title: Direct evaluation of the lifetime matrix by the hyperquantization algorithm: narrow resonances in the F + H2 reaction dynamics and their splitting for nonzero angular momentum.
abstract: We propose a new method for the direct and efficient evaluation of the Felix Smith's lifetime Q matrix for reactive scattering problems. Simultaneous propagation of the solution to a set of close-coupled equations together with its energy derivative allows one to avoid common problems pertinent to the finite-difference approach. The procedure is implemented on a reactive scattering code which employs the hyperquantization algorithm and the Johnson-Manolopoulos [J. Comput. Phys. 13, 455 (1973); J. Chem. Phys 85, 6425 (1986)] propagation to obtain the complete S matrix and scattering observables. As an application of the developed formalism, we focus on the total angular momentum dependence of narrow under-barrier resonances supported by van der Waals wells of the title reaction. Using our method, we fully characterize these metastable states obtaining their positions and lifetimes from Lorentzian fits to the largest eigenvalue of the lifetime matrix. Remarkable splittings of the resonances observed at J>0 are rationalized in terms of a hyperspherical model. In order to provide an insight on the decay mechanism, the Q-matrix eigenvectors are analyzed and the dominant channels populated during the decomposition of metastable states are determined. Possible relevance of the present results to reactive scattering experiments is discussed.
authors.affiliation: Dipartimento di Chimica, Università di Perugia, 06123 Perugia, Italy.
authors.forename: Vincenzo
authors.initials: V
authors.lastname: Aquilanti
authors.forename: Simonetta
authors.initials: S
authors.lastname: Cavalli
authors.forename: Dario
authors.initials: D
authors.lastname: De Fazio
authors.forename: Andrea
authors.initials: A
authors.lastname: Simoni
authors.forename: Timur V
authors.initials: TV
authors.lastname: Tscherbul