An EXAFS study of the formation of a nanoporous metal-organic framework: evidence for the retention of secondary building units during synthesis.
EXAFS data measured from amorphous intermediates and crystallisation solutions provides the first evidence that trimeric iron oxide secondary building units remain intact during crystallisation of the metal-organic framework MIL-89 from starting materials to products.
Surblé
Suzy
S
Institut Lavoisier, UMR CNRS 8637, Université de Versailles St-Quentin en Yvelines, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France.
Millange
Franck
F
Serre
Christian
C
Férey
Gérard
G
Walton
Richard I
RI