Synthesis of an optically pure synthetic intermediate of aloperine from a yeast-reductive product.
Optically pure (S)- and (R)-vinylpiperidine 2 and (S)- and (R)-(hydroxyethyl)piperidine 3, which were key intermediates for the synthesis of aloperine, were synthesized from yeast-reductive products.
Yamauchi
Satoshi
S
Faculty of Agriculture, Ehime University, Japan. syamauch@agr.ehime-u.ac.jp
Omi
Yasushi
Y
D010084:Oxidation-Reduction; D010880:Piperidines / Q000138:chemical synthesis* / Q000737:chemistry; D054837:Quinolizidines; D012441:Saccharomyces cerevisiae / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013237:Stereoisomerism
D010880:Piperidines; D054837:Quinolizidines; C062701:aloperine