title: A highly selective cascade approach to diverse aromatic ring systems from simple aromatic aldehydes and propiolates.
abstract: [reaction: see text] A new triethylamine-catalyzed cascade reaction of aromatic aldehydes with propiolates has been developed. This serial multi-bond-forming process furnishes diverse polycyclic aromatic hydrocarbons, including naphthalenes, phenanthrenes, benzofurans, and 2,3,9,9a-tetrahydronaphtha[2,3-b]furans. The chemical outcome of the process depends on the reaction temperature and can be tailored selectively by an appropriate choice of experimental conditions.
authors.affiliation: Department of Chemistry, Zhejiang University, Hangzhou 310027, P. R. China. orgwyg@zju.edu.cn
authors.forename: Yan-Guang
authors.initials: YG
authors.lastname: Wang
authors.forename: Sun-Liang
authors.initials: SL
authors.lastname: Cui
authors.forename: Xu-Feng
authors.initials: XF
authors.lastname: Lin