A supramolecular photosynthetic triad of slipped cofacial porphyrin dimer, ferrocene, and fullerene.
A supramolecular triad consisting of self-assembled imidazolyl-zinc-porphyrin dimer, ferrocene, and fullerene was successfully constructed, resulting in long-lived charge separated species after efficient photoinduced electron transfer and charge shift reactions.
Nakagawa
Hiromichi
H
School of Materials Science, Nara Institute of Science and Technology, 8916-5 Takayama-cho, Ikoma, Nara 630-0101, Japan.
Ogawa
Kazuya
K
Satake
Akiharu
A
Kobuke
Yoshiaki
Y
D019281:Dimerization; D004579:Electron Transport; D005296:Ferrous Compounds / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D000075163:Metallocenes; D010788:Photosynthesis; D011166:Porphyrins / Q000737:chemistry*; D012993:Solar Energy
D005296:Ferrous Compounds; D037741:Fullerenes; D000075163:Metallocenes; D011166:Porphyrins; C069837:fullerene C60; C004998:ferrocene