title: Redox-induced synthesis and encapsulation of metal nanoparticles in shell-cross-linked organometallic nanotubes.
abstract: A new approach to encapsulate silver nanoparticles inside block copolymer nanotubes is reported and involves an in situ redox reaction between a polyferrocenylsilane (PFS) inner wall and silver ions. Partial preoxidation of the PFS domains was found to be a key step for the efficient formation of one-dimensional arrays of silver nanoparticles confined within the nanotubes.
authors.affiliation: Center for Nanostructured Inorganic and Polymeric Materials, Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada M5S 3H6.
authors.forename: Xiao-Song
authors.initials: XS
authors.lastname: Wang
authors.forename: Hai
authors.initials: H
authors.lastname: Wang
authors.forename: Neil
authors.initials: N
authors.lastname: Coombs
authors.forename: Mitchell A
authors.initials: MA
authors.lastname: Winnik
authors.forename: Ian
authors.initials: I
authors.lastname: Manners
mesh_terms: D005296:Ferrous Compounds / Q000737:chemistry; D000075163:Metallocenes; D049329:Nanostructures / Q000737:chemistry*; D043942:Nanotubes / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D011145:Polyvinyls / Q000737:chemistry; D012821:Silanes / Q000737:chemistry; D012833:Siloxanes / Q000737:chemistry; D012834:Silver / Q000737:chemistry*; D013499:Surface Properties
chemical_list: D005296:Ferrous Compounds; D000075163:Metallocenes; D009942:Organometallic Compounds; D011145:Polyvinyls; D012821:Silanes; D012833:Siloxanes; D012834:Silver; C014766:polymethylvinylsiloxane; C004998:ferrocene