Controlled generation of heterochiral or homochiral coordination polymer: helical conformational polymorphs and argentophilicity-induced spontaneous resolution.
In the pair of helical conformational polymorphs of the coordination polymer {[AgL](CF3SO3)}infinity(L=2-pyridinyl-3-pyridinylmethanone), the 2(1) helices of opposite chirality in one supramolecular isomer are stacked alternately to form a racemate, while the 4(1) helices in the other are assembled homochirally by inter-chain argentophilic interaction to generate a conglomerate.
Chen
Xu-Dong
XD
Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China.
Du
Miao
M
Mak
Thomas C W
TC