title: Twinning and structure of Eu(0.6)Sr(0.4)MnO3.
abstract: The crystal structure of europium strontium manganese trioxide, Eu(0.6)Sr(0.4)MnO3, has been refined using a multiply twinned single crystal containing six twin components. The MnO6 octahedra show Jahn-Teller distortions with nearly fourfold symmetry, but the octahedral tilting scheme reduces the crystal symmetry to orthorhombic (space group Pbnm). The refinement of site occupancies and the analysis of difference Fourier maps show that the Eu3+ and Sr2+ cations occupy different crystallographic positions with eightfold and twelvefold coordination, respectively.
authors.affiliation: Molecule Structure Research Center, National Academy of Science Ra, Azatutyan ave. 26, 375014 Yerevan, Armenia. rafael@msrc.am
authors.forename: Rafael
authors.initials: R
authors.lastname: Tamazyan
authors.forename: Nicola
authors.initials: N
authors.lastname: Rotiroti
authors.forename: Sander
authors.initials: S
authors.lastname: van Smaalen
authors.forename: Yakov
authors.initials: Y
authors.lastname: Mukovskii
authors.forename: A
authors.initials: A
authors.lastname: Arsenov