Photodegradation of toluene over TiO(2-x)N(x) under visible light irradiation.
We report the photooxidation of toluene over nitrogen doped TiO(2) (TiO(2-x)N(x)) under visible light irradiation. The photocatalytic oxidation of toluene in air over TiO(2-x)N(x) powders was studied using diffuse reflectance Fourier transform infrared spectroscopy (DRIFTS), gas chromatography (GC), ion chromatography (IC), and gas chromatography mass spectrometry (GC-MS), focusing on the photocatalytic decomposition processes of toluene. Results obtained indicate that toluene, weakly adsorbed on the catalyst surface, is initially photooxidized to benzaldehyde which adsorbs onto the TiO(2-x)N(x) surface more strongly, leading to the formation of ring-opening products such as carboxylic acids and aldehydes. No gaseous intermediates were detected during the photooxidation. Major intermediates adsorbed at the catalyst surface were oxalic acid, (COOH)(2), acetic acid, CH(3)COOH, formic acid, HCOOH, and pyruvic acid, CH(3)COCOOH, whereas more complicated carboxylic species, including propionic acid, CH(3)CH(2)COOH, isovaleric acid, (CH(3))(2)CHCH(2)COOH, and succinic acid, (CH(2)COOH)(2), were also found in the early stage of the photooxidation. These intermediate products were gradually photodegraded to CO(2) and H(2)O under visible light irradiation.
Irokawa
Yoshihiro
Y
Toyota Central Research and Development Laboratories, Inc., Nagakute, Aichi 480-1192, Japan. y-irokawa@mosk.tytlabs.co.jp
Morikawa
Takeshi
T
Aoki
Koyu
K
Kosaka
Satoru
S
Ohwaki
Takeshi
T
Taga
Yasunori
Y
D002384:Catalysis; D008027:Light; D010084:Oxidation-Reduction; D010777:Photochemistry; D014025:Titanium / Q000737:chemistry* / Q000528:radiation effects
C009495:titanium dioxide; D014025:Titanium