title: Synthesis of functionalized vinylgermanes through a new ruthenium-catalyzed coupling reaction.
abstract: Vinyl-substituted germanes react stereo- and regioselectively with olefins in the presence of complexes containing Ru-H and Ru-Ge bonds with the formation of functionalized vinylgermanes that cannot be synthesized by olefin cross-metathesis procedures. The reaction opens a new catalytic route for preparation of a class of organogermanes that are potent organometallic reagents for organic synthesis because they show very low toxicity and could replace organotin compounds. The mechanism of this new catalytic route was proven to involve an interesting insertion of the vinylgermane into the Ru-H bond and beta-Ge transfer to the metal with elimination of ethylene and generation of an Ru-Ge bond, followed by insertion of the alkene into the Ru-Ge bond and beta-H transfer to the metal to eliminate the substituted vinylgermane.
authors.affiliation: Department of Organometallic Chemistry, Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznan, Poland. marcinb@amu.edu.pl
authors.forename: Bogdan
authors.initials: B
authors.lastname: Marciniec
authors.forename: Hanna
authors.initials: H
authors.lastname: Ławicka
authors.forename: Mariusz
authors.initials: M
authors.lastname: Majchrzak
authors.forename: Maciej
authors.initials: M
authors.lastname: Kubicki
authors.forename: Ireneusz
authors.initials: I
authors.lastname: Kownacki