Comparative solubilisation of potassium carbonate, sodium bicarbonate and sodium carbonate in hot dimethylformamide: application of cylindrical particle surface-controlled dissolution theory.
A surface-controlled dissolution of cylindrical solid particles model is applied to potassium carbonate, sodium bicarbonate and sodium carbonate in dimethylformamide at elevated temperatures. Previously published data for the dissolution of potassium carbonate is interpreted assuming a cylindrical rather than a spherical shape of the particles, the former representing a closer approximation to the true shape of the particles as revealed by scanning electron microscopy. The dissolution kinetics of sodium carbonate and sodium bicarbonate in dimethylformamide at 100 degrees C were investigated via monitoring of the deprotonation of 2-cyanophenol with dissolved solid to form the 2-cyanophenolate anion that was detected with UV-visible spectroscopy. From fitting of experimental results to theory, the dissolution rate constant, k, for the dissolutions of potassium carbonate, sodium bicarbonate and sodium carbonate in dimethylformamide at 100 degrees C were found to have the values of (1.0 +/- 0.1) x 10(-7) mol cm(-2) s(-1), (5.5 +/- 0.3) x 10(-9) mol cm(-2) s(-1) and (9.7 +/- 0.8) x 10(-9) mol cm(-2) s(-1), respectively.
Physical and Theoretical Chemistry Laboratory, University of Oxford, UK.
Claire L
CL
Forryan
Richard G
RG
Compton
Oleksiy V
OV
Klymenko
Colin M
CM
Brennan
Catherine L
CL
Taylor
Martin
M
Lennon
D000327:Adsorption; D002254:Carbonates / Q000737:chemistry*; D002626:Chemistry, Pharmaceutical; D004058:Diffusion; D004126:Dimethylformamide / Q000737:chemistry*; D007700:Kinetics; D008855:Microscopy, Electron, Scanning; D010316:Particle Size; D010636:Phenols / Q000737:chemistry; D011188:Potassium / Q000737:chemistry*; D017693:Sodium Bicarbonate / Q000737:chemistry*; D012995:Solubility; D013056:Spectrophotometry, Ultraviolet; D013696:Temperature
D002254:Carbonates; D010636:Phenols; C005686:sodium carbonate; D004126:Dimethylformamide; D017693:Sodium Bicarbonate; C037593:potassium carbonate; D011188:Potassium