Feigrisolide C: structural revision and synthesis.
[Carbohydrate structure: see text] The original macrodiolide structure proposed for feigrisolide C was incorrect. The true structure of feigrisolide C was identified as (2'S,3'S,6'R,8'R)-homononactoyl (2R,3R,6S,8S)-nonactic acid, which was confirmed by total synthesis.
Kim
Woo Han
WH
Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea.
Jung
Jae Hoon
JH
Lee
Eun
E
D000900:Anti-Bacterial Agents / Q000138:chemical synthesis / Q000737:chemistry; D007783:Lactones / Q000138:chemical synthesis* / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure
D000900:Anti-Bacterial Agents; D007783:Lactones; C417114:feigrisolide A