[Raman spectroscopy studies on the aqueous solutions of sodium formate and lithium formate].
The structures of the aqueous solutions of sodium formate and lithium formate are studied according to the growth conditions of the crystals under different supersaturations and temperatures by Raman spectroscopy. The effects of temperature, concentration, supersaturation and cation on the structures of solutions and the structure difference between lithium formate solution and lithium formate monohydrate crystal are analyzed. The result shows that the concentration, temperature and supersaturation effect the structures of the solutions slightly and the cation effects the frequency of the bands greatly.
Su
Jing
J
Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China.
Yu
Xi-ling
XL
You
Jing-lin
JL
Yin
Shao-tang
ST
D003460:Crystallization; D005561:Formates / Q000737:chemistry*; D018020:Lithium Compounds / Q000737:chemistry*; D015394:Molecular Structure; D017670:Sodium Compounds / Q000737:chemistry*; D012996:Solutions; D013059:Spectrum Analysis, Raman / Q000379:methods*; D013696:Temperature; D013816:Thermodynamics; D014867:Water / Q000737:chemistry
D005561:Formates; D018020:Lithium Compounds; D017670:Sodium Compounds; D012996:Solutions; D014867:Water; C030544:formic acid