Supercritical fluid attachment of palladium nanoparticles on aligned carbon nanotubes.
Nanocomposite materials consisting of Pd nanoparticles deposited on aligned multi-walled carbon nanotubes have been fabricated through hydrogen reduction of palladium-beta-diketone precursor in supercritical carbon dioxide. The supercritical fluid processing allowed deposition of high-density Pd nanoparticles (approximately 5-10 nm) on both as-grown (unfunctionalized) and functionalized (using HNO3 oxidation) nanotubes. However, the wet processing for functionalization results in pre-agglomerated, bundle-shaped nanotubes, thus significantly reducing the effective surface area for Pd particle deposition, although the bundling provides more secure, lock-in-place positioning of nanotubes and Pd catalyst particles. The nanotube bundling is substantially mitigated by Pd nanoparticle deposition on the unfunctionalized and geometrically separated nanotubes, which provides much higher catalyst surface area. Such nanocomposite materials utilizing geometrically secured and aligned nanotubes can be useful for providing much enhanced catalytic activities to chemical and electrochemical reactions (e.g., fuel cell reactions), and eliminate the need for tedious catalyst recovery process after the reaction is completed.
Ye
Xiang-Rong
XR
Pacific Northwest National Laboratory, Richland, WA 99352, USA. 2
Lin
Yuehe
Y
Wai
Chien M
CM
Talbot
Jan B
JB
Jin
Sungho
S
D000327:Adsorption; D025924:Chromatography, Supercritical Fluid / Q000379:methods*; D003460:Crystallization / Q000379:methods*; D004566:Electrodes; D008422:Materials Testing; D008968:Molecular Conformation; D037742:Nanotubes, Carbon / Q000032:analysis / Q000737:chemistry* / Q000648:ultrastructure*; D010165:Palladium / Q000032:analysis / Q000737:chemistry*; D010316:Particle Size
D037742:Nanotubes, Carbon; D010165:Palladium