title: Langmuir-Blodgett patterning of phospholipid microstripes: effect of the second component.
abstract: We systematically describe the striped pattern formation of the mixed monolayers of 1,2-di(2,4-octadecadienoyl)-sn-glycero-3-phosphocholine (DOEPC) and l-alpha-dipalmitoylphosphatidylcholine (DPPC) from the liquid expanded (LE) phase onto a mica surface by Langmuir-Blodgett (LB) transfer. The addition of the second component, DOEPC, strongly affects the formation of DPPC stripe patterns. When the molar ratio of DPPC and DOEPC is 1:0.1, the horizontal stripes dominate, while in the case of pure DPPC monolayer, there are three kinds of patterns: horizontal stripes, grids, and vertical stripes. The width and periodicity of stripes formed from the mixed monolayers are ca. 4-5 times smaller than those formed from pure DPPC patterns at the same transfer conditions, while the widths of channels are similar. A phase shift of substrate-mediated microphase separation in the two-component system during LB transfer is considered to be the mechanism for the influence of the second component on the formation of DPPC stripe patterns.
authors.affiliation: Physikalisches Institut and Center for Nanotechnology (CeNTech), Westfälische Wilhelms-Universität, D-48149 Münster, Germany.
authors.forename: Xiaodong
authors.initials: X
authors.lastname: Chen
authors.forename: Nan
authors.initials: N
authors.lastname: Lu
authors.forename: Hui
authors.initials: H
authors.lastname: Zhang
authors.forename: Michael
authors.initials: M
authors.lastname: Hirtz
authors.forename: Lixin
authors.initials: L
authors.lastname: Wu
authors.forename: Harald
authors.initials: H
authors.lastname: Fuchs
authors.forename: Lifeng
authors.initials: L
authors.lastname: Chi