A bis(phosphinimino)methanide lanthanum amide as catalyst for the hydroamination/cyclisation, hydrosilylation and sequential hydroamination/hydrosilylation catalysis.
[La[N(SiHMe2)2]2[CH(PPh2NSiMe3)2]], which was obtained via an amine elimination starting from [CH2(PPh2NSiMe3)2] and [La[N(SiHMe2)2]3(THF)2], was used as catalyst for the hydroamination/cyclisation, the hydrosilylation and the sequential hydroamination/hydrosilylation reaction.
Institut für Chemie und Biochemie, Freie Universität Berlin, Fabeckstrasse 34-36, 14195, Berlin, Germany.
Marcus
M
Rastätter
Agustino
A
Zulys
Peter W
PW
Roesky