Adsorption of branched alkylbenzene sulfonate onto styrene and acrylic ester resins.
In this study, a series of acrylic ester resins were prepared and characterized. The adsorption behaviors of sodium 6-dodecyl benzenesulfonate (6-NaDBS) on styrene resin XAD-4 and acrylic ester resins have been studied. As compared to commercial acrylic ester resins Amberlite XAD-7 and Diaion HP2MG, YWB-38, one of the as-prepared resins, exhibits better adsorption properties toward 6-NaDBS. The experimental equilibrium data were fitted to the Langmuir and double-Langmuir models. The two models provide very good fit for all acrylic ester resins over the temperature range studied, whereas fitted results for styrene resin XAD-4 are less accurate. The investigation indicates that the adsorbate molecules are directly adsorbed on acrylic ester resins as a bi-layer, while the molecules are adsorbed on XAD-4 as monolayer formation followed by the establishment of bi-layer. Adsorption kinetics and elution processes were also investigated for further exploring the adsorption behavior and mechanism on styrene resin XAD-4 and YWB-38.
Yang
Wei Ben
WB
State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093, PR China.
Li
Aimin
A
Fan
Jun
J
Yang
Licheng
L
Zhang
Quanxing
Q
D000179:Acrylates / Q000737:chemistry*; D000327:Adsorption; D004952:Esters / Q000737:chemistry*; D007700:Kinetics; D020058:Styrene / Q000737:chemistry*; D013451:Sulfonic Acids / Q000737:chemistry*; D013501:Surface-Active Agents / Q000737:chemistry
D000179:Acrylates; D004952:Esters; D013451:Sulfonic Acids; D013501:Surface-Active Agents; D020058:Styrene