Characterization of PM(2.5) in the ambient air of Shanghai City by analyzing individual particles.
PM(2.5) samples were collected simultaneously at three representative areas (central city, industrial area and clean air suburban) of Shanghai City. Their morphologies and elemental compositions were determined by scanning electron microscopy coupled with energy analysis (SEM-EDX). The particles were classified into four groups based on morphology and elemental composition. Soot aggregates and spherical fly ash particles were the two dominant types and they were identified as originating from automobile exhaust, metallurgical industry and coal combustion. The size distribution of the particles showed that most had diameters in the range of 0.2-1.4 microm. Individual particles were measured by synchrotron radiation micro-beam X-ray fluorescence (micro-SXRF) and the micro-SXRF spectra were obtained. Pattern recognition techniques, which took the micro-SXRF spectrum of a single aerosol particle as its fingerprint, were used to identify the origins of the particles. Seven source types were identified. They were: metallurgical industry, vehicle exhaust, soil dust, coal combustion, diesel exhaust, oil combustion and motorcycle exhaust. Metallurgical industry, automobile exhaust, and coal combustion were recognized to be the main pollution sources of PM(2.5) in the air of Shanghai City.
Yue
Weisheng
W
Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China.
Li
Xiaolin
X
Liu
Jiangfeng
J
Li
Yan
Y
Yu
Xiaohan
X
Deng
Biao
B
Wan
Tianmin
T
Zhang
Guilin
G
Huang
Yuying
Y
He
Wei
W
Hua
Wei
W
Shao
Longyi
L
Li
Weijun
W
Yang
Shushen
S
D000393:Air Pollutants / Q000032:analysis*; D002244:Carbon; D002681:China; D002947:Cities; D003031:Coal; D060729:Coal Ash; D004391:Dust / Q000032:analysis*; D004784:Environmental Monitoring / Q000379:methods; D008669:Metallurgy; D008855:Microscopy, Electron, Scanning; D008903:Minerals; D052638:Particulate Matter; D011210:Power Plants; D012987:Soil; D013052:Spectrometry, X-Ray Emission; D001335:Vehicle Emissions
D000393:Air Pollutants; D003031:Coal; D060729:Coal Ash; D004391:Dust; D008903:Minerals; D052638:Particulate Matter; D012987:Soil; D001335:Vehicle Emissions; D002244:Carbon