Oxidative cyclization of diols derived from 1,5-dienes: formation of enantiopure cis-tetrahydrofurans by using catalytic osmium tetroxide; formal synthesis of (+)-cis-solamin.
Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, UK. timothy.donohoe@chem.ox.ac.uk
Timothy J
TJ
Donohoe
Sam
S
Butterworth
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D001558:Benzethonium / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003500:Cyclization; D005663:Furans / Q000138:chemical synthesis* / Q000737:chemistry; D008968:Molecular Conformation; D009993:Osmium Tetroxide / Q000737:chemistry*; D010084:Oxidation-Reduction; D013237:Stereoisomerism
D000475:Alkenes; D005663:Furans; D001558:Benzethonium; D009993:Osmium Tetroxide