Validity of the Franck-Condon principle in the optical spectroscopy: optical conductivity of the Fröhlich polaron.
The optical absorption of the Fröhlich polaron model is obtained by an approximation-free diagrammatic Monte Carlo method and compared with two new approximate approaches that treat lattice relaxation effects in different ways. We show that: (i) a strong coupling expansion, based on the Franck-Condon principle, well describes the optical conductivity for large coupling strengths (alpha > 10); (ii) a memory function formalism with phonon broadened levels reproduces the optical response for weak coupling strengths (alpha < 6) taking the dynamic lattice relaxation into account. In the coupling regime 6 < alpha < 10, the optical conductivity is a rapidly changing superposition of both Franck-Condon and dynamic contributions.
De Filippis
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Coherentia CNR-INFM and Dipartimento di Scienze Fisiche, Università di Napoli Federico II, I-80126 Napoli, Italy.
Cataudella
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Mishchenko
A S
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Perroni
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Devreese
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