One-dimensional mu-chloromanganese(II)-tetrathiafulvalene (TTF) coordination compound.
A new tetrathiafulvalene derivative 1 bearing a single pyridine group and its coordination complex 2, with stoichiometry [Mn(mu-Cl)Cl(1)2(CH3OH)]n, have been synthesized and fully characterized. The complex 2 shows an extended chain structure, which is potentially favorable for electrical conductivity. Notably, this is the first monohalogen-bridged Mn(II) polymer exhibiting a moderate antiferromagnetic coupling between the Mn(II) centers.
Jia
Chunyang
C
Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, CH-3012 Bern, Switzerland.
Liu
Shi-Xia
SX
Ambrus
Christina
C
Neels
Antonia
A
Labat
Gaël
G
Decurtins
Silvio
S