Solid-state architecture of saccharin salts of some diamines.
Hydrazinium saccharinate, N2H5+.C7H4NO3S-, crystallizes in a 1:1 ratio, while ethylenediaminium bis(saccharinate), C2H10N2(2+).2C7H4NO3S-, and butane-1,4-diaminium bis(saccharinate), C4H14N2(2+).2C7H4NO3S-, form in a 1:2 cation-anion stoichiometry. The structures contain many strong hydrogen bonds of the N+-H...N-, N+-H...O, N-H...O and N-H...N types, with auxiliary C-H...O interactions.
Banerjee
Rahul
R
School of Chemistry, University of Hyderabad, Hyderabad 500 046, India.
Saha
Binoy K
BK
Desiraju
Gautam R
GR
D000588:Amines / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008958:Models, Molecular; D015394:Molecular Structure; D012439:Saccharin / Q000737:chemistry*; D012492:Salts / Q000737:chemistry*
D000588:Amines; D012492:Salts; D012439:Saccharin