A tris-pyrazolylborate ligand with hemilabile O-donor groups. Examples of eta3, eta5, eta6 and bridging modes of bonding to Li+, Na+, K+, Tl+ and Ca2+ ions.
A tris-pyrazolylborate ligand bearing ether appendages is shown to be a potential hemilabile ligand based on NMR studies and structural characterization of its eta3, eta5, eta6, and micro-binding modes in coordination with Li+, Na+, K+, Tl+, and Ca2+ ions.
Chisholm
Malcolm H
MH
Newman and Wolfrom Laboratories, Ohio State University, 100 W. 18th Avenue, Columbus, OH 43210, USA. chisholm@chemistry.ohio-state.edu
Gallucci
Judith C
JC
Yaman
Gülşah
G