title: [Cp*Rh(bpy)(H2O)]2+ as a coenzyme substitute in enzymatic oxidations catalyzed by Baeyer-Villiger monooxygenases.
abstract: [Cp*Rh(bpy)(H2O)]2+ was applied as a flavin regenerating reagent in BVMO catalyzed oxidations of organic sulfides to chiral sulfoxides.
authors: Istituto di Chimica del Riconoscimento Molecolare, CNR, via Mario Bianco 9, 20131, Milano, Italy.
authors: Gonzalo
authors: G
authors: de Gonzalo
authors: Gianluca
authors: G
authors: Ottolina
authors: Giacomo
authors: G
authors: Carrea
authors: Marco W
authors: MW
authors: Fraaije
mesh_terms: D002384:Catalysis; D003067:Coenzymes / Q000737:chemistry* / Q000378:metabolism*; D006899:Mixed Function Oxygenases / Q000378:metabolism*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry* / Q000378:metabolism*; D010084:Oxidation-Reduction; D012238:Rhodium / Q000737:chemistry* / Q000378:metabolism*; D013379:Substrate Specificity; D013440:Sulfides / Q000737:chemistry / Q000378:metabolism; D013463:Sulfuric Acid Esters / Q000737:chemistry / Q000378:metabolism
chemical_list: D003067:Coenzymes; D009942:Organometallic Compounds; D013440:Sulfides; D013463:Sulfuric Acid Esters; C093850:methylphenylsulfide; D012238:Rhodium; D006899:Mixed Function Oxygenases; C011612:diethyl sulfate