Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework.
The solvent contained within the cylindrical one-dimensional pores of the novel three-dimensional metal organic framework Ni2(dhtp)(H2O)2.8H2O can be removed without decomposition of the network, allowing gas storage within the cavities.
Dietzel
Pascal D C
PD
SINTEF Materials and Chemistry, Postboks 124, Blindern, N-0314 Oslo, Norway. pascal.dietzel@sintef.no
Panella
Barbara
B
Hirscher
Michael
M
Blom
Richard
R
Fjellvåg
Helmer
H