Highly enantioselective hydrovinylation of alpha-alkyl vinylarenes. an approach to the construction of all-carbon quaternary stereocenters.
The highly enantioselective hydrovinylation of alpha-alkyl vinylarenes was realized by using nickel complexes of chiral spiro phosphoramidite ligands. The method provided a new approach to the construction of chiral all-carbon quaternary centers.
Shi
Wen-Jian
WJ
State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China.
Zhang
Qi
Q
Xie
Jian-Hua
JH
Zhu
Shou-Fei
SF
Hou
Guo-Hua
GH
Zhou
Qi-Lin
QL
D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis* / Q000737:chemistry; D009943:Organophosphorus Compounds / Q000737:chemistry; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D006841:Hydrocarbons, Aromatic; D009943:Organophosphorus Compounds; D014753:Vinyl Compounds; C434331:phosphoramidite