Thermochromic triangular [MCo2] (M = Rh, Ir, Ru) clusters containing a planar metalladithiolene ring in eta3 coordination.
The first series of triangular cluster complexes of [MCo(2)] (M = Rh, Ir, Ru) with a planar metalladithiolene ring coordinating in the eta(3)-bonding mode were synthesized, and the crystal structures, spectral and electrochemical properties, and thermochromism of these complexes were revealed.
Nakagawa
Norikiyo
N
Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Japan.
Yamada
Teppei
T
Murata
Masaki
M
Sugimoto
Manabu
M
Nishihara
Hiroshi
H