Salvidorol, a nor-abietane diterpene with a rare carbon skeleton and two abietane diterpene derivatives from Salvia dorrii.
Salvidorol (1), a irregular nor-abietane-type diterpene, was isolated from the aerial parts of Salvia dorrii, in addition to two epimeric abietane diterpenes (2 and 3). This is the first report of a nor-diterpene with an irregular skeleton. The structures were established by high-field NMR techniques ((1)H-(1)H COSY, DEPT, HMQC, HMBC, NOESY and HRMS) and in case of 2 was confirmed by X-ray analysis.
Ahmed
Ahmed A
AA
Department of Chemistry, Faculty of Science, El-Minia University, El-Minia 91516, Egypt. abdellaahmed@yahoo.com
Mohamed
Abou El-Hamd H
Ael-H
Karchesy
Joe
J
Asakawa
Yoshinori
Y
D045784:Abietanes / Q000737:chemistry* / Q000145:classification / Q000302:isolation & purification; D002244:Carbon / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006801:Humans; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D035261:Plant Components, Aerial / Q000737:chemistry; D010936:Plant Extracts / Q000737:chemistry; D027544:Salvia / Q000737:chemistry*
C510922:7-methoxyrosmanol; D045784:Abietanes; D010936:Plant Extracts; C510920:salvidorol; D002244:Carbon