Immobilization of the [RuII(edta)NO+] Ion on the surface of functionalized silica gel.
The reaction of NO and the immobilized dimer complex (edta)(2)Ru(2)(III(1/2),III(1/2)) on silica gel chemically modified with [3-(2-aminoethyl)aminopropyl]trimethoxysilane (AEATS) produces the corresponding immobilized nitrosyl complex AEATS/Ru(II)NO(+). This compound, a monomer, was obtained by reducing the immobilized ruthenium dimer either electrochemically or with Eu(II) and reacting this species with NO(2)(-) ions. The properties of [Ru(edta)NO](-) in solution and anchored (AEATS/Ru(II)NO(+)) on silica were compared using electrochemical (DPV, CV) and spectroscopic (IR, UV-vis, and ESR) techniques. The results indicate that immobilization does not alter the reactivity of the ruthenium complex and confirm that [Ru(edta)(H(2)O)](2)(-) may be used, either in solution or immobilized, as a catalyst for the conversion of NO(2)(-) to NO(+). Both the anchored nitrosyl complex AEATS/Ru(II)NO(+) and the [Ru(edta)NO](-) species in solution, upon one-electron reduction, liberate NO at comparable rates.
Zanichelli
Patrícia G
PG
Instituto de Química de São Carlos, Universidade de São Paulo, CEP 13566 São Carlos, SP, Brazil.
Sernaglia
Rosana L
RL
Franco
Douglas W
DW