title: In situ wiring of single molecules into an electrical circuit via electrochemical distance tunneling spectroscopy.
abstract: The electrical conductance of single n-alkanethiol and alpha,omega-alkanedithiol molecules was measured via in situ distance tunneling spectroscopy in aqueous 0.1 M KOH solution. The statistical analysis of the conductance values show that the alpha,omega-alkanedithiol molecule trapped in the STM break junction can adopt two distinct geometries that result in "lower" and "higher" conductivity values. In contrast, n-alkanethiol molecules trapped in the junction show only a single conductivity value characteristic for a particular molecule. Furthermore, the "lower" conductivity value determined for alpha,omega-alkanedithiol is virtually identical to the electrical conductivity of the n-alkanethiol containing the same number of atoms in the backbone. Moreover when the STM tip is polarized to electrochemical potential preventing a chemical reaction between the terminal -SH group and Au, only "lower" conductivity values are observed for alpha,omega-alkaneditiols.
authors.affiliation: Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Blvd., Long Beach, California 90840, USA.
authors.forename: Emil
authors.initials: E
authors.lastname: Wierzbinski
authors.forename: Krzysztof
authors.initials: K
authors.lastname: Slowinski
mesh_terms: D004553:Electric Conductivity; D004563:Electrochemistry / Q000379:methods; D006878:Hydroxides / Q000737:chemistry*; D017680:Potassium Compounds / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013057:Spectrum Analysis; D013438:Sulfhydryl Compounds / Q000032:analysis*
chemical_list: D006878:Hydroxides; D017680:Potassium Compounds; D013438:Sulfhydryl Compounds; C029943:potassium hydroxide