Unexpected interconversion reaction of 1,4-diaminofullerenes.
A facile substitution of amine groups attached to the fullerene cage occurs when 1,4-diaminofullerenes C60[NR2]2 are allowed to react with excess of another amine R'2NH; this reaction proceeds rapidly at room temperature without any additional initiators.
Troshina
Olesya A
OA
Institute of Problems of Chemical Physics of RAS, Chernogolovka, Moscow Region, Russia. troshin@cat.icp.ac.ru
Troshin
Pavel A
PA
Peregudov
Alexander S
AS
Lyubovskaya
Rimma N
RN