Systematizing structural motifs and nomenclature in 1,n'-disubstituted ferrocene peptides.
Ferrocene peptide conjugates display an array of structural features including helical ferrocene based chirality and a number of different intramolecular hydrogen bonding patterns. In this tutorial review we present a rigorous nomenclature for these systems, followed by a section that summarises and categorises the structures known to date. The issues discussed herein are of general relevance for all metallocene-based chiral transition metal catalysts and peptide turn mimetics.
Kirin
Srećko I
SI
Institut für Pharmazie und Molekulare Biotechnologie, Universität Heidelberg, Im Neuenheimer Feld 364, D-69120 Heidelberg, Germany.
Kraatz
Heinz-Bernhard
HB
Metzler-Nolte
Nils
N
D005296:Ferrous Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D000075163:Metallocenes; D008958:Models, Molecular; D015394:Molecular Structure; D010455:Peptides / Q000737:chemistry*; D009626:Terminology as Topic
D005296:Ferrous Compounds; D000075163:Metallocenes; D010455:Peptides; C004998:ferrocene