Low pressure Pd-catalyzed carbonylation in an ionic liquid using a multiphase microflow system.
A low pressure microflow system was developed for palladium-catalyzed multiphase carbonylation reactions in an ionic liquid. The microflow system resulted in superior selectivity and higher yields in carbonylative Sonogashira coupling and amidation reactions of aryl iodides compared to the conventional batch system.
Rahman
Md Taifur
MT
Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka, 599-8531, Japan.
Fukuyama
Takahide
T
Kamata
Naoya
N
Sato
Masaaki
M
Ryu
Ilhyong
I
D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D008832:Microchemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D011312:Pressure
D000577:Amides; D006847:Hydrocarbons, Iodinated; D052578:Ionic Liquids; D010165:Palladium