Biosynthesis of thiamin thiazole: determination of the regiochemistry of the S/O acyl shift by using 1,4-dideoxy-D-xylulose-5-phosphate.
Chatterjee
Abhishek
A
Department of Chemistry and Chemical Biology, Cornell University, Ithaca, NY 14853, USA.
Han
Xuemei
X
McLafferty
Fred W
FW
Begley
Tadhg P
TP
D001412:Bacillus subtilis / Q000378:metabolism*; D002384:Catalysis; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D010100:Oxygen / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization; D013455:Sulfur / Q000737:chemistry*; D013831:Thiamine / Q000031:analogs & derivatives* / Q000096:biosynthesis*; D013844:Thiazoles / Q000737:chemistry / Q000378:metabolism; D014996:Xylulose / Q000031:analogs & derivatives* / Q000737:chemistry
C520800:1,4-dideoxy-D-xylulose-5-phosphate; D013844:Thiazoles; C012572:2-(4-methyl-1,3-thiazol-5-yl)ethanol; D014996:Xylulose; D013455:Sulfur; D010100:Oxygen; D013831:Thiamine