title: A geometric switching approach toward thermal activation of metalloenediynes.
abstract: Tetradentate metalloenediynes with strong imine and weaker thioether coordination serve as a geometrically non-rigid switch to drive thermal Bergman cyclization.
authors.affiliation: Department of Chemistry, Indiana University, Bloomington, IN, USA.
authors.forename: Sibaprasad
authors.initials: S
authors.lastname: Bhattacharyya
authors.forename: David F
authors.initials: DF
authors.lastname: Dye
authors.forename: Maren
authors.initials: M
authors.lastname: Pink
authors.forename: Jeffrey M
authors.initials: JM
authors.lastname: Zaleski
mesh_terms: D003500:Cyclization; D053281:Enediynes / Q000737:chemistry*; D006358:Hot Temperature; D008670:Metals / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure
chemical_list: D053281:Enediynes; D008670:Metals