title: Oxone as an inexpensive, safe, and environmentally benign oxidant for C-H bond oxygenation.
abstract: [reaction: see text] This paper describes the application of peroxide-based oxidants in the Pd(OAc)(2)-catalyzed acetoxylation and etherification of arene and alkane C-H bonds. Oxone in acetic acid and/or methanol proved particularly effective, and these transformations were applied to a wide variety of substrates.
authors.affiliation: University of Michigan, Department of Chemistry, 930 North University Avenue, Ann Arbor, Michigan 48109-1055, USA.
authors.forename: Lopa V
authors.initials: LV
authors.lastname: Desai
authors.forename: Hasnain A
authors.initials: HA
authors.lastname: Malik
authors.forename: Melanie S
authors.initials: MS
authors.lastname: Sanford
mesh_terms: D020650:Combinatorial Chemistry Techniques; D007202:Indicators and Reagents; D015394:Molecular Structure; D016877:Oxidants / Q000737:chemistry* / Q000191:economics; D010545:Peroxides / Q000737:chemistry*; D013464:Sulfuric Acids / Q000737:chemistry* / Q000191:economics
chemical_list: D007202:Indicators and Reagents; D016877:Oxidants; D010545:Peroxides; D013464:Sulfuric Acids; C048813:potassium peroxymonosulfuric acid