Phthalocyanine-modulated isomerization behaviour of an azo-based photoswitch.
A photoswitchable azobenzene-phthalocyanine-azobenzene triad has been synthesized and its electrochemical properties determined. Energy transfer among the subunits allows for modification of the E-Z ratio by selective excitation of the phthalocyanine moiety.
Rodríguez-Redondo
José L
JL
División de Química Orgánica, Instituto de Bioingeniería, Universidad Miguel Hernández, Avda. del Ferrocarril s/n, Elche 03202, Spain.
Sastre-Santos
Angela
A
Fernández-Lázaro
Fernando
F
Soares
Dilcelli
D
Azzellini
Gianluca C
GC
Elliott
Bevan
B
Echegoyen
Luis
L
D001391:Azo Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D004563:Electrochemistry; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D054833:Isoindoles; D015394:Molecular Structure; D010777:Photochemistry; D013056:Spectrophotometry, Ultraviolet; D013237:Stereoisomerism
D001391:Azo Compounds; D007211:Indoles; D054833:Isoindoles; C013647:phthalocyanine