Tandem radical rearrangement/Pd-catalysed translocation of bicyclo[2.2.2]lactones. An efficient access to the oxa-triquinane core structure.
The skeletal rearrangement of bicyclo[2.2.2]lactones, involving a mild and chemoselective palladium-catalysed translocation key-step, provides an efficient and diastereoselective access to synthetically useful bicyclo[3.3.0]lactones.
Liao
Jyh-Hsiung
JH
Université catholique de Louvain, Département de Chimie, Bâtiment Lavoisier, Place Louis Pasteur 1, 1348, Louvain-la-Neuve, Belgium.
Maulide
Nuno
N
Augustyns
Benoît
B
Markó
István E
IE