Removal of reactive dyes from wastewater by adsorption on coir pith activated carbon.
The removal efficiency of activated carbon prepared from coir pith towards three highly used reactive dyes in textile industry was investigated. Batch experiments showed that the adsorption of dyes increased with an increase in contact time and carbon dose. Maximum de-colorisation of all the dyes was observed at acidic pH. Adsorption of dyes was found to follow the Freundlich model. Kinetic studies indicated that the adsorption followed first order and the values of the Lagergren rate constants of the dyes were in the range of 1.77 x 10(-2)-2.69 x 10(-2)min(-1). The column experiments using granular form of the carbon (obtained by agglomeration with polyvinyl acetate) showed that adsorption efficiency increased with an increase in bed depth and decrease of flow rate. The bed depth service time (BDST) analysis carried out for the dyes indicated a linear relationship between bed depth and service time. The exhausted carbon could be completely regenerated and put to repeated use by elution with 1.0M NaOH. The coir pith activated carbon was not only effective in removal of colour but also significantly reduced COD levels of the textile wastewater.
Santhy
K
K
Center for Environmental Studies, Anna University, Chennai 600 025, India.
Selvapathy
P
P
D000327:Adsorption; D000838:Anions / Q000737:chemistry; D002482:Cellulose / Q000737:chemistry*; D002606:Charcoal / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry* / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008031:Lignin / Q000031:analogs & derivatives* / Q000737:chemistry; D009282:Naphthalenesulfonates / Q000737:chemistry; D013783:Textile Industry; D013997:Time Factors; D014227:Triazines / Q000737:chemistry; D014865:Waste Disposal, Fluid / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000737:chemistry* / Q000302:isolation & purification*
D000838:Anions; D004396:Coloring Agents; D009282:Naphthalenesulfonates; D014227:Triazines; D014874:Water Pollutants, Chemical; C507903:coir; C098610:reactive red 2; C036598:procion blue MX-R; D002606:Charcoal; D002482:Cellulose; D008031:Lignin