Novel phosphoranido complex of rhodium(III) tetraphenylporphyrin. Synthesis and characterization.
A novel phosphoranido complex of rhodium(III) porphyrin was prepared by the reaction of a lithium phosphoranide, generated from a P-H phosphorane bearing two 8-oxy-1-naphthyl groups, with (TPP)RhCl (TPP = dianion of 5,10,15,20-tetraphenylporphyrin). The crystal structure of the complex was determined by X-ray structural analysis.
Kajiyama
Kazumasa
K
Department of Chemistry, School of Science, Kitasato University, 1-15-1 Kitasato, Sagamihara, Kanagawa 228-8555, Japan.
Miyamoto
Takeshi K
TK
Sawano
Kaita
K