Highly stereoselective synthesis of TMS-, alkyl-, or aryl-substituted cis-[3]cumulenols via alpha-alkynylated zirconacyclopentenes.
Liu
Yuanhong
Y
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, P.R. China. yhliu@mail.sioc.ac.cn
Gao
Hongjun
H
Zhou
Shaolin
S
D000447:Aldehydes / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D002070:Butadienes / Q000737:chemistry*; D003517:Cyclopentanes / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D013237:Stereoisomerism; D015040:Zirconium / Q000737:chemistry*
D000447:Aldehydes; D000480:Alkynes; D002070:Butadienes; D003517:Cyclopentanes; D007659:Ketones; D009942:Organometallic Compounds; D015040:Zirconium