title: Phase diagrams of self-assembled mono-tethered nanospheres from molecular simulation and comparison to surfactants.
abstract: We perform Brownian dynamics simulations on model 3-D systems of mono-tethered nanospheres (TNS) to study the equilibrium morphologies formed by their self-assembly in a selective solvent. We predict that in contrast to flexible amphiphiles the nanospheres are locally ordered and there is an increase in the local order with an increase in concentration or relative nanoparticle diameter. We present the temperature vs concentration phase diagram for a system of TNS and propose a dimensionless scaling factor F(v) (headgroup volume/tether volume) that allows a comparison between the morphologies formed from TNS and traditional surfactants.
authors.affiliation: Departments of Chemical Engineering and Materials Science & Engineering, University of Michigan, Ann Arbor, MI 48109-2136, USA.
authors.forename: Christopher R
authors.initials: CR
authors.lastname: Iacovella
authors.forename: Mark A
authors.initials: MA
authors.lastname: Horsch
authors.forename: Zhenli
authors.initials: Z
authors.lastname: Zhang
authors.forename: Sharon C
authors.initials: SC
authors.lastname: Glotzer