Preparation and characterization of unique inorganic-organic hybrid mesoporous materials incorporating arenetricarbonyl complexes [-C6H4M(CO)3-] (M = Cr, Mo).
Unique inorganic-organic hybrid mesoporous materials incorporating arenetricarbonyl complexes [-C6H4M(CO)3-] (M = Cr, Mo) within their mesoporous frameworks have been successfully prepared by a simple CVD treatment of the phenylene-bridged organosilica mesoporous materials with metal hexacarbonyls [M(CO)6] (M = Cr, Mo). FT-IR and UV-vis investigations revealed that the arenetricarbonyl complexes exist stably even at temperatures above 473 K under vacuum.
Kamegawa
Takashi
T
Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, Japan.
Sakai
Takahiro
T
Matsuoka
Masaya
M
Anpo
Masakazu
M