Three-dimensional networks of lanthanide 1,2,4-triazolates: infinity(3)[Yb(Tz)3] and [Eu2(Tz)5(TzH)2], the first 4f networks with complete nitrogen coordination.
The solvent-free melt reaction of Eu and Yb with the N-heterocycle 1,2,4-triazole, gives the first three-dimensional networks of the lanthanides with complete nitrogen coordination spheres, further being the first unsubstituted triazolates of the lanthanides and exhibiting different valences.
Müller-Buschbaum
Klaus
K
Institut für Anorganische Chemie, Universität zu Köln, Greinstrasse 6, D-50939, Köln, Germany. Klaus.Mueller-Buschbaum@uni-koeln.de
Mokaddem
Yassin
Y