Stable and robust polymer nanotubes stretched from polymersomes.
We create long polymer nanotubes by directly pulling on the membrane of polymersomes using either optical tweezers or a micropipette. The polymersomes are composed of amphiphilic diblock copolymers, and the nanotubes formed have an aqueous core connected to the aqueous interior of the polymersome. We stabilize the pulled nanotubes by subsequent chemical cross-linking. The cross-linked nanotubes are extremely robust and can be moved to another medium for use elsewhere. We demonstrate the ability to form networks of polymer nanotubes and polymersomes by optical manipulation. The aqueous core of the polymer nanotubes together with their robust character makes them interesting candidates for nanofluidics and other applications in biotechnology.
Reiner
Joseph E
JE
Physics Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899-8424, USA.
Wells
Jeffrey M
JM
Kishore
Rani B
RB
Pfefferkorn
Candace
C
Helmerson
Kristian
K
D055598:Chemical Phenomena; D002627:Chemistry, Physical; D003432:Cross-Linking Reagents / Q000494:pharmacology; D008051:Lipid Bilayers / Q000737:chemistry; D008422:Materials Testing; D018613:Microscopy, Confocal; D046529:Microscopy, Electron, Transmission; D018715:Microscopy, Video; D036103:Nanotechnology; D043942:Nanotubes / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D013696:Temperature
D003432:Cross-Linking Reagents; D008051:Lipid Bilayers; D011108:Polymers