On the stereospecific conversion of proximally-oxygenated trisubstituted vinyltriphenylstannanes into stereodefined trisubstituted alkenes.
[reaction: see text] Allylically oxygenated vinyl alpha-triphenylstannanes such as 22 can be readily converted into vinyl iodides and thereafter stereodefined trisubstituted alkenes with retention of configuration.
Dimopoulos
Paschalis
P
The Christopher Ingold Laboratories, The Chemistry Department, University College London, 20 Gordon Street, London WC1H 0AJ, United Kingdom.
Athlan
Audrey
A
Manaviazar
Soraya
S
Hale
Karl J
KJ