Air-stable racemization catalyst for dynamic kinetic resolution of secondary alcohols at room temperature.
[reaction: see text] A novel racemization catalyst was synthesized for the dynamic kinetic resolution (DKR) of alcohols with a lipase at room temperature in the air. Furthermore, a polymer-supported derivative was also synthesized and tested as a recyclable catalyst for the aerobic DKR of alcohols.
Kim
Namdu
N
National Research Laboratory of Chirotechnology, Department of Chemistry, Division of Molecular and Life Sciences, Pohang University of Science and Technology (POSTECH), San 31 Hyojadong, Pohang 790-784, Korea.
Ko
Soo-Byung
SB
Kwon
Min Serk
MS
Kim
Mahn-Joo
MJ
Park
Jaiwook
J
D000388:Air; D000438:Alcohols / Q000737:chemistry*; D001592:Benzyl Alcohols / Q000737:chemistry; D002384:Catalysis; D007536:Isomerism; D007700:Kinetics; D015394:Molecular Structure; D012428:Ruthenium / Q000737:chemistry; D013696:Temperature
D000438:Alcohols; D001592:Benzyl Alcohols; D012428:Ruthenium; C002017:methylphenyl carbinol