Single C59N molecule as a molecular rectifier.
We report a new kind of experimental realization of a molecular rectifier, which is based on a single azafullerene C59N molecule in a double-barrier tunnel junction via the single electron tunneling effect. An obvious rectifying effect is observed. The positive onset voltage is about 0.5-0.7 V, while the negative onset voltage is about 1.6-1.8 V. Theoretical analyses show that the half-occupied molecular orbital of the C59N molecule and the asymmetric shift of the molecular Fermi level when the molecule is charged are responsible for the molecular rectification.
Zhao
Jin
J
Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei, Anhui.
Zeng
Changgan
C
Cheng
Xin
X
Wang
Kedong
K
Wang
Guanwu
G
Yang
Jinlong
J
Hou
J G
JG
Zhu
Qingshi
Q