Coexistence of ferro- and antiferromagnetic interactions in a metal-organic radical-based (6,3)-helical network with large channels.
A metal-organic open-framework with an unprecedented (6,3)-helical topology, large channels and mixed ferro- and antiferromagnetic interactions has been synthesized using a three-connecting tricarboxylic polychlorotriphenylmethyl radical and Co(ii) ions.
Maspoch
Daniel
D
Institut de Ciència de Materials de Barcelona (CSIC), Campus Universitari, Bellaterra, 08193, Catalonia, Spain.
Domingo
Neus
N
Ruiz-Molina
Daniel
D
Wurst
Klaus
K
Hernández
Joan-Manel
JM
Vaughan
Gavin
G
Rovira
Concepció
C
Lloret
Francesc
F
Tejada
Javier
J
Veciana
Jaume
J