Ring-opening polymerisation of coordination compounds: a silver(I) network with both ring and polymer components.
The terpyridyl ligand 2,6-C5H3N{C(=O)N(Me)-4-C5H4N}2, 1, combined with silver(I) salts to give the complexes [Ag2(1)2][BF4]2, 2, and [{Ag3(1)2}n][CF3SO3]3n, 3; the network structure of complex contains both macrocyclic units [Ag2(mu-1)2]2+ and ring-opened polymeric units [{Ag(mu-1)}n]n+.
Yue
Nancy L S
NL
Department of Chemistry, University of Western Ontario, London, Canada.
Jennings
Michael C
MC
Puddephatt
Richard J
RJ
D018360:Crystallography, X-Ray; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D012680:Sensitivity and Specificity; D012834:Silver / Q000737:chemistry*; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization
D008024:Ligands; D009942:Organometallic Compounds; D011108:Polymers; D012834:Silver