A molecular pinwheel multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ with mu4-sulfido, mu3-thiolato and nitrogen ligands.
A copper(I) complex with new N2S thiol ligand transforms to a multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ (1); its X-ray structure exhibiting mu4-sulfido and mu3-thiolato coordination is presented and compared to other cuprous thiolato/sulfido clusters including that observed in the copper enzyme nitrous oxide reductase.
Lee
Yunho
Y
Department of Chemistry, John Hopkins University, 3400 North Charles Street, Baltimore, MD 21218, USA.
Sarjeant
Amy A Narducci
AA
Karlin
Kenneth D
KD
D001665:Binding Sites; D003300:Copper / Q000737:chemistry* / Q000378:metabolism; D018360:Crystallography, X-Ray; D007454:Iodides / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D009584:Nitrogen / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010088:Oxidoreductases / Q000737:chemistry / Q000378:metabolism; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013440:Sulfides / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry*
D007454:Iodides; D008024:Ligands; D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D013440:Sulfides; D013455:Sulfur; D003300:Copper; D010088:Oxidoreductases; C022763:nitrous oxide reductase; D009584:Nitrogen