Spontaneous shears in smectic elastomers.
We model the spontaneous elastic shear deformations of smectic elastomers as they make the thermal transition between the A and C phases. Tilt of the director is accompanied by shear. Unlike nematic elastomers where spontaneous elongation is associated with changes in the magnitude of order, spontaneous distortion in smectics is instead shear and is associated with rotation of the director of the underlying nematic order. The effect of the multistage cross-linking associated with creating monodomain elastomers is taken into account. The angle of molecular tilt and the angle associated with spontaneous shear deformation are not simply related.
Adams
J M
JM
Cavendish Laboratory, University of Cambridge, Madingley Road, Cambridge CB3 0HE, UK.
Warner
M
M