A six-bowl carceplex that entraps seven guest molecules.
A six-bowl carceplex that entraps seven guest molecules, 5.(DMSO)7, was synthesized and characterized. The dynamics of the host shell was studied in solution in the absence and presence of water. A multiple-molecule template was found to drive the formation of 5.(DMSO)x.G(7-x) (G = DMA, DMF; x = 5-7). Higher selectivity was found for species containing greater numbers of DMSO molecules.
Makeiff
Darren A
DA
Department of Chemistry, 2036 Main Mall, University of British Columbia, Vancouver, British Columbia, Canada V6T 1Z1.
Sherman
John C
JC
D000081:Acetamides / Q000737:chemistry; D004121:Dimethyl Sulfoxide / Q000737:chemistry*; D004126:Dimethylformamide / Q000737:chemistry; D004988:Ethers, Cyclic / Q000138:chemical synthesis*; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D012118:Resorcinols / Q000138:chemical synthesis*; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; D014867:Water / Q000737:chemistry
D000081:Acetamides; D004988:Ethers, Cyclic; D047028:Macrocyclic Compounds; D012118:Resorcinols; C506097:carceplex; C442939:cavitand; D014867:Water; D004126:Dimethylformamide; C030686:acetamide; D004121:Dimethyl Sulfoxide