A superior P-H phosphonite: asymmetric allylic substitutions with fenchol-based palladium catalysts.
The fenchol-based P-H phosphonite BIFOP-H exeeds with 65% ee other monodentate ligands in the Pd-catalyzed substitution of 1-phenyl-2-propenyl acetate with dimethylmalonate.
Goldfuss
Bernd
B
Institut für Organische Chemie, Universität zu Köln, Germany. goldfuss@uni-koeln.de
Löschmann
Thomas
T
Kop-Weiershausen
Tina
T
Neudörfl
Jörg
J
Rominger
Frank
F