Unexpected bromination ring-opening of tetraarylporphyrins.
An unexpected, mild, efficient bromination ring-opening method has been developed for convenient synthesis of various novel biladienes or brominated porphyrins by controlling the amounts of NBS used.
Liu
Chao
C
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Road, 200032, China.
Shen
Dong-Mei
DM
Chen
Qing-Yun
QY
D001966:Bromine / Q000737:chemistry*; D008956:Models, Chemical; D008958:Models, Molecular; D011166:Porphyrins / Q000737:chemistry*; D013237:Stereoisomerism
D011166:Porphyrins; D001966:Bromine