Nanocrystalline ceria powders through citrate-nitrate combustion.
Nanocrystalline ceria powders have been synthesized by combustion technique using citric acid as a fuel and nitrate as an oxidizer. The auto-ignition of the gels containing cerium nitrate and citric acid resulted in ceria powders. A theory based on adiabatic flame temperature for different citric acid-to-cerium nitrate molar ratios has been proposed to explain the nature of combustion reaction and its correlation with the powder characteristics. Specific surface area and primary particle size of the ceria powder obtained through fuel-deficient precursor was found to be approximately = 127 m2/g and 2.5-10 nm, respectively. The combustion synthesized ceria powder when cold pressed and sintered in air at 1250 degrees C for 1 hour resulted in approximately = 96% of its theoretical density with sub-micron grains.
Purohit
R D
RD
Powder Metallurgy Division, Bhabha Atomic Research Centre, Vashi Complex, Navi Mumbai-400 705, India.
Saha
S
S
Tyagi
A K
AK
D002563:Cerium / Q000737:chemistry*; D002951:Citrates / Q000737:chemistry*; D003460:Crystallization; D007477:Ions; D007700:Kinetics; D008854:Microscopy, Electron; D049329:Nanostructures / Q000737:chemistry; D009566:Nitrates / Q000737:chemistry*; D012996:Solutions; D013816:Thermodynamics; D014961:X-Ray Diffraction
D002951:Citrates; D007477:Ions; D009566:Nitrates; D012996:Solutions; D002563:Cerium