Isotopic signature and impact of car catalysts on the anthropogenic osmium budget.
Higher osmium concentrations and lower 187Os/188Os ratios in sediments from urban areas have been linked to anthropogenic osmium sources. Automobile catalytic converters that use platinum group metals (PGM) are a potential source for this Os pollution. We present the first direct Os concentrations and isotopic measurements of catalytic converters for major automobile brands to test the assumption that car catalysts release Os with a distinct signature in the environment. The analysis of four new catalytic converters yields similar low 187Os/188Os ratios (0.1-0.2), suggesting a similar source for the PGM. The Os concentrations measured are in the ppt range (6-228 ppt). From our results, the osmium contribution of the car catalysts to the environment through attrition (wearing and grinding down of the catalyst by friction) is predicted to be low, <0.2 pg Os/m2/year in highly urbanized environment. We show that Os loss from catalysts as volatile OsO4 is important at car catalyst operating temperatures. Moreover, we estimate that car catalysts may be responsible for up to approximately 120 pg Os/m2 deposited per year in urban areas and that part of it may be exported to sedimentary sinks. Car catalytic converters are thus an important anthropogenic osmium source in densely populated areas. The NIST car catalyst standard (SRM-2557, made from recycled used catalysts) yields higher concentrations (up to 721 ppt Os) and a more radiogenic isotopic composition (approximately 0.38), perhaps indicative of Os contamination during its preparation.
Poirier
André
A
GEOTOP-UQAM-McGILL, Geochemistry and Geodynamics Research Centre, CP 8888, Succ. Centreville, Montréal, Quebec, Canada, H3C 3P8. andre@olympus.geotop.uqam.ca
Gariépy
Clement
C
D001336:Automobiles; D002384:Catalysis; D013058:Mass Spectrometry; D009992:Osmium / Q000032:analysis*; D013696:Temperature; D001335:Vehicle Emissions / Q000032:analysis*
D001335:Vehicle Emissions; D009992:Osmium