Synthesis and characterization of aluminum-containing tin(IV) heterobimetallic sulfides.
Three novel aluminum-containing tin(IV) heterobimetallic sulfides are reported. The reaction of [LAl(SLi)2(THF)2]2 (1) [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3] with Ph2SnCl2, Me2SnCl2, and SnCl4 in THF respectively afforded LAl(mu-S)2SnPh2 (2), LAl(mu-S)2SnMe2 (3), and LAl(mu-S)2Sn(mu-S)2AlL (4) in moderate yields. Compounds 2, 3, and 4 were characterized by elemental analysis, NMR, electron-impact mass spectrometry, and single-crystal X-ray structural analysis.
Yang
Zhi
Z
Institut für Anorganische Chemie der Georg-August-Universität Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany.
Ma
Xiaoli
X
Jancik
Vojtech
V
Zhang
Zhensheng
Z
Roesky
Herbert W
HW
Magull
Jörg
J
Noltemeyer
Mathias
M
Schmidt
Hans-Georg
HG
Cea-Olivares
Raymundo
R
Toscano
Rubén A
RA