Stereospecific addition of H-P bond to alkenes: a simple method for the preparation of (R(P))-phenylphosphinates.
[reaction: see text] A variety of functionalized optically pure (R(P))-alkylphenylphosphinates are readily prepared by stereospecific radical or base-catalyzed additions of the easily available (R(P))-menthyl phenylphosphinate to alkenes.
Han
Li-Biao
LB
National Institute of Advanced Industrial Science and Technology, Tsukuba, Ibaraki 305-8565, Japan. libiao-han@aist.go.jp
Zhao
Chang-Qiu
CQ
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D010721:Phosphinic Acids / Q000737:chemistry*; D013237:Stereoisomerism
D000475:Alkenes; D010721:Phosphinic Acids; C480970:phenylphosphinic acid