Phase separation, interface properties, and charge density waves in a simplified model for a macroion suspension.
A simplified density functional theory for a macroion suspension is examined, where the correlation free energy corresponds to the macroion self-energy, treated within a linearized or Debye-Hückel approximation. The model possesses a miscibility gap (liquid-liquid phase separation) at low ionic strength. Within the gap, density profiles, electrical structure, and surface tension are calculated for the interface between coexisting phases, using a variational approximation. Additionally, structure factors are calculated for the homogeneous system. As one approaches the critical points, the structure factors can diverge at a nonzero wave vector, signaling the onset of charge density wave phases. Although the quantitative results should be treated with care, the results may be indicative of the rich phenomenology that can arise in asymmetric charged systems.
Warren
Patrick B
PB
Unilever R&D Port Sunlight, Bebington, Wirral, CH63 3JW, United Kingdom.