'Magic blue'--subtle reagent for EPR studies on H-abstraction from various substrates.
This paper is an EPR study on the generation of new 'magic blue' (MB) reagent containing bis{perfluoro[1-(2-fluorosulfonyl)ethoxy]ethyl}nitroxide 2 and perfluoro[1-nitroso-1-(2-fluorosulfonyl)ethoxy]ethane 3, both bearing chemically convertible terminal omega-fluorosulfonyl group -SO2F, and its H-abstraction reactions from arylalkanes, alcohols, aldehydes and polymers, leading to a large number of new fluorinated nitroxides (FN).
Dou
Hong-Yan
HY
Department of Chemistry, Shanghai Jiaotong University, Shanghai 200240, China.
Ni
Hong-Bo
HB
Lin
Zheng-Huan
ZH
Zhao
Cheng-Xue
CX