title: Regio- and stereoselectivity in preparation of 2-deoxysugar glycoglycerolipid derivatives evaluated by high resolution 1H NMR.
abstract: New glycoglycerolipids, derivatives of 2-deoxysugars bearing one or two fatty acid chains have been synthesised. Various levels of regio- and stereoselectivity have been attained for the triphenylphosphine hydrobromide (TPHB) catalysed addition of the glycerol moiety to some representative glycals. The influence of the structure of glycal derivatives in glycosylation reactions is discussed.
authors.affiliation: Department of Organic Chemistry, Bioorganic Chemistry and Biotechnology, Faculty of Chemistry, Silesian University of Technology, 44-100 Gliwice, Krzywoustego 4, Poland. ilona.wandzik@polsl.pl
authors.forename: Ilona
authors.initials: I
authors.lastname: Wandzik
authors.forename: Joanna
authors.initials: J
authors.lastname: Bugla
authors.forename: Wiesław
authors.initials: W
authors.lastname: Szeja
mesh_terms: D055598:Chemical Phenomena; D002627:Chemistry, Physical; D006017:Glycolipids / Q000138:chemical synthesis* / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D006017:Glycolipids; C015903:glycerolglycolipids