The electrochemical evaluation of a Zr-based bulk metallic glass in a phosphate-buffered saline electrolyte.
Bulk metallic glasses (BMGs) represent an emerging class of materials with an amorphous structure and a unique combination of properties. The objectives of this investigation were to define the electrochemical behavior of a specific Zr-based BMG alloy in a physiologically relevant environment and to compare these properties to standard, crystalline biomaterials as well as other Zr-based BMG compositions. Cyclic-anodic-polarization studies were conducted with a Zr52.5Cu17.9Ni14.6Al10.0Ti5.0 (at %) BMG in a phosphate-buffered saline electrolyte with a physiologically relevant oxygen content at 37 degrees C. The results were compared to three common, crystalline biomaterials: CoCrMo, 316L stainless steel, and Ti-6Al-4V. The BMG alloy was found to have a lower corrosion penetration rate (CPR), as compared to the 316L stainless steel, and an equivalent CPR, as compared to the CoCrMo and Ti-6Al-4V alloys. Furthermore, the BMG alloy demonstrated better localized corrosion resistance than the 316L stainless steel. However, the localized corrosion resistance of the BMG alloy was not as high as those of the CoCrMo and Ti-6Al-4V alloys in the tested environment. The excellent electrochemical properties demonstrated by the BMG alloy are combined with a low modulus and unparalleled strength. This unique combination of properties dramatically demonstrates the potential for amorphous alloys as a new generation of biomaterials.
Morrison
M L
ML
Department of Materials Science and Engineering, The University of Tennessee, 434 Dougherty Engineering Building, Knoxville, Tennessee 37996-2200, USA. mmorrison@utk.edu
Buchanan
R A
RA
Leon
R V
RV
Liu
C T
CT
Green
B A
BA
Liaw
P K
PK
Horton
J A
JA
D002021:Buffers; D004563:Electrochemistry; D004566:Electrodes; D005898:Glass / Q000737:chemistry*; D017669:Mercury Compounds; D010710:Phosphates; D012965:Sodium Chloride; D014961:X-Ray Diffraction; D015040:Zirconium / Q000737:chemistry*
D002021:Buffers; D017669:Mercury Compounds; D010710:Phosphates; D012965:Sodium Chloride; D015040:Zirconium; C015728:calomel