Metallabenzenes and metallabenzenoids.
Metallabenzenes are analogues of benzene in which one of the benzene CH groups has been formally replaced by a transition metal and its ancillary ligands. This article summarises some of the important recent highlights of metallabenzene chemistry including the synthesis of the first platinabenzene, the synthesis of the first metallanaphthalene (an iridanaphthalene) and the development of new synthetic routes to metallabenzenes. The results of a number of theoretical studies that provide important insights into the nature and reactivity of metallabenzenes are discussed and in the concluding section some of the immediate goals and challenges in this field are identified.
Department of Chemistry, University of Auckland, Private Bag 92019, Auckland, New Zealand. lj.wright@auckland.ac.nz
L James
LJ
Wright
D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D019216:Metals, Heavy / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013237:Stereoisomerism
D019216:Metals, Heavy; D009942:Organometallic Compounds