title: Formation of [(L)Ni(mu2-S)x{Fe(CO)3}x] adducts (x = 1 or 2): analogues of the active site of [NiFe] hydrogenase.
abstract: The binuclear [Ni(L)Fe(CO)3], , and trinuclear [Ni(L){Fe(CO)3}2], , complexes adopt unusual structural motifs whereby Fe(CO)3 units bind to [Ni(L)] via mu2-S bridging modes, C=N imine pi-bonds and potential Ni-Fe bonding interactions.
authors.affiliation: School of Chemistry, University of Nottingham, Nottingham, UK NG7 2RD.
authors.forename: Philip A
authors.initials: PA
authors.lastname: Stenson
authors.forename: Armando
authors.initials: A
authors.lastname: Marin-Becerra
authors.forename: Claire
authors.initials: C
authors.lastname: Wilson
authors.forename: Alexander J
authors.initials: AJ
authors.lastname: Blake
authors.forename: Jonathan
authors.initials: J
authors.lastname: McMaster
authors.forename: Martin
authors.initials: M
authors.lastname: Schröder
mesh_terms: D001665:Binding Sites; D002248:Carbon Monoxide / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006864:Hydrogenase / Q000737:chemistry* / Q000378:metabolism; D007097:Imines / Q000737:chemistry; D058085:Iron Compounds / Q000737:chemistry*; D008956:Models, Chemical; D009532:Nickel / Q000737:chemistry*; D013457:Sulfur Compounds / Q000737:chemistry*
chemical_list: D007097:Imines; D058085:Iron Compounds; D013457:Sulfur Compounds; D009532:Nickel; D002248:Carbon Monoxide; C043296:nickel-iron hydrogenase; D006864:Hydrogenase