Extended wedge covariance for wetting and filling transitions.
Fluid adsorption on nonplanar and heterogeneous substrates is studied using a simple interfacial model. For systems with short-ranged forces, we find that, by tuning the local strength of the substrate potential, it is possible to find the exact equilibrium interfacial profile as a functional of the wall shape psi x. The tuning of the local substrate potential takes the form of a gauge condition theta x=+/-psi x, where theta x can be interpreted as a local effective contact angle. For wedgelike geometries with asymptotic tilt angle alpha, the midpoint interfacial height and roughness satisfy the same covariance relations previously found for simple linear wedges. For troughlike geometries satisfying the gauge condition, covariance is also found for the two-point correlation function. Predictions for more microscopic Landau and Ising models are also discussed.
Parry
A O
AO
Department of Mathematics, Imperial College London, London SW7 2BZ, United Kingdom. a.o.parry@imperical.ac.uk
Rascón
C
C
Morgan
L
L