Narrow pore-diameter polypyrrole nanotubes.
Bulk quantities of electrically conducting nanotubes of polypyrrole having narrow pore diameter (6 nm) can be synthesized rapidly by chemical oxidative polymerization of pyrrole in the presence of stoichiometric amounts of V2O5 nanofibers. The V2O5 nanofibers act as templates for polymerization and yield, as the initial product, polypyrrole nanotubes with pores filled with V2O5. The V2O5 dissolves readily in aq. 1.0 M HCl, yielding hollow polypyrrole nanotubes having conductivity of approximately 2 S/cm. As-synthesized polypyrrole nanotubes spontaneously reduce noble metal ions to the corresponding metal nanoparticles at room temperature without any capping or dispersing agents. For example, 3-5 nm size nanoparticles of Ag, Au, and Pd, etc., deposit readily on the surface of the tubes which then migrate spontaneously to the pore, and, in the case of Ag, coalesce in the core, yielding 4-8 nm diameter coaxial cables of Ag surrounded by a 20-30 nm thick polypyrrole fiber sheath.
Zhang
Xinyu
X
Alan G. MacDiarmid Center for Innovation, Department of Chemistry, The University of Texas at Dallas, Richardson, TX 75080, USA.
Manohar
Sanjeev K
SK
D002712:Chlorides; D005290:Ferric Compounds / Q000737:chemistry; D043942:Nanotubes / Q000737:chemistry*; D010084:Oxidation-Reduction; D010316:Particle Size; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D016062:Porosity; D011758:Pyrroles / Q000138:chemical synthesis* / Q000737:chemistry; D013499:Surface Properties; D017968:Vanadium Compounds / Q000737:chemistry
D002712:Chlorides; D005290:Ferric Compounds; D011108:Polymers; D011758:Pyrroles; D017968:Vanadium Compounds; C067635:polypyrrole; C066075:vanadium pentoxide; C024555:ferric chloride