Square planar bis(imino)pyridine iron halide and alkyl complexes.
Square planar iron methyl complexes containing bis(imino)pyridine (PDI) ligands have been prepared by reductive alkylation of the corresponding ferrous dichloride; dialkylation is observed upon treatment with a larger alkyl lithium.
Bouwkamp
Marco W
MW
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853, USA.
Bart
Suzanne C
SC
Hawrelak
Eric J
EJ
Trovitch
Ryan J
RJ
Lobkovsky
Emil
E
Chirik
Paul J
PJ
D001966:Bromine / Q000737:chemistry*; D002713:Chlorine / Q000737:chemistry*; D005290:Ferric Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D007097:Imines / Q000737:chemistry*; D015394:Molecular Structure; D011725:Pyridines / Q000737:chemistry*
D005290:Ferric Compounds; D007097:Imines; D011725:Pyridines; D002713:Chlorine; D001966:Bromine