"Beta-cis-SAr effect" on decarbonylation from alpha,beta-unsaturated acyl and aroyl complexes.
Lone pair of heteroatom located at the beta-cis position in alpha,beta-unsaturated acyl and aroyl group 10 metal complexes dramatically facilitated the stoichiometric and catalytic decarbonylation reactions.
Department of Applied Chemistry & Frontier Research Center, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka Suita, Osaka, 565-0871, Japan.
Tomohiro
T
Kato
Hitoshi
H
Kuniyasu
Takamichi
T
Kajiura
Yasunori
Y
Minami
Atsushi
A
Ohtaka
Masanori
M
Kinomoto
Jun
J
Terao
Hideo
H
Kurosawa
Nobuaki
N
Kambe