title: Cyano-bridged CuII-MV (M = Mo, W) bimetallic layered complexes exhibiting novel honeycomblike structures.
abstract: Self-assembly of a new precursor [Cu(L)](ClO4)2 (1) (L = macrocyclic ligand) with octacyanometalates [M(CN)8]3- (M = Mo, W) produced two-dimensional cyano-bridged Cu(II)-M(V) bimetallic assemblies [Cu(L)]3n[M(CN)8]2n.6nH2O [M = Mo (2), W (3)] with novel honeycomblike structures, characterized by spectroscopic data, single-crystal X-ray diffraction studies, and magnetic measurements. The crystallographic determination reveals that compounds 2 and 3 are isostructural and crystallize in the triclinic system (P). The Cu atom in a distorted octahedral environment experiences a tetragonal elongation of apical nitrogen atoms exhibiting average Cu-Nax lengths of 2.566 Angstroms for 2 and 2.593 Angstroms for 3, which accounts for the Jahn-Teller effect of a Cu(II) ion. The Cu-NC angles are magnetically important, ranging from 135.7 to 159.2 degrees. Three types of L in the crystal lattice are observed, which are dependent on the relative positions of the pendant hydroxyl groups with respect to the CuN4 basal plane. The positions are correlated with hydrogen bonding of OH groups to neighboring atoms. The magnetic data indicate that ferromagnetic and antiferromagnetic interactions between Cu(II) and M(V) through the CN linkage coexist.
authors.affiliation: Department of Chemistry, Korea University, Seoul.
authors.forename: Young Sin
authors.initials: YS
authors.lastname: You
authors.forename: Jung Hee
authors.initials: JH
authors.lastname: Yoon
authors.forename: Jeong Hak
authors.initials: JH
authors.lastname: Lim
authors.forename: Hyoung Chan
authors.initials: HC
authors.lastname: Kim
authors.forename: Chang Seop
authors.initials: CS
authors.lastname: Hong