Study of thermal behavior of vitamin D3 by pyrolysis-GC-MS in combination with boiling point-retention time correlation.
The thermal behavior of vitamin D3 was studied based on pyrolysis-GC-MS technique. It was pyrolyzed at 600 degrees C, 750 degrees C, 900 degrees C, respectively. The pyrolysis product were separated With an HP-5 column and identified by the NIST mass spectral search program in combination with the correlation of boiling point and retention time (BP-RT). There are totally 50 components, including mono aromatics and polycyclic aromatic hydrocarbons (PAHs), were determined. It is shown that the contents of the PAHs are increasing with the increasing of the pyrolysis temperature. The contents of the determined components vary from 0.04% to 37.08%.
Sun
Yu'an
Y
Department of Applied Chemistry, Zhengzhou Institute of Light Industry, Zhengzhou, Henan, 450002, PR China. sya@371.net
Liu
Baoxia
B
Wang
Guoqing
G
Zhang
Rongjie
R
Xie
Bing
B
D002762:Cholecalciferol / Q000032:analysis* / Q000737:chemistry; D002849:Chromatography, Gas / Q000379:methods*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods*; D006358:Hot Temperature; D006841:Hydrocarbons, Aromatic / Q000032:analysis; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis; D013995:Time; D044366:Transition Temperature
D006841:Hydrocarbons, Aromatic; D011084:Polycyclic Aromatic Hydrocarbons; D002762:Cholecalciferol