Bromoiodinanes with an I(III)-Br bond: preparation, X-ray crystallography and reactivity as electrophilic brominating agents.
Bromoiodinanes--conveniently and directly prepared from iodobenzenecarbinols and N-bromosuccinimide, and characterised for the first time crystallographically--act as electrophilic bromine donors.
Braddock
D Christopher
DC
Department of Chemistry, Imperial College London, London, UKSW7 2AZ. c.braddock@imperial.ac.uk
Cansell
Gemma
G
Hermitage
Stephen A
SA
White
Andrew J P
AJ
D001965:Bromides / Q000737:chemistry*; D001966:Bromine / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004583:Electrons; D007455:Iodine / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure
D001965:Bromides; D007455:Iodine; D001966:Bromine