Rotationally resolved electronic spectroscopy of tryptophol in the gas phase.
High resolution S1-S0 fluorescence excitation spectra of tryptophol have been observed in the collision-free environment of a supersonic beam. Each origin band has been assigned to a unique conformer based on its observed rotational constants. Unlike its close relative tryptamine, which exhibits seven distinguishable conformers under similar conditions, tryptophol exhibits only four (GPy-in, GPh-in, and two anti structures). Possible reasons for this difference in behavior are discussed.
Yi
John T
JT
Department of Chemistry, University of Pittsburgh, Pittsburgh, PA 15260, USA.
Pratt
David W
DW
D005740:Gases / Q000032:analysis* / Q000737:chemistry*; D007211:Indoles / Q000032:analysis* / Q000737:chemistry*; D007536:Isomerism; D008968:Molecular Conformation; D044367:Phase Transition; D013050:Spectrometry, Fluorescence / Q000379:methods*; D000438:Alcohols
D005740:Gases; D007211:Indoles; C005949:tryptophol; D000438:Alcohols