Solvent and ligand partition reaction pathways in nickel-mediated carboxylation of methylenecyclopropanes.
Methylenecyclopropanes are carboxylated with gaseous carbon dioxide in the presence of a stoichiometric amount of a nickel complex; the reaction pathways are significantly influenced by the reaction solvent and the amine ligand.
Murakami
Masahiro
M
Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan. murakami@sbchem.kyoto-u.ac.jp
Ishida
Naoki
N
Miura
Tomoya
T