Decolorization and degradation of dyes with mediated fenton reaction.
A mediated Fenton system has been evaluated for decolorization of several types of dyes. The result shows that the Fenton system with a dihydroxybenzoic acid (DHBA) chelator-mediator effectively reduced the color of a diluted solution of Carta Yellow RW liquid, Carta Yellow G liquid, and Cartasol Red 2GF liquid dye to a colorless level after 90 minutes of treatment with 100 microM iron II (Fe[II]), 100 microM DHBA, and 10 mM hydrogen peroxide (H2O2) at room temperature. Our results show that compared to a neat Fenton process, the mediated Fenton decolorization process increased the production, and therefore the effective longevity, of hydroxyl radical (OH) species to increase the decolorization efficiency. Our results suggest that application of this system would also result in an increase in dissolved oxygen (DO) in solution, which in turn would result in reduction of chemical oxygen demand (COD), biochemical oxygen demand (BOD), and total organic carbon (TOC).
Goodell
Barry
B
Wood Science and Technology, University of Maine, Oronto, Maine 04469, USA. goodell@umit.maine.edu
Qian
Yuhui
Y
Jellison
Jody
J
Richard
Mike
M
D002396:Catechols / Q000737:chemistry; D003116:Color; D004396:Coloring Agents / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D062385:Hydroxybenzoates; D017665:Hydroxyl Radical / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D010100:Oxygen / Q000032:analysis; D013053:Spectrophotometry; D014865:Waste Disposal, Fluid / Q000379:methods*
D002396:Catechols; D004396:Coloring Agents; C045076:Fenton's reagent; D062385:Hydroxybenzoates; D017665:Hydroxyl Radical; C009135:2,3-dihydroxybenzoic acid; D006861:Hydrogen Peroxide; D007501:Iron; D010100:Oxygen