Conformational analysis of chiral helical perfluoroalkyl chains by VCD.
Vibrational circular dichroism (VCD) technique successfully revealed the absolute configuration of the biased helix of perfluoroalkyl chains in solution with the aid of theoretical calculations, which was supported by an X-ray crystallographic study.
Monde
Kenji
K
Division of Biological Sciences, Graduate School of Science, Frontier Research Center for Post-Genomic Science and Technology, Hokkaido University, Kita-ku, Sapporo 001-0021, Japan. kmonde@glyco.sci.hokudai.ac.jp
Miura
Nobuaki
N
Hashimoto
Mai
M
Taniguchi
Tohru
T
Inabe
Tamotsu
T