title: Reduction of N2 to ammonia and hydrazine utilizing H2 as the reductant.
abstract: The trans-Fe(DMeOPrPE)2Cl2 complex (where DMeOPrPE = 1,2-bis(bis(methoxypropyl)phosphino)ethane) undergoes a series of reactions that involve the activation of both H2 and N2 to produce ammonia and hydrazine. A Leigh-type cycle was employed to achieve laboratory fixation of dinitrogen at room temperature and pressure utilizing H2 as the reductant.
authors: Department of Chemistry, University of Oregon, Eugene, Oregon 97403, USA.
authors: John D
authors: JD
authors: Gilbertson
authors: Nathaniel K
authors: NK
authors: Szymczak
authors: David R
authors: DR
authors: Tyler