Structural disorder of a new zeolite-like lithosilicate, K(2.6)Li(5.4)[Li4Si16O38].4.3H2O.
The framework structure of the synthetic microporous lithosilicate RUB-30 (K(2.6)Li(5.4)[Li4Si16O38].4.3H2O) is similar to that of the fibrous zeolites such as natrolite, edingtonite and thomsonite, since all their frameworks include the same secondary structural building unit, the so-called 4-1 T5O10 cluster of tetrahedra. Unique to the structure of RUB-30, each 4-1 unit consists of a LiSi4O10 moiety within which the single [LiO4] tetrahedron is strictly segregated from the other four [SiO4] tetrahedra. The connection of neighboring 4-1 units through edge-sharing [LiO4] tetrahedra results in a new framework topology. The present work reports an ;average' structure of RUB-30 solved by synchrotron X-ray single-crystal diffraction data collected at a second-generation source. A superstructure with a x 2b x c (relative to the subcell quoted above) could be seen in X-ray diffraction data collected with better resolution and higher brightness at a third generation source. Diffuse streaks along k with l = odd and unusual superstructure hkl reflections, with k = odd and l = odd only, indicate a more complicated real structure of the material. To explain this observation we propose two different structure types which are statistically, but coherently, intergrown in RUB-30.
Park
So Hyun
SH
Sektion Kristallographie, Department für Geo- und Umweltwissenschaften, Ludwig-Maximilians Universität München, 80333 München, Germany. sohyun.park@physik.uni-muenchen.de
Boysen
Hans
H
Parise
John B
JB