New diphosphine ligands based on diphenyl ether for the Pd-catalyzed CO/ethene copolymerization.
The catalytic activity and selectivity of palladium(II) complexes of new, flexible bidentate ligands in the CO/ethene copolymerization reaction have been found to change considerably with the steric properties of the ligands.
Caporali
Maria
M
Department of Chemical Engineering and Chemistry, Technische Universiteit Eindhoven, P.O. Box 513, 5600 MB, Eindhoven, The Netherlands.
Müller
Christian
C
Staal
Bastiaan B P
BB
Tooke
Duncan M
DM
Spek
Anthony L
AL
van Leeuwen
Piet W N M
PW
D002248:Carbon Monoxide / Q000737:chemistry; D002384:Catalysis; D005030:Ethylenes / Q000737:chemistry; D008024:Ligands; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010647:Phenyl Ethers / Q000737:chemistry; D010720:Phosphines / Q000138:chemical synthesis / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis; D013237:Stereoisomerism
D005030:Ethylenes; D008024:Ligands; D009942:Organometallic Compounds; D010647:Phenyl Ethers; D010720:Phosphines; D011108:Polymers; C031538:phenyl ether; D010165:Palladium; D002248:Carbon Monoxide; C036216:ethylene