Flexible self-assembling porphyrin supramolecules.
The design and chemical synthesis of a series of hybrid flexible self-assembling supramolecules utilising both crown ether-naphthalene diimide host-guest chemistry and metalloporphyrin-pyridyl coordination is discussed. The resulting compound structures and dynamics are probed using a variety of techniques, including diffusion ordered NMR spectroscopy (DOSY) and cold-spray ionisation mass spectrometry (CSI-MS).
Johnstone
Ken D
KD
School of Biological, Biomedical and Molecular Sciences, University of New England, Armidale, NSW 2350, Australia.
Yamaguchi
Kentaro
K
Gunter
Maxwell J
MJ
D043844:Crown Ethers / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008665:Metalloporphyrins / Q000737:chemistry*; D043862:Rotaxanes / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization
D043844:Crown Ethers; D008665:Metalloporphyrins; D043862:Rotaxanes