Enantioselective modular synthesis of 2,4-disubstituted cyclopentenones by iridium-catalyzed allylic alkylation.
Schelwies
Mathias
M
Organisch-Chemisches Institut der Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
Dübon
Pierre
P
Helmchen
Günter
G
D000478:Alkylation; D000498:Allyl Compounds / Q000737:chemistry*; D002384:Catalysis; D003517:Cyclopentanes / Q000138:chemical synthesis / Q000737:chemistry*; D007495:Iridium / Q000737:chemistry*; D008314:Malonates / Q000737:chemistry; D015394:Molecular Structure; D011437:Propylamines / Q000737:chemistry; D013237:Stereoisomerism
D000498:Allyl Compounds; D003517:Cyclopentanes; D008314:Malonates; D011437:Propylamines; D007495:Iridium; C007442:diisopropylamine; C005230:methyl malonate; C013905:cyclopentenone