Influence of substitution at the benzylic position on the behavior of stereoisomeric phosphorus compounds as precursors of stabilized carbon-centered radicals.
Efficient benzylic radical formation from benzo[d]-1,2-oxaphospholes has demonstrated their suitability as precursors of stabilized C-centered radicals, a property associated with antioxidant potential. A remarkable stereodifferentiation is observed for alkyl- and aryl-substituted derivatives. [reaction: see text]
Pérez-Prieto
Julia
J
Departamento de Química Orgánica/ICMOL, Universidad de Valencia, Av. Vicent Andrés Estellés s/n, 46100 Burjassot, Valencia, Spain. julia.perez@uv.es
Galian
Raquel Eugenia
RE
Burgos
Pascual Oña
PO
Morant Miñana
Maria del Carmen
Mdel C
Miranda
Miguel Angel
MA
López-Ortiz
Fernando
F