title: Full multinuclear resonance analysis of 4-amino-1,1,2,2,9,9,10,10-octafluoro[2.2]paracyclophane.
abstract: The complete assignment of 19F, 1H and 13C NMR spectra for a monosubstituted octafluoro[2.2]paracyclophane derivative is described for the first time. The unambiguous assignments were achieved through the combination of 19F--1H HOESY, 1H COSY and 19F COSY techniques and then further confirmed employing a complementary approach using a Karplus-dependent 3JCF interaction. Interesting aspects of the coupling patterns for various JHH, JHF, JCF and JFF interactions are also discussed.
authors.affiliation: Rutgers, The State University of New Jersey, Department of Chemistry, 315 Penn St, Camden, NJ 08102-1411, USA. alroche@crab.rutgers.edu
authors.forename: Alex J
authors.initials: AJ
authors.lastname: Roche
authors.forename: Alexander A
authors.initials: AA
authors.lastname: Marchione
authors.forename: Sheryl A
authors.initials: SA
authors.lastname: Rabinowitz