title: Recoverable fluorous CBS methodology for asymmetric reduction of ketones.
abstract: [reaction: see text]. An operationally simple and recoverable fluorous CBS methodology was developed. The in situ-generated fluorous oxazaborolidine efficiently catalyzed the reduction of ketones with high enantioselectivity and reactivity. The subsequent recycling of the fluorous prolinol precatalyst was achieved by fluorous solid-phase extraction.
authors: Institute of Biomolecular Chemistry, Chemical Research Center of Hungarian Academy of Science, Budapest.
authors: Zoltán
authors: Z
authors: Dalicsek
authors: Ferenc
authors: F
authors: Pollreisz
authors: Agnes
authors: A
authors: Gömöry
authors: Tibor
authors: T
authors: Soós
mesh_terms: D002384:Catalysis; D005461:Fluorine / Q000737:chemistry*; D007202:Indicators and Reagents; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D011759:Pyrrolidines / Q000138:chemical synthesis* / Q000737:chemistry*
chemical_list: D007202:Indicators and Reagents; D007659:Ketones; D011759:Pyrrolidines; D005461:Fluorine; C010509:prolinol