title: Characterization of pore scale NAPL morphology in homogeneous sands as a function of grain size and NAPL dissolution.
abstract: In this study, we investigate pore scale morphology of nonaqueous phase liquids (NAPLs) trapped in different pore sizes using tracer techniques. Specific interfacial area and saturation of NAPL trapped in homogeneous sands were measured using the interfacial and partitioning tracer techniques. The observed NAPL-water interfacial areas increased in a log-linear fashion with decreasing sand grain size, but showed no clear trend with residual NAPL saturation formed in the various grain sizes. The measured values were used to calculate the NAPL morphology index, which characterizes the spatial NAPL distribution within the pore space. The NAPL morphology indices, increased exponentially with decreasing grain size, indicating that the NAPL becomes smaller, but more blobs. For a fixed grain size, the specific interfacial area and saturation of the NAPL were measured following changes caused by dissolution using alcohol. The observed interfacial areas showed a decrease linearly as a function of the NAPL saturation.
authors.affiliation: Department of Environmental Engineering Sciences, University of Florida, P.O. Box 116450, 220 Black Hall, Gainesville, FL 32611-6450, USA.
authors.forename: Jaehyun
authors.initials: J
authors.lastname: Cho
authors.forename: Michael D
authors.initials: MD
authors.lastname: Annable
mesh_terms: D000327:Adsorption; D001557:Benzenesulfonates; D001965:Bromides; D008962:Models, Theoretical; D010316:Particle Size; D016062:Porosity; D017680:Potassium Compounds; D012822:Silicon Dioxide / Q000737:chemistry*; D012989:Soil Pollutants; D012995:Solubility; D013501:Surface-Active Agents; D013750:Tetrachloroethylene / Q000737:chemistry*
chemical_list: D001557:Benzenesulfonates; D001965:Bromides; D017680:Potassium Compounds; D012989:Soil Pollutants; D013501:Surface-Active Agents; C001114:dodecylbenzenesulfonic acid; D012822:Silicon Dioxide; C039004:potassium bromide; D013750:Tetrachloroethylene