Brønsted guanidine acid-base ionic liquids: novel reaction media for the palladium-catalyzed Heck reaction.
[reaction: see text]. Brønsted acid-base ionic liquids (GILs) based on guanidine and acetic acid are efficient reaction media for palladium-catalyzed Heck reactions. They offer the advantages of high activity and reusability. GIL2 plays multiple roles in the reaction: it could act as solvent, as a strong base to facilitate beta-hydride elimination, and as a ligand to stabilize activated Pd species.
Li
Shenghai
S
State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Graduate School of the Chinese Academy of Sciences, Changchun 130022, China.
Lin
Yingjie
Y
Xie
Haibo
H
Zhang
Suobo
S
Xu
Jianing
J
D000085:Acetates / Q000737:chemistry; D002384:Catalysis; D006146:Guanidines / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D012997:Solvents
D000085:Acetates; D006146:Guanidines; D012997:Solvents; D010165:Palladium