title: Generation effects on the microstructure and product distribution in ethylene polymerization promoted by dendritic nickel catalysts.
abstract: Carbosilane dendrimers Gn-[(ONNMe2)NiBr2]m, containing up to sixteen terminal pyridylimine nickel complexes, have been studied as catalysts for polymerization of ethylene; the microstructure and the oligomer/polymer distribution are significantly affected by the generation of the dendritic precursor.
authors.affiliation: Departamento de Química Inorgánica, Universidad de Alcalá, Campus Universitario, 28871, Alcalá de Henares, Madrid, Spain.
authors.forename: José M
authors.initials: JM
authors.lastname: Benito
authors.forename: Ernesto
authors.initials: E
authors.lastname: de Jesús
authors.forename: F Javier
authors.initials: FJ
authors.lastname: de la Mata
authors.forename: Juan C
authors.initials: JC
authors.lastname: Flores
authors.forename: Rafael
authors.initials: R
authors.lastname: Gómez