Effect of surface modification on the reactivity of MCF-supported IndaBOX.
MCF-immobilized indaBOX-copper complexes, which show high enantioselectivities in asymmetric Diels-Alder and cyclopropanation reactions and have reactivities strongly affected by their environment, were prepared using various linker groups and silanol capping agents.
Lancaster
Thomas M
TM
Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
Lee
Su Seong
SS
Ying
Jackie Y
JY
D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D003432:Cross-Linking Reagents; D003521:Cyclopropanes / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D010080:Oxazoles / Q000737:chemistry*; D013237:Stereoisomerism; D013499:Surface Properties
D003432:Cross-Linking Reagents; D003521:Cyclopropanes; D009942:Organometallic Compounds; D010080:Oxazoles; D003300:Copper; C030797:cyclopropane