Diels-Alder addition to fluorinated single walled carbon nanotubes.
Fluorinated single walled carbon nanotubes (SWNTs) undergo a facile Diels-Alder [4 + 2] cycloaddition with a range of dienes resulting in a C ratio substituent ratio between 20 ratio 1 to 32 ratio 1; IR, Raman, AFM and (13)C NMR characterization are consistent with sidewall functionalization.
Department of Chemistry and Center for Nanoscale Science and Technology, Rice University, 6100 Main Street, Houston, Texas 77005, USA.
Lei
L
Zhang
Jianzhong
J
Yang
Christopher L
CL
Edwards
Lawrence B
LB
Alemany
Valery N
VN
Khabashesku
Andrew R
AR
Barron