A non-heme dinuclear iron(II) complex containing a single, unsupported hydroxo bridge.
Complexation of the tetrapodal pentadentate NN4 ligand 2,6-C5H3N[CMe(CH2NH2)2]2 (I) with iron(II) perchlorate hydrate in methanol, in the presence of N-methylimidazole, produces a diferrous complex with a single, unsupported mu-OH ligand between two {(I)FeII} coordination modules.
López
Jesús Pitarch
JP
Technische Universität Berlin, Institut für Chemie, Sekretariat C2, Strasse des 17. Juni 135, D-10623 Berlin, Germany. andreas.grohmann@chem.tu-berlin.de
Kämpf
Holger
H
Grunert
Matthias
M
Gütlich
Philipp
P
Heinemann
Frank W
FW
Prakash
Raju
R
Grohmann
Andreas
A