Thiocarbonyl compounds as regulating reagent in the radical addition of tertiary amines with alkenes using photoelectron transfer conditions.
The efficiency of the photoinduced radical addition of tertiary amines to olefinic double bonds is significantly enhanced and the stereoselectivity is influenced when thiocarbonyl compounds are added to the reaction mixture.
Laboratoire des Réactions Sélectives et Applications, UMR CNRS et Université de Reims Champagne-Ardenne, UFR Sciences, B.P. 1039, F-51687 Reims, cedex 02, France.
Dominique
D
Harakat
Jens
J
Pesch
Sinisa
S
Marinković
Norbert
N
Hoffmann