New mono- and bis-carbene samarium complexes: synthesis, X-ray crystal structures and reactivity.
New samarium carbene complexes have been synthesized and characterized by X-ray diffraction analysis; the carbenic nature was assessed by reactivity studies.
Cantat
Thibault
T
Laboratoire 'Hétéroéléments et Coordination' UMR CNRS 7653 (DCPH), Département de Chimie, Ecole Polytechnique, 91128, Palaiseau cedex, France.
Jaroschik
Florian
F
Nief
François
F
Ricard
Louis
L
Mézailles
Nicolas
N
Le Floch
Pascal
P
D018360:Crystallography, X-Ray; D006838:Hydrocarbons / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D012493:Samarium / Q000737:chemistry*; D013237:Stereoisomerism
D006838:Hydrocarbons; D009942:Organometallic Compounds; C030011:carbene; D012493:Samarium; D008697:Methane