Incorporation of selective population transfer and homo-spin decoupling into selective one-dimensional experiments.
The incorporation of selective population transfer (SPT) and homo-spin decoupling (HSD) into selective one-dimensional (1D) experiments has been shown to be very useful in obtaining information on the elucidation of the structure of organic compounds. To demonstrate this, the determination of the relative configuration of the sugar moiety of Mi-saponins has been presented.
Uzawa
Jun
J
Plant Science Center, Riken (The Institute of Physical and Chemical Research), 2-1 Hirosawa, Wako-shi, Saitama 351-0198, Japan. uzwj@ck9.so-net.ne.jp
Fujimoto
Yasuo
Y
Yoshida
Shigeo
S
D002240:Carbohydrate Sequence; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008832:Microchemistry; D008969:Molecular Sequence Data; D015394:Molecular Structure; D009844:Oligosaccharides / Q000737:chemistry; D012503:Saponins / Q000737:chemistry*; D013237:Stereoisomerism; D013331:Strychnine / Q000737:chemistry
D009844:Oligosaccharides; D012503:Saponins; D013331:Strychnine