Simultaneous measurement of D and T2 using the distant dipolar field.
The presence of long-range dipolar fields in liquids is known to introduce a non-linear term in the Bloch-Torrey equations which is responsible for many interesting effects in nuclear magnetic resonance as well as in magnetic resonance imaging. We show here, for the first time, that the diffusion coefficient D and the spin-spin relaxation time T2 can be obtained simultaneously from the time evolution profile of the long-range dipolar field refocused signal. In a COSY Revamped by Z-asymmetric Echo Detection sequence, the analytical first-order approximation solution of the Bloch-Torrey equations modified to include the effect of the distant dipolar field is used to demonstrate the technique in an experiment using doped water.
Barros
Wilson
W
Vanderbilt University Institute of Imaging Science (VUIIS), Vanderbilt University Medical Center, R-1302 Medical Center North, Nashville, TN 37232-2310, USA. wilson.barros@vanderbilt.edu
Gore
John C
JC
Gochberg
Daniel F
DF
D004058:Diffusion; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D012815:Signal Processing, Computer-Assisted; D014867:Water / Q000737:chemistry*
D014867:Water