Synthesis of hydrophosphorylated fullerene under neutral conditions.
[chemical reaction: see text]. A variety of phosphorous compounds such as secondary phosphines, phosphine oxides, phosphinates, and phosphonates undergo addition to [60]fullerene in DMSO/C6H5Cl without extraneous reagents to produce hydrophosphorylated fullerene derivatives in moderate to high yield.
Isobe
Hiroyuki
H
Department of Chemistry and ERATO (JST), The University of Tokyo, Hongo, Tokyo 113-0033, Japan. hsobe@chem.s.u-tokyo.ac.jp
Chen
Ai-Jan
AJ
Solin
Niclas
N
Nakamura
Eiichi
E