Study of molecular rotational isomerism using deuterium NMR in chiral oriented solvents.
Deuterium NMR in polypeptide chiral liquid crystals is used for the first time to investigate the internal rotational isomerism phenomenon, illustrated by the interconversion between conformers of 1-(2,6-dideutero-4-methylphenyl)naphthalene
Lesot
Philippe
P
Laboratoire de Chimie Structurale Organique, UMR 8074, ICMMO, Bât. 410, Université de Paris-Sud, 91405, Orsay, France. philesot@icmo.u-psud.fr
Lafon
Olivier
O
Kagan
Henri B
HB
Fan
Chun-An
CA