The effect of microwave irradiation on Mo(VI) catalyzed transformations of reducing saccharides.
Efficient microwave-assisted Mo(VI)-catalyzed transformations of the 10 most common aldoses are described. Both pentoses and hexoses were converted to the corresponding epimers in considerably shorter reaction times. The yields were comparable, or better compared to conventional synthetic methods.
Hricovíniová
Zuzana
Z
Institute of Chemistry, Slovak Academy of Sciences, SK-845 38 Bratislava, Slovakia. chemhric@savba.sk
D002384:Catalysis / Q000528:radiation effects; D006601:Hexoses / Q000737:chemistry; D007536:Isomerism; D008872:Microwaves; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry*; D009005:Monosaccharides / Q000737:chemistry*; D010084:Oxidation-Reduction / Q000528:radiation effects; D010429:Pentoses / Q000737:chemistry
D006601:Hexoses; D009005:Monosaccharides; D010429:Pentoses; D008982:Molybdenum