New diphosphine ligands based on diphenyl ether for the Pd-catalyzed CO/ethene copolymerization.
The catalytic activity and selectivity of palladium(II) complexes of new, flexible bidentate ligands in the CO/ethene copolymerization reaction have been found to change considerably with the steric properties of the ligands.
Department of Chemical Engineering and Chemistry, Technische Universiteit Eindhoven, P.O. Box 513, 5600 MB, Eindhoven, The Netherlands.
Maria
M
Caporali
Christian
C
Müller
Bastiaan B P
BB
Staal
Duncan M
DM
Tooke
Anthony L
AL
Spek
Piet W N M
PW
van Leeuwen
D002248:Carbon Monoxide / Q000737:chemistry; D002384:Catalysis; D005030:Ethylenes / Q000737:chemistry; D008024:Ligands; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010647:Phenyl Ethers / Q000737:chemistry; D010720:Phosphines / Q000138:chemical synthesis / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis; D013237:Stereoisomerism
D005030:Ethylenes; D008024:Ligands; D009942:Organometallic Compounds; D010647:Phenyl Ethers; D010720:Phosphines; D011108:Polymers; C031538:phenyl ether; D010165:Palladium; D002248:Carbon Monoxide; C036216:ethylene