title: Mutual consistency between simulated and measured pressure drops in silica monoliths based on geometrical parameters obtained by three-dimensional laser scanning confocal microscope observations.
abstract: The geometrical properties of co-continuous macroporous silica monoliths have been studied by laser scanning confocal microscopy (LSCM) and a comparison has been made with those obtained by conventional mercury intrusion method. Tetrahedral skeleton model (TMS), which mimics the gel skeleton shape of monoliths, was compared with real monoliths in terms of macropore and porosity using the geometrical parameters extracted from the LSCM observations. Liquid flow behavior through the macroporous silica monoliths was examined in comparison with those simulated using TSM, based on the geometrical properties obtained from LSCM observations. Heterogeneity in macropore topology and connectivity in pores and skeletons are suggested to contribute to the improvement of the model structure for macroporous monoliths.
authors.affiliation: Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku-katsura, Nishikyo-ku, Japan.
authors.forename: Haruko
authors.initials: H
authors.lastname: Saito
authors.forename: Kazuki
authors.initials: K
authors.lastname: Nakanishi
authors.forename: Kazuyuki
authors.initials: K
authors.lastname: Hirao
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Jinnai
mesh_terms: D018613:Microscopy, Confocal; D011312:Pressure; D012822:Silicon Dioxide / Q000737:chemistry*
chemical_list: D012822:Silicon Dioxide