Mapping electrochemiluminescence as generated at double-band microelectrodes by confocal microscopy under steady state.
A confocal microspectrometer was used to collect spatially resolved electrochemiluminescence (ECL) spectra from the annihilation reaction between Ru(bpy)3+ and Ru(bpy)3(3+), each species being generated at a platinum band microelectrode and separated by a micrometric insulating gap. The use of a confocal microspectrometer allows in situ photon detection of the ECL reaction with micrometric spatial resolution and observes the concentration distribution of the photon source in the vicinity of the interelectrode gap.
Amatore
Christian
C
Ecole Normale Supérieure, Département de Chimie, UMR CNRS-ENS-UPMC 8640 PASTEUR, 24 rue Lhomond, 75231 Paris Cedex 05, France. christian.amatore@ens.fr
Pebay
Cécile
C
Servant
Laurent
L
Sojic
Néso
N
Szunerits
Sabine
S
Thouin
Laurent
L