title: Ionic liquids as reaction medium in cellulose functionalization.
abstract: The application of different ionic liquids (IL), namely 1-N-butyl-3-methylimidazolium chloride ([C(4)mim](+)Cl(-)), 3-methyl-N-butyl-pyridinium chloride and benzyldimethyl(tetradecyl)ammonium chloride were investigated as solvents for cellulose. The ILs used have the ability to dissolve cellulose with a degree of polymerization in the range from 290 to 1 200 to a very high concentration. Using [C(4)mim](+)Cl(-), no degradation of the polymer appears. By (13)C NMR measurement it was confirmed that this IL is a so-called non-derivatizing solvent. [C(4)mim](+)Cl(-) can be applied as a reaction medium for the synthesis of carboxymethyl cellulose and cellulose acetate. Without using any catalyst, cellulose derivatives with high degree of substitution could be prepared.(13)C NMR spectrum of cellulose dissolved in the IL [C(4)mim](+)Cl(-) (top). The (13)C NMR spectrum of cellulose dissolved in DMSO/tetrabutylammonium fluoride trihydrate is shown for comparison (bottom).
authors.affiliation: Kompetenzzentrum Polysaccharidforschung, Friedrich-Schiller-Universität Jena, Humboldtstrasse 10, D-07743 Jena, Germany. Thomas.Heinze@uni-jena.de
authors.forename: Thomas
authors.initials: T
authors.lastname: Heinze
authors.forename: Katrin
authors.initials: K
authors.lastname: Schwikal
authors.forename: Susann
authors.initials: S
authors.lastname: Barthel
mesh_terms: D000107:Acetylation; D000838:Anions; D002266:Carboxymethylcellulose Sodium / Q000138:chemical synthesis; D002412:Cations; D002482:Cellulose / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D012995:Solubility; D012997:Solvents
chemical_list: D000838:Anions; D002412:Cations; D012997:Solvents; D002482:Cellulose; D002266:Carboxymethylcellulose Sodium