Ru(IV)-catalyzed isomerization of allylamines in water: a highly efficient procedure for the deprotection of N-allylic amines.
A general and efficient method for the deprotection of N-allylic substrates in aqueous media, using catalytic amounts of the bis(allyl)-ruthenium(IV) complexes [Ru(eta3:eta2:eta3-C12H18)Cl2] and [{Ru(eta3:eta3-C10H16)(micro-Cl)Cl}2], has been developed.
Cadierno
Victorio
V
Departamento de Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica Enrique Moles (Unidad Asociada al C.S.I.C.), Universidad de Oviedo, 33071, Oviedo, Spain. vcm@uniovi.es
García-Garrido
Sergio E
SE
Gimeno
José
J
Nebra
Noel
N