Effective manipulation of the electronic effects and its influence on the emission of 5-substituted tris(8-quinolinolate) aluminum(III) complexes.
The unique electron-transport and emissive properties of tris(8-quinolinolate) aluminum(III) (Alq(3)) have resulted in extensive use of this material for small molecular organic light-emitting diode (OLED) fabrication. So far, efforts to prepare stable and easy-to-process red/green/blue (RGB)-emitting Alq(3) derivatives have met with only a limited success. In this paper, we describe how the electronic nature of various substituents, projected via an arylethynyl or aryl spacer to the position of the highest HOMO density (C5), may be used for effective emission tuning to obtain blue-, green-, and red-emitting materials. The synthetic strategy consists of four different pathways for the attachment of electron-donating and electron-withdrawing aryl or arylethynyl substituents to the 5-position of the quinolinolate ring. Successful tuning of the emission color covering the whole visible spectrum (lambda=450-800 nm) was achieved. In addition, the photophysical properties of the luminophores were found to correlate with the Hammett constant of the respective substituents, providing a powerful strategy with which to predict the optical properties of new materials. We also demonstrate that the electronic nature of the substituent affects the emission properties of the resulting complex through effective modification of the HOMO levels of the quinolinolate ligand.
Montes
Victor A
VA
Department of Chemistry and Center for Photochemical Sciences, Bowling Green State University (BGSU), Bowling Green, OH 43403, USA.
Pohl
Radek
R
Shinar
Joseph
J
Anzenbacher
Pavel
P
D000535:Aluminum / Q000737:chemistry*; D004563:Electrochemistry; D004579:Electron Transport; D004583:Electrons; D008027:Light; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011805:Quinolinic Acids / Q000138:chemical synthesis / Q000737:chemistry*; D012666:Semiconductors; D013057:Spectrum Analysis
D009942:Organometallic Compounds; D011805:Quinolinic Acids; D000535:Aluminum