title: Chiral 1,2- and 1,3-diol-functionalized chromophores as Lego building blocks for coupled structures.
abstract: Chiral nitroanilines containing 1,2- or 1,3-diol functionalities have been synthesized by nucleophilic aromatic substitution of fluoronitroanilines with 1-aminopropane-2,3-diols and 2-aminopropane-1,3-diol in the melt. X-ray structure analyses confirm retention of the configuration of the chiral center. The novel chromophores are suitable to link reversibly to various substituted arylboronic acids which allows the construction of new solvatochromic sensor molecules suitable to response to solvent and anion coordination by fluoride. The solvatochromism of the new compounds has been studied using the Kamlet-Taft LSE relationship.
authors.affiliation: Department of Polymer Chemistry, Institute of Chemistry, Chemnitz University of Technology, 09111 Chemnitz, Germany. stefan.spange@chemie.tu-chemnitz.de
authors.forename: Stefan
authors.initials: S
authors.lastname: Spange
authors.forename: Katja
authors.initials: K
authors.lastname: Hofmann
authors.forename: Bernhard
authors.initials: B
authors.lastname: Walfort
authors.forename: Tobias
authors.initials: T
authors.lastname: Rüffer
authors.forename: Heinrich
authors.initials: H
authors.lastname: Lang