Catalytic and enantioselective allylic C-H activation with donor-acceptor-substituted carbenoids.
In this perspective we give an overview of enantioselective C-H activation at allylic sites by means of rhodium(II)-stabilized donor-acceptor-substituted carbenoids. This methodology has been proven to be both an equivalent to established asymmetric reaction sequences and a new synthetic approach with no established counterpart in organic synthesis.
Davies
Huw M L
HM
Department of Chemistry, University at Buffalo, The State University of New York, Buffalo 14260, USA. hdavies@acsu.buffalo.edu
Nikolai
Joachim
J