The flavonoid glycosides and procyanidin composition of Deglet Noor dates (Phoenix dactylifera).
The fruits of the date palm (Phoenix dactylifera) are consumed throughout the world and are an important part of the diet in the Middle East. Dates at the rutab and tamar maturity and ripening stages contain a wide array of phenolic antioxidants, but little is known about the composition of phenolic compounds in dates at the khalal stage of ripening. In the current study, the flavonoid glycoside and procyanidin compositions of dates of the cultivar Deglet Noor harvested at the khalal stage of maturity were characterized using liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI/MS/MS). Procyanidin oligomers through decamers were identified in extracts of these dates. Higher molecular weight polymers, undecamers through heptadecamers, were also apparent from mass spectra. Thirteen flavonoid glycosides of luteolin, quercetin, and apigenin, 19 when considering isomeric forms, were also identified. Mass spectra indicate that both methylated and sulfated forms of luteolin and quercetin are present as mono-, di-, and triglycosylated conjugates whereas apigenin is present as only the diglycoside. LC-ESI/MS/MS spectra indicate that quercetin and luteolin formed primarily O-glycosidic linkages whereas apigenin is present as the C-glycoside.
Hong
Yun Jeong
YJ
Department of Food Science and Technology, University of California Davis, One Shields Avenue, Davis, California 95616, USA.
Tomas-Barberan
F A
FA
Kader
Adel A
AA
Mitchell
Alyson E
AE
D028023:Arecaceae / Q000737:chemistry*; D044946:Biflavonoids / Q000032:analysis*; D002392:Catechin / Q000032:analysis*; D002851:Chromatography, High Pressure Liquid; D005419:Flavonoids / Q000032:analysis*; D005638:Fruit / Q000737:chemistry*; D006027:Glycosides / Q000032:analysis*; D044945:Proanthocyanidins / Q000032:analysis*; D011794:Quercetin / Q000032:analysis; D021241:Spectrometry, Mass, Electrospray Ionization
D044946:Biflavonoids; D005419:Flavonoids; D006027:Glycosides; D044945:Proanthocyanidins; C017674:procyanidin; D002392:Catechin; D011794:Quercetin