Spectral studies of SnO2 nanofibres prepared by electrospinning method.
Tin oxide nanofibres with 100-150 nm diameter has been prepared, for the first time by calcination of poly(vinyl acetate) (PVAc)/SnO2 composite fibres prepared by electrospinning method as precursor. Scanning electron microscopic images revealed cylindrical morphology of the fibres after calcination at 600 degrees C. Both, X-ray diffraction (XRD) and Raman spectral data confirmed the presence of phase pure tetragonal rutile tin oxide after calcination process. Room temperature photoluminescence (PL) spectra of tin oxide nanofibres under excitation at 325 nm wavelength show a strong green emission at 525 nm with a band gap of 2.41 eV. FT-IR spectra confirmed the formation of pure tin oxide after calcination at 600 degrees C and complete removal of PVAc during calcination. UV-vis spectrum of the fibres showed absorption at 315 nm due to the direct electron transfer in tin oxide.
Dharmaraj
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Department of Chemistry, Government Arts College, Udumalpet 642 126, India. dharmaraj67@yahoo.com
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D003460:Crystallization; D004560:Electricity; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods*; D013057:Spectrum Analysis; D017971:Tin Compounds / Q000737:chemistry*; D014961:X-Ray Diffraction
D017971:Tin Compounds; C045358:stannic oxide