Stabilisation of a paramagnetic BH(4-)-bridged dinickel(II) complex by a macrodinucleating hexaaza-dithiophenolate ligand.
The first paramagnetic borohydrido-bridged dinuclear nickel(II) complex, [(L)Ni(II)2(mu(1,3)-BH4)]+, stabilised by a sterically demanding hexaaza-dithiophenolate macrocycle, has been obtained by the reaction of [(L)Ni(II)2(micro-ClO4)]+ with N(n)Bu4BH4.
Journaux
Yves
Y
Laboratoire de Chimie Inorganique et Matériaux Moléculaires Bat F UMR CNRS 7071, case courrier 42, Université Pierre et Marie Curie, 4 place Jussieu, F75252, Paris cedex 05, France. jour@ccr.jussieu.fr
Lozan
Vasile
V
Klingele
Julia
J
Kersting
Berthold
B