Resolving electron transfer kinetics at the nanocrystal/solution interface.
The kinetics of electron transfer between individual gold nanocrystals and a solution redox species is quantified. The observed rate is dependent on the extent of electronic coupling between nanocrystals in the monolayer indicating the effect of Coulomb blockade on electrochemical kinetics.
Liljeroth
Peter
P
Condensed Matter and Interfaces, Debye Institute, University of Utrecht, PO Box 80000, 3508 TA Utrecht, The Netherlands.
Quinn
Bernadette M
BM