[Di-2-pyridyl ketone N4,N4-(butane-1,4-diyl)thiosemicarbazonato-kappa3N,N',S]dioxovanadium(V).
The V(V) atom in the title complex, [V(C(16)H(16)N(5)S)O(2)], is five-coordinate in a highly distorted square-pyramidal geometry, with the pyridyl N, the azomethine N and the thiolate S atoms of the di-2-pyridyl ketone N(4),N(4)-(butane-1,4-diyl)thiosemicarbazone ligand and one oxo ligand occupying the basal coordination positions, while the second oxo ligand occupies the apical position. The molecules are interconnected by weak intermolecular interactions, mainly of the C-H...O type, involving the oxo atoms.
Philip
Varughese
V
Department of Applied Chemistry, Cochin University of Science and Technology, Kochi 682 022, Kerala, India.
Manoj
E
E
Prathapachandra Kurup
M R
MR
Nethaji
Munirathinam
M