title: Stable cyclic (alkyl)(amino)carbenes as rigid or flexible, bulky, electron-rich ligands for transition-metal catalysts: a quaternary carbon atom makes the difference.
authors.affiliation: UCR-CNRS Joint Research Chemistry Laboratory (UMR 2282), Department of Chemistry, University of California, Riverside, CA 92521-0403, USA.
authors.forename: Vincent
authors.initials: V
authors.lastname: Lavallo
authors.forename: Yves
authors.initials: Y
authors.lastname: Canac
authors.forename: Carsten
authors.initials: C
authors.lastname: Präsang
authors.forename: Bruno
authors.initials: B
authors.lastname: Donnadieu
authors.forename: Guy
authors.initials: G
authors.lastname: Bertrand
mesh_terms: D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D018360:Crystallography, X-Ray; D004583:Electrons; D006838:Hydrocarbons / Q000138:chemical synthesis / Q000737:chemistry; D006844:Hydrocarbons, Cyclic / Q000138:chemical synthesis* / Q000737:chemistry; D008670:Metals / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure
chemical_list: D000588:Amines; D006838:Hydrocarbons; D006844:Hydrocarbons, Cyclic; D008670:Metals; C030011:carbene; D008697:Methane