title: Pressure response of Raman spectra of water and its implication to the change in hydrogen bond interaction.
abstract: In situ Raman spectroscopic measurements of water in the region of OH vibration were conducted up to 0.4 GPa at 23 and 52 degrees C. The frequencies of the decomposed OH stretching bands initially decreased with increasing pressure, reached a minimum at 0.15 GPa and increased up to 0.3 GPa and then decreased, which corresponds to the variations of the strength of hydrogen bonding. This variation was observed at 23 degrees C, but not at 52 degrees C, which suggests a change in pressure dependence on the hydrogen bond interaction between these two temperatures. Based on the equilibration model between hydrogen-bonded and nonhydrogen-bonded molecules, the present experimental results indicate that the pressure variation of the viscosity depends on the ratio of hydrogen-bonded molecules, rather than the strength of hydrogen bonding between molecules.
authors: Laboratory for Earthquake Chemistry, Graduate School of Science, University of Tokyo, Tokyo 113-0033, Japan. okataku@ess.sci.osaka-u.ac.jp
authors: Taku
authors: T
authors: Okada
authors: Kazuki
authors: K
authors: Komatsu
authors: Tatsuhiko
authors: T
authors: Kawamoto
authors: Takamitsu
authors: T
authors: Yamanaka
authors: Hiroyuki
authors: H
authors: Kagi
mesh_terms: D006860:Hydrogen Bonding; D011312:Pressure; D013059:Spectrum Analysis, Raman; D013696:Temperature; D014867:Water / Q000737:chemistry*
chemical_list: D014867:Water