Misleading effects of impurities derived from the extremely long-lived electron-transfer state of 9-mesityl-10-methylacridinium ion.
9-Mesityl-10-methylacridinium ion has an extremely long-lived electron-transfer state, which results in the misleading effects of electron donor impurities contained in benzonitrile to produce the stable acridinyl radical.
Ohkubo
Kei
K
Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST, Japan Science and Technology Agency, Suita, Osaka 565-0871, Japan.
Kotani
Hiroaki
H
Fukuzumi
Shunichi
S
D000166:Acridines / Q000737:chemistry*; D004583:Electrons; D006863:Hydrogen-Ion Concentration; D009570:Nitriles / Q000737:chemistry; D010084:Oxidation-Reduction; D012996:Solutions; D013056:Spectrophotometry, Ultraviolet; D014466:Ultraviolet Rays
C484398:9-mesityl-10-methylacridinium; D000166:Acridines; D009570:Nitriles; D012996:Solutions