Copper-catalyzed allylation of carbonyl derivatives using allyl(2-pyridyl)silanes.
[reaction: see text] We have developed an efficient copper-catalyzed allylation of carbonyl derivatives using allyl(2-pyridyl)silanes, in which the strong directing effect of the 2-pyridyl group was observed. A useful synthesis and allylation of substituted allyl(2-pyridyl)silanes is also described.
Kamei
Toshiyuki
T
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan.
Fujita
Kazuyoshi
K
Itami
Kenichiro
K
Yoshida
Jun-ichi
J