Glycosylation of acid sensitive acceptors. Synthesis of (2,3-epoxy-1-propyl) glycosides.
Treatment of O-benzylated derivatives of glycosyl N-allyl thiocarbamate with racemic or enantiomerically pure glycidol and bromine provides the 1,2-cis-glycidyl glycosides. This protocol was mild, highly stereoselective and efficient.
Kasprzycka
Anna
A
Silesian Technical University, Department of Chemistry, Krzywoustego 4, 44-100 Gliwice, Poland. akasprzycka@interia.pl
Szeja
Wiesław
W
Grynkiewicz
Grzegorz
G
D004852:Epoxy Compounds / Q000138:chemical synthesis*; D005989:Glycerides / Q000138:chemical synthesis*; D006031:Glycosylation
D004852:Epoxy Compounds; D005989:Glycerides; C020344:glycidyl ethers