title: Experimental quantification of cavitation yield revisited: focus on high frequency ultrasound reactors.
abstract: Acoustic cavitation plays an important role in enhancing the reaction rate of chemical processes in sonochemical systems. However, quantification of cavitation intensity in sonochemical systems is generally limited to low frequency systems. In this study, an empirical determination of cavitation yield in high frequency ultrasound systems was performed by measuring the amount of iodine liberated from the oxidation of potassium iodide (KI) solution at 1.7 and 2.4 MHz. Experiments for determining cavitation were carried out at various solute (KI) concentrations under constant temperature, obtained by direct cooling of the solution and variable temperature conditions, in the absence of external cooling. Cavitation yield measurements, reported in this work, extend previously reported results and lend credence to the two step reaction pathway in high frequency systems. Additionally, the concentration of KI and temperature affect the cavitation yield of a system such that the iodine production is proportional to both conditions. It is proposed that direct cooling of sonicated KI solution may be advantageous for optimization of cavitation intensity in high frequency sonochemical reactors.
authors.affiliation: Institute for Chemical Process and Environmental Technology, National Research Council of Canada, M-12 Montreal Road, Ottawa, ON, Canada K1A 0R6. deepak.kirpalani@nrc.ca
authors.forename: D M
authors.initials: DM
authors.lastname: Kirpalani
authors.forename: K J
authors.initials: KJ
authors.lastname: McQuinn
mesh_terms: D005591:Chemical Fractionation / Q000379:methods*; D002617:Chemical Industry / Q000295:instrumentation / Q000379:methods; D045424:Complex Mixtures / Q000737:chemistry / Q000528:radiation effects; D004307:Dose-Response Relationship, Radiation; D007455:Iodine / Q000032:analysis / Q000737:chemistry* / Q000528:radiation effects*; D011193:Potassium Iodide / Q000032:analysis / Q000737:chemistry* / Q000528:radiation effects*; D011829:Radiation Dosage; D011846:Radio Waves; D013010:Sonication; D014618:Vacuum
chemical_list: D045424:Complex Mixtures; D011193:Potassium Iodide; D007455:Iodine