Multifunctional microsized modified kaolin and its application in wastewater treatment.
The multifunctional microsized ZnO-PO(4)(3-)-modified kaolin of average diameter about 500nm with the composition Na(2)O:ZnO:Na(3)PO(4):SiO(2):Al(2)O(3)=2.5-8.5:0.04-0.65:0.8-4.5:1.5-2.5:1 (molar ratio) were firstly synthesized from ZnO, Na(3)PO(4), NaOH and kaolin and characterized by standard techniques, its application in oilfield produced wastewater purification was also studied. It was found that the physical properties of ZnO-PO(4)(3-)-modified kaolin such as specific surface area, porous volume and pore diameter increased independently compared to the starting kaolin. It was also found that the prepared kaolin has multifunctional properties to decrease COD and BOD value, remove scaling ion (Fe(n+), Ca(2+) and Mg(2+)), improve MF, decrease bacteria and inhibit corrosion and can be used effectively in oilfield wastewater purification.
Ma
H-Zh
HZ
Institute of Energy Chemistry, College of Chemistry and Materials Science, Shaanxi Normal University, Xi'An 710062, China. mahongzh@126.com
Wang
B
B
D007616:Kaolin / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D010316:Particle Size; D014874:Water Pollutants, Chemical / Q000737:chemistry*
D014874:Water Pollutants, Chemical; D007616:Kaolin