A yellow transient forms in the decomposition in acidic solution of the blue-violet nickel(II) complex of a trifurcated hexamine.
In the decomposition in acidic solution of the octahedral high-spin nickel(II) complex with the hexamine sen, a thermodynamically unstable, kinetically controlled, square-planar low-spin species forms, with a lifetime of 5 s.
Cacchione
Giovanni
G
Dipartimento di Chimica Generale, Università di Pavia, 27100 Pavia, Italy.
Fabbrizzi
Luigi
L
Foti
Francesco
F
Taglietti
Angelo
A