Mu1,1-azide-bridged ferromagnetic MnIII dimer with slow relaxation of magnetization.
A new end-on azide-bridged dimeric Mn(III) complex has been synthesized by using the tridentate N-isonicotinamidosalicylaidimine ligand. Magnetic studies show that the complex has a high-spin ground state of S = 4 and is ac out-of-phase frequency-dependent.
Ge
Chun-Hua
CH
Department of Chemistry, Tsinghua University, Beijing 100084, People's Republic of China.
Cui
Ai-Li
AL
Ni
Zhong-Hai
ZH
Jiang
Yun-Bo
YB
Zhang
Li-Fang
LF
Ribas
Joan
J
Kou
Hui-Zhong
HZ