Metal directed assembly of ditopic containers and their complexes with alkylammonium salts.
A new self-folding cavitand has been assembled through metal coordination to give a thermodynamically stable ditopic receptor of nanosize dimensions which has been used in the reversible binding of di-alkylammonium and n-alkylammonium salts.
Menozzi
Edoardo
E
Skaggs Institute for Chemical Biology and Department of Chemistry, Scripps Research Institute, MB-26, La Jolla, California 92037, USA.
Rebek
Julius
J
D000478:Alkylation; D018360:Crystallography, X-Ray; D019281:Dimerization; D009682:Magnetic Resonance Spectroscopy; D008670:Metals / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D012492:Salts / Q000737:chemistry*
D008670:Metals; D000644:Quaternary Ammonium Compounds; D012492:Salts