A basket tetradecavanadate cluster with blue luminescence.
A blue luminescent tetradecavanadate compound, [Et4N]5[V14O36Cl], has been synthesized. It possesses an unprecedented half-open basket framework. Through the {ABAB}-type stacking, the {V14O36} clusters form infinite one-dimensional channels with considerable accessible volume in the crystalline state.
Chen
Lian
L
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, and Graduate School of the Chinese Academy of Sciences, Fujian, Fuzhou 350002, China.
Jiang
Feilong
F
Lin
Zhengzhong
Z
Zhou
Youfu
Y
Yue
Chengyang
C
Hong
Maochun
M