Strategies for the generation of molecularly imprinted polymeric nitroxide catalysts.
[reaction: see text] Two strategies for preparing catalytically active molecularly imprinted nitroxide-containing polymers are outlined. Both strategies rely upon the thermal rearrangement chemistry of tertiary amine N-oxides. To this end, several polymers were prepared and the polymeric nitroxides were revealed by oxidation with m-CPBA. All of the resulting polymeric catalysts proved to be competent mediators of the oxidation of alcohols.
Anderson
Christopher D
CD
Department of Chemistry, University of California-Irvine, 92697-2025, USA.
Shea
Kenneth J
KJ
Rychnovsky
Scott D
SD
D000975:Antioxidants / Q000138:chemical synthesis / Q000737:chemistry; D001672:Biocompatible Materials / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003497:Cyclic N-Oxides / Q000138:chemical synthesis* / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry
D000975:Antioxidants; D001672:Biocompatible Materials; D003497:Cyclic N-Oxides; D011108:Polymers; C003959:TEMPO