Metal-mediated efficient synthesis, structural characterization, and skeletal rearrangement of octasubstituted semibullvalenes.
The first metal-mediated efficient synthesis of octasubstituted semibullvalenes, including octaalkyl and mixed tetraalkyl and tetraphenyl derivatives, was developed. The structures of these semibullvalenes were determined by single-crystal X-ray structural analysis. Their intramolecular skeletal rearrangement and reaction chemistry were investigated.
Wang
Chao
C
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
Yuan
Jian
J
Li
Guotao
G
Wang
Zitao
Z
Zhang
Shiwei
S
Xi
Zhenfeng
Z
D018360:Crystallography, X-Ray; D003500:Cyclization; D003516:Cycloparaffins / Q000138:chemical synthesis / Q000737:chemistry*; D018020:Lithium Compounds / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D011083:Polycyclic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011090:Polyenes / Q000737:chemistry
D003516:Cycloparaffins; D018020:Lithium Compounds; D011083:Polycyclic Compounds; D011090:Polyenes