Metal to insulator transition in films of molecularly linked gold nanoparticles.
We report a metal to insulator transition (MIT) in disordered films of molecularly linked gold nanoparticles (NPs). As the number of carbons (n) of alkanedithiol linker molecules (C(n)S2) is varied, resistance (R) at low temperature (T = 2 K) and at 200 K, as well as trends in R vs T data at intermediate temperatures, all point to an MIT occurring at n = 5. We describe these results in a context of a Mott-Hubbard MIT. We find that all insulating samples (n > or = 5) exhibit a universal scaling behavior R approximately exp[(T0/T)nu] with nu = 0.65, and all metallic samples (n < or = 5) exhibit weaker R-T dependencies than bulk gold. We discuss these observations in terms of competitive thermally activated processes and strong, T-independent elastic scattering, respectively.
Zabet-Khosousi
Amir
A
Department of Chemistry, University of Toronto, Toronto, Ontario, M5S 3H6, Canada.
Trudeau
Paul-Emile
PE
Suganuma
Yoshinori
Y
Dhirani
Al-Amin
AA
Statt
Bryan
B