Unprecedented CO2-promoted aminochlorination of olefins with Chloramine-T.
A new synthetic procedure for the aminochlorination of olefins for the synthesis of vicinal chloroamine derivatives using a combination of Chloramine-T and carbon dioxide is described. The method can be applied to a variety of olefins, including an electron-sufficient olefin and a conjugated diene.
Department of Applied Chemistry, Center for Atomic and Molecular Technologies, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka 565-0871, Japan.
Satoshi
S
Minakata
Yoshimi
Y
Yoneda
Yoji
Y
Oderaotoshi
Mitsuo
M
Komatsu