title: Evaluating a drinking-water waste by-product as a novel sorbent for arsenic.
abstract: Arsenic (As) carcinogenicity to humans and other living organisms has promulgated extensive research on As treatment technologies with varying levels of success; generally, the most efficient methods come with a significantly higher cost burden and they usually perform better in removing As(V) than As(III) from solution. In the reported study, a novel sorbent, a waste by-product of the drinking-water treatment process, namely, drinking-water treatment residuals (WTRs) were evaluated for their ability to adsorb both As(V) and As(III). Drinking-WTRs can be obtained free-of-charge from drinking-water treatment plants, and they have been successfully used to reduce soluble phosphorus (P) concentrations in poorly P-sorbing soils. Phosphate and arsenate molecules have the same tetrahedral geometry, and they chemically behave in a similar manner. We hypothesized that the WTRs would be effective sorbents for both As(V) and As(III) species. Two WTRs (one Fe- and one Al-based) were used in batch experiments to optimize the maximum As(V) and As(III) sorption capacities, utilizing the effects of solid:solution ratios and reaction kinetics. Results showed that both WTRs exhibited high affinities for soluble As(V) and As(III), exhibiting Freundlich type adsorption with no obvious plateau after 2-d of reaction (15000 mg kg-1). The Al-WTR was highly effective in removing both As(V) and As(III), although As(III) removal was much slower. The Fe-WTR showed greater affinity for As(III) than for As(V) and reached As(III) sorption capacity levels similar to those obtained with the Al-WTR-As(V) system (15000 mg kg-1). Arsenic sorption kinetics were biphasic, similar to what has been observed with P sorption by the WTRs. Minimal (<3%) desorption of sorbed As(III) and As(V) was observed, using phosphate as the desorbing ligand. Dissolved Fe2+ concentrations measured during As(III) sorption were significantly correlated (r2=0.74, p<0.005) with the amount of As(III) sorbed by the Fe-WTR. Lack of correlation between Fe2+ in solution and sorbed As(V) (r2=0.2) suggests reductive dissolution of the Fe-WTR mediating As(III) sorption. Results show promising potential for the WTRs in irreversibly retaining As(V) and As(III) that should be further tested in field settings.
authors.affiliation: University of Texas at San Antonio, Earth and Environmental Science, 6900 N Loop 1604 W, San Antonio, TX 78249, United States.
authors.forename: Konstantinos C
authors.initials: KC
authors.lastname: Makris
authors.forename: Dibyendu
authors.initials: D
authors.lastname: Sarkar
authors.forename: Rupali
authors.initials: R
authors.lastname: Datta
mesh_terms: D000327:Adsorption; D001151:Arsenic / Q000302:isolation & purification*; D002412:Cations; D005290:Ferric Compounds / Q000737:chemistry; D006256:Hazardous Waste / Q000032:analysis / Q000517:prevention & control; D006801:Humans; D013997:Time Factors; D014865:Waste Disposal, Fluid / Q000379:methods*; D018508:Water Purification / Q000379:methods*; D014881:Water Supply
chemical_list: D002412:Cations; D005290:Ferric Compounds; D006256:Hazardous Waste; D001151:Arsenic