A concise and general method for doubly attaching 2-ketosugars to aglycon diols: synthesis of the gomphosides and spectinomycin.
Clemens-Schöpf-Institut für Organische Chemie und Biochemie, Technische Universität Darmstadt, Petersenstrasse 22, 64287 Darmstadt, Germany. lichtenthaler@chemie-tu-darmstadt.de
Frieder W
FW
Lichtenthaler
Eckehard
E
Cuny
Osamu
O
Sakanaka
D000438:Alcohols / Q000737:chemistry*; D029062:Apocynaceae / Q000737:chemistry; D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D002298:Cardenolides / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D007661:Ketoses / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D008969:Molecular Sequence Data; D000198:Spectinomycin / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D000438:Alcohols; D002298:Cardenolides; D007661:Ketoses; C053382:gomphoside; D000198:Spectinomycin