Ammonolysis of (3-chloropropyl)trimethoxysilane.
Technological parameters of the ammonolysis of (3-chloropropyl)trimethoxysilane to (3-aminopropyl)trimethoxysilane have been determined. Influence of temperature, reaction time and the molar ratio of ammonia to (3-chloropropyl)trimethoxysilane has been examined. Influence of the parameters has been described using the following factors describing the process: the degree of conversion of (3-chloropropyl)trimethoxysilane and the selectivity of transformation to (3-aminopropyl)trimethoxysilane in relation to consumed (3-chloropropyl)trimethoxysilane.
Bartkowiak
Marcin
M
Szczecin University of Technology, Institute of Chemical Organic Technology, Pulaskiego 10, Pl 70-322 Szczecin, Poland. mbartkowiak@ps.pl
Pełech
Robert
R
Milchert
Eugeniusz
E
D000641:Ammonia / Q000737:chemistry*; D002849:Chromatography, Gas; D013058:Mass Spectrometry; D011437:Propylamines / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D013696:Temperature
D011437:Propylamines; D012821:Silanes; C088294:3-aminopropyltrimethoxysilane; D000641:Ammonia