Dynamic surface elasticity of polyelectrolyte/surfactant adsorption films at the air/water interface: dodecyltrimethylammonium bromide and copolymer of sodium 2-acrylamido-2-methyl-1-propansulfonate with N-isopropylacrylamide.
The complex dynamic surface elasticity of the solutions of copolymer of sodium 2-acrylamido-2-methyl-1-propansulfonate with N-isopropylacrylamide and dodecyltrimethylammonium bromide was measured as a function of the surfactant concentration and the surface age by the oscillating bubble and drop methods. The kinetic dependencies of the surface elasticity proved to be non-monotonic at low concentrations and the main features of the surface viscoelasticity differed from the results for other polyelectrolyte/surfactant solutions films studied so far. The observed peculiarities were connected with the properties of the copolymer chain.
Noskov
B A
BA
St. Petersburg State University, Chemical Faculty, Universitetsky pr. 2, 198904 St. Petersburg, Russia.
Loglio
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Lin
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Miller
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