title: Diuron mobility through vineyard soils contaminated with copper.
abstract: The herbicide diuron is frequently applied to vineyard soils in Burgundy, along with repeated treatments with Bordeaux mixture (a blend of copper sulfate and calcium hydroxide) that result in elevated copper concentrations. Cu could in principle affect the fate and transport of diuron or its metabolites in the soil either directly by complexation or indirectly by altering the populations or activity of microbes involved in their degradation. To assess the effect of high Cu concentrations on diuron transport, an experiment was designed with ten undisturbed columns of calcareous and acidic soils contaminated with 17--509 mg kg(-1) total Cu (field-applied). Grass was planted on three columns. Diuron was applied to the soils in early May and in-ground lysimeters were exposed to outdoor conditions until November. Less than 1.2% of the diuron applied was found in the leachates as diuron or its metabolites. Higher concentrations were found in the effluents from the grass-covered columns (0.1--0.45%) than from the bare-soil columns (0.02--0.14%), and they were correlated with increases in dissolved organic carbon. The highest amounts of herbicide were measured in acidic-soil column leachates (0.98--1.14%) due to the low clay and organic matter contents of these soils. Cu also leached more readily through the acidic soils (32.8--1042 microg) than in the calcareous soils (9.5--63.4 microg). Unlike in the leachates, the amount of diuron remaining in the soils at the end of the experiment was weakly related to the Cu concentrations in the soils.
authors.affiliation: UMR INRA 1229 Microbiologie-Géochimie des Sols, Centre des Sciences de la Terre, Université de Bourgogne, 6 Bd Gabriel, 21000 Dijon, France. arj5@cornell.edu
authors.forename: Astrid R
authors.initials: AR
authors.lastname: Jacobson
authors.forename: Sylvie
authors.initials: S
authors.lastname: Dousset
authors.forename: Nathalie
authors.initials: N
authors.lastname: Guichard
authors.forename: Philippe
authors.initials: P
authors.lastname: Baveye
authors.forename: Francis
authors.initials: F
authors.lastname: Andreux
mesh_terms: D000383:Agriculture; D003300:Copper; D004237:Diuron / Q000032:analysis*; D004784:Environmental Monitoring / Q000379:methods; D004787:Environmental Pollution; D005659:Fungicides, Industrial; D006540:Herbicides / Q000032:analysis*; D006812:Humic Substances; D008962:Models, Theoretical; D006109:Poaceae; D012987:Soil; D012989:Soil Pollutants / Q000032:analysis*; D014872:Water Movements; D014920:Wine
chemical_list: D005659:Fungicides, Industrial; D006540:Herbicides; D006812:Humic Substances; D012987:Soil; D012989:Soil Pollutants; D003300:Copper; C006788:Bordeaux mixture; D004237:Diuron