Dichlorooxo(quinoline-8-thiolato-kappa2N,S)(triphenylphosphine oxide-kappaO)rhenium(V) acetone solvate.
The complex molecule in the title compound, [Re(C(9)H(6)NS)Cl(2)O(C(18)H(15)OP)].C(3)H(6)O, has distorted octahedral geometry. The Re=O bond occupies the position trans to the triphenylphosphine oxide O atom. The Re-Cl bond trans to the thiolate S atom is longer than that trans to the quinoline N atom, implying a stronger trans influence of the S atom. Intra- and intermolecular pi-pi interactions are also observed between the pi rings in the complex.
Miyashita
Yoshitaro
Y
Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba 305-8571, Japan. ymiya@chem.tsukuba.ac.jp
Ohashi
Tetuya
T
Imai
Akiomi
A
Amir
Nagina
N
Fujisawa
Kiyoshi
K
Okamoto
Ken-ichi
K