title: Theoretical and experimental study on formation and adsorption of enolic species on Ag-Pd/Al2O3 catalyst.
abstract: The formation and adsorption of enolic species on a palladium promoted Ag/Al2O3 catalyst (denoted Ag-Pd/Al2O3) during the selective catalytic reduction (SCR) of NOx by C3H6 has been studied by means of DRIFTS and density functional calculations. The structure of the enolic species adsorbed on Ag-Pd/Al2O3 catalyst has been established based on the in situ DRIFTS spectra and simulated results. The reaction mechanism from C3H6 to enolic species on Ag-Pd/Al2O3 catalyst was proposed and the hypothesis about the Pd promotion was discussed.
authors.affiliation: State Key Laboratory of Environmental Chemistry and Ecotoxicology, Chinese Academy of Sciences, Beijing 100085, China.
authors.forename: Hongwei
authors.initials: H
authors.lastname: Gao
authors.forename: Hong
authors.initials: H
authors.lastname: He
authors.forename: Qingcai
authors.initials: Q
authors.lastname: Feng
authors.forename: Jin
authors.initials: J
authors.lastname: Wang
mesh_terms: D000537:Aluminum Oxide / Q000737:chemistry*; D002384:Catalysis; D008956:Models, Chemical; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013696:Temperature; D014732:Vibration
chemical_list: D012834:Silver; D010165:Palladium; D000537:Aluminum Oxide