title: CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap.
authors.affiliation: UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California, Riverside, CA 92521-0403, USA.
authors.forename: Vincent
authors.initials: V
authors.lastname: Lavallo
authors.forename: Yves
authors.initials: Y
authors.lastname: Canac
authors.forename: Bruno
authors.initials: B
authors.lastname: Donnadieu
authors.forename: Wolfgang W
authors.initials: WW
authors.lastname: Schoeller
authors.forename: Guy
authors.initials: G
authors.lastname: Bertrand
mesh_terms: D000588:Amines / Q000737:chemistry*; D002248:Carbon Monoxide / Q000737:chemistry*; D005030:Ethylenes / Q000737:chemistry*; D006838:Hydrocarbons / Q000138:chemical synthesis; D006844:Hydrocarbons, Cyclic / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000138:chemical synthesis; D008958:Models, Molecular; D013057:Spectrum Analysis; D013816:Thermodynamics
chemical_list: D000588:Amines; D005030:Ethylenes; D006838:Hydrocarbons; D006844:Hydrocarbons, Cyclic; D007659:Ketones; C030011:carbene; D002248:Carbon Monoxide; C008223:ketene; D008697:Methane