Optical spectra of some 6-styrylo-1H-pyrazolo[3,4-b]quinolines.
It was proposed a method of synthesis several 6-styrylo1-1H-pyrazolo[3,4-b]quinolines as promising material for optoelectronics. Particularly, 6-styryl-1,3-diphenyl-1H-pyrazolo[3,4-b]quinolines were prepared by Wadsworth-Emmons reaction. One of advantageous of these materials is stability of their optical spectra versus the possible cis- and trans-transformation. Theoretical and experimental studies of optical absorption and photoluminescence excitation spectra for styryloquinolines were done. They show that the AM1 semi-empirical method gives better results compared to other approaches. We have found that the solvents do not play a role in the behavior of the spectra. The backside-substituted groups do not influence substantially the observed optical spectra.
Fuks-Janczarek
I
I
Institute of Physics, J. Długosz University of Czestochowa, Al.Armii Krajowej 13/15, Czestochowa, Poland.
Gondek
E
E
Kityk
I V
IV
Danel
K
K
Krzemińska
L
L
Sanetra
J
J
Kwiecień
B
B
D049449:Luminescence; D008956:Models, Chemical; D055095:Optics and Photonics; D011804:Quinolines / Q000737:chemistry*; D013057:Spectrum Analysis; D055672:Static Electricity
D011804:Quinolines