Electrostatic self-assembly of binary nanoparticle crystals with a diamond-like lattice.
Self-assembly of charged, equally sized metal nanoparticles of two types (gold and silver) leads to the formation of large, sphalerite (diamond-like) crystals, in which each nanoparticle has four oppositely charged neighbors. Formation of these non-close-packed structures is a consequence of electrostatic effects specific to the nanoscale, where the thickness of the screening layer is commensurate with the dimensions of the assembling objects. Because of electrostatic stabilization of larger crystallizing particles by smaller ones, better-quality crystals can be obtained from more polydisperse nanoparticle solutions.
Kalsin
Alexander M
AM
Department of Chemical and Biological Engineering, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA.
Fialkowski
Marcin
M
Paszewski
Maciej
M
Smoukov
Stoyan K
SK
Bishop
Kyle J M
KJ
Grzybowski
Bartosz A
BA