A novel octanuclear Mn(III) aggregate as a single-molecule magnet.
The novel octanuclear cluster [Mn8O2(OH)2(OMe)12(OAc)2(Mesalim)4] (1) presents SMM behaviour with a relatively high experimental energy barrier (eff/kB= 36.0 K) as shown by its dc and ac magnetic properties.
Godbole
Meenal D
MD
Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, P.O. Box 9502, 2300 RA Leiden, The Netherlands. bouwman@chem.leidenuniv.nl.
Roubeau
Olivier
O
Clérac
Rodolphe
R
Kooijman
Huub
H
Spek
Anthony L
AL
Bouwman
Elisabeth
E