Stereoselective E/Z photoisomerization of oxazolidinone functionalized enecarbamates: direct and triplet sensitized irradiation.
Oxazolidinone-functionalized enecarbamates undergo diastereoselective E/Z photoisomerization upon direct and triplet sensitized irradiations with chiral/achiral sensitizers, showing that the enhanced product diastereoselectivity depends on the solvent and temperature.
Department of Chemistry and the Department of Chemical Engineering, Columbia University, 3000 Broadway, Mail Code 3119, New York, NY 10027, USA.
Hideaki
H
Saito
J
J
Sivaguru
Steffen
S
Jockusch
Yoshihisa
Y
Inoue
Waldemar
W
Adam
Nicholas J
NJ
Turro