One-dimensional coordination polymers containing penta-supertetrahedral sulfide clusters linked by dipyridyl ligands.
Three new one-dimensional coordination polymers [Zn8S(SC6H5)14.C12H10N2](1), [Zn7CoS(SC6H5)14.C13H14N2](2) and [Zn8S(SC6H5)14.C13H14N2](3) have been prepared containing penta-supertetrahedral clusters and linear crosslinking dipyridyl ligands; the two complexes show optical transitions with band gaps of approximately 3.44 eV (1) and approximately 3.54 eV (2).
Xie
Jingli
J
Department of Chemistry, University of California, Riverside, CA 92521, USA.
Bu
Xianhui
X
Zheng
Nanfeng
N
Feng
Pingyun
P
D008024:Ligands; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D013057:Spectrum Analysis; D013440:Sulfides / Q000737:chemistry*
D008024:Ligands; D011108:Polymers; D011725:Pyridines; D013440:Sulfides; C023666:pyridine