title: Production of oxidants by ion irradiation of water/carbon dioxide frozen mixtures.
abstract: We present new experimental results on the formation of oxidants, such as hydrogen peroxide, ozone, and carbonic acid, under ion irradiation of icy mixtures of water/carbon dioxide at different ratios and temperatures (16 and 80 K). Pure water ice layers and mixtures with carbon dioxide were irradiated by 200 keV He+ ions. We found that the CO(2)/H(2)O ratio progressively decreased to a value of about 0.1, the H(2)O(2) production increased with increasing CO(2) abundance at both 16 and 80 K, and the CO and H(2)CO(3) production increased with increasing CO(2) abundance at 16 K. At 80 K, the synthesis of CO was less efficient because of the high volatility of the molecule that partially sublimed from the target. The production of carbonic acid was connected with the production of CO(3). O(3) was detected only after ion irradiation of CO(2)-rich mixtures. The experimental results are discussed with regard to the relevance they may have in the production of an energy source for a europan or a martian biosphere.
authors.affiliation: INAF-Osservatorio Astrofisico, Via S. Sofia 78, I-95123 Catania, Italy. gianni@oact.inaf.it
authors.forename: G
authors.initials: G
authors.lastname: Strazzulla
authors.forename: G
authors.initials: G
authors.lastname: Leto
authors.forename: F
authors.initials: F
authors.lastname: Spinella
authors.forename: O
authors.initials: O
authors.lastname: Gomis
mesh_terms: D002255:Carbonic Acid / Q000138:chemical synthesis / Q000737:chemistry; D004367:Dry Ice; D006371:Helium; D006861:Hydrogen Peroxide / Q000138:chemical synthesis / Q000737:chemistry; D007053:Ice; D016877:Oxidants / Q000138:chemical synthesis* / Q000737:chemistry; D010126:Ozone / Q000138:chemical synthesis / Q000737:chemistry; D011827:Radiation; D013055:Spectrophotometry, Infrared; D013696:Temperature
chemical_list: D004367:Dry Ice; D007053:Ice; D016877:Oxidants; D006371:Helium; D002255:Carbonic Acid; D010126:Ozone; D006861:Hydrogen Peroxide