Synthesis of alpha-onoceradiene-like terpene dimers by intermolecular metathesis processes.
[reaction: see text] New alpha-onoceradiene analogues having a terpene homodimer skeleton are accessible from Weinreb's amide 2 derived from commercial (R)-(+)-sclareolide using an intermolecular metathesis reaction as the key step to build the linker joining both terpene moieties.
Instituto de Química Orgánica, Consejo Superior de Investigaciones Científicas (CSIC), Juan de la Cierva 3, 28006 Madrid, Spain. iqot310@iqog.csic.es
María C
MC
de la Torre
Antonio M
AM
Deometrio
Elsa
E
Alvaro
Isabel
I
García
Miguel A
MA
Sierra
D002384:Catalysis; D004224:Diterpenes / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism; D013729:Terpenes / Q000138:chemical synthesis* / Q000737:chemistry
D004224:Diterpenes; D013729:Terpenes; C109395:sclareolide