[Cp*Rh(bpy)(H2O)]2+ as a coenzyme substitute in enzymatic oxidations catalyzed by Baeyer-Villiger monooxygenases.
[Cp*Rh(bpy)(H2O)]2+ was applied as a flavin regenerating reagent in BVMO catalyzed oxidations of organic sulfides to chiral sulfoxides.
de Gonzalo
Gonzalo
G
Istituto di Chimica del Riconoscimento Molecolare, CNR, via Mario Bianco 9, 20131, Milano, Italy.
Ottolina
Gianluca
G
Carrea
Giacomo
G
Fraaije
Marco W
MW
D002384:Catalysis; D003067:Coenzymes / Q000737:chemistry* / Q000378:metabolism*; D006899:Mixed Function Oxygenases / Q000378:metabolism*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry* / Q000378:metabolism*; D010084:Oxidation-Reduction; D012238:Rhodium / Q000737:chemistry* / Q000378:metabolism*; D013379:Substrate Specificity; D013440:Sulfides / Q000737:chemistry / Q000378:metabolism; D013463:Sulfuric Acid Esters / Q000737:chemistry / Q000378:metabolism
D003067:Coenzymes; D009942:Organometallic Compounds; D013440:Sulfides; D013463:Sulfuric Acid Esters; C093850:methylphenylsulfide; D012238:Rhodium; D006899:Mixed Function Oxygenases; C011612:diethyl sulfate