title: Passive sampler derived air concentrations of PBDEs along an urban-rural transect: spatial and temporal trends.
abstract: Passive air samplers consisting of polyurethane foam (PUF) disks housed in chambers were deployed at several sites along a approximately 75 km urban-rural gradient in Toronto and analyzed for polybrominated diphenyl ethers (PBDEs). Samplers were allowed to integrate gas-phase PBDEs over three consecutive seasons starting in the summer of 2000. PBDEs were fairly uniform along the transect with air concentrations in Toronto (10-30 pgm(-3)) about a factor of two greater than at rural sites. Lowest concentrations were observed during the winter and probably associated with reduced inputs from indoor sources of PBDEs and to a preference for PBDEs to partition to the particle-phase at colder temperatures. The composition of PBDEs in the air samples did not differ across the transect or for the different seasons.
authors.affiliation: Science & Technology Branch, Environment Canada, 4905 Dufferin Street, Toronto, ON, Canada. tom.harner@ec.gc.ca
authors.forename: Tom
authors.initials: T
authors.lastname: Harner
authors.forename: Mahiba
authors.initials: M
authors.lastname: Shoeib
authors.forename: Miriam
authors.initials: M
authors.lastname: Diamond
authors.forename: Michael
authors.initials: M
authors.lastname: Ikonomou
authors.forename: Gary
authors.initials: G
authors.lastname: Stern
mesh_terms: D000388:Air / Q000032:analysis* / Q000592:standards; D000392:Air Movements; D000393:Air Pollutants / Q000032:analysis*; D004784:Environmental Monitoring / Q000295:instrumentation* / Q000379:methods / Q000592:standards; D005411:Flame Retardants / Q000032:analysis*; D009864:Ontario; D010647:Phenyl Ethers / Q000032:analysis; D011075:Polybrominated Biphenyls / Q000032:analysis*; D012423:Rural Health; D012621:Seasons; D014504:Urban Health
chemical_list: D000393:Air Pollutants; D005411:Flame Retardants; D010647:Phenyl Ethers; D011075:Polybrominated Biphenyls