title: A concise synthesis of (-)-centrolobine via a diastereoselective ring rearrangement metathesis-isomerisation sequence.
abstract: A total synthesis of (-)-centrolobine (1) based on a diastereoselective ring rearrangement metathesis-double bond isomerisation sequence and a one-pot cross metathesis-hydrogenation procedure is described.
authors.affiliation: TU Berlin - Berlin University of Technology, Institute of Chemistry, Strasse des 17. Juni 115, Sekr. C3, 10623 Berlin, Germany.
authors.forename: Verena
authors.initials: V
authors.lastname: Böhrsch
authors.forename: Siegfried
authors.initials: S
authors.lastname: Blechert
mesh_terms: D007536:Isomerism; D015394:Molecular Structure; D011714:Pyrans / Q000138:chemical synthesis* / Q000737:chemistry*
chemical_list: D011714:Pyrans; C432457:centrolobin