title: Water sorption studies of hybrid biofiber-reinforced natural rubber biocomposites.
abstract: Hybrid biofibers (sisal and oil palm) were incorporated into natural rubber matrix. The water absorption characteristics of the composites were evaluated with reference to fiber loading. The influence of temperature on water sorption of the composites is also analyzed. Moisture uptake was found to be dependent on the properties of the biofibers. The mechanism of diffusion in the gum sample was found to be Fickian in nature, while in the loaded composites, it was non-Fickian. Sisal and oil palm fibers were subjected to different treatments such as mercerization and silanation. The effect of chemical modification on moisture uptake was also analyzed. Chemical modification was seen to decrease the water uptake in the composites. The thermodynamic parameters of the sorption process were also evaluated. Activation energy was found to be maximum for the gum sample.
authors.affiliation: School of Chemical Sciences, Mahatma Gandhi University, Priyadarshini Hills P.O. Kottayam, Kerala, India-686 560.
authors.forename: Maya
authors.initials: M
authors.lastname: Jacob
authors.forename: K T
authors.initials: KT
authors.lastname: Varughese
authors.forename: Sabu
authors.initials: S
authors.lastname: Thomas
mesh_terms: D000042:Absorption; D001672:Biocompatible Materials / Q000737:chemistry*; D001703:Biophysics / Q000379:methods; D004058:Diffusion; D007700:Kinetics; D046911:Macromolecular Substances / Q000737:chemistry*; D008422:Materials Testing; D008855:Microscopy, Electron, Scanning; D008956:Models, Chemical; D000073878:Palm Oil; D010938:Plant Oils / Q000737:chemistry; D019279:Resin Cements; D012408:Rubber / Q000737:chemistry; D012821:Silanes / Q000737:chemistry; D013696:Temperature; D013816:Thermodynamics; D013997:Time Factors; D014867:Water / Q000737:chemistry*
chemical_list: D001672:Biocompatible Materials; D046911:Macromolecular Substances; D010938:Plant Oils; D019279:Resin Cements; D012821:Silanes; D014867:Water; D000073878:Palm Oil; D012408:Rubber