One-dimensional chiral self-assembly of pyrene derivatives based on dendritic oligopeptides.
Supramolecular chiral columnar liquid crystals have been formed through one-dimensional self-assembly of pyrene-containing oligopeptides. Supramolecular chirality is further tuned by cooperation of intermolecular hydrogen bonding and electron donor-acceptor interactions. [reaction: see text]
Kamikawa
Yuko
Y
Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Kato
Takashi
T
D006860:Hydrogen Bonding; D008968:Molecular Conformation; D015394:Molecular Structure; D009842:Oligopeptides / Q000737:chemistry*; D011099:Polyglutamic Acid / Q000031:analogs & derivatives* / Q000737:chemistry*; D011721:Pyrenes / Q000737:chemistry*
D009842:Oligopeptides; D011721:Pyrenes; D011099:Polyglutamic Acid