A highly active, isospecific cobalt catalyst for propylene oxide polymerization.
A highly active cobalt complex ((salph)CoOAc; salph = N,N'-bis(3,5-di-tert-butylsalicylidine-1,2-benzenediamine)) was discovered for the isospecific polymerization of rac-propylene oxide.
Peretti
Kathryn L
KL
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.
Ajiro
Hiroharu
H
Cohen
Claire T
CT
Lobkovsky
Emil B
EB
Coates
Geoffrey W
GW
D002247:Carbon Isotopes; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004852:Epoxy Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*
D002247:Carbon Isotopes; D004852:Epoxy Compounds; D009942:Organometallic Compounds; D003035:Cobalt; C009068:propylene oxide