Nickel(0)-catalyzed isomerization of an aryne complex: formation of a dinuclear Ni(I) complex via C-H rather than C-F bond activation.
The reaction of the aryne complex (PEt3)2Ni(eta2-C6H2-4,5-F2) with a catalytic amount of Ni(PEt3)2 results in a dinuclear Ni(I) complex from the coupling of the isomer (PEt3)2Ni(eta2-C6H2-3,4-F2), obtained via rearrangement of the aromatic C-H bonds, which demonstrates that Ni(PEt3)2 is kinetically capable of C-H bond activation, even in the presence of C-F bonds. The intermediate [(PEt3)2Ni]2(mu-eta2:eta2-C6H2-4,5-F2) was isolated and crystallographically characterized; the mu-eta2:eta2-bonding mode observed is unprecedented in aryne chemistry.
Keen
Alana L
AL
Department of Chemistry & Biochemistry, University of Windsor, Windsor, Ontario, Canada N9B 3P4.
Johnson
Samuel A
SA