title: Assembly of heterometallic clusters and coordination polymers by combining Mo-S-based clusters with Mn2+.
abstract: Addition of [Mo(V)2O2S2(edt)2]2- (edt =1,2-ethanedithiolate) to acetonitrile and/or methanol solutions of MnII containing bipyridines [4,4'-trimethylenedipyridine (TDP), 4,4'-bipyridine (4,4'-bpy), 2,2'-bipyridine (2,2'-bpy)] or 15-crown-5 produces three new heterometallic cluster coordination polymers, [Mn2[Mo2O2S2(edt)2]2(TDP)3(CH3OH)2(NCMe)2].3CH3OH.0.25MeCN (1), [Mn(TDP)2(H2O)2]2+[Mn[Mo2O2S2(edt)2)2(TDP)2]]2-.6CH3OH (2), [Mn[Mo2O2S2(edt)2](TDP)2(CH3OH)(H2O)].CH3OH (3), and three new multinuclear clusters, [Mn[Mo2O2S2(edt)2](4,4'-bpy)(CH3OH)4].0.5(4,4'-bpy) (4), [Mn[Mo2O2S2(edt)2](2,2'-bpy)2].2CH3OH (5), and (NEt4)2[Mn(15-crown-5)[Mo2O2S2(edt)2]2] (6). All compounds were characterized by X-ray crystallography. The coordination mode of Mn in these compounds depends on the ligands and the crystallization conditions. Compound 2 readily converts to 1 or 3 depending on the reaction and solvent conditions. Compounds 1 and 2 were analyzed using thermogravimetric analysis combined with mass spectroscopy (TG-MS) in the temperature range 25-500 degrees C. The room-temperature magnetic moments for compounds 1-6 were determined.
authors: Chemisty, School of Natural Sciences, University of Newcastle, Newcastle upon Tyne, NE1 7RU, UK.
authors: Ping
authors: P
authors: Lin
authors: William
authors: W
authors: Clegg
authors: Ross W
authors: RW
authors: Harrington
authors: Richard A
authors: RA
authors: Henderson
authors: Ashleigh J
authors: AJ
authors: Fletcher
authors: Jon
authors: J
authors: Bell
authors: K Mark
authors: KM
authors: Thomas