Determination of the helicity of oriented photofragments.
Equations to enable determination of the helicity (angular momentum orientation) of photofragments resulting from single-photon dissociation of an isotropic sample of molecules are presented. The symmetry of the photofragment distribution is illustrated by three-dimensional vector plots of the expectation values of projections of the fragment total angular momentum. Equations describing circular polarization of light in the spherical tensor basis are presented. Methods for the optical measurement of angular momentum orientation are discussed, including determination of the helicity of circularly polarized light by a quarter-wave plate or single Fresnel rhomb.
Alexander
Andrew J
AJ
School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh EH9 3JJ, Scotland, UK. andrew.alexander@ed.ac.uk