Speciation of phytate ion in aqueous solution. Sequestering ability toward mercury(II) cation in NaClaq at different ionic strengths.
As a contribution to understanding the speciation of mercury in the environment and to the study of the sequestering ability of phytate (Phy) toward heavy metal and organometal cations, this paper describes the results of an investigation (at t = 25 degrees C by potentiometry, ISE-H+ glass electrode) of its interactions with mercury(II) cation in NaCl aqueous solutions at different ionic strengths (I = 0.15 and 1.0 mol L(-1)), in the pH range 2.5 < or = pH < or = 9.5 and considering metal-to-ligand ratios of 1:1 < or = Hg/Phy < or = 4:1. The formation of 11 HgiHjPhy(12-2i-j)(- species with i = 1 and 0 < or = j < or = 7 and i = 2 and 0 < or = j < or = 2 was observed. Their complex formation constant values proved to be fairly dependent on ionic strength. The speciation of phytic acid and mercury(II) is also dependent on the metal-to-ligand ratio; the dependence of the stability of phytate-mercury(II) species on the phytate protonation step was modeled, and an empirical predictive relationship was proposed. From the results obtained, phytate has very good sequestering ability toward Hg2+, even in the presence of considerable excesses of chloride ion, that is, another ligand strongly interacting with mercury; this supports future studies both on the use of plants that naturally synthesize it for phytoremediation purposes and on its direct application in remediation techniques.
De Stefano
Concetta
C
Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina, Salita Sperone 31, I-98166 Messina (Vill. S. Agata), Italy.
Milea
Demetrio
D
Porcino
Nunziatina
N
Sammartano
Silvio
S
D002412:Cations; D006863:Hydrogen-Ion Concentration; D008628:Mercury / Q000737:chemistry*; D009994:Osmolar Concentration; D010833:Phytic Acid / Q000032:analysis / Q000737:chemistry*; D011522:Protons; D012965:Sodium Chloride / Q000737:chemistry*; D012996:Solutions; D014867:Water
D002412:Cations; D011522:Protons; D012996:Solutions; D014867:Water; D012965:Sodium Chloride; D010833:Phytic Acid; D008628:Mercury