Solid-state (207)Pb NMR studies of lead-group 16 and mixed transition-metal/lead-group 16 element-containing materials.
(207)Pb solid-state NMR studies have been conducted on binary lead-group 16 and mixed transition-metal/lead group 16 materials, correlating the NMR chemical shifts of the materials with their structures. The experimental results show that the (207)Pb chemical shifts are strongly influenced by the local electronic structure. Data are reported for lead selenide, lead selenate, calcium plumbate, strontium plumbite, barium plumbite, lead borate, lead zirconate, lead tungstate, lead meta-tantalate, lead niobate, lead molybdate, lead meta-vanadate, lead sulfite, and lead sulfate.
Department of Chemistry, Widener University, Chester, PA 19013, USA.
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Van Bramer
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Glatfelter
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Bai
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Dybowski
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Neue
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Perry