Regioselective indium(III) trifluoromethanesulfonate-catalyzed hydrothiolation of non-activated olefins.
Indium(III) trifluoromethanesulfonate was found to be an excellent catalyst for the highly regioselective intra- and intermolecular addition of thiols to non-activated olefins and could be recycled and reused without loss of activity.
Weïwer
Michel
M
Laboratoire Arômes, Synthèses et Interactions, Université de Nice-Sophia Antipolis, Parc Valrose, 06108 Nice cedex 2, France.
Coulombel
Lydie
L
Duñach
Elisabet
E
D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D002412:Cations; D003500:Cyclization; D007204:Indium / Q000737:chemistry*; D008698:Mesylates / Q000737:chemistry*; D008956:Models, Chemical; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*
D000475:Alkenes; D002412:Cations; D008698:Mesylates; D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D007204:Indium; C012077:trifluoromethanesulfonic acid