title: Influence of hydrology on heavy metal speciation and mobility in a Pb-Zn mine tailing.
abstract: Among the inorganic toxicants of greatest concern in mine tailings, Pb, Zn, Cu, Cd and As figure prominently due to their abundance and potential toxicity. Here we report on their biolability and solid-phase speciation in two sediment cores subject to variable hydrological regimes at an abandoned pyritic mine tailing. The oxic conditions of well-drained sediments induced pyrite oxidation and the subsequent liberation of H+, SO4(2-) and considerable quantities of Fe(III), which precipitated as goethite. Solubility of Pb, Zn, Cu and Cd was closely coupled to pH and goethite presence. Metal lability was particularly low in zones of neutralization, formed by the accumulation of calcite, first carried then deposited by percolating waters in both saturated and unsaturated cores. We conclude that differential hydrology induces variable heavy metal speciation and biolability in Pb-Zn mine tailings, and suggest that site-specific risk assessments must account for past and present hydrological regimes.
authors.affiliation: Department of Water and Environmental Management, Center of Agricultural Sciences, University of Debrecen, H-4015 Debrecen, P.O. Box 10, Hungary. ekovacs@gisserver1.date.hu
authors.forename: Elza
authors.initials: E
authors.lastname: Kovács
authors.forename: William E
authors.initials: WE
authors.lastname: Dubbin
authors.forename: János
authors.initials: J
authors.lastname: Tamás
mesh_terms: D001682:Biological Availability; D002104:Cadmium / Q000032:analysis; D002119:Calcium Carbonate / Q000032:analysis; D003300:Copper / Q000032:analysis; D004553:Electric Conductivity; D004785:Environmental Pollutants / Q000032:analysis*; D019015:Geologic Sediments / Q000032:analysis*; D006863:Hydrogen-Ion Concentration; D007501:Iron / Q000032:analysis; D058085:Iron Compounds / Q000032:analysis; D007854:Lead / Q000032:analysis; D019216:Metals, Heavy / Q000032:analysis*; D008903:Minerals; D008906:Mining; D010084:Oxidation-Reduction; D010316:Particle Size; D012995:Solubility; D013440:Sulfides; D014867:Water / Q000737:chemistry*; D015032:Zinc / Q000032:analysis
chemical_list: D004785:Environmental Pollutants; D058085:Iron Compounds; D019216:Metals, Heavy; D008903:Minerals; D013440:Sulfides; D002104:Cadmium; D014867:Water; C094886:goethite; C011342:pyrite; D007854:Lead; D003300:Copper; D007501:Iron; D002119:Calcium Carbonate; D015032:Zinc