Early stages of ZnS nanoparticle growth studied by in-situ stopped-flow UV absorption spectroscopy.
The early stages of ZnS nanoparticle growth from supersaturated solution are investigated in situ by stopped-flow UV absorption spectroscopy with a time resolution of 1.28 ms. A model for data analysis is suggested which makes it possible to study both the average particle radius and the concentration. The average radii lie in the sub-nanometer range. During the first 40 ms, growth is predominantly governed by ripening.
Tiemann
Michael
M
Institutionen för Fysikalisk Kemi, Abo Akademi, Porthansgatan 3-5, 20500 Abo, Finland.
Weiss
Ozlem
O
Hartikainen
Juha
J
Marlow
Frank
F
Lindén
Mika
M