Rhombimines-cyclic tetraimines of trans-1,2-diaminocyclohexane shaped by the diaryl ether structural motif.
[reaction: see text] Rhombimines, chiral macrocyclic tetraimines, are preferentially formed because of the structural bias in the reaction of aromatic ether-linked dialdehydes with enantiomerically pure trans-1,2-diaminocyclohexane.
Gawroński
Jacek
J
Department of Chemistry, A. Mickiewicz University, 60 780 Poznan, Poland. gawronsk@amu.edu.pl
Brzostowska
Małgorzata
M
Kwit
Marcin
M
Plutecka
Agnieszka
A
Rychlewska
Urszula
U
D003514:Cyclohexylamines / Q000737:chemistry*; D007097:Imines / Q000138:chemical synthesis* / Q000737:chemistry; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008968:Molecular Conformation; D013237:Stereoisomerism
D003514:Cyclohexylamines; D007097:Imines; D047028:Macrocyclic Compounds; C030435:1,2-cyclohexanediamine