Catalytic ethylene dimerization and oligomerization: recent developments with nickel complexes containing P,N-chelating ligands.
Catalytic ethylene oligomerization represents a topic of considerable current academic and industrial interest, in particular for the production of linear alpha-olefins in the C4-C10 range, whose demand is growing fast. Identifying and fine-tuning the parameters that influence the activity and selectivity of metal catalysts constitute major challenges at the interface between ligand design, coordination/organometallic chemistry, and homogeneous catalysis. In this Account, we show how comparative studies aiming at modulating the coordinating properties of functional ligands for a metal, such as nickel, which is used in industrial processes, lead to beneficial effects in catalytic ethylene oligomerization.
Speiser
Fredy
F
Laboratoire de Chimie de Coordination (UMR 7513 CNRS), Université Louis Pasteur, 4 rue Blaise Pascal, F-67070 Strasbourg Cédex, France, and Institut Français du Pétrole, Direction Catalyse et Séparation, IFP-Lyon, BP 3, F-69390 Vernaison, France.
Braunstein
Pierre
P
Saussine
Lucien
L
D002384:Catalysis; D002614:Chelating Agents / Q000737:chemistry*; D019281:Dimerization; D005030:Ethylenes / Q000737:chemistry*; D008024:Ligands; D008956:Models, Chemical; D009532:Nickel / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*; D010758:Phosphorus / Q000737:chemistry*
D002614:Chelating Agents; D005030:Ethylenes; D008024:Ligands; D010758:Phosphorus; D009532:Nickel; C036216:ethylene; D009584:Nitrogen