Salicylaldehyde 4,4'-(hexane-1,6-diyl)thiosemicarbazone.
The title compound, C14H19N3OS, is in the thioketo form, with the thione S and hydrazine N atoms cis with respect to each other so that the S atom is involved in inter- and intramolecular hydrogen bonds simultaneously. Intermolecular C-H...S and C-H...O hydrogen bonds result in one-dimensional polymeric chains of molecules along the a axis. A weak C-H...pi ring interaction binds the polymeric chains together.
Latheef
Leji
L
Department of Applied Chemistry, Cochin University of Science and Technology, Kochi 682022, Kerala, India.
Manoj
E
E
Prathapachandra Kurup
M R
MR
D000447:Aldehydes / Q000737:chemistry*; D002614:Chelating Agents / Q000737:chemistry; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D015394:Molecular Structure; D013882:Thiosemicarbazones / Q000737:chemistry*
D000447:Aldehydes; D002614:Chelating Agents; D013882:Thiosemicarbazones; C013243:salicylaldehyde