title: Dehydration of the nanoporous coordination framework ErIII[CoIII(CN)6].4(H2O): single crystal to single crystal transformation and negative thermal expansion in ErIII[CoIII(CN)6].
abstract: Desorption of bound and unbound water molecules from the nanoporous coordination framework ErIII[CoIII(CN)6].4(H2O) to form the apohost, ErIII[CoIII(CN)6], proceeds via a single crystal to single crystal transformation in which the Er(III) cations change from 8- to 6-coordinate; dehydration results in a striking change in the thermal expansion properties.
authors.affiliation: School of Chemistry, University of Sydney, Australia.
authors.forename: Thorsten
authors.initials: T
authors.lastname: Pretsch
authors.forename: Karena W
authors.initials: KW
authors.lastname: Chapman
authors.forename: Gregory J
authors.initials: GJ
authors.lastname: Halder
authors.forename: Cameron J
authors.initials: CJ
authors.lastname: Kepert