An FTIR study of the effects of artificial saliva on the physical characteristics of the glass ionomer cements used for art.
OBJECTIVE
To investigate the physical and chemical changes of five esthetic restorative materials in an artificial saliva using Fourier transform infrared spectroscopy (FTIR).


METHODS
The materials included two glass polyalkenoate (ionomer) cements, one polyacid-modified resin composite, and two resin composites. Five fresh and 20 aged specimens for each material were immersed in 2 ml of artificial saliva at 37 degrees C for 1 week, 2 weeks, 1 month, and 2 months. They were examined by laser surface profilometer and FTIR.


RESULTS
Surface roughness average (Ra) value showed significant differences among the physical properties of glass ionomers, polyacid-modified resin composite, and resin composites.


CONCLUSIONS
FTIR spectra showed that a major chemical changes in Fuji IX GP Fast glass ionomer cement in P-NH2 group bonding (900-1000 cm(-1)) that may explain the previously reported increase in microhardness after immersion. There was no direct correlation between surface roughness and spectral changes of the materials tested.
Yip
H K
HK
Faculty of Dentistry, University of Hong Kong, Prince Philip Dental Hospital, 34 Hospital Road, Hong Kong SAR, China. hkyip@hkusua.hku.hk
To
W M
WM
D020770:Compomers / Q000737:chemistry; D003188:Composite Resins / Q000737:chemistry; D005899:Glass Ionomer Cements / Q000737:chemistry*; D006801:Humans; D007101:Immersion; D007834:Lasers; D008422:Materials Testing; D009584:Nitrogen / Q000737:chemistry; D010758:Phosphorus / Q000737:chemistry; D012464:Saliva, Artificial / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013499:Surface Properties; D013696:Temperature; D013997:Time Factors
D020770:Compomers; D003188:Composite Resins; C444701:Filtek Z250; C477332:Freedom Compomer; C439808:Fuji IX GP Fast; D005899:Glass Ionomer Cements; C424245:Ketac-Molar Aplicap; D012464:Saliva, Artificial; C487361:Unifil F; D010758:Phosphorus; D009584:Nitrogen