Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate.
Deprotonation of the titanium formate complex [Ar(t-Bu)N]3TiOC(O)H with LiN(i-Pr)2 resulted in the release of free CO and the formation of a titanium(IV) oxoanion complex, isolated as its lithium salt.
Mendiratta
Arjun
A
Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Ave, Room 2-227, Cambridge, MA 02139, USA.
Figueroa
Joshua S
JS
Cummins
Christopher C
CC
D000838:Anions / Q000737:chemistry; D002248:Carbon Monoxide / Q000737:chemistry; D018020:Lithium Compounds / Q000737:chemistry*; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D011437:Propylamines / Q000737:chemistry; D011522:Protons; D014025:Titanium / Q000737:chemistry*
D000838:Anions; D018020:Lithium Compounds; D009942:Organometallic Compounds; D011437:Propylamines; D011522:Protons; D002248:Carbon Monoxide; C007442:diisopropylamine; D014025:Titanium