Three novel silver complexes with ligand-unsupported argentophilic interactions and their luminescent properties.
Three novel silver complexes, namely, [Ag5(CN)5(bipy)2]n (1) with a 1-D to 3-D architecture constructed through ligand-unsupported argentophilic interactions, [Ag5(SCN)4(CN)(bipy)2]n (2) with a 2-D interesting topology formed by cyanide groups linking [Ag5(SCN)4(bipy)2]n(n+) cationic columns, and [(Me4N)Ag3(CN)4]n (3) with 3-fold-interpenetrated 3-D 3-connected (10, 3)-g nets, have been solvothermally synthesized, and all exhibit efficient luminescence.
Liu
Xi
X
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China.
Guo
Guo-Cong
GC
Fu
Ming-Lai
ML
Liu
Xue-Hui
XH
Wang
Ming-Sheng
MS
Huang
Jin-Shun
JS