Preferential interactions in pigmented, polymer blends - C.I. Pigment Blue 15:4 and C.I. Pigment Red 122 - as used in a poly(carbonate)-poly(butylene terephthalate) polymer blend.
Some important characteristics of selected pigments have been evaluated, using the inverse gas chromatography (IGC) technique, that indicate the occurrence of preferential interactions in pigmented polymer blends. Attention has been given to copper phthalocyanine pigments and to quinacridone pigments incorporated in polycarbonate-poly(butylene terephthalate) blends. Selected supporting techniques were used to provide supplementary information concerning the pigments of interest, C.I. Pigment Blue 15:4 and C.I. Pigment Red 122. For C.I. Pigment Red 122 and for C.I. Pigment Blue, the dispersive component of the surface free energy decreases as the temperature increases, indicating the relative ease with which the molecules can be removed from the surface.
Fagelman
K E
KE
Department of Colour and Polymer Chemistry, University of Leeds, West Yorkshire, UK.
Guthrie
J T
JT
D001391:Azo Compounds / Q000737:chemistry*; D002849:Chromatography, Gas / Q000379:methods*; D004396:Coloring Agents / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D009942:Organometallic Compounds / Q000737:chemistry*; D010316:Particle Size; D011091:Polyesters / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D013816:Thermodynamics
D001391:Azo Compounds; C506937:C.I. Pigment Blue 15:4; D004396:Coloring Agents; D009942:Organometallic Compounds; D011091:Polyesters; D011108:Polymers; C506938:poly(carbonate)-poly(butylene terephthalate) polymer; C069430:Pigment Red 22