Substituted m-phenylene bridges as strong ferromagnetic couplers for Cu(II)-bridge-Cu(II) magnetic interactions: new perspectives.
Based on a combined theoretical-experimental study, we propose that substituted m-phenylene ligands (m-N-Phi-N) can act as tuneable strong ferromagnetic couplers connecting Cu(II) ions; a new complex presenting that bridge with J close to +15 cm(-1) has been suggested and synthesized.
Paital
Alok Ranjan
AR
Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India.
Mitra
Tamoghna
T
Ray
Debashis
D
Wong
Wing Tak
WT
Ribas-Ariño
Jordi
J
Novoa
Juan J
JJ
Ribas
Joan
J
Aromí
Guillem
G
D003300:Copper / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D008956:Models, Chemical; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010655:Phenylenediamines / Q000737:chemistry*; D011789:Quantum Theory; D013237:Stereoisomerism; D013696:Temperature
D008024:Ligands; D009942:Organometallic Compounds; D010655:Phenylenediamines; D003300:Copper; C008381:3-phenylenediamine