Coordination polymers formed in solution and in solvent-free environment. Structural transformation due to interstitial solvent removal revealed by X-ray powder diffraction.
The crystal-to-powder transformation induced by solvent removal has been examined through a direct comparison of the structures of the solvated and the unsolvated coordination products determined by single crystal and powder X-ray diffraction, respectively.
Dikarev
Evgeny V
EV
Department of Chemistry, University at Albany, SUNY, Albany, New York 12222, USA. dikarev@albany.edu
Li
Bo
B
Chernyshev
Vladimir V
VV
Shpanchenko
Roman V
RV
Petrukhina
Marina A
MA