title: Adsorption of unsaturated hydrocarbon moieties on H:Si(111) by Grignard reaction.
abstract: Grafting of unsaturated hydrocarbon moieties (-CH(2)-CH=CH(2), -CH=CH(2), -CH(2)-CH=CH-CH(3), and -CCH) by a C-Si covalent bond was attempted by the Grignard reaction on hydrogen-terminated Si(111) in tetrahydrofuran solutions. The product adsorbates were monitored by vibrational methods of high-resolution electron energy loss spectroscopy and multiple internal infrared reflection absorption spectroscopy, as well as Auger electron spectroscopy. The temperature and the period of reaction were adjusted so as to preserve the unsaturated carbon-carbon bonds. The -CH(2)-CH=CH(2) group was introduced by a mild reaction condition, with the reservation of the C=C double bond confirmed. The unsaturated bonds in -CH(2)-CH=CH-CH(3) and -CCH were also reserved. Only in the case of -CH=CH(2) was the reservation of the C=C double bond not realized. Unsaturated hydrocarbon moieties are applicable for further organic modification to introduce functional groups, and are prospective materials in nanofabrication and biological application on silicon wafer surfaces.
authors.affiliation: RIKEN (The Institute for Chemical and Physical Research), 2-1 Hirosawa, Wako-shi, Saitama 351-0198, Japan.
authors.forename: Taro
authors.initials: T
authors.lastname: Yamada
authors.forename: Kaoru
authors.initials: K
authors.lastname: Shirasaka
authors.forename: Madomi
authors.initials: M
authors.lastname: Noto
authors.forename: Hiroyuki S
authors.initials: HS
authors.lastname: Kato
authors.forename: And Maki
authors.initials: AM
authors.lastname: Kawai