title: Removal of chromium and toxic ions present in mine drainage by Ectodermis of Opuntia.
abstract: This work presents conditions for hexavalent and trivalent chromium removal from aqueous solutions using natural, protonated and thermally treated Ectodermis of Opuntia. A removal of 77% of Cr(VI) and 99% of Cr(III) can be achieved. The sorbent material is characterized using scanning electron microscopy, energy dispersive X-ray spectroscopy, infrared spectroscopy, thermogravimetric analysis, before and after the contact with the chromium containing aqueous media. The results obtained from the characterization techniques indicate that the metal ion remains on the surface of the sorbent material. The percentage removal is found to depend on the initial chromium concentration and pH. The Cr(VI) and Cr(III) uptake process is maximum at pH 4, using 0.1g of sorbent per liter of aqueous solution. The natural Ectodermis of Opuntia showed a chromium adsorption capacity that was adequately described by the Langmuir adsorption isotherm. Finally, an actual mine drainage sample that contained Cd, Cr, Cu, Fe Zn, Ni and Pb was tested under optimal conditions for chromium removal and Ectodermis of Opuntia was found to be a suitable sorbent material. The use of this waste material for the treatment of metal-containing aqueous solutions as well as mine drainage is effective and economical.
authors.affiliation: Universidad Autónoma del Estado de México, Facultad de Química, Paseo Colón intersección Paseo Tollocan S/N, C.P. 50120, Toluca, Estado de México, Mexico.
authors.forename: Hector
authors.initials: H
authors.lastname: Barrera
authors.forename: Fernando
authors.initials: F
authors.lastname: Ureña-Núñez
authors.forename: Bryan
authors.initials: B
authors.lastname: Bilyeu
authors.forename: Carlos
authors.initials: C
authors.lastname: Barrera-Díaz
mesh_terms: D000327:Adsorption; D000465:Algorithms; D018533:Biomass; D002857:Chromium / Q000737:chemistry* / Q000302:isolation & purification; D004055:Differential Thermal Analysis; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste / Q000032:analysis*; D007700:Kinetics; D008855:Microscopy, Electron, Scanning; D008906:Mining; D024301:Plant Bark / Q000737:chemistry; D010944:Plants / Q000737:chemistry*; D012996:Solutions; D017550:Spectroscopy, Fourier Transform Infrared; D013816:Thermodynamics; D014865:Waste Disposal, Fluid; D014961:X-Ray Diffraction
chemical_list: D007220:Industrial Waste; D012996:Solutions; D002857:Chromium