STM/STS observation of polyoxoanions on HOPG surfaces: the wheel-shaped [Cu20Cl(OH)24(H2O)12(P8W48O184)]25- and the ball-shaped [{Sn(CH3)2(H2O)}24{Sn(CH3)2}12(A-PW9O34)12]36-.
A combination of scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS) techniques have been performed on the wheel-shaped [Cu20Cl(OH)24(H2O)12(P8W48O184)]25- and the ball-shaped [{Sn(CH3)2(H2O)}24{Sn(CH3)2}12(A-PW9O34)12]36- deposited on highly oriented pyrolytic graphite surfaces. Small, regular molecule clusters, as well as separated single molecules, were observed. The size of the molecules is in agreement with the data determined by X-ray crystallography. In STS measurements, we found a rather large contrast at the expected location of the Cu metal centers in our molecules, i.e., the location of the individual Cu ions in their organic matrix is directly addressable by STS.
Alam
Mohammad S
MS
Physikalisches Institut III, Universität Erlangen-Nürnberg, Erwin-Rommel-Strasse 1, 91058 Erlangen, Paul Verlaine University - LPMD/IPC, 1 Bd. Arago, F-57078 Metz, France.
Dremov
Viacheslav
V
Müller
Paul
P
Postnikov
Andrei V
AV
Mal
Sib Sankar
SS
Hussain
Firasat
F
Kortz
Ulrich
U