Kinetic studies for sorption of amino acids using a strong anion-exchange resin. Effect of ionic strength.
This work deals with the influence of the ionic strength on the sorption of L-phenylalanine and L-tyrosine by a strong basic anion-exchange resin, converted to the hydroxide form with sodium hydroxide. Equilibrium uptake isotherms were obtained for phenylalanine and tyrosine by carrying out batch experiments at different ionic strength values of the solution. The model used to correlate these results is the modified Langmuir equation which has been applied with success to biological systems. Batch kinetic experiments were performed using a packed bed of differential length inserted in a liquid circulation loop and in which the ionic strength of the solution was varied. Moreover, an experiment at variable pH for tyrosine was also performed. Experimental transient concentration profiles were compared to those predicted by the pore diffusion model and enabled the estimation of the intraparticle diffusivities for phenylalanine and tyrosine.
Moreira
Maria J
MJ
Department of Chemical Engineering, University of Coimbra, Polo II-Pinhal de Marrocos, 3030 Coimbra, Portugal.
Ferreira
Licínio M
LM
D000596:Amino Acids / Q000737:chemistry*; D000837:Anion Exchange Resins; D002852:Chromatography, Ion Exchange; D007700:Kinetics; D009994:Osmolar Concentration; D013816:Thermodynamics
D000596:Amino Acids; D000837:Anion Exchange Resins