Laser ablation of imidazolium based ionic liquids.
Time-of-flight mass spectrometry has been used to investigate the IR ablation of several ionic liquid imidazolium salts of the form R(1)R(2)Iium X (R(1) = methyl; R(2) = methyl, ethyl, butyl, and hexyl; X = Cl(-), NO(3)(-), and CH(3)SO(4)(-)). The ablated ionic species were analyzed by time-of-flight mass spectrometry using pulsed extraction, and neutral species were detected using vacuum UV photoionization at 10.5 eV. The results demonstrate that at least 99% of the ablated material is removed in the form of nano- or microdroplets consisting of intact ionic liquid. Approximately 1% is ejected as imidazole molecules (R(1)R(2)Im) produced through the elimination of HCl, and about 0.1% of the material is ejected in the form of single salt molecules of R(1)R(2)Iium X. A chemical thermometer was used to measure the internal temperature (475 +/- 25 K) of the ablated vapor plume.
Dessiaterik
Yury
Y
Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599-3290, USA.
Baer
Tomas
T
Miller
Roger E
RE