title: An azido-metal-isonicotinate complex showing long-range ordered ferromagnetic interaction: synthesis, structure and magnetic properties.
abstract: A new 3D Cu(II) complex [Cu1.5(N3)2(isonicotinate)]n [1], which features two types of bridging modes for azide (mu(1,1) and the rare asymmetric mu(1,1,3)) where the three bonds of the mu(1,1,3)-N3(-) group to Cu exhibit three different distances, has been synthesized and characterized, and magnetic measurements indicate that [1] experiences long-range ferromagnetic ordering at approximately 6 K.
authors.affiliation: Department of Chemistry, Nankai University, Tianjin, 300071, China.
authors.forename: Yong-Fei
authors.initials: YF
authors.lastname: Zeng
authors.forename: Fu-Chen
authors.initials: FC
authors.lastname: Liu
authors.forename: Jiong-Peng
authors.initials: JP
authors.lastname: Zhao
authors.forename: Shuang
authors.initials: S
authors.lastname: Cai
authors.forename: Xian-He
authors.initials: XH
authors.lastname: Bu
authors.forename: Joan
authors.initials: J
authors.lastname: Ribas