Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference.
Lavallo
Vincent
V
UCR-CNRS Joint Research Chemistry Laboratory (UMR 2282), Department of Chemistry, University of California, Riverside, CA 92521-0403, USA.
Canac
Yves
Y
Präsang
Carsten
C
Donnadieu
Bruno
B
Bertrand
Guy
G
D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D018360:Crystallography, X-Ray; D004583:Electrons; D006838:Hydrocarbons / Q000138:chemical synthesis / Q000737:chemistry; D006844:Hydrocarbons, Cyclic / Q000138:chemical synthesis* / Q000737:chemistry; D008670:Metals / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure
D000588:Amines; D006838:Hydrocarbons; D006844:Hydrocarbons, Cyclic; D008670:Metals; C030011:carbene; D008697:Methane