Fabrication of gradient colloidal topography.
A rather simple but yet effective way to self-assemble polystyrene (PS) beads in gradient colloidal crystal topography is proposed. The PS bead concentration, solvent, and substrate have a big effect on the colloidal crystal topography. Whether the gradient-shaped crystals can form or not depends on the Bond number [Bo; the ratio of gravitational potential energy (G) to adhesive energy (E(a)), or gravitational to capillary forces]. When Bo < 1, that is, the capillary force dominates over the gravitational force, the liquid meniscus is stable. The gradient-shaped crystals can form. Otherwise, PS beads form a uniform multilayer structure.
Zhang
Jilin
J
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Graduate School of the Chinese Academy of Sciences, Changchun 130022, People's Republic of China.
Xue
Longjian
L
Han
Yanchun
Y