Direct observation of the disorder of the methyl group of (R)-1,2-diaminopropane ligand in the quasi-1D bromo-bridged Ni(III) complex by STM.
Scanning tunneling microscopy (STM) has been measured in quasi-one-dimensional (Quasi-ID) bromo-bridged Ni(III) complexes. In the STM image of [Ni(pn)2Br]Br2 (pn = (R)-1,2-diaminopropane), the bright spots are fluctuated zigzags. Such a result indicates that the methyl groups of the pn ligands are not arranged on the right- and left-hand alternatively along the chains, but in the domain structures or fluctuated structures. This is the first direct observation of the disorder of the methyl group of pn ligands in real space.
Sasaki
Mari
M
Department of Chemistry, Tokyo Metropolitan University, Hachioji 192-0097, Japan.
Takaishi
Shinya
S
Miyasaka
Hitoshi
H
Sugiura
Ken-ichi
K
Yamashita
Masahiro
M