title: Generation of N-heterocyclic carbenes by metal-mediated coupling of propargylamine and isocyanides.
abstract: A new method for the synthesis of heterocyclic carbenes of imidazol-2-ylidene and oxazol-2-ylidene types implying a cycloaddition reaction of propargylamine and propargylic alcohol, respectively, to coordinated isocyanide ligands has been developed.
authors.affiliation: Departamento de Química Orgánica e Inorgánica, Facultad de Química, Universidad de Oviedo, 33006 Oviedo, Spain. jruiz@fq.uniovi.es
authors.forename: Javier
authors.initials: J
authors.lastname: Ruiz
authors.forename: Gabriel
authors.initials: G
authors.lastname: García
authors.forename: Marta E G
authors.initials: ME
authors.lastname: Mosquera
authors.forename: Bernabé F
authors.initials: BF
authors.lastname: Perandones
authors.forename: Marta P
authors.initials: MP
authors.lastname: Gonzalo
authors.forename: Marilín
authors.initials: M
authors.lastname: Vivanco