Mean chain length of adsorbed supramolecular polymers.
We present a theoretical study of reversible supramolecular polymers near an adsorbing surface. Mean chain lengths for free and adsorbed supramolecular polymers were calculated for a broad range of concentrations. As far as we know, this is the first report that describes a regime where the mean chain length decreases with increasing monomer concentration. It is shown that this anomalous behavior is caused by a change of the structure of the adsorbed layer.
Zweistra
Henk J A
HJ
Laboratory of Physical Chemistry and Colloid Science, Dreijenplein 6, NL-6703 HB Wageningen, The Netherlands. henk.zweistra@wur.nl
Besseling
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D000327:Adsorption; D001672:Biocompatible Materials / Q000737:chemistry*; D008968:Molecular Conformation; D011108:Polymers / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry; D013499:Surface Properties; D013816:Thermodynamics
D001672:Biocompatible Materials; D011108:Polymers; D012997:Solvents