title: Pressure dependence of fragile-to-strong transition and a possible second critical point in supercooled confined water.
abstract: By confining water in nanopores of silica glass, we can bypass the crystallization and study the pressure effect on the dynamical behavior in deeply supercooled state using neutron scattering. We observe a clear evidence of a cusplike fragile-to-strong (FS) dynamic transition. Here we show that the transition temperature decreases steadily with an increasing pressure, until it intersects the homogenous nucleation temperature line of bulk water at a pressure of 1600 bar. Above this pressure, it is no longer possible to discern the characteristic feature of the FS transition. Identification of this end point with the possible second critical point is discussed.
authors.affiliation: Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
authors.forename: Li
authors.initials: L
authors.lastname: Liu
authors.forename: Sow-Hsin
authors.initials: SH
authors.lastname: Chen
authors.forename: Antonio
authors.initials: A
authors.lastname: Faraone
authors.forename: Chun-Wan
authors.initials: CW
authors.lastname: Yen
authors.forename: Chung-Yuan
authors.initials: CY
authors.lastname: Mou