Highly diastereoselective amplification from a dynamic combinatorial library of macrocyclic oligoimines.
Cadmium promoted diastereoselective amplification of a single member from a dynamic combinatorial library of stereoisomeric oligoimines of different sizes allows the efficient preparation of a new macrocyclic polyamine.
González-Alvarez
Almudena
A
Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, Julián Clavería, E-33071, (Oviedo), Spain.
Alfonso
Ignacio
I
Gotor
Vicente
V
D002104:Cadmium / Q000737:chemistry; D020650:Combinatorial Chemistry Techniques; D003500:Cyclization; D007097:Imines / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000737:chemistry*; D008956:Models, Chemical; D008958:Models, Molecular; D015394:Molecular Structure; D019151:Peptide Library; D011073:Polyamines / Q000737:chemistry; D013237:Stereoisomerism
D007097:Imines; D047028:Macrocyclic Compounds; D019151:Peptide Library; D011073:Polyamines; D002104:Cadmium