Configuration and photochemical reaction of a bolaamphiphilic diacid with a diazo resin in monolayers and Langmuir-Blodgett films.
The monolayer formation of a bolaamphiphile, 1,18-octadecanedicarboxylic acid (ODA), on pure water and the subphase containing a positively charged photoactive 2-nitro-N-methyldiphenylamine-4-diazoniumformaldehyde resin (NDR) have been investigated by pi-A isotherms, pi-t curves, and Brewster angle microscopy (BAM) measurements. It has been revealed that although an unstable monolayer was formed by ODA alone, a stable complex monolayer between ODA and NDR could be formed at the interface through electrostatic adsorption and hydrogen bonding. It has been shown that the ODA formed a U-shaped monolayer at a lower pressure and was converted to a stretched configuration upon compression to a higher surface pressure on the subphase containing NDR. Under UV irradiation at the interface photoreaction can occur in the complex monolayer, which causes shrinkage of the monolayer. Photochemical reactions can also occur in deposited Langmuir-Blodgett films. In reactions occurring at the air/water interface, the two ends of ODA can react with NDR to form an ester containing aromatic rings. This makes the compound more hydrophobic and can easily be stretched without any phase transition upon compression. When the film with U-shaped configuration was deposited onto solid substrates, the configuration could be kept even upon photoirradiation.
Zhang
Li
L
Key Laboratory of Colloid and Interface Science, Institute of Chemistry, Chinese Academy of Sciences, 100080 Beijing, People's Republic of China.
Jiang
Siguang
S
Liu
Minghua
M
D003979:Diazonium Compounds / Q000737:chemistry*; D003998:Dicarboxylic Acids / Q000737:chemistry*; D010777:Photochemistry; D013501:Surface-Active Agents / Q000737:chemistry*; D014867:Water
D003979:Diazonium Compounds; D003998:Dicarboxylic Acids; D013501:Surface-Active Agents; D014867:Water