title: Controlled subnanosecond isomerization of HCN to CNH in solution.
abstract: We report a study of control of the HCN-->CNH isomerization in a liquid Ar solution. We show, using molecular dynamics simulations, nearly complete conversion from HCN to CNH can be achieved in solution on the subnanosecond time scale without requiring laser pulse shaping or molecular alignment. The mechanism of the isomerization reaction involves multiphoton rovibrational excitation on the ground electronic state potential energy surface coupled with rapid rovibrational relaxation in solution. The results demonstrate the important role of rotation-vibration coupling in multiphoton excitation of small molecules and constitute the first realistic computational demonstration of fast, robust, and high-yield laser field manipulation of solution-phase molecular processes.
authors.affiliation: Department of Chemistry and The James Franck Institute, The University of Chicago, Illinois 60637, USA.
authors.forename: Jiangbin
authors.initials: J
authors.lastname: Gong
authors.forename: Ao
authors.initials: A
authors.lastname: Ma
authors.forename: Stuart A
authors.initials: SA
authors.lastname: Rice