Unbinding and preunbinding in surfactant solutions.
We propose models for the first-order unbinding transition of lyotropic lamellae in surfactant solutions. The coupling between the surfactant volume fraction and the elastic degree of freedom is considered so that the net attractive interaction between the surfactant molecules is enhanced. The elastic degree of freedom can be either (i) a membrane elastic degree of freedom or (ii) a bulk elastic degree of freedom. The phase behaviors of these two models are analyzed. For both cases, the unbinding transition becomes first order when the coupling is strong enough. We determine the associated preunbinding line which separates two lamellar phases having different repeat distances.
Komura
S
S
Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Tokyo 192-0397, Japan. komura@comp.metro-u.ac.jp
Shimokawa
N
N
Kato
T
T