title: One-dimensional mu-chloromanganese(II)-tetrathiafulvalene (TTF) coordination compound.
abstract: A new tetrathiafulvalene derivative 1 bearing a single pyridine group and its coordination complex 2, with stoichiometry [Mn(mu-Cl)Cl(1)2(CH3OH)]n, have been synthesized and fully characterized. The complex 2 shows an extended chain structure, which is potentially favorable for electrical conductivity. Notably, this is the first monohalogen-bridged Mn(II) polymer exhibiting a moderate antiferromagnetic coupling between the Mn(II) centers.
authors.affiliation: Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, CH-3012 Bern, Switzerland.
authors.forename: Chunyang
authors.initials: C
authors.lastname: Jia
authors.forename: Shi-Xia
authors.initials: SX
authors.lastname: Liu
authors.forename: Christina
authors.initials: C
authors.lastname: Ambrus
authors.forename: Antonia
authors.initials: A
authors.lastname: Neels
authors.forename: Gaël
authors.initials: G
authors.lastname: Labat
authors.forename: Silvio
authors.initials: S
authors.lastname: Decurtins