title: Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center.
abstract: Treatment of mononuclear nonheme iron(II) complexes bearing two cis-labile sites with perbenzoic acids results in the self-hydroxylation of the aromatic ring to form the corresponding iron(III)-salicylate complexes through an intramolecular oxo-transfer process.
authors.affiliation: Department of Chemistry, Division of Nano Sciences and Center for Biomimetic Systems, Ewha Womans University, Seoul, 120-750, Korea.
authors.forename: Na Young
authors.initials: NY
authors.lastname: Oh
authors.forename: Mi Sook
authors.initials: MS
authors.lastname: Seo
authors.forename: Mi Hee
authors.initials: MH
authors.lastname: Lim
authors.forename: Mark B
authors.initials: MB
authors.lastname: Consugar
authors.forename: Mi Joo
authors.initials: MJ
authors.lastname: Park
authors.forename: Jan-Uwe
authors.initials: JU
authors.lastname: Rohde
authors.forename: Jaehong
authors.initials: J
authors.lastname: Han
authors.forename: Kwan Mook
authors.initials: KM
authors.lastname: Kim
authors.forename: Jinheung
authors.initials: J
authors.lastname: Kim
authors.forename: Lawrence
authors.initials: L
authors.lastname: Que
authors.forename: Wonwoo
authors.initials: W
authors.lastname: Nam
mesh_terms: D001565:Benzoates / Q000737:chemistry*; D006418:Heme / Q000737:chemistry; D006900:Hydroxylation; D007501:Iron / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction
chemical_list: D001565:Benzoates; D006418:Heme; C017611:peroxybenzoic acid; D007501:Iron