Synthesis and structural characterization of the first metal organic thallium antimonide.
The first metal organic thallium antimonide, the heterocycle [Me2TlSb(SiMe3)2]3, was synthesized by reaction of [Me2AlSb(SiMe3)2]3 with the Lewis acid-base adduct dmap-TlMe3 (dmap = 4-dimethylaminopyridine). The analogous TlBi heterocycle [Me2TlBi(SiMe3)2]3 couldn't be isolated due to its limited thermal stability in solution.
Schulz
Stephan
S
Department Chemie, Universität Paderborn, Warburger Strasse 100, J6.214, 33098 Paderborn, Germany. stephan.schulz@upb.de
Thomas
Florian
F
Nieger
Martin
M