Approach toward nanoplate poly(styrene sulfate): synthesis of nano-polymers with special morphology by using Ldhs as template.
A simple chemical method to obtain nanopolymers with special morphology is reported. The key to the success of this preparation was the use of layered double hydroxides (LDHs), a two-dimensional host material, as template. Typical procedures include in-situ polymerization of the monomers in the interlayers of the LDH template, followed by the dissolution of LDH sheets so that the formed polymers can be free and collected. The obtained results demonstrate potential of LDHs as tools for the controlled synthesis of nanopolymers with platelike morphology.
Wang
Ge
G
School of Material Science and Engineering, University of Science and Technology Beijing, Beijing 100083, P.R. China.
Si
Lichun
L
Yang
Huai
H
Cai
Fuli
F
Wang
Zhiqiang
Z
Duan
Xue
X
D003460:Crystallization / Q000379:methods*; D006878:Hydroxides / Q000032:analysis / Q000737:chemistry; D046911:Macromolecular Substances / Q000032:analysis / Q000737:chemistry; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000032:analysis / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D011108:Polymers / Q000032:analysis / Q000737:chemistry; D011137:Polystyrenes / Q000032:analysis / Q000737:chemistry*
D006878:Hydroxides; D046911:Macromolecular Substances; D011108:Polymers; D011137:Polystyrenes; C071389:polystyrene sulfate