A microchip capillary electrophoretic reactor: a new methodology for direct measurement of dissociation kinetics of metal complexes.
A microchip capillary electrophoretic reactor has been proposed and successfully demonstrated in the direct evaluation of the solvolytic dissociation rate constant of the complex of Ce3+ with a polyaminocarboxylic ligand, 8-amino-2-[(2-amino-5-methylphenoxyl)methyl]-6-methoxyquinoline-N,N,N',N'-tetraacetic acid.
Takahashi
Toru
T
Division of Environmentally Benign Systems, Graduate School of Environmental Studies, Tohoku University, Aramaki, Sendai 980-8579, Japan. toru@analchem.che.tohoku.ac.jp
Ohtsuka
Kei-ichirou
K
Iki
Nobuhiko
N
Hoshino
Hitoshi
H
D046209:Electrophoresis, Microchip / Q000295:instrumentation / Q000379:methods*; D006801:Humans; D008670:Metals / Q000032:analysis; D009942:Organometallic Compounds / Q000737:chemistry*
D008670:Metals; D009942:Organometallic Compounds