title: Three isomeric (E)-nitrobenzaldehyde nitrophenylhydrazones: chains of rings in isomorphous (E)-2-nitrobenzaldehyde 3-nitrophenylhydrazone and (E)-3-nitrobenzaldehyde 2-nitrophenylhydrazone, and centrosymmetric dimers in (E)-4-nitrobenzaldehyde 2-nitrophenylhydrazone.
abstract: The isomeric compounds (E)-2-nitrobenzaldehyde 3-nitrophenylhydrazone and (E)-3-nitrobenzaldehyde 2-nitrophenylhydrazone, both C13H10N4O4, are isomorphous and effectively isostructural, and in both, the molecules are disordered across centres of inversion in the space group P21/c. The molecules are linked into complex chains of rings by N-H...O and C-H...O hydrogen bonds. In the isomeric compound (E)-4-nitrobenzaldehyde 2-nitrophenylhydrazone, the fully ordered molecules are linked by N-HO hydrogen bonds into centrosymmetric dimers.
authors.affiliation: School of Chemistry, University of St Andrews, Fife KY16 9ST, Scotland.
authors.forename: George
authors.initials: G
authors.lastname: Ferguson
authors.forename: Christopher
authors.initials: C
authors.lastname: Glidewell
authors.forename: John N
authors.initials: JN
authors.lastname: Low
authors.forename: Janet M S
authors.initials: JM
authors.lastname: Skakle
authors.forename: James L
authors.initials: JL
authors.lastname: Wardell