Chiral diphosphites and diphosphoramidites as cheap and efficient ligands in Rh-catalyzed asymmetric olefin hydrogenation.
Chiral diphosphites and diphosphoramidites derived from BINOL or diphenylprolinol are efficient ligands in asymmetric Rh-catalyzed olefin hydrogenation, provided the proper achiral backbone is chosen.
Reetz
Manfred T
MT
Max-Planck-Institut für Kohlenforschung, D-45470, Mülheim/Ruhr, Germany. reetz@mpi-muelheim.mpg.de
Mehler
Gerlinde
G
Bondarev
Oleg
O