Asymmetric [3 + 2] annulations catalyzed by a planar-chiral derivative of DMAP.
A planar-chiral DMAP derivative catalyzes an intriguing [3 + 2] annulation reaction of silylated indenes to produce diquinanes that bear three contiguous stereocenters (one quaternary and two tertiary).
Bappert
Erhard
E
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA.
Müller
Peter
P
Fu
Gregory C
GC
D002384:Catalysis; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D011725:Pyridines / Q000737:chemistry*; D013237:Stereoisomerism
C417980:4-(dimethylamine)pyridine; D011725:Pyridines