Forensic analysis of architectural finishes using fourier transform infrared and Raman spectroscopy, part I: the resin bases.
The ability of Raman spectroscopy and Fourier transform infrared (FT-IR) microscopy to discriminate between resins used for the manufacture of architectural finishes was examined in a study of 39 samples taken from a commercial resin library. Both Raman and FT-IR were able to discriminate between different types of resin and both split the samples into several groups (six for FT-IR, six for Raman), each of which gave similar, but not identical, spectra. In addition, three resins gave unique Raman spectra (four in FT-IR). However, approximately half the library comprised samples that were sufficiently similar that they fell into a single large group, whether classified using FT-IR or Raman, although the remaining samples fell into much smaller groups. Further sub-division of the FT-IR groups was not possible because the experimental uncertainty was of similar magnitude to the within-group variation. In contrast, Raman spectroscopy was able to further discriminate between resins that fell within the same groups because the differences in the relative band intensities of the resins, although small, were larger than the experimental uncertainty.
Bell
Steven E J
SE
School of Chemistry, Queen's University, Belfast, BT9 5AG, U.K. s.bell@qub.ac.uk
Fido
Louise A
LA
Speers
S James
SJ
Armstrong
W James
WJ
Spratt
Sharon
S
D001108:Architecture / Q000379:methods*; D003252:Construction Materials / Q000032:analysis*; D044707:Forensic Sciences / Q000379:methods*; D010150:Paint / Q000032:analysis*; D012117:Resins, Synthetic / Q000032:analysis*; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods*; D013059:Spectrum Analysis, Raman / Q000379:methods*
D012117:Resins, Synthetic