Iron(II) and zinc(II) monohelical binaphthyl salen complexes.
A new chiral binaphthyl salen ligand with rigid polyaromatic sidearms gives monohelical complexes (Fe(II) and Zn(II)) of predetermined handedness.
Wiznycia
Alexander V
AV
111 Willard Hall, Department of Chemistry, Kansas State University, Manhattan, Kansas 66506, USA.
Desper
John
J
Levy
Christopher J
CJ
D018360:Crystallography, X-Ray; D005296:Ferrous Compounds / Q000138:chemical synthesis*; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D015032:Zinc / Q000737:chemistry*
C518199:(2,2'-bis((4-hydroxyphenanthren-3-yl)formimino)-1,1'-bisnaphthalene)iron(II); C518200:(2,2'-bis((4-hydroxyphenanthren-3-yl)formimino)-1,1'-bisnaphthalene)zinc(II); D005296:Ferrous Compounds; D008024:Ligands; D009942:Organometallic Compounds; D007501:Iron; D015032:Zinc