Triazole-based monophosphines for Suzuki-Miyaura coupling and amination reactions of aryl chlorides.
[reaction: see text] A new class of triazole-based monophosphine 1 (ClickPhos) has been prepared via efficient 1,3-dipolar cycloadditions of readily available azides and acetylenes. Palladium complexes derived from these ligands provide highly active catalysts for Suzuki-Miyaura coupling and amination reactions of aryl chlorides.
Liu
Duan
D
Department of Chemistry, Pennsylvania State University, University Park, 16802, USA.
Gao
Wenzhong
W
Dai
Qian
Q
Zhang
Xumu
X