Group IV complexes of a tetradentate amine mono(phenolate) ligand: a second side-arm donor stabilizes cationic species.
An amine mono(phenolate) ligand bearing two side-arm donors led to octahedral trialkoxo and trialkyl group IV metal complexes, in which one of the donors was unbound, and to exceptionally stable cationic complexes in which the two side-arm donors were tightly bound.
Groysman
Stanislav
S
School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv 69978, Israel.
Sergeeva
Ekaterina
E
Goldberg
Israel
I
Kol
Moshe
M