Critical adsorption of polyelectrolytes onto charged spherical colloids.
The adsorption of a flexible polyelectrolyte in a salt solution onto an oppositely charged spherical surface is investigated. An analytical solution is derived, which is valid for any sphere radius and consistently recovers the result of a planar surface in the limit of large sphere radii, by substituting the Debye-Hückel potential via the Hulthén potential. Expressions for critical quantities such as the critical radius and the critical surface charge density are provide. A comparison of our theoretical results with experiments and computer simulations yields remarkable good agreement.
Winkler
Roland G
RG
Institut für Festkörperforschung, Forschungszentrum Jülich, D-52425 Jülich, Germany.
Cherstvy
Andrey G
AG