title: Chlorination kinetics of glyphosate and its by-products: modeling approach.
abstract: Chlorination reactions of glyphosate, glycine, and sodium cyanate were conducted in well-agitated reactors to generate experimental kinetic measurements for the simulation of chlorination kinetics under the conditions of industrial water purification plants. The contribution of different by-products to the overall degradation of glyphosate during chlorination has been identified. The kinetic rate constants for the chlorination of glyphosate and its main degradation products were either obtained by calculation according to experimental data or taken from published literature. The fit of the kinetic constants with experimental data allowed us to predict consistently the concentration of the majority of the transitory and terminal chlorination products identified in the course of the glyphosate chlorination process. The simulation results conducted at varying aqueous chlorine/glyphosate molar ratios have shown that glyphosate is expected to degrade in fraction of a second under industrial aqueous chlorination conditions. Glyphosate chlorination products are not stable under the conditions of drinking water chlorination and are degraded to small molecules common to the degradation of amino acids and other naturally occurring substances in raw water. The kinetic studies of the chlorination reaction of glyphosate, together with calculations based on kinetic modeling in conditions close to those at real water treatment plants, confirm the reaction mechanism that we have previously suggested for glyphosate chlorination.
authors.affiliation: Laboratoire Science Chimiques de Rennes UMR CNRS 6226, ENSCR, UR1, Equipe Chimie et Ingénierie des Procédés, Ecole Nationale Supérieure de Chimie de Rennes, Avenue du Général Leclerc, 35700 Rennes, France. Stephan.Bosillon@ensc-rennes.fr
authors.forename: Stephan
authors.initials: S
authors.lastname: Brosillon
authors.forename: Dominique
authors.initials: D
authors.lastname: Wolbert
authors.forename: Marguerite
authors.initials: M
authors.lastname: Lemasle
authors.forename: Pascal
authors.initials: P
authors.lastname: Roche
authors.forename: Akbar
authors.initials: A
authors.lastname: Mehrsheikh
mesh_terms: D002713:Chlorine / Q000737:chemistry*; D004203:Disinfection; D005998:Glycine / Q000031:analogs & derivatives* / Q000737:chemistry / Q000302:isolation & purification / Q000378:metabolism; D006540:Herbicides / Q000302:isolation & purification; D007700:Kinetics; D008956:Models, Chemical; D014865:Waste Disposal, Fluid / Q000379:methods*; D014876:Water Pollution / Q000517:prevention & control; D018508:Water Purification / Q000379:methods*; D014881:Water Supply; D000097797:Glyphosate
chemical_list: D002713:Chlorine; D005998:Glycine; D006540:Herbicides; D000097797:Glyphosate