title: Model studies towards the synthesis of gilvocarcin M.
abstract: In model studies towards the synthesis of gilvocarcin M, a convergent, xanthate-based free-radical strategy was tested in order to construct the key aromatic ring attached to the sugar unit.
authors.affiliation: Laboratoire de Synthèse Organique associé au CNRS, Ecole Polytechnique, 91128 Palaiseau, France. cordero@dcso.polytechnique.fr
authors.forename: Alejandro
authors.initials: A
authors.lastname: Cordero-Vargas
authors.forename: Béatrice
authors.initials: B
authors.lastname: Quiclet-Sire
authors.forename: Samir Z
authors.initials: SZ
authors.lastname: Zard
mesh_terms: D000617:Aminoglycosides / Q000138:chemical synthesis* / Q000737:chemistry / Q000145:classification; D002384:Catalysis; D003374:Coumarins; D003500:Cyclization; D003516:Cycloparaffins / Q000737:chemistry; D006027:Glycosides; D007783:Lactones / Q000737:chemistry; D007854:Lead; D008956:Models, Chemical; D015394:Molecular Structure
chemical_list: D000617:Aminoglycosides; D003374:Coumarins; D003516:Cycloparaffins; D006027:Glycosides; D007783:Lactones; D007854:Lead; C031782:gilvocarcin M