title: Quinine/selectfluor combination induced asymmetric semipinacol rearrangement of allylic alcohols: an effective and enantioselective approach to alpha-quaternary beta-fluoro aldehydes.
abstract: A quinine/Selectfluor combination inducing rearrangement reaction of allylic alcohols was discovered, which involved a moderate yield with good enantioselective construction of alpha-quaternary carbon center and beta-fluoro aldehyde under base condition.
authors.affiliation: State Key Laboratory of Applied Organic Chemistry & Department of Chemistry, Lanzhou University, Lanzhou, 730000, P. R. China.
authors.forename: Min
authors.initials: M
authors.lastname: Wang
authors.forename: Bao Min
authors.initials: BM
authors.lastname: Wang
authors.forename: Lei
authors.initials: L
authors.lastname: Shi
authors.forename: Yong Qiang
authors.initials: YQ
authors.lastname: Tu
authors.forename: Chun-An
authors.initials: CA
authors.lastname: Fan
authors.forename: Shao Hua
authors.initials: SH
authors.lastname: Wang
authors.forename: Xiang Dong
authors.initials: XD
authors.lastname: Hu
authors.forename: Shu Yu
authors.initials: SY
authors.lastname: Zhang
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D053138:Cyclohexenes / Q000737:chemistry*; D003979:Diazonium Compounds / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry*; D015394:Molecular Structure; D020005:Propanols / Q000737:chemistry*; D011803:Quinine / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000447:Aldehydes; D053138:Cyclohexenes; D003979:Diazonium Compounds; D020005:Propanols; C519041:semipinacol; D005461:Fluorine; C006463:allyl alcohol; C408750:selectfluor; D011803:Quinine