title: Effects of de-icing chemicals sodium chloride and potassium formate on cadmium solubility in a coarse mineral soil.
abstract: Excessive use of sodium chloride (NaCl) as de-icing chemical causes environmental problems, such as elevated chloride concentrations in groundwater. On vulnerable sites, this can be avoided by using alternative organic de-icing chemicals, such as potassium formate (KHCOO). The environmental impacts of KCHOO are, however, not well known. This study reports the potential effects of NaCl and KCHOO on mechanisms controlling the mobility of cadmium (Cd) in roadside soils as a result of vehicular traffic. Changes in the solubility of Cd in a coarse mineral soil treated with these two de-icing chemicals were studied in a 50-day incubation experiment under four different moisture and temperature combinations and an initial soil Cd concentration of 3 mg kg(-1). After incubation, the distribution of soil Cd into different fractions was analyzed using a sequential extraction method. Soil pH and soil redox potential were recorded and the occurrence of Cd-Cl complexes in the soil was estimated using published stability constants. During incubation, KCHOO lowered the soil redox potential, but this was not accompanied by a decrease in the sorption capacity of oxides and the release of oxide-bound Cd into soil solution. On the other hand, elevated pH (from 4.3 to 6.7-8.5) in the formate treatments increased the sorption of Cd onto the oxide surfaces (up to 80% of total sorbed Cd). In the NaCl treatments, cation competition and formation of Cd-Cl complexes increased the water-soluble Cd fraction. Consequently, the amount of bioavailable Cd was 3.5 times smaller in the KCHOO than in the NaCl treatments.
authors.affiliation: Department of Applied Chemistry and Microbiology, University of Helsinki, P.O. Box 27, FIN-00014, University of Helsinki, Finland. kimmo.rasa@helsinki.fi
authors.forename: Kimmo
authors.initials: K
authors.lastname: Rasa
authors.forename: Tommi
authors.initials: T
authors.lastname: Peltovuori
authors.forename: Helinä
authors.initials: H
authors.lastname: Hartikainen
mesh_terms: D002104:Cadmium / Q000032:analysis / Q000737:chemistry*; D005561:Formates / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007053:Ice; D010084:Oxidation-Reduction; D012965:Sodium Chloride / Q000737:chemistry*; D012988:Soil Microbiology; D012989:Soil Pollutants / Q000032:analysis; D012995:Solubility; D014186:Transportation
chemical_list: D005561:Formates; D007053:Ice; D012989:Soil Pollutants; D002104:Cadmium; D012965:Sodium Chloride