Dynamic helicity inversion in an octahedral cobalt(II) complex system via solvato-diastereomerism.
The helical sense of a mononuclear Co(II) complex with an amino acid-based chiral tetradentate ligand was dynamically inverted by changing the solvent component.
Miyake
Hiroyuki
H
Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan. miyake@sci.osaka-cu.ac.jp
Sugimoto
Hideki
H
Tamiaki
Hitoshi
H
Tsukube
Hiroshi
H
D000596:Amino Acids / Q000737:chemistry; D002942:Circular Dichroism; D006863:Hydrogen-Ion Concentration; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry; D012997:Solvents; D013237:Stereoisomerism
D000596:Amino Acids; D008024:Ligands; D009942:Organometallic Compounds; D012997:Solvents; C518189:bis(acrylonitrile)(2,5,8,11-tetraaza-4,5,8,9-tetramethyldodecane)cobalt(II); C518190:nitrato(2,5,8,11-tetraaza-4,5,8,9-tetramethyldodecane)cobalt(II)