Synthesis of new organic super acids-N-(trifluoromethylsulfonyl)imino derivatives of trifluoromethanesulfonic acid and bis(trifluoromethylsulfonyl)imide.
Salts of N-trifluoromethylsulfonyl derivatives of trifluoromethyl- and phenylsulfonimidoyl imides have been synthesized by two different routes. Both methods are one-pot reactions, that run in mild conditions with good yields. Two novel organic super acids: bis[N-(trifluoromethylsulfonyl)trifluoromethanesulfonimidoyl]imide and N,N'-bis(trifluoromethyl-sulfonyl)diimino trifluoromethanesulfonic acid were prepared and the structure of their potassium salts was obtained by single-crystal X-ray diffraction.
Garlyauskayte
Romute Yu
RY
Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 02094 Murmanskaya str. 5, Kiev, Ukraine. roma@bpci.kiev.ua
Chernega
Alexander N
AN
Michot
Christophe
C
Armand
Michel
M
Yagupolskii
Yurii L
YL
Yagupolskii
Lev M
LM