title: Calculations on the group 15 intraring substituted benzenes (pyridine to bismin series) and their datively bonded oxides and sulfides.
abstract: The series of heterocyclic compounds pyridine, phosphorin, arsenin, antimonin, bismin, and the related series of pyridine oxide, etc., and pyridine sulfide, etc., were investigated using density functional theory. In addition to molecular geometries and energies, the nucleus independent chemical shift (NICS) values were calculated for each ring, and the CHELPG atomic charges were calculated. Calculated heats of formation are: pyridine +133, phosphorin +181, arsenin +231, antimonin +329, bismin +468, pyridine oxide +143, phosphorin oxide +1, arsenin oxide +183, antimonin oxide +344, bismin oxide +570, pyridine sulfide +252, phosphorin sulfide +205, arsenin sulfide +328, antimonin sulfide +435, and bismin sulfide + 642 kJ/mol. The question of aromaticity for these heterocycles was discussed. On the basis of hydrogenation energies, NICS values, and lack of bond alternation, the entire series from pyridine to bismin appears to be aromatic and to a roughly equal degree. The situation for the oxides and sulfides of pyridine, phosphorin, and arsenin is much the same, but bismin oxide and bismin sulfide are nonplanar and according to NICS nonaromatic. Antimonin oxide is aromatic by some of the criteria and nonaromatic by others.
authors.affiliation: dshobe@sud-chemieinc.com
authors.forename: David S
authors.initials: DS
authors.lastname: Shobe