title: Synthesis and characterization of a polyoxovanadate cluster representing a new topology.
abstract: A new type of mixed-valence polyoxoanionic cluster, [V(V)13V(IV)3O42(Cl)]8-, composed of 14 {VO5} square pyramids and 2 {VO4} tetrahedral units, hosting a chloride ion has been synthesized and characterized.
authors.affiliation: Department of Biological, Chemical, and Physical Sciences, Illinois Institute of Technology, Chicago, IL 60616, USA. khan@iit.edu
authors.forename: M
authors.initials: M
authors.lastname: Ishaque Khan
authors.forename: Samar
authors.initials: S
authors.lastname: Ayesh
authors.forename: Robert J
authors.initials: RJ
authors.lastname: Doedens
authors.forename: Minghui
authors.initials: M
authors.lastname: Yu
authors.forename: Charles J
authors.initials: CJ
authors.lastname: O'Connor
mesh_terms: D002712:Chlorides / Q000737:chemistry; D018360:Crystallography, X-Ray; D007202:Indicators and Reagents; D008958:Models, Molecular; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D011726:Pyridinium Compounds / Q000737:chemistry; D013055:Spectrophotometry, Infrared; D013818:Thermogravimetry; D014638:Vanadates / Q000737:chemistry*; D014867:Water / Q000737:chemistry
chemical_list: C518198:(V(V)(13)V(IV)(3)O(42)Cl) (8-) ion; D002712:Chlorides; D007202:Indicators and Reagents; D011726:Pyridinium Compounds; D014867:Water; D014638:Vanadates