Merging homogeneous catalysis with biocatalysis; papain as hydrogenation catalyst.
Papain, modified at Cys-25 with a monodentate phosphite ligand and complexed with Rh(COD)2BF4, is an active catalyst in the hydrogenation of methyl 2-acetamidoacrylate.
Panella
Lavinia
L
Department of Organic & Molecular Inorganic Chemistry, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands.
Broos
Jaap
J
Jin
Jianfeng
J
Fraaije
Marco W
MW
Janssen
Dick B
DB
Jeronimus-Stratingh
Margot
M
Feringa
Ben L
BL
Minnaard
Adriaan J
AJ
de Vries
Johannes G
JG
D002384:Catalysis; D006865:Hydrogenation; D006868:Hydrolysis; D015394:Molecular Structure; D010206:Papain / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization
D010206:Papain