Two-dimensional self-assembly of 1-pyrylphosphonic acid: transfer of stacks on structured surface.
Strong hydrogen bonding and pi-pi stacking between 1-pyrylphosphonic acid (PYPA) molecules were exploited to create self-assembled two-dimensional supramolecular structures. Polycrystalline films of these laminate crystalline PYPA bilayers were easily deposited onto the solid supports through a simple spin-coating technique. Atomic force microscopy (AFM), scanning tunneling microscopy (STM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), UV-vis absorption, and fluorescence spectroscopy reveal that processing parameters, such as solvent, concentration, and surface of the substrate, are critical factors in determining the final morphology of the stacked film. Robust laminate structures could be obtained only when short alkyl chain protic solvents (methanol or ethanol) and a nonhydrophobic substrate surface were used. Polycrystalline films were formed through the nucleation and growth of PYPA molecules into laminate structures at the air/solvent interface before they land on the substrate during the spin-coating process. These films possess good mechanical properties and were easily transferred onto a SiO2/Si substrate that was patterned with Au electrodes without breaking their crystalline structures. The successful transfer of the laminate crystals allows us to probe their electrical properties through a field effect transistor device. A gating effect on the charge transport of the stacked films indicates that PYPA laminate crystal possesses p-typed semiconductor characteristics.
Yip
Hin-Lap
HL
Department of Materials Science and Engineering, University of Washington, Seattle, Washington 98195, USA.
Ma
Hong
H
Jen
Alex K-Y
AK
Dong
Jianchun
J
Parviz
Babak A
BA
D006860:Hydrogen Bonding; D018625:Microscopy, Atomic Force; D063065:Organophosphonates / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013499:Surface Properties; D014961:X-Ray Diffraction
D063065:Organophosphonates