Tricalysiosides H-O: Ent-kaurane glucosides from the leaves of Tricalysia dubia.
Eight ent-kaurane glucosides, named tricalysiosides H-O, were isolated from Tricalysia dubia. Tricalysioside H possessed a hydroxyl group at the 1-position, to which the glucose moiety was attached. The structure was first elucidated by means of spectroscopic data analysis and finally confirmed by X-ray crystallography. Since acid hydrolysis of 1 gave D-glucose, the aglycone was proved to have an enantio-kaurane type skeleton. The structures of tricalysiosides I-O were mainly elucidated from analysis of spectroscopic evidence.
He
Dong-Hui
DH
Department of Pharmacognosy, Graduate School of Biomedical Sciences, Hiroshima University, 1-2-3 Kasumi, Minami-ku, Hiroshima 734-8551, Japan.
Matsunami
Katsuyoshi
K
Otsuka
Hideaki
H
Shinzato
Takakazu
T
Aramoto
Mitsunori
M
Bando
Masahiko
M
Takeda
Yoshio
Y
D018360:Crystallography, X-Ray; D045786:Diterpenes, Kaurane / Q000737:chemistry*; D005960:Glucosides / Q000737:chemistry*; D015394:Molecular Structure; D018515:Plant Leaves / Q000737:chemistry*; D019666:Rubiaceae / Q000737:chemistry*
D045786:Diterpenes, Kaurane; D005960:Glucosides