Self-assembly of bidentate ligands for combinatorial homogeneous catalysis: asymmetric rhodium-catalyzed hydrogenation.
The first chiral ligand library based on self-assembly through complementary hydrogen-bonding was realized. From a 10 x 4 ligand library, catalysts that show excellent activity and enantioselectivity for the asymmetric rhodium-catalyzed hydrogenation have been identified.
Institut für Organische Chemie und Biochemie, Albert-Ludwigs-Universität Freiburg, Germany.
Martine
M
Weis
Christoph
C
Waloch
Wolfgang
W
Seiche
Bernhard
B
Breit