title: Single-wall carbon nanotube-based proton exchange membrane assembly for hydrogen fuel cells.
abstract: A membrane electrode assembly (MEA) for hydrogen fuel cells has been fabricated using single-walled carbon nanotubes (SWCNTs) support and platinum catalyst. Films of SWCNTs and commercial platinum (Pt) black were sequentially cast on a carbon fiber electrode (CFE) using a simple electrophoretic deposition procedure. Scanning electron microscopy and Raman spectroscopy showed that the nanotubes and the platinum retained their nanostructure morphology on the carbon fiber surface. Electrochemical impedance spectroscopy (EIS) revealed that the carbon nanotube-based electrodes exhibited an order of magnitude lower charge-transfer reaction resistance (R(ct)) for the hydrogen evolution reaction (HER) than did the commercial carbon black (CB)-based electrodes. The proton exchange membrane (PEM) assembly fabricated using the CFE/SWCNT/Pt electrodes was evaluated using a fuel cell testing unit operating with H(2) and O(2) as input fuels at 25 and 60 degrees C. The maximum power density obtained using CFE/SWCNT/Pt electrodes as both the anode and the cathode was approximately 20% better than that using the CFE/CB/Pt electrodes.
authors.affiliation: Radiation Laboratory and Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, USA.
authors.forename: G
authors.initials: G
authors.lastname: Girishkumar
authors.forename: Matthew
authors.initials: M
authors.lastname: Rettker
authors.forename: Robert
authors.initials: R
authors.lastname: Underhile
authors.forename: David
authors.initials: D
authors.lastname: Binz
authors.forename: K
authors.initials: K
authors.lastname: Vinodgopal
authors.forename: Paul
authors.initials: P
authors.lastname: McGinn
authors.forename: Prashant
authors.initials: P
authors.lastname: Kamat
mesh_terms: D004563:Electrochemistry; D004566:Electrodes; D006859:Hydrogen / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D037742:Nanotubes, Carbon / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry; D013059:Spectrum Analysis, Raman
chemical_list: D037742:Nanotubes, Carbon; D006859:Hydrogen; D010100:Oxygen