instant "base-promoted" generation of roper's-type Ru(0) complexes Ru(CO)2(PR3)3 from a simple carbonylchlororuthenium(II) precursor.
An uncommon synergism in the concerted action of OH- and PR3 toward the simple Ru(II) complex Ru(CO)3Cl2(thf) allows a highly efficient reduction of the metal in ethanol or acetonitrile solution at 0 degrees C, with selective production of the corresponding Roper's-type Ru(0) complexes Ru(CO)2(PR3)3 in high yields within 10 min.
Sentets
Stephane
S
Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France.
Rodriguez Martinez
Maria del Carmen
Mdel C
Vendier
Laure
L
Donnadieu
Bruno
B
Huc
Vincent
V
Lugan
Noël
N
Lavigne
Guy
G
D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry*
D009942:Organometallic Compounds; D012428:Ruthenium