title: Rare Earth coordination polymers with zeolite topology constructed from 4-connected building units.
abstract: A series of rare earth coordination polymers, M(BTC)(DMF)(DMSO) (M = Tb (1), Ho (2), Er (3), Yb (4), Y (5)), with zeolite ABW topology have been synthesized under mild conditions. They exhibit the same three-dimensional (3D) architecture and crystallize in monoclinic symmetry space group P2(1)/n. Their structures are built up from inorganic and organic 4-connected building units, whose vertex symbols are 4.4.6.6.6.8. The building units link to each other to generate approximate 5 x 8 angstroms2 channels along the [100] direction. The luminescent and magnetic properties of these compounds are investigated, and the results reveal that they could be anticipated to be potential antiferromagnetic and fluorescent materials.
authors: State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun 130012, China.
authors: Xiaodan
authors: X
authors: Guo
authors: Guangshan
authors: G
authors: Zhu
authors: Zhongyue
authors: Z
authors: Li
authors: Yan
authors: Y
authors: Chen
authors: Xiaotian
authors: X
authors: Li
authors: Shilun
authors: S
authors: Qiu