1H-15N NMR studies of the complex bis(S-allyl-L-cysteinate)palladium(II).
1H-15N 2D NMR data for S-allyl-L-cysteine (deoxyalliin) and for bis(S-allyl-L-cysteinate)palladium(II) complex are presented in this manuscript. Large upfield 15N NMR shift of the amine nitrogen in the spectrum of the complex when compared to the spectrum of the ligand shows clearly coordination of S-allyl-L-cysteine, in the anion form, to palladium(II) through the NH2 group.
Corbi
Pedro P
PP
Departamento de Química Geral e Inorgânica, Instituto de Química-UNESP, Rua Prof. Francisco Degni s/n, CP 355, CEP 14801-970, Araraquara, SP, Brazil. pedrcorb@posgrad.iq.unesp.br
Massabni
Antonio C
AC
D000588:Amines / Q000737:chemistry; D003545:Cysteine / Q000031:analogs & derivatives* / Q000737:chemistry*; D006859:Hydrogen; D009682:Magnetic Resonance Spectroscopy; D009587:Nitrogen Isotopes; D010165:Palladium / Q000737:chemistry*
D000588:Amines; D009587:Nitrogen Isotopes; D010165:Palladium; D006859:Hydrogen; D003545:Cysteine