H2, N2, CO, and CO2 sorption properties of a series of robust sodalite-type microporous coordination polymers.
H2, N2, CO, and CO2 are readily incorporated in the porous, 3D sodalitic frameworks of coordination polymers of the [ML2]n type, with M = Pd(II) or Cu(II) and HL = 2-hydroxypyrimidine or 4-hydroxypyrimidine. The metal ion and ligand functionalization modulate their sorption properties, making these materials suitable for gas storage and separation purposes.
Navarro
Jorge A R
JA
Departamento de Química Inorganica, Universidad de Granada, Av. Fuentenueva S/N, 18071 Granada, Spain. jarn@ugr.es
Barea
Elisa
E
Salas
Juan M
JM
Masciocchi
Norberto
N
Galli
Simona
S
Sironi
Angelo
A
Ania
Conchi O
CO
Parra
José B
JB