Bis(triazacyclohexane) sandwich complexes of (Cu(I))(2), Cu(II) and Zn(II): complexes with cuprophilic attraction between two cationic copper(I) leading to unusual reactivity with dioxygen.
As the first 1st-row transition metal complexes having six tertiary amine donor groups, bis(triazacyclohexane) sandwich complexes [L2M](BF4)2 (L = benzyl- or p-fluorobenzyl-triazacyclohexane, M = Cu or Zn) have been obtained by the protonolysis of Et2Zn in the presence of L or by reaction of [Cu(MeCN)4](BF4) with L in CH2Cl2 and subsequent air oxidation via an unprecedented Cu(I)(2) sandwich complex containing a short Cu-Cu contact.
Köhn
Randolf D
RD
Department of Chemistry, University of Bath, Bath, UK BA2 7AY. r.d.kohn@bath.ac.uk
Pan
Zhida
Z
Haufe
Matthias
M
Kociok-Köhn
Gabriele
G
D002412:Cations / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D013237:Stereoisomerism; D015032:Zinc / Q000737:chemistry*
D002412:Cations; D008024:Ligands; D009942:Organometallic Compounds; D003300:Copper; D015032:Zinc; D010100:Oxygen