Analysis of lanthanide-induced NMR shifts of the Ce@C82 anion.
The mapping of bond connectivity in the carbon cage of [Ce@C82]- and full assignment of the NMR lines were successfully achieved by means of 2D INADEQUATE NMR measurement. Paramagnetic NMR analysis shows that the Ce atom in [Ce@C82]- is located at an off-centered position adjacent to a hexagonal ring along the C2 axis of the C2v-C82 cage.
Yamada
Michio
M
Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan.
Wakahara
Takatsugu
T
Lian
Yongfu
Y
Tsuchiya
Takahiro
T
Akasaka
Takeshi
T
Waelchli
Markus
M
Mizorogi
Naomi
N
Nagase
Shigeru
S
Kadish
Karl M
KM