Asymmetric azido-copper(II) bridges: ferro- or antiferromagnetic? experimental and theoretical magneto-structural studies.
Reaction of NaN(3) with the [Cu(II)(tn)](2+) ion (tn = 1,3-diaminopropane) in basic aqueous solution yields the azido-bridged complex of formula [Cu(2)(tn)(2)(N(3))(4)] (1), which is characterized by X-ray crystallography. The structure of 1 is made up of dinuclear neutral complexes, of formula [Cu(2)(tn)(2)(N(3))(4)], resulting from the assembling of two mononuclear units through two equivalent end-on azide bridges connecting asymmetrically two Cu(tn)(N(3))(2) entities. These dinuclear units are connected through two asymmetric end-to-end N(3) bridges to form a chain of dimers. Magnetic measurements for compound 1 show weak antiferromagnetic exchange interactions between the Cu(II) ions. The magnetic data were modeled using the susceptibility expression derived for an alternating AF S = 1/2 chain. A very satisfactory fit over the whole temperature range was obtained with g = 2.1438(4), J(1) = -3.71(2) cm(-1), and J(2) = -3.10(2) cm(-1) (J(1) and J(2) are the singlet-triplet separations). This magnetic behavior differs from those observed for similar examples which were reported as having alternating ferro- and antiferromagnetic exchange interactions; thus, DFT calculations were done to understand the nature of the magnetic coupling in such asymmetric end-on and end-to-end N(3) bridges. Theoretical results show that the double asymmetric end-on bridges produce antiferromagnetic coupling while the end-to-end ones can present ferro- or antiferromagnetic coupling depending on the copper coordination sphere.
Triki
Smaïl
S
UMR CNRS 6521, University of Bretagne Occidentale, 6 avenue V. Le Gorgeu, BP 809, 29285 Brest Cedex, France. smail.triki@univ-brest.fr
Gómez-García
Carlos J
CJ
Ruiz
Eliseo
E
Sala-Pala
Jean
J
D001386:Azides / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007501:Iron / Q000737:chemistry*; D008280:Magnetics; D008956:Models, Chemical; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013696:Temperature
D001386:Azides; D009942:Organometallic Compounds; D003300:Copper; D007501:Iron