Characterization of cross-linked hydroxycinnamic acid amides isolated from potato common scab lesions.
Four feruloyl amides, N-trans-feruloyloctopamine (1), N-cis-feruloyloctopamine (2), N-trans-feruloyltyramine (3), N-cis-feruloyltyramine (4), a cross-linked N-trans-feruloyltyramine dimer (5), and a cross-linked N-cis-feruloyltyramine dimer (6) were isolated from potato common scab lesions. The compounds were purified by TLC and characterized by a combination of (1)H and (13)C NMR spectroscopic techniques. The presence of an accompanying minor complex of cross-linked dimers containing both feruloyltyramines and feruloyloctopamines was also demonstrated. This is the first characterization of cross-linked hydroxycinnamic acid amides associated with wound healing in potato (Solanum tuberosum) tubers.
King
Russell R
RR
Agriculture and Agric-Food Canada, Potato Research Centre, Fredericton, NB, Canada. kingr@agr.gc.ca
Calhoun
Larry A
LA
D000577:Amides / Q000737:chemistry* / Q000302:isolation & purification; D002473:Cell Wall / Q000737:chemistry; D002855:Chromatography, Thin Layer; D003373:Coumaric Acids / Q000737:chemistry* / Q000302:isolation & purification; D003432:Cross-Linking Reagents / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D010935:Plant Diseases; D011198:Solanum tuberosum / Q000737:chemistry* / Q000166:cytology*; D014439:Tyramine / Q000031:analogs & derivatives / Q000737:chemistry
D000577:Amides; D003373:Coumaric Acids; D003432:Cross-Linking Reagents; C074004:feruloyltyramine; D014439:Tyramine