Formation of an unusual charge-transfer network from an ionic liquid.
An intriguing and novel charge-transfer complex between dimethyldihydrophenazine and diethylviologen has been crystallized from an ionic liquid at room temperature, resulting in an interesting stacking motif of interrupted D***A***D type triads: efficient formation of the complex is seen within an ionic liquid and acetone, with the complex absorbing strongly across nearly the entire visible-NIR spectral region.
Del Sesto
Rico E
RE
Structural and Inorganic Chemistry, Division of Chemistry, Los Alamos National Laboratory, NM 87545, USA.
Baker
Gary A
GA
Baker
Sheila N
SN
Scott
Brian L
BL
Keizer
Timothy S
TS
Burrell
Anthony K
AK
McCleskey
T Mark
TM