Diffusion in a generalized Rubinstein-Duke model of electrophoresis with kinematic disorder.
Using a generalized Rubinstein-Duke model, we prove rigorously that kinematic disorder leaves the prediction of the standard reptation theory for the scaling of the diffusion constant in the limit for long polymer chains D proportional to L(-2) unaffected. Based on an analytical calculation as well as on Monte Carlo simulations, we predict kinematic disorder to affect the center-of-mass diffusion constant of an entangled polymer in the limit for long chains by the same factor as single particle diffusion in a random barrier model.
Willmann
Richard D
RD
Institut für Festkörperforschung, Forschungszentrum Jülich, Germany. r.willmann@fz-juelich.de
Schütz
Gunter M
GM
Jain
Kavita
K