Gold(I)-catalyzed oxidative cleavage of a C-C double bond in water.
[reaction: see text] Oxidative cleavage of the C=C bond to afford ketone or aldehyde products with tert-butyl hydrogenperoxide (TBHP) as the oxidant can be catalyzed by AuCl with neocuproine (1) in water.
Department of Chemistry, East China Normal University, Shanghai 200062, China.
Dong
D
Xing
Bingtao
B
Guan
Guixin
G
Cai
Zhao
Z
Fang
Liping
L
Yang
Zhangjie
Z
Shi