The synthesis of isostructural Mo2+ porphyrin and N-confused porphyrin complexes.
We have synthesized the first early transition metal N-confused porphyrin complex Mo(NCTPP)(pip)2; this species is isostructural to its normal porphyrin analog Mo(TPP)(pip)2 but exhibits significant electronic differences arising from the inversion of a single pyrrolic group.
Harvey
John D
JD
Department of Chemistry, University of Akron, Akron, OH 44325-3601, USA.
Shaw
Janet L
JL
Herrick
Richard S
RS
Ziegler
Christopher J
CJ
D018360:Crystallography, X-Ray; D004578:Electron Spin Resonance Spectroscopy; D004583:Electrons; D008958:Models, Molecular; D008982:Molybdenum / Q000737:chemistry*; D011166:Porphyrins / Q000138:chemical synthesis*; D011758:Pyrroles; D013056:Spectrophotometry, Ultraviolet
D011166:Porphyrins; D011758:Pyrroles; D008982:Molybdenum