Synthesis and coordination chemistry of a photoswitchable bis(phosphine) ligand.
A 1,2-dithienylethene compound bearing bis(phosphine) groups (1o) represents a new class of photoresponsive ligands where there are steric and electronic differences between two photogenerated isomers. The coordination chemistry of this ligand class is demonstrated by preparing a gold(I) complex (2o) and a phosphine selenide (3o).
Sud
David
D
Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, British Columbia, Canada V5A 1S6.
McDonald
Robert
R
Branda
Neil R
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