A simple and mild synthesis of a 4,5-cyclopropanated carbohydrate.
The synthesis of a 4,5-cyclopropanated carbohydrate was achieved in five steps from methyl alpha-D-mannopyranoside under mild conditions that avoid the use of carbene chemistry.
Instituto de Química Orgánica de Síntesis, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario-CONICET, Suipacha 531, S2002LRK Rosario, Argentina.
Sebastián A
SA
Testero
Rolando A
RA
Spanevello
D002240:Carbohydrate Sequence; D002241:Carbohydrates / Q000138:chemical synthesis* / Q000737:chemistry; D003521:Cyclopropanes / Q000737:chemistry*; D015394:Molecular Structure
D002241:Carbohydrates; D003521:Cyclopropanes; C030797:cyclopropane