Tris(1,10-phenanthroline)copper(II) di-mu-iodo-bis(diiodomercurate) dimethyl sulfoxide monohydrate.
In the cationic complex present in the title compound, [Cu(C12H8N2)3][Hg2I6].C2H6OS.H2O, the copper(II) center adopts a highly distorted octahedral geometry, ligated by the six N atoms of three 1,10-phenanthroline ligands. The structure includes an iodide-bridged dimeric mercurate anion for neutrality and uncoordinated dimethyl sulfoxide and water molecules.
Oh
Myeong-Jin
MJ
Department of Chemistry and Chemistry Institute for Functional Materials, Pusan National University, Pusan 609-735, South Korea.
Lee
Yong-Min
YM
Lee
Seung-Jae
SJ
Kang
Sung-Kwon
SK
Choi
Sung-Nak
SN