title: instant "base-promoted" generation of roper's-type Ru(0) complexes Ru(CO)2(PR3)3 from a simple carbonylchlororuthenium(II) precursor.
abstract: An uncommon synergism in the concerted action of OH- and PR3 toward the simple Ru(II) complex Ru(CO)3Cl2(thf) allows a highly efficient reduction of the metal in ethanol or acetonitrile solution at 0 degrees C, with selective production of the corresponding Roper's-type Ru(0) complexes Ru(CO)2(PR3)3 in high yields within 10 min.
authors.affiliation: Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France.
authors.forename: Stephane
authors.initials: S
authors.lastname: Sentets
authors.forename: Maria del Carmen
authors.initials: Mdel C
authors.lastname: Rodriguez Martinez
authors.forename: Laure
authors.initials: L
authors.lastname: Vendier
authors.forename: Bruno
authors.initials: B
authors.lastname: Donnadieu
authors.forename: Vincent
authors.initials: V
authors.lastname: Huc
authors.forename: Noël
authors.initials: N
authors.lastname: Lugan
authors.forename: Guy
authors.initials: G
authors.lastname: Lavigne
mesh_terms: D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D012428:Ruthenium