title: A strategy for the build-up of transition-metal complexes containing tripodal [ArPOS2]2- and [ArPS3]2- ligands (Ar = 4-anisyl).
abstract: The investigation presents new synthetic methods for the generation of tripodal P/S ligands by reactions of metal alkoxides and carboxylates with the organoperthiophosphinic acid anhydride Lawesson's reagent. Four new transition-metal complexes containing various tripodal ligand sets were synthesised and characterised.
authors.affiliation: Institut für Anorganische Chemie der Universität Karlsruhe, Geb. 30.45, Engesserstr. 15a, D-76131, Karlsruhe, Germany.
authors.forename: Weifeng
authors.initials: W
authors.lastname: Shi
authors.forename: Maryam
authors.initials: M
authors.lastname: Shafaei-Fallah
authors.forename: Christopher E
authors.initials: CE
authors.lastname: Anson
authors.forename: Alexander
authors.initials: A
authors.lastname: Rothenberger