Liquid-phase oxidation of alkylaromatics by a H-atom transfer mechanism with a new heterogeneous CoSBA-15 catalyst.
A new pseudo-tetrahedral Co(II) complex has been grafted onto the surface of SBA-15 and successfully utilized for the catalytic oxidization of alkylaromatic substrates with tert-butyl hydroperoxide (TBHP)via an H-atom transfer mechanism.
Brutchey
Richard L
RL
Department of Chemistry, University of California, Berkeley, Berkeley, California 94720-1460, USA.
Drake
Ian J
IJ
Bell
Alexis T
AT
Tilley
T Don
TD
D000478:Alkylation; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D012822:Silicon Dioxide
C518143:CoSBA-15; D009942:Organometallic Compounds; C509969:SBA-15; D012822:Silicon Dioxide; D006859:Hydrogen