Synthesis and characterization of a Mo/Ag/Rb heterotrimetallic cluster with double-cage architecture.
The first Mo/Ag/Rb heterotrimetallic cluster has been synthesised by a self-assembly reaction involving [Mo2O2S2edt2]2-, Ag+, Rb+, S2- and dibenzo-18-crown-6 (DB18C6); the structure consists of two [{Mo6Ag6O6S7edt6}2{Rb(DB18C6)}]3- units linked by Rb-C contacts.
Lin
Ping
P
Chemistry, School of Natural Sciences, Bedson Building, University of Newcastle, Newcastle Upon Tyne NE1 7RU, UK.
Clegg
William
W
Harrington
Ross W
RW
Henderson
Richard A
RA