title: Diastereoselective addition of 2H-2-oxo-1,4,2-oxazaphosphinanes to aldehydes and imines.
abstract: [reaction: see text] Diastereoselective additions of 2-hydrogeno-2-oxo-1,4,2-oxazaphosphinanes to aldehydes and imines are described. alpha,alpha'-Diaminophosphinic and alpha-amino-alpha'-hydroxyphosphinic derivatives were obtained with de's ranging from 24 to 90%.
authors.affiliation: Laboratoire de Chimie Organique, UMR5076-ENSCM, 8 rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France. pirat@cit.enscm.fr
authors.forename: Jean-Luc
authors.initials: JL
authors.lastname: Pirat
authors.forename: Jérôme
authors.initials: J
authors.lastname: Monbrun
authors.forename: David
authors.initials: D
authors.lastname: Virieux
authors.forename: Jean-Noël
authors.initials: JN
authors.lastname: Volle
authors.forename: Monique
authors.initials: M
authors.lastname: Tillard
authors.forename: Henri-Jean
authors.initials: HJ
authors.lastname: Cristau
mesh_terms: D000447:Aldehydes / Q000138:chemical synthesis; D007097:Imines / Q000138:chemical synthesis; D008968:Molecular Conformation; D010721:Phosphinic Acids / Q000138:chemical synthesis*
chemical_list: D000447:Aldehydes; D007097:Imines; D010721:Phosphinic Acids