Copolymerisation of Pt-carbonyl clusters with Lewis acids: synthesis and crystal structure of the molecular [Cd2Cl4[Pt9(CO)18]2-]infinity 1-D polymer.
Reaction of [NBu4]2[Pt9(CO)18] with the soft Lewis acid CdCl2 gives the [Pt9(CO)18(micro3-CdCl2)2]2- adduct, which self-assembles upon crystallization into a 1-D [[Pt9(CO)18(micro3-CdCl2)2]2-]infinity polymer via the formation of chloride bridges.
Femoni
Cristina
C
Dipartimento di Chimica Fisica ed Inorganica, Università di Bologna, viale Risorgimento 4, 40136 Bologna, Italy.
Kaswalder
Francesco
F
Iapalucci
Maria Carmela
MC
Longoni
Giuliano
G
Zacchini
Stefano
S