Formation of [(L)Ni(mu2-S)x{Fe(CO)3}x] adducts (x = 1 or 2): analogues of the active site of [NiFe] hydrogenase.
The binuclear [Ni(L)Fe(CO)3], , and trinuclear [Ni(L){Fe(CO)3}2], , complexes adopt unusual structural motifs whereby Fe(CO)3 units bind to [Ni(L)] via mu2-S bridging modes, C=N imine pi-bonds and potential Ni-Fe bonding interactions.
Stenson
Philip A
PA
School of Chemistry, University of Nottingham, Nottingham, UK NG7 2RD.
Marin-Becerra
Armando
A
Wilson
Claire
C
Blake
Alexander J
AJ
McMaster
Jonathan
J
Schröder
Martin
M
D001665:Binding Sites; D002248:Carbon Monoxide / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006864:Hydrogenase / Q000737:chemistry* / Q000378:metabolism; D007097:Imines / Q000737:chemistry; D058085:Iron Compounds / Q000737:chemistry*; D008956:Models, Chemical; D009532:Nickel / Q000737:chemistry*; D013457:Sulfur Compounds / Q000737:chemistry*
D007097:Imines; D058085:Iron Compounds; D013457:Sulfur Compounds; D009532:Nickel; D002248:Carbon Monoxide; C043296:nickel-iron hydrogenase; D006864:Hydrogenase