title: The first supramolecular photosensitization of enantiodifferentiating bimolecular reaction: anti-Markovnikov photoaddition of methanol to 1,1-diphenylpropene sensitized by modified beta-cyclodextrin.
abstract: Enantiodifferentiating polar photoaddition of methanol to 1,1-diphenylpropene included and sensitized by cyanonaphthalene-modified beta-cyclodextrin was examined for the first time to give optically active anti-Markovnikov adduct with accompanying inversion of the chiral sense of the photoproduct by temperature, which is entropic in origin.
authors.affiliation: Department of Applied Chemistry, Osaka University, 2-1 Yamada-oka, Suita 565-0871, Japan. inoue@chem.eng.osaka-u.ac.jp
authors.forename: Gaku
authors.initials: G
authors.lastname: Fukuhara
authors.forename: Tadashi
authors.initials: T
authors.lastname: Mori
authors.forename: Takehiko
authors.initials: T
authors.lastname: Wada
authors.forename: Yoshihisa
authors.initials: Y
authors.lastname: Inoue