Unique self-assembled 2D metal-tetrazolate networks: crystal structure and magnetic properties of [M(pmtz)2](M = Co(II) and Fe(II); Hpmtz = 5-(pyrimidyl)tetrazole).
The title compounds, which have been prepared from M(II) salts (M = Co and Fe) and 5-(pyrimidyl)tetrazole under hydrothermal conditions, are isomorphous and exhibit a 2D square-grid-like structure; the cobalt complex is a spin-canted antiferromagnet with Tc= 15 K.
Rodríguez
Antonio
A
Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, E-18071 Granada, Spain. ecolacio@ugr.es antonio5@ugr.es.
Kivekäs
Raikko
R
Colacio
Enrique
E