Sterically non-hindering endocyclic ligands of the bi-isoquinoline family.
Bi-isoquinoline can be used as a building block to prepare a new family of non-sterically hindering chelates, including a macrocyclic system; the endocyclic nature of the ligands has been confirmed by the X-ray structure of an octahedral tris-chelate iron(II) complex, which shows that the three chelates are easily accommodated in the coordination sphere of the metal in spite of their crescent shape.
Durola
Fabien
F
Laboratoire de Chimie Organo-Minérale, UMR 7513 du CNRS, Institut Le Bel, Université Louis Pasteur, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France.
Sauvage
Jean-Pierre
JP
Wenger
Oliver S
OS
D018360:Crystallography, X-Ray; D003500:Cyclization; D007546:Isoquinolines / Q000138:chemical synthesis* / Q000737:chemistry; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism
D007546:Isoquinolines; D008024:Ligands