Silver-catalyzed imination of sulfoxides and sulfides.
[reaction: see text] Silver salts in the presence of a chelating ligand efficiently catalyze the stereospecific imination of sulfoxides and sulfides with sulfonylamides and PhI(OAc)(2) to afford sulfoximines and sulfilimines, respectively, in good yields.
Cho
Gae Young
GY
Institute of Organic Chemistry, RWTH Aachen University, Germany.
Bolm
Carsten
C