A metal-oxo mediated approach to the synthesis of 21,22-diepi-membrarollin.
A synthesis of 21,22-diepi-membrarollin (14) is described, which employed sequential metal-oxo mediated oxidative cyclisations to introduce six of the seven stereogenic centres.
Hu
Yulai
Y
School of Chemistry, University of Southampton, Highfield, Southampton, UK SO17 1BJ.
Brown
Richard C D
RC