Reversible hydrogen gas uptake in nanoporous Prussian Blue analogues.
The family of dehydrated nanoporous Prussian Blue analogues, M(II)3[Co(III)(CN)6]2 (M(II) = Mn, Fe, Co, Ni, Cu, Zn, Cd), which contain coordinatively unsaturated divalent metal cations, undergoes reversible sorption of hydrogen gas up to 1.2 wt% (at 77 K, 101.3 kPa), the capacity of which depends on the metal ion.
School of Chemistry, University of Sydney, NSW 2006, Australia.
Karena W
KW
Chapman
Peter D
PD
Southon
Colin L
CL
Weeks
Cameron J
CJ
Kepert