Pesticide extraction efficiency of two solid phase disk types after shipping.
An interlaboratory study was conducted to compare pesticide recovery from Empore C(18) and Speedisks C(18)XF solid phase extraction disks after shipping. Four pesticides were used for the comparison of the two disk extraction materials: atrazine, diazinon, metolachlor, and tebuconazole. These pesticides were chosen to provide a range of physiochemical properties. Water samples were extracted onto the disk types and shipped to a cooperating laboratory for elution and analysis. The mean recoveries from Empore disks were atrazine, 95%; diazinon, 91%; metolachlor, 92%; and tebuconazole, 83%. The recoveries from Speedisks C(18)XF were atrazine, 89%; diazinon, 87%; metolachlor, 86%; and tebuconazole, 79%. Means for each of the pesticides using the different disk types were not statistically different (alpha = 0.05), but results were more variable when using Speedisks C(18)XF as compared to Empore disks. Reasons for the increased variability are discussed, but overall results indicate that Speedisks C(18)XF could be used as an alternative to Empore disks. Speedisks C(18)XF are enclosed in a plastic housing, so they can be used more easily in remote sampling sites without the possibility of glassware breakage, no prefiltration of samples is needed, and there are realignment problems that can be associated with the Empore disks.
Riley
Melissa B
MB
Entomology, Soils, and Plant Sciences Department, 120 Long Hall, Clemson University, South Carolina 29634-0315, USA. mbriley@clemson.edu
Dumas
Jose A
JA
Gbur
Edward E
EE
Massey
Joseph H
JH
Mattice
John D
JD
Mersie
Wondi
W
Mueller
Thomas C
TC
Potter
Thomas
T
Senseman
Scott A
SA
Watson
Elizabeth
E
D000081:Acetamides / Q000737:chemistry / Q000302:isolation & purification; D001280:Atrazine / Q000737:chemistry / Q000302:isolation & purification; D002623:Chemistry Techniques, Analytical / Q000379:methods*; D003976:Diazinon / Q000737:chemistry / Q000302:isolation & purification; D010575:Pesticides / Q000737:chemistry / Q000302:isolation & purification*; D014230:Triazoles / Q000737:chemistry / Q000302:isolation & purification; D014873:Water Pollutants / Q000032:analysis / Q000302:isolation & purification
D000081:Acetamides; D010575:Pesticides; D014230:Triazoles; D014873:Water Pollutants; C087114:tebuconazole; D001280:Atrazine; C051786:metolachlor; D003976:Diazinon