Molecular assembling using axial phenolate on an iron N-confused porphyrin complex.
The reaction of sodium phenolate and Fe(HCTPPH)Br assembles a dimeric iron(III) complex with a channel-like solid state packing; the intramolecular iron-to-iron distance of 8.864 A is the longest among the available N-confused porphyrin dimeric complexes.
Hung
Chen-Hsiung
CH
Institute of Chemistry, Academia Sinica, Nankang Taipei, 105 Taiwan. chhung@chem.sinica.edu.tw
Chang
Chia-Hao
CH
Ching
Wei-Min
WM
Chuang
Chuan-Hung
CH