Polymer resin library and the discovery of highly efficient polymer supported reagents and scavengers.
This paper is focused on the preparation of a library of highly efficient, tailor made, macroporous resins as supports for reagents and scavengers. From this library a macroporous resin, prepared with 40% cross-linking and with a porogen level of 300% in toluene gave a material superior to those presently available, and was shown to be highly efficient in the preparation of novel highly reactive polymer supported reagents, including scavengers and oxidants.
Galaffu
Nicola
N
Combinatorial Centre of Excellence, School of Chemistry, University of Southampton, Highfield, Southampton, SO 17 1BJ, UK.
Sechi
Gianluca
G
Bradley
Mark
M
D020650:Combinatorial Chemistry Techniques; D006536:Heptanes; D007202:Indicators and Reagents / Q000737:chemistry; D007475:Ion Exchange Resins / Q000138:chemical synthesis; D017953:Isocyanates / Q000138:chemical synthesis; D008863:Microspheres; D010084:Oxidation-Reduction; D011108:Polymers / Q000737:chemistry*; D012117:Resins, Synthetic / Q000737:chemistry*; D013440:Sulfides; D014050:Toluene
D006536:Heptanes; D007202:Indicators and Reagents; D007475:Ion Exchange Resins; D017953:Isocyanates; D011108:Polymers; D012117:Resins, Synthetic; D013440:Sulfides; D014050:Toluene