Redox activation of a B-H bond: a new route to metallaboratrane complexes.
Oxidative activation of a B-H bond of a coordinated scorpionate ligand provides an unprecedented route to rhodaboratranes.
Blagg
Robin J
RJ
School of Chemistry, University of Bristol, Bristol, UK BS8 1TS.
Charmant
Jonathan P H
JP
Connelly
Neil G
NG
Haddow
Mairi F
MF
Orpen
A Guy
AG
D001880:Boranes / Q000737:chemistry*; D001895:Boron / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006859:Hydrogen / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D012238:Rhodium / Q000737:chemistry*
D001880:Boranes; D008024:Ligands; D009942:Organometallic Compounds; D006859:Hydrogen; D012238:Rhodium; D001895:Boron