title: An allylstannane reagent on non-cross-linked polystyrene support.
abstract: [reaction: see text] A new allylstannane reagent on non-cross-linked polystyrene was developed for the first time. This support differs markedly from standard cross-linked polymers because it is completely soluble in organic solvents; moreover, the reactions can be conveniently monitored directly by standard 1H NMR methods. The allylstannane underwent a free radical reaction with an alkyl halide to form a new allyl appendage. Tin byproducts can be easily recovered from cold methanol as white crystalline solids.
authors.affiliation: Department of Chemistry, University of Florida, Gainesville, Florida 32611, USA. enholm@chem.ufl.edu
authors.forename: E J
authors.initials: EJ
authors.lastname: Enholm
authors.forename: M E
authors.initials: ME
authors.lastname: Gallagher
authors.forename: K M
authors.initials: KM
authors.lastname: Moran
authors.forename: J S
authors.initials: JS
authors.lastname: Lombardi
authors.forename: J P
authors.initials: JP
authors.lastname: Schulte