Synthesis, characterization, and electrical, electrochemical and gas sensing properties of a novel ball-type four t-butylcalix[4]arene bridged binuclear zinc(II) phthalocyanine.
1,3 dimethoxy-4-t-butylcalix[4]arene has been used to synthesize a novel ball-type dimeric zinc(II) phthalocyanine, [Zn2Pc2(tbca)4] that exhibits mixed-valence behaviour and non-Arrhenius type dependence of conductivity.
Ceyhan
Tanju
T
Department of Biochemistry, Division of Organic Chemistry, Gülhane Medical Academy, GATA, Ankara, Turkey.
Altindal
Ahmet
A
Ozkaya
Ali Riza
AR
Erbil
Mehmet K
MK
Salih
Bekir
B
Bekaroğlu
Ozer
O
D001952:Bridged-Ring Compounds / Q000138:chemical synthesis; D047250:Calixarenes / Q000737:chemistry*; D002413:Cations, Divalent; D019281:Dimerization; D004563:Electrochemistry; D005740:Gases; D007211:Indoles / Q000138:chemical synthesis*; D054833:Isoindoles; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis; D011838:Radiation-Sensitizing Agents / Q000138:chemical synthesis*; D019032:Spectrometry, Mass, Matrix-Assisted Laser Desorption-Ionization; D014633:Valine / Q000031:analogs & derivatives / Q000737:chemistry; D015032:Zinc / Q000737:chemistry*
C434726:4-tert-butylcalix(4)arene tetravaline benzyl ester; D001952:Bridged-Ring Compounds; D002413:Cations, Divalent; D005740:Gases; D007211:Indoles; D054833:Isoindoles; D009942:Organometallic Compounds; D011838:Radiation-Sensitizing Agents; D047250:Calixarenes; D014633:Valine; D015032:Zinc; C013647:phthalocyanine