Deep cavitands provide organized solvation of reactions.
Deep self-folding cavitands have been shown to stabilize the charged enolate intermediate of the alpha-deuteration of activated olefins by means of a network of organized solvation.
Hooley
Richard J
RJ
The Skaggs Institute for Chemical Biology and Department of Chemistry, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, California 92037, USA.
Rebek
Julius
J
D000179:Acrylates / Q000737:chemistry*; D000473:Alkanes / Q000737:chemistry*; D001665:Binding Sites; D001643:Bridged Bicyclo Compounds / Q000737:chemistry; D003903:Deuterium / Q000737:chemistry; D004988:Ethers, Cyclic / Q000737:chemistry*; D006860:Hydrogen Bonding; D007097:Imines / Q000737:chemistry; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D012118:Resorcinols / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry*
D000179:Acrylates; D000473:Alkanes; D001643:Bridged Bicyclo Compounds; D004988:Ethers, Cyclic; D007097:Imines; D012118:Resorcinols; D012997:Solvents; C442939:cavitand; D003903:Deuterium; C017573:nonane; C035956:methyl acrylate