Selective nucleation and growth of metal-organic open framework thin films on patterned COOH/CF3-terminated self-assembled monolayers on Au(111).
Metal-Organic open Framework coordination polymers (MOFs) are a fascinating class of materials. We demonstrate the selective growth of patterned thin films of MOF-5 and the subsequent loading with a palladium organic compound, which acts as a precursor for the deposition of palladium nanoclusters inside the cavities of the MOF-5 material.
Hermes
Stephan
S
Anorganische Chemie II, Organometallics and Materials Chemistry, Ruhr-Universität Bochum, D-44870 Bochum, Germany.
Schröder
Felicitas
F
Chelmowski
Rolf
R
Wöll
Christof
C
Fischer
Roland A
RA
D006046:Gold / Q000737:chemistry*; D008567:Membranes, Artificial; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D010316:Particle Size; D013499:Surface Properties
D008567:Membranes, Artificial; D009942:Organometallic Compounds; D006046:Gold