Spatially resolved Suzuki coupling reaction initiated and controlled using a catalytic AFM probe.
Appropriately modified proximal probes can be utilized in the spatially resolved chemical coupling of surface-bound and solution-phase reagents. Herein we report a chemically specific Suzuki coupling reaction between a surface-confined aryl bromide and boronic acid reagents in solution achieved using a catalytic AFM probe.
Davis
Jason J
JJ
Inorganic Chemistry Department, Central Research Laboratory, Oxford University, UK. jason.davis@chem.ox.ac.uk
Coleman
Karl S
KS
Busuttil
Katerina L
KL
Bagshaw
Claire B
CB
D001897:Boronic Acids / Q000737:chemistry; D002384:Catalysis; D006842:Hydrocarbons, Brominated / Q000138:chemical synthesis* / Q000737:chemistry; D018625:Microscopy, Atomic Force / Q000295:instrumentation / Q000379:methods*; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D013499:Surface Properties
D001897:Boronic Acids; D006842:Hydrocarbons, Brominated; D010165:Palladium; C010686:benzeneboronic acid