A new organometallic heteropolytungstate related to [Sb2W22O74(OH)2](12-): synthesis and structural characterisation of the bis-{Ru(p-cymene)}(2+)-containing anion [Sb2W20O70{Ru(p-cymene)}2](10-).
The easy synthesis of [Sb2W20O70{Ru(p-cymene)}2](10-) by the reaction between the organometallic precursor [Ru(p-cymene)Cl2]2 and [Sb2W20O70]14-, formed in situ, confirms the importance of the organometallic route to well defined ruthenium(+II)-substituted heteropolytungstates.
Laurencin
Danielle
D
Laboratoire de Chimie Inorganique et Matériaux Moléculaires, UMR 7071, Université Pierre et Marie Curie, 4 Place Jussieu, Case courrier 42, 75252, Paris cedex 05, France.
Villanneau
Richard
R
Herson
Patrick
P
Thouvenot
René
R
Jeannin
Yves
Y
Proust
Anna
A