Syntheses and synthetic applications of stannylated allylic alcohols.
Allenyl carbinols undergo regioselective hydrostannation in the presence of MoBl3, a catalyst originally developed for the hydrostannation of alkynes, giving rise to allyl stannanes. These allyl stannanes can easily be converted into useful synthetic building blocks such as allyl iodides or vinyl epoxides.
Kazmaier
Uli
U
Institut für Organische Chemie, Universität des Saarlandes, D-66123 Saarbrücken, Germany. u.kazmaier@mx.uni-saarland.de
Lucas
Simon
S
Klein
Manuela
M
D002384:Catalysis; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry; D009947:Organotin Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D020005:Propanols / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D009947:Organotin Compounds; D020005:Propanols; C006463:allyl alcohol; D008982:Molybdenum