title: Lanthanum(III) and praseodymium(III) derivatives with dithiocarbamates derived from alpha-amino acids.
abstract: Lanthanum(III) and praseodymium(III) complexes with dithiocarbamates have been synthesized by the reactions of lanthanum(III) and praseodymium(III) chloride with barium dithiocarbamate and complexes of type [LnCl(L)H2O]n have been obtained (where Ln=La(III) or Pr(III); L=barium salt of dithiocarbamate derived from glycine, L-leucine, L-valine, DL-alanine). The complexes have been characterized by elemental analysis, molar conductance, electronic absorption and fluorescence, infrared, far infrared, 1H NMR spectral studies. The presence of coordinated water molecule is inferred from thermogravimetric analysis which indicates the loss of one water molecule at 150-170 degrees C. The oscillator strength, Judd-Ofelt intensity parameter, stimulated emission cross-section, etc. have been obtained for different transitions of Pr3+.
authors.affiliation: Department of Chemistry, Jagatpur P.G. College, Varanasi 221005, India. sbrai49@yahoo.co.in
authors.forename: Anita
authors.initials: A
authors.lastname: Rai
authors.forename: Soumitra K
authors.initials: SK
authors.lastname: Sengupta
authors.forename: Om P
authors.initials: OP
authors.lastname: Pandey
mesh_terms: D000596:Amino Acids / Q000737:chemistry*; D007811:Lanthanum / Q000737:chemistry*; D011221:Praseodymium / Q000737:chemistry*; D013050:Spectrometry, Fluorescence; D013859:Thiocarbamates / Q000737:chemistry*
chemical_list: D000596:Amino Acids; D013859:Thiocarbamates; D007811:Lanthanum; D011221:Praseodymium