Surprising reactions of a 2H-azaphosphirene complex with a silylene.
Reaction of the 2H-azaphosphirene complex with the silylene yielded the bicyclic carbene complex as sole product at ambient temperature; the reaction was less selective at elevated temperatures; additionally, the synthesis and structure of the first 1,2,4,3-azadiphosphasilol-5-ene complex is presented.
Ionescu
Emanuel
E
Institut für Anorganische Chemie, Rheinische Friedrich-Wilhelms-Universität Bonn, Germany.
Gehrhus
Barbara
B
Hitchcock
Peter B
PB
Nieger
Martin
M
Streubel
Rainer
R
D000475:Alkenes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D017655:Silicon Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D014414:Tungsten / Q000737:chemistry*
D000475:Alkenes; D009942:Organometallic Compounds; D017655:Silicon Compounds; D014414:Tungsten