title: Sequential energy and electron transfer in aggregates of tetrakis[oligo(p-phenylene vinylene)] porphyrins and C60 in water.
abstract: Chiral aggregation of oligo(p-phenylene vinylene)-functionalized Zn and free-base porphyrins is observed in water. The formation of mixed assemblies containing both porphyrins results in sequential energy transfer from OPV via zinc porphyrin to free-base porphyrin. Furthermore, the incorporation of C60 as electron acceptor yields a charge separated state by ultimate electron transfer.
authors.affiliation: Laboratory of Macromolecular and Organic Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
authors.forename: Martin
authors.initials: M
authors.lastname: Wolffs
authors.forename: Freek J M
authors.initials: FJ
authors.lastname: Hoeben
authors.forename: Edwin H A
authors.initials: EH
authors.lastname: Beckers
authors.forename: Albertus P H J
authors.initials: AP
authors.lastname: Schenning
authors.forename: E W
authors.initials: EW
authors.lastname: Meijer