Regio- and stereoselective synthesis of enantiomerically pure [60]fullerene tris-adducts with an inherently chiral e,e,e addition pattern.
The synthesis and flash column chromatographic separation of enantiomerically pure tris-adducts of C60 with an e,e,e-addition pattern is achieved via cyclopropanation with chiral D3-symmetrical cyclo-tris(malonate) tethers.
Chronakis
Nikos
N
Institut für Organische Chemie der Universität Erlangen, Henkestrasse 42, D-91054 Erlangen, Germany.
Hirsch
Andreas
A