title: Synthesis of alpha-D-idoseptanosyl glycosides using an S-phenyl septanoside donor.
abstract: [reaction: see text] An S-phenyl alpha-D-idoseptanoside donor was used in the selective preparation of a series of alpha-D-idoseptanosyl glycosides. Glycosylation of a methyl beta-D-glycero-D-guloseptanoside acceptor with the new donor constituted the first synthesis of a septanose disaccharide.
authors.affiliation: Department of Chemistry, University of Connecticut, 55 North Eagleville Road U-3060, Storrs, Connecticut 06269, USA.
authors.forename: Steve
authors.initials: S
authors.lastname: Castro
authors.forename: W Sean
authors.initials: WS
authors.lastname: Fyvie
authors.forename: Susan A
authors.initials: SA
authors.lastname: Hatcher
authors.forename: Mark W
authors.initials: MW
authors.lastname: Peczuh
mesh_terms: D002236:Carbohydrate Conformation; D004187:Disaccharides / Q000138:chemical synthesis* / Q000737:chemistry; D006031:Glycosylation; D015394:Molecular Structure; D013237:Stereoisomerism; D013865:Thioglycosides / Q000737:chemistry*
chemical_list: D004187:Disaccharides; D013865:Thioglycosides