title: Investigating the reaction of N-carbobenzoxy-O-carbobenzoxy- hydroxylamine with dimethyl sulfoxide: formation of S,S-dimethyl-N-[(phenylmethoxy)- carbonyl]sulfoximine.
abstract: [Reaction: see text]. N-carbobenzoxy-O-carbobenzoxyhydroxylamine (1a) underwent a thermally induced reaction in DMSO in which there is net N-alpha-eliminative oxidation with tandem oxidative incorporation of DMSO to yield S,S-dimethyl-N-[(phenylmethoxy)carbonyl]sulfoximine. Mechanisms for the formation of the sulfoximine are presented as well as the product characterizations, including the X-ray crystal structure.
authors.affiliation: Department of Chemistry, McNeese State University, Lake Charles, Louisiana 70609, USA. rdarbeau@mail.mcneese.edu
authors.forename: Ron W
authors.initials: RW
authors.lastname: Darbeau
authors.forename: Noe T
authors.initials: NT
authors.lastname: Alvarez
authors.forename: Gregory A
authors.initials: GA
authors.lastname: Trahan
authors.forename: Frank R
authors.initials: FR
authors.lastname: Fronczek