title: Highly stereoselective [2,3]-sigmatropic rearrangement of sulfur ylide generated through Cu(I) carbene and sulfides.
abstract: A highly stereoselective [2,3]-sigmatropic rearrangement of sulfur ylide generated through Cu(I) carbene and allyl and propargyl sulfides by a double asymmetric induction approach that combines a chiral camphor sultam auxiliary and Cu(I) catalyst with chiral or achiral diimine ligands has been developed.
authors.affiliation: Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
authors.forename: Ming
authors.initials: M
authors.lastname: Ma
authors.forename: Lingling
authors.initials: L
authors.lastname: Peng
authors.forename: Changkun
authors.initials: C
authors.lastname: Li
authors.forename: Xiu
authors.initials: X
authors.lastname: Zhang
authors.forename: Jianbo
authors.initials: J
authors.lastname: Wang