Glycosyl trichloroacetylcarbamate: a new glycosyl donor for O-glycosylation.
Glycosyl trichloroacetylcarbamates, readily obtained by reacting 1-hydroxy sugars with trichloroacetylisocyanate, have been found as excellent glycosyl donors, and the corresponding O-glycosides are formed in good to excellent yields with a fairly good degree of selectivity.
Jayakanthan
K
K
Department of Chemistry, Indian Institute of Technology, Kanpur 208 016, India.
Vankar
Yashwant D
YD
D002219:Carbamates / Q000737:chemistry*; D002236:Carbohydrate Conformation; D006027:Glycosides / Q000138:chemical synthesis* / Q000737:chemistry*; D006031:Glycosylation; D007202:Indicators and Reagents; D007700:Kinetics; D008958:Models, Molecular; D013402:Sugar Alcohols / Q000737:chemistry*
D002219:Carbamates; D006027:Glycosides; D007202:Indicators and Reagents; D013402:Sugar Alcohols