Preparation, characterization, and properties of chitosan-g-poly(vinyl alcohol) copolymer.
The graft copolymer chitosan-g-poly(vinyl alcohol), with nontoxicity, biodegradability, and biocompatibility, was prepared by a novel method. The copolymer with porous net structure was observed by scanning electron microscopy (SEM). It is a potential method to combine chitosan with the synthetic polymers. The grafting reactions were conducted with various poly(vinyl alcohol) (PVA)/6-O-succinate-N-phthaloyl-chitosan (PHCSSA) feed ratios to obtain chitosan-g-poly(vinyl alcohol) copolymers with various PVA contents. The chemical structure of the chitosan-g-poly(vinyl alcohol) was characterized by Fourier transform infrared and nuclear magnetic resonance (NMR) spectroscopy. Differential scanning calorimetry (DSC), X-ray diffraction (XRD), and SEM were also detected to characterize the copolymer.
Huang
Meifang
M
Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026, People's Republic of China. huangmf@mail.ustc.edu.cn
Fang
Yue'e
Y
D048271:Chitosan / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry* / Q000378:metabolism; D006358:Hot Temperature; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D011142:Polyvinyl Alcohol / Q000737:chemistry* / Q000378:metabolism; D011145:Polyvinyls / Q000138:chemical synthesis* / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared
D011145:Polyvinyls; C511088:chitosan-g-poly(vinyl alcohol) copolymer; D011142:Polyvinyl Alcohol; D048271:Chitosan