title: Size tunable synthesis of cysteine-capped CdS nanoparticles by gamma-irradiation.
abstract: Highly water soluble and biocompatible L-cysteine-capped CdS nanoparticles having narrow size distribution were synthesized for the first time by gamma-irradiation technique without using any additional stabilizer. FTIR study shows that CdS nanoparticles are capped through mercapto-group of cysteine amino acid while its free amino and carboxylate groups make it amenable to bio-conjugation. Size and luminescence of the nanoparticles can be well controlled by varying the parameters like radiation dose, pH and concentration of cysteine. The observed results suggest that pH 7 can be optimum for the synthesis of L-cysteine-capped CdS nanoparticles. CdS nanoparticles synthesized with molar ratio of Cd(2+):cysteine, 1:60 at pH 7 were found to be most luminescent. All nanoparticles formed lie in the size quantization regime and exhibit good crystallinity. Remarkable improvement in stability and luminescence was achieved on changing pH of as-prepared nanoparticles from 7 to 11.
authors.affiliation: UGC-DAE Consortium for Scientific Research, Kolkata Centre, III/LB-8, Bidhannagar, Kolkata 700098, India.
authors.forename: Anindita
authors.initials: A
authors.lastname: Chatterjee
authors.forename: Amiya
authors.initials: A
authors.lastname: Priyam
authors.forename: Satyen K
authors.initials: SK
authors.lastname: Das
authors.forename: Abhijit
authors.initials: A
authors.lastname: Saha