Incorporation of nonlinear thermorheological complexity into the phenomenologies of structural relaxation.
A distribution of activation energies is introduced into the nonlinear Adam-Gibbs ("Hodge-Scherer") phenomenology for structural relaxation. The resulting dependencies of the stretched exponential beta parameter on thermodynamic temperature and fictive temperature (nonlinear thermorheological complexity) are derived. No additional adjustable parameters are introduced, and contact is made with the predictions of the random first-order transition theory of aging of Lubchenko and Wolynes [J. Chem. Physics121, 2852 (2004)].
Hodge
Ian M
IM
Department of Physics, Rochester Institute of Technology, Rochester, New York 14623, USA. imhsps@rit.edu