title: Regulating the stability of 2D crystal structures using an oxidation state-dependent molecular conformation.
abstract: The oxidation state of the phenol-substituted porphyrin TDtBHPP is coupled with its structure so that its 2-electron oxidation leads to a coplanarization of the molecule and a substantial stabilization of its surface self-assembled structures adsorbed at metal substrates.
authors.affiliation: International Center for Young Scientists, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan. Jonathan.Hill@nims.go.jp
authors.forename: Jonathan P
authors.initials: JP
authors.lastname: Hill
authors.forename: Yutaka
authors.initials: Y
authors.lastname: Wakayama
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Schmitt
authors.forename: Tohru
authors.initials: T
authors.lastname: Tsuruoka
authors.forename: Takashi
authors.initials: T
authors.lastname: Nakanishi
authors.forename: Melvin L
authors.initials: ML
authors.lastname: Zandler
authors.forename: Amy L
authors.initials: AL
authors.lastname: McCarty
authors.forename: Francis
authors.initials: F
authors.lastname: D'Souza
authors.forename: Lionel R
authors.initials: LR
authors.lastname: Milgrom
authors.forename: Katsuhiko
authors.initials: K
authors.lastname: Ariga
mesh_terms: D003460:Crystallization; D018360:Crystallography, X-Ray; D004583:Electrons; D008670:Metals / Q000737:chemistry; D016252:Microscopy, Scanning Tunneling; D008958:Models, Molecular; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D010636:Phenols / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D013499:Surface Properties
chemical_list: D008670:Metals; D010636:Phenols; D011166:Porphyrins; C518922:tetrakis(3,5-di-t-butyl-4-hydroxyphenyl)porphyrin