Palladium-catalyzed asymmetric hydrophosphorylation of norbornenes.
[reaction: see text] By using Josiphos ligands, palladium-catalyzed hydrophosphorylation of norbornenes with hydrogen phosphonates proceeded efficiently to give the corresponding phosphonates in high enantioselectivities.
Xu
Qing
Q
National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki, Japan.
Han
Li-Biao
LB