A strategy for the build-up of transition-metal complexes containing tripodal [ArPOS2]2- and [ArPS3]2- ligands (Ar = 4-anisyl).
The investigation presents new synthetic methods for the generation of tripodal P/S ligands by reactions of metal alkoxides and carboxylates with the organoperthiophosphinic acid anhydride Lawesson's reagent. Four new transition-metal complexes containing various tripodal ligand sets were synthesised and characterised.
Shi
Weifeng
W
Institut für Anorganische Chemie der Universität Karlsruhe, Geb. 30.45, Engesserstr. 15a, D-76131, Karlsruhe, Germany.
Shafaei-Fallah
Maryam
M
Anson
Christopher E
CE
Rothenberger
Alexander
A