title: Concomitant dimorphs of tri-O-[p-halobenzoyl]-myo-inositol 1,3,5-orthoformates with different halogen bonding contacts: first order crystal-to-crystal thermal phase transition of kinetic form to the thermodynamic form.
abstract: Crystallization of tri-O-[p-halobenzoyl]-myo-inositol 1,3,5-orthoformates from ethyl acetate-petroleum ether solution produced concomitant dimorphs that have different halogen bonding contacts; the kinetic form with C-Br...O-C contacts upon heating to 185 degrees C, converts completely to the thermodynamic form with C-Br...O=C contacts via crystal-to-crystal first order phase transition.
authors.affiliation: Center for Materials Characterization, National Chemical Laboratory, Pune, India.
authors.forename: Rajesh G
authors.initials: RG
authors.lastname: Gonnade
authors.forename: Mohan M
authors.initials: MM
authors.lastname: Bhadbhade
authors.forename: Mysore S
authors.initials: MS
authors.lastname: Shashidhar
authors.forename: Aditya K
authors.initials: AK
authors.lastname: Sanki