title: A polar oxide with a large magnetization synthesized at ambient pressure.
abstract: The perovskite Bi2Mn4/3Ni2/3O6 is polar and combines relative permittivity behavior consistent with ferroelectricity with the magnetic response of a concentrated spin-glass. Bi2Mn4/3Ni2/3O6 is accessible by ambient pressure synthesis despite the instability of the end-members BiMnO3 and BiNiO3 under these conditions.
authors.affiliation: Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, UK.
authors.forename: Helen
authors.initials: H
authors.lastname: Hughes
authors.forename: Mathieu M B
authors.initials: MM
authors.lastname: Allix
authors.forename: Craig A
authors.initials: CA
authors.lastname: Bridges
authors.forename: John B
authors.initials: JB
authors.lastname: Claridge
authors.forename: Xiaojun
authors.initials: X
authors.lastname: Kuang
authors.forename: Hongjun
authors.initials: H
authors.lastname: Niu
authors.forename: Stephen
authors.initials: S
authors.lastname: Taylor
authors.forename: Wenhai
authors.initials: W
authors.lastname: Song
authors.forename: Matthew J
authors.initials: MJ
authors.lastname: Rosseinsky
mesh_terms: D001729:Bismuth / Q000737:chemistry; D008280:Magnetics; D008345:Manganese / Q000737:chemistry; D019216:Metals, Heavy / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*; D011312:Pressure; D013696:Temperature
chemical_list: D019216:Metals, Heavy; D008345:Manganese; D009532:Nickel; D010100:Oxygen; D001729:Bismuth