Highly enantioselective iridium-catalysed allylic aminations with anionic N-nucleophiles.
Iridium-catalysed allylic substitutions with anionic N-nucleophiles were achieved with regioselectivity of up to 49:1 and enantiomeric excess of up to 98%.
Weihofen
Robert
R
Organisch-Chemisches Institut der Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69207 Heidelberg, Germany. g.helmchen@urz.uni-heidelberg.de
Dahnz
Axel
A
Tverskoy
Olena
O
Helmchen
Günter
G