Stabilisation of emissive charge-separated states in pi-stacked donor-acceptor ensembles.
pi-Stacking of an electron donor and acceptor minimises reorganisation energy and stabilises charge-separated state.
Guldi
Dirk M
DM
Institute for Physical and Theoretical Chemistry, Egerlandstr. 3, 91058 Erlangen, Germany. dirk.guldi@chemie.uni-erlangen.de
Scheloske
Michael
M
Hirsch
Andreas
A
D004583:Electrons; D015394:Molecular Structure; D010777:Photochemistry; D013057:Spectrum Analysis; D013696:Temperature