title: Preparation of a clay-modified carbon paste electrode based on 2-thiazoline-2-thiol-hexadecylammonium sorption for the sensitive determination of mercury.
abstract: A montmorillonite from Wyoming-USA was used to prepare an organo-clay complex, named 2-thiazoline-2-thiol-hexadecyltrimethylammonium-clay (TZT-HDTA-clay), for the purpose of the selective adsorption of the heavy metals ions and possible use as a chemically modified carbon paste electrode (CMCPE). Adsorption isotherms of Hg2+, Pb2+, Cd2+, Cu2+, and Zn2+ from aqueous solutions as a function of the pH were studied at 298 K. Conditions for quantitative retention and elution were established for each metal by batch and column methods. The organo-clay complex was very selective to Hg(II) in aqueous solution in which other metals and ions were also present. The accumulation voltammetry of Hg(II) was studied at a carbon paste electrode chemically modified with this material. The mercury response was evaluated with respect to the pH, electrode composition, preconcentration time, mercury concentration, "cleaning" solution, possible interferences and other variables. A carbon paste electrode modified by TZT-HDTA-clay showed two peaks: one cathodic peak at about 0.0 V and an anodic peak at 0.25 V, scanning the potential from -0.2 to 0.8 V (0.05 M KNO3 vs. Ag/AgCl). The anodic peak at 0.25 V presents excellent selectivity for Hg(II) ions in the presence of foreign ions. The detection limit was estimated as 0.1 microg L(-1). The precision of determination was satisfactory for the respective concentration level.
authors.affiliation: Departamento de Física e Química, Unesp-Universidade Estadual Paulista, Ilha Solteira, SP, Brazil. nldias@dfq.feis.unesp.br
authors.forename: Newton L Dias
authors.initials: NL
authors.lastname: Filho
authors.forename: Devaney R
authors.initials: DR
authors.lastname: do Carmo
authors.forename: Fergus
authors.initials: F
authors.lastname: Gessner
authors.forename: André H
authors.initials: AH
authors.lastname: Rosa
mesh_terms: D000327:Adsorption; D000538:Aluminum Silicates / Q000737:chemistry; D000838:Anions / Q000737:chemistry; D001546:Bentonite / Q000737:chemistry*; D002138:Calibration; D002244:Carbon / Q000737:chemistry*; D002413:Cations, Divalent / Q000737:chemistry; D000077286:Cetrimonium; D002593:Cetrimonium Compounds / Q000737:chemistry*; D000077215:Clay; D004563:Electrochemistry; D005618:Fresh Water / Q000032:analysis; D006863:Hydrogen-Ion Concentration; D017736:Ion-Selective Electrodes; D008628:Mercury / Q000032:analysis* / Q000737:chemistry; D010084:Oxidation-Reduction; D015203:Reproducibility of Results; D012623:Seawater / Q000032:analysis; D013844:Thiazoles / Q000737:chemistry*; D053778:Thiazolidines; D014961:X-Ray Diffraction
chemical_list: D000538:Aluminum Silicates; D000838:Anions; D002413:Cations, Divalent; D002593:Cetrimonium Compounds; D013844:Thiazoles; D053778:Thiazolidines; D001546:Bentonite; D002244:Carbon; C005104:2-mercaptothiazoline; D008628:Mercury; D000077215:Clay; D000077286:Cetrimonium