Room temperature formation of ammonia by oxidizing hydrogenated cerium nanoparticles in the air.
Ammonia formation was observed when hydrogenated cerium nanoparticles prepared by hydrogen plasma-metal reaction (HPMR) were exposed to the air at room temperature. This novel phenomenon represents a successful example of room temperature cleavage of dinitrogen and may find application in low temperature synthesis of ammonia under thermodynamically favorable conditions. A possible mechanism is also proposed. We suggest that the oxidation of cerium hydride offers chemical force to drive the hydrogen atoms out of the lattice. The monoatomic H released to the surface is highly active and readily reacts with N2 to yield ammonia. Some surface processes, which we know little about at the moment, are likely to be involved so as to lower the energy barrier of nitrogen dissociation. Further investigation is required to elucidate the detailed mechanism.
Zhang
Yaohua
Y
State Key Laboratory of Rare Earth Materials, Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P R China.
Liu
Tong
T
Wang
Zhong
Z
Li
Yan
Y
Li
Xingguo
X
D000388:Air; D000641:Ammonia / Q000737:chemistry*; D002563:Cerium / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D006859:Hydrogen / Q000737:chemistry*; D006860:Hydrogen Bonding; D008422:Materials Testing; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods*; D010084:Oxidation-Reduction; D010316:Particle Size; D013696:Temperature
D002563:Cerium; D000641:Ammonia; D006859:Hydrogen