Further study of the reaction of Fe2+ with CN-: synthesis and characterization of cis and trans [FeII,III(CN)4L2]n- complexes.
The reaction of Fe2+ with CN-, which was first performed in 1704, has been used to synthesize a new series of basic [FeII,III(CN)4L2]n- complexes, where L is a monodentate ligand. trans-Na2[FeII(CN)4(DMSO)2] and cis-[NEt4]2[FeII(CN)4(pyridine)2] are synthesized by the direct reaction of FeCl2 with 4 equiv of CN- in DMSO or pyridine. Air oxidation of the latter compound gives cis-[NEt4][FeIII(CN)4(pyridine)2]. The non-cyanide ligands in these complexes undergo facile ligand exchange reactions with solvent. Reaction of cis-[NEt4]2[FeII(CN)4(pyridine)2] with CO at room temperature gives trans-[NEt4]2[FeII(CN)4(pyridine)(CO)].
Chiarella
Gina M
GM
Department of Chemistry, State University of New York at Stony Brook, Stony Brook, New York 11794-3400, USA.
Melgarejo
Doris Y
DY
Koch
Stephen A
SA
D018360:Crystallography, X-Ray; D003486:Cyanides / Q000138:chemical synthesis / Q000737:chemistry*; D005290:Ferric Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D005296:Ferrous Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D013816:Thermodynamics
D003486:Cyanides; D005290:Ferric Compounds; D005296:Ferrous Compounds; D008024:Ligands