title: Ternary Mn/Ge/Se anions from reactions of [Ba2(H2O)9][GeSe4]: synthesis and characterization of compounds containing discrete or polymeric [Mn6Ge4Se17]6- units.
abstract: [Ba2(H2O)9][GeSe4] is suitable for the formation of novel M/14/16 anions [Mn6Ge4Se17]6- --discrete or linked in an as yet unprecedented porous network--with antiferromagnetically coupled Mn(II) centers and relatively small electronic excitation energies.
authors.affiliation: Institut für Anorganische Chemie der Universität Karlsruhe (TH), Engesserstrasse 15, 76131 Karlsruhe, Germany.
authors.forename: Maike
authors.initials: M
authors.lastname: Melullis
authors.forename: Rodolphe
authors.initials: R
authors.lastname: Clérac
authors.forename: Stefanie
authors.initials: S
authors.lastname: Dehnen