title: Water trapped in dibenzo-18-crown-6: theoretical and spectroscopic (IR, Raman) studies.
abstract: Experimental (IR and Raman) and theoretical (Kohn-Sham calculations) methods are used in a combined analysis aimed at refining the available structural data concerning the molecular guests in channels formed by stacked dibenzo-18-crown-6 (DB18C6) crown ether. The calculations are performed for a simplified model comprising isolated DB18C6 unit and its complexes with either H2O or H3O+ guests, which are the simplest model ingredients of a one-dimensional diluted acid chain, to get structural and energetic data concerning the formation of the complex and to assign the characteristic spectroscopic bands. The oxygen centers in the previously reported crystallographic structure are assigned to either H2O or protonated species.
authors.affiliation: Department of Physical Chemistry, University of Geneva, 30, quai Ernest-Ansermet, CH-1211 Geneva 4, Switzerland.
authors.forename: Marcin
authors.initials: M
authors.lastname: Dułak
authors.forename: Rémi
authors.initials: R
authors.lastname: Bergougnant
authors.forename: Katharina M
authors.initials: KM
authors.lastname: Fromm
authors.forename: Hans R
authors.initials: HR
authors.lastname: Hagemann
authors.forename: Adeline Y
authors.initials: AY
authors.lastname: Robin
authors.forename: Tomasz A
authors.initials: TA
authors.lastname: Wesołowski
mesh_terms: D043844:Crown Ethers / Q000737:chemistry*; D008962:Models, Theoretical; D009861:Onium Compounds / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman; D014732:Vibration; D014867:Water / Q000737:chemistry*
chemical_list: D043844:Crown Ethers; D009861:Onium Compounds; D014867:Water; C002564:dibenzo-18-crown-6; C027727:hydronium ion; D010100:Oxygen