One-color two-photon mass-analyzed threshold ionization spectroscopy of ethyl bromide through a dissociative intermediate state.
Mass-analyzed threshold ionization (MATI) spectra of ethyl bromide were obtained using one-color two-photon ionization through a dissociative intermediate state. Accurate values for the adiabatic ionization energy have been obtained, 83099+/-5 and 85454+/-5 cm(-1) for the X1 2E and X2 2E states of the ethyl bromide cation, respectively, giving a splitting of 2355+/-10 cm(-1). Compared with conventional photoelectron data, the two-photon MATI spectrum exhibited a more extensive vibrational structure with a higher resolution, mainly containing the modes involving the dissociation coordinate. The observed modes were analyzed and discussed in terms of wave packet evolving on the potential-energy surface of the dissociative state.
Tang
Bifeng
B
State Key Laboratory of Magnetic Resonance and Atomic Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071, People's Republic of China.
Zhang
Song
S
Wang
Yanmei
Y
Tang
Ying
Y
Zhang
Bing
B