title: Neutron reflectometry and spectroscopic ellipsometry studies of cross-linked poly(dimethylsiloxane) after irradiation at 172 nm.
abstract: Poly(dimethylsiloxane) (PDMS) was irradiated under ambient conditions in air with a Xe2-excimer lamp. The formation of atomic oxygen and ozone during irradiation in air by V-UV photons results in the transformation of PDMS to silicon oxide. The irradiated surfaces were studied by spectroscopic ellipsometry and neutron reflectometry. The measurements revealed the formation of a rough, i.e., between 11 and 20 nm, oxidized surface layer and a decrease of the total layer thickness. The thickness of the oxidized layer decreased for a given PDMS thickness when the polymer was irradiated for longer times and/or higher intensities. The composition of the oxidized layer after irradiation was not uniform through the layer and consisted of a mixture of original polymer and silicon bonded to three or four oxygen atoms (SiOx). The refractive index n determined by ellipsometry reaches a value similar to values reported for SiO2.
authors.affiliation: General Energy Research Department, Paul-Scherrer-Institut, CH-5232 Villigen, Switzerland.
authors.forename: Vera-Maria
authors.initials: VM
authors.lastname: Graubner
authors.forename: Daniel
authors.initials: D
authors.lastname: Clemens
authors.forename: Thomas
authors.initials: T
authors.lastname: Gutberlet
authors.forename: Rüdiger
authors.initials: R
authors.lastname: Kötz
authors.forename: Thomas
authors.initials: T
authors.lastname: Lippert
authors.forename: Oskar
authors.initials: O
authors.lastname: Nuyken
authors.forename: Bernhard
authors.initials: B
authors.lastname: Schnyder
authors.forename: Alexander
authors.initials: A
authors.lastname: Wokaun