Variation in crystallization conditions allows the isolation of trimeric as well as dimeric and monomeric forms of [(alkyl isocyanide)4RhI]+.
Trimeric green [(i-PrNC)12Rh(I)3]Cl3.4.5H2O, monomeric [(C6H11NC)4Rh(I)](BPh4) and [(i-PrNC)4Rh(I)](BPh4) (both yellow), and red, dimeric [(C6H11NC)8Rh(I)2]Cl2.0.5C6H6.2H2O have been crystallized.
Tran
Ngon T
NT
Department of Chemistry, University of California, One Shields Avenue, Davis, CA, USA.
Stork
Jay R
JR
Pham
David
D
Olmstead
Marilyn M
MM
Fettinger
James C
JC
Balch
Alan L
AL