title: Iron hydrogenase active site mimic holding a proton and a hydride.
abstract: The first model of the iron hydrogenase active site has been prepared which concomitantly carries a proton and a hydride; the title species was characterized by IR and NMR spectroscopy and is reduced at more positive potential than any other mimic of this kind.
authors.affiliation: Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, 10691, Stockholm, Sweden.
authors.forename: Lennart
authors.initials: L
authors.lastname: Schwartz
authors.forename: Gerriet
authors.initials: G
authors.lastname: Eilers
authors.forename: Lars
authors.initials: L
authors.lastname: Eriksson
authors.forename: Adolf
authors.initials: A
authors.lastname: Gogoll
authors.forename: Reiner
authors.initials: R
authors.lastname: Lomoth
authors.forename: Sascha
authors.initials: S
authors.lastname: Ott
mesh_terms: D001665:Binding Sites; D006859:Hydrogen / Q000737:chemistry*; D006864:Hydrogenase / Q000737:chemistry* / Q000378:metabolism*; D007506:Iron-Sulfur Proteins / Q000737:chemistry* / Q000378:metabolism*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D018716:Molecular Mimicry; D011522:Protons; D013055:Spectrophotometry, Infrared
chemical_list: D007506:Iron-Sulfur Proteins; D011522:Protons; D006859:Hydrogen; C118830:iron hydrogenase; D006864:Hydrogenase