title: Ion-association aggregation of an anionic porphyrin at the liquid/liquid interface studied by second harmonic generation spectroscopy.
abstract: Interfacial ion-association adsorption and aggregation of a water-soluble porphyrin, tetrakis(4-sulfonatephenyl)porphyrin (TPPS) diacid, which was promoted by a cationic cetyltrimethylammonium ion (CTA(+)), was studied by second harmonic generation (SHG) spectroscopy. Comparing the interfacial SH spectrum with the transmission absorption spectrum of TPPS in the aqueous solution elucidated the aggregation behavior of TPPS at the heptane/water interface. The time-dependent SHG spectra for TPPS aggregation and the interfacial tension lowering in the presence of CTA(+) were discussed on the basis of an electrostatic adsorption model. Then, it was suggested that TPPS diacid was highly concentrated by the ion-association with CTA(+) at the interface, which was the intermediate state before the final aggregated state.
authors.affiliation: Department of Chemistry, Graduate school of Science, Osaka University, Toyonaka, Osaka 560-0043 Japan.
authors.forename: Kazuhiko
authors.initials: K
authors.lastname: Fujiwara
authors.forename: Sayaka
authors.initials: S
authors.lastname: Wada
authors.forename: Hideaki
authors.initials: H
authors.lastname: Monjushiro
authors.forename: Hitoshi
authors.initials: H
authors.lastname: Watarai