Deracemization of quaternary stereocenters by Pd-catalyzed enantioconvergent decarboxylative allylation of racemic beta-ketoesters.
Mohr
Justin T
JT
The Arnold and Mabel Beckman Laboratories of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, 1200 E. California Boulevard, MC 164-30, Pasadena, CA 91125, USA.
Behenna
Douglas C
DC
Harned
Andrew M
AM
Stoltz
Brian M
BM
D000478:Alkylation; D002384:Catalysis; D003653:Decarboxylation; D004952:Esters / Q000138:chemical synthesis*; D007659:Ketones / Q000138:chemical synthesis*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
D004952:Esters; D007659:Ketones; D009942:Organometallic Compounds; D010165:Palladium