title: Synthesis and structural characterization of endohedral pyrrolidinodimetallofullerene: La2@C80(CH2)2NTrt.
abstract: The endohedral pyrrolidinodimetallofullerene, La2@C80(CH2)2NTrt (Trt = triphenylmethyl), was successfully synthesized and characterized. X-ray crystallographic and NMR spectroscopic analyses reveal that two La atoms in the 6,6-adduct are localized at the stable site on the mirror plane. Theoretical calculation also suggests the localization of two La atoms in the 6,6-adduct.
authors.affiliation: Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan.
authors.forename: Michio
authors.initials: M
authors.lastname: Yamada
authors.forename: Takatsugu
authors.initials: T
authors.lastname: Wakahara
authors.forename: Tsukasa
authors.initials: T
authors.lastname: Nakahodo
authors.forename: Takahiro
authors.initials: T
authors.lastname: Tsuchiya
authors.forename: Yutaka
authors.initials: Y
authors.lastname: Maeda
authors.forename: Takeshi
authors.initials: T
authors.lastname: Akasaka
authors.forename: Kenji
authors.initials: K
authors.lastname: Yoza
authors.forename: Ernst
authors.initials: E
authors.lastname: Horn
authors.forename: Naomi
authors.initials: N
authors.lastname: Mizorogi
authors.forename: Shigeru
authors.initials: S
authors.lastname: Nagase