title: Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer.
abstract: Structure/reactivity and structure/structure correlations of 5 sulfate monoesters and 11 sulfamate esters determined by low temperature X-ray crystallography reveal similar ground state deformations that suggest similar reaction coordinates for sulfuryl and sulfamyl group transfer.
authors.affiliation: School of Chemistry, University of Melbourne, Parkville, Australia.
authors.forename: Emma
authors.initials: E
authors.lastname: Denehy
authors.forename: Jonathan M
authors.initials: JM
authors.lastname: White
authors.forename: Spencer J
authors.initials: SJ
authors.lastname: Williams
mesh_terms: D003080:Cold Temperature; D018360:Crystallography, X-Ray; D008956:Models, Chemical; D013451:Sulfonic Acids / Q000737:chemistry*; D013463:Sulfuric Acid Esters / Q000737:chemistry*; D013464:Sulfuric Acids / Q000737:chemistry*
chemical_list: D013451:Sulfonic Acids; D013463:Sulfuric Acid Esters; D013464:Sulfuric Acids; C005741:sulfamic acid