Trinuclear lanthanide complexes of a compartmental ligand N,N'-bis(2-pyridinyl)-2,6-pyridinedicarboxamide: a spectroscopic investigation.
Trinuclear lanthanide complexes of the formula [Ln(3)(PPDA)(NO(3))(6)(H(2)O)(2)].NO(3).2H(2)O where Ln=La(III), Pr(III), Sm(III), Nd(III), Eu(III) Gd(III) Tb(III), Dy(III) and Y(III); H(2)PPDA=N,N'-bis(2-pyridinyl)-2,6-pyridinedicarboxamide, have been isolated. The complexes were characterized by elemental analyses, conductivity measurements, magnetic susceptibility measurements and spectral (IR, NMR, UV-vis, fluorescence, FAB and EPR) and thermal studies.
Gudasi
Kalagouda B
KB
Department of Chemistry, Karnatak University, Dharwad 580003, India. kbgudasi@rediffmail.com <kbgudasi@rediffmail.com>
Shenoy
Rashmi V
RV
Vadavi
Ramesh S
RS
Patil
Siddappa A
SA
D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D011725:Pyridines / Q000737:chemistry*; D013057:Spectrum Analysis
D028581:Lanthanoid Series Elements; D008024:Ligands; C517279:N,N'-bis(2-pyridinyl)-2,6-pyridinedicarboxamide; D011725:Pyridines