Interphase structure-property relationships in thermoset dimethacrylate nanocomposites.
OBJECTIVE
The aim of this research was to better understand the relationships between interphase composition and the resultant mechanical properties of thermoset methacrylate nanocomposites, ultimately for the purpose of improving the properties of dental restorative materials through manipulation of the interphase.


METHODS
Silica nanoparticles were silanized with three different silanes and blends of those silanes to generate six different interphase compositions. The silanes varied in their relative polarity, flexibility, and reactivity towards photo-polymerization. Composites containing 60% by mass of the silanized fillers were prepared and analyzed for uncured paste handling characteristics, vinyl conversion, biaxial flexure strength (BFS), modulus, and Knoop hardness.


RESULTS
Dual silanization of the fillers improved the handling characteristics of the uncured composite pastes compared to those containing fillers silanized with 3-methacryloxypropyltrimethoxysilane. To obtain high BFS, functional groups reactive in free radical polymerization were needed in the composite interphase, but a high concentration of those groups was not necessary. Moduli were highest for composites with interphases that contained styrylethyltrimethoxysilane, a reactive aromatic silane. The hardness values of the composites with reactive interphases were all comparable. Methacrylate conversion was only modestly influenced by silane interphase composition.


CONCLUSIONS
This study suggests that dual silanization is a practical method for improving the handling characteristics of uncured dental restorative nanocomposites while maintaining or improving the mechanical properties of the cured composites.
Wilson
Kristen S
KS
Polymers Division, National Institute of Standards and Technology, 100 Bureau Drive, MS 8545, Gaithersburg, MD 20899, USA.
Antonucci
Joseph M
JM
D055598:Chemical Phenomena; D002627:Chemistry, Physical; D003188:Composite Resins / Q000737:chemistry* / Q000528:radiation effects; D003764:Dental Materials / Q000737:chemistry* / Q000528:radiation effects; D004548:Elasticity; D004563:Electrochemistry; D006244:Hardness; D006801:Humans; D008027:Light; D008422:Materials Testing; D008689:Methacrylates / Q000737:chemistry* / Q000528:radiation effects; D053761:Nanocomposites / Q000737:chemistry* / Q000528:radiation effects; D053758:Nanoparticles / Q000737:chemistry / Q000528:radiation effects; D018583:Pliability; D011108:Polymers / Q000737:chemistry / Q000528:radiation effects; D012821:Silanes / Q000737:chemistry / Q000528:radiation effects; D012822:Silicon Dioxide / Q000737:chemistry / Q000528:radiation effects; D013314:Stress, Mechanical; D013329:Structure-Activity Relationship; D014753:Vinyl Compounds / Q000737:chemistry / Q000528:radiation effects
D003188:Composite Resins; D003764:Dental Materials; D008689:Methacrylates; D011108:Polymers; D012821:Silanes; D014753:Vinyl Compounds; C017492:methacryloxypropyltrimethoxysilane; D012822:Silicon Dioxide; C071717:trimethoxysilane