Coordination chemistry of the hexavacant tungstophosphate [H2P(2W12O48]12-: synthesis and characterization of iron(III) complexes derived from the unprecedented {P2W14O54} fragment.
Clusters which display the rare cubic Fe8 topology have been obtained by reaction of the metastable hexavacant polyoxotungstate [H2P2W12O48]12- with basic trinuclear metal acetates.
Godin
Béatrice
B
Laboratoire de Chimie Inorganique et Matériaux Moléculaires, UMR CNRS 7071, Institut de Chimie Moléculaire FR 2769, Université Pierre et Marie Curie, 4 Place Jussieu, 75252 Paris Cedex 05, France.
Vaissermann
Jacqueline
J
Herson
Patrick
P
Ruhlmann
Laurent
L
Verdaguer
Michel
M
Gouzerh
Pierre
P