Synthesis of Im3[Re3mu3-S)(mu-S3)Br9]Br (Im = 1-ethyl-3-methylimidazolium) by means of an ionic liquid.
Reaction of [Re3(mu3-S)(mu-S2)3Cl6]Cl with an ionic liquid composed of 1-ethyl-3-methylimidazolium bromide (ImBr) and aluminum bromide (AlBr3) formed a new trinuclear rhenium sulfide cluster compound Im3[Re3(mu3-S)(mu-S)3Br9]Br with nine terminal bromo ligands.
Sakamoto
Hideshi
H
Department of Chemistry, Faculty of Science, Kanagawa University, Hiratsuka, 259-1293 Kanagawa, Japan.
Watanabe
Yusuke
Y
Saito
Taro
T