title: Hydrothermal and mechanical stresses degrade fiber-matrix interfacial bond strength in dental fiber-reinforced composites.
abstract: Fiber-reinforced composites (FRCs) show great promise as long-term restorative materials in dentistry and medicine. Recent evidence indicates that these materials degrade in vivo, but the mechanisms are unclear. The objective of this study was to investigate mechanisms of deterioration of glass fiber-polymer matrix bond strengths in dental fiber-reinforced composites during hydrothermal and mechanical aging. Conventional three-point bending tests on dental FRCs were used to assess flexural strengths and moduli. Micro push-out tests were used to measure glass fiber-polymer matrix bond strengths, and nanoindentation tests were used to determine the modulus of elasticity of fiber and polymer matrix phases separately. Bar-shaped specimens of FRCs (EverStick, StickTech, and Vectris Pontic, Ivoclar-Vivadent) were either stored at room temperature, in water (37 and 100 degrees C) or subjected to ageing (10(6) cycles, load: 49 N), then tested by three-point bending. Thin slices were prepared for micro push-out and nanoindentation tests. The ultimate flexural strengths of both FRCs were significantly reduced after aging (p < 0.05). Both water storage and mechanical loading reduced the interfacial bond strengths of glass fibers to polymer matrices. Nanoindentation tests revealed a slight reduction in the elastic modulus of the EverStick and Vectris Pontic polymer matrix after water storage. Mechanical properties of FRC materials degrade primarily by a loss of interfacial bond strength between the glass and resin phases. This degradation is detectable by micro push-out and nanoindentation methods.
authors.affiliation: Department of Cariology and Endodontology, School of Dental Medicine, University of Geneva, Geneva, Switzerland. serge.bouillaguet@medecine.unige.ch
authors.forename: Serge
authors.initials: S
authors.lastname: Bouillaguet
authors.forename: Andrea
authors.initials: A
authors.lastname: Schütt
authors.forename: Pasi
authors.initials: P
authors.lastname: Alander
authors.forename: Patrick
authors.initials: P
authors.lastname: Schwaller
authors.forename: Gerhard
authors.initials: G
authors.lastname: Buerki
authors.forename: Johann
authors.initials: J
authors.lastname: Michler
authors.forename: Maria
authors.initials: M
authors.lastname: Cattani-Lorente
authors.forename: Pekka K
authors.initials: PK
authors.lastname: Vallittu
authors.forename: Ivo
authors.initials: I
authors.lastname: Krejci
mesh_terms: D001696:Biomechanical Phenomena; D003764:Dental Materials; D008855:Microscopy, Electron, Scanning; D036103:Nanotechnology
chemical_list: D003764:Dental Materials