Diastereoselective synthesis of fulleropyrrolidines from suitably functionalized chiral cyclobutanes.
The first diastereoselective synthesis of fulleropyrrolidines endowed with diastereomerically pure functionalized cyclobutanes is reported. The new C(60)-based cyclobutane derivatives 7a,b and 9 are suitably functionalized for further incorporation into peptide surrogates.
Illescas
Beatriz M
BM
Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, E-28040 Madrid, Spain.
Martín
Nazario
N
Poater
Jordi
J
Solà
Miquel
M
Aguado
Gemma P
GP
Ortuño
Rosa M
RM
D003503:Cyclobutanes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D011759:Pyrrolidines / Q000138:chemical synthesis*; D013237:Stereoisomerism
D003503:Cyclobutanes; D011759:Pyrrolidines