title: Substituted m-phenylene bridges as strong ferromagnetic couplers for Cu(II)-bridge-Cu(II) magnetic interactions: new perspectives.
abstract: Based on a combined theoretical-experimental study, we propose that substituted m-phenylene ligands (m-N-Phi-N) can act as tuneable strong ferromagnetic couplers connecting Cu(II) ions; a new complex presenting that bridge with J close to +15 cm(-1) has been suggested and synthesized.
authors.affiliation: Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India.
authors.forename: Alok Ranjan
authors.initials: AR
authors.lastname: Paital
authors.forename: Tamoghna
authors.initials: T
authors.lastname: Mitra
authors.forename: Debashis
authors.initials: D
authors.lastname: Ray
authors.forename: Wing Tak
authors.initials: WT
authors.lastname: Wong
authors.forename: Jordi
authors.initials: J
authors.lastname: Ribas-Ariño
authors.forename: Juan J
authors.initials: JJ
authors.lastname: Novoa
authors.forename: Joan
authors.initials: J
authors.lastname: Ribas
authors.forename: Guillem
authors.initials: G
authors.lastname: Aromí
mesh_terms: D003300:Copper / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D008956:Models, Chemical; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010655:Phenylenediamines / Q000737:chemistry*; D011789:Quantum Theory; D013237:Stereoisomerism; D013696:Temperature
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D010655:Phenylenediamines; D003300:Copper; C008381:3-phenylenediamine