A paramagnetic Cu(I)/Cu(II)/Zn(II) coordination polymer with multiple CN-binding modes and its solid-state NMR characterization.
A Cu(I)/Cu(II)/Zn(II) mixed-valent [Cu(en)2][Zn(NC)4(CuCN)2] polymer, which has a 2-D layer structure with six structurally inequivalent cyanides in four distinct bonding modes, has been prepared; structurally informative 13C and 15N MAS NMR spectra of this paramagnetic system are readily observable.
Ouyang
Liang
L
Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, B.C. V5A 1S6, Canada.
Aguiar
Pedro M
PM
Batchelor
Raymond J
RJ
Kroeker
Scott
S
Leznoff
Daniel B
DB