The "triamino-analogue" of methyl allocholate; a rigid, functionalised scaffold for supramolecular chemistry.
Cholic acid has been converted into triamine with the all-trans polycyclic allocholanoyl skeleton and co-directed, axial amino groups; the potential of this system as a scaffold is illustrated by conversion to a preorganised anion receptor.
Bhattarai
Khadga M
KM
School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK BS8 1TS.
del Amo
Vicente
V
Magro
Germinal
G
Sisson
Adam L
AL
Joos
Jean-Baptiste
JB
Charmant
Jonathan P H
JP
Kantacha
Anob
A
Davis
Anthony P
AP
D055598:Chemical Phenomena; D002621:Chemistry; D002793:Cholic Acids / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D046911:Macromolecular Substances / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation
D002793:Cholic Acids; D046911:Macromolecular Substances; C518924:methyl allocholate