Corrosion behavior of pure titanium and titanium alloys in various concentrations of Acidulated Phosphate Fluoride (APF) solutions.
The corrosion behaviors of Ti, Ti-6Al-7Nb and Ti-6Al-4V alloys, and an experimentally produced Ti-0.5Pt alloy in 0.05% to 2.0% concentrations of Acidulated Phosphate Fluoride (APF) solutions (corresponding to 226 to 9,050 ppm fluoride at pH 3.5 or 3.6) were examined. While the corrosion of Ti, Ti-6Al-7Nb and Ti-6Al-4V alloys might occur easily even in a diluted 0.05% APF solution, dissolution of Ti from the Ti-0.5Pt alloy was observed only in test solutions with APF concentration exceeding 0.2%. When Ti-6Al-7Nb and Ti-6Al-4V alloys were immersed in 2.0% APF solution, their surfaces were entirely covered by compact corrosion products of Na3TiF6 due to severe corrosion. As a result, Ti dissolution was prevented and the amount of Ti dissolved decreased. However, since Ti was covered by porous, large-sized corrosion products of Na3TiF6 and that Ti-0.5Pt alloy was not covered with any corrosion product, the amount of Ti dissolved increased in the 2.0% APF solution.
Matono
Yoshinari
Y
Department of Biomaterials, Faculty of Dental Science, Kyushu University, Fukuoka, Japan.
Nakagawa
Masaharu
M
Matsuya
Shigeki
S
Ishikawa
Kunio
K
Terada
Yoshihiro
Y
D000149:Acidulated Phosphate Fluoride / Q000009:adverse effects*; D000497:Alloys; D000704:Analysis of Variance; D002327:Cariostatic Agents / Q000009:adverse effects*; D003343:Corrosion; D014025:Titanium / Q000737:chemistry*
D000497:Alloys; D002327:Cariostatic Agents; C070282:Ti-6Al-7Nb alloy; C031462:titanium alloy (TiAl6V4); D000149:Acidulated Phosphate Fluoride; D014025:Titanium