Synthesis and properties of a novel phenylazomethine dendrimer with a tetraphenylmethane core.
[structure: see text] A new type of phenylazomethine dendrimer with a tetraphenylmethane core was synthesized by a convergent method. The properties of the dendrimer were confirmed by thermal, rheological, TEM, and AFM measurements. A stepwise radial complexation was clearly observed with SnCl(2).
Department of Chemistry, Faculty of Science and Technology, Keio University, Yokohama 223-8522, Japan.
Osamu
O
Enoki
Hideaki
H
Katoh
Kimihisa
K
Yamamoto
D001391:Azo Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D050091:Dendrimers / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry*; D017971:Tin Compounds / Q000737:chemistry; D014050:Toluene / Q000737:chemistry*
D001391:Azo Compounds; D050091:Dendrimers; D011166:Porphyrins; D017971:Tin Compounds; C506824:phenylazomethine; C023599:stannous chloride; D014050:Toluene