Inorganic salt hydrates as cryoporometric probe materials to obtain pore size distribution.
The depression of the melting temperature of Zn(NO3)2.6H2O was used to obtain the pore size distributions in controlled pore glasses. Measured by 1H NMR, the average value of the temperature depression DeltaT and the known average pore size yield K=DeltaT.d approximately 116 K.nm as the material-dependent factor for Zn(NO3)2.6H2O in the Gibbs-Thompson equation. The melting temperature is close to room temperature. Hence, this salt hydrate and some related other ones are better materials than water (K approximately 50 K.nm) for cryoporometric studies of systems with hydrophilic pores. The data also provide 46 mN/m for the solid-liquid surface tension of this salt hydrate.
Vargas-Florencia
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Division of Physical Chemistry and Industrial NMR Center, Department of Chemistry, Royal Institute of Technology, SE-10044 Stockholm, Sweden.
Petrov
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Furó
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