Hybrid bidentate ligand for functional recognition: an application to regioselective C=C double bond hydrogenation.
Regioselectivity increases in C=C double bond hydrogenation could be obtained for Lewis basic substrates on a Lewis acidic support by using a rhodium complex supported on a mesoporous solid.
Goettmann
Frédéric
F
Laboratoire de Chimie de la Matière Condensée de Paris, UMR CNRS 7574, Université Pierre et Marie Curie, 4 place Jussieu, 75005 Paris, France.
Le Floch
Pascal
P
Sanchez
Clément
C
D000080462:Acyclic Monoterpenes; D001643:Bridged Bicyclo Compounds / Q000737:chemistry; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D020134:Catalytic Domain; D003500:Cyclization; D006865:Hydrogenation; D008024:Ligands; D015394:Molecular Structure; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity; D013729:Terpenes / Q000737:chemistry
D000080462:Acyclic Monoterpenes; D001643:Bridged Bicyclo Compounds; D008024:Ligands; D013729:Terpenes; D002244:Carbon; D012238:Rhodium; C007836:geraniol