Stereoselective E/Z photoisomerization of oxazolidinone functionalized enecarbamates: direct and triplet sensitized irradiation.
Oxazolidinone-functionalized enecarbamates undergo diastereoselective E/Z photoisomerization upon direct and triplet sensitized irradiations with chiral/achiral sensitizers, showing that the enhanced product diastereoselectivity depends on the solvent and temperature.
Saito
Hideaki
H
Department of Chemistry and the Department of Chemical Engineering, Columbia University, 3000 Broadway, Mail Code 3119, New York, NY 10027, USA.
Sivaguru
J
J
Jockusch
Steffen
S
Inoue
Yoshihisa
Y
Adam
Waldemar
W
Turro
Nicholas J
NJ