Enantioselective synthesis of linear polypropionate arrays using anthracene-tagged organosilanes.
[reaction: see text] Preparation and use of anthracene-tagged organosilanes in an iterative, resin-capture-release protocol for the stereocontrolled synthesis of polypropionate arrays are described.
Kesavan
Sarathy
S
Department of Chemistry and Center for Chemical Methodology and Library Development, Boston University, 590 Commonwealth Avenue, Boston, Massachusetts 02215, USA.
Su
Qibin
Q
Shao
Jian
J
Porco
John A
JA
Panek
James S
JS
D000873:Anthracenes / Q000737:chemistry*; D001688:Biological Products / Q000737:chemistry; D002851:Chromatography, High Pressure Liquid; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D011422:Propionates / Q000138:chemical synthesis* / Q000737:chemistry; D012821:Silanes / Q000737:chemistry*; D013237:Stereoisomerism
D000873:Anthracenes; D001688:Biological Products; D011422:Propionates; D012821:Silanes; C034020:anthracene