Oxidative transformations of nucleoside fluorenemethyl H-phosphonoselenoate diesters.
9-Fluorenemethyl H-phosphonoselenoate monoester has been used to produce thymidine 3'-O-phosphoroselenoate monoester from which various P(V) derivatives containing multiple modifications at phosphorus were obtained; e.g., thymidine 3'-O-phosphoroselenofluoridate, 3'-O-phosphoroselenothioate, or 3'-O-phosphorodiselenoate monoesters.
Kullberg
Martin
M
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, Stockholm, Sweden.
Stawinski
Jacek
J
D004952:Esters / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D008967:Molecular Biology / Q000379:methods*; D016877:Oxidants / Q000494:pharmacology; D010100:Oxygen / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry; D012643:Selenium / Q000737:chemistry; D018036:Selenium Compounds / Q000737:chemistry* / Q000494:pharmacology; D013237:Stereoisomerism; D013997:Time Factors
C479441:9-fluorenemethyl H-phosphonoselenoate; D004952:Esters; D016877:Oxidants; D011725:Pyridines; D018036:Selenium Compounds; D006859:Hydrogen; D012643:Selenium; D010100:Oxygen