title: [Photocatalytic removing of a mustard gas analogue 2-CEES vapor over SO4(2-)/TiO2].
abstract: Disinfection with photocatalysis, compared to with the conventional cleanout, is both high efficient and non contaminative, but the simple TiO2 photocatalyst is showing to be of low activity and low active stability so to be hardly practical application. In the paper, SO4(2-)/TiO2 were papered by surface modification of TiO2 with dilute H2SO4, and the photocatalytic degradation of 2-chloroethyl ethyl sulfide (2-CEES) on the samples was examined in a fixed-bed microreactor. The examination show that the acidic modification enhanced both the activity and the active stability of TiO2, and the sample ST200 prepared by calcination at 200 degrees C was better than ST400 by calcination at 400 degrees C. The effect of water vapor content and reaction temperature on the photocatalytic degradation of 2-CEES was also tested, showing that the sample ST200 had high activity and stability at 90 degrees C, and kept a constant activity when adding 30.5 mL/L water vapor into the reactive system in which 2-CEES initial concentration was low to < 61 microL x L(-1). In addition, it was found that supporting SO4(2-)/TiO2 on gamma-Al2O3, SiO2 and active carbon could improve on the activity and stability of SO4(2-)/TiO2, and on supports SiO2 is the best one.
authors.affiliation: The Academy of Chemical Defence, The People's Liberation Army, Beijing 102205, China.
authors.forename: Shi-tong
authors.initials: ST
authors.lastname: Han
authors.forename: Hai-ling
authors.initials: HL
authors.lastname: Xi
authors.forename: Xu-xu
authors.initials: XX
authors.lastname: Wang
authors.forename: Xian-zhi
authors.initials: XZ
authors.lastname: Fu
mesh_terms: D000393:Air Pollutants / Q000737:chemistry; D000397:Air Pollution / Q000517:prevention & control*; D002384:Catalysis; D002619:Chemical Warfare Agents / Q000737:chemistry*; D009151:Mustard Gas / Q000031:analogs & derivatives* / Q000737:chemistry; D010777:Photochemistry / Q000379:methods*; D013458:Sulfur Dioxide / Q000737:chemistry; D013464:Sulfuric Acids / Q000737:chemistry; D014025:Titanium / Q000737:chemistry
chemical_list: D000393:Air Pollutants; D002619:Chemical Warfare Agents; D013464:Sulfuric Acids; D013458:Sulfur Dioxide; C009495:titanium dioxide; C031278:2-chloroethyl ethyl sulfide; D014025:Titanium; D009151:Mustard Gas