Fullerene polypyridine ligands: synthesis, ruthenium complexes, and electrochemical and photophysical properties.
Fullerene coordination ligands bearing one bipyridine or terpyridine unit were synthesized, and their coordination to ruthenium(II) formed linear rod-like donor-acceptor systems. Steady-state fluorescence of [Ru(bpy)(2)(bpy-C(60))](2+) showed a rapid solvent-dependent, intramolecular quenching of the ruthenium(II) MLCT excited state. Time-resolved flash photolysis in CH(3)CN revealed characteristic transient absorption changes that have been ascribed to the formation of the C(60) triplet state, suggesting that photoexcitation of [Ru(bpy)(2)(bpy-C(60))](2+) results in a rapid intramolecular transduction of triplet excited state energy. The electrochemical studies on both [Ru(bpy)(2)(bpy-C(60))](2+) and [Ru(tpy)(tpy-C(60))](2+) indicated electronic coupling between the metal center and the fullerene core.
Zhou
Zhiguo
Z
Department of Chemistry, New York University, New York, NY 10003, USA. zhouz@lunananoworks.com
Sarova
Ginka H
GH
Zhang
Sheng
S
Ou
Zhongping
Z
Tat
Fatma T
FT
Kadish
Karl M
KM
Echegoyen
Luis
L
Guldi
Dirk M
DM
Schuster
David I
DI
Wilson
Stephen R
SR