title: Phase separations in pH-responsive polyelectrolyte multilayers: charge extrusion versus charge expulsion.
abstract: Polyelectrolyte multilayers with continuously variable amounts of ionizable weak acid functionality were prepared by blending ionizable and nonionizable polyelectrolytes in the deposition solutions. Diluting ionizable groups in this way yielded multilayers that were more structurally stable, shown by thickness and atomic force microscopy measurements, as their internal polymer charge was varied by the pH of the external solution. Multilayers prepared with opposite surface charge to that appearing within the bulk (as a result of ionization) were more stable, as were thinner films, both results suggesting the extrusion of bulk charge to the surface. These multilayers were able to control the direction and magnitude of electroosmotic flow in microfluidics systems. Multilayers bearing only one, diluted layer ofionizable material were surprisingly effective in this respect.
authors.affiliation: Department of Chemistry and Biochemistry, Center for Materials Research and Technology (MARTECH), The Florida State University, Tallahassee, Florida 32306-4390, USA.
authors.forename: Zhijie
authors.initials: Z
authors.lastname: Sui
authors.forename: Joseph B
authors.initials: JB
authors.lastname: Schlenoff
mesh_terms: D004573:Electrolytes / Q000737:chemistry*; D053841:Electroosmosis; D006863:Hydrogen-Ion Concentration; D008567:Membranes, Artificial; D044085:Microfluidics; D018625:Microscopy, Atomic Force; D010316:Particle Size; D011108:Polymers / Q000737:chemistry*; D012680:Sensitivity and Specificity; D012996:Solutions / Q000737:chemistry; D013499:Surface Properties
chemical_list: D004573:Electrolytes; D008567:Membranes, Artificial; D011108:Polymers; D012996:Solutions