The first A2B2-heterometal ferrimagnetic chain. Structures and magnetic properties of polymeric [Gd2Cu2]n and the corresponding monomer.
One-dimensional polymeric complexes consisting of alternating dicopper(II) and digadolinium(III) units exhibited ferrimagnetic behavior which was ascribable to antiferromagnetic coupling across the oximate N-O bridges between the high-spin homodinuclear units.
Ueki
Sohei
S
Department of Applied Physics and Chemistry, University of Electro-Communications, Chofu, Tokyo, 182-8585, Japan.
Kobayashi
Yasuko
Y
Ishida
Takayuki
T
Nogami
Takashi
T
D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005682:Gadolinium / Q000737:chemistry*; D008280:Magnetics; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013696:Temperature
D009942:Organometallic Compounds; D003300:Copper; D005682:Gadolinium