title: Effect of glass fiber surface treatments on mechanical strength of epoxy based composite materials.
abstract: Sizing glass fibers with silane coupling agents enhances the adhesion and the durability of the fiber/polymer matrix interface in composite materials. There are several tests to determine the interfacial strength between a fiber and resin, but all of them present difficulties in interpreting the results and/or sample preparation. In this study, we observed the influence of different aminosilanes fiber coatings on the resistance of epoxy-based composite materials using a very easy fractographic test. In addition, we tried a new fluorescence method to get information on a molecular level precisely at the interface. Strength was taken into account from two standpoints: (i) mechanical strength and (ii) the resistance to hydrolysis of the interface in oriented glass-reinforced epoxy-based composites. Three silanes: gamma-aminopropyltriethoxysilane, gamma-Aminopropylmethyldiethoxysilane, and gamma-Aminopropyldimethylethoxysilane were used to obtain different molecular structures at the interface. It was concluded that: (i) the more accessible amine groups are, the higher the interface rigidity is; (ii) an interpenetrating network mechanism seems to be the most important for adhesion and therefore to the interfacial strength; and (iii) the higher the degree of crosslinking in the silane coupling layer is, the higher the hydrolytic damage rate is.
authors.affiliation: Departamento de Ciencia de Materiales, Universidad Carlos III de Madrid, Madrid, Spain.
authors.forename: J G
authors.initials: JG
authors.lastname: Iglesias
authors.forename: J
authors.initials: J
authors.lastname: González-Benito
authors.forename: A J
authors.initials: AJ
authors.lastname: Aznar
authors.forename: J
authors.initials: J
authors.lastname: Bravo
authors.forename: J
authors.initials: J
authors.lastname: Baselga