The impact of NiO on microstructure and electrical property of solid oxide fuel cell anode.
Ni-Ce(0.8)Sm(0.2)O(1.9) (Ni-SDC) cermet was selected as anode material for reduced temperature (800 degrees C) solid oxide fuel cells in this study. The influence of NiO powder fabrication methods for Ni-SDC cermets on the electrode performance was investigated so that the result obtained can be applied to make high-quality anode. Three kinds of NiO powder were synthesized with a fourth kind being available in the market. Four types of anode precursors were fabricated with these NiO powders and Ce(0.8)Sm(0.2)O(1.9) (SDC), and then were reduced to anode wafers for sequencing measurement. The electrical conductivity of the anodes was measured and the effect of microstructure was investigated. It was found that the anode electrical conductivity depends strongly on the NiO powder morphologies, microstructure of the cermet anode and particle sizes, which are decided by NiO powder preparation technique. The highest electrical conductivity is obtained for anode cermets with NiO powder synthesized by NiCO(3).2Ni(OH)(2).4H(2)O or Ni(NO(3))(2).6H(2)O decomposition technique.
Li
Yan
Y
Institute for Thermal Power Engineering, Clean Energy and Environment Engineering Key Laboratory of Ministry of Education, Zhejiang University, Hangzhou 310027, China.
Luo
Zhong-yang
ZY
Yu
Chun-jiang
CJ
Luo
Dan
D
Xu
Zhu-an
ZA
Cen
Ke-fa
KF
D017097:Electric Impedance; D011211:Electric Power Supplies; D004563:Electrochemistry / Q000295:instrumentation* / Q000379:methods; D004566:Electrodes; D004867:Equipment Design; D019544:Equipment Failure Analysis; D009532:Nickel / Q000737:chemistry*; D011208:Powders; D013499:Surface Properties
D011208:Powders; D009532:Nickel; C028007:nickel monoxide