Stereoisomerism in polyoxometalates: structural and spectroscopic studies of bis(malate)-functionalized cluster systems.
The tetrameric macrocycle [(P(mu-NtBu))2(1,4-(NH)2C6H4)]4, obtained from the reaction of the phosphazane dimer [ClP(mu-NtBu)]2 with p-phenylenediamine, has an unusual folded conformation in the solid state and contains a roughly tetrahedral arrangement of endo N-H groups for the potential coordination of anions.
Fang
Xikui
X
Department of Chemistry, Emory University, 1515 Dickey Drive, Atlanta, GA 30322, USA.
Anderson
Travis M
TM
Hou
Yu
Y
Hill
Craig L
CL
D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008293:Malates / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D013237:Stereoisomerism; D017973:Tungsten Compounds / Q000737:chemistry*
D008293:Malates; D017973:Tungsten Compounds; C030298:malic acid