The folded, tetrameric phosph(III)azane macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4.
The tetrameric macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4, obtained from the reaction of the phosphazane dimer [ClP(mu-NtBu)]2 with p-phenylenediamine, has an unusual folded conformation in the solid state and contains a roughly tetrahedral arrangement of endo N-H groups for the potential coordination of anions.
Dodds
Fay
F
Chemistry Department, University of Cambridge, Lensfield Road, Cambridge, UK.
García
Felipe
F
Kowenicki
Richard A
RA
McPartlin
Mary
M
Riera
Lucía
L
Steiner
Alexander
A
Wright
Dominic S
DS
D001388:Aziridines / Q000737:chemistry*; D003432:Cross-Linking Reagents / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry; D047028:Macrocyclic Compounds / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry
D001388:Aziridines; D003432:Cross-Linking Reagents; D047028:Macrocyclic Compounds; D006859:Hydrogen; D009584:Nitrogen