title: Preparation and characterization of thin films of SiO(x) on gold substrates for surface plasmon resonance studies.
abstract: We report here on the fabrication and characterization of stable thin films of amorphous silica (SiO(x)) deposited on glass slides coated with a 5 nm adhesion layer of titanium and 50 nm of gold, using the plasma-enhanced chemical vapor deposition (PECVD) technique. The resulting surfaces were characterized using atomic force microscopy (AFM), ellipsometry, contact angle measurements, and surface plasmon resonance (SPR). AFM analysis indicates that homogeneous films of silica with low roughness were formed on the gold surface. The deposited silica films showed excellent stability in different solvents and in piranha solution. There was no significant variation in the thickness or in the SPR signal after these harsh treatments. The Au/SiO(x) interfaces were investigated for their potential applications as new surface plasmon resonance sensor chips. Silica films with thicknesses up to 40 nm allowed visualization of the surface plasmon effect, while thicker films resulted in the loss of the SPR characteristics. SPR allowed further the determination of the silica thickness and was compared to ellipsometric results. Chemical treatment of the SiO(x) film with piranha solution led to the generation of silanol surface groups that have been coupled with a trichlorosilane.
authors.affiliation: Laboratoire d'Electrochimie et de Physicochimie des Matériaux et des Interfaces, CNRS-INPG-UJF, 1130 rue de la piscine, BP 75, 38402 St. Martin d'Hères Cedex, France. sabine.szunerits@enseeg.inpg.fr
authors.forename: Sabine
authors.initials: S
authors.lastname: Szunerits
authors.forename: Rabah
authors.initials: R
authors.lastname: Boukherroub