Synthesis of alpha-onoceradiene-like terpene dimers by intermolecular metathesis processes.
[reaction: see text] New alpha-onoceradiene analogues having a terpene homodimer skeleton are accessible from Weinreb's amide 2 derived from commercial (R)-(+)-sclareolide using an intermolecular metathesis reaction as the key step to build the linker joining both terpene moieties.
de la Torre
María C
MC
Instituto de Química Orgánica, Consejo Superior de Investigaciones Científicas (CSIC), Juan de la Cierva 3, 28006 Madrid, Spain. iqot310@iqog.csic.es
Deometrio
Antonio M
AM
Alvaro
Elsa
E
García
Isabel
I
Sierra
Miguel A
MA
D002384:Catalysis; D004224:Diterpenes / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism; D013729:Terpenes / Q000138:chemical synthesis* / Q000737:chemistry
D004224:Diterpenes; D013729:Terpenes; C109395:sclareolide