title: Highly enantioselective hydrovinylation of alpha-alkyl vinylarenes. an approach to the construction of all-carbon quaternary stereocenters.
abstract: The highly enantioselective hydrovinylation of alpha-alkyl vinylarenes was realized by using nickel complexes of chiral spiro phosphoramidite ligands. The method provided a new approach to the construction of chiral all-carbon quaternary centers.
authors.affiliation: State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China.
authors.forename: Wen-Jian
authors.initials: WJ
authors.lastname: Shi
authors.forename: Qi
authors.initials: Q
authors.lastname: Zhang
authors.forename: Jian-Hua
authors.initials: JH
authors.lastname: Xie
authors.forename: Shou-Fei
authors.initials: SF
authors.lastname: Zhu
authors.forename: Guo-Hua
authors.initials: GH
authors.lastname: Hou
authors.forename: Qi-Lin
authors.initials: QL
authors.lastname: Zhou
mesh_terms: D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis* / Q000737:chemistry; D009943:Organophosphorus Compounds / Q000737:chemistry; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D006841:Hydrocarbons, Aromatic; D009943:Organophosphorus Compounds; D014753:Vinyl Compounds; C434331:phosphoramidite