Porous coordination polymers with zeolite topologies constructed from 4-connected building units.
Two novel 3D coordination polymers, Cd(CTC)(H2O).(H2PIP)(0.5)(H2O) (1) with zeolite ABW topology and Cd(CTC).(HIPA) (2) with zeolite BCT topology, have been synthesized by constructing inorganic and organic 4-connected building units and using the organic bases as templates, and the frameworks of and not only expand the original structures of zeolites ABW and BCT, but also exhibit significant advantages over them in terms of thermal stability, ion exchange and adsorption.
Fang
Qian-Rong
QR
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130012, China.
Zhu
Guang-Shan
GS
Xue
Ming
M
Sun
Jin-Yu
JY
Qiu
Shi-Lun
SL