Highly enantioselective Cu-catalyzed conjugate additions of dialkylzinc reagents to unsaturated furanones and pyranones: preparation of air-stable and catalytically active Cu-peptide complexes.
Brown
M Kevin
MK
Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, MA 02467, USA.
Degrado
Sylvia J
SJ
Hoveyda
Amir H
AH
D000478:Alkylation; D002384:Catalysis; D003300:Copper / Q000737:chemistry* / Q000378:metabolism; D005663:Furans / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010455:Peptides / Q000138:chemical synthesis / Q000737:chemistry* / Q000378:metabolism; D011714:Pyrans / Q000737:chemistry*; D013237:Stereoisomerism; D015032:Zinc / Q000737:chemistry*
D005663:Furans; D009942:Organometallic Compounds; D010455:Peptides; D011714:Pyrans; D003300:Copper; D015032:Zinc