A new type of luminescent alkynyl Au4Cu2 cluster.
Changes in the optical properties of an alkynyldigold(I) complex upon reaction with Cu(I) are associated with a complicated structural change to form an unusual Au4Cu2 cluster with metallophilic interactions as well as pi-alkyne coordination.
School of Chemistry, Queen's University Belfast, UK.
Héctor
H
de la Riva
Mark
M
Nieuwhuyzen
Claudio
C
Mendicute Fierro
Paul R
PR
Raithby
Louise
L
Male
M Cristina
MC
Lagunas