Evidences for zeolite nucleation at the solid-liquid interface of gel cavities.
The entire sequence of crystallization events, starting with formation of the initial organic-cation-free gel, proceeding through the zeolite nucleation stage, and finishing with complete transformation into LTA-type zeolite crystals, has been monitored by means of high-resolution transmission electron microscopy. Formation and development of voids, containing highly hydrated material transformed later into negative crystals, has been discovered in the solid part of the system. The evolution of these areas has been found to be an integral and noteworthy part of the chemical transformation of the gel that preceded the nucleation in the system. These void structures and, in particular, their solid-liquid interfaces have been identified as the specific locations where the formation of protozeolite nuclei took place. Further development of the system followed the classical for zeolite-yielding systems of crystallization that could be described by the autocatalytic model.
Valtchev
Valentin P
VP
Laboratoire de Matériaux à Porosité Contrôlée, UMR-7016 CNRS, ENSCMu, Université de Haute Alsace, 3 rue Alfred Werner, 68093 Mulhouse Cedex, France. Valentin.Valtchev@uha.fr
Bozhilov
Krassimir N
KN