Synthesis and characterization of side-bound aryldiazo and end-bound nitrosyl complexes of nickel.
Structural characterization of a nickel aryldiazo complex supported by the bulky 1,2-bis(di-tert-butylphosphino)ethane ligand reveals square-planar Ni geometry and an unusual side-on coordination mode for the N2R moiety, while the related nitrosyl complex displays trigonal-planar geometry at Ni and end-on coordination of the NO ligand.
Iluc
Vlad M
VM
Searle Chemistry Laboratory, Department of Chemistry, University of Chicago, 5735 S. Ellis Ave., Chicago, IL 60637, USA.
Miller
Alexander J M
AJ
Hillhouse
Gregory L
GL
D001391:Azo Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009532:Nickel / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*
D001391:Azo Compounds; D009532:Nickel; D009584:Nitrogen