An efficient synthesis of D-erythro- and D-threo-sphingosine from D-glucose: olefin cross-metathesis approach.
[reaction: see text] The D-erythro- and D-threo-sphingosine were synthesized via E-selective olefin cross-metathesis using a D-glucose-derived building block and long-chain terminal alkene.
Chaudhari
Vinod D
VD
Department of Chemistry, Garware Research Centre, University of Pune, Pune-411 007, India.
Kumar
K S Ajish
KS
Dhavale
Dilip D
DD
D000475:Alkenes / Q000737:chemistry*; D005947:Glucose / Q000737:chemistry*; D015394:Molecular Structure; D013110:Sphingosine / Q000031:analogs & derivatives / Q000138:chemical synthesis / Q000737:chemistry; D013237:Stereoisomerism
D000475:Alkenes; D005947:Glucose; D013110:Sphingosine