Characterisation of the thermally accessible spin triplet state in dimers of the 7pi ClCNSSS+* in the solid state.
[ClCNSSS]2(2+) is the first example of a thiazyl radical dimer where population of a thermally excited spin triplet state has been detected, as is proved by VT-powder and single-crystal EPR spectroscopy.
Cameron
T Stanley
TS
Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, B3H 4J3, Canada.
Decken
Andreas
A
Kowalczyk
Radoslaw M
RM
McInnes
Eric J L
EJ
Passmore
Jack
J
Rawson
Jeremy M
JM
Shuvaev
Konstantin V
KV
Thompson
Laurence K
LK