Dihydrobis(methimazolyl)borate and methimazolyl complexes of titanium.
The first poly(methimazolyl)borato complex of group 4, [Ti([double bond, length as m-dash]NCMe(3)){H(2)B(mt)(2)}(2)](mt = methimazolyl), results from the reaction of Na[H(2)B(mt)(2)] with [Ti([double bond, length as m-dash]NCMe(3))Cl(2)(py)(3)] and features both kappa(2)-S,S' and kappa(3)-H,S,S' coordination of H(2)B(mt)(2) ligands coincident within the same molecule.
Hill
Anthony F
AF
Research School of Chemistry, Institute of Advanced Studies, Australian National University, Canberra, A.C.T., Australia. a.hill@anu.edu.au
Smith
Matthew K
MK