title: Conversion of municipal solid waste into carboxylic acids by anaerobic countercurrent fermentation: effect of using intermediate lime treatment.
abstract: Municipal solid waste (MSW) and sewage sludge (SS) were combined and anaerobically converted into carboxylate salts by using a mixed culture of acid-forming microorganisms. MSW is an energy source and SS is a source of nutrients. In this study, MSW and SS were combined, so they complemented each other. Four fermentors were arranged in series for a countercurrent fermentation process. In this process, the solids and liquid were transferred in opposite directions, with the addition of fresh biomass to fermentor 1 and fresh liquid media to fermentor 4. An intermediate lime treatment of solids exiting fermentor 3 before entering fermentor 4 was applied to improve the product acid concentration from the untreated MSW/SS fermentations. All fermentations were performed under anaerobic conditions at 40 degrees C. Calcium carbonate was added to neutralize the carboxylic acids and to control the pH. Iodoform was used as a methanogen inhibitor. Carboxylic acid concentration and gas composition were determined by gas chromatography. Substrate conversion was measured by volatile solids loss, and carboxylic acid productivity was calculated as the function of the total carboxylic acids produced, the amount of liquid in all fermentors, and time. The addition of intermediate lime treatment increased product concentration and conversion by approx 30 and 15%, respectively. The highest carboxylic acid concentrations for untreated MSW/SS fermentations with and without intermediate lime treatment were 22.2 and 17.7 g of carboxylic acid/L of liquid, respectively. These results confirm that adding a treatment step between fermentor 3 and fermentor 4 will increase the digestibility and acid productivity of the fermentation.
authors.affiliation: Departamento de Química, Facultad de Ingeniería Coordinación de Ciclo Básico, Universidad del Zulia, Maracaibo 4002, Venezuela.
authors.forename: Cateryna
authors.initials: C
authors.lastname: Aiello-Mazzarri
authors.forename: Guillermo
authors.initials: G
authors.lastname: Coward-Kelly
authors.forename: Frank K
authors.initials: FK
authors.lastname: Agbogbo
authors.forename: Mark T
authors.initials: MT
authors.lastname: Holtzapple
mesh_terms: D000693:Anaerobiosis; D018533:Biomass; D017610:Calcium Compounds / Q000737:chemistry*; D002264:Carboxylic Acids / Q000378:metabolism*; D003377:Countercurrent Distribution / Q000379:methods; D004783:Environmental Microbiology; D005285:Fermentation; D010087:Oxides / Q000737:chemistry*; D012037:Refuse Disposal / Q000295:instrumentation / Q000379:methods*; D012722:Sewage / Q000737:chemistry
chemical_list: D017610:Calcium Compounds; D002264:Carboxylic Acids; D010087:Oxides; D012722:Sewage; C016538:lime