Gold(III)-catalyzed nucleophilic substitution of propargylic alcohols.
Gold-catalyzed nucleophilic substitution on propargylic alcohols, with various C-, O-, and S-nucleophiles, is described under very mild conditions (room temperature, dichloromethane) in 0-97% yield.
Georgy
Marie
M
Institut de Chimie des Substances Naturelles, CNRS, Avenue de la Terrasse, F-91190 Gif-sur-Yvette, France.
Boucard
Valérie
V
Campagne
Jean-Marc
JM
D000438:Alcohols / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006046:Gold / Q000737:chemistry*; D015394:Molecular Structure; D020005:Propanols / Q000737:chemistry*
D000438:Alcohols; D000480:Alkynes; D020005:Propanols; D006046:Gold; C028255:propargyl alcohol