First metal azide complex with isonicotinate as a bridging ligand showing new net topology: hydrothermal synthesis, structure, and magnetic properties.
A new 3D azido-bridged coordination polymer, [Co1.5(N3)(OH)(Isonic)]n (1), has been synthesized and characterized and its magnetic properties studied. Isonicotinate acts as a bridging coligand in this complex. In 1, all of the ligands take tridentate bridging coordination modes, and the overall structure of 1 exhibits a new 3,6-connected net topology.
Department of Chemistry, Nankai University, Tianjin 300071, China.
Fu-Chen
FC
Liu
Yong-Fei
YF
Zeng
Jiao
J
Jiao
Xian-He
XH
Bu
Joan
J
Ribas
Stuart R
SR
Batten
D001386:Azides / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D007539:Isonicotinic Acids / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D013696:Temperature
D001386:Azides; D007539:Isonicotinic Acids; D008024:Ligands; D009942:Organometallic Compounds; D003035:Cobalt