title: Thiacalix[3]pyridine produces a stable mononuclear rhodium(II) complex with mutual Jahn-Teller effect.
abstract: Thiacalix[3]pyridine (Py3S3) consists of pyridines and bridging sulfur atoms producing a stable octahedral mononuclear Rh(II) complex [Rh(II)(Py3S3)2]2+ showing mutual Jahn-Teller effect, a metal based reversible redox couple of Rh(III/II) at 0.02 V vs. SCE and a g(perpendicular) > g(||) relationship in EPR measurements.
authors.affiliation: Department of Molecular Materials Science, Graduate School of Science, Osaka City University, Sumuyoshi-ku, Japan.
authors.forename: Rika Tanaka
authors.initials: RT
authors.lastname: Hamazawa
authors.forename: Takanori
authors.initials: T
authors.lastname: Nishioka
authors.forename: Isamu
authors.initials: I
authors.lastname: Kinoshita
authors.forename: Takeji
authors.initials: T
authors.lastname: Takui
authors.forename: Ryoko
authors.initials: R
authors.lastname: Santo
authors.forename: Akio
authors.initials: A
authors.lastname: Ichimura