Depolarization ratio and correlation between the relative intensity data and the abundance ratio of various isotopes of liquid carbon tetrachloride at room temperature.
The room temperature Stokes and anti-Stokes Raman spectra of liquid CCl(4) have been recorded. The intensity ratios of anti-Stokes to Stokes Raman bands as a function of Raman shift are obtained in agreement with polarizability theory. The depolarization ratio rho (nu) as a function of Raman shift is obtained also in agreement with automatically scanned depolarization ratio rho (nu). Ratio of the intensity of the isotopic nu(1) bands indicates small deviation from the theoretical relative abundance of CCl(4) isotopes. The intensity ratio of the [nu(3)-nu(4), (nu(1)+nu(4))-nu(4)] and nu(1) bands is obtained. The consequences of the presence of different isotopes of CCl(4) on the depolarization ratio of its vibrational bands are discussed. The effects of impurities in liquid CCl(4) on depolarization ratio of the nu(1) band are estimated.
Chakraborty
Taposh
T
Sophisticated Analytical Instrument Facility, North-Eastern Hill University, Bijni Complex, Laitumkhrah, Shillong 793003 Meghalaya, India. bortys@yahoo.com
Rai
Sachchida Nand
SN
D002247:Carbon Isotopes; D002250:Carbon Radioisotopes; D002251:Carbon Tetrachloride / Q000737:chemistry*; D002713:Chlorine; D007554:Isotopes; D011868:Radioisotopes; D012997:Solvents; D013059:Spectrum Analysis, Raman; D013816:Thermodynamics; D014732:Vibration
D002247:Carbon Isotopes; D002250:Carbon Radioisotopes; D007554:Isotopes; D011868:Radioisotopes; D012997:Solvents; D002713:Chlorine; D002251:Carbon Tetrachloride