Photooxidation of Co-thiolato complexes in protic and aprotic solvents.
Protic solvents decrease the susceptibility of the thiolate ligand in Co(III) thiolato complexes toward attack by singlet oxygen, but greatly increase the conversion of the peroxidic intermediate to the sulfenato product.
Hernandez
Billy
B
Department of Chemistry & Biochemistry, California State University, Los Angeles, CA 90032, USA.
Wang
Yanju
Y
Zhang
Dong
D
Selke
Matthias
M
D003035:Cobalt / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry; D010777:Photochemistry; D011522:Protons; D012997:Solvents / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*
D011522:Protons; D012997:Solvents; D013438:Sulfhydryl Compounds; D003035:Cobalt; D010100:Oxygen