cis-dihydroxylation of unsaturated potassium alkyl- and aryltrifluoroborates.
[reaction: see text] The cis-dihydroxylation of olefin-containing potassium alkyl- and aryltrifluoroborates proceeds readily in moderate to excellent yields. The resulting diols are efficient coupling partners in Suzuki-Miyaura-type reactions with both alkenyl and aryl bromides.
Molander
Gary A
GA
Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, 19104-6323, USA. gmolandr@sas.upenn.edu
Figueroa
Ruth
R
D001881:Borates / Q000737:chemistry*; D006900:Hydroxylation; D011188:Potassium / Q000737:chemistry*
D001881:Borates; D011188:Potassium