Structural elucidation of sumanene and generation of its benzylic anions.
The structure of sumanene in a solid state was elucidated. The silyl-substituted sumanene was stereoselectively synthesized through generation of the benzylic anions of sumanene.
Sakurai
Hidehiro
H
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan. hsakurai@ims.ac.jp
Daiko
Taro
T
Sakane
Hiroyuki
H
Amaya
Toru
T
Hirao
Toshikazu
T
D000838:Anions / Q000737:chemistry; D001593:Benzyl Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D011084:Polycyclic Aromatic Hydrocarbons / Q000138:chemical synthesis / Q000737:chemistry; D013237:Stereoisomerism
D000838:Anions; D001593:Benzyl Compounds; D011084:Polycyclic Aromatic Hydrocarbons; C505028:sumanene