Studies of removal of platinum(IV) ion microquantities from the model solutions of aluminium, copper, iron, nickel and zinc chloride macroquantities on the anion exchanger Duolite S 37.
Platinum has been widely applied in catalytic industry and the recovery of noble metals from industrial wastes becomes an economic issue. The laboratory studies of platinum(IV) microquantities removal from 1M aluminium, copper, iron, nickel and zinc chloride solutions in 0.1M hydrochloric acid solutions on the anion exchanger Duolite S 37 of the functional secondary and tertiary amine groups were carried out. For this anion exchanger the fraction extracted values (%E, Pt(IV)) as well as the sorption isotherms were determined depending on the kind of aqueous phase and phase contact time. Moreover, the bed and weight distribution coefficients as well as working and total ion-exchange capacities were calculated from the platinum(IV) breakthrough curves. Kinetic parameters were determined.
Department of Inorganic Chemistry, Faculty of Chemistry, Maria Curie-Skłodowska University, Maria Curie-Skłodowska Square 2, 20-031 Lublin, Poland. hubicki@hermes.umcs.lublin.pl
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D000465:Algorithms; D000837:Anion Exchange Resins; D007202:Indicators and Reagents; D008670:Metals / Q000032:analysis*; D010984:Platinum / Q000032:analysis*; D012117:Resins, Synthetic / Q000737:chemistry*; D012996:Solutions
D000837:Anion Exchange Resins; C515531:Duolite S 37; D007202:Indicators and Reagents; D008670:Metals; D012117:Resins, Synthetic; D012996:Solutions; D010984:Platinum