title: Botanical and geographical origin identification of industrial ethanol by stable isotope analyses of C, H, and O.
abstract: The isotope ratios of carbon, hydrogen, and oxygen of rectified alcohols were determined to distinguish their botanical and geographical origins by continuous flow-isotope ratio mass spectrometry (CF-IRMS). The (13)C/(12)C and (18)O/(16)O ratios of 27 fermented alcohols with known origins showed clusters derived from each botanical origin, viz. corn, sugarcane, wheat, and tapioca. C3 and C4 plants were easily distinguishable by the (13)C/(12)C ratio. Sugarcane and corn are both C4 plants, and they showed small differences in isotope ratios. The combination plots of the D/H and (18)O/(16)O ratios enabled us to designate the geographical origins of alcohol derived from the same kind of crop, such as Chinese or American corn. The chemically synthetic and fermented alcohols were clearly distinguished by D/H and (18)O/(16)O ratios. Isotope ratios were useful for origin identification of alcohol. We plan to construct a database of alcohol isotope ratios to determine the origins of raw materials in alcohol.
authors.affiliation: R and D Center, Alcohol Enterprise Head Office, New Energy and Industrial Technology Development Organization, Chiba, Japan. fujii@jp-alcohol.com
authors.forename: Keiko
authors.initials: K
authors.lastname: Ishida-Fujii
authors.forename: Shingo
authors.initials: S
authors.lastname: Goto
authors.forename: Ryu
authors.initials: R
authors.lastname: Uemura
authors.forename: Keita
authors.initials: K
authors.lastname: Yamada
authors.forename: Michikatsu
authors.initials: M
authors.lastname: Sato
authors.forename: Naohiro
authors.initials: N
authors.lastname: Yoshida
mesh_terms: D002247:Carbon Isotopes / Q000032:analysis; D000431:Ethanol / Q000032:analysis*; D005285:Fermentation; D005843:Geography; D006859:Hydrogen / Q000032:analysis; D007554:Isotopes / Q000032:analysis*; D010103:Oxygen Isotopes / Q000032:analysis; D010944:Plants
chemical_list: D002247:Carbon Isotopes; D007554:Isotopes; D010103:Oxygen Isotopes; D000431:Ethanol; D006859:Hydrogen