Scaling behavior for the pressure and energy of shearing fluids.
Recent simulation work has established that the widely accepted mode-coupling theory for the strain rate dependence of the pressure and energy of simple fluids under shear (i.e., energy and pressure are functions of strain rate to the power 3 / 2) is observed in the vicinity of the triple point. Away from the triple point, the scaling exponent of the strain rate was seen to be closer to 2 than 3 / 2, suggesting a possible analytic behavior. In this paper, we accurately determine the scaling exponent behavior for a Lennard-Jones fluid in the dense fliud region and find that it varies continuously between approximately 1.2 and approximately 2 as a function of density and temperature, thus confirming its nonanalyticity. We furthermore find that the behavior is characterized by a simple linear function of density and temperature.
Ge
Jialin
J
Centre for Molecular Simulation, Swinburne University of Technology, Hawthorn, Victoria, Australia.
Todd
B D
BD
Wu
Guangwen
G
Sadus
Richard J
RJ