Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center.
Treatment of mononuclear nonheme iron(II) complexes bearing two cis-labile sites with perbenzoic acids results in the self-hydroxylation of the aromatic ring to form the corresponding iron(III)-salicylate complexes through an intramolecular oxo-transfer process.
Oh
Na Young
NY
Department of Chemistry, Division of Nano Sciences and Center for Biomimetic Systems, Ewha Womans University, Seoul, 120-750, Korea.
Seo
Mi Sook
MS
Lim
Mi Hee
MH
Consugar
Mark B
MB
Park
Mi Joo
MJ
Rohde
Jan-Uwe
JU
Han
Jaehong
J
Kim
Kwan Mook
KM
Kim
Jinheung
J
Que
Lawrence
L
Nam
Wonwoo
W
D001565:Benzoates / Q000737:chemistry*; D006418:Heme / Q000737:chemistry; D006900:Hydroxylation; D007501:Iron / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction
D001565:Benzoates; D006418:Heme; C017611:peroxybenzoic acid; D007501:Iron