C-H-Activated aluminum hydroxide via molecular oxygen.
The reaction of LAl[eta2-(C2(SiMe3)2)] (1; L = HC[(CMe)(NDipp)]2, Dipp = 2,6-iPr2C6H3) with dioxygen leads to the elimination of bis(trimethylsilyl)acetylene and the formation of the corresponding aluminum monohydroxide via the oxidation of one of the CHMe2 groups on the Dipp ring.
Li
Xiaofei
X
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, People's Republic of China.
Song
Haibin
H
Duan
Lili
L
Cui
Chunming
C
Roesky
Herbert W
HW