Flavin-based [2]rotaxanes.
[reaction: see text] We report the synthesis of flavin-stoppered hydrogen bonded [2]rotaxanes 1 and 2. We also report the electrochemically controllable properties of these systems in solution, and for derivative 2, as an electropolymerized thin film.
Cooke
Graeme
G
WestCHEM, Department of Chemistry, Joseph Black Building, University of Glasgow, UK. graemec@chem.gla.ac.uk
Garety
James F
JF
Jordan
Brian
B
Kryvokhyzha
Nadiya
N
Parkin
Andy
A
Rabani
Gouher
G
Rotello
Vincent M
VM
D018360:Crystallography, X-Ray; D004563:Electrochemistry / Q000379:methods; D005415:Flavins / Q000737:chemistry*; D006860:Hydrogen Bonding; D008968:Molecular Conformation; D015394:Molecular Structure; D043862:Rotaxanes / Q000138:chemical synthesis* / Q000737:chemistry*
D005415:Flavins; D043862:Rotaxanes