Gas-phase uranyl-nitrile complex ions.
Electrospray ionization was used to generate doubly charged complex ions composed of the uranyl ion and nitrile ligands. The complexes, with general formula [UO2(RCN)n]2+, n = 0-5 (where R=CH3-, CH3CH2-, or C6H5-), were isolated in an ion-trap mass spectrometer to probe intrinsic reactions with H2O. For these complexes, two general reaction pathways were observed: (a) the direct addition of one or more H2O ligands to the doubly charged complexes and (b) charge-reduction reactions. For the latter, the reactions produced uranyl hydroxide, [UO2OH], complexes via collisions with gas-phase H2O molecules and the elimination of protonated nitrile ligands.
Van Stipdonk
Michael J
MJ
Department of Chemistry, Wichita State University, Wichita, Kansas 67260-0051, USA.
Chien
Winnie
W
Bulleigh
Kellis
K
Wu
Qun
Q
Groenewold
Gary S
GS