title: Addition of a chiral copper reagent derived from propargylic oxazolidininone to aldehydes.
abstract: [reaction: see text] The copper reagent arising from an optically pure propargylic oxazolidinone was found to react regio- and diastereoselectively with aldehydes, leading, in a one-pot procedure, to the anti homopropargylic amino alcohols derivatives in good yields.
authors.affiliation: Laboratoire de Chimie Organique, UMR 761, Institut de Chimie Moléculaire FR 2769, Université Pierre et Marie Curie, 75252 Paris Cedex 05, France.
authors.forename: Nacira
authors.initials: N
authors.lastname: Alouane
authors.forename: Frederic
authors.initials: F
authors.lastname: Bernaud
authors.forename: Jerôme
authors.initials: J
authors.lastname: Marrot
authors.forename: Emmanuel
authors.initials: E
authors.lastname: Vrancken
authors.forename: Pierre
authors.initials: P
authors.lastname: Mangeney