{2,2'-[1,1'-(4-Azaheptane-1,7-diyldinitrilo)diethylidyne]diphenolato}copper(II).
The quinquedentate ligand 2,2'-[1,1'-(4-azaheptane-1,7-diyldinitrilo)diethylidyne]diphenol in the title compound, [Cu(C22H27N3O2)], furnishes an N3O2 donor set, which results in a distorted square-pyramidal coordination; the two O and two imine N atoms lie in the basal plane, while the secondary amine N atom of the ligand occupies the axial position. The axial Cu-N bond is 0.33 A longer than the average of the equatorial bonds, and the O atoms are trans. The symmetry of the molecule is lowered by the twist-boat and chair conformations adopted by the two CuNN chelate rings. The complex contains two intramolecular C-H...O interactions, and two molecules of the complex are linked into a dimer by means of moderate N-H...O hydrogen bonds. Spectroscopic evidence supports the presence of hydrogen bonds.
Morshedi
Mahbod
M
Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Iran.
Meghdadi
Soraia
S
Schenk
Kurt J
KJ