title: Direct asymmetric hydroxyamination reaction catalyzed by an axially chiral secondary amine catalyst.
abstract: A direct asymmetric hydroxyamination reaction of aldehydes with nitrosobenzene was found to be catalyzed by the novel axially chiral secondary amine catalyst (S)-1d. The resulting optically enriched hydroxyamination products were readily converted to beta-amino alcohols or 1,2-diamines in one pot.
authors: Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502, Japan.
authors: Taichi
authors: T
authors: Kano
authors: Mitsuhiro
authors: M
authors: Ueda
authors: Jun
authors: J
authors: Takai
authors: Keiji
authors: K
authors: Maruoka