Solvent-tuned azido-bridged Co2+ layers: square, honeycomb, and Kagomé.
Three azido-bridged Co2+ complexes with square, honeycomb, and Kagomé layered structures were synthesized and structurally characterized. Crystallization solvents are found to be critical in generating the observed topologies. These structurally related complexes are of significance in studying two-dimensional antiferromagnetism and geometric frustration.
Wang
Xin-Yi
XY
College of Chemistry and Molecular Engineering, State Key Laboratory of Rare Earth Materials Chemistry and Applications, Peking University, Beijing 100871, PR China.
Wang
Lu
L
Wang
Zhe-Ming
ZM
Gao
Song
S