title: Density of hydrous silicate melt at the conditions of Earth's deep upper mantle.
abstract: The chemical evolution of the Earth and the terrestrial planets is largely controlled by the density of silicate melts. If melt density is higher than that of the surrounding solid, incompatible elements dissolved in the melt will be sequestered in the deep mantle. Previous studies on dry (water-free) melts showed that the density of silicate melts can be higher than that of surrounding solids under deep mantle conditions. However, melts formed under deep mantle conditions are also likely to contain some water, which will reduce the melt density. Here we present data constraining the density of hydrous silicate melt at the conditions of approximately 410 km depth. We show that the water in the silicate melt is more compressible than the other components, and therefore the effect of water in reducing melt density is markedly diminished under high-pressure conditions. Our study indicates that there is a range of conditions under which a (hydrous) melt could be trapped at the 410-km boundary and hence incompatible elements could be sequestered in the deep mantle, although these conditions are sensitive to melt composition as well as the composition of the surrounding mantle.
authors.affiliation: Department of Environmental Sciences, Ibaraki University, Mito, Ibaraki 310-0056, Japan. kmatsu@mx.ibaraki.ac.jp
authors.forename: Kyoko N
authors.initials: KN
authors.lastname: Matsukage
authors.forename: Zhicheng
authors.initials: Z
authors.lastname: Jing
authors.forename: Shun-ichiro
authors.initials: S
authors.lastname: Karato