EPR study on the ligand-exchange reaction between bis(diethyldiselenocarbamato)copper(II) and bis(octyldithiocarbonato)copper(II).
EPR study on the ligand-exchange reaction between bis(diethyldiselenocarbamato)copper(II), Cu(Et2dsc)2, and bis(octyldithiocarbonato)copper(II), Cu(octxant)2, in CH2Cl2, CHCl3, CCl4, C6H6 and C6H5.CH3 is reported for the first time. Mixing of equimolar amounts of the parents (chromophores CuSe4 and CuS4, respectively) in C6H6, C6H5.CH3 and CH2Cl2 makes EPR signals of both parents superimposed by the spectrum of a mixed-chelate Cu(xant)(dsc) complex (chromophore CuS2Se2). A new additional EPR spectrum appears in CHCl3 or CCl4 due to a five-coordinate mixed-ligand complex with the chromophore Cu(S3Se)S as follows by comparing the g-values of parents and mixed-ligand complexes. The appearance of this complex could be explained having in mind donor-acceptor properties of complexes, solvents and the resultant reaction of Cu(octxant)2 with the ester of diselenocarbamic acid yielded in Cu(Et2dsc)2 destruction by CCl4 or CHCl3.
Laboratory EPR, Institute of Catalysis, Bulgarian Academy of Sciences, 1113 Sofia, Bulgaria. ndyepr@ic.bas.bg
Nicola D
ND
Yordanov
Anna
A
Dimitrova
D002219:Carbamates / Q000032:analysis / Q000737:chemistry*; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D003300:Copper / Q000737:chemistry*; D004578:Electron Spin Resonance Spectroscopy / Q000379:methods*; D004583:Electrons; D007700:Kinetics; D008024:Ligands; D009942:Organometallic Compounds / Q000032:analysis / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry; D013696:Temperature
D002219:Carbamates; D008024:Ligands; D009942:Organometallic Compounds; D012997:Solvents; C409665:bis(diethyl-diselenocarbamato)copper(II); D003300:Copper