Intramolecular arene hydroxylation versus intermolecular olefin epoxidation by (mu-eta2:eta2-peroxo)dicopper(II) complex supported by dinucleating ligand.
A discrete (mu-eta2:eta2-peroxo)Cu(II)2 complex, [Cu2(O2)(H-L)]2+, is capable of performing not only intramolecular hydroxylation of a m-xylyl linker of a dinucleating ligand but also intermolecular epoxidation of styrene via electrophilic reaction to the C=C bond and hydroxylation of THF by H-atom abstraction.
Matsumoto
Takahiro
T
Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan.
Furutachi
Hideki
H
Kobino
Masashi
M
Tomii
Masato
M
Nagatomo
Shigenori
S
Tosha
Takehiko
T
Osako
Takao
T
Fujinami
Shuhei
S
Itoh
Shinobu
S
Kitagawa
Teizo
T
Suzuki
Masatatsu
M
D001555:Benzene Derivatives / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D004852:Epoxy Compounds / Q000737:chemistry*; D006900:Hydroxylation; D007700:Kinetics; D008024:Ligands; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry; D011725:Pyridines / Q000737:chemistry
D001555:Benzene Derivatives; D004852:Epoxy Compounds; D008024:Ligands; D009942:Organometallic Compounds; D011725:Pyridines; D003300:Copper