Novel structural and magnetic properties of a 1-D iron(II)-manganese(II) LIESST compound bridged by cyanide.
The 1-D compound [Fe(L)(CN)2][Mn(hfac)2] (1), which adopts the -NC-Fe-CN-Mn- heterometallic structure, has been shown to exhibit light-induced excited spin-state trapping effects. After illumination, anti-ferromagnetic coupling was observed between the iron(II) (S = 2) and manganese(II) (S = 5/2) ions.
Hayami
Shinya
S
Department of Chemistry, Graduate School of Sciences, Kyushu University, 6-10-1 Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan.
Juhász
Gergely
G
Maeda
Yonezo
Y
Yokoyama
Toshihiko
T
Sato
Osamu
O
D003486:Cyanides; D007501:Iron; D008027:Light; D008280:Magnetics; D008345:Manganese; D008670:Metals / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D017550:Spectroscopy, Fourier Transform Infrared; D013816:Thermodynamics
D003486:Cyanides; D008670:Metals; D008345:Manganese; D007501:Iron