Rational modulation of the periodicity in linear hydrogen-bonded assemblies of trimesic acid on surfaces.
We demonstrate a surprising cooperative adsorption process at the liquid-solid interface, involving self-assembly in which a three-fold hydrogen-bonding unit (trimesic acid, TMA) is forced into a linear pattern by noncovalent interaction with an alcohol. Our work shows that the unexpected linear pattern formed by coadsorption of TMA and alcohols can be modulated in size by choosing alcohols with different chain lengths.
Nath
Krishna G
KG
Centre Energie, Matériaux et Télécommunications, Institut National de la Recherche Scientifique, Varennes, QC, Canada. rosei@emt.inrs.ca
Ivasenko
Oleksandr
O
Miwa
Jill A
JA
Dang
Hung
H
Wuest
James D
JD
Nanci
Antonio
A
Perepichka
Dmitrii F
DF
Rosei
Federico
F
D003461:Crystallography; D006108:Graphite / Q000737:chemistry*; D006860:Hydrogen Bonding; D013499:Surface Properties; D014233:Tricarboxylic Acids / Q000737:chemistry*
D014233:Tricarboxylic Acids; D006108:Graphite; C069849:trimesic acid