title: Electrochemically assisted photocatalytic degradation of Acid Orange 7 with beta-PbO2 electrodes modified by TiO2.
abstract: Modification of beta-PbO(2) electrodes was carried out by TiO(2) co-deposition and characterized by scanning electron microscopy (SEM) and X-ray diffraction (XRD). The 2.0 g TiO(2) (the amount of TiO(2) used in 200 mL electrodeposition solution) modified beta-PbO(2) electrode was more compact and more uniform in comparison with the unmodified beta-PbO(2) electrode. TiO(2) particles were tightly attached on and between beta-PbO(2) crystals on modified beta-PbO(2) electrode. It was also used in electrochemically assisted photocatalytic degradation (EAPD) of Acid Orange 7. Compared with the total efficiency by a single application of ultraviolet irradiation and electrochemical procedure, application of a 1.5 V potential in EAPD improved the apparent first-order rate constant by 44.2% for 2.0 g TiO(2) modified beta-PbO(2) electrode even if it was not freshly used. A synergetic effect was significant. Within the amount of TiO(2) investigated, the more TiO(2) used in electro-deposition solution, the higher the degradation efficiencies were. Effects of initial dye concentration, initial pH values and applied potentials across the electrodes were investigated. Acidic condition and high potentials applied across the electrodes favored color or TOC removal of the dye. Decolorization rate decreased with an increase in the dye concentration in the range of 5-50mg/L. Experiments above demonstrate that TiO(2) modified beta-PbO(2) electrode, which realized TiO(2) immobilization successfully, performed well in EAPD of Acid Orange 7.
authors.affiliation: State Key laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Beijing 100085, PR China.
authors.forename: Guoting
authors.initials: G
authors.lastname: Li
authors.forename: Jiuhui
authors.initials: J
authors.lastname: Qu
authors.forename: Xiwang
authors.initials: X
authors.lastname: Zhang
authors.forename: Jiantuan
authors.initials: J
authors.lastname: Ge
mesh_terms: D001391:Azo Compounds / Q000737:chemistry*; D001557:Benzenesulfonates; D002384:Catalysis; D004396:Coloring Agents / Q000737:chemistry; D004563:Electrochemistry; D004566:Electrodes; D007854:Lead / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D010777:Photochemistry; D014025:Titanium / Q000737:chemistry; D018508:Water Purification / Q000379:methods*
chemical_list: D001391:Azo Compounds; D001557:Benzenesulfonates; D004396:Coloring Agents; D010087:Oxides; C009495:titanium dioxide; D007854:Lead; C047365:lead oxide; D014025:Titanium; C014722:2-naphthol orange