The first structurally characterized nitrosyl heme thiolate model complex.
The NO ligand in the formally {FeNO}6 compound [Fe(oep)(NO)(thiolate)] is bent, and does not impart a significant structural trans effect to the Fe-S bond.
Xu
Nan
N
Department of Chemistry and Biochemistry, University of Oklahoma, 620 Parrington Oval, Norman, Oklahoma, USA.
Powell
Douglas R
DR
Cheng
Lin
L
Richter-Addo
George B
GB
D006418:Heme / Q000737:chemistry*; D058085:Iron Compounds / Q000737:chemistry*; D008956:Models, Chemical; D009569:Nitric Oxide / Q000737:chemistry / Q000378:metabolism; D009603:Nitroso Compounds / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*
D058085:Iron Compounds; D009603:Nitroso Compounds; D013438:Sulfhydryl Compounds; D009569:Nitric Oxide; D006418:Heme