title: The disposal of radioactive ferric floc.
abstract: An iron hydroxide floc is used as treatment for adsorbing low amounts of actinides during nuclear fuel re-processing. This waste is cemented only after pre-treatment with Ca(OH)(2). Characterisation of all simulant material has been undertaken using XRD, TGA and SEM/EDS. The floc is a moderately alkaline colloidal slurry containing approximately 15wt% solids, with the main particulate being an amorphous hydrated iron oxide. The main phase formed during pre-treatment appears to be an X-ray amorphous hydrated calcium-ferrate phase. Embedded within this are small amounts of crystalline Ca(OH)(2), calcite, Fe(6)(OH)(12)(CO(3)), Ca(6)Fe(2)(SO(4))(3)(OH)(12).26H(2)O and Ca(3)B(2)O(6), and can form depending on concentrations of Ca(OH)(2) and time. Apart from Ca(OH)(2) and calcite, none of the crystalline phases detected during pre-treatment are detected when the floc is encapsulated in an OPC/PFA composite cement hydrated for 90 days. The main crystalline phase detected in the hardened wasteform is a solid solution hydrogarnet, Ca(3)AlFe(SiO(4))(OH)(8), known as C(3)(A,F)SH(4) in cement chemistry nomenclature.
authors.affiliation: Immobilisation Science Laboratory, Department of Engineering Materials, University of Sheffield, Mappin Street, Sheffield, S1 3JD, UK. n.collier@sheffield.ac.uk
authors.forename: N C
authors.initials: NC
authors.lastname: Collier
authors.forename: N B
authors.initials: NB
authors.lastname: Milestone
authors.forename: J
authors.initials: J
authors.lastname: Hill
authors.forename: I H
authors.initials: IH
authors.lastname: Godfrey
mesh_terms: D003252:Construction Materials; D005290:Ferric Compounds; D008855:Microscopy, Electron, Scanning; D011850:Radioactive Waste; D014961:X-Ray Diffraction
chemical_list: D005290:Ferric Compounds; D011850:Radioactive Waste