title: Redox activation of a B-H bond: a new route to metallaboratrane complexes.
abstract: Oxidative activation of a B-H bond of a coordinated scorpionate ligand provides an unprecedented route to rhodaboratranes.
authors.affiliation: School of Chemistry, University of Bristol, Bristol, UK BS8 1TS.
authors.forename: Robin J
authors.initials: RJ
authors.lastname: Blagg
authors.forename: Jonathan P H
authors.initials: JP
authors.lastname: Charmant
authors.forename: Neil G
authors.initials: NG
authors.lastname: Connelly
authors.forename: Mairi F
authors.initials: MF
authors.lastname: Haddow
authors.forename: A Guy
authors.initials: AG
authors.lastname: Orpen
mesh_terms: D001880:Boranes / Q000737:chemistry*; D001895:Boron / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006859:Hydrogen / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D012238:Rhodium / Q000737:chemistry*
chemical_list: D001880:Boranes; D008024:Ligands; D009942:Organometallic Compounds; D006859:Hydrogen; D012238:Rhodium; D001895:Boron