Collision-induced dissociation studies of protonated ether--(H2O)n (n = 1-3) clusters.
We have studied the protonated ether-(H2O)n (n = 1-3) complexes containing tetrahydrofuran, dimethyl, diethyl, dibutyl, and butylmethyl ethers using a flowing afterglow triple-quadrupole mass spectrometer. Collision-induced dissociation, CID, of all clusters with n = 1, 2 shows sequential water loss. The n = 3 cluster of dimethyl ether shows sequential water loss, while all other ether clusters display selective product formation. The CID spectra are interpreted based on known energetics, and theoretical studies of the dimethyl and diethyl ether systems.
Goebbert
Daniel J
DJ
Department of Chemsitry, Purdue University, 560 Oval Drive, West Lafayette, IN 47907, USA.
Chen
Hao
H
Wenthold
Paul G
PG