title: 2'-Carboxybenzyl glycosides: glycosyl donors for C-glycosylation and conversion into other glycosyl donors.
abstract: Glycosylation of various glycosyl acceptors with 2'-carboxybenzyl (CB) 2,3,4,6-tetra-O-benzyl-beta-D-glucopyranoside and CB 2,3,4,6-tetra-O-benzyl-alpha-D-mannopyranoside as glycosyl donors afforded alpha-C-glycosides exclusively or predominantly in good yields. CB glycosides were also converted to other well-known glycosyl donors, the corresponding phenyl thioglycoside and the glycosyl fluoride derivatives.
authors.affiliation: Center for Bioactive Molecular Hybrids and Department of Chemistry, Yonsei University, Seoul 120-749, Republic of Korea.
authors.forename: Yong Joo
authors.initials: YJ
authors.lastname: Lee
authors.forename: Ju Yuel
authors.initials: JY
authors.lastname: Baek
authors.forename: Bo-Young
authors.initials: BY
authors.lastname: Lee
authors.forename: Sung Soo
authors.initials: SS
authors.lastname: Kang
authors.forename: Hye-Seo
authors.initials: HS
authors.lastname: Park
authors.forename: Heung Bae
authors.initials: HB
authors.lastname: Jeon
authors.forename: Kwan Soo
authors.initials: KS
authors.lastname: Kim
mesh_terms: D001593:Benzyl Compounds / Q000737:chemistry*; D006027:Glycosides / Q000737:chemistry*; D006031:Glycosylation
chemical_list: D001593:Benzyl Compounds; D006027:Glycosides