title: A 'dry' condensation origin for circumstellar carbonates.
abstract: The signature of carbonate minerals has long been suspected in the mid-infrared spectra of various astrophysical environments such as protostars. Abiogenic carbonates are considered as indicators of aqueous mineral alteration in the presence of CO2-rich liquid water. The recent claimed detection of calcite associated with amorphous silicates in two planetary nebulae and protostars devoid of planetary bodies questions the relevance of this indicator; but in the absence of an alternative mode of formation under circumstellar conditions, this detection remains controversial. The main dust component observed in circumstellar envelopes is amorphous silicates, which are thought to have formed by non-equilibrium condensation. Here we report experiments demonstrating that carbonates can be formed with amorphous silicates during the non-equilibrium condensation of a silicate gas in a H2O-CO2-rich vapour. We propose that the observed astrophysical carbonates have condensed in H2O(g)-CO2(g)-rich, high-temperature and high-density regions such as evolved stellar winds, or those induced by grain sputtering upon shocks in protostellar outflows.
authors.affiliation: Centre de Recherches Pétrographiques et Géochimiques-CNRS UPR 2300, 15 rue Notre Dame des Pauvres, BP 20, Vandoeuvre-les-Nancy, France. toppani2@llnl.gov
authors.forename: Alice
authors.initials: A
authors.lastname: Toppani
authors.forename: François
authors.initials: F
authors.lastname: Robert
authors.forename: Guy
authors.initials: G
authors.lastname: Libourel
authors.forename: Philippe
authors.initials: P
authors.lastname: de Donato
authors.forename: Odile
authors.initials: O
authors.lastname: Barres
authors.forename: Louis
authors.initials: L
authors.lastname: d'Hendecourt
authors.forename: Jaafar
authors.initials: J
authors.lastname: Ghanbaja