Thiacalix[3]pyridine produces a stable mononuclear rhodium(II) complex with mutual Jahn-Teller effect.
Thiacalix[3]pyridine (Py3S3) consists of pyridines and bridging sulfur atoms producing a stable octahedral mononuclear Rh(II) complex [Rh(II)(Py3S3)2]2+ showing mutual Jahn-Teller effect, a metal based reversible redox couple of Rh(III/II) at 0.02 V vs. SCE and a g(perpendicular) > g(||) relationship in EPR measurements.
Hamazawa
Rika Tanaka
RT
Department of Molecular Materials Science, Graduate School of Science, Osaka City University, Sumuyoshi-ku, Japan.
Nishioka
Takanori
T
Kinoshita
Isamu
I
Takui
Takeji
T
Santo
Ryoko
R
Ichimura
Akio
A