Capillary array electrophoresis for the research of asymmetric transformation reaction of L-proline to D-proline.
One asymmetric transformation reaction of L-proline (L-Pro) to D-proline was studied by a home-made capillary array electrophoresis (CAE) for the first time. The aldehyde catalysts and the organic acid solvents for the asymmetric transformation reaction were rapidly screened and the enantiomeric excess values of the asymmetric product of L-Pro were directly obtained from the electrophoretogram of CAE.
Wang
Jun
J
State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, P. R. China.
Liu
Kaiying
K
Sun
Guangming
G
Bai
Jiling
J
Wang
Li
L
D000447:Aldehydes / Q000032:analysis; D002384:Catalysis; D002623:Chemistry Techniques, Analytical / Q000379:methods; D019075:Electrophoresis, Capillary / Q000379:methods*; D008956:Models, Chemical; D011392:Proline / Q000032:analysis*; D012997:Solvents / Q000494:pharmacology; D013237:Stereoisomerism; D013997:Time Factors
D000447:Aldehydes; D012997:Solvents; D011392:Proline