Highly regioselective terminal alkynes hydroformylation and Pauson-Khand reaction catalysed by mesoporous organised zirconium oxide based powders.
Zirconia-silica mesoporous powders act as very efficient heterogeneous catalysts for both alkyne hydroformylation and Pauson-Khand reaction and yield regioselectivities opposite to those usually observed.
Goettmann
Frédéric
F
Laboratoire de Chimie de la Matière Condensée, Université Pierre et Marie Curie, 75005 Paris, France.
Le Floch
Pascal
P
Sanchez
Clément
C
D000480:Alkynes / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D011208:Powders / Q000737:chemistry; D012822:Silicon Dioxide / Q000737:chemistry*; D013237:Stereoisomerism; D015040:Zirconium / Q000737:chemistry*
D000480:Alkynes; D009942:Organometallic Compounds; D011208:Powders; D012822:Silicon Dioxide; D015040:Zirconium; C028541:zirconium oxide