2-Pyridinealdoxime, a new ligand for a Pd-precatalyst: application in solid-phase-assisted Suzuki-Miyaura reaction.
The preparation of a new palladium(II) complex with a 2-pyridinealdoxime ligand and its use as a Pd(0) precatalyst in the cross-coupling Suzuki-Miyaura reaction is described. Several concepts for the immobilization of this catalytic system are presented and compared in order to develop an efficient catalytic tool for high-throughput synthesis.
Solodenko
Wladimir
W
Institut für Organische Chemie, Universität Hannover, Schneiderberg 1b, D-30167, Hannover, Germany.
Brochwitz
Christoph
C
Wartchow
Rudolf
R
Hashem
Md Abul
MA
Dawood
Kamal M
KM
Vaultier
Michel
M
Kirschning
Andreas
A
D001897:Boronic Acids; D001965:Bromides; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D008024:Ligands; D008872:Microwaves; D008956:Models, Chemical; D010091:Oximes / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D002721:omega-Chloroacetophenone / Q000031:analogs & derivatives
D001897:Boronic Acids; D001965:Bromides; D008024:Ligands; D010091:Oximes; D011725:Pyridines; C023897:pentachloroacetophenone; D010165:Palladium; D002721:omega-Chloroacetophenone; C060977:pyridine-2-aldoxime