title: Diastereoselective synthesis of fulleropyrrolidines from suitably functionalized chiral cyclobutanes.
abstract: The first diastereoselective synthesis of fulleropyrrolidines endowed with diastereomerically pure functionalized cyclobutanes is reported. The new C(60)-based cyclobutane derivatives 7a,b and 9 are suitably functionalized for further incorporation into peptide surrogates.
authors.affiliation: Departamento de Química Orgánica, Facultad de Química, Universidad Complutense, E-28040 Madrid, Spain.
authors.forename: Beatriz M
authors.initials: BM
authors.lastname: Illescas
authors.forename: Nazario
authors.initials: N
authors.lastname: Martín
authors.forename: Jordi
authors.initials: J
authors.lastname: Poater
authors.forename: Miquel
authors.initials: M
authors.lastname: Solà
authors.forename: Gemma P
authors.initials: GP
authors.lastname: Aguado
authors.forename: Rosa M
authors.initials: RM
authors.lastname: Ortuño
mesh_terms: D003503:Cyclobutanes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D011759:Pyrrolidines / Q000138:chemical synthesis*; D013237:Stereoisomerism
chemical_list: D003503:Cyclobutanes; D011759:Pyrrolidines