Temperature- or guest-induced drastic single-crystal-to-single-crystal transformations of a nanoporous coordination polymer.
Aside from a temperature-induced structural transformation, a new nanoporous coordination polymer [Ag6Cl(atz)4].OH.6H2O (Hatz = 3-amino-1,2,4,-triazole) comprised of interpenetrated Ag3(atz)2 coordination nets exhibits a single-crystal-to-single-crystal transformation of a 5-fold to 6-fold net interpenetration change triggered by guest desorption/absorption.
Zhang
Jie-Peng
JP
State Key Laboratory of Photoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, P. R. China.
Lin
Yan-Yong
YY
Zhang
Wei-Xiong
WX
Chen
Xiao-Ming
XM
D003460:Crystallization; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D049329:Nanostructures / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D012834:Silver / Q000737:chemistry; D013696:Temperature
D009942:Organometallic Compounds; D011108:Polymers; D012834:Silver