Effect of initial solution pH on the degradation of Orange II using clay-based Fe nanocomposites as heterogeneous photo-Fenton catalyst.
Effect of initial solution pH on the discoloration and mineralization of 0.2 mM Orange II by using two clay-based Fe nanocomposites (Fe-B (Fe supported on bentonite clay) and Fe-Lap-RD (Fe supported on laponite clay)) as catalysts was studied in detail. It was found that the initial solution pH not only influences the photo-catalytic activity of Fe-B and Fe-Lap-RD but also the Fe leaching from the two catalysts. Both catalysts show the best photo-catalytic activity at an initial solution pH of 3.0, and the activity of the catalysts decreases as the initial solution pH increases. At optimal conditions, 100% discoloration and mineralization of 0.2 mM Orange II are achieved in 60 and 120 min reaction in the presence of 10 mM H2O2, 1.0 g/L Fe-B, and 1 x 8 W UVC at initial solution pH of 3.0. 100% discoloration and 90% mineralization of 0.2 mM Orange II are achieved when Fe-Lap-RD is used as catalyst under the same conditions. Both catalysts also display a reasonable good photo-catalytic activity and negligible Fe leaching at an initial solution pH of 6.6 that is very close to neutral pH. This characteristic makes it possible for the Fe-B and Fe-Lap-RD to have a long-term stability. It also becomes feasible for the photo-Fenton process to treat the original wastewater without the need to pre-adjust the solution pH.
Feng
Jiyun
J
Department of Chemical Engineering, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong.
Hu
Xijun
X
Yue
Po Lock
PL
D000538:Aluminum Silicates; D001391:Azo Compounds / Q000737:chemistry*; D001557:Benzenesulfonates / Q000737:chemistry*; D000077215:Clay; D004396:Coloring Agents / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007501:Iron / Q000737:chemistry; D049329:Nanostructures; D010084:Oxidation-Reduction; D010777:Photochemistry; D014865:Waste Disposal, Fluid
D000538:Aluminum Silicates; D001391:Azo Compounds; D001557:Benzenesulfonates; D004396:Coloring Agents; D007501:Iron; C014722:2-naphthol orange; D000077215:Clay