The application of phenylmethanethiol and benzenethiol derivatives as odorless organosulfur reagents in the synthesis of thiosugars and thioglycosides.
p-octyloxyphenylmethanethiol and p-dodecylbenzenethiol were prepared as new odorless organosulfur reagents. Thiosugars and thioglycosides were synthesized using these reagents without encountering any malodorous procedures.
Hasegawa
Jun-ya
JY
Department of Pharmaceutical Manufacturing Chemistry, 21st Century COE program, Kyoto Pharmaceutical University, Misasagi, Kyoto 607-8414, Japan.
Hamada
Masahiro
M
Miyamoto
Tetsuo
T
Nishide
Kiyoharu
K
Kajimoto
Tetsuya
T
Uenishi
Jun-ichi
J
Node
Manabu
M
D007202:Indicators and Reagents; D009812:Odorants; D010429:Pentoses / Q000138:chemical synthesis*; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013457:Sulfur Compounds / Q000138:chemical synthesis*; D013865:Thioglycosides / Q000138:chemical synthesis*
C506678:4-dodecylbenzenethiol; C506677:4-octyloxyphenylmethanethiol; D007202:Indicators and Reagents; D010429:Pentoses; D013438:Sulfhydryl Compounds; D013457:Sulfur Compounds; D013865:Thioglycosides