title: Influence of substitution at the benzylic position on the behavior of stereoisomeric phosphorus compounds as precursors of stabilized carbon-centered radicals.
abstract: Efficient benzylic radical formation from benzo[d]-1,2-oxaphospholes has demonstrated their suitability as precursors of stabilized C-centered radicals, a property associated with antioxidant potential. A remarkable stereodifferentiation is observed for alkyl- and aryl-substituted derivatives. [reaction: see text]
authors.affiliation: Departamento de Química Orgánica/ICMOL, Universidad de Valencia, Av. Vicent Andrés Estellés s/n, 46100 Burjassot, Valencia, Spain. julia.perez@uv.es
authors.forename: Julia
authors.initials: J
authors.lastname: Pérez-Prieto
authors.forename: Raquel Eugenia
authors.initials: RE
authors.lastname: Galian
authors.forename: Pascual Oña
authors.initials: PO
authors.lastname: Burgos
authors.forename: Maria del Carmen
authors.initials: Mdel C
authors.lastname: Morant Miñana
authors.forename: Miguel Angel
authors.initials: MA
authors.lastname: Miranda
authors.forename: Fernando
authors.initials: F
authors.lastname: López-Ortiz