title: The folded, tetrameric phosph(III)azane macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4.
abstract: The tetrameric macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4, obtained from the reaction of the phosphazane dimer [ClP(mu-NtBu)]2 with p-phenylenediamine, has an unusual folded conformation in the solid state and contains a roughly tetrahedral arrangement of endo N-H groups for the potential coordination of anions.
authors.affiliation: Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UK.
authors.forename: Fay
authors.initials: F
authors.lastname: Dodds
authors.forename: Felipe
authors.initials: F
authors.lastname: García
authors.forename: Richard A
authors.initials: RA
authors.lastname: Kowenicki
authors.forename: Mary
authors.initials: M
authors.lastname: McPartlin
authors.forename: Lucía
authors.initials: L
authors.lastname: Riera
authors.forename: Alexander
authors.initials: A
authors.lastname: Steiner
authors.forename: Dominic S
authors.initials: DS
authors.lastname: Wright
mesh_terms: D001388:Aziridines / Q000737:chemistry*; D003432:Cross-Linking Reagents / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry; D047028:Macrocyclic Compounds / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry
chemical_list: D001388:Aziridines; D003432:Cross-Linking Reagents; D047028:Macrocyclic Compounds; D006859:Hydrogen; D009584:Nitrogen