The assignment of absolute configuration of cyanohydrins by NMR.
Derivatization of aldehyde cyanohydrins as (R)- and (S)-MPA esters and comparison of the corresponding 1H- and 13C-NMR spectra allows the assignment of their absolute configuration.
Louzao
Iria
I
Departamento de Química Orgánica, Facultad de Química y Unidad de RMN de Biomoléculas Asociada al CSIC, Universidad de Santiago de Compostela, E-15782, Santiago de Compostela, Spain.
Seco
José Manuel
JM
Quiñoá
Emilio
E
Riguera
Ricardo
R