title: Catalytic C-C bond cleavage and C-Si bond formation in the reaction of RCN with Et3SiH promoted by an iron complex.
abstract: Catalytic C-C bond cleavage of acetonitrile and C-Si bond formation have been attained in the photoreaction of MeCN with Et3SiH in the presence of an iron complex, Cp(CO)2FeMe. This catalytic system can be applied for arylnitrile C-C bond cleavage.
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka City University, Sumiyoshi-ku, Osaka 558-8585, Japan. nakazawa@sci.osaka-cu.ac.jp
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Nakazawa
authors.forename: Kouji
authors.initials: K
authors.lastname: Kamata
authors.forename: Masumi
authors.initials: M
authors.lastname: Itazaki