Single-column method of ion chromatography for the determination of common cations and some transition metals.
A single-column method for the simultaneous determination of common cations and transition metals in real samples is proposed in this paper. Eleven cations (copper, lithium, sodium, ammonium, potassium, cobalt, nickel, magnesium, calcium, strontium and zinc) were separated and analyzed by means of ion chromatography using an isocratic elution with 2.5 mM methane sulfonic acid and 0.8 mM oxalic acid as mobile phase, IonPac SCS1 (250 mm x 4 mm I.D.) as the separation column and non-suppressed conductor detection. Optimized analytical conditions were further validated in terms of accuracy, precision and total uncertainty and the results showed the reliability of the IC method. The relative standard deviations (RSDs) of the retention time and peak area were less than 0.04 and 1.30%, respectively. The coefficients of determination for cations ranged from 0.9988 to 1.000. The method developed was successfully applied to determination of cations in samples of beer and bottled mineral water. The spiked recoveries for the cations were 94-106%. The method was applied to beer and beverage without interferences.
Department of Chemistry, Xixi Campus of Zhejiang University, Hangzhou, Zhejiang 310028, China.
Wenfang
W
Zeng
Yongxin
Y
Chen
Hairong
H
Cui
Feiyan
F
Wu
Yan
Y
Zhu
James S
JS
Fritz
D002412:Cations / Q000032:analysis* / Q000737:chemistry; D002852:Chromatography, Ion Exchange / Q000379:methods*; D008670:Metals / Q000032:analysis* / Q000737:chemistry; D008900:Mineral Waters / Q000032:analysis; D019815:Oxalic Acid / Q000737:chemistry; D012015:Reference Standards; D015203:Reproducibility of Results; D013451:Sulfonic Acids / Q000737:chemistry
D002412:Cations; D008670:Metals; D008900:Mineral Waters; D013451:Sulfonic Acids; D019815:Oxalic Acid