Solid-phase synthesis of diaryl sulfides: direct coupling of solid-supported aryl halides with thiols using an insoluble polymer-supported reagent.
[reaction: see text] Diaryl sulfides have been prepared by direct nickel(II)-catalyzed coupling of thiols with iodoaryl bound to SynPhase polystyrene lanterns in the presence of polymer-supported borohydride.
Gendre
Fabrice
F
Galderma R&D, Les Templiers, 2400 route des Colles 06410 Biot, Sophia Antipolis Cedex, France.
Yang
Mathieu
M
Diaz
Philippe
P