Substituent effects on the structure and supramolecular assembly of bis(dioxaborole)s.
Solid-state and solution analysis shows that dialkyl substituents on the central phenyl ring of bis(dioxaborole)s, such as , do not have an appreciable effect on the planarity but do significantly alter the supramolecular assembly of these compounds.
Niu
Weijun
W
Department of Chemistry & Biochemistry, 631 Sumter Street, University of South Carolina, Columbia, SC 29208, USA.
Rambo
Brett
B
Smith
Mark D
MD
Lavigne
John J
JJ
D001881:Borates / Q000138:chemical synthesis / Q000737:chemistry; D018360:Crystallography, X-Ray; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry; D013237:Stereoisomerism
D001881:Borates; D046911:Macromolecular Substances; D011108:Polymers; C516858:poly(dioxaborole)