title: Microwave-assisted cross-coupling reaction of alkynylstibanes with aryl iodides in the presence of ammonium salt.
abstract: The scope of microwave-assisted coupling reaction of alkynylstibane and aryl iodides to form diarylalkynes is presented. Highly efficient reaction took place smoothly in dimethyl sulfoxide in the presence of cetyltrimethylammonium bromide with much shorter time (1 min) and lower catalyst loading (0.5 mol%) than the conventional method (heating for 24 h with 10 mol% catalyst).
authors.affiliation: Faculty of Pharmaceutical Sciences, Hokuriku University, Kanazawa, Japan.
authors.forename: Naoki
authors.initials: N
authors.lastname: Kakusawa
authors.forename: Jyoji
authors.initials: J
authors.lastname: Kurita
mesh_terms: D000965:Antimony / Q000737:chemistry* / Q000528:radiation effects; D002384:Catalysis; D000077286:Cetrimonium; D002593:Cetrimonium Compounds / Q000737:chemistry* / Q000528:radiation effects; D006847:Hydrocarbons, Iodinated / Q000737:chemistry* / Q000528:radiation effects; D008872:Microwaves; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry / Q000528:radiation effects
chemical_list: D002593:Cetrimonium Compounds; D006847:Hydrocarbons, Iodinated; D009942:Organometallic Compounds; D000965:Antimony; D000077286:Cetrimonium