Immobilization of TiO2 nanopowder on glass beads for the photocatalytic decolorization of an azo dye C.I. Direct Red 23.
TiO2 supported on glass beads was prepared and its photocatalytic activity was determined by photooxidation of the commercial textile dye, C.I. Direct Red 23, in aqueous solution illuminated by a UV-C lamp (30 W). The progress of photocatalytic decolorization of the C.I. Direct Red 23 was studied by measuring the absorbance at lambda(max) = 507 nm by UV Vis spectrophotometer. The experiments indicated that both UV light and TiO2 were needed for the effective destruction of the dye. The effect of pH on the rate of decolorization efficiency was followed in the pH range 2-12. Acidic pH range was found to favor the decolorization rate. The addition of a proper amount of hydrogen peroxide improved the decolorization, whereas the excess hydrogen peroxide quenched the formation of hydroxyl radicals (*OH). The electrical energy consumption per order of magnitude for photocatalytic decolorization of the dye was lower in the UV/TiO2/H2O2 process than that in the UV/TiO2 process. In the real wastewater sample the efficiency of the method was determined by measuring the changes in the absorption spectra of the dye solution during photodegradation. Our results indicated that during the photooxidation process, the decolorization efficiency was more than 80% at irradiation time of 3 h.
Water and Wastewater Treatment Research Laboratory, Department of Applied Chemistry, Faculty of Chemistry, University of Tabriz, Tabriz, Iran. nezam_daneshvar@yahoo.com
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Daneshvar
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Salari
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Niaei
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Rasoulifard
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Khataee
D001391:Azo Compounds / Q000737:chemistry*; D002384:Catalysis; D004396:Coloring Agents / Q000737:chemistry*; D005898:Glass; D049329:Nanostructures; D009282:Naphthalenesulfonates / Q000737:chemistry*; D010777:Photochemistry; D013783:Textile Industry; D014025:Titanium / Q000737:chemistry*; D014466:Ultraviolet Rays; D014865:Waste Disposal, Fluid / Q000379:methods*; D018508:Water Purification / Q000379:methods*
D001391:Azo Compounds; D004396:Coloring Agents; D009282:Naphthalenesulfonates; C009495:titanium dioxide; D014025:Titanium; C504885:C.I. Direct Red 23