Synthesis of tetrasubstituted and functionalized enol ethers by E-selective olefination of esters with ynolates.
We have developed the E-selective olefination of ester carbonyls to afford tetrasubstituted, functionalized olefins and the C-S insertion of thiol esters to give beta-keto thiol esters via ynolates.
Shindo
Mitsuru
M
Institute of Health Biosciences, The University of Tokushima Graduate School, Japan. shindo@cm.kyushu-u.ac.jp
Kita
Taisuke
T
Kumagai
Toshihiro
T
Matsumoto
Kenji
K
Shishido
Kozo
K