Source determination of highly chlorinated biphenyl isomers in pine needles - comparison to several PCB preparations.
The isomer specific composition of 13 technical PCB formulations of different origin and of pine needles was analyzed using GC/MS and HRGC/HRMS. Nonachlorinated biphenyls were identified in 11 among 13 formulations analyzed, with the highest abundance found for highly chlorinated ones (Aroclors 1268 and 1260, Chlorofen, Sovol, Kanechlors 600 and 500, Delor 106, Clophen A60). Decachlorobiphenyl was identified only in Aroclor 1268, Clophen A60, Aroclor 1260 and Chlorofen, comprising, respectively, 8.9, 2.8, 1.3 and 0.82% of the total bulk of nona- and decaCBs detected. Nona- and decaCB were detected in pine needles in Poland with the highest concentrations found at the sites neighboring to a former production sites of the Polish PCB formulations, while in pine needles collected around the Tokyo Bay nona- and decacCB were detected only in four of 10 sites and the concentrations corresponded to those found at the rural areas of Poland.
Wyrzykowska
Barbara
B
National Institute of Advanced Industrial Science and Technology (AIST), EMTECH, Potential Pollutants Group, Tsukuba, Japan.
Bochentin
Ilona
I
Hanari
Nobuyasu
N
Orlikowska
Anna
A
Falandysz
Jerzy
J
Yuichi
Horii
H
Yamashita
Nobuyoshi
N
D001673:Biodegradation, Environmental; D002617:Chemical Industry; D004784:Environmental Monitoring / Q000379:methods; D004785:Environmental Pollutants / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry; D006843:Hydrocarbons, Chlorinated / Q000032:analysis; D007220:Industrial Waste; D028223:Pinus / Q000737:chemistry*; D018515:Plant Leaves / Q000737:chemistry; D011044:Poland; D011078:Polychlorinated Biphenyls / Q000032:analysis*; D013057:Spectrum Analysis; D014041:Tokyo
D004785:Environmental Pollutants; D006843:Hydrocarbons, Chlorinated; D007220:Industrial Waste; C001870:nonachlor; D011078:Polychlorinated Biphenyls; C005381:decachlorobiphenyl