title: Chemical engineering of the single-walled carbon nanotube-nylon 6 interface.
abstract: We report an approach to the chemical engineering of the single-walled carbon nanotube (SWNT)-polymer interfacial interaction in a nylon 6 graft copolymer composite which is based on the degree of SWNT functionality. Continuous fibers are drawn from composites fabricated from the in situ polymerization of caprolactam with SWNTs possessing a range of carboxylic acid (SWNT-COOH) and amide (SWNT-CONH(2)) functionalities. Mechanical performance evaluation of the composite fibers shows that a high concentration of the carboxylic acid functional groups leads to a stronger SWNT-nylon interfacial interaction, as reflected in greater values of the Young's modulus and mechanical strength. Replacement of the COOH group by CONH(2) in the SWNT starting material changes the grafting polymerization chemistry, thereby leading to the covalent attachment of longer graft copolymer chains to the SWNTs, and alters the composite morphology while increasing the composite flexibility and toughness.
authors.affiliation: Carbon Solutions, Inc., Riverside, California 92506, USA.
authors.forename: Junbo
authors.initials: J
authors.lastname: Gao
authors.forename: Bin
authors.initials: B
authors.lastname: Zhao
authors.forename: Mikhail E
authors.initials: ME
authors.lastname: Itkis
authors.forename: Elena
authors.initials: E
authors.lastname: Bekyarova
authors.forename: Hui
authors.initials: H
authors.lastname: Hu
authors.forename: Verina
authors.initials: V
authors.lastname: Kranak
authors.forename: Aiping
authors.initials: A
authors.lastname: Yu
authors.forename: Robert C
authors.initials: RC
authors.lastname: Haddon