title: New mono- and bis-carbene samarium complexes: synthesis, X-ray crystal structures and reactivity.
abstract: New samarium carbene complexes have been synthesized and characterized by X-ray diffraction analysis; the carbenic nature was assessed by reactivity studies.
authors.affiliation: Laboratoire 'Hétéroéléments et Coordination' UMR CNRS 7653 (DCPH), Département de Chimie, Ecole Polytechnique, 91128, Palaiseau cedex, France.
authors.forename: Thibault
authors.initials: T
authors.lastname: Cantat
authors.forename: Florian
authors.initials: F
authors.lastname: Jaroschik
authors.forename: François
authors.initials: F
authors.lastname: Nief
authors.forename: Louis
authors.initials: L
authors.lastname: Ricard
authors.forename: Nicolas
authors.initials: N
authors.lastname: Mézailles
authors.forename: Pascal
authors.initials: P
authors.lastname: Le Floch
mesh_terms: D018360:Crystallography, X-Ray; D006838:Hydrocarbons / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D012493:Samarium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D006838:Hydrocarbons; D009942:Organometallic Compounds; C030011:carbene; D012493:Samarium; D008697:Methane