Aqua(thiosulfato-kappa2O,S)[2,4,6-tri-2-pyridyl-1,3,5-triazine-kappa3N2,N1,N6]zinc(II) hemihydrate.
The title compound, [Zn(S2O3)(C18H12N6)(H2O)].0.5H2O, contains two almost identical independent monomeric moieties composed of an octahedral Zn centre coordinated by a tridentate 2,4,6-tri-2-pyridyl-1,3,5-triazine (tpt) ligand, one aqua ligand and an O,S-chelating thiosulfate anion. The structure is stabilized by a solvent water molecule. Multiple strong hydrogen bonds with additional weaker pi-pi interactions between tpt groups define a multiple column spatial organization.
Díaz de Vivar
M Enriqueta
ME
Universidad Nacional de la Patagonia, Sede Puerto Madryn, 9120 Puerto Madryn, Chubut, Argentina. undiaz@cenpat.edu.ar
Baggio
Sergio
S
Baggio
Ricardo
R