title: Capillary array electrophoresis for the research of asymmetric transformation reaction of L-proline to D-proline.
abstract: One asymmetric transformation reaction of L-proline (L-Pro) to D-proline was studied by a home-made capillary array electrophoresis (CAE) for the first time. The aldehyde catalysts and the organic acid solvents for the asymmetric transformation reaction were rapidly screened and the enantiomeric excess values of the asymmetric product of L-Pro were directly obtained from the electrophoretogram of CAE.
authors.affiliation: State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, P. R. China.
authors.forename: Jun
authors.initials: J
authors.lastname: Wang
authors.forename: Kaiying
authors.initials: K
authors.lastname: Liu
authors.forename: Guangming
authors.initials: G
authors.lastname: Sun
authors.forename: Jiling
authors.initials: J
authors.lastname: Bai
authors.forename: Li
authors.initials: L
authors.lastname: Wang
mesh_terms: D000447:Aldehydes / Q000032:analysis; D002384:Catalysis; D002623:Chemistry Techniques, Analytical / Q000379:methods; D019075:Electrophoresis, Capillary / Q000379:methods*; D008956:Models, Chemical; D011392:Proline / Q000032:analysis*; D012997:Solvents / Q000494:pharmacology; D013237:Stereoisomerism; D013997:Time Factors
chemical_list: D000447:Aldehydes; D012997:Solvents; D011392:Proline