title: In situ observation of place exchange reactions of gold nanoparticles. Correlation of monolayer structure and stability.
abstract: Place exchange reactions were studied using dye displacement: subtle changes in ligand structure greatly affected both the rate of displacement and the stability of the monolayer.
authors.affiliation: Department of Chemistry, University of Massachusetts, Amherst, Massachusetts 01003, USA.
authors.forename: Rui
authors.initials: R
authors.lastname: Hong
authors.forename: Joseph M
authors.initials: JM
authors.lastname: Fernández
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Nakade
authors.forename: Rochelle
authors.initials: R
authors.lastname: Arvizo
authors.forename: Todd
authors.initials: T
authors.lastname: Emrick
authors.forename: Vincent M
authors.initials: VM
authors.lastname: Rotello
mesh_terms: D001896:Boron Compounds / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D007700:Kinetics; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008567:Membranes, Artificial; D053758:Nanoparticles / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013438:Sulfhydryl Compounds / Q000737:chemistry; D013499:Surface Properties; D013696:Temperature; D013997:Time Factors
chemical_list: C095489:4,4-difluoro-4-bora-3a,4a-diaza-s-indacene; D001896:Boron Compounds; D008024:Ligands; D008567:Membranes, Artificial; D013438:Sulfhydryl Compounds; D006046:Gold