Process effects on activated carbon with large specific surface area from corn cob.
The main factors that affect the large specific surface area (SSA) of the activated carbon from agricultural waste corn cobs were studied by chemically activated method with solution of KOH and soap which acted as surfactant. The experiment showed that not only the activation temperature, activation time and the mass ratio of KOH to the carbonized material, but also the activated methods using activator obviously influenced the SSA of activated carbon. The experimental operating conditions were as follows: the carbonized temperature being 450 degrees C and keeping time being 4 h using N2 as protective gas; the activation temperature being 850 degrees C and holding time being 1.2 h; the mass ratio of KOH to carbonized material being 4.0; the time of soaking carbonized material in the solution of KOH and soap being 30 min. Under the optimal conditions, the SSA of activated carbon from corn cobs reached 2700 m2/g. And the addition of the soap as surfactant may shorten the soaking time. The structure of the activated carbon prepared had narrow distribution of pore size and the micro-pores accounted for 78%. The advantages of the method described were easy and feasible.
Cao
Qing
Q
Key Laboratory for Coal Science and Technology of Shanxi Province and Ministry of Education, Taiyuan University of Technology, Shanxi Province 030024, PR China.
Xie
Ke-Chang
KC
Lv
Yong-Kang
YK
Bao
Wei-Ren
WR
D002244:Carbon / Q000737:chemistry*; D006358:Hot Temperature; D006878:Hydroxides; D017680:Potassium Compounds; D013499:Surface Properties; D013997:Time Factors; D003313:Zea mays / Q000737:chemistry*
D006878:Hydroxides; D017680:Potassium Compounds; D002244:Carbon; C029943:potassium hydroxide