Mononuclear nonheme ferric-peroxo complex in aldehyde deformylation.
A mononuclear nonheme ferric-peroxo complex bearing a macrocyclic tetradentate N4 ligand, [(TMC)Fe(III)-O2]+, was prepared and used in mechanistic studies of aldehyde deformylation; a catalytic aldehyde deformylation by a nonheme iron(II) complex, [Fe(II)(TMC)]2+, and molecular oxygen is reported as well.
Annaraj
Jamespandi
J
Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womans University, Seoul 120-750, Korea.
Suh
Yumi
Y
Seo
Mi Sook
MS
Kim
Sun Ok
SO
Nam
Wonwoo
W
D000447:Aldehydes / Q000737:chemistry*; D002384:Catalysis; D005290:Ferric Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D005561:Formates / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry; D011166:Porphyrins / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet
D000447:Aldehydes; D005290:Ferric Compounds; D005561:Formates; D011166:Porphyrins; C518394:peroxo(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)iron(III); C030544:formic acid; D010100:Oxygen