Spectroscopic and thermal studies of chromium(III), molybdenum(VI) and ruthenium(0) complexes of maleic hydrazide.
Interaction of maleic hydrazide (LH(2)) with [Cr(CO)(6)] in air at atmospheric pressure resulted in the formation of the complex [(LH)Cr(mu-O)(2)Cr(LH)] (1). Reaction of LH(2) with [Mo(CO)(6)] in air also gave the complex [(LH(2))O(2)Mo(mu-O)(2)MoO(2)(LH(2))] (2). Under the same conditions, the reaction of LH(2) with [Ru(3)(CO)(12)] resulted in the formation of the tricarbonyl complex [Ru(CO)(3)(LH(2))] (3). The complexes were characterized by elemental analysis, IR, and (1)H NMR spectroscopy. The thermal properties of the complexes were investigated by thermogravimetry technique.
Mohamed
Hassan A
HA
Department of Chemistry, Faculty of Science, Cairo University, El-Faiyum Branch, El-Faiyum, Egypt.
Ali
Saadia A
SA
Ramadan
Ramadan M
RM
D002857:Chromium / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008300:Maleic Hydrazide / Q000737:chemistry*; D008956:Models, Chemical; D008982:Molybdenum / Q000737:chemistry*; D011312:Pressure; D012428:Ruthenium / Q000737:chemistry*; D013053:Spectrophotometry / Q000379:methods*; D013055:Spectrophotometry, Infrared / Q000379:methods*; D017550:Spectroscopy, Fourier Transform Infrared / Q000295:instrumentation / Q000379:methods*; D013818:Thermogravimetry
D002857:Chromium; D012428:Ruthenium; D008982:Molybdenum; D008300:Maleic Hydrazide