title: A reverse cation-exchange route to hollow PbSe nanospheres evolving from Se/Ag2Se core/shell colloids.
abstract: A reverse cation-exchange approach for the synthesis of hollow PbSe nanospheres is successfully established. This route involves a new strategy of a stepwise, in-situ template-based evolution from spherical amorphous Se colloids to Se/Ag(2)Se core/shell colloids, then to hollow PbSe nanospheres. Se colloids are prepared as the initial product by utilizing the chelation of ethylenediamine to bulk Se. They are converted into Se/Ag(2)Se core/shell colloids through the reaction with Ag(+) in ethylene glycol. During the conversion from Ag(2)Se shell to PbSe shell, a small amount of tributylphosphine is crucial as the capping agent. The characterization results, including XRD, SEM, TEM, HRTEM, and EDX, reveal that hollow PbSe nanospheres with polycrystalline and cubic structure are prepared. The corresponding optical band gap is calculated to be 0.56 eV. This conformation is potentially beneficial to the improvement concerning the applications of PbSe nanostructures.
authors.affiliation: State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, PR China.
authors.forename: Wei
authors.initials: W
authors.lastname: Zhu
authors.forename: Wenzhong
authors.initials: W
authors.lastname: Wang
authors.forename: Jianlin
authors.initials: J
authors.lastname: Shi