title: Lewis acid adducts of [PCl2N]3.
abstract: Reaction of aluminum trichloride or gallium trichloride with the extremely weak base hexachlorotriphosphazene gives adducts in which the group 13 element is bound to a phosphazene nitrogen atom. In solution, the adducts exhibit fluxional behavior. The phosphazene ring of the adducts is distorted into a slight chair conformation.
authors.affiliation: Department of Chemistry, University of Akron, 190 East Buchtel Commons, Akron, OH 44325-3601, USA.
authors.forename: Amy J
authors.initials: AJ
authors.lastname: Heston
authors.forename: Matthew J
authors.initials: MJ
authors.lastname: Panzner
authors.forename: Wiley J
authors.initials: WJ
authors.lastname: Youngs
authors.forename: Claire A
authors.initials: CA
authors.lastname: Tessier
mesh_terms: D000143:Acids / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*
chemical_list: D000143:Acids; D009943:Organophosphorus Compounds; D011108:Polymers