A high-nuclearity, beyond "fully reduced" polyoxo(alkoxo)vanadium(III/IV) cage.
The solvothermal synthesis, crystal structure and preliminary magnetic studies are reported of the first high nuclearity V(III)-based polyoxo(alkoxo)vanadium cage, a V(III)16V(IV)2 complex.
Tidmarsh
Ian S
IS
School of Chemistry, University of Manchester, Manchester, UK M13 9PL.
Laye
Rebecca H
RH
Brearley
Paul R
PR
Shanmugam
Maheswaran
M
Sañudo
E Carolina
EC
Sorace
Lorenzo
L
Caneschi
Andrea
A
McInnes
Eric J L
EJ