Comparative structural analysis of 5,6,7,9-tetra-O-acetyl-4,8-anhydro-1,3-dideoxy-D-glycero-L-gluco-nonulose and its 1-O-acetylated analog, 1,2,3,4,6-penta-O-acetyl-beta-D-galactopyranose using X-ray crystallography.
Comparative X-ray diffraction analysis of 5,6,7,9-tetra-O-acetyl-4,8-anhydro-1,3-dideoxy-D-glycero-L-gluco-nonulose (1) and a structurally related analog, 1,2,3,4,6-penta-O-acetyl-beta-D-galactopyranose (2), are reported. Both crystals have one molecule in the unit cell and the pyranose rings in both exist in the 4C1 conformation.
Kumar
Rishi
R
Medicinal and Process Chemistry Division and Molecular and Structural Biology Division, Central Drug Research Institute, Chattar Manzil Palace, Lucknow 226001, UP, India.
Tiwari
Pallavi
P
Maulik
Prakas R
PR
Misra
Anup Kumar
AK
D003460:Crystallization; D018360:Crystallography, X-Ray / Q000379:methods; D005697:Galactosides / Q000737:chemistry*; D006358:Hot Temperature; D009005:Monosaccharides / Q000737:chemistry*
D005697:Galactosides; D009005:Monosaccharides; C020450:1,2,3,4,6-penta-O-acetylgalactopyranose