title: Irradiation of imine-group VI carbene complexes in the presence of alkynes. 2. Control of product distribution.
abstract: The photoreactivity of iminecarbene complexes in the presence of alkynes has been explored. Up to four different reaction paths are available depending on the alkyne and carbene complex substituents, although in each case only one type of product is isolated. 2H-Pyrrole derivatives are formed mainly from aryl alkynes. When alkyl alkynes are used, the method affords a new type of aza-dendralene product in good yields. Isoquinoline derivatives can also be formed in a two-step one-pot photochemical process when the appropriate substituents are present. Finally, indene derivatives are also available through a benzannulation reaction. To explore the underlying mechanism, we carried out computations using DFT methods. Experimental and theoretical results compare well, which allows control over the reaction and product distribution.
authors.affiliation: Departamento de Química, Universidad de La Rioja, Grupo de Síntesis Química de La Rioja, Unidad Asociada al C.S.I.C., Madre de Dios 51, E-26006 Logroño, Spain. diego.sampedro@dq.unirioja.es
authors.forename: Diego
authors.initials: D
authors.lastname: Sampedro
authors.forename: Míriam
authors.initials: M
authors.lastname: Caro
authors.forename: Miguel A
authors.initials: MA
authors.lastname: Rodríguez
authors.forename: Pedro J
authors.initials: PJ
authors.lastname: Campos