Alkaline hydrothermal conversion of fly ash filtrates into zeolites 2: utilization in wastewater treatment.
Filtrates were collected using a codisposal reaction wherein fly ash was reacted with acid mine drainage. These codisposal filtrates were then analyzed by X-ray Fluorescence spectrometry for quantitative determination of the SiO2 and Al2O3 content. Alkaline hydrothermal zeolite synthesis was then applied to the filtrates to convert the fly ash material into zeolites. The zeolites formed under the experimental conditions were faujasite, sodalite, and zeolite A. The use of the fly ash-derived zeolites and a commercial zeolite was explored in wastewater decontamination experiments as it was applied to acid mine drainage in different dosages. The concentrations of Ni, Zn, Cd, As, and Pb metal ions in the treated wastewater were investigated. The results of the treatment of the acid mine drainage with the prepared fly ash zeolites showed that the concentrations of Ni, Zn, Cd, and Hg were decreased as the zeolite dosages of the fly ash zeolite (FAZ1) increased.
Sensor Research Laboratory, Department of Chemistry, University of the Western Cape, Bellville, South Africa. vsomerset@uwc.ac.za
Vernon
V
Somerset
Leslie
L
Petrik
Emmanuel
E
Iwuoha
D002244:Carbon / Q000737:chemistry*; D060729:Coal Ash; D005374:Filtration; D006863:Hydrogen-Ion Concentration; D008906:Mining; D052638:Particulate Matter; D013052:Spectrometry, X-Ray Emission; D014865:Waste Disposal, Fluid / Q000379:methods*; D017641:Zeolites / Q000737:chemistry*
D060729:Coal Ash; D052638:Particulate Matter; D017641:Zeolites; D002244:Carbon