title: Deracemization of quaternary stereocenters by Pd-catalyzed enantioconvergent decarboxylative allylation of racemic beta-ketoesters.
authors.affiliation: The Arnold and Mabel Beckman Laboratories of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 E. California Boulevard, MC 164-30, Pasadena, CA 91125, USA.
authors.forename: Justin T
authors.initials: JT
authors.lastname: Mohr
authors.forename: Douglas C
authors.initials: DC
authors.lastname: Behenna
authors.forename: Andrew M
authors.initials: AM
authors.lastname: Harned
authors.forename: Brian M
authors.initials: BM
authors.lastname: Stoltz
mesh_terms: D000478:Alkylation; D002384:Catalysis; D003653:Decarboxylation; D004952:Esters / Q000138:chemical synthesis*; D007659:Ketones / Q000138:chemical synthesis*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D004952:Esters; D007659:Ketones; D009942:Organometallic Compounds; D010165:Palladium