Influence of pressure on the electric-field-induced phase transitions in liquid crystals.
Within the framework of Landau-de-Gennes formulation, we analyse the effect of pressure on electric-field-induced phase transitions in a liquid crystal which shows spontaneously an isotropic-smectic A transition. Inferring from the experimental pressure dependences on the layer spacing in smectic A phase, as well as the nematic-smectic A metastable temperature T*(AN), we incorporated the pressure dependence in the free energy through (the surface energy term) and the coupling between the quadrupolar nematic ordering Q(ij) and the smectic order parameter psi. From the S-T phase diagram, we found that the stability of field-induced nematic phase increases with pressure, whereas the discontinuity of the transition decreases. Also, the region where paranematic phase transits directly to smectic A phase increases with pressure.
Srivastava
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Department of Physics, Banaras Hindu University, Varanasi-221005, India.
Sa
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Singh
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D004560:Electricity; D050866:Liquid Crystals / Q000737:chemistry*; D044367:Phase Transition; D011108:Polymers / Q000737:chemistry*; D013314:Stress, Mechanical; D013696:Temperature
D011108:Polymers; C422409:liquid crystal polymer