title: An insight into the protonation property of a diiron azadithiolate complex pertinent to the active site of Fe-only hydrogenases.
abstract: Protonation of [{(mu-SCH2)2N(C6H4-p-NO2)}{Fe(CO)2(PMe3)}2] in the presence of 4 equiv. of HOTf afforded two species, a micro-hydride diiron complex, the molecular structure of which was crystallographically characterized, and a micro-S-protonated species, which was readily deprotonated in the presence of pyridine.
authors.affiliation: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Zhongshan Road 158-46, 116012 Dalian, PR China.
authors.forename: Weibing
authors.initials: W
authors.lastname: Dong
authors.forename: Mei
authors.initials: M
authors.lastname: Wang
authors.forename: Xiaoyang
authors.initials: X
authors.lastname: Liu
authors.forename: Kun
authors.initials: K
authors.lastname: Jin
authors.forename: Guanghua
authors.initials: G
authors.lastname: Li
authors.forename: Fujun
authors.initials: F
authors.lastname: Wang
authors.forename: Licheng
authors.initials: L
authors.lastname: Sun