title: An ultra-clean firn core from the Devon Island Ice Cap, Nunavut, Canada, retrieved using a titanium drill specially designed for trace element studies.
abstract: An electromechanical drill with titanium barrels was used to recover a 63.7 m long firn core from Devon Island Ice Cap, Nunavut, Canada, representing 155 years of precipitation. The core was processed and analysed at the Geological Survey of Canada by following strict clean procedures for measurements of Pb and Cd at concentrations at or below the pg g(-1) level. This paper describes the effectiveness of the titanium drill with respect to contamination during ice core retrieval and evaluates sample-processing procedures in laboratories. The results demonstrate that: (1) ice cores retrieved with this titanium drill are of excellent quality with metal contamination one to four orders of magnitude less than those retrieved with conventional drills; (2) the core cleaning and sampling protocols used were effective, contamination-free, and adequate for analysis of the metals (Pb and Cd) at low pg g(-1) levels; and (3) results from 489 firn core samples analysed in this study are comparable with published data from other sites in the Arctic, Greenland and the Antarctic.
authors.affiliation: GSC Northern Canada, Geological Survey of Canada, Natural Resources Canada, 601 Booth Street, Ottawa, Canada K1A 0E8. jzheng@nrcan.gc.ca
authors.forename: J
authors.initials: J
authors.lastname: Zheng
authors.forename: D
authors.initials: D
authors.lastname: Fisher
authors.forename: E
authors.initials: E
authors.lastname: Blake
authors.forename: G
authors.initials: G
authors.lastname: Hall
authors.forename: J
authors.initials: J
authors.lastname: Vaive
authors.forename: M
authors.initials: M
authors.lastname: Krachler
authors.forename: C
authors.initials: C
authors.lastname: Zdanowicz
authors.forename: J
authors.initials: J
authors.lastname: Lam
authors.forename: G
authors.initials: G
authors.lastname: Lawson
authors.forename: W
authors.initials: W
authors.lastname: Shotyk
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D001110:Arctic Regions; D002104:Cadmium / Q000032:analysis; D004784:Environmental Monitoring / Q000295:instrumentation* / Q000379:methods; D046448:Ice Cover / Q000737:chemistry*; D007854:Lead / Q000032:analysis; D008670:Metals / Q000032:analysis*; D020957:Nunavut; D013997:Time Factors; D014025:Titanium
chemical_list: D000393:Air Pollutants; D008670:Metals; D002104:Cadmium; D007854:Lead; D014025:Titanium