title: Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation.
abstract: A mononuclear nonheme ferric-peroxo complex bearing a macrocyclic tetradentate N4 ligand, [(TMC)Fe(III)-O2]+, was prepared and used in mechanistic studies of aldehyde deformylation; a catalytic aldehyde deformylation by a nonheme iron(II) complex, [Fe(II)(TMC)]2+, and molecular oxygen is reported as well.
authors.affiliation: Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womans University, Seoul 120-750, Korea.
authors.forename: Jamespandi
authors.initials: J
authors.lastname: Annaraj
authors.forename: Yumi
authors.initials: Y
authors.lastname: Suh
authors.forename: Mi Sook
authors.initials: MS
authors.lastname: Seo
authors.forename: Sun Ok
authors.initials: SO
authors.lastname: Kim
authors.forename: Wonwoo
authors.initials: W
authors.lastname: Nam
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D002384:Catalysis; D005290:Ferric Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D005561:Formates / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry; D011166:Porphyrins / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet
chemical_list: D000447:Aldehydes; D005290:Ferric Compounds; D005561:Formates; D011166:Porphyrins; C518394:peroxo(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)iron(III); C030544:formic acid; D010100:Oxygen