Lewis acid adducts of [PCl2N]3.
Reaction of aluminum trichloride or gallium trichloride with the extremely weak base hexachlorotriphosphazene gives adducts in which the group 13 element is bound to a phosphazene nitrogen atom. In solution, the adducts exhibit fluxional behavior. The phosphazene ring of the adducts is distorted into a slight chair conformation.
Heston
Amy J
AJ
Department of Chemistry, University of Akron, 190 East Buchtel Commons, Akron, OH 44325-3601, USA.
Panzner
Matthew J
MJ
Youngs
Wiley J
WJ
Tessier
Claire A
CA
D000143:Acids / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*
D000143:Acids; D009943:Organophosphorus Compounds; D011108:Polymers