title: Photoelectron spectroscopy of S1 toluene: II. Intramolecular dynamics of selected vibrational levels in S1 toluene studied by nanosecond and picosecond time-resolved photoelectron spectroscopies.
abstract: We present results which suggest that the photophysics of S(1) toluene is significantly more complicated than that of the related molecules p-fluorotoluene or p-difluorobenzene. We have measured a range of photoelectron spectra for a number of S(1) internal energies, on different time scales and at different temperatures, in an attempt to unravel the competing processes, but the final conclusion remains outstanding.
authors.affiliation: School of Chemistry, University of Nottingham, Nottingham NG7 2RD, United Kingdom.
authors.forename: Paul T
authors.initials: PT
authors.lastname: Whiteside
authors.forename: Adrian K
authors.initials: AK
authors.lastname: King
authors.forename: Julia A
authors.initials: JA
authors.lastname: Davies
authors.forename: Katharine L
authors.initials: KL
authors.lastname: Reid
authors.forename: Michael
authors.initials: M
authors.lastname: Towrie
authors.forename: Pavel
authors.initials: P
authors.lastname: Matousek