Novel self-assembled chain of water molecules in a metal-organic framework structure of Co(II) with tartrate acid.
1-D water chains constructed by dimer water clusters and edge-sharing cyclic pentamer have been observed in the compound [Co(C4H4O6)(2,2'-bipy) x 5H2O] (1), in which the water chains join the 1-D coordination polymeric chains to a 3-D network through hydrogen-bond interactions.
Lu
Jing
J
College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin, 130023, China.
Yu
Jie-Hui
JH
Chen
Xiao-Yan
XY
Cheng
Peng
P
Zhang
Xiao
X
Xu
Ji-Qing
JQ
D003035:Cobalt / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D013644:Tartrates / Q000737:chemistry*; D014867:Water / Q000737:chemistry*
D013644:Tartrates; D014867:Water; D003035:Cobalt; C029768:tartaric acid