A one-pot synthesis of a 243-allyl dendrimer under ambient conditions.
[reaction: see text] Hydrosilylation of a nonaallyl dendritic core using HSi(Me)(2)Cl followed by reaction with a phenolate dendronic brick bearing three allyl groups, followed by repetition of this sequence of reactions twice, allows a one-pot synthesis of a 243-allyl dendrimer under ambient conditions.
Ornelas
Catia
C
Nanosciences and Catalysis Group, LCOO, UMR CNRS No. 5802, ENSCPB, Université Bordeaux I, Talence, France.
Aranzaes
Jaime Ruiz
JR
Cloutet
Eric
E
Astruc
Didier
D