Thioglycosides in sequential glycosylation strategies.
This tutorial review surveys the use of thioglycosides in the development of sequential glycosylation methodologies, with a focus on chemoselective, orthogonal and iterative glycosylation strategies reported since the beginning of this century. Both fundamental aspects of glycosidic bond formation and ingenious state-of-the-art methodologies are presented.
Codée
Jeroen D C
JD
Leiden Institute of Chemistry, Leiden University, P. O. Box 9502, 2300 RA Leiden, The Netherlands.
Litjens
Remy E J N
RE
van den Bos
Leendert J
LJ
Overkleeft
Herman S
HS
van der Marel
Gijsbert A
GA
D000596:Amino Acids / Q000737:chemistry; D002240:Carbohydrate Sequence; D002625:Chemistry, Organic / Q000379:methods*; D006031:Glycosylation; D006493:Heparin / Q000138:chemical synthesis; D008969:Molecular Sequence Data; D009844:Oligosaccharides / Q000138:chemical synthesis*; D013237:Stereoisomerism; D013865:Thioglycosides / Q000737:chemistry*
D000596:Amino Acids; D009844:Oligosaccharides; D013865:Thioglycosides; D006493:Heparin