Novel catalytic effects in ester aminolysis in chlorobenzene.
The mechanism of glyme catalyzed ester aminolysis in chlorobenzene should be modified by including a new reaction pathway that shows a first-order dependence on the concentration of the phase transfer catalyst and a second-order dependence on butylamine.
Basilio
Nuno
N
Dpto. Química Física, Facultade de Química, Universidade de Santiago de Compostela, Avda. das Ciencias s/n, 15782 Santiago de Compostela, Spain.
García-Río
Luís
L
Leis
J Ramón
JR
Mejuto
Juan C
JC
Pérez-Lorenzo
Moisés
M