Photoelectron spectroscopy of S1 toluene: II. Intramolecular dynamics of selected vibrational levels in S1 toluene studied by nanosecond and picosecond time-resolved photoelectron spectroscopies.
We present results which suggest that the photophysics of S(1) toluene is significantly more complicated than that of the related molecules p-fluorotoluene or p-difluorobenzene. We have measured a range of photoelectron spectra for a number of S(1) internal energies, on different time scales and at different temperatures, in an attempt to unravel the competing processes, but the final conclusion remains outstanding.
Whiteside
Paul T
PT
School of Chemistry, University of Nottingham, Nottingham NG7 2RD, United Kingdom.
King
Adrian K
AK
Davies
Julia A
JA
Reid
Katharine L
KL
Towrie
Michael
M
Matousek
Pavel
P