title: Triphosph(III)azanes to diphosph(III)azanes; a cracking transformation.
abstract: The reversible interconversion between trimeric [ClPNEt]3 and dimeric [ClPNEt]2 reported here is the first observation of such a thermally induced rearrangement between two cyclophosphazane oligomers; the structure of 1.cis is reported along with NMR studies of its conversion into 2.
authors: Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UKCB2 1EW.
authors: Felipe
authors: F
authors: García
authors: Richard A
authors: RA
authors: Kowenicki
authors: Lucía
authors: L
authors: Riera
authors: Dominic S
authors: DS
authors: Wright
mesh_terms: D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D009943:Organophosphorus Compounds / Q000737:chemistry*; D012680:Sensitivity and Specificity
chemical_list: D009943:Organophosphorus Compounds