Silver(I) carbonyl and silver(I) ethylene complexes of a B-protected fluorinated tris(pyrazolyl)borate ligand.
B-methylated ligand [MeB(3-(C2F5)Pz)3]-enables the isolation of a lithium adduct [MeB(3-(C2F5)Pz)3]Li with fac-N3F3 coordination, and rare isolable silver carbon monoxide and silver ethylene complexes, [MeB(3-(C2F5)Pz)3]AgCO and [MeB(3-(C2F5)Pz)3]AgC2H4.
Dias
H V Rasika
HV
Department of Chemistry and Biochemistry, University of Texas at Arlington, Arlington, TX 76019, USA. dias@uta.edu
Wang
Xiaoyu
X
D001896:Boron Compounds / Q000737:chemistry*; D002248:Carbon Monoxide / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005030:Ethylenes / Q000737:chemistry*; D008024:Ligands; D008094:Lithium / Q000737:chemistry; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D011720:Pyrazoles / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*
D001896:Boron Compounds; D005030:Ethylenes; D008024:Ligands; D009942:Organometallic Compounds; D011720:Pyrazoles; D012834:Silver; D002248:Carbon Monoxide; D008094:Lithium