Iron-catalyzed imination of sulfoxides and sulfides.
[reaction: see text] The Fe(III)-catalyzed imination of sulfoxides and sulfides with sulfonylamides in the presence of iodinanes has been investigated. The best results were obtained when Fe(acac)(3) was used as a catalyst in combination with iodosylbenzene, providing an effective alternative (stereospecific) access to sulfoximines and sulfilimines.
Mancheño
Olga García
OG
Institute of Organic Chemistry, RWTH Aachen University, Germany.
Bolm
Carsten
C