title: Merging homogeneous catalysis with biocatalysis; papain as hydrogenation catalyst.
abstract: Papain, modified at Cys-25 with a monodentate phosphite ligand and complexed with Rh(COD)2BF4, is an active catalyst in the hydrogenation of methyl 2-acetamidoacrylate.
authors.affiliation: Department of Organic & Molecular Inorganic Chemistry, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands.
authors.forename: Lavinia
authors.initials: L
authors.lastname: Panella
authors.forename: Jaap
authors.initials: J
authors.lastname: Broos
authors.forename: Jianfeng
authors.initials: J
authors.lastname: Jin
authors.forename: Marco W
authors.initials: MW
authors.lastname: Fraaije
authors.forename: Dick B
authors.initials: DB
authors.lastname: Janssen
authors.forename: Margot
authors.initials: M
authors.lastname: Jeronimus-Stratingh
authors.forename: Ben L
authors.initials: BL
authors.lastname: Feringa
authors.forename: Adriaan J
authors.initials: AJ
authors.lastname: Minnaard
authors.forename: Johannes G
authors.initials: JG
authors.lastname: de Vries
mesh_terms: D002384:Catalysis; D006865:Hydrogenation; D006868:Hydrolysis; D015394:Molecular Structure; D010206:Papain / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization
chemical_list: D010206:Papain