PegPhos: a monodentate phosphoramidite ligand for enantioselective rhodium-catalysed hydrogenation in water.
A BICOL derived monodentate phosphoramidite ligand gives ee's up to 89% in the enantioselective Rh-catalysed hydrogenation of N-acyl dehydroalanine using water as the solvent.
Hoen
Rob
R
Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands.
Leleu
Stephane
S
Botman
Peter N M
PN
Appelman
Vanessa A M
VA
Feringa
Ben L
BL
Hiemstra
Henk
H
Minnaard
Adriaan J
AJ
van Maarseveen
Jan H
JH