Rates of C-S bond cleavage in tert-alkyl phenyl sulfide radical cations.
[reaction: see text] Radical cations of tert-alkyl phenyl sulfides 1-4 have been generated photochemically in MeCN in the presence of the N-methoxyphenanthridinium cation (MeOP(+)), and the rates of C-S bond cleavage have been determined by laser flash photolysis.
Dipartimento di Chimica, Università La Sapienza and IMC-CNR, Sezione Meccanismi di Reazione, P.le A. Moro, 5 I-00185 Rome, Italy. enrico.baciocchi@uniroma1.it
Enrico
E
Baciocchi
Tiziana
T
Del Giacco
Maria Francesca
MF
Gerini
Osvaldo
O
Lanzalunga