MIL-103, a 3-D lanthanide-based metal organic framework with large one-dimensional tunnels and a high surface area.
A lanthanide-based metal organic framework, formulated Tb(C27H15O6)(H2O).2C6H11OH, has been solvothermally synthesized using the extended rigid tritopic ligand 1,3,5-tribenzoate. Included free solvent could be removed upon heating, and the resulting material presents large 1-D micropores (free diameter = 10 A) and a high surface area (SLangmuir > 1000 m2.g-1).
Devic
Thomas
T
Institut Lavoisier, UMR CNRS 8637, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles Cedex, France. ferey@chimie.uvsq.fr
Serre
Christian
C
Audebrand
Nathalie
N
Marrot
Jérôme
J
Férey
Gérard
G
D000327:Adsorption; D018360:Crystallography, X-Ray; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008958:Models, Molecular; D009584:Nitrogen / Q000737:chemistry; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013499:Surface Properties
D028581:Lanthanoid Series Elements; C505502:MIL-103; D009942:Organometallic Compounds; D009584:Nitrogen