title: Structural determination of metallofullerene Sc3C82 revisited: a surprising finding.
abstract: We report here the structural determination of the Sc3C82 molecule by 13C NMR spectroscopy and X-ray single-crystal structure analysis. From the present study, it is obvious that the structure of Sc3C82 is not Sc3@C82 but Sc3C2@C80.
authors.affiliation: Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan.
authors.forename: Yuko
authors.initials: Y
authors.lastname: Iiduka
authors.forename: Takatsugu
authors.initials: T
authors.lastname: Wakahara
authors.forename: Tsukasa
authors.initials: T
authors.lastname: Nakahodo
authors.forename: Takahiro
authors.initials: T
authors.lastname: Tsuchiya
authors.forename: Akihiro
authors.initials: A
authors.lastname: Sakuraba
authors.forename: Yutaka
authors.initials: Y
authors.lastname: Maeda
authors.forename: Takeshi
authors.initials: T
authors.lastname: Akasaka
authors.forename: Kenji
authors.initials: K
authors.lastname: Yoza
authors.forename: Ernst
authors.initials: E
authors.lastname: Horn
authors.forename: Tatsuhisa
authors.initials: T
authors.lastname: Kato
authors.forename: Michael T H
authors.initials: MT
authors.lastname: Liu
authors.forename: Naomi
authors.initials: N
authors.lastname: Mizorogi
authors.forename: Kaoru
authors.initials: K
authors.lastname: Kobayashi
authors.forename: Shigeru
authors.initials: S
authors.lastname: Nagase
mesh_terms: D002247:Carbon Isotopes; D018360:Crystallography, X-Ray; D037741:Fullerenes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry; D012538:Scandium / Q000737:chemistry*
chemical_list: D002247:Carbon Isotopes; D037741:Fullerenes; D009942:Organometallic Compounds; D012538:Scandium