Formation of a bowl-shaped, pentacyclic phosphonium cage by methylation of a nucleophilic phosphinidene.
Driess
Matthias
M
Institute of Chemistry: Metalorganics and Inorganic Materials, Technical University of Berlin, Strasse des 17. Juni 135, Sekr. C2, 10623 Berlin, Germany. matthias.driess@tu-berlin.de
Muresan
Nicoleta
N
Merz
Klaus
K
Päch
Michael
M
D018360:Crystallography, X-Ray; D008745:Methylation; D008958:Models, Molecular; D008968:Molecular Conformation; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010720:Phosphines / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D009943:Organophosphorus Compounds; D010720:Phosphines