title: Degree of remaining C=C bonds, polymerization shrinkage and stresses of dual-cured core build-up resin composites.
abstract: This study measured the degree of remaining C=C bonds (RDB), linear polymerization shrinkage (LPS) and polymerization stresses (PS) of dual-cured resin composite build-up materials using a variety of light exposure scenarios. Four commercially available materials were used: Bis-Core, FluoroCore, Build-it! and Permalute. The RDB was measured using FTIR spectroscopy, and custom-made devices were used to measure LPS and PS values. Data were obtained using three different modes of photoactivation: NLC (No Light-Curing); ILC (Immediate Light-Curing, where 60 second light-curing was applied at the start of the observation period); and DLC (Delayed Light-Curing, where 60-second light-curing was applied 10 minutes from the start of the observation period). Statistical evaluation of the data at the end of the 13-minute observation period was performed with two-way analysis of variance (ANOVA), Tukey's Studentized Range (HSD) Test (p=0.05) and simple linear regression. Differences in the development of LPS and PS during the 13 minutes were studied using mathematical calculus. Bis-Core presented the highest RDB and Permalute the lowest when ILC was applied, while no differences were found between Build-it! and FluoroCore and NLC and DLC increased RDB for FluoroCore and Permalute compared to ILC; whereas, no differences were noted for Build-it! and Bis-Core. Using DLC, a decrease in RDB was found only for Build-it! FluoroCore and Permalute exhibited a reduction in LPS and PS using NLC relative to ILC. No differences in LPS and PS values were detected for the materials Bis-Core and Build-it! when subjected to NLC or DLC, compared to ILC. Simple linear regression showed that only the two polymerization shrinkage properties studied were highly correlated (LPS-PS r2=0.85). The RDB rate was not correlated with either polymerization shrinkage properties (RDB-LPS r2=0.40; RDB-PS r2=0.57). A study of the evolution of the real-time curves of percentage values of LPS and PS showed that these properties evolved in a similar exponential mode and that, most often, there was a delay in the development of PS.
authors.affiliation: Division of Cariology and Endodontology, School of Dentistry, University of Geneva, Geneva, Switzerland. mstaurid@dent.uoa.gr
authors.forename: Minos M
authors.initials: MM
authors.lastname: Stavridakis
authors.forename: Afrodite I
authors.initials: AI
authors.lastname: Kakaboura
authors.forename: Ivo
authors.initials: I
authors.lastname: Krejci
mesh_terms: D002244:Carbon / Q000737:chemistry* / Q000528:radiation effects; D003188:Composite Resins / Q000737:chemistry* / Q000528:radiation effects; D003764:Dental Materials / Q000737:chemistry* / Q000528:radiation effects; D005460:Fluorides, Topical / Q000737:chemistry; D006801:Humans; D008027:Light; D008422:Materials Testing; D011108:Polymers / Q000737:chemistry* / Q000528:radiation effects; D019279:Resin Cements / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013314:Stress, Mechanical; D013499:Surface Properties; D013997:Time Factors
chemical_list: C409386:Bisco Glaze; C483702:Build-it composite resin; D003188:Composite Resins; D003764:Dental Materials; D005460:Fluorides, Topical; C074316:FluoroCore; D011108:Polymers; D019279:Resin Cements; C458820:permalute; D002244:Carbon