Porous metal-organic truncated octahedron constructed from paddle-wheel squares and terthiophene links.
A metal-organic truncated octahedron (termed MOP-28) has been constructed from six rigid square-shaped Cu2(CO2)4 paddle-wheel building units and twelve 2,2':5',2' '-terthiophene-5,5' '-dicarboxylate (TTDC) linkers. TTDC linker in the cis,cis conformation provides the critical 90 degrees linkage for this unique construction. The porous structure of MOP-28 is maintained even after the removal of guest species, as evidenced by this compound's nitrogen sorption isotherm of Type I characteristics and unprecedented surface area (Langmuir surface area 1100 m2/g, BET surface area 914 m2/g) among materials composed of discrete molecules.
Ni
Zheng
Z
Materials Design and Discovery Group, Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA.
Yassar
Abderrahim
A
Antoun
Tarek
T
Yaghi
Omar M
OM
D003300:Copper / Q000737:chemistry*; D003460:Crystallization; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D016062:Porosity; D013876:Thiophenes / Q000737:chemistry*
D009942:Organometallic Compounds; D013876:Thiophenes; C019101:alpha-terthienyl; D003300:Copper