Tetrapiperidinium di-mu-methoxy-di-mu5-oxo-tetra-mu3-oxo-dodeca-mu2-oxo-octaoxodecavanadate.
The structure of the title compound, (C5H12N)4[V10O26(CH3O)2], reveals the presence of four protonated piperidinium cations and a [{V10O26}(OCH3)2]4- polyanion having an embedded centre of inversion. The compound is distinguished by presenting, in contrast with other anionic decavanadates, two methoxy groups bridging the outermost V atoms, and it becomes the first example of this type among reported decavanadates.
Sun
Fen
F
Marine Drug and Food Institute, Ocean University of China, 266003 Qingdao, People's Republic of China.
Li
Yan Tuan
YT
Wu
Zhi Yong
ZY
Wang
Da Qi
da Q
Dou
Jian Min
JM
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D014638:Vanadates / Q000737:chemistry*
D009942:Organometallic Compounds; C515542:tetrapiperidinium di-mu-methoxy-di-mu5-oxo-tetra-mu3-oxo-dodeca-mu2-oxo-octaoxodecavanadate; D014638:Vanadates