title: Organic thin-film electronics from vitreous solution-processed rubrene hypereutectics.
abstract: Electronic devices based on single crystals of organic semiconductors provide powerful means for studying intrinsic charge-transport phenomena and their fundamental electronic limits. However, for technological exploitation, it is imperative not to be confined to the tedious growth and cumbersome manipulation of molecular crystals-which generally show notoriously poor mechanical properties-but to be able to process such materials into robust architectures by simple and efficient means. Here, we advance a general route for facile fabrication of thin-film devices from solution. The key beneficial feature of our process-and the principal difference from existing vapour deposition and solution-processing schemes-is the incorporation of a glass-inducing diluent that enables controlled crystallization from an initial vitreous state of the organic semiconductor, formed in a selected area of the phase diagram of the two constituents. We find that the vitrifying diluent does not adversely affect device performance. Indeed, our environmentally stable, discrete rubrene-based transistors rival amorphous silicon devices, reaching saturated mobilities of up to 0.7 cm2 V-1 s-1, ON-OFF ratios of >or=10(6) and subthreshold slopes as steep as 0.5 V per decade. A nearly temperature-independent device mobility, indicative of a high crystalline quality of our solution-processed, rubrene-based films, corroborates these findings. Inverter and ring-oscillator structures are also demonstrated.
authors: Philips Research Laboratories, Professor Holstlaan 4, 5656 AA, Eindhoven, The Netherlands. n.stingelin-stutzmann@qmul.ac.uk
authors: Natalie
authors: N
authors: Stingelin-Stutzmann
authors: Edsger
authors: E
authors: Smits
authors: Harry
authors: H
authors: Wondergem
authors: Cristina
authors: C
authors: Tanase
authors: Paul
authors: P
authors: Blom
authors: Paul
authors: P
authors: Smith
authors: Dago
authors: D
authors: de Leeuw