Monomeric lithium triazapentadienyl complexes.
Treatment of 1,3,5-triazapentadienes [N{(C3F7)C(Mes)N}2]H and [N{(C3F7)C(Dipp)N}2]H (where Mes = 2,4,6-Me3C6H2; Dipp = 2,6-Pr(i)2C6H3) with n-BuLi in hexane, followed by the crystallization from hexane-THF mixture afforded the corresponding lithium 1,3,5-triazapentadienyl complexes as their THF solvates. X-Ray crystallographic analyses revealed that [N{(C3F7)C(Mes)N}2]Li(THF)2 and [N{(C3F7)C(Dipp)N}2]Li(THF) are monomeric in the solid state. [N{(C3F7)C(Mes)N}2]Li(THF)2 has a four-coordinate lithium center with a distorted tetrahedral geometry, and features a boat-shaped C2N3Li metallacycle. [N{(C3F7)C(Dipp)N}2]Li(THF) has a three-coordinate lithium atom and a planar, U-shaped C2N3 ligand backbone. The synthesis, solid-state structure, and 1H and 19F NMR spectroscopic details of [N{(C3F7)C(Mes)N}2]H are also reported.
Dias
H V Rasika
HV
Department of Chemistry and Biochemistry, University of Texas at Arlington, Arlington, Texas 76019, USA. dias@uta.edu
Singh
Shreeyukta
S
D001372:Aza Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008094:Lithium / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011073:Polyamines / Q000737:chemistry; D012680:Sensitivity and Specificity
D001372:Aza Compounds; D008024:Ligands; D009942:Organometallic Compounds; D011073:Polyamines; D008094:Lithium