Valence tautomeric transitions with thermal hysteresis around room temperature and photoinduced effects observed in a cobalt-tetraoxolene complex.
A dinuclear complex, [(CoTPA)2(DHBQ)](PF6)3, has been successfully synthesized that exhibits a valence tautomeric transition with a distinct hysteresis effect (13 K) around room temperature and photoinduced valence tautomerism under low temperature.
Tao
Jun
J
Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga, 816-8580 Fukuoka, Japan.
Maruyama
Hiroyuki
H
Sato
Osamu
O