title: Carbonate release from carbonated hydroxyapatite in the wide temperature rage.
abstract: Synthetic carbonated apatite ceramics are considered as promising alternative to auto- and allograft materials for bone substitute. The aim of this study was to investigate the thermal stability of an AB-type carbonated apatite in the wide temperature range. The data on the thermal stability have to allow the conditions of the sintering of the ceramics to be controlled. Initial carbonated apatite powders were prepared by interaction between calcium oxide and ammonium hydrogen phosphate with addition of ammonium carbonate. Decomposition process was monitored by infra red spectroscopy, weight loss and X-ray diffraction of solid, and by infra red analysis of condensed gas phase resulted from the thermal decomposition of the sample in equilibrium conditions. Features of carbon monoxide and carbon dioxide release were revealed. The synthesized AB-type carbonated apatite is started to decompose at about 400 degrees Celsius releasing mainly carbon dioxide, but retained some carbonate groups and apatite structure at the temperature 1100 degrees Celsius useful to prepare porous carbonate-apatite ceramics intended for bone tissue engineering scaffolds.
authors.affiliation: Instutute for Physical Chemistry of Ceramics, Russian Academy of Sciences, Ozernaya 48, 119361, Moscow, Russia. barinov_s@mail.ru
authors.forename: S M
authors.initials: SM
authors.lastname: Barinov
authors.forename: J V
authors.initials: JV
authors.lastname: Rau
authors.forename: S Nunziante
authors.initials: SN
authors.lastname: Cesaro
authors.forename: J
authors.initials: J
authors.lastname: Durisin
authors.forename: I V
authors.initials: IV
authors.lastname: Fadeeva
authors.forename: D
authors.initials: D
authors.lastname: Ferro
authors.forename: L
authors.initials: L
authors.lastname: Medvecky
authors.forename: G
authors.initials: G
authors.lastname: Trionfetti
mesh_terms: D001031:Apatites / Q000032:analysis*; D001672:Biocompatible Materials / Q000737:chemistry*; D018786:Bone Substitutes; D017610:Calcium Compounds / Q000737:chemistry; D002254:Carbonates / Q000032:analysis* / Q000737:chemistry; D017886:Durapatite / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry; D010710:Phosphates / Q000737:chemistry; D011208:Powders / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D014961:X-Ray Diffraction
chemical_list: D001031:Apatites; D001672:Biocompatible Materials; D018786:Bone Substitutes; D017610:Calcium Compounds; D002254:Carbonates; D010087:Oxides; D010710:Phosphates; D011208:Powders; C024788:ammonium phosphate; C030782:carboapatite; D017886:Durapatite; C016538:lime; C040502:ammonium carbonate