Structure and reactivity of a new anionic N-heterocyclic carbene silver(I) complex.
The efficient synthesis of aN-benzoyliminoimidazolium ylide provides access to a new type of N-hetereocyclic anionic carbene, from which air stable Ag(I) and Cu(II) complexes and a catalytically active Rh(I) complex were formed.
Legault
Claude Y
CY
Département de Chimie, Université de Montréal, P.O. Box 6128, Station Downtown, Montréal, QC, Canada H3C 3J7.
Kendall
Christopher
C
Charette
André B
AB
D000838:Anions / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D006838:Hydrocarbons / Q000737:chemistry; D007097:Imines / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D018030:Silver Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013696:Temperature
D000838:Anions; D006571:Heterocyclic Compounds; D006838:Hydrocarbons; D007097:Imines; D018030:Silver Compounds; C030011:carbene; D008697:Methane