The new polynuclear titanium(IV) complex [(Cp*TiCl)(mu-O)2(Cp*Ti)2(mu-O)(mu-O)2]2Ti (Cp* is eta5-C5Me5).
A new polynuclear titanium(IV) complex, dichlorodeca-mu2-oxo-hexakis(pentamethylcyclopentadienyl)hexatitanium(IV), [Ti6(C10H15)6Cl2O10], has been synthesized by hydrolysis of a titanium complex bearing an N-(2-hydroxy-3,5-dimethylbenzyl)diethanolamine Mannich ligand. The molecule has two O-bridged Ti3O3 rings linked to two similar rings through a tetrahedrally O-coordinated Ti atom. All Ti atoms except the central one are coordinated to pentamethylcyclopentadienyl (Cp*) ligands. The Cp* ligands are arranged with approximate symmetry with respect to the Ti/O/Cl core.
Chen
Jie
J
State Key Laboratory of Polymer Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, No. 5625 Renmin Street, Changchun 130022, People's Republic of China.
Hu
Ning-Hai
NH
Zhan
Jie
J
Li
Yue-Sheng
YS