Ruthenium(II)-catalysed cycloisomerisation of 1,6-dienes by focused microwave dielectric heating: improved rates and selectivities leading to exo-methylenecyclopentanes.
We herein report the effect of microwave dielectric heating in the Ru-catalysed cycloisomerisation of 1,6-dienes. Substantially improved reaction rates are attained for a series of 1,6-diene substrates, with equivalent or higher isomeric purity than conventional thermal heating.
Fairlamb
Ian J S
IJ
Department of Chemistry, University of York, Heslington, York YO10 5DD, UK. ijsf1@york.ac.uk
McGlacken
Gerard P
GP
Weissberger
Felix
F
D002384:Catalysis; D003500:Cyclization; D003517:Cyclopentanes / Q000737:chemistry*; D006361:Heating; D007700:Kinetics; D008745:Methylation; D008872:Microwaves; D015394:Molecular Structure; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
D003517:Cyclopentanes; D012428:Ruthenium