A second metalloid Ga18 cluster and its topological similarity to the high-pressure Ga-II modification.
The topology of many modifications of elemental gallium is reflected in the large variety of metalloid Ga clusters that have been isolated as intermediates on the way from the metastable molecular GaX species (X=Cl, Br, I) by means of disproportionation to the bulk metal. Herein, we report the synthesis and characterization of the first metalloid cluster anion [Ga(18)(PtBu(2))(10)](3-) with the singular core topology that resembles the gallium high-pressure modification Ga-II. The stabilization of the cluster anion through ion-pair contacts with a chainlike "Li(4)Br(2) backbone" is discussed. Furthermore, the compound is discussed in context of the other metalloid clusters Ga(18)R(8) and Ga(22)R(8) (R=SitBu(3)) and their structural relation to the elemental modifications Ga-III and beta-Ga, respectively.
Steiner
Jochen
J
Institute of Inorganic Chemistry, University of Karlsruhe (TH), Engesserstrasse 15, Geb. 30.45, 76128 Karlsruhe, Germany.
Schnöckel
Hansgeorg
H