title: Synthesis of C8 alkyl glycosides via palladium-catalyzed telomerization of butadiene with O-benzylated aldoses.
abstract: Conditions of the butadiene telomerization with benzylated aldoses with a free anomeric hydroxyl, which efficiently furnish the corresponding octadienyl compounds have been determined. Deprotection and hydrogenation of the telomers over Pd/C led to the octyl glycosides.
authors.affiliation: Unité Mixte de Recherche Réactions Sélectives et Applications, CNRS-Université de Reims Champagne-Ardenne, B.P. 1039, 51687 Reims, France.
authors.forename: Alla
authors.initials: A
authors.lastname: Bessmertnykh
authors.forename: Françoise
authors.initials: F
authors.lastname: Hénin
authors.forename: Anna
authors.initials: A
authors.lastname: Serra-Muns
authors.forename: Jacques
authors.initials: J
authors.lastname: Muzart
authors.forename: Henri
authors.initials: H
authors.lastname: Baillia
mesh_terms: D001593:Benzyl Compounds / Q000737:chemistry*; D002070:Butadienes / Q000737:chemistry*; D002384:Catalysis; D006027:Glycosides / Q000138:chemical synthesis*; D006865:Hydrogenation; D010165:Palladium / Q000737:chemistry
chemical_list: D001593:Benzyl Compounds; D002070:Butadienes; D006027:Glycosides; D010165:Palladium; C031763:1,3-butadiene