Palladium-catalyzed insertion of isocyanides into P(O)-H bonds: selective formation of phosphinoyl imines and bisphosphinoylaminomethanes.
Palladium and rhodium catalyzed the addition of H-phosphine oxides to isocyanides to selectively generate alpha-iminophosphine oxides and bisphosphinoylaminomethanes, respectively.
Hirai
Takayoshi
T
National Institute of Advanced Industrial Science and Technology, Tsukuba, Ibaraki, Japan.
Han
Li-Biao
LB
D002384:Catalysis; D003486:Cyanides / Q000737:chemistry*; D006860:Hydrogen Bonding; D007097:Imines / Q000138:chemical synthesis*; D008744:Methylamines / Q000138:chemical synthesis*; D008956:Models, Chemical; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D009943:Organophosphorus Compounds; D010165:Palladium / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*
D003486:Cyanides; D007097:Imines; D008744:Methylamines; D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; D010720:Phosphines; D010165:Palladium; C027451:methylamine