Shear-induced collapse in a lyotropic lamellar phase.
An entropically stabilized cetylpyridinium chloride, hexanol, and heavy brine lyotropic lamellar phase subjected to shear flow has been observed here by small angle neutron scattering to undergo collapse of smectic order above a threshold shear rate. The results are compared with theories predicting that such a lamellar phase sheared above a critical rate should lose its stability by a loss of resistance to compression due to the suppression of membrane fluctuations.
Porcar
L
L
National Institute of Standards and Technology, Center for Neutron Research, Gaithersburg, Maryland 20899, USA.
Warr
G G
GG
Hamilton
W A
WA
Butler
P D
PD
D002594:Cetylpyridinium / Q000737:chemistry; D019277:Entropy; D000441:Hexanols / Q000737:chemistry; D008051:Lipid Bilayers / Q000737:chemistry; D008566:Membranes / Q000737:chemistry*; D008567:Membranes, Artificial; D033081:Shear Strength
D000441:Hexanols; D008051:Lipid Bilayers; D008567:Membranes, Artificial; D002594:Cetylpyridinium