New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn8(mu4-O)4(phpz)8(thf)4].
Reaction of Mn(ClO4)2.6H2O with 3(5)-methyl-5(3)-(2-hydroxyphenyl)pyrazole (H2phpz) affords a highly asymmetric octanuclear manganese(III) cluster resulting from the different bridging coordination modes of the ligand H2phpz.
Tanase
Stefania
S
Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, The Netherlands.
Aromí
Guillem
G
Bouwman
Elisabeth
E
Kooijman
Huub
H
Spek
Anthony L
AL
Reedijk
Jan
J
D018360:Crystallography, X-Ray; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular
D008345:Manganese