Living polymerization of alpha-olefins with an alpha-diimine Ni(II) catalyst: formation of well-defined ethylene-propylene copolymers through controlled chain-walking.
A C2-symmetric Ni(II) catalyst was found to polymerize alpha-olefins with high levels of omega,2-regiochemistry. The resulting products are ethylene-propylene-type copolymers with methylene sequences of precise length between methyl branches. Modification of reaction conditions can introduce omega,1-enchainments into the polymers which increases the average length of methylene sequences between methyl branches.
Rose
Jeffrey M
JM
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.
Cherian
Anna E
AE
Coates
Geoffrey W
GW