Unsymmetrical surface modification of a heteropolyoxotungstate via in-situ generation of monomeric and dimeric copper(II) species.
Unsymmetrical functionalization of a discrete alpha-{SiW12O40} Keggin with two heterometallic building blocks, a Cu(II) dimer and a Cu(II) monomer, results in the formation of [{Cu2(O2CMe)2(5,5'-dimethyl-2,2'-bipy)2}{Cu(5,5'-dimethyl-2,2'-bipy)2}SiW12O40] that displays interesting physical properties.
Ritchie
Chris
C
University of Glasgow, Department of Chemistry, Joseph Black Building, University Avenue, Glasgow, G12 8QQ, UK.
Burkholder
Eric
E
Kögerler
Paul
P
Cronin
Leroy
L
D003300:Copper / Q000737:chemistry*; D008280:Magnetics; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D033362:Powder Diffraction; D012825:Silicon / Q000737:chemistry; D013499:Surface Properties; D013696:Temperature; D017973:Tungsten Compounds / Q000737:chemistry*
D009942:Organometallic Compounds; D017973:Tungsten Compounds; D003300:Copper; C045951:tungstate; D012825:Silicon