A polar oxide with a large magnetization synthesized at ambient pressure.
The perovskite Bi2Mn4/3Ni2/3O6 is polar and combines relative permittivity behavior consistent with ferroelectricity with the magnetic response of a concentrated spin-glass. Bi2Mn4/3Ni2/3O6 is accessible by ambient pressure synthesis despite the instability of the end-members BiMnO3 and BiNiO3 under these conditions.
Hughes
Helen
H
Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, UK.
Allix
Mathieu M B
MM
Bridges
Craig A
CA
Claridge
John B
JB
Kuang
Xiaojun
X
Niu
Hongjun
H
Taylor
Stephen
S
Song
Wenhai
W
Rosseinsky
Matthew J
MJ
D001729:Bismuth / Q000737:chemistry; D008280:Magnetics; D008345:Manganese / Q000737:chemistry; D019216:Metals, Heavy / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*; D011312:Pressure; D013696:Temperature
D019216:Metals, Heavy; D008345:Manganese; D009532:Nickel; D010100:Oxygen; D001729:Bismuth