title: Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)3C6H2CNSSN..
abstract: The sterically protected dithiadiazolyl radical (F3C)3C6H2CNSSN. (1) crystallises in two polymorphs: 1alpha, comprised of monomeric units and 1beta, containing a mixture of both pi*-pi* dimers and S = (1/2) monomers; whilst both polymorphs exhibit similar structure-directing motifs, the variation in packing leads to different magnetic behaviour.
authors.affiliation: Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UKCB2 1EW.
authors.forename: Antonio
authors.initials: A
authors.lastname: Alberola
authors.forename: Caroline S
authors.initials: CS
authors.lastname: Clarke
authors.forename: Delia A
authors.initials: DA
authors.lastname: Haynes
authors.forename: Sofia I
authors.initials: SI
authors.lastname: Pascu
authors.forename: Jeremy M
authors.initials: JM
authors.lastname: Rawson