Novel triptycene-based cylindrical macrotricyclic host: synthesis and complexation with paraquat derivatives.
[reaction: see text] A novel triptycene-based cylindrical macrotricyclic polyether containing two dibenzo[24]crown-8 cavities has been synthesized and proved to be a highly efficient host for the complexation with paraquat derivatives. Consequently, a new kind of very stable pseudorotaxane-type complex was formed in solution and in the solid state.
Zong
Qian-Shou
QS
Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China.
Chen
Chuan-Feng
CF
D043844:Crown Ethers / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D008968:Molecular Conformation; D015394:Molecular Structure; D010269:Paraquat / Q000031:analogs & derivatives* / Q000737:chemistry*; D043862:Rotaxanes / Q000138:chemical synthesis / Q000737:chemistry*
D043844:Crown Ethers; D043862:Rotaxanes; D010269:Paraquat