title: Enantiomer fractions of polychlorinated biphenyls in three selected Standard Reference Materials.
abstract: The enantiomer composition of six chiral polychlorinated biphenyls (PCBs) were measured in three different certified Standard Reference Materials (SRMs) from the US National Institute of Standards and Technology (NIST): SRM 1946 (Lake Superior fish tissue), SRM 1939a (PCB Congeners in Hudson River Sediment), and SRM 2978 (organic contaminants in mussel tissue--Raritan Bay, New Jersey) to aid in quality assurance/quality control methodologies in the study of chiral pollutants in sediments and biota. Enantiomer fractions (EFs) of PCBs 91, 95, 136, 149, 174, and 183 were measured using a suite of chiral columns by gas chromatography/mass spectrometry. Concentrations of target analytes were in agreement with certified values. Target analyte EFs in reference materials were measured precisely (<2% relative standard deviation), indicating the utility of SRM in quality assurance/control methodologies for analyses of chiral compounds in environmental samples. Measured EFs were also in agreement with previously published analyses of similar samples, indicating that similar enantioselective processes were taking place in these environmental matrices.
authors.affiliation: Department of Chemistry, 11227 Saskatchewan Drive, University of Alberta, Edmonton, Alta., Canada T6G 2G2.
authors.forename: Joshua A
authors.initials: JA
authors.lastname: Morrissey
authors.forename: Derek S
authors.initials: DS
authors.lastname: Bleackley
authors.forename: Nicholas A
authors.initials: NA
authors.lastname: Warner
authors.forename: Charles S
authors.initials: CS
authors.lastname: Wong
mesh_terms: D000818:Animals; D049872:Bivalvia / Q000378:metabolism; D004784:Environmental Monitoring / Q000379:methods / Q000592:standards; D008401:Gas Chromatography-Mass Spectrometry; D011078:Polychlorinated Biphenyls / Q000032:analysis* / Q000737:chemistry / Q000592:standards; D012015:Reference Standards; D013237:Stereoisomerism; D014337:Trout / Q000378:metabolism; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014876:Water Pollution / Q000032:analysis*
chemical_list: D014874:Water Pollutants, Chemical; D011078:Polychlorinated Biphenyls