title: Structural, morphological, and magnetic study of nanocrystalline cobalt-nickel-copper particles.
abstract: Nanocrystalline Co(x)Ni(y)Cu(100-x-y) particles were synthesized by the reduction of metal acetates in a mixture of polyol and Tween 80. Inductively coupled plasma (ICP) analysis revealed that the actual wt% of Co, Ni, and Cu in these nanoparticles was nearly the same as in the starting solutions. The structures of the particles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), selected area electron diffraction (SAED) spectroscopy, and vibrating sample magnetometry (VSM). The results of XRD and VSM confirmed that there was no metastable alloying in the particles. The particles were composites, consisting of nanoscale crystallites of face-centered cubic (fcc) Cu, face-centered cubic (fcc) Ni, and face-centered cubic (fcc) Co. During preparation the nucleation of Cu occurred first; then small Cu nuclei acted as cores for the precipitation of Co and Ni. The particles showed an increase in saturation magnetization (M(s)) as the concentration of Co or Ni in the particles was increased. The changes of both M(s) and coercivity of the particles with increasing annealing temperatures were studied. The coercivity of the particles was very high; it could reach as high as 489 Oe for Co34.3Ni31.2Cu34.5) .
authors.affiliation: Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China. wwzhang429@sina.com
authors.forename: Wen-Wei
authors.initials: WW
authors.lastname: Zhang
authors.forename: Qing-Qi
authors.initials: QQ
authors.lastname: Cao
authors.forename: Jin-Li
authors.initials: JL
authors.lastname: Xie
authors.forename: Xiao-Ming
authors.initials: XM
authors.lastname: Ren
authors.forename: Chang-Sheng
authors.initials: CS
authors.lastname: Lu
authors.forename: Yang
authors.initials: Y
authors.lastname: Zhou
authors.forename: Yuan-Gen
authors.initials: YG
authors.lastname: Yao
authors.forename: Qing-Jin
authors.initials: QJ
authors.lastname: Meng