Facile synthesis of enantiopure chiral molecular rectangles exhibiting induced circular dichroism.
[structure: see text] The facile syntheses of enantiopure molecular rectangles using 1,8-bis(trans-Pt(PEt(3))(2)(NO(3)))anthracene and optically pure d- or l-tartrate are reported in high yields. These self-assembled macrocycles are unique examples where the phenomenon of induced chiral dichroism (ICD) has been observed in chiral metallosupramolecular assemblies.
Das
Neeladri
N
Department of Chemistry, University of Utah, 315 S, 1400 E, Salt Lake City, Utah 84112, USA.
Ghosh
Ashutosh
A
Singh
Okram M
OM
Stang
Peter J
PJ
D000873:Anthracenes / Q000138:chemical synthesis / Q000737:chemistry*; D002942:Circular Dichroism / Q000379:methods*; D015394:Molecular Structure; D009944:Organoplatinum Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013644:Tartrates / Q000138:chemical synthesis / Q000737:chemistry*
D000873:Anthracenes; D009944:Organoplatinum Compounds; D013644:Tartrates