Model studies towards the synthesis of gilvocarcin M.
In model studies towards the synthesis of gilvocarcin M, a convergent, xanthate-based free-radical strategy was tested in order to construct the key aromatic ring attached to the sugar unit.
Cordero-Vargas
Alejandro
A
Laboratoire de Synthèse Organique associé au CNRS, Ecole Polytechnique, 91128 Palaiseau, France. cordero@dcso.polytechnique.fr
Quiclet-Sire
Béatrice
B
Zard
Samir Z
SZ
D000617:Aminoglycosides / Q000138:chemical synthesis* / Q000737:chemistry / Q000145:classification; D002384:Catalysis; D003374:Coumarins; D003500:Cyclization; D003516:Cycloparaffins / Q000737:chemistry; D006027:Glycosides; D007783:Lactones / Q000737:chemistry; D007854:Lead; D008956:Models, Chemical; D015394:Molecular Structure
D000617:Aminoglycosides; D003374:Coumarins; D003516:Cycloparaffins; D006027:Glycosides; D007783:Lactones; D007854:Lead; C031782:gilvocarcin M