Oxone as an inexpensive, safe, and environmentally benign oxidant for C-H bond oxygenation.
[reaction: see text] This paper describes the application of peroxide-based oxidants in the Pd(OAc)(2)-catalyzed acetoxylation and etherification of arene and alkane C-H bonds. Oxone in acetic acid and/or methanol proved particularly effective, and these transformations were applied to a wide variety of substrates.
Desai
Lopa V
LV
University of Michigan, Department of Chemistry, 930 North University Avenue, Ann Arbor, Michigan 48109-1055, USA.
Malik
Hasnain A
HA
Sanford
Melanie S
MS
D020650:Combinatorial Chemistry Techniques; D007202:Indicators and Reagents; D015394:Molecular Structure; D016877:Oxidants / Q000737:chemistry* / Q000191:economics; D010545:Peroxides / Q000737:chemistry*; D013464:Sulfuric Acids / Q000737:chemistry* / Q000191:economics
D007202:Indicators and Reagents; D016877:Oxidants; D010545:Peroxides; D013464:Sulfuric Acids; C048813:potassium peroxymonosulfuric acid