Studies on intrinsic ionization constants of Fe-Al-Mg hydrotalcite-like compounds.
The theoretical analysis of the intrinsic ionization constant (K(a2)(int)) of Fe-Al-Mg hydrotalcite-like compounds (HTlc) possessing permanent charges was first performed using the double extrapolation method proposed by James et al. The theoretical permanent charge density (sigma(p,T)) of the HTlc sample was calculated from the crystal structure of HTlc, and the influence of sigma(p,T) on the K(a2)(int) was also examined. From the experimental results, these conclusions can be obtained: the zero point of the charge (pH(ZPC)) of Fe-Al-Mg HTlc increases with decreased Fe3+ content and increases with increased Mg2+ in the HTlc. The pK(a2)(int) of Fe-Al-Mg HTlc also increases with decreased Fe3+ and increased Mg2+ content in the sample; furthermore, the pK(a2)(int) of Fe-Al-Mg HTlc increases with decreased sigma(p,T).
Li
Shu-Ping
SP
Key Laboratory for Colloid and Interface Chemistry of Education Ministry, Shandong University, Jinan, Shandong 250100, People's Republic of China. lishuping2@yahoo.com.cn
Hou
Wan-Guo
WG
Han
Shu-Hua
SH
Li
Li-Fang
LF
Zhao
Wei-An
WA