Photocrystallographic structure determination of a new geometric isomer of [Ru(NH3)4(H2O)(eta1-OSO)][MeC6H4SO3]2.
The structure of a new metastable geometric isomer of [Ru(NH3)4(H2O)(SO2)][MeC6H4SO3]2 in which the SO2 group is coordinated through a single oxygen in an eta1-OSO bonding mode has been determined at 13 K; the new isomer was obtained as a 36% component of the structure within a single crystal upon irradiation using a tungsten lamp.
Bowes
Katharine F
KF
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UKCB2 1EW.
Cole
Jacqueline M
JM
Husheer
Shamus L G
SL
Raithby
Paul R
PR
Savarese
Teresa L
TL
Sparkes
Hazel A
HA
Teat
Simon J
SJ
Warren
John E
JE