Star polymers in shear flow.
Linear and star polymers in solution are studied in the presence of shear flow. The solvent is described by a particle-based mesoscopic simulation technique, which accounts for hydrodynamic interactions. The scaling properties of the average gyration tensor, the orientation angle, and the rotation frequency are investigated for various arm lengths and arm numbers. With increasing functionality f, star polymers exhibit a crossover in their flow properties from those of linear polymers to a novel behavior, which resembles the tank-treading motion of elastic capsules.
Ripoll
M
M
Institut für Festkörperforschung, Forschungszentrum Jülich, D-52425 Jülich, Germany. m.ripoll@fz-juelich.de
Winkler
R G
RG
Gompper
G
G
D004548:Elasticity; D044085:Microfluidics; D008962:Models, Theoretical; D011108:Polymers / Q000737:chemistry*; D012212:Rheology; D033081:Shear Strength; D014783:Viscosity
D011108:Polymers