Improved surface properties of polyaniline films by blending with Pluronic polymers without the modification of the other characteristics.
Films of conductive polyaniline and amphiphilic Pluronic (P105) copolymer blends were prepared by dissolving the two polymers in N-methylpyrrolidinone (NMP) followed by a slow solvent evaporation at 55 degrees C. The characteristics of both doped and undoped films were determined by X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), water droplet contact angles, differential scanning calorimetry (DSC), thermal gravimetry analysis (TG), wide-angle X-ray diffraction (WAXD), and tensile strength measurements. The surface of the blends became more hydrophilic than that of the hydrophobic PANI film, but the other properties of the blends did not change appreciably for Pluronic content lower than 50 wt%. Compared to PANI films, the more hydrophilic surfaces decreased the amount of bovine serum albumin protein adsorbed. By preventing biofouling, the polyaniline-Pluronic blends can become more useful as biosensors than the polyaniline films.
Li
Z F
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Department of Chemical Engineering, State University of New York at Buffalo, Buffalo, NY 14260, USA.
Ruckenstein
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D000327:Adsorption; D000814:Aniline Compounds / Q000737:chemistry*; D000818:Animals; D015374:Biosensing Techniques; D002152:Calorimetry, Differential Scanning; D002417:Cattle; D020099:Coated Materials, Biocompatible; D008855:Microscopy, Electron, Scanning; D011108:Polymers / Q000737:chemistry*; D012710:Serum Albumin, Bovine / Q000737:chemistry; D013499:Surface Properties; D014961:X-Ray Diffraction
D000814:Aniline Compounds; D020099:Coated Materials, Biocompatible; D011108:Polymers; C416807:polyaniline; D012710:Serum Albumin, Bovine