title: cis-Dichloro[tris(2-benzimidazolylmethyl)amine]iron(III) chloride ethanol dihydrate: hydrogen bonding changing the arrangement of tapes built from pi-pi and C-H...pi interactions.
abstract: The title compound, [FeCl2(C24H21N7)]Cl.C2H5OH.2H2O, comprises an [FeCl2(C24H21N7)]+ cation, a Cl- anion, an ethanol molecule and two water molecules. The cations are linked by pi-pi and C-H...pi interactions into one-dimensional tapes, and hydrogen bonding between the cations, Cl- anions, and ethanol and water molecules links these tapes into a three-dimensional network.
authors.affiliation: Institute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Shanxi University, Taiyuan, Shanxi 030006, People's Republic of China.
authors.forename: Si-Si
authors.initials: SS
authors.lastname: Feng
authors.forename: Li-Ping
authors.initials: LP
authors.lastname: Lu
authors.forename: Shu-Xia
authors.initials: SX
authors.lastname: Wang
authors.forename: Li
authors.initials: L
authors.lastname: Li
authors.forename: Miao-Li
authors.initials: ML
authors.lastname: Zhu
mesh_terms: D001562:Benzimidazoles / Q000737:chemistry*; D003461:Crystallography; D005290:Ferric Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D013055:Spectrophotometry, Infrared
chemical_list: D001562:Benzimidazoles; D005290:Ferric Compounds; D009942:Organometallic Compounds; C515683:cis-dichloro(tris(2-benzimidazolylmethyl)amine)iron(III) chloride ethanol dihydrate