Eu8(NCN)5-deltaI6+2delta (delta= 0.05): a novel rare-earth carbodiimide iodide containing oligomeric tritetrahedral Eu8 clusters.
Eu8(NCN)4.95I6.10 is the first compound with discrete tritetrahedral Eu8 clusters which are interconnected by coordinating NCN2- carbodiimide anions on their triangular faces to form separated layers, the latter being bridged by iodide and carbodiimide anions.
Liao
Wuping
W
Institut für Anorganische Chemie der RWTH Aachen, Landoltweg 1, D-52056 Aachen, Germany.
Fokwa
Boniface P T
BP
Dronskowski
Richard
R