Removal of molybdate from water by adsorption onto ZnCl2 activated coir pith carbon.
Removal and recovery of molybdate from aqueous solution was investigated using ZnCl2 activated carbon developed from coir pith. Studies were conducted to delineate the effects of contact time, adsorbent dose, molybdate concentration, pH and temperature. Two theoretical adsorption isotherms, namely, Langmuir and Freundlich were used to describe the experimental results. The Langmuir adsorption capacity (Q0) was found to be 18.9 mg molybdate/g of the adsorbent. Adsorption followed second order kinetics. Studies were performed at different pH values to find out the pH at which maximum adsorption occurred. The pH effect and desorption studies showed that ion exchange and chemisorption mechanism were involved in the adsorption process. Thermodynamic parameters such as DeltaG0, DeltaH0 and DeltaS0 for the adsorption were evaluated. Effect of foreign ions on adsorption of molybdate has been examined. The results showed that ZnCl2 activated coir pith carbon was effective for the removal and recovery of molybdate from water.
Namasivayam
C
C
Environmental Chemistry Division, Department of Environmental Sciences, Bharathiar University, Coimbatore 641 046, India. cnamasi@vsnl.com
Sangeetha
D
D
D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D002712:Chlorides / Q000493:pharmacokinetics*; D006863:Hydrogen-Ion Concentration; D008982:Molybdenum / Q000302:isolation & purification*; D012996:Solutions; D013696:Temperature; D013816:Thermodynamics; D014867:Water / Q000737:chemistry*; D017967:Zinc Compounds / Q000493:pharmacokinetics*
D002712:Chlorides; D012996:Solutions; D017967:Zinc Compounds; D014867:Water; C044659:molybdate; D002244:Carbon; D008982:Molybdenum