title: A stable rearrangement product of humulene-4,5-epoxide.
abstract: Humulene-4,5-monoepoxide, 1, may rearrange to the cyclopropyl diol 2 during chromatography over silica. The rearrangement can be reversed with acid.
authors.affiliation: Chemistry, The University of Queensland, Brisbane, Queensland, Australia 4072. carman@chemistry.uq.edu.au
authors.forename: Raymond M
authors.initials: RM
authors.lastname: Carman
mesh_terms: D002845:Chromatography; D004852:Epoxy Compounds / Q000737:chemistry*; D015394:Molecular Structure; D000081222:Monocyclic Sesquiterpenes; D012717:Sesquiterpenes / Q000737:chemistry*
chemical_list: D004852:Epoxy Compounds; D000081222:Monocyclic Sesquiterpenes; D012717:Sesquiterpenes; C505329:humulene-4,5-epoxide; C042686:humulene