title: Sustainable Mizoroki-Heck reaction in water: remarkably high activity of Pd(OAc)2 immobilized on reversed phase silica gel with the aid of an ionic liquid.
abstract: Palladium acetate immobilized on reversed phase amorphous silica gel with the aid of an ionic liquid, [bmim]PF6, was highly efficient in the promotion of the Mizoroki-Heck reaction in pure water without a ligand up to the sixth re-use, in 95% average yield with TON and TOF 1,600,000 and 71,000 (h(-1)), respectively.
authors.affiliation: Graduate School of Science and Technology, Niigata University, 8050, 2-Nocho, Ikarashi, Niigata, Japan. hagiwara@gs.niigata-u.ac.jp
authors.forename: Hisahiro
authors.initials: H
authors.lastname: Hagiwara
authors.forename: Yoshitaka
authors.initials: Y
authors.lastname: Sugawara
authors.forename: Takashi
authors.initials: T
authors.lastname: Hoshi
authors.forename: Toshio
authors.initials: T
authors.lastname: Suzuki