title: Degradation of polychlorinated dibenzo-p-dioxins in aqueous solution by Fe(II)/H2O2/UV system.
abstract: The photodegradation of polychlorinated dibenzo-p-dioxins (PCDDs), which include tetra- to octa-CDDs (TeCDD, PeCDD, HxCDD, HpCDD and OCDD), was carried out in the presence of Fe(II) and H2O2 mixed reagent. The degradation efficiency was strongly influenced by UV irradiation, and the initial concentrations of H2O2 and Fe(II). An initial TeCDD concentration of 10 ng l(-1) was completely degraded within 20 min under the optimum conditions. All PCDDs tested were successfully degraded by Fe(II)/H2O2/UV treatment and complete degradation of TeCDD, PeCDD and HxCDD was achieved within 120 min. PCDD photodegradation rates decreased with the number of chlorine atoms. The degradation process of TeCDD by this system seems to be initiated by an oxidative reaction (OH* radical attack) because less chlorinated DDs as intermediate products were not detected. From the Frontier electron density calculation, the first OH* radical attack positions on TeCDD were found to be four C atoms neighboring two O atoms. The decomposition of TeCDD gave 4,5-dichlorocatechol as an intermediate product. A TeCDD degradation scheme was proposed based on the identified intermediate and the values of Frontier electron density. Based on these results, Fe(II)/H2O2/UV system could be useful technology for the treatment of wastewater containing persistent pollutants such as dioxins and polychlorinated biphenyls.
authors.affiliation: Sattelite Venture Business Laboratory, Mie University, Tsu, Mie 514-8507, Japan. hidek@chem.mie-u.ac.jp
authors.forename: Hideyuki
authors.initials: H
authors.lastname: Katsumata
authors.forename: Satoshi
authors.initials: S
authors.lastname: Kaneco
authors.forename: Tohru
authors.initials: T
authors.lastname: Suzuki
authors.forename: Kiyohisa
authors.initials: K
authors.lastname: Ohta
authors.forename: Yoshihiro
authors.initials: Y
authors.lastname: Yobiko
mesh_terms: D008401:Gas Chromatography-Mass Spectrometry; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D010777:Photochemistry / Q000379:methods*; D000072317:Polychlorinated Dibenzodioxins / Q000031:analogs & derivatives / Q000737:chemistry*; D014466:Ultraviolet Rays; D014874:Water Pollutants, Chemical
chemical_list: D000072317:Polychlorinated Dibenzodioxins; D014874:Water Pollutants, Chemical; D006861:Hydrogen Peroxide; D007501:Iron; C018117:octachlorodibenzo-4-dioxin