A steep one-step [HS-HS] to [LS-LS] spin transition in a 4,4'-bipyridine linked one-dimensional coordination polymer constructed from a pyrazolato bridged Fe(II) dimer.
The variable temperature magnetic susceptibility, X-ray crystallography, and Mössbauer and Raman spectra of a new dinuclear complex-based one-dimensional coordination polymer [[Fe(II)2(NCS)2(mu-bpypz)2](micro-4,4'-bpy)].MeOH demonstrated a steep one-step [HS-HS] to [LS-LS] spin transition.
Yoneda
Ko
K
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka, 560-0043, Japan.
Adachi
Keiichi
K
Hayami
Shinya
S
Maeda
Yonezo
Y
Katada
Motomi
M
Fuyuhiro
Akira
A
Kawata
Satoshi
S
Kaizaki
Sumio
S