Direct influence of hydrogen-bonding on the reduction potential of a CuII center.
Two hydrogen-bonds from geometrically constrained OH groups to coordinated oxygen donors shift the reduction potential of a Cu(II) complex by +270 mV as compared to the structurally analogous reference complex missing the OH groups.
Glaser
Thorsten
T
Lehrstuhl für Anorganische Chemie I, Fakultät für Chemie, Universität Bielefeld, Universitätsstr. 25, D-33615 Bielefeld, Germany. thorsten.glaser@uni-bielefeld.de
Liratzis
Ioannis
I
Kataeva
Olga
O
Fröhlich
Roland
R
Piacenza
Manuel
M
Grimme
Stefan
S