Synthesis, characterization, and X-ray crystal structure of a gallium monohydroxide and a hetero-bimetallic gallium zirconium oxide.
A monomeric hydroxide of gallium, LGa(Me)OH, containing terminal hydroxide and methyl groups was prepared by the hydrolysis of LGa(Me)Cl in the presence of N-heterocyclic carbene and water [L = HC{(CMe)(2,6-i-Pr2C6H3N)}2] in high yield and in a pure form. LGa(Me)OH was used as a synthon to assemble the first hetero-bimetallic compound with a Ga-O-Zr core, [(LGaMe)(Cp2ZrMe)](mu-O).
Singh
Sanjay
S
Institut für Anorganische Chemie der Georg-August-Universität Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany.
Jancik
Vojtech
V
Roesky
Herbert W
HW
Herbst-Irmer
Regine
R
D018360:Crystallography, X-Ray; D005708:Gallium / Q000737:chemistry*; D006878:Hydroxides / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D015040:Zirconium / Q000737:chemistry*
D006878:Hydroxides; D009942:Organometallic Compounds; D015040:Zirconium; D005708:Gallium; C028541:zirconium oxide