Interpenetrated networks from a novel nanometer-sized pseudopeptidic ligand, bridging water, and transition metal ions with cds topology.
The combination of a new pseudopeptidic ligand, transition metal ions, and bridging water molecules results in the formation of [M(mu-TBG)(mu-H2O)(H2O)2].2H2O (M: Cu, Co and H2TBG: terephthaloylbisglycine); both compounds show rare two-fold interpenetrated three-dimensional cds-nets and reversible loss of coordinated and lattice water molecules.
Kostakis
George E
GE
Dipartimento di Chimica Generale, Universitá di Pavia, Via Taramelli 12, 27100 Pavia, Italy.
Casella
Luigi
L
Hadjiliadis
Nick
N
Monzani
Enrico
E
Kourkoumelis
Nikolaos
N
Plakatouras
John C
JC