Synthesis of N-diphenylphosphinoylimines using the Kresze reaction.
[reaction: see text] The synthesis of N-diphenylphosphinoylimines involving the treatment of aldehydes with P,P-diphenyl N-sulfinylphosphoramidate (Ph2P(O)NSO) is described. The reagent is prepared from P,P-diphenylphosphinic amide, thionyl chloride, and imidazole.
Lauzon
Caroline
C
Département de Chimie, Université de Montréal, P.O. Box 6128, Station Downtown, Montréal, QC, Canada H3C 3J7.
Desrosiers
Jean-Nicolas
JN
Charette
André B
AB
D007097:Imines / Q000138:chemical synthesis*; D010721:Phosphinic Acids; D012997:Solvents
D007097:Imines; D010721:Phosphinic Acids; D012997:Solvents