title: Synthesis of functionalized benzylsilanes from arylzinc compounds and (iodomethyl)trimethylsilane by means of a novel Rh catalysis.
abstract: [reaction: see text] The catalytic activity of a Rh complex in cross-coupling between ArZnI and TMSCH2I was examined in which the Rh complex, generated in situ from [RhCl(1,5-cyclooctadiene)]2 and 1,1'-bis(diphenylphosphino)ferrocene, exhibited excellent catalytic activity for the production of various functionalized benzylsilanes in good yields. From 31P NMR studies of various solutions containing several of the reaction components, confirmation of the rapid and quantitative transfer of aryl groups from ArZnI to the Rh complex to form arylrhodium species was ascertained. A catalytic cycle, commencing with the transmetalation, was thus proposed for the reaction.
authors.affiliation: Department of Chemistry, Faculty of Science, Okayama University, Tsushima, Okayama 700-8530, Japan.
authors.forename: Hideki
authors.initials: H
authors.lastname: Takahashi
authors.forename: Kabir M
authors.initials: KM
authors.lastname: Hossain
authors.forename: Yasushi
authors.initials: Y
authors.lastname: Nishihara
authors.forename: Takanori
authors.initials: T
authors.lastname: Shibata
authors.forename: Kentaro
authors.initials: K
authors.lastname: Takagi