Adhesive properties and kinetic polymerization behavior of resins containing adhesion promoting monomers for precious metals.
Adhesion promoting monomers -5-(4-vinylbenzyl)-2-thiobarbituric acid (5VS), 9,10-epithiodecyl methacrylate (EP8MA), 9,10-epithiodecyl 4-vinylbenzoate (EP8VB), and 3,4-epithiobutyl 2,2-bis(methacryloyloxymethyl)propionate (EP2BMA)--were added to the MMA liquid of a MMA-PMMA/TBBO resin. Three dental precious metal alloys were butt-jointed together with the MMA-PMMA/TBBO adhesive resin, and tensile bond strength was measured after 2,000 thermocycles in water. Polymerization kinetics of MMA by 2,2'-azobis (isobutyronitrile) at 70 degrees C in the presence of 5VS, EP8MA, EP8VB, or EP2BMA were examined quantitatively using a DSC to clarify the relationship between the adhesive properties of MMA-PMMA/TBBO adhesive resin and the kinetic polymerization behavior thereof. Obtained kinetic parameters indicated that 5VS was not suitable as an adhesive monomer for adhesive resin formulations and that EP2BMA possessed the latent potential as an adhesive monomer. Further, tensile test results revealed the applicability of EP8MA, EP8VB, and EP2BMA as an adhesive monomer component of adhesive resin formulations.
Kadoma
Yoshinori
Y
Department of Applied Functional Molecules, Division of Biofunctional Molecules, Institute of Biomaterials and Bioengineering, Tokyo Medical and Dental University, 2-3-10, Kanda-surugadai, Chiyoda-ku, Tokyo 101-0062, Japan. y-kadoma.fm@tmd.ac.jp
D000268:Adhesiveness; D001896:Boron Compounds / Q000737:chemistry; D002152:Calorimetry, Differential Scanning; D003188:Composite Resins / Q000737:chemistry*; D003722:Dental Alloys / Q000737:chemistry*; D001840:Dental Bonding; D003799:Dental Stress Analysis; D006047:Gold Alloys / Q000737:chemistry; D006573:Heterocyclic Compounds, 1-Ring / Q000737:chemistry; D006801:Humans; D007700:Kinetics; D008422:Materials Testing; D008689:Methacrylates / Q000737:chemistry; D008768:Methylmethacrylates / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D019904:Polymethyl Methacrylate / Q000737:chemistry; D019279:Resin Cements / Q000737:chemistry*; D012834:Silver / Q000737:chemistry; D013314:Stress, Mechanical; D013343:Styrenes / Q000737:chemistry; D013718:Tensile Strength; D013858:Thiobarbiturates / Q000737:chemistry; D014867:Water / Q000737:chemistry
C481020:5-(4-vinylbenzyl)-2-thiobarbituric acid; C468512:9,10-epithiodecyl methacrylate; D001896:Boron Compounds; D003188:Composite Resins; D003722:Dental Alloys; D006047:Gold Alloys; D006573:Heterocyclic Compounds, 1-Ring; D008689:Methacrylates; D008768:Methylmethacrylates; D019279:Resin Cements; D013343:Styrenes; D013858:Thiobarbiturates; C476987:methylmethacrylate-tributylborane resin; D014867:Water; D012834:Silver; D010165:Palladium; D019904:Polymethyl Methacrylate; C105064:4-vinylbenzoic acid