A missing allene of heavy Group 14 elements: 2-germadisilaallene.
The first stable 2-germadisilaallene was synthesized by the reduction of a 2 ratio 1 mixture of a stable dialkylsilylene and dichlorogermylene-dioxane complex with KC8; the 2-germadisilaallene showed dynamic disorder similar to the corresponding trisilaallene in the solid state.
Iwamoto
Takeaki
T
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan.
Abe
Takashi
T
Kabuto
Chizuko
C
Kira
Mitsuo
M
D000466:Alkadienes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005857:Germanium / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012825:Silicon / Q000737:chemistry*; D013237:Stereoisomerism
D000466:Alkadienes; D009942:Organometallic Compounds; D005857:Germanium; C025947:propadiene; D012825:Silicon