title: Carbon-carbon and carbon-heteroatom bond formation on solid phase using cationic iron carbonyl complexes.
abstract: Iron-mediated methodology for the formation of carbon-carbon and carbon-heteroatom sp(3) bonds on solid phase has been developed. Treatment of a polymer-bound cationic iron cyclohexadienyl complex with carbon, oxygen, nitrogen, and phosphorus nucleophiles, followed by cleavage with amines and subsequent decomplexation, yielded 18 different cyclohexadienoic acid amides of high purity. [reaction: see text]
authors.affiliation: Organic Chemistry, Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-41296 Göteborg, Sweden.
authors.forename: Henrik
authors.initials: H
authors.lastname: Gradén
authors.forename: Thomas
authors.initials: T
authors.lastname: Olsson
authors.forename: Nina
authors.initials: N
authors.lastname: Kann