Preparation, crystallographic characterization and theoretical study of C70(CF3)16 and C70(CF3)18.
C70(CF3)16 and C70(CF3)18, the first trifluoromethylated fullerene derivatives to comprise a pair of adjacent CF3 groups, have been isolated from a mixture obtained via reaction of C70 with CF3I, characterized in a single crystal XRD study and theoretically investigated at the DFT level of theory.
Avdoshenko
Stanislav M
SM
Chemistry Department, Moscow State University, Leninskie Gory, 119992 Moscow, Russia.
Goryunkov
Alexey A
AA
Ioffe
Ilya N
IN
Ignat'eva
Daria V
DV
Sidorov
Lev N
LN
Pattison
Philip
P
Kemnitz
Erhard
E
Troyanov
Sergey I
SI