[Spectra of rare earth complexes RE(Et2 dtc),3 (phen)].
The ternary solid complexes RE(Et2dtc)3 (phen) (RE=La, Pr, Nd, Sm-Er) were synthesized with sodium diethyldithiocarbamate (NaEt2 dtc x 3H2O), 1,10-phenanthroline (o-phen x H2O) and hydrated lanthanide chlorides in absolute ethanol by improved reported method. IR results revealed that RE3+ coordinated with sulfur atoms of NaEt2 dtc and nitrogen atoms of o-phen. As for UV spectrum of the complexes, energy transfer between o-phen and RE3+ was the primary process, and the main absorption peaks showed a slight red shift compared to that of o-phen; FS spectrum, as a comparison, showed that the complexes Sm (Et2 dtc)3 (phen) and Eu(Et2dtc)3 (phen) have a higher efficiency of intermolecular energy transfer and a stronger fluorescence character.
Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi'an 710069, China.
Li
L
Zhu
San-Ping
SP
Chen
Xu-Wu
XW
Yang
Bao-Juan
BJ
Jiao
Sheng-Li
SL
Gao