title: Acyl migration during debenzylation of 1,3-di-O-benzyl-2-O-acylglycerols.
abstract: In investigating the preparation of 2-acylglycerol by debenzylation of 1,3-di-O-benzyl-2-O-acylglycerol, twelve 1,3-di-O-benzyl-2-O-acylglycerols were synthesized. 2-O-Acyl moieties with one or more protons at the carbon atom adjacent to carbonyl group were found to migrate from C-2 to C-1 of the glycerol moiety during hydrogenation under Pd/C at room temperature.
authors.affiliation: Chengdu Institute of Biology of the Chinese Academy of Sciences, Chengdu 610041, China.
authors.forename: Lijian
authors.initials: L
authors.lastname: Yue
authors.forename: Chenggang
authors.initials: C
authors.lastname: Zhang
authors.forename: Guolin
authors.initials: G
authors.lastname: Zhang
mesh_terms: D004075:Diglycerides / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D050178:Monoglycerides / Q000737:chemistry
chemical_list: D004075:Diglycerides; D050178:Monoglycerides