Fresnel lens to concentrate solar energy for the photocatalytic decoloration and mineralization of orange II in aqueous solution.
The decoloration and mineralization of the azo dye orange II under conditions of artificial ultraviolet light and solar energy concentrated by a Fresnel lens in the presence of hydrogen peroxide and TiO(2)-P25 was studied. A comparative study to demonstrate the viability of this solar installation was done to establish if the concentration reached in the focus of the Fresnel lens was enough to improve the photocatalytic degradation reaction. The degradation efficiency was higher when the photolysis was carried out under concentrated solar energy irradiation as compared to UV light source in the presence of an electron acceptor such us H(2)O(2) and the catalyst TiO(2). The effect of hydrogen peroxide, pH and catalyst concentration was also determined. The increase of H(2)O(2) concentration until a critical value (14.7 mM) increased both the solar and artificial UV oxidation reaction rate by generating hydroxyl radicals and inhibiting the (e(-)/h(+)) pair recombination, but the excess of hydrogen peroxide decreases the oxidation rate acting as a radical or hole scavenger and reacting with TiO(2) to form peroxo-compounds, contributing to the inhibition of the reaction. The use of the response surface methodology allowed to fit the optimal values of the parameters pH and catalyst concentration leading to the total solar degradation of orange II. The optimal pH range was 4.5-5.5 close to the zero point charge of TiO(2) depending on surface charge of catalyst and dye ionization state. Dosage of catalyst higher than 1.1 gl(-1) decreases the degradation efficiency due to a decrease of light penetration.
Monteagudo
J M
JM
Universidad de Castilla-La Mancha, Departamento de Ingeniería Química, Escuela Técnica Superior de Ingenieros Industriales, Avda. Camilo José Cela, 1, 13071 Ciudad Real, Spain. josemaria.monteagudo@uclm.es
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D001391:Azo Compounds / Q000737:chemistry / Q000528:radiation effects*; D001557:Benzenesulfonates / Q000737:chemistry / Q000528:radiation effects*; D002244:Carbon / Q000032:analysis; D002384:Catalysis; D003116:Color; D004396:Coloring Agents / Q000737:chemistry / Q000528:radiation effects*; D006861:Hydrogen Peroxide / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007909:Lenses; D010777:Photochemistry; D012993:Solar Energy; D013472:Sunlight; D014025:Titanium / Q000737:chemistry; D014466:Ultraviolet Rays; D014865:Waste Disposal, Fluid; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000528:radiation effects*; D018508:Water Purification / Q000379:methods
D001391:Azo Compounds; D001557:Benzenesulfonates; D004396:Coloring Agents; D014874:Water Pollutants, Chemical; C009495:titanium dioxide; D002244:Carbon; D006861:Hydrogen Peroxide; D014025:Titanium; C014722:2-naphthol orange