Intramolecular triplet energy transfer in donor-acceptor molecules linked by a crown ether bridge.
Bichromophoric compounds BP-C-NP and BP-C-NBD were synthesized with benzophenone chromophore (BP) as the donor, and 2-naphthyl (NP) and norbornadiene group (NBD) as the acceptor, respectively. Their intramolecular triplet energy transfer was examined. The bridges linking the donor and acceptors in these molecules involve a crown ether moiety complexing a sodium ion. Phosphorescence quenching, flash photolysis and photosensitized isomerization experiments indicate that intramolecular triplet energy transfer occurs with rate constants of about 3.3 x 10(5) and 4.8 x 10(5) s(-1) and efficiencies of about 33 and 42 % for BP-C-NP and BP-C-NBD, respectively. Theoretical calculations indicate that these molecules adopt conformations below room temperature which allow their two-end chromophores conducive to through-space energy transfer.
Xu
Xiao-He
XH
Technical Institute of Physics and Chemistry, The Chinese Academy of Sciences, Beijing 100101, PR China.
Fu
Xiao-Gang
XG
Wu
Li-Zhu
LZ
Chen
Bin
B
Zhang
Li-Ping
LP
Tung
Chen-Ho
CH
Ji
Hai-Feng
HF
Schanze
Kirk S
KS
Zhang
Rui-Qin
RQ