Indirect detection of selective nuclear spin-spin interactions in a hostile environment.
We present a number of techniques which may be used to obtain precise values of selective spin-spin interactions between two nuclear spins in a hostile environment. Such an environment may be characterized by very fast relaxation and decoherence, e.g. due to the strong coupling of the two spins of interest to electron spins in their vicinity as well as other nuclei. Here, we used dilute paramagnetic Ce(3+) centers hosted in a single crystal of CaF(2). Selected (19)F internuclear interactions were measured indirectly by applying different electron nuclear double resonance (ENDOR) pulse sequences.
Heidebrecht
A
A
Univesität Stuttgart, Pfaffenwaldring 57, 70569 Stuttgart, Germany.
Mende
J
J
Mehring
M
M
D000465:Algorithms; D002124:Calcium Fluoride / Q000032:analysis* / Q000737:chemistry*; D004777:Environment; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D012815:Signal Processing, Computer-Assisted; D013113:Spin Labels
D013113:Spin Labels; D002124:Calcium Fluoride