Remediation of soil contaminated with the heavy metal (Cd2+).
Soil contamination by heavy metals is increasing. The biosorption process for removal of the heavy metal Cd(2+) from contaminated soil is chosen for this study due to its economy, commercial applications, and because it acts without destroying soil structure. The study is divided into four parts (1) soil leaching: the relationships between the soil leaching effect and agitation rates, solvent concentrations, ratios of soil to solvent, leaching time and pH were studied to identify their optimum conditions; (2) adsorption Cd(2+) tests of immobilized Saccharomycetes pombe beads: different weight percentages of chitosan and polyvinyl alcohol (PVAL) were added to alginate (10 wt.%) and then blended or cross-linked by epichlorohydrin (ECH) to increase their mechanical strength. Next, before blending or cross-linking, different weight percentages of S. pombe 806 or S. pombe ATCC 2476 were added to increase Cd(2+) adsorption. Thus, the optimum beads (blending or cross-linking, the percentages of chitosan, PVAL and S. pombe 806 or S. pombe ATCC 2476) and the optimum adsorption conditions (agitation rate, equilibrium adsorption time, and pH in the aqueous solution) were ascertained; (3) regeneration tests of the optimum beads: the optimum beads adsorbing Cd(2+) were regenerated by various concentrations of aqueous HCl solutions. The results indicate that the reuse of immobilized pombe beads was feasible; and (4) adsorption model/kinetic model/thermodynamic property: the equilibrium adsorption, kinetics, change in Gibbs free energy of adsorption of Cd(2+) on optimum beads were also investigated.
Lin
Chuen-Chang
CC
Department of Chemical Engineering, National Yunlin University of Science and Technology, Taiwan, ROC. linchuen@pine.yuntech.edu.tw
Lin
Hong-Long
HL
D000327:Adsorption; D000464:Alginates / Q000737:chemistry; D002104:Cadmium / Q000737:chemistry*; D048271:Chitosan / Q000737:chemistry; D020723:Glucuronic Acid / Q000737:chemistry; D006256:Hazardous Waste / Q000517:prevention & control*; D006603:Hexuronic Acids / Q000737:chemistry; D008863:Microspheres; D011142:Polyvinyl Alcohol / Q000737:chemistry; D012440:Saccharomyces / Q000378:metabolism; D012989:Soil Pollutants / Q000032:analysis / Q000378:metabolism*
D000464:Alginates; D006256:Hazardous Waste; D006603:Hexuronic Acids; D012989:Soil Pollutants; D002104:Cadmium; D020723:Glucuronic Acid; D011142:Polyvinyl Alcohol; D048271:Chitosan