Direct C-allylation of aryl-alkyl/glycosyl carbinols: facile synthesis of C-linked carbo-beta2-/gamma2-/delta2-amino acids.
A facile ZrCl4-catalyzed direct allylation of the p-methoxyphenyl-alkyl/glycosyl carbinols at room temperature, and the conversion of the derived aryl-glycosyl-alkenes into hitherto unknown C-linked carbo-beta2-/gamma2-/delta2-amino acids is reported.
Sharma
Gangavaram V M
GV
D-211, Discovery Laboratory, Organic Chemistry Division III, Indian Institute of Chemical Technology, Hyderabad 500 007, India. sharmagvm@yahoo.com
Reddy
Katta Laxmi
KL
Lakshmi
P Sree
PS
Ravi
R
R
Kunwar
Ajit C
AC