Supported metalloporphyrin catalysts for alkene epoxidation.
This review is devoted to the recent advances in the preparation of immobilised metalloporphyrins and their use as heterogeneous catalysts for alkene epoxidation. The wide range of supports, nature of attachments, and metalloporphyrins that have been reported is detailed and a comparison is made between the activities of the resulting catalysts in the epoxidation of different alkenes. The important issue of recyclability of the metalloporphyrins is also covered.
Brulé
Emilie
E
Université Pierre et Marie Curie, Paris VI, Laboratoire de synthèse organique et organométallique, Tour 44-45, 1erétage, 4 Place Jussieu, 75252, Paris Cedex 05, France.
de Miguel
Yolanda R
YR
D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D004852:Epoxy Compounds / Q000737:chemistry*; D008665:Metalloporphyrins / Q000737:chemistry*; D055672:Static Electricity; D013237:Stereoisomerism
D000475:Alkenes; D004852:Epoxy Compounds; D008665:Metalloporphyrins