title: Photochemical ring-opening and intramolecular hydrogen shift reactions in sulfur analogues of alpha-pyrone.
abstract: A combined matrix isolation FTIR and theoretical DFT(B3LYP)/6-311++G(d,p) study of the photochemistry of sulfur analogues of alpha-pyrone [2H-thiopyran-2-one (TP) and 2H-pyran-2-thione (PT)] was carried out. The vibrational spectra of monomers of the compounds isolated in low-temperature argon matrixes were studied experimentally and assigned completely on the basis of theoretical calculations. UV irradiation (lambda > 337 nm) of the studied compounds isolated in low-temperature matrixes results mainly in the ring-opening reaction by means of the cleavage of the alpha-bond. Other photoprocesses, not involving the alpha-bond-cleavage step (such as generation of Dewar valence isomer), correspond to the minor reaction channels in both studied compounds. The ring-opening photoreaction in PT represents the first reported case of an alpha-bond cleavage in a compound with a C=S group attached to a six-membered ring, in which the internal strain practically does not exist, whereas the corresponding reaction in TP (a cleavage of a C-S bond in the alpha position with respect to a carbonyl group) is now reported for the first time. Following the ring-opening reactions, isomerization processes and intramolecular hydrogen shift reactions were observed, enabling production of TP from PT and vice versa. A detailed study of such processes was undertaken, and kinetical and mechanistical data are presented and discussed.
authors.affiliation: Department of Chemistry, University of Coimbra, P-3004-535 Coimbra, Portugal.
authors.forename: S
authors.initials: S
authors.lastname: Breda
authors.forename: I
authors.initials: I
authors.lastname: Reva
authors.forename: L
authors.initials: L
authors.lastname: Lapinski
authors.forename: M L S
authors.initials: ML
authors.lastname: Cristiano
authors.forename: L
authors.initials: L
authors.lastname: Frija
authors.forename: R
authors.initials: R
authors.lastname: Fausto