title: Oxaziridine-mediated amination of branched allylic sulfides: stereospecific formation of allylic amine derivatives via [2,3]-sigmatropic rearrangement.
abstract: Reaction of branched allylic sulfides with the N-Boc-oxaziridine 1 results in [2,3]-sigmatropic rearrangement of the intermediate allylic N-Boc-sulfimides with a high level of chirality transfer. The first example of formation of a quaternary stereocenter using this transformation is reported.
authors: Department of Chemistry, Imperial College London, South Kensington, London SW7 2AZ, UK. a.armstrong@imperial.ac.uk
authors: Alan
authors: A
authors: Armstrong
authors: Lee
authors: L
authors: Challinor
authors: Richard S
authors: RS
authors: Cooke
authors: Jennifer H
authors: JH
authors: Moir
authors: Nigel R
authors: NR
authors: Treweeke