Removal of chromium(III) from tannery wastewater using activated carbon from sugar industrial waste.
Chromium is commonly found in huge quantities in tannery wastewaters. For this reason, the removal and recovery of the chromium content of tannery wastewaters is crucial for environmental protection and economic reasons. Removal and recovery of chromium were carried out by using low-cost potential adsorbents. For this purpose three types of activated carbon; C1, the waste generated from sugar industry as waste products and the others (C2, C3) are commercial granular activated carbon, were used. The adsorption process and extent of adsorption are dependent on the physical and chemical characteristics of the adsorbent, adsorbate and experimental condition. The effect of pH, particle size and different adsorbent on the adsorption isotherm of Cr(III) was studied in batch system. The sorption data fitted well with Langmuir adsorption model. The efficiencies of activated carbon for the removal of Cr(III) were found to be 98.86, 98.6 and 93 % for C1, C2 and C3, respectively. The order of selectivity is C1>C2>C3 for removal of Cr(III) from tannery wastewater. Carbon "C1" of the highest surface area (520.66 m(2)/g) and calcium content (333.3 mg/l) has the highest adsorptive capacity for removal of Cr(III). The results revealed that the trivalent chromium is significantly adsorbed on activated carbon collected from sugar industry as waste products and the method could be used economically as an efficient technique for removal of Cr(III) and purification of tannery wastewaters.
Fahim
N F
NF
Department of Inorganic Chemistry, National Research Center, Dokki, Giza, Egypt. fnarges@hotmail.com
Barsoum
B N
BN
Eid
A E
AE
Khalil
M S
MS
D000327:Adsorption; D002241:Carbohydrates / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002857:Chromium / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste; D010316:Particle Size; D013633:Tanning; D013816:Thermodynamics; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
D002241:Carbohydrates; D007220:Industrial Waste; D014874:Water Pollutants, Chemical; D002857:Chromium; D002244:Carbon