Photoinduced reversible change of fluid viscosity.
We report a reversible photoinduced fluid viscosity change. A small amount of a "photoswitchable" azobenzene-modified cationic surfactant (4-butylazobenzene-4'-(oxyethyl)trimethylammonium bromide, AZTMA) was added to a wormlike micellar solution of cetyltrimethylammonium bromide (CTAB) containing sodium salicylate (NaSal). The trans-AZTMA solution had a remarkably high viscosity as a result of the entangled network of wormlike micelles. UV light irradiation on the trans-AZTMA solution remarkably decreased the viscosity of the solution because the bulky structure of cis-AZTMA is likely to disrupt the network structure of wormlike micelles. This photoinduced viscosity change is perfectly reversible between the trans- and cis-AZTMA solutions.
Sakai
Hideki
H
Faculty of Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510, Japan. hisakai@rs.noda.tus.ac.jp
Orihara
Yoichi
Y
Kodashima
Hideki
H
Matsumura
Atsutoshi
A
Ohkubo
Takahiro
T
Tsuchiya
Koji
K
Abe
Masahiko
M