Charging effects in a CdSe nanotetrapod.
The charging effects in a CdSe nanotetrapod have been theoretically investigated by using an atomistic pseudopotential method. We showed that the simple quasiparticle equation based on classical electrostatic consideration can be derived from the many-body GW equation under proper approximations. We found that the surface polarization potential can significantly change the electron wave functions, and there is an incomplete cancellation for this potential between the single particle energies and the electron-hole Coulomb interaction. Thus, it is necessary to include this potential in the calculation for complex unconvex systems. We also calculated the electron addition energies for a tetrapod. Unlike a simple spherical quantum dot, in which the addition energies are almost a constant, there is a large variation in the calculated addition energies for different numbers of electrons in a tetrapod.
Wang
Lin-Wang
LW
Computational Research Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA. lwwang@lbl.gov