[Ozonolysis of methacrolein and methyl vinyl ketone in aqueous solutions].
The experimental simulation was employed to study the aqueous-phase ozonolysis reactions of methacrolein (MAC) and methyl vinyl ketone (MVK) in the atmosphere, at the 25.0 degrees C +/- 0.1 degree C temperature and 1.0 x 10(5) Pa pressure of air. In both MAC and MVK ozonolysis reactions in water, formaldehyde, methylglyoxal, hydrogen peroxides (H2O2) and hydroxymethyl hydroperoxides (HMHP) were found; and their yields (%) were determined: 49.9 +/- 2.9, 26.6 +/- 3.9, 4.6 +/- 0.4 and 10.0 +/- 0.8 respectively for MAC; 40.8+/- 2.2, 40.7 +/- 3.5, 6.8 +/- 0.5 and 10.4 +/- 0.8 respectively for MVK. Finally, the reaction mechanisms are deduced to explain the formation of products observed.
Zhu
Li-hua
LH
The State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Science, Peking University, Beijing 100871, China.
Chen
Zhong-ming
ZM
D000171:Acrolein / Q000031:analogs & derivatives* / Q000737:chemistry; D000393:Air Pollutants / Q000737:chemistry*; D002074:Butanones / Q000737:chemistry*; D008956:Models, Chemical; D010126:Ozone / Q000737:chemistry*; D014867:Water
D000393:Air Pollutants; D002074:Butanones; D014867:Water; D010126:Ozone; D000171:Acrolein; C039175:methacrylaldehyde; C057920:3-buten-2-one