DNAPL source depletion: linking architecture and flux response.
The relationship between dense non-aqueous phase liquid (DNAPL) mass reduction and contaminant mass flux was investigated experimentally in four model source zones. The flow cell design for the experiments featured a segmented extraction well that allowed for analysis of spatially resolved flux information. This flux information was coupled with image analysis of the NAPL spatial distribution to investigate the relationship between flux and the up-gradient NAPL architecture. Results indicate that in the systems studied, the relationship between DNAPL mass reduction and contaminant mass flux was primarily controlled by the NAPL architecture. A specific definition of NAPL architecture was employed where the source zone is resolved into a collection of streamtubes with spatial variability in NAPL saturation along each streamtube integrated and transformed into an effective NAPL content for each streamtube. The distribution of NAPL contents among the streamtubes (NAPL architecture) controlled dissolution dynamics. Two simplified models, a streamtube model and an effective Damkohler number model, were investigated for their ability to simulate dissolution dynamics.
Fure
Adrian D
AD
Department of Environmental Engineering Sciences Department, University of Florida, Gainesville, FL 32611, USA.
Jawitz
James W
JW
Annable
Michael D
MD
D007700:Kinetics; D008962:Models, Theoretical; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014876:Water Pollution / Q000517:prevention & control
D014874:Water Pollutants, Chemical