Photocatalytic degradation of mixed gaseous carbonyl compounds at low level on adsorptive TiO2/SiO2 photocatalyst using a fluidized bed reactor.
An adsorptive silica-supported titania photocatalyst TiO(2)/SiO(2) was prepared by using nanosized titania (anatase) immobilized on silica gel by the sol-gel technique with the titanium tetra isopropoxide as the main raw material and acetic acid as the acid catalyst. Meanwhile the structure and properties of the TiO(2)/SiO(2) photocatalyst were studied by means of many modern analysis techniques such as TEM, XRD, and BET. Gas-solid heterogeneous photocatalytic decomposition of four carbonyl compounds mixture at low concentration levels over ultraviolet irradiated TiO(2)/SiO(2) photocatalyst were carried out with high degradation efficiencies in a coaxial triple-cylinder-type fluidized bed photocatalytic reactor, which provided efficient continuous contact of ultraviolet photons, silica-supported titania photocatalyst, and gaseous reactants. Experimental results showed that the photocatalyst had a high adsorption performance and a good photocatalytic activity for four carbonyl compounds mixture. Some factors influencing the photocatalytic decomposition of the mixed carbonyl compounds, i.e. the gas flowrate, relative humidity, concentration of oxygen, and illumination time, were discussed in detail. It is found that the photocatalytic reaction rate of four carbonyl compounds decreased in this order: propionaldehyde, acetone, acetaldehyde and formaldehyde.
Zhang
Maolin
M
State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environmental Resources Utilization and Protection, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Wushan Street, Guangzhou 510640, PR China.
An
Taicheng
T
Fu
Jiamo
J
Sheng
Guoying
G
Wang
Xinming
X
Hu
Xiaohong
X
Ding
Xuejun
X
D000327:Adsorption; D000393:Air Pollutants / Q000032:analysis*; D000447:Aldehydes / Q000032:analysis*; D002384:Catalysis; D005740:Gases / Q000032:analysis; D049329:Nanostructures / Q000737:chemistry; D010777:Photochemistry; D058428:Silica Gel; D012822:Silicon Dioxide / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*; D018505:Waste Management / Q000295:instrumentation / Q000379:methods
D000393:Air Pollutants; D000447:Aldehydes; D005740:Gases; C009495:titanium dioxide; D058428:Silica Gel; D012822:Silicon Dioxide; D014025:Titanium