Mixed micelles formed by SDS and a bolaamphiphile with carbohydrate headgroups.
The formation of micelles in aqueous mixtures of a carbohydrate-based bolaamphiphile and sodium dodecyl sulfate (SDS) is investigated by surface tension and small-angle neutron scattering. The obtained values of critical micelle concentration (CMC) are analyzed within the framework of regular solution theory. Synergetic interactions between the bolaamphiphile and SDS are observed (parameter beta is negative; a minimum in the plot CMC vs composition). SANS data are collected for mixtures containing protonated and deuterated SDS. This gives us the possibility to conclude that mixed micelles with a homogeneous distribution of surfactant molecules within the micelle are formed. The shape of the micelles is found to be slightly oblate.
Gerber
Sven
S
Institute of Organic Chemistry, University of Hamburg, Martin-Luther-King-Platz 6, 20146 Hamburg, Germany.
Garamus
Vasil M
VM
Milkereit
Götz
G
Vill
Volkmar
V