Recycling spent zinc manganese dioxide batteries through synthesizing Zn-Mn ferrite magnetic materials.
A novel process to reclaim spent zinc manganese dioxide batteries (SDBs) through synthesizing Zn-Mn ferrite magnetic materials is present. Firstly, the dismantling, watering, magnetism, baking and griddling steps were consecutively carried out to obtain iron battery shells, zinc grains and manganese compounds using the collected SDBs, and then these separated substances were dissolved with 4 mol L(-1) H(2)SO(4) to prepare FeSO(4), ZnSO(4) and MnSO(4) reactant solutions. Secondly, Zn-Mn ferrites with stoichiometric ratio of Mn(0.26)Zn(0.24)FeO(2) were synthesized using chemical co precipitation process with ammonium oxalate precipitator. The XRD results showed that the obtained Zn-Mn ferrites had spinel structure and high purity at the calcining temperatures of 850-1250 degrees C. With the increase of calcining temperature, the finer crystalline structure could be formed, and their intensity of saturation magnetization reached the highest value at 1150 degrees C. The magnetization performances of Zn-Mn ferrites prepared from the SDBs were similar to that of from analysis reagents, suggesting the feasibility to synthesize Zn-Mn ferrites with high properties from SDBs.
Nan
Junmin
J
School of Chemistry and Environment, South China Normal University, Guangzhou, Guangdong, PR China. jmnan@scnu.edu.cn
Han
Dongmei
D
Cui
Ming
M
Yang
Minjie
M
Pan
Linmao
L
D003247:Conservation of Natural Resources; D003460:Crystallization; D004560:Electricity; D005290:Ferric Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D008280:Magnetics; D017895:Manganese Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D010087:Oxides / Q000737:chemistry*; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D012996:Solutions; D013456:Sulfur Acids / Q000737:chemistry; D014961:X-Ray Diffraction; D015032:Zinc / Q000737:chemistry*; D017967:Zinc Compounds / Q000138:chemical synthesis* / Q000737:chemistry*
D005290:Ferric Compounds; D017895:Manganese Compounds; D010087:Oxides; D000644:Quaternary Ammonium Compounds; D012996:Solutions; D013456:Sulfur Acids; D017967:Zinc Compounds; C039048:manganese-zinc ferrite; D015032:Zinc; C016552:manganese dioxide