Size-dependent structures of NanI+n-1 cluster ions with a methanol adsorbate: a combined study by photodissociation spectroscopy and density-functional theory calculation.
Methanol adsorption sites on NanI+n-1 ions were investigated. Photoexcitation to charge-transfer states of NanI+n-1 (methanol) predominantly produces two fragment ions: Nan-1I+n-2 (methanol) (neutral NaI loss) and Nan-1I+n-2(neutral NaI and methanol loss), without forming NanI+n-1 (methanol loss). The relative intensities of these fragments are correlated with the geometries and binding energies.
Misaizu
Fuminori
F
Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan. misaizu@qpcrkk.chem.tohoku.ac.jp
Tsuruta
Mamoru
M
Tsunoyama
Hironori
H
Furuya
Ari
A
Ohno
Koichi
K
Lintuluoto
Masami
M