Solvolytic routes to new nonabismuth hydroxy- and alkoxy-oxo complexes: synthesis, characterization and solid-state structures of novel nonabismuth polyoxo cations Bi9(mu3-O)8(mu3-OR)6 5+ (R = H, Et).
Base hydrolysis of BiO(ClO4) yields ClO4- salts of the novel nonabismuth polyoxo cation Bi9(mu3-O)8(mu3-OH)6(5+); ethanolysis converts to the ethoxide Bi9(mu3-O)8(mu3-OEt)6(5+).
Thurston
John H
JH
Department of Chemistry, The University of Iowa, Iowa City, IA 52242, USA.
Swenson
Dale C
DC
Messerle
Louis
L
D001729:Bismuth / Q000737:chemistry*; D002412:Cations / Q000138:chemical synthesis / Q000737:chemistry; D018360:Crystallography, X-Ray; D004980:Ethane / Q000737:chemistry; D006878:Hydroxides / Q000737:chemistry; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*
D002412:Cations; D006878:Hydroxides; D009942:Organometallic Compounds; C031356:hydroxide ion; D004980:Ethane; D010100:Oxygen; D001729:Bismuth