Asymmetric allylic alkylation of cyclic vinylogous esters and thioesters by Pd-catalyzed decarboxylation of enol carbonate and beta-ketoester substrates.
Trost
Barry M
BM
Department of Chemistry, Stanford University, Stanford, CA 94305-5080, USA. bmtrost@stanford.edu
Bream
Robert N
RN
Xu
Jiayi
J
D000478:Alkylation; D000498:Allyl Compounds / Q000138:chemical synthesis*; D002254:Carbonates / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D004952:Esters / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D008956:Models, Chemical; D010165:Palladium / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D014753:Vinyl Compounds / Q000138:chemical synthesis*
D000498:Allyl Compounds; D002254:Carbonates; D004952:Esters; D007659:Ketones; D013438:Sulfhydryl Compounds; D014753:Vinyl Compounds; D010165:Palladium