Measuring rate constants for active species in the polymerization of ethylene by MAO-activated metallocene catalysts by electrospray ionization mass spectrometry.
Electrospray ionization mass spectrometry (ESI-MS) of MAO-activated metallocene-catalyzed polymerizations quenched with carbodiimides provides a method for the determination of rate constants in Ziegler-Natta polymerizations.
di Lena
Fabio
F
Laboratorium für Organische Chemie, ETH Zürich, Switzerland.
Quintanilla
Esther
E
Chen
Peter
P