[Spectral study of N2O under pulsed DC discharge].
A new equipment of pulsed DC discharge supersonic molecular beam was set up for producing transient species. Thepulsed DC discharge can be used stably under 10 kV. In data collection using software, it can be utilized as gated integrators and averagers. Using this equipment, the processes of N2O discharge were studied. The emission spectra of N2O+ (A2sigma+ - X2IIi) were obtained. From the intensity of vibrational spectra, the vibrational populations of the N2O+ (A2sigma+ ) states were calculated. Compared with other results, A states of N2O+ depart even more from a Boltzmann distribution.
Zhang
Xian-yi
XY
Laboratory of Environmental Spectroscopy, Anhui Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Hefei 230031, China.
Kan
Rui-feng
RF
Kong
Xiang-lei
XL
Luo
Xiao-lin
XL
Zhng
Wei
W
Li
Hai-yang
HY
D000465:Algorithms; D055664:Electrochemical Techniques / Q000295:instrumentation / Q000379:methods*; D009609:Nitrous Oxide / Q000737:chemistry*; D012984:Software; D013050:Spectrometry, Fluorescence / Q000295:instrumentation / Q000379:methods*
D009609:Nitrous Oxide