Porphyrin-carborane organometallic assemblies based on 1, 2-dicarba-closo-dodecaborane (12) ligands.
The assembly of soluble, air-stable, supramolecular structures {(Zn-TPyP)[Cp*Ir{S2C2(B10H10)}]4(THF)2}(2), {(Cu-TPyP)[Cp*Ir{S2C2(B10H10)}]4(THF)2}(3) and {(Zn-TPyP)[Cp*Ir{S2C2(B10H10)}]2.6(CHCl3)}n (4), based on metal-containing moieties [Cp*Ir{S2C2(B10H10)}] (1) bridged by nitrogen-based organic spacers, are described.
Wang
Jian-Qiang
JQ
Laboratory of Molecular Catalysis and Innovative Material, Department of Chemistry, Fudan University, Shanghai 200433, P. R. China.
Ren
Chun-Xia
CX
Weng
Lin-Hong
LH
Jin
Guo-Xin
GX
D001896:Boron Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*
D001896:Boron Compounds; D008024:Ligands; D009942:Organometallic Compounds; D011166:Porphyrins; C119788:dodecaborate