Design and synthesis of novel propellanes by using claisen rearrangement and ring-closing metathesis as the key steps.
Novel hexacyclic caged compounds are prepared by a combination of Claisen rearrangement and ring-closing metathesis (RCM). Additionally, a Grignard reaction in conjugation with RCM produced intricate hexacyclic caged molecules.
Kotha
Sambasivarao
S
Indian Institute of Technology, Bombay, Powai, Mumbai-400076, India. srk@chem.iitb.ac.in
Dipak
Mirtunjay Kumar
MK
D015394:Molecular Structure; D011083:Polycyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D011083:Polycyclic Compounds