Experimental and theoretical investigations of IR spectra and electronic structures of the U(OH)2, UO2(OH), and UO2(OH)2 molecules.
Reactions of laser-ablated U atoms and H2O2 molecules produce UO2, H2UO2, and UO2(OH)2 as major products and U(OH)2 and HU(O)OH as minor products. Complementary information is obtained from similar reactions of U atoms with D2O2, with H2 + O2 mixtures, and with H2O in excess Ar. Through extensive relativistic density functional theory calculations, we have determined the geometry structures and ground states of these U species with a variety of oxidation states U(II), U(IV), U(V), and U(VI). The calculated vibrational frequencies, IR intensities, and isotopic frequency ratios are in good agreement with the experimental values, thus supporting assignments of the observed matrix IR spectra. We propose that the reactions proceed by forming an energized [U(OH)4] intermediate from reactions of the excited U atom with two H2O2 molecules. Because of the special stability of the U(VI) oxidation state, this intermediate decomposes to the UO2(OH)2 molecule, which reveals a distinctive difference between the chemistries of U and Th, where the major product in analogous Th reactions is the tetrahedral Th(OH)4 molecule owing to the stable Th(IV) oxidation state.
Wang
Xuefeng
X
Department of Chemistry, University of Virginia, McCormick Road, P.O. Box 400319, Charlottesville, Virginia 22904-4319, USA.
Andrews
Lester
L
Li
Jun
J