Enantioselective rh-catalyzed arylation of N-tosylarylimines with arylboronic acids.
The asymmetric arylation of N-tosylarylimines with arylboronic acids was realized by using rhodium/(S)-ShiP as catalyst. The reaction proceeded in aqueous toluene to give diarylmethylamines in good yields with up to 96% ee. [reaction: see text]
Duan
Hai-Feng
HF
State Key Laboratory and Institute of Elemento-organic Chemistry, Nankai University, Tianjin 300071, China.
Jia
Yi-Xia
YX
Wang
Li-Xin
LX
Zhou
Qi-Lin
QL