Synthesis of alpha-D-idoseptanosyl glycosides using an S-phenyl septanoside donor.
[reaction: see text] An S-phenyl alpha-D-idoseptanoside donor was used in the selective preparation of a series of alpha-D-idoseptanosyl glycosides. Glycosylation of a methyl beta-D-glycero-D-guloseptanoside acceptor with the new donor constituted the first synthesis of a septanose disaccharide.
Castro
Steve
S
Department of Chemistry, University of Connecticut, 55 North Eagleville Road U-3060, Storrs, Connecticut 06269, USA.
Fyvie
W Sean
WS
Hatcher
Susan A
SA
Peczuh
Mark W
MW
D002236:Carbohydrate Conformation; D004187:Disaccharides / Q000138:chemical synthesis* / Q000737:chemistry; D006031:Glycosylation; D015394:Molecular Structure; D013237:Stereoisomerism; D013865:Thioglycosides / Q000737:chemistry*
D004187:Disaccharides; D013865:Thioglycosides