walled carbon nanotubes.
Here we demonstrate that the incorporation of boron (B) atoms between double-walled carbon nanotubes (DWNTs) during thermal annealing (1400-1600 degrees C) results in covalent nanotube "Y" junctions, DWNT coalescence, and the formation of flattened multiwalled carbon nanotubes (MWNTs). These processes occur via the merging of adjacent tubes, which is triggered by B interstitial atoms. We observe that B atom interstitials between DWNTs are responsible for the rapid establishment of covalent connections between neighboring tubes (polymerization), thereby resulting in the fast annealing of the carbon cylinders with B atoms embedded in the newly created carbon nanotube network. Once B is in the lattice, tube faceting (polygonization) starts to occur, and the electronic properties are expected to change dramatically. Therefore, B atoms indeed act as atomic nanotube fusers (or welders), and this process could now be used in assembling novel electronic nanotube devices, nanotube networks, carbon nanofoams and heterojunctions exhibiting p-type electronic properties.
Endo
Morinobu
M
Faculty of Engineering, Shinshu University, 4-17-1 Wakasato, Nagano-shi 380-8553, Japan. endo@endomoribu.shinshu-u.ac.jp
Muramatsu
Hiroyuki
H
Hayashi
Takuya
T
Kim
Yoong-Ahm
YA
Van Lier
Gregory
G
Charlier
Jean-Christophe
JC
Terrones
Humberto
H
Terrones
Mauricio
M
Dresselhaus
Mildred S
MS
D001895:Boron / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D004583:Electrons; D006358:Hot Temperature; D046911:Macromolecular Substances / Q000737:chemistry; D046529:Microscopy, Electron, Transmission; D008958:Models, Molecular; D036103:Nanotechnology / Q000379:methods*; D043942:Nanotubes / Q000737:chemistry; D037742:Nanotubes, Carbon / Q000737:chemistry*; D011487:Protein Conformation; D013059:Spectrum Analysis, Raman; D013696:Temperature
D046911:Macromolecular Substances; D037742:Nanotubes, Carbon; D002244:Carbon; D001895:Boron