Synthesis and structural characterization of endohedral pyrrolidinodimetallofullerene: La2@C80(CH2)2NTrt.
The endohedral pyrrolidinodimetallofullerene, La2@C80(CH2)2NTrt (Trt = triphenylmethyl), was successfully synthesized and characterized. X-ray crystallographic and NMR spectroscopic analyses reveal that two La atoms in the 6,6-adduct are localized at the stable site on the mirror plane. Theoretical calculation also suggests the localization of two La atoms in the 6,6-adduct.
Yamada
Michio
M
Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan.
Wakahara
Takatsugu
T
Nakahodo
Tsukasa
T
Tsuchiya
Takahiro
T
Maeda
Yutaka
Y
Akasaka
Takeshi
T
Yoza
Kenji
K
Horn
Ernst
E
Mizorogi
Naomi
N
Nagase
Shigeru
S