title: Polymer resin library and the discovery of highly efficient polymer supported reagents and scavengers.
abstract: This paper is focused on the preparation of a library of highly efficient, tailor made, macroporous resins as supports for reagents and scavengers. From this library a macroporous resin, prepared with 40% cross-linking and with a porogen level of 300% in toluene gave a material superior to those presently available, and was shown to be highly efficient in the preparation of novel highly reactive polymer supported reagents, including scavengers and oxidants.
authors.affiliation: Combinatorial Centre of Excellence, School of Chemistry, University of Southampton, Highfield, Southampton, SO 17 1BJ, UK.
authors.forename: Nicola
authors.initials: N
authors.lastname: Galaffu
authors.forename: Gianluca
authors.initials: G
authors.lastname: Sechi
authors.forename: Mark
authors.initials: M
authors.lastname: Bradley
mesh_terms: D020650:Combinatorial Chemistry Techniques; D006536:Heptanes; D007202:Indicators and Reagents / Q000737:chemistry; D007475:Ion Exchange Resins / Q000138:chemical synthesis; D017953:Isocyanates / Q000138:chemical synthesis; D008863:Microspheres; D010084:Oxidation-Reduction; D011108:Polymers / Q000737:chemistry*; D012117:Resins, Synthetic / Q000737:chemistry*; D013440:Sulfides; D014050:Toluene
chemical_list: D006536:Heptanes; D007202:Indicators and Reagents; D007475:Ion Exchange Resins; D017953:Isocyanates; D011108:Polymers; D012117:Resins, Synthetic; D013440:Sulfides; D014050:Toluene