title: A missing allene of heavy Group 14 elements: 2-germadisilaallene.
abstract: The first stable 2-germadisilaallene was synthesized by the reduction of a 2 ratio 1 mixture of a stable dialkylsilylene and dichlorogermylene-dioxane complex with KC8; the 2-germadisilaallene showed dynamic disorder similar to the corresponding trisilaallene in the solid state.
authors.affiliation: Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
authors.forename: Takeaki
authors.initials: T
authors.lastname: Iwamoto
authors.forename: Takashi
authors.initials: T
authors.lastname: Abe
authors.forename: Chizuko
authors.initials: C
authors.lastname: Kabuto
authors.forename: Mitsuo
authors.initials: M
authors.lastname: Kira
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005857:Germanium / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012825:Silicon / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000466:Alkadienes; D009942:Organometallic Compounds; D005857:Germanium; C025947:propadiene; D012825:Silicon