Swelling and mechanical properties of glycol chitosan/poly(vinyl alcohol) IPN-type superporous hydrogels.
Glycol chitosan/poly(vinyl alcohol) interpenetrating polymer network type superporous hydrogels were prepared using a gas foaming/freeze-drying method. The effect of the molecular weight of the strengthener, poly(vinyl alcohol) (PVA), on the swelling and mechanical behavior of the superporous hydrogels was investigated. The introduction of a small amount of high molecular weight PVA significantly enhanced the mechanical strength but slightly reduced the swelling capacity. The freezing/thawing (F/T) drying process had a significant effect on the physical properties of the glycol chitosan/PVA superporous hydrogels, because hydrogen bonds were formed between the PVA molecules as a result of the number of F/T cycles. The swelling ratio decreased but the mechanical strength increased with increasing freezing time. However, this effect was not as strong as the number of F/T cycles. The differential scanning calorimetry was used to examine how the thermal behavior associated with the hydrogen bond-induced crystalline structure was affected by the F/T process.
Park
Hyojin
H
Department of Chemical Engineering, Polymer Technology Institute, Sungkyunkwan University, Suwon, Korea.
Kim
Dukjoon
D
D002152:Calorimetry, Differential Scanning; D048271:Chitosan; D005615:Freezing; D020100:Hydrogels; D008422:Materials Testing; D008970:Molecular Weight; D011142:Polyvinyl Alcohol
D020100:Hydrogels; D011142:Polyvinyl Alcohol; D048271:Chitosan