Design and construction of a 2D metal organic framework with multiple cavities: a nonregular net with a paracyclophane that codes for multiply fused nodes.
A metal organic framework with two different nodes (circle and square) and a structure related to one of the 20 known 2-uniform nets has been constructed using an organic building unit that codes for multiply fused nodes.
Papaefstathiou
Giannis S
GS
Department of Chemistry, University of Iowa, Iowa City, IA 52242-1294, USA.
Friscić
Tomislav
T
MacGillivray
Leonard R
LR
D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003503:Cyclobutanes / Q000737:chemistry*; D006860:Hydrogen Bonding; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D011083:Polycyclic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D016062:Porosity
D003503:Cyclobutanes; D009942:Organometallic Compounds; D011083:Polycyclic Compounds; D003035:Cobalt