title: Diastereoselective Ni(0)-catalyzed carbocyclization to chiral vinylic sulfoxide.
abstract: Diastereoselective Ni(0)-catalyzed carbocyclization of enone to chiral vinylic sulfoxide has been accomplished, wherein two stereogenic centers were constructed simultaneously to give cis- and trans-disubstituted cyclopentanes from (E)- and (Z)-vinylic sulfoxides, respectively.
authors.affiliation: Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamadaoka, Suita, Osaka 565-0871, Japan.
authors.forename: Naoyoshi
authors.initials: N
authors.lastname: Maezaki
authors.forename: Hiroaki
authors.initials: H
authors.lastname: Sawamoto
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Ishihara
authors.forename: Tetsuaki
authors.initials: T
authors.lastname: Tanaka
mesh_terms: D002384:Catalysis; D009682:Magnetic Resonance Spectroscopy; D009532:Nickel / Q000737:chemistry*; D013237:Stereoisomerism; D013454:Sulfoxides / Q000737:chemistry*
chemical_list: C519113:8-phenyl-1,6-octadienyl tolyl sulfide S-oxide; D013454:Sulfoxides; D009532:Nickel