Synthesis and characterization of seven-coordinate tripodal imidazole complexes of iron(II) and manganese(II).
The iron(II) and manganese(II) complexes of the N(7) Schiff-base condensate of tris(3-aminopropyl)amine with 1-methyl-2-imidazolecarbaldehyde and the manganese(II) complex of the N(7) Schiff-base condensate of tris(3-aminopropyl)amine with 4-imidazolecarbaldehyde are high-spin mono capped octahedral seven-coordinate complexes with a short, approximately 2.44 è, metal to apical nitrogen bond.
Brewer
Cynthia
C
The Catholic University of America, Washington, DC 20064, USA. brewer@cua.edu
Brewer
Greg
G
Butcher
Ray J
RJ
Carpenter
Everett E
EE
Cuenca
Luciann
L
Schmiedekamp
Ann M
AM
Viragh
Carol
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