Crystalline Na-Si(NN) derivatives [Si(NN)= Si((NCH2tBu)2C6H4-1,2)]: the silylenoid [Si(NN)OMe]-, the dianion [(NN)Si-Si(NN)]2-, and the radical anion c-[Si(NN)]3-.
Reactions of the silylene Si[(NCH2Bu(t))2C6H4-1,2], [Si(NN)], with NaOMe, excess Na or 1/3 Na yield the X-ray-characterised crystalline compounds [Na(micro-Si(NN)OMe)(THF)(OEt2)]2 (2b), [Na(THF)2Si(NN)]2 (3) and [Na(THF)4][(Si(NN))3-c] (4).
Antolini
Floria
F
Department of Chemistry, School of Life Sciences, University of Sussex, Brighton, UK.
Gehrhus
Barbara
B
Hitchcock
Peter B
PB
Lappert
Michael F
MF
D000838:Anions / Q000737:chemistry*; D003460:Crystallization; D018360:Crystallography, X-Ray; D004578:Electron Spin Resonance Spectroscopy; D005609:Free Radicals / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D017646:Organosilicon Compounds / Q000737:chemistry*; D012828:Silicones / Q000737:chemistry*; D012964:Sodium / Q000737:chemistry*
D000838:Anions; D005609:Free Radicals; D017646:Organosilicon Compounds; D012828:Silicones; D012964:Sodium