A diiron center stabilized by a bis-TPA ligand as a model of soluble methane monooxygenase: predominant alkene epoxidation with H2O2.
Kodera
Masahito
M
Department of Molecular Science and Technology, Faculty of Engineering, Doshisha University, Kyotanabe, Kyoto 610-0321, Japan. mkodera@mail.doshisha.ac.jp
Itoh
Motoharu
M
Kano
Koji
K
Funabiki
Takuzo
T
Reglier
Marius
M
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D018360:Crystallography, X-Ray; D004852:Epoxy Compounds / Q000737:chemistry*; D004980:Ethane / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry; D005290:Ferric Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D006861:Hydrogen Peroxide / Q000737:chemistry; D008024:Ligands; D008956:Models, Chemical; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010105:Oxygenases / Q000737:chemistry*; D011725:Pyridines / Q000138:chemical synthesis / Q000737:chemistry*
C513863:1,2-bis(2-(bis(2-pyridylmethyl)amino-methyl)-6-pyridyl)ethane; D000475:Alkenes; D004852:Epoxy Compounds; D005290:Ferric Compounds; D008024:Ligands; D011725:Pyridines; C431843:tris(2-pyridylmethyl)amine; D006861:Hydrogen Peroxide; D010105:Oxygenases; C021555:methane monooxygenase; D004980:Ethane