Suzuki coupling reaction of 1,6,7,12-tetrabromoperylene bisimide.
1,6,7,12-Tetrabromoperylene-3,4,9,10-tetracarboxylic acid bisanhydride and the corresponding tetrabrominated perylene bisimide were first synthesized with high yields. The Suzuki coupling reaction of novel tetrabromoperylene bisimide with phenylbonoric acid was studied. The four bromines in the bay position of the perylene core were substituted successfully to yield 1,6,7,12-teraphenylperylene bisimide. The photochemical properties of the novel perylene bisimides were studied and presented.
Qiu
Wenfeng
W
Organic Solids Laboratory, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, P. R. China.
Chen
Shiyan
S
Sun
Xiaobo
X
Liu
Yunqi
Y
Zhu
Daoben
D