title: The performance of a natural treatment system for landfill leachate with special emphasis on the fate of organic pollutants.
abstract: A natural treatment system for the treatment of leachate was studied at Moskogen landfill in southern Sweden. This facility consists of three consecutive ponds and a soil-plant (SP)-system. A test area, receiving water from the third pond with the same hydraulic load as the SP-system, was used for estimation of the latter system. Quality parameters including biochemical oxygen demand, total organic carbon, ammonium, nitrate, orthophosphate, and total suspended solids along the treatment line were determined as well as soluble metals (Cu, Cd, Zn, Cr, Ni, and Pb). In addition a thorough investigation along the treatment line has also been performed concerning volatile organic compounds and semi-volatile organic compounds. Non-polar organic compounds were investigated using gas chromatography-mass spectrometry. Quantification was based on the assumption of equal response for the compounds found in comparison with the chosen marker substances. For polar, water-soluble compounds the measurements were restricted to phenolic compounds using high-performance liquid chromatography. Several different types of organic compounds were found in the raw leachate including aromatics, benzene-sulfonamides, biphenyls, naphthalene, organic phosphates, polycyclic aromatic hydrocarbons, polychlorinated biphenyls, phenols and phthalates. The treatment system efficiently reduced organic pollutants, heavy metals, and nitrogen/phosphorous compounds. Most metals and organic compounds in the leachate were already significantly reduced to a low level in the treatment ponds and ammonium-N was efficiently transformed to nitrate-N in the SP-system.
authors.affiliation: Department of Analytical Chemistry, Lund University, SE-221 00 Lund, Sweden. Lars.Thorneby@analykem.lu.se
authors.forename: Lars
authors.initials: L
authors.lastname: Thörneby
authors.forename: Lennart
authors.initials: L
authors.lastname: Mathiasson
authors.forename: Lennart
authors.initials: L
authors.lastname: Mårtensson
authors.forename: William
authors.initials: W
authors.lastname: Hogland
mesh_terms: D002851:Chromatography, High Pressure Liquid; D008401:Gas Chromatography-Mass Spectrometry; D019216:Metals, Heavy / Q000032:analysis; D009584:Nitrogen / Q000032:analysis* / Q000737:chemistry; D009930:Organic Chemicals / Q000032:analysis* / Q000737:chemistry; D010100:Oxygen / Q000378:metabolism; D012037:Refuse Disposal / Q000379:methods*; D012989:Soil Pollutants / Q000032:analysis*; D012995:Solubility; D013548:Sweden; D014835:Volatilization; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D019216:Metals, Heavy; D009930:Organic Chemicals; D012989:Soil Pollutants; D014874:Water Pollutants, Chemical; D009584:Nitrogen; D010100:Oxygen