title: Kinetic resolution of alpha-acetoxy N-acyl oxazolidinethiones by a chiral O-nucleophilic acyl transfer catalyst.
abstract: The kinetic resolution of alpha-acetoxy N-acyl oxazolidinethiones using the chiral, nonracemic O-nucleophilic acyl transfer catalyst 8 is described. The reaction proceeds on a variety of substrates in excellent yields, with s-factors ranging from 17 to 31.
authors.affiliation: Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309-0215, USA.
authors.forename: Gregory T
authors.initials: GT
authors.lastname: Notte
authors.forename: Tarek
authors.initials: T
authors.lastname: Sammakia
authors.forename: Peter J
authors.initials: PJ
authors.lastname: Steel
mesh_terms: D002384:Catalysis; D007700:Kinetics; D010080:Oxazoles / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D010080:Oxazoles