title: Organotin(IV) complexes of thiohydrazones: synthesis, characterization and antifungal study.
abstract: Some new organotin(IV) complexes with salicylaldehyde aniline-N-thiohydrazone (L1) and cinamaldehyde aniline-N-thiohydrazone (L2) of the type (p-ClC6H4)3Sn[L] Cl and (p-ClC6H4)2Sn[L]Cl2 have been synthesized (where L = L1 and L2). The complexes and ligands were characterized by elemental analysis and spectral (UV-vis, IR and 1H NMR) studies. In all the complexes, ligands act as bidentate, coordination through sulphur and azomethane nitrogen. Complexes are 1:1 metal ligands complexes. Antifungal studies of some complexes against Rhizoctonia bataticola fungal strain have been carried out.
authors.affiliation: Department of Chemistry, University of Delhi, Delhi-110007, India. ajaykmishra1@yahoo.com
authors.forename: A K
authors.initials: AK
authors.lastname: Mishra
authors.forename: N
authors.initials: N
authors.lastname: Manav
authors.forename: N K
authors.initials: NK
authors.lastname: Kaushik
mesh_terms: D000935:Antifungal Agents / Q000138:chemical synthesis* / Q000737:chemistry / Q000494:pharmacology*; D006835:Hydrazones / Q000138:chemical synthesis / Q000737:chemistry* / Q000494:pharmacology; D015394:Molecular Structure; D009947:Organotin Compounds / Q000737:chemistry*; D012232:Rhizoctonia / Q000187:drug effects; D013053:Spectrophotometry; D013438:Sulfhydryl Compounds / Q000737:chemistry*
chemical_list: D000935:Antifungal Agents; D006835:Hydrazones; D009947:Organotin Compounds; D013438:Sulfhydryl Compounds