[Study on the spectra of NTO and its rubidium salt in aqueous solution].
In this paper, the Raman and difference FTIR spectra of NTO crystal, NTO solutions at different pH and saturated aqueous solution of Rb(NTO) x H2O have been studied. The determined structure of crystal suggests that the metal ion with oxygen and nitrogen atoms of [chemical structure see text] C-N, [chemical structure see text] C-NO2, [chemical structure see text] C=O and H2O formed bonds. The highest characterization peaks of Raman and FTIR spectra show that [chemical structure see text] C-NO2, [chemical structure see text] C=O and [chemical structure see text] C-N of NTO- formed week coordination bonds. The vibration spectra of saturation solution basically accord with those of the crystal. The bonds of saturation solution of the coordination compound have not changed. Therefore, the different vibration spectra of the saturation water solution of Rb (NTO) x H2O can be explicated by the formation of the bonds in crystal. The coordination compound formation mechanism of metal ion with NTO in alkali aqueous solution is discussed.
Xia
Shu-Ping
SP
College of Chemistry and Material Science, Shaanxi Normal University, Xi'an 710063, China.
Hu
Man-Cheng
MC
Gao
Shi-Yang
SY
Jiang
Yu-Cheng
YC
D006863:Hydrogen-Ion Concentration; D008956:Models, Chemical; D015394:Molecular Structure; D009574:Nitro Compounds / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry; D012413:Rubidium / Q000737:chemistry*; D012996:Solutions; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman; D014230:Triazoles / Q000737:chemistry*; D014867:Water / Q000737:chemistry
D009574:Nitro Compounds; D009942:Organometallic Compounds; D012996:Solutions; D014230:Triazoles; D014867:Water; C108812:5-nitro-1,2,4-triazol-3-one; D012413:Rubidium