New versatile building block for the construction of tetrathiafulvalene-based donor-acceptor systems.
[reaction: see text] A new dissymmetrical tetrathiafulvalene (TTF) derivative 1 was synthesized as a versatile building block to reach TTF-based donor-acceptor assemblies incorporating C(60) in triad C(60)-TTF-C(60) 2 and/or p-benzoquinone (Q) in fused dyad Q-TTF 3 and triad Q-TTF-C(60) 4.
Laboratoire de Chimie, Ingénierie Moléculaire et Matériaux d'Angers (CIMMA), Groupe Synthèse Organique et Matériaux Fonctionnels (SOMaF), UMR CNRS 6200, Université d'Angers, 2 Bd Lavoisier, F-49045 Angers, France.
Jérôme
J
Baffreau
Frédéric
F
Dumur
Piétrick
P
Hudhomme