title: Infrared and Raman spectroscopic studies of l-valine l-valinium perchlorate monohydrate.
abstract: FT-IR and FT-Raman spectra were recorded and analyzed for l-valine l-valinium perchlorate monohydrate crystals. The wave number assignments have been made for the functional groups, viz. COOH, COO(-), --[NH(3)](+), C--(CH(3))(2), C--C--N and C--H. One of the two amino acid residues remains in the zwitterionic form while the other residue exists in the cationic form. The symmetry of the ClO(4)(-) anion has been found to be lowered corresponding to ClO(2) group. The hydrogen bonds that prevail between amino acid residues, perchlorate anion and water molecule influence the wave numbers of several stretching and deformation modes to deviate from the expected values.
authors.affiliation: Laser Laboratory, Department of Microprocessor and Computer, School of Physics, Madurai Kamaraj University, Madurai 625021, India. sprapk@yahoo.com
authors.forename: S
authors.initials: S
authors.lastname: Pandiarajan
authors.forename: M
authors.initials: M
authors.lastname: Umadevi
authors.forename: R K
authors.initials: RK
authors.lastname: Rajaram
authors.forename: V
authors.initials: V
authors.lastname: Ramakrishnan
mesh_terms: D006860:Hydrogen Bonding; D008958:Models, Molecular; D008968:Molecular Conformation; D010472:Perchlorates / Q000737:chemistry*; D013055:Spectrophotometry, Infrared / Q000379:methods; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods; D013059:Spectrum Analysis, Raman / Q000379:methods; D014633:Valine / Q000737:chemistry*; D014732:Vibration
chemical_list: D010472:Perchlorates; D014633:Valine