Hydrogen-bonded self-assemblies in a polychlorotriphenylmethyl radical derivative substituted with six meta-carboxylic acid groups.
The synthesis, self assembly and magnetic properties of a polychlorotriphenylmethyl radical, substituted with six meta-carboxylic groups, are reported showing that radical-radical hydrogen bonds in the solid state yield to very weak intermolecular ferromagnetic interactions.
Roques
Nans
N
Institut de Ciència de Materials de Barcelona (CSIC), Campus Universitari, Bellaterra, Catalonia, Spain.
Maspoch
Daniel
D
Domingo
Neus
N
Ruiz-Molina
Daniel
D
Wurst
Klaus
K
Tejada
Javier
J
Rovira
Concepció
C
Veciana
Jaume
J
D002264:Carboxylic Acids / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005609:Free Radicals / Q000138:chemical synthesis / Q000737:chemistry; D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis* / Q000737:chemistry*; D006860:Hydrogen Bonding; D008280:Magnetics; D008958:Models, Molecular; D015394:Molecular Structure; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry*; D013696:Temperature
D002264:Carboxylic Acids; D005609:Free Radicals; D006841:Hydrocarbons, Aromatic; D011108:Polymers