Relationship between phase transitions and topological changes in one-dimensional models.
We address the question of the quantitative relationship between thermodynamic phase transitions and topological changes in the potential energy manifold analyzing two classes of one dimensional models, the Burkhardt solid-on-solid model and the Peyrard-Bishop model for DNA thermal denaturation, both in the confining and nonconfining version. These models, apparently, do not fit [M. Kastner, Phys. Rev. Lett. 93, 150601 (2004)] in the general idea that the phase transition is signaled by a topological discontinuity. We show that in both models the phase transition energy v(c) is actually noncoincident with, and always higher than, the energy v(theta) at which a topological change appears. However, applying a procedure already successfully employed in other cases as the mean field phi4 model, i.e., introducing a map M:v-->v(s) from levels of the energy hypersurface V to the level of the stationary points "visited" at temperature T, we find that M (v(c))=v(theta). This result enhances the relevance of the underlying stationary points in determining the thermodynamics of a system, and extends the validity of the topological approach to the study of phase transition to the elusive one-dimensional systems considered here.
Angelani
L
L
Dipartimento di Fisica, Università di Roma La Sapienza, P.le A. Moro 2, 00185 Roma, Italy.
Ruocco
G
G
Zamponi
F
F
D001703:Biophysics / Q000379:methods*; D004247:DNA / Q000737:chemistry*; D015233:Models, Statistical; D009690:Nucleic Acid Conformation; D044367:Phase Transition; D013499:Surface Properties; D013696:Temperature; D013816:Thermodynamics
D004247:DNA