title: A highly selective, organocatalytic route to chiral dihydro-1,2-oxazines.
abstract: [reaction: see text] The organocatalyzed asymmetric synthesis of chiral dihydro-1,2-oxazines from achiral starting materials proceeds in moderate to excellent yields and excellent enantioselectivity. This sequential reaction gives the desired products in a single pot.
authors.affiliation: Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK.
authors.forename: Sirirat
authors.initials: S
authors.lastname: Kumarn
authors.forename: David M
authors.initials: DM
authors.lastname: Shaw
authors.forename: Deborah A
authors.initials: DA
authors.lastname: Longbottom
authors.forename: Steven V
authors.initials: SV
authors.lastname: Ley
mesh_terms: D000080462:Acyclic Monoterpenes; D000447:Aldehydes / Q000737:chemistry; D001688:Biological Products / Q000737:chemistry; D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D015394:Molecular Structure; D039821:Monoterpenes / Q000737:chemistry; D009584:Nitrogen / Q000737:chemistry; D010078:Oxazines / Q000737:chemistry*; D020005:Propanols / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000080462:Acyclic Monoterpenes; D000447:Aldehydes; D001688:Biological Products; D039821:Monoterpenes; D010078:Oxazines; D020005:Propanols; C006463:allyl alcohol; D006859:Hydrogen; D009584:Nitrogen; C108217:citronellal