Identify the injury implements by SEM/EDX and ICP-AES.
The forensic investigator is frequently confronted with the discrimination and deduction of injury implements, which is one of the most important physical testimonies in courts. The usual method used in actual cases is from points of morphology. In the forensic discrimination of injury implements, such as metal implements, the analysis and comparison of elements are expected to provide excellent results, and simultaneous multi-elemental analysis is required to analyze various kinds of elements. This study was designed to establish discrimination and deduction of metal injury implements by scanning electron microscope/energy disperse X-ray microanalyzer (SEM/EDX) and inductively coupled plasma atomic emission spectrometry (ICP-AES). Examined metal particles in five wounds made on the skin of domestic pigs, respectively, using Cu-Zn or Cr-Ni coated and carbon steel kitchen implements by EDX. For carbon steel kitchen implements, analyzed five samples from the back and blade separately in the contents and varieties of elements by ICP-AES. In the wounds by the coated implements, the special particles only containing Cu, Zn or Cr, Ni were found. In the wounds by carbon steel kitchen implements, the particles containing Fe, Cr, Si or Fe, Mn, Si were found. The differences of contents of elements between the back and blade was no significant except No. 5 for carbon steel kitchen implements, and the significant differences of elements exited in Cr, Mn, Si, Cu, Mo among the stainless kitchen knives, Mn, Si among the other kitchen implements and for the blade of No. 5 knife, relative standard deviations (R.S.D.s) were significantly different in Mn, Si, Mo, Ti, S, P, Ni. Using EDX to examine the particles in wounds can deduce the categories of metal injury implements, and we can still deduce the different implements in the same category by ICP-AES.
Bai
Rufeng
R
Department of Forensic Science, Medical College of Shantou University, Shantou, PR China. brf1000cn@yahoo.com.cn
Wan
Lihua
L
Li
Hongwei
H
Zhang
Zhong
Z
Ma
Zhihua
Z
D000818:Animals; D049429:Forensic Pathology; D019216:Metals, Heavy / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D023421:Models, Animal; D011237:Predictive Value of Tests; D012680:Sensitivity and Specificity; D013054:Spectrophotometry, Atomic; D013552:Swine; D014951:Wounds, Stab / Q000473:pathology*
D019216:Metals, Heavy