[Dipentaerythritol in the synthesis of the new type of phospholipids].
The first representatives of phospholipids of new types were synthesized on the basis of dipentaerythritol, 2,2'-[oxybis(methylen)]bis(hydroxymethyl))-1,3-propandiol. The starting polyol was phosphorylated with hexaethylphosphoric triamide to biphosphite, which was converted into thio- and selenophosphates by treatment with sulfur or selenium. The phosphoacetals were transformed into thio- and selenoanalogues of phospholipids by direct acylation with higher fatty acid chlorides. The English version of the paper: Russian Journal of Bioorganic Chemistry, 2005, vol. 31, no. 6; see also http://www.maik.ru.
Savin
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D004896:Erythritol / Q000031:analogs & derivatives* / Q000138:chemical synthesis*; D010743:Phospholipids / Q000138:chemical synthesis*
D010743:Phospholipids; D004896:Erythritol