title: Direction of topological isomers of silver(I) coordination polymers induced by solvent, and selective anion-exchange of a class of PtS-type host frameworks.
abstract: The construction of two types of coordination polymers with closely related 4-connected topologies [PtS and lvt (4(2).8(4))] were achieved based on a well-designed bent dipyrazine linker, and the topological differences only result from the stereochemistry of silver(I) coordination sphere with the same coordination donors. Selective anion-exchange functions of the series of PtS-type coordination networks containing different counter anions (from small BF4- to very large SbF6-) were identified.
authors.affiliation: College of Chemistry and Life Science, Tianjin Normal University, PR. China. dumiao@public.tpt.tj.cn
authors.forename: Miao
authors.initials: M
authors.lastname: Du
authors.forename: Xiao-Jun
authors.initials: XJ
authors.lastname: Zhao
authors.forename: Jian-Hua
authors.initials: JH
authors.lastname: Guo
authors.forename: Stuart R
authors.initials: SR
authors.lastname: Batten