NIS/TFA: a general method for hydrolyzing thioglycosides.
A variety of thioglycosides are chemoselectively hydrolyzed to the corresponding 1-hydroxy glycosides using equimolar amounts of NIS/TFA as promoter systems.
Leiden Institute of Chemistry, Leiden University, PO Box 9502, 2300 RA Leiden, The Netherlands.
Jasper
J
Dinkelaar
Martin D
MD
Witte
Leendert J
LJ
van den Bos
Herman S
HS
Overkleeft
Gijsbert A
GA
van der Marel
D006868:Hydrolysis; D013388:Succinimides / Q000737:chemistry*; D013865:Thioglycosides / Q000737:chemistry*; D014269:Trifluoroacetic Acid / Q000737:chemistry*
D013388:Succinimides; D013865:Thioglycosides; C008155:N-iodosuccinimide; D014269:Trifluoroacetic Acid