Synthesis and characterization of a polyoxovanadate cluster representing a new topology.
A new type of mixed-valence polyoxoanionic cluster, [V(V)13V(IV)3O42(Cl)]8-, composed of 14 {VO5} square pyramids and 2 {VO4} tetrahedral units, hosting a chloride ion has been synthesized and characterized.
Ishaque Khan
M
M
Department of Biological, Chemical, and Physical Sciences, Illinois Institute of Technology, Chicago, IL 60616, USA. khan@iit.edu
Ayesh
Samar
S
Doedens
Robert J
RJ
Yu
Minghui
M
O'Connor
Charles J
CJ
D002712:Chlorides / Q000737:chemistry; D018360:Crystallography, X-Ray; D007202:Indicators and Reagents; D008958:Models, Molecular; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D011726:Pyridinium Compounds / Q000737:chemistry; D013055:Spectrophotometry, Infrared; D013818:Thermogravimetry; D014638:Vanadates / Q000737:chemistry*; D014867:Water / Q000737:chemistry
C518198:(V(V)(13)V(IV)(3)O(42)Cl) (8-) ion; D002712:Chlorides; D007202:Indicators and Reagents; D011726:Pyridinium Compounds; D014867:Water; D014638:Vanadates