Ground state structures of sulfate monoesters and sulfamates reveal similar reaction coordinates for sulfuryl and sulfamyl transfer.
Structure/reactivity and structure/structure correlations of 5 sulfate monoesters and 11 sulfamate esters determined by low temperature X-ray crystallography reveal similar ground state deformations that suggest similar reaction coordinates for sulfuryl and sulfamyl group transfer.
Denehy
Emma
E
School of Chemistry, University of Melbourne, Parkville, Australia.
White
Jonathan M
JM
Williams
Spencer J
SJ
D003080:Cold Temperature; D018360:Crystallography, X-Ray; D008956:Models, Chemical; D013451:Sulfonic Acids / Q000737:chemistry*; D013463:Sulfuric Acid Esters / Q000737:chemistry*; D013464:Sulfuric Acids / Q000737:chemistry*
D013451:Sulfonic Acids; D013463:Sulfuric Acid Esters; D013464:Sulfuric Acids; C005741:sulfamic acid