Acyl 1,3-migration in rhodium-catalyzed reactions of acetylenic beta-ketoesters with aryl boronic acids: application to two-carbon-atom ring expansions.
Miura
Tomoya
T
Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan.
Shimada
Masahiko
M
Murakami
Masahiro
M
D000107:Acetylation; D000480:Alkynes / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D004952:Esters / Q000138:chemical synthesis* / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
D000480:Alkynes; D001897:Boronic Acids; D004952:Esters; D007659:Ketones; D009942:Organometallic Compounds; D002244:Carbon; D012238:Rhodium