Ferrocenylalanes: solid-state and solution structures of some new aluminum-bridged ansa-ferrocenes.
Addition of dilithiated ferrocene to AlEt2Cl and Al(kappa2-C,NNMe2CH2C6H4)Cl2 yields the trimeric ferrocenyl derivative 1 and the dimeric [1,1']-ferrocenophane 2, respectively. Solution spectroscopy is consistent with the solid-state structures, which reveal unusual and unprecedented bonding around the aluminum centers.
Braunschweig
Holger
H
Institut für Anorganische Chemie, Bayerische Julius-Maximilians Universität der Würzburg, Am Hubland, Würzburg D-97074, Germany. h.braunschweig@mail.uni-wuerzburg.de
Burschka
Christian
C
Clentsmith
Guy K B
GK
Kupfer
Thomas
T
Radacki
Krzysztof
K