Preparation, crystallographic characterization and theoretical study of two isomers of C70(CF3)12.
Two isomers of C70(CF3)12 have been isolated from a mixture obtained by trifluoromethylation of C70 with CF3I; their molecular structures determined by X-ray crystallography are in good agreement with the results of theoretical DFT calculations for the most stable C70(CF3)12 isomers.
Ignat'eva
Daria V
DV
Chemistry Department, Moscow State University, Leninskie Gory, 119992 Moscow, Russia. sergej.troyanov@rz.hu-berlin.de
Goryunkov
Alexey A
AA
Tamm
Nadezhda B
NB
Ioffe
Ilya N
IN
Avdoshenko
Stanislav M
SM
Sidorov
Lev N
LN
Dimitrov
Anton
A
Kemnitz
Erhard
E
Troyanov
Sergey I
SI