Solvent-free methylthiomethyllithium [LiCH2SMe]infinity: solid state structure and thermal decomposition.
Solvent-free [LiCH2SMe]infinity forms a layer structure consisting of four- (Li2C2), five- (Li2CS2), and six-membered (Li2C2S2) rings in the solid state; the compound violently explodes upon heating to T=160+/-5 degrees C under an argon atmosphere.
Institut für Anorganische Chemie, J.W. Goethe-Universität Frankfurt, Marie-Curie-Strasse 11, D-60439, Frankfurt (Main), Germany.
Kai
K
Ruth
Robert E
RE
Dinnebier
Stefan W
SW
Tönnes
Edith
E
Alig
Ingeborg
I
Sänger
Hans-Wolfram
HW
Lerner
Matthias
M
Wagner
D006358:Hot Temperature; D018020:Lithium Compounds / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds; D012997:Solvents / Q000737:chemistry
D018020:Lithium Compounds; D009942:Organometallic Compounds; D012997:Solvents; C518322:methylthiomethyllithium