title: Chiral analysis of pollutants and their metabolites by capillary electromigration methods.
abstract: Chiral separation of enantiomers is one of the most challenging tasks for any analytical technique including CE. Since the first report in 1985 showing the great possibilities of CE for the separation of chiral compounds, the amount of publications concerning this topic has quickly increased. Although chiral electromigration methods have mainly been used for enantioseparation of drugs and pharmaceuticals, they have also been applied to analyze chiral pollutants. This article intends to provide an updated overview, including works published till January 2005, on the principal applications of CE to the chiral analysis of pollutants and their metabolites, with special emphasis on articles published in the last 10 years. The main advantages and drawbacks regarding the use of CE for chiral separation of pollutants are addressed including some discussion on the foreseen trends of electromigration procedures applied to chiral analysis of contaminants.
authors.affiliation: Department of Analytical Chemistry, Nutrition and Food Science, University of La Laguna, La Laguna, Tenerife, Spain.
authors.forename: Javier
authors.initials: J
authors.lastname: Hernández-Borges
authors.forename: Miguel Angel
authors.initials: MA
authors.lastname: Rodríguez-Delgado
authors.forename: Francisco J
authors.initials: FJ
authors.lastname: García-Montelongo
authors.forename: Alejandro
authors.initials: A
authors.lastname: Cifuentes
mesh_terms: D020374:Chromatography, Micellar Electrokinetic Capillary / Q000379:methods; D019075:Electrophoresis, Capillary / Q000379:methods*; D004785:Environmental Pollutants / Q000302:isolation & purification*; D010575:Pesticides / Q000302:isolation & purification; D013237:Stereoisomerism
chemical_list: D004785:Environmental Pollutants; D010575:Pesticides