title: Experimental variability in characterization of cyfluthrin sorption to soil.
abstract: To assess the risk of a pesticide to leach to groundwater or to run off to surface water after application, it is necessary to characterize the sorption of the pesticide to soil. For pyrethroids, their hydrophobicity, strong sorption to various materials, and low solubility make it difficult to accurately characterize sorption processes. The objective of this research was to evaluate the variability in cyfluthrin ((RS)-alpha -cyano-4-fluoro-3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate) sorption to soil as affected by experiment conditions. To minimize cyfluthrin sorption on the walls of glass, silanized-glass, stainless steel, and PTFE centrifuge tubes, cyfluthrin solution was added to aqueous soil slurries or directly to soil, after which it was equilibrated with aqueous solution. Depending on the soil, variation in sorption coefficients, Koc, obtained using different experimental methodologies with one soil can be comparable to the variation in Koc values obtained for soils with different physical and chemical properties using one method. Koc values for cyfluthrin ranged from 56,000 to 300,000 L kg-1. Sorption methodology needs to be evaluated before sorption coefficients are used in predictive transport models.
authors.affiliation: USDA-Agricultural Research Service, St. Paul, Minnesota, USA. koskinen@sumn.edu
authors.forename: William C
authors.initials: WC
authors.lastname: Koskinen
authors.forename: Pamela J
authors.initials: PJ
authors.lastname: Rice
authors.forename: Jeffery
authors.initials: J
authors.lastname: Seebinger
mesh_terms: D000327:Adsorption; D005544:Forecasting; D019015:Geologic Sediments / Q000737:chemistry; D007306:Insecticides / Q000737:chemistry*; D009570:Nitriles / Q000737:chemistry*; D011722:Pyrethrins / Q000737:chemistry*; D012987:Soil / Q000032:analysis*; D012989:Soil Pollutants / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis
chemical_list: D007306:Insecticides; D009570:Nitriles; D011722:Pyrethrins; D012987:Soil; D012989:Soil Pollutants; D014874:Water Pollutants, Chemical; C052570:cyfluthrin