Geometric preferences in iron(II) and zinc(II) model complexes of peptide deformylase.
A combination of experimental and theoretical studies on (N,S(thiolate))M(II)-formate complexes (M = Fe, Zn) suggests a rationale for the metal ion dependence of peptide deformylase.
Karambelkar
Vivek V
VV
Department of Chemistry, Johns Hopkins University, Baltimore, Maryland 21218, USA.
Xiao
Chuanyun
C
Zhang
Yingkai
Y
Sarjeant
Amy A Narducci
AA
Goldberg
David P
DP
D000581:Amidohydrolases / Q000737:chemistry*; D005296:Ferrous Compounds / Q000737:chemistry*; D008958:Models, Molecular; D014961:X-Ray Diffraction; D015032:Zinc / Q000737:chemistry*
D005296:Ferrous Compounds; D000581:Amidohydrolases; C084507:peptide deformylase; D015032:Zinc