Characterization of soil particle surfaces using adsorption excess isotherms.
Measurement of adsorption excess isotherms of methanol-benzene mixtures was applied to the characterization of soil particle surfaces. The sorption capacity and Gibbs energy of sorption of the solid-liquid interface were determined for montmorillonite, three types of soil, and their humin fractions. The soils were found to be less polar or less hydrophilic than the clay, and the humin fraction of soils was found to be less hydrophilic than the whole soils. The soil and humin samples have heterogeneous surfaces which can be divided in two regions on the basis of their relative polarity. The x-axis intersection of the straight section of isotherm assigns the relative proportions of the hydrophilic and hydrophobic regions of the surface.
Berka
Marta
M
Department of Colloid and Environmental Chemistry, University of Debrecen, Debrecen, H-4010 Debrecen Egyetem tér 1, Hungary. mberka@tigris.unideb.hu
Pla
Sandrine Palau
SP
Rice
James A
JA