NMR evidence for the participation of triflated ionic liquids in glycosylation reaction mechanisms.
A systematic low-temperature NMR study of a glycosylation reaction was performed in the presence of different ionic liquids and acidic catalysts. The influence of the triflate anion derived from [emim][OTf] on the stereochemistry of the glycosylation products was evaluated.
Rencurosi
Anna
A
CNR, Istituto di Scienze e Tecnologie Molecolari, via Golgi, 19, 20133 Milan, Italy.
Lay
Luigi
L
Russo
Giovanni
G
Caneva
Enrico
E
Poletti
Laura
L
D019840:2-Propanol / Q000737:chemistry*; D002384:Catalysis; D006031:Glycosylation; D007477:Ions; D009682:Magnetic Resonance Spectroscopy; D013696:Temperature
D007477:Ions; D019840:2-Propanol