Enhancing heterogeneous catalysis through cooperative hybrid organic-inorganic interfaces.
Active-site/surface cooperativity can enhance heterogeneous organic and organometallic catalysis. We review the powerful role of the solid surface in this context for generating local acidity and, as an inner-sphere ligand, for stabilizing immobilized supramolecular assemblies and unsaturated organometallic complexes that are often unstable in solution.
Notestein
Justin M
JM
Department of Chemical Engineering, University of California at Berkeley, Berkeley California 94720-1462, USA.
Katz
Alexander
A
D001665:Binding Sites; D002384:Catalysis; D004355:Drug Stability; D007287:Inorganic Chemicals / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D012996:Solutions; D013237:Stereoisomerism
D007287:Inorganic Chemicals; D009942:Organometallic Compounds; D012996:Solutions