[Infrared spectra and coordinated mode of manganese (II), iron (II), cobalt (II) complexes with dithiolene and 1, 10-phenanthroline-5, 6-dione ligands].
The infrared spectra and far-infrared spectra of M(mnt)(phen-5, 6-dione) [M= Manganese(II), Iron(II), Cobalt(II). mnt2- = 1, 2-dicyano-1, 2-ethylenedithiolate or maleonitriledithiolate, phen-5, 6-dione = 1, 10-phenanthroline-5, 6-dione] are reported in detail. In infrared spectra and far-infrared, characteristic v (C[triplebond]N) , v (C==)) , (C==C) v (C-N), v (C-S), v (M-S) and V(M-N) are very strong. Far-infrared spectra shows that M-S bond is slightly strong than M-N bond. Through comparing infrared spectra, simple regular coordinate mode of M(mnt) (phen-5, 6-dione) is analysed. The relation between infrared spectra and structure of the title complexes is discussed. In the title complexes, transition metals ion with 1, 2-dicyano-1, 2-ethylenedithiolate and 1, 10-phenanthroline-5, 6-dione form quadridentate distortion tetrahedral configuration molecules. The symmetry is approximate to C2 and C2v.
Pan
Qing-cai
QC
Department of Chemistry and Chemical Engineering, Huanghuai College, Zhumadian 463000, China.
Zhao
Yong-he
YH
Peng
Zheng-he
ZH
D000465:Algorithms; D003035:Cobalt / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D008956:Models, Chemical; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010618:Phenanthrolines / Q000737:chemistry; D013055:Spectrophotometry, Infrared
D008024:Ligands; D009942:Organometallic Compounds; D010618:Phenanthrolines; D003035:Cobalt; D008345:Manganese; D007501:Iron