Donor effect on supramolecular structures of silver(I) perchlorate complexes of macrocycles with O2S2X (X=S, O and NH) donor sets.
By virtue of simple one donor variations of O(2)S(2)X-donor macrocycles (L(1): X=S, L(2): X=O and L(3): X=NH) towards silver(I) perchlorates, four supramolecular complexes (1-3) with different topologies have been isolated; L(1) afforded solvent- and anion-free sandwich complex (1), otherwise L(2) and L(3) gave the dimeric (2a), 1-D polymeric (2b), and tetrameric bowl-type (3) complexes with solvent or anion coordination.
Department of Chemistry and Research Institute of Natural Sciences, Gyeongsang National University, Chinju 660-701, S. Korea.
Il
I
Yoon
Joobeom
J
Seo
Ji-Eun
JE
Lee
Mi Ryoung
MR
Song
So Young
SY
Lee
Kyu Seong
KS
Choi
Ok-Sang
OS
Jung
Ki-Min
KM
Park
Shim Sung
SS
Lee