title: Preparation of (Cyanomethylene)tributylphosphorane: a new mitsunobu-type reagent.
abstract: (Cyanomethylene)tributylphosphorane (CMBP), which promoted the alkylation of various nucleophiles (HA) with alcohols (ROH) to give RA (Mitsunobu-type reaction), was prepared in two steps starting from chloroacetonitrile.
authors.affiliation: Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Japan.
authors.forename: Izumi
authors.initials: I
authors.lastname: Sakamoto
authors.forename: Takeshi
authors.initials: T
authors.lastname: Nishii
authors.forename: Fumie
authors.initials: F
authors.lastname: Ozaki
authors.forename: Hiroto
authors.initials: H
authors.lastname: Kaku
authors.forename: Masami
authors.initials: M
authors.lastname: Tanaka
authors.forename: Tetsuto
authors.initials: T
authors.lastname: Tsunoda
mesh_terms: D000097:Acetonitriles; D000438:Alcohols; D000478:Alkylation; D007202:Indicators and Reagents / Q000138:chemical synthesis*; D009682:Magnetic Resonance Spectroscopy; D014050:Toluene
chemical_list: D000097:Acetonitriles; D000438:Alcohols; D007202:Indicators and Reagents; D014050:Toluene; C069277:chloroacetonitrile