title: Impregnated active carbons to control atmospheric emissions: influence of impregnation methodology and raw material on the catalytic activity.
abstract: Previous studies have reported the influence of raw material on the catalytic activity of metal oxides impregnated in activated carbons. However, knowledge was as yet quite scarce for impregnation performed before activation. The main objective of the study here reported was the development of such knowledge. Olive stones, pinewood sawdust, nutshells, and almond shells were recycled to prepare the activated carbons. Transition metal oxides (CoO, Co3O4, and CrO3) were impregnated aiming to prepare activated carbons to be used for the complete catalytic oxidation of benzene. When impregnation was performed after activation the impregnated species were deposited on the internal surface, blocking part of the initial porous texture. When impregnation was performed before activation, the metal species acted as catalysts during the activation step, allowing better catalyst distribution on a more well-developed mesoporous texture. Co3O4 was the best catalyst and almond shells were the best support. With this catalyst/support pair a conversion of 90% was possible at 404 K, the lowest temperature of all the carbons studied. Good conversions were obtained at temperatures that guarantee carbon stability (lower than 575 K). It was concluded that activated carbon was a suitable support for metal oxide catalysts aiming for the complete oxidation of benzene, especially when a suitable porous texture is induced, by performing the impregnation step before activation.
authors.affiliation: LEPAE, Departamento de Engenharia Química, Faculdade de Engenharia, Universidade do Porto, R. Dr. Roberto Frias, 4200-465 Oporto, Portugal. aferraz@fe.up.pt
authors.forename: Maria C M
authors.initials: MC
authors.lastname: Alvim-Ferraz
authors.forename: Carla M T B
authors.initials: CM
authors.lastname: Gaspar
mesh_terms: D000397:Air Pollution / Q000517:prevention & control*; D001554:Benzene / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D003247:Conservation of Natural Resources; D008670:Metals / Q000737:chemistry; D009754:Nuts; D010084:Oxidation-Reduction; D010087:Oxides / Q000737:chemistry; D014835:Volatilization; D014934:Wood
chemical_list: D008670:Metals; D010087:Oxides; D002244:Carbon; D001554:Benzene