Influence of ion properties on the equilibrium and transport properties of electrolyte solutions.
Strong electrolytes are described in the framework of the primitive model in which the solvent is regarded as a dielectric continuum, using the mean spherical approximation. The analytical solution of the equilibrium and transport properties is dependent on the ions' diameters and valencies. For hydrated or nonspherical ions, an effective diameter must be fitted. A sensitivity study of the osmotic coefficient and the transport coefficients is performed on theoretical 1-1, 2-1, and 3-1 electrolytes, up to a total ion concentration of 2 mol/L.
Van Damme
Steven
S
Computational Electrochemistry Group (CEG), Department of Electrotechnics and power electronics (ETEC), Vrije Universiteit Brussel (VUB), Pleinlaan 2, 1050 Brussel, Belgium. stvdamme@vub.ac.be
Dufrêche
Jean-François
JF
Deconinck
Johan
J