Self-organization of amide dendrons and their dendronized macromolecules.
A polymerizable methacryl unit was introduced at the focal moiety of the amide dendrons which have amide branches and alkyl periphery. Their dendronized polymers were also prepared by the radical polymerization of the methacryl units. The self-organization characteristics of dendrons and dendronized polymers were then investigated in both the organic and aqueous phases. The amide dendrons (1M and 2M) in which the focal carboxyl group was blocked with methacryl units did not form gel in organic media such as chloroform or THF, whereas amide dendrons with a free carboxyl group at the focal point form self-organized structures. In the aqueous phase, 1M and 2M formed spherical vesicular assemblies. The dendronized polymers with first and second generation dendrons, 1P and 2P, respectively, exhibited lamellar and columnar organization in toluene. In addition to hydrogen bonding between the dendritic amide branches and van der Waals interactions between the alkyl periphery, steric confinement of dendritic side groups along the polymer backbone played a key role in the packing process of the dendronized polymers. In aqueous phase, 1P and 2P showed spherical vesicular aggregates with persistent stability in the presence of Triton X-100.
Department of Polymer Science and Engineering, Hyperstructured Organic Materials Research Center, Inha University, Incheon 402-751, Korea.
Chiyoung
C
Park
Kyoung Sik
KS
Choi
Yumi
Y
Song
Hye-Jin
HJ
Jeon
Hyun Hoon
HH
Song
Ji Young
JY
Chang
Chulhee
C
Kim