title: Regioselective aromatic C-H silylation of five-membered heteroarenes with fluorodisilanes catalyzed by iridium(I) complexes.
abstract: The aromatic C-H silylation of five-membered heteroarenes with 1,2-di-tert-butyl-1,1,2,2-tetrafluorodisilane regioselectively proceeded at 120 degrees C in octane in the presence of a catalytic amount of iridium(I) complexes generated from 1/2[Ir(OMe)(COD)]2 and 2-tert-butyl-1,10-phenanthroline.
authors.affiliation: Division of Chemical Process Engineering, Graduate School of Engineering, Hokkaido University, Sapporo, 060-8628, Japan. ishiyama@org-mc.eng.hokudai.ac.jp
authors.forename: Tatsuo
authors.initials: T
authors.lastname: Ishiyama
authors.forename: Kazuaki
authors.initials: K
authors.lastname: Sato
authors.forename: Yukihiro
authors.initials: Y
authors.lastname: Nishio
authors.forename: Takeaki
authors.initials: T
authors.lastname: Saiki
authors.forename: Norio
authors.initials: N
authors.lastname: Miyaura