title: Gel-type polyacrylic resins cross-linked with trimethylolpropanetrimethacrylate: the issue of their nanostructure and molecular accessibility unveiled with a combination of inverse steric exclusion chromatography (ISEC), and ESR and CP-MAS 13C NMR spectroscopy.
abstract: Six gel-type functional resins, that is, three poly-DMAA-co-TMPTP (DMAA = N,N-dimethylacrylamide, TMPTP = trimethylolpropyltrimethacrylate) samples with different degrees of cross-linking (0.6, 1.2, 1.7 % mol) and three poly-DMAA-co-MA-co-TMPTP (MA = methacrylic acid, ca. 5.5 % mol) samples with 1.7, 3.5, and 7 % mol cross-linking were investigated with ISEC (inverse steric exclusion chromatography), and ESR and CP-MAS (cross polarization magic angle spinning) 13C NMR spectroscopy after swelling in water and other solvents. This unprecedented combination of conceptually independent physicochemical techniques provides a thorough overall consistent picture of the morphology of the resins on the nanometer scale and of the molecular accessibility of the swollen polymer framework to the paramagnetic probe TEMPONE (2,2,6,6-tetramethyl-4-oxo-1-oxypiperidine) and to selected solvents.
authors.affiliation: Dipartimento di Scienze Chimiche, Università di Padova, Via Marzolo 1, 35131 Padova, Italy.
authors.forename: Franco
authors.initials: F
authors.lastname: Pozzar
authors.forename: Alessandro
authors.initials: A
authors.lastname: Sassi
authors.forename: Giuseppe
authors.initials: G
authors.lastname: Pace
authors.forename: Silvano
authors.initials: S
authors.lastname: Lora
authors.forename: Angelo Antonio
authors.initials: AA
authors.lastname: D'Archivio
authors.forename: Karel
authors.initials: K
authors.lastname: Jeràbek
authors.forename: Alfonso
authors.initials: A
authors.lastname: Grassi
authors.forename: Benedetto
authors.initials: B
authors.lastname: Corain