title: A planar water tetramer with tetrahedrally coordinated water embedded in a hydrogen bonding network of [Tc4(CO)12-(mu3-OH)4.4H2O].
abstract: A virtually planar water tetramer in which the water molecules are virtually tetrahedrally coordinated could be realized in the solid in a three-dimensional network of [Tc4(CO)12-(mu3-OH)4.4H2O]. The network could be produced by cocrystallization of the new cubane-like cluster [Tc(CO)3-(mu3-OH)]4 and water as a complementary component. The amphiphilic behavior of cluster and water results in a highly ordered three-dimensional network. The complementary components, the water tetramer and the cubic cluster, independently of one another form two interpenetrating tetragonal lattice networks held together exclusively by hydrogen bonds.
authors.affiliation: Klinik für Nuklearmedizin U-K Schleswig Holstein, Campus Kiel, Germany. mzuhayra@nuc-med.uni-kiel.de
authors.forename: Maaz
authors.initials: M
authors.lastname: Zuhayra
authors.forename: Willm Uwe
authors.initials: WU
authors.lastname: Kampen
authors.forename: Eberhard
authors.initials: E
authors.lastname: Henze
authors.forename: Zsolt
authors.initials: Z
authors.lastname: Soti
authors.forename: Laslo
authors.initials: L
authors.lastname: Zsolnai
authors.forename: Gottfried
authors.initials: G
authors.lastname: Huttner
authors.forename: Franz
authors.initials: F
authors.lastname: Oberdorfer