title: Determination of cooling rates in a quadrupole ion trap.
abstract: Collisional cooling rates of infrared excited ions are measured in a quadrupole ion trap (QIT) mass spectrometer at different combinations of temperature and pressure. Measurements are carried out by monitoring fragmentation efficiency of leucine enkephalin as a function of irradiation time by an infrared laser after a short excitation and incrementally increasing cooling periods. Cooling rates are observed to be directly related to bath gas pressure and inversely related to bath gas temperature. The cooling rate at typical ion trap operating pressure (1 mTorr) and temperature (room T) is faster than can be measured. At elevated temperature and the lowest pressure used for the studies, the rate of collisional cooling becomes negligible compared to the rate of radiative cooling.
authors.affiliation: Kenan Laboratory, Department of Chemistry, University of North Carolina, 27599-3290, Chapel Hill, NC, USA.
authors.forename: David M
authors.initials: DM
authors.lastname: Black
authors.affiliation: Kenan Laboratory, Department of Chemistry, University of North Carolina, 27599-3290, Chapel Hill, NC, USA.
authors.forename: Anne H
authors.initials: AH
authors.lastname: Payne
authors.affiliation: Kenan Laboratory, Department of Chemistry, University of North Carolina, 27599-3290, Chapel Hill, NC, USA. glish@unc.edu.
authors.forename: Gary L
authors.initials: GL
authors.lastname: Glish
mesh_terms: D000465:Algorithms; D003198:Computer Simulation; D004743:Enkephalin, Leucine / Q000737:chemistry*; D008956:Models, Chemical; D021241:Spectrometry, Mass, Electrospray Ionization / Q000379:methods*; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods*; D013696:Temperature
chemical_list: D004743:Enkephalin, Leucine