title: Water-based latex dispersions 4. Exchange dynamics and residence times of nonylphenol ethoxylate in concentrated latex dispersions.
abstract: The equilibrium residence times of the nonionic surfactant nonylphenol ethoxylate (NP100) in a latex dispersion were determined using NMR diffusometry. At 16% w/w particle concentration and 0.12, 0.43 and 0.81% w/w NP100, the residence times of the surfactant were 0.16, 1.02 and 4.73 s in solution (tau(A)) and 0.3, 0.37 and 0.61 s on the surface of the particles (tau(B)), respectively. At even higher particle concentration (>45% w/w), tau(A) and tau(B) were 1.47 and 2.2 s. Calculating the number of collisions that ought to result in adsorbed species, at 16% w/w, only 2, 5 and 2 per thousand (corresponding to 0.12, 0.43 and 0.81% w/w NP100) resulted in adsorption, whereas at >45% w/w, only 12 per thousand resulted in adsorption, which suggested that the surfactant was irreversibly adsorbed on the particles. The small increase in collision frequency with increased particle concentration could be a result of a diffusion controlled adsorption, while an energy barrier for desorption controlled the overall exchange dynamics in the dispersion. The slow dynamics in the dispersion was controlled, mainly by the nonylphenol group, which gave NP100 a strong preference to surfaces. In addition, the chain length of the poly(ethylene glycol) (PEG) group changed the solution behavior from being that of a typical surfactant to that of a polymer.
authors.affiliation: Chalmers University of Technology, Department of Chemical and Biological Engineering, Applied Surface Chemistry, SE-412 96 Göteborg, Sweden. catherine.boissier@astrazeneca.com
authors.forename: Catherine
authors.initials: C
authors.lastname: Boissier
authors.forename: Jan-Erik
authors.initials: JE
authors.lastname: Löfroth
authors.forename: Magnus
authors.initials: M
authors.lastname: Nydén
authors.forename: Staffan
authors.initials: S
authors.lastname: Schantz
mesh_terms: D005026:Ethylene Glycols / Q000737:chemistry*; D007840:Latex / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D013499:Surface Properties; D013997:Time Factors; D014867:Water / Q000737:chemistry
chemical_list: D005026:Ethylene Glycols; D007840:Latex; D014867:Water; C021754:terics