title: Synthesis and characterization of aluminum-containing tin(IV) heterobimetallic sulfides.
abstract: Three novel aluminum-containing tin(IV) heterobimetallic sulfides are reported. The reaction of [LAl(SLi)2(THF)2]2 (1) [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3] with Ph2SnCl2, Me2SnCl2, and SnCl4 in THF respectively afforded LAl(mu-S)2SnPh2 (2), LAl(mu-S)2SnMe2 (3), and LAl(mu-S)2Sn(mu-S)2AlL (4) in moderate yields. Compounds 2, 3, and 4 were characterized by elemental analysis, NMR, electron-impact mass spectrometry, and single-crystal X-ray structural analysis.
authors.affiliation: Institut für Anorganische Chemie der Georg-August-Universität Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany.
authors.forename: Zhi
authors.initials: Z
authors.lastname: Yang
authors.forename: Xiaoli
authors.initials: X
authors.lastname: Ma
authors.forename: Vojtech
authors.initials: V
authors.lastname: Jancik
authors.forename: Zhensheng
authors.initials: Z
authors.lastname: Zhang
authors.forename: Herbert W
authors.initials: HW
authors.lastname: Roesky
authors.forename: Jörg
authors.initials: J
authors.lastname: Magull
authors.forename: Mathias
authors.initials: M
authors.lastname: Noltemeyer
authors.forename: Hans-Georg
authors.initials: HG
authors.lastname: Schmidt
authors.forename: Raymundo
authors.initials: R
authors.lastname: Cea-Olivares
authors.forename: Rubén A
authors.initials: RA
authors.lastname: Toscano