title: Oxidation of gas phase trichloroethylene and toluene using composite sol-gel TiO2 photocatalytic coatings.
abstract: The previously developed composite sol-gel (CSG) process is proposed for the deposition of thick (10-50 microm) porous films of photocatalytic TiO2. The CSG titania was developed by binding pre-calcined TiO2 particles with TiO2 sol. It had relatively high surface area (15-35 m2/g) and good resistance against mechanical stress and abrasion. Photocatalytic activity tests were carried out on trichloroethylene (TCE) and toluene, and compared with those of standard Degussa P-25 titania. The CSG photocatalyst provided good photo-efficiency in removing both pollutants from contaminated air streams. When compared with P-25 titania, the CSG photocatalyst showed a similar photo-efficiency with first-order kinetic rate constants not significantly different from that of P-25. For both photocatalysts the rate of photocatalytic oxidation of TCE was significantly greater than that obtained for toluene. Overall, the combination of better mechanical integrity, resistance against abrasion, and comparable photocatalytic efficiency of the CSG titania versus that of P-25 titania, make the composite sol-gel (CSG) photocatalyst a viable alternative for industrial applications where long term stability, superior mechanical properties, and good photo-efficiency are of critical value.
authors.affiliation: Department of Materials Engineering, University of British Columbia, 309-6350 Stores Rd., Vancouver, BC, Canada V6T 1Z4. keshmiri@interchange.ubc.ca
authors.forename: Mehrdad
authors.initials: M
authors.lastname: Keshmiri
authors.forename: Tom
authors.initials: T
authors.lastname: Troczynski
authors.forename: Madjid
authors.initials: M
authors.lastname: Mohseni
mesh_terms: D002384:Catalysis; D005740:Gases; D007220:Industrial Waste / Q000517:prevention & control*; D010083:Oxidants, Photochemical / Q000737:chemistry; D010084:Oxidation-Reduction; D044367:Phase Transition; D010777:Photochemistry; D013499:Surface Properties; D014025:Titanium; D014050:Toluene / Q000737:chemistry*; D014241:Trichloroethylene / Q000737:chemistry*
chemical_list: D005740:Gases; D007220:Industrial Waste; D010083:Oxidants, Photochemical; C009495:titanium dioxide; D014241:Trichloroethylene; D014050:Toluene; D014025:Titanium