Radical polymerisation of styrene in porous coordination polymers.
The first radical polymerisation of styrene in porous coordination polymers has been carried out, providing stable propagating radicals (living radicals), and a specific space effect of the host frameworks on the monomer reactivity is demonstrated.
Uemura
Takashi
T
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Kyoto, 615-8510, Japan.
Kitagawa
Kana
K
Horike
Satoshi
S
Kawamura
Takashi
T
Kitagawa
Susumu
S
Mizuno
Motohiro
M
Endo
Kazunaka
K