A new hydrothermal route for synthesis of molybdenum disulphide nanorods and related nanostructures.
A simple approach to prepare nanorods of Molybdenum Disulphide (MoS2) using hydrothermal method by reacting aqueous solutions of (NH4)6Mo7O24.4H20, C2H4NS and Na2S2O4 at 190 degrees C for 24 h is described. The hydrothermal product has been subsequently subjected to the thermal treatment in nitrogen atmosphere at 675 degrees C for 6 h and characterized. X-ray diffraction (XRD) of the hydrothermal product indicated the formation of MoS2 relatively with much lower crystallinity compared to when it thermally treated. Energy dispersive analysis (EDX) was done to know the chemical composition of the product. TEM showed onset growth of MoS2 nanorods within the hydrothermal products itself and in thermally treated products it was prominent with the diameter of the nanorods ranging between 10-20 nm. Photoluminescence spectra MoS2 nanorods shows an intense absorbance at around 429 nm. TGA of the MoS2 nanorods in air and nitrogen atmosphere has also been studied. The extent of formation of MoS2 from the precursors obtained at 190 degrees C for duration of 12, 18, and 24 h and annealed at 675 degrees C for 6 h under nitrogen atmosphere is also demonstrated based on XRD data.
Inorganic Materials and Nanocomposite Laboratory, Department of Chemistry, Indian Institute of Technology, Kharagpur-721302, India.
Jyoti R
JR
Ota
Suneel K
SK
Srivastava
D004220:Disulfides / Q000138:chemical synthesis* / Q000737:chemistry*; D007202:Indicators and Reagents; D007700:Kinetics; D049449:Luminescence; D008854:Microscopy, Electron; D008958:Models, Molecular; D008982:Molybdenum / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry*; D014961:X-Ray Diffraction
D004220:Disulfides; D007202:Indicators and Reagents; D008982:Molybdenum; C082964:molybdenum disulfide