A dinuclear triple-stranded helicate with a bis(benzene-o-dithiolato) ligand.
The bis(benzene-o-dithiol) ligand H4-1 reacts with Ti4+ in a self-assembly reaction to give the dinuclear triple-stranded helicate [Ti2(1)3]4- which is the first helicate build exclusively from benzene-o-dithiolato donor groups.
Hahn
F Ekkehardt
FE
Institut für Anorganische und Analytische Chemie, Universität Münster, Wilhelm Klemm Strasse 8, D-48149, Münster, Germany. fehahn@uni-muenster.de
Kreickmann
Thorsten
T
Pape
Tania
T
D000838:Anions; D001554:Benzene / Q000737:chemistry*; D002412:Cations; D002626:Chemistry, Pharmaceutical / Q000379:methods; D008024:Ligands; D046911:Macromolecular Substances; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D008968:Molecular Conformation; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry; D021241:Spectrometry, Mass, Electrospray Ionization; D013438:Sulfhydryl Compounds / Q000737:chemistry*
D000838:Anions; D002412:Cations; D008024:Ligands; D046911:Macromolecular Substances; D011108:Polymers; D013438:Sulfhydryl Compounds; D001554:Benzene