A key step in the formation of acrylic acid from CO2 and ethylene: the transformation of a nickelalactone into a nickel-acrylate complex.
The reaction of a nickelalactone with dppm, resulting in the formation of a stable binuclear Ni(I) complex with an acrylate, a Ph2P- and a dppm bridge, models a key step in the formation of acrylic acid from CO2 and ethylene.
Fischer
Reinald
R
Department of Inorganic and Analytical Chemistry, University of Jena, D-07743 Jena, Germany.
Langer
Jens
J
Malassa
Astrid
A
Walther
Dirk
D
Görls
Helmar
H
Vaughan
Gavin
G
D000179:Acrylates / Q000138:chemical synthesis* / Q000737:chemistry; D002245:Carbon Dioxide / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D005030:Ethylenes / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D000179:Acrylates; D005030:Ethylenes; D008024:Ligands; D009942:Organometallic Compounds; D002245:Carbon Dioxide; D009532:Nickel; C036216:ethylene; C036658:acrylic acid