Triphosph(III)azanes to diphosph(III)azanes; a cracking transformation.
The reversible interconversion between trimeric [ClPNEt]3 and dimeric [ClPNEt]2 reported here is the first observation of such a thermally induced rearrangement between two cyclophosphazane oligomers; the structure of 1.cis is reported along with NMR studies of its conversion into 2.
García
Felipe
F
Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UKCB2 1EW.
Kowenicki
Richard A
RA
Riera
Lucía
L
Wright
Dominic S
DS
D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D009943:Organophosphorus Compounds / Q000737:chemistry*; D012680:Sensitivity and Specificity
D009943:Organophosphorus Compounds