title: Intermolecular C-N addition of amides and S-N addition of sulfinamides to arynes.
abstract: An efficient, mild, transition-metal-free method has been developed for the intermolecular C-N sigma-bond addition of amides and S-N sigma-bond addition of sulfinamides to arynes to form one C-C bond and one heteroatom-carbon bond in one step at room temperature. Evidence for a stepwise mechanism is provided.
authors.affiliation: Department of Chemistry, Iowa State University, Ames, Iowa 50011, USA.
authors.forename: Zhijian
authors.initials: Z
authors.lastname: Liu
authors.forename: Richard C
authors.initials: RC
authors.lastname: Larock
mesh_terms: D000577:Amides / Q000138:chemical synthesis / Q000737:chemistry*; D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure
chemical_list: D000577:Amides; D006841:Hydrocarbons, Aromatic