Near-infrared chemiluminescence from the oxidation of ammonia in aqueous alkaline solution.
The chemiluminescent oxidation of ammonia with hypobromite in aqueous alkaline solution evokes a broadly distributed emission in the near-infrared region, with intensity maxima at 1055 nm and 1270 nm.
Francis
Paul S
PS
School of Biological and Chemical Sciences, Deakin University, Geelong, Victoria 3217, Australia. psf@deakin.edu.au
Barnett
Neil W
NW
Smith
Trevor A
TA
Spizzirri
Paul G
PG
Wang
Xueqin
X
Krausz
Elmars
E
D000468:Alkalies / Q000737:chemistry*; D000641:Ammonia / Q000737:chemistry*; D001959:Bromates / Q000737:chemistry*; D049449:Luminescence; D010084:Oxidation-Reduction; D012680:Sensitivity and Specificity; D012996:Solutions / Q000737:chemistry; D019265:Spectroscopy, Near-Infrared / Q000379:methods; D014867:Water / Q000737:chemistry
D000468:Alkalies; D001959:Bromates; D012996:Solutions; D014867:Water; D000641:Ammonia; C027664:hypobromous acid