Bimodal association of a bis-1,2,3-dithiazolyl radical.
The N-ethyl pyrazine-bridged bis-1,2,3-dithiazolyl radical (R(1) = Et) associates at room temperature as a C-C bonded sigma-dimer which, on heating, converts to a laterally S-S sigma-bonded structure.
Leitch
Alicea A
AA
Department of Chemistry, University of Waterloo, Waterloo, Ontario N2L 3G1, Canada.
McKenzie
Courtney E
CE
Oakley
Richard T
RT
Reed
Robert W
RW
Richardson
John F
JF
Sawyer
Lenora D
LD