Highly diastereoselective synthesis of bicyclo[3.2.1]octenones through phosphine-mediated condensations of 1,4-dien-3-ones.
McDougal
Nolan T
NT
Department of Chemistry, Metcalf Center for Science and Engineering, Boston University, 590 Commonwealth Avenue, Boston, MA 02215, USA.
Schaus
Scott E
SE
D001643:Bridged Bicyclo Compounds / Q000737:chemistry*; D003500:Cyclization; D034242:Cyclooctanes / Q000737:chemistry*; D008956:Models, Chemical; D010720:Phosphines / Q000737:chemistry*; D013237:Stereoisomerism
D001643:Bridged Bicyclo Compounds; D034242:Cyclooctanes; D010720:Phosphines; C044646:phosphine