Complete assignments of the 1H and 13C NMR spectra of 9,10-didehydro retinoic acids.
A new class of retinoic acids was synthesized containing a 9,10-rigid bond. 1H and 13C NMR spectra were assigned for eight new compounds (all-E, 13Z) containing a carboxylic acid or tertiobutylester polar end group. Assignments were based on the combination of one- and two-dimensional experiments (APT, COSY, HMBC).
Laboratoire de Synthèse et Physicochimie Organique et Thérapeutique, Faculté des Sciences de Tours, Parc de Grandmont, EA 3857, 37200 Tours, France.
J
J
Thibonnet
A
A
Duchêne
J-L
JL
Parrain
M
M
Abarbri
D002247:Carbon Isotopes / Q000032:analysis; D003903:Deuterium / Q000032:analysis; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D012176:Retinoids / Q000138:chemical synthesis / Q000737:chemistry*
D002247:Carbon Isotopes; D012176:Retinoids; D003903:Deuterium