Reversible electrochemical monitoring of surface confined reactions at liquid-liquid interfaces by modulation of ion transfer fluxes.
The adsorption of the neutral surfactant Brij35 at a liquid-liquid interface is reversibly monitored via its disturbance of an electrochemically imposed ion flux across the interface, forming a promising experimental tool for the detection of surface confined reactions at such liquids and polymers.
Xu
Yida
Y
Department of Chemistry and Biochemistry, Auburn University, Auburn, AL 36849, USA.
De Marco
Roland
R
Shvarev
Alexey
A
Bakker
Eric
E
D000327:Adsorption; D004563:Electrochemistry / Q000379:methods*; D007477:Ions / Q000737:chemistry*; D011108:Polymers; D012996:Solutions / Q000737:chemistry*; D013499:Surface Properties; D013501:Surface-Active Agents
D007477:Ions; D011108:Polymers; D012996:Solutions; D013501:Surface-Active Agents