Diastereoselection of chiral acids in a cylindrical capsule.
The cylindrical dimeric capsule binds two chiral carboxylic acids with modest selectivity for homochiral or heterochiral pairs.
Palmer
Liam C
LC
Skaggs Institute for Chemical Biology and Department of Chemistry, Scripps Research Institute, La Jolla, California 92037, USA.
Zhao
Yi-Lei
YL
Houk
K N
KN
Rebek
Julius
J
D000143:Acids / Q000737:chemistry*; D019281:Dimerization; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism
D000143:Acids