An expeditious synthesis of tailed tren-capped porphyrins.
[structure: see text] A one-pot two-step versatile synthesis of tailed tren-capped porphyrins has been achieved. The two resulting ligands demonstrate that this expeditious method can be applied to various axial bases to obtain highly functionalized macromolecules attractive for heme modeling purposes. Dioxygen binding of the pyridine-tailed iron complex is reported as a direct application.
Even
Pascale
P
Université de Rennes1, Institut de Chimie, UMR CNRS 6509, Organométalliques et catalyse, 35042 Rennes Cedex, France.
Ruzié
Christian
C
Ricard
David
D
Boitrel
Bernard
B
D002248:Carbon Monoxide / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D010100:Oxygen / Q000737:chemistry; D011166:Porphyrins / Q000138:chemical synthesis / Q000737:chemistry*
D011166:Porphyrins; D002248:Carbon Monoxide; D010100:Oxygen