Selective and controlled synthesis of alpha- and beta-cobalt hydroxides in highly developed hexagonal platelets.
We report on the controlled synthesis of single-crystal platelets of alpha- and beta-Co(OH)2 via homogeneous precipitation using hexamethylenetetramine as a hydrolysis agent. The alpha- and beta-Co(OH)2 hexagonal platelets of several micrometers in width and about 15 nm in thickness were reproducibly yielded in rather dilute CoCl2 solutions in the presence and absence of NaCl at 90 degrees C, respectively. The phase and size control of the products were achieved by varying both CoCl2 and NaCl concentrations. Polarized optical microscope observations revealed clear liquid crystallinity of colloidal suspensions of these high aspect-ratio platelets. The as-prepared alpha-Co(OH)2 containing interlayer chloride ions was intercalated with various inorganic or organic anions, keeping its high crystallinity and hexagonal platelike morphology.
Liu
Zhaoping
Z
Advanced Materials Laboratory, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.
Ma
Renzhi
R
Osada
Minoru
M
Takada
Kazunori
K
Sasaki
Takayoshi
T
D003035:Cobalt / Q000737:chemistry*; D003460:Crystallization; D006878:Hydroxides / Q000138:chemical synthesis* / Q000737:chemistry; D010316:Particle Size; D013237:Stereoisomerism; D013499:Surface Properties; D013696:Temperature
D006878:Hydroxides; D003035:Cobalt