Stereoselective intramolecular 1,3 C-H insertion in Rh(II) carbene reactions.
[reaction: see text] 1,3 C-H insertion has been found to be a predominant reaction pathway in the Rh(II)-mediated reaction of beta-tosyl alpha-diazo carbonyl compounds.
Key Laboratory of Bioorganic Chemistry and Molecular Engineering, Ministry of Education, College of Chemistry, Peking University, Beijing, China.
Weifeng
W
Shi
Bo
B
Zhang
Jian
J
Zhang
Binge
B
Liu
Shiwei
S
Zhang
Jianbo
J
Wang