title: Recovery of homogeneous polyoxometallate catalysts from aqueous and organic media by a mesoporous ceramic membrane without loss of catalytic activity.
abstract: The recovery of homogeneous polyoxometallate (POM) oxidation catalysts from aqueous and non-aqueous media by a nanofiltration process using mesoporous gamma-alumina membranes is reported. The recovery of Q(12)[WZn(3)(ZnW(9)O(34))(2)] (Q=[MeN(n-C(8)H(17))(3)](+)) from toluene-based media was quantitative within experimental error, while up to 97 % of Na(12)[WZn(3)(ZnW(9)O(34))(2)] could be recovered from water. The toluene-soluble POM catalyst was used repeatedly in the conversion of cyclooctene to cyclooctene oxide and separated from the product mixture after each reaction. The catalytic activity increased steadily with the number of times that the catalyst had been recycled, which was attributed to partial removal of the excess QCl that is known to have a negative influence on the catalytic activity. Differences in the permeability of the membrane for different liquid media can be attributed to viscosity differences and/or capillary condensation effects. The influence of membrane pore radius on permeability and recovery is discussed.
authors.affiliation: University of Twente, MESA+ Institute for Nanotechnology, P.O. Box 217, 7500 AE Enschede, The Netherlands.
authors.forename: Sankhanilay
authors.initials: S
authors.lastname: Roy Chowdhury
authors.forename: Peter T
authors.initials: PT
authors.lastname: Witte
authors.forename: Dave H A
authors.initials: DH
authors.lastname: Blank
authors.forename: Paul L
authors.initials: PL
authors.lastname: Alsters
authors.forename: Johan E
authors.initials: JE
authors.lastname: Ten Elshof
mesh_terms: D002384:Catalysis; D002516:Ceramics; D008567:Membranes, Artificial; D009942:Organometallic Compounds / Q000302:isolation & purification*; D012996:Solutions; D014867:Water
chemical_list: D008567:Membranes, Artificial; D009942:Organometallic Compounds; D012996:Solutions; D014867:Water