A highly effective catalyst system for the Pd-catalyzed amination of vinyl bromides and chlorides.
[reaction: see text] A highly efficient synthesis of enamines and imines by Pd-catalyzed amination of vinyl bromides or chlorides with amines is described using the Pd2(dba)3/P(i-BuNCH2CH2)3N catalyst system.
Venkat Reddy
Chinta Reddy
CR
Department of Chemistry, Gilman Hall, Iowa State University, Ames, Iowa 50011, USA.
Urgaonkar
Sameer
S
Verkade
John G
JG