Chemo-, regio-, and stereoselective cobalt-mediated [2+2+2] cycloaddition of alkynyl boronates to alkenes: 1,3- and 1,4-diboryl-1,3-cyclohexadienes.
Gandon
Vincent
V
Université Pierre et Marie Curie, Institut de Chimie Moléculaire-FR2769, Laboratoire de Chimie Organique -UMR 7611, Paris, France.
Leboeuf
David
D
Amslinger
Sabine
S
Vollhardt
K Peter C
KP
Malacria
Max
M
Aubert
Corinne
C
D000480:Alkynes / Q000737:chemistry*; D001896:Boron Compounds / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003500:Cyclization; D003510:Cyclohexanes / Q000138:chemical synthesis* / Q000737:chemistry; D053138:Cyclohexenes; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D000480:Alkynes; D001896:Boron Compounds; D003510:Cyclohexanes; D053138:Cyclohexenes; D009942:Organometallic Compounds; D003035:Cobalt; C034005:1,3-cyclohexadiene