Complete 1H and 13C NMR assignments of aurasperone A and fonsecinone A, two bis-naphthopyrones produced by Aspergillus aculeatus.
Complete assignments of 1H and 13C NMR chemical shifts of the polyketides aurasperone A and fonsecinone A were made by means of nuclear Overhauser enhancement and heteronuclear NMR correlation experiments. These compounds were isolated for the first time from Aspergillus aculeatus, an endophytic fungus obtained from leaves of Melia azedarach(Meliaceae).
Campos
Francinete Ramos
FR
Departamento de Química, Universidade Federal de São Carlos, Rod. Washington Luiz, CP 676, CEP 13565-905, São Carlos, SP, Brazil.
Barison
Andersson
A
Daolio
Cristina
C
Ferreira
Antonio G
AG
Rodrigues-Fo
Edson
E
D001230:Aspergillus / Q000737:chemistry*; D002247:Carbon Isotopes; D002867:Chromones / Q000737:chemistry* / Q000302:isolation & purification; D009682:Magnetic Resonance Spectroscopy / Q000379:methods* / Q000592:standards*; D015394:Molecular Structure; D009281:Naphthalenes / Q000737:chemistry* / Q000302:isolation & purification; D011522:Protons; D011753:Pyrones / Q000737:chemistry* / Q000302:isolation & purification; D012015:Reference Standards
D002247:Carbon Isotopes; D002867:Chromones; D009281:Naphthalenes; D011522:Protons; D011753:Pyrones; C507895:fonsecinone A; C507894:aurasperone A