title: Rate constants for the reactions of CO3- and O3- with SO2 from 300 to 1440 K.
abstract: Rate constants for the reactions of CO(3) (-) and O(3) (-) with SO(2) have been measured between 300 and 1440 K in a high temperature flowing afterglow apparatus. The CO(3) (-) rate constants near to the collision rate at low temperatures and fall by about a factor of 50 with temperature until a broad minimum is reached at 900-1300 K. The highest temperature point shows the increasing rate constant. Comparison to drift tube data taken in a helium buffer shows that total energy controls the reactivity, presumably because the reaction goes through a long lived complex even at 1440 K. The reaction of O(3) (-) with SO(2) was studied up to 1400 K. The rate constant is collisional until 700 K and then decreases with increasing temperature. Rate constants measured at 1300 and 1400 K appear to show an increase, but that observation is questionable since O(3) (-) could not be made cleanly. The O(3) (-) data at 1200 K and below show that total energy controls reactivity in that range.
authors.affiliation: Air Force Research Laboratory, Space Vehicles Directorate, Hanscom Air Force Base, Massachusetts 01731-3010, USA.
authors.forename: Thomas M
authors.initials: TM
authors.lastname: Miller
authors.forename: Jeffrey F
authors.initials: JF
authors.lastname: Friedman
authors.forename: John S
authors.initials: JS
authors.lastname: Williamson
authors.forename: A A
authors.initials: AA
authors.lastname: Viggiano