Formation of aluminacyclobutenes via carbon monoxide and isocyanide insertion.
Reaction of LAl[eta2-(CSiMe3)2] (L = HC[(CMe)(NAr)]2, Ar = 2,6-iPr2C6H3) with carbon monoxide and tert-butyl isocyanide afforded unique AlC3 aluminacyclobutenes via insertion into one of the aluminium-carbon bonds.
Li
Xiaofei
X
State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, P. R. China.
Ni
Chengbao
C
Song
Haibing
H
Cui
Chunming
C