An efficient stereoselective dihydroxylation of glycals using a bimetallic system, RuCl3/CeCl3/NaIO4.
A catalytic dihydroxylation reaction on glycals has been developed using a bimetallic oxidizing system to furnish sugar 1,2-diols in a highly stereoselective manner.
Medicinal and Process Chemistry Division, Central Drug Research Institute, Chattar Manzil Palace, Lucknow-226 001, U.P., India.
Pallavi
P
Tiwari
Anup Kumar
AK
Misra
D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D002586:Cesium / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D006027:Glycosides / Q000138:chemical synthesis* / Q000737:chemistry; D006900:Hydroxylation; D007452:Iodates / Q000737:chemistry*; D008969:Molecular Sequence Data; D010084:Oxidation-Reduction; D017975:Ruthenium Compounds / Q000737:chemistry*; D012964:Sodium / Q000737:chemistry*; D013237:Stereoisomerism
D002712:Chlorides; D006027:Glycosides; D007452:Iodates; D017975:Ruthenium Compounds; D002586:Cesium; D012964:Sodium; C028019:cesium chloride; C038365:ruthenium chloride