Investigation of the specific adsorption of sulfate ions on powdered TiO2.
The specific adsorption of radiolabeled sulfate ions from perchlorate supporting electrolyte onto TiO2 powder (anatase) has been investigated. The pH and concentration dependence of the adsorption was determined. Langmuir-like adsorption behavior similar to that on other oxides was found. From the pH dependence it follows that the protonation of the surface should precede the specific anion adsorption. The results obtained are compared with those reported for TiO2 bulk electrodes.
Horányi
G
G
Institute of Chemistry, Chemical Research Center, Hungarian Academy of Sciences, P.O. Box 17, 1525 Budapest, Hungary. hor34@ludens.elte.hu