Long-range exciton-coupled circular dichroism: application for determination of the absolute configuration of oligonaphthalenes.
Hexadecanaphthalenes (S,S,S,S,S,S,S,S,S,S,S,S,S,S,S)-4b and (S,S,S,S,S,S,S,R,S,S,S,S,S,S,S)-4b that possess two tetraphenylporphyrins (TPP) on the upper and lower naphthalene rings were synthesized. Long-range exciton-coupled CD in the Soret region of TPP (about 66 A) was observed. [structure: see text]
Tsubaki
Kazunori
K
Institute for Chemical Research, Kyoto University, Gokasho, Uji, Kyoto 611-0011, Japan. tsubaki@fos.kuicr.kyoto-u.ac.jp
Takaishi
Kazuto
K
Tanaka
Hiroyuki
H
Miura
Masaya
M
Kawabata
Takeo
T