title: Size-dependent structures of NanI+n-1 cluster ions with a methanol adsorbate: a combined study by photodissociation spectroscopy and density-functional theory calculation.
abstract: Methanol adsorption sites on NanI+n-1 ions were investigated. Photoexcitation to charge-transfer states of NanI+n-1 (methanol) predominantly produces two fragment ions: Nan-1I+n-2 (methanol) (neutral NaI loss) and Nan-1I+n-2(neutral NaI and methanol loss), without forming NanI+n-1 (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.
authors.affiliation: Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan. misaizu@qpcrkk.chem.tohoku.ac.jp
authors.forename: Fuminori
authors.initials: F
authors.lastname: Misaizu
authors.forename: Mamoru
authors.initials: M
authors.lastname: Tsuruta
authors.forename: Hironori
authors.initials: H
authors.lastname: Tsunoyama
authors.forename: Ari
authors.initials: A
authors.lastname: Furuya
authors.forename: Koichi
authors.initials: K
authors.lastname: Ohno
authors.forename: Masami
authors.initials: M
authors.lastname: Lintuluoto