title: Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)4(H2O)(eta1-OSO)][MeC6H4SO3]2.
abstract: The structure of a new metastable geometric isomer of [Ru(NH3)4(H2O)(SO2)][MeC6H4SO3]2 in which the SO2 group is coordinated through a single oxygen in an eta1-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.
authors.affiliation: Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UKCB2 1EW.
authors.forename: Katharine F
authors.initials: KF
authors.lastname: Bowes
authors.forename: Jacqueline M
authors.initials: JM
authors.lastname: Cole
authors.forename: Shamus L G
authors.initials: SL
authors.lastname: Husheer
authors.forename: Paul R
authors.initials: PR
authors.lastname: Raithby
authors.forename: Teresa L
authors.initials: TL
authors.lastname: Savarese
authors.forename: Hazel A
authors.initials: HA
authors.lastname: Sparkes
authors.forename: Simon J
authors.initials: SJ
authors.lastname: Teat
authors.forename: John E
authors.initials: JE
authors.lastname: Warren