Phosphine gold(I)-catalyzed hydroamination of alkenes under thermal and microwave-assisted conditions.
[reaction: see text] Phosphine gold(I) complexes catalyzed isomerization of terminal alkenes and hydroamination of unactivated alkenes under thermal and microwave-assisted conditions. This is the first example of the use of microwave radiation as a heat source for gold(I)-catalyzed organic reactions.
Liu
Xin-Yuan
XY
Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, PR China.
Li
Cheng-Hui
CH
Che
Chi-Ming
CM