An Assessment of the Rubisco Inhibitor: 2-Carboxyarabinitol-1-Phosphate and d-Hamamelonic Acid 2-Phosphate Are Identical Compounds.
2-Carboxyarabinitol-1-phosphate, the nocturnal inhibitor of ribulose-1,5-bisphosphate carboxylase/oxygenase is identical with d-hamamelonic acid-2(1)-phosphate. Reasoning is based on theoretical considerations as well as on mass spectra and (1)H- and (13)C-NMR spectra of the phosphate-free compounds. d-Hamamelonic acid-2(1)-phosphate is interpreted as a metabolic derivative of d-hamamelose-2(1),5-bisphosphate which originates in the chloroplast from fructose-1,6-bisphosphate. A simple method for the synthesis of the inhibitor is suggested.
Beck
E
E
Lehrstuhl Pflanzenphysiologie, Universität Bayreuth, D 8580 Bayreuth, Federal Republic of Germany.
Scheibe
R
R
Reiner
J
J