PegPhos: a monodentate phosphoramidite ligand for enantioselective rhodium-catalysed hydrogenation in water.
A BICOL derived monodentate phosphoramidite ligand gives ee's up to 89% in the enantioselective Rh-catalysed hydrogenation of N-acyl dehydroalanine using water as the solvent.
Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands.
Rob
R
Hoen
Stephane
S
Leleu
Peter N M
PN
Botman
Vanessa A M
VA
Appelman
Ben L
BL
Feringa
Henk
H
Hiemstra
Adriaan J
AJ
Minnaard
Jan H
JH
van Maarseveen