Multivalency and cooperativity in supramolecular chemistry.
Multivalent interactions, which rely upon noncovalent bonds, are essential ingredients in the mediation of biological processes, as well as in the construction of complex (super)structures for materials applications. A fundamental understanding of multivalency in supramolecular chemistry is necessary not only to construct motors and devices on the nanoscale but also to synthesize model systems to provide insight into how biological processes work. This Account focuses on the application of multivalency to supramolecular chemistry in particular and the nanosciences in general.
Badjić
Jovica D
JD
California NanoSystems Institute, Department of Chemistry and Biochemistry, University of California, Los Angeles, California 90095-1569, USA.
Nelson
Alshakim
A
Cantrill
Stuart J
SJ
Turnbull
W Bruce
WB
Stoddart
J Fraser
JF
D046911:Macromolecular Substances / Q000737:chemistry*; D008956:Models, Chemical; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry*; D036103:Nanotechnology; D013816:Thermodynamics; D047392:beta-Cyclodextrins / Q000737:chemistry*
D046911:Macromolecular Substances; D047392:beta-Cyclodextrins