title: Unprecedented asymmetric induction through configurationally stable lithium N-(alpha-methylbenzyl)phosphinamides. A new entry to enantiomerically pure gamma-aminophosphinic acids and esters.
abstract: The first examples of configurationally stable N-benzyl-N-phosphinoyl carbanions are described. Their applications to the synthesis of homochiral gamma-aminophosphinic acids and esters via highly enantioselective dearomatising reactions are shown.
authors.affiliation: Area de Química Orgánica, Universidad de Almería, Carretera de Sacramento, 04120, Almería, Spain.
authors.forename: Ignacio
authors.initials: I
authors.lastname: Fernández
authors.forename: Gloria Ruiz
authors.initials: GR
authors.lastname: Gómez
authors.forename: Ignacio
authors.initials: I
authors.lastname: Alfonso
authors.forename: María J
authors.initials: MJ
authors.lastname: Iglesias
authors.forename: Fernando López
authors.initials: FL
authors.lastname: Ortiz