Direction of topological isomers of silver(I) coordination polymers induced by solvent, and selective anion-exchange of a class of PtS-type host frameworks.
The construction of two types of coordination polymers with closely related 4-connected topologies [PtS and lvt (4(2).8(4))] were achieved based on a well-designed bent dipyrazine linker, and the topological differences only result from the stereochemistry of silver(I) coordination sphere with the same coordination donors. Selective anion-exchange functions of the series of PtS-type coordination networks containing different counter anions (from small BF4- to very large SbF6-) were identified.
Du
Miao
M
College of Chemistry and Life Science, Tianjin Normal University, PR. China. dumiao@public.tpt.tj.cn
Zhao
Xiao-Jun
XJ
Guo
Jian-Hua
JH
Batten
Stuart R
SR