Unconventional spinodal surface fluctuations on polymer films.
We study the temporal growth pattern of surface fluctuations on a series of spinodally unstable polymer films where the instability can be adjusted with the film thickness, h0. For the most unstable film studied (whose /(h0 - h(sp))/h(sp)/ = 0.988; h(sp) is the thickness where the second derivative of the interfacial potential of the film equals zero), the growth rate function of the surface modes as a function of the wavevector fits well to the mean-field theory. When the film thickness is increased such that /(h0 - h(sp))/h(sp)/ < or = 0.977, the mean-field theory demonstrates marked disagreement with experiment, notwithstanding the provision of the known corrections from nonlinear effects and thermal noise. We show that the deviations arise from large-amplitude fluctuations induced by homogeneous nucleation, which are not considered in the conventional treatments.
Department of Physics and Institute of Nanoscience and Technology, Hong Kong University of Science and Technology, Clear Water Bay, Hong Kong.
Y J
YJ
Wang
Ophelia K C
OK
Tsui