title: Synthesis of amorphous carbon nanoparticles and carbon encapsulated metal nanoparticles in liquid benzene by an electric plasma discharge in ultrasonic cavitation field.
abstract: A newly-developed method permits an electric plasma discharge to occur with relatively low electric power in insulating organic solutions due to the presence of an ultrasonic cavitation. A stable electric plasma could be generated in an ultrasonic cavitation field containing a thousand tiny activated bubbles, in which the electric conductivity could be improved due to formed radicals and free electrons, using copper electrodes and a titanium ultrasonic horn. This method allowed us to synthesize pyrolytic amorphous carbon nanoparticles smaller than about 30 nm in diameter from benzene liquid. In addition, we synthesized TiC nanoparticles about 50-150 nm in size, and copper nanoparticles smaller than 10 nm, which were encapsulated in multilayered graphite cages. Finally, we used GC-MS and MALDI-TOF-MS to observe and analyze the polymerized compounds and the degree of polymerization of the benzene liquid after the plasma treatment.
authors.affiliation: Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, 1,1 Katahira, 2-Chome, Aobaku, Sendai 980-8577, Japan.
authors.forename: Ruslan
authors.initials: R
authors.lastname: Sergiienko
authors.forename: Etsuro
authors.initials: E
authors.lastname: Shibata
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Suwa
authors.forename: Takashi
authors.initials: T
authors.lastname: Nakamura
authors.forename: Zentaro
authors.initials: Z
authors.lastname: Akase
authors.forename: Yasukazu
authors.initials: Y
authors.lastname: Murakami
authors.forename: Daisuke
authors.initials: D
authors.lastname: Shindo
mesh_terms: D001554:Benzene / Q000737:chemistry*; D020099:Coated Materials, Biocompatible / Q000737:chemistry / Q000528:radiation effects; D003460:Crystallization / Q000379:methods*; D004563:Electrochemistry / Q000379:methods*; D006358:Hot Temperature; D008670:Metals / Q000737:chemistry*; D037742:Nanotubes, Carbon / Q000737:chemistry* / Q000528:radiation effects / Q000648:ultrastructure; D010316:Particle Size; D012996:Solutions; D014465:Ultrasonics
chemical_list: D020099:Coated Materials, Biocompatible; D008670:Metals; D037742:Nanotubes, Carbon; D012996:Solutions; D001554:Benzene