title: Effect of ionic surfactants on the phase behavior and structure of sucrose ester/water/oil systems.
abstract: The phase behavior and structure of sucrose ester/water/oil systems in the presence of long-chain cosurfactant (monolaurin) and small amounts of ionic surfactants was investigated by phase study and small angle X-ray scattering. In a water/sucrose ester/monolaurin/decane system at 27 degrees C, instead of a three-phase microemulsion, lamellar liquid crystals are formed in the dilute region. Unlike other systems in the presence of alcohol as cosurfactant, the HLB composition does not change with dilution, since monolaurin adsorbs almost completely in the interface. The addition of small amounts of ionic surfactant, regardless of the counterion, increases the solubilization of water in W/O microemulsions. The solubilization on oil in O/W microemulsions is not much affected, but structuring is induced and a viscous isotropic phase is formed. At high ionic surfactant concentrations, the single-phase microemulsion disappears and liquid crystals are favored.
authors.affiliation: Graduate School of Environment and Information Sciences, Yokohama National University, Tokiwadai 79-7, Hodogaya-ku, Yokohama 240-8501, Japan.
authors.forename: Carlos
authors.initials: C
authors.lastname: Rodríguez
authors.forename: Durga P
authors.initials: DP
authors.lastname: Acharya
authors.forename: Shigeki
authors.initials: S
authors.lastname: Hinata
authors.forename: Masahiko
authors.initials: M
authors.lastname: Ishitobi
authors.forename: Hironobu
authors.initials: H
authors.lastname: Kunieda