Base-catalysed asymmetric hydroamination/cyclisation of aminoalkenes utilising a dimeric chiral diamidobinaphthyl dilithium salt.
A dimeric proline derived diamidobinaphthyl dilithium salt represents the first example of a chiral main group metal based catalyst for asymmetric hydroamination/cyclisation reactions of aminoalkenes.
Martínez
Patricia Horrillo
PH
Institut für Organische Chemie, Friedrich-Alexander Universität Erlangen-Nürnberg, Henkestr. 42, D-91054, Erlangen, Germany.
Hultzsch
Kai C
KC
Hampel
Frank
F
D000475:Alkenes / Q000737:chemistry*; D000586:Amination; D002384:Catalysis; D003500:Cyclization; D019281:Dimerization; D008094:Lithium / Q000737:chemistry*; D008956:Models, Chemical; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D011392:Proline / Q000737:chemistry*
D000475:Alkenes; D009942:Organometallic Compounds; D011392:Proline; D008094:Lithium