title: Preconcentration and determination of cadmium by GFAAS after solid-phase extraction with synthetic zeolite.
abstract: The solid-phase extraction (SPE) method for the preconcentration of trace amounts of cadmium using synthetic zeolite A-4 and its determination by graphite furnace atomic absorption spectrometry (GFAAS) was investigated. The preconcentration conditions, such as the optimum pH range of the sample solution for the adsorption of cadmium and the kind of acid solution for dissolving the cadmium-adsorbed synthetic zeolite A-4, as well as the measurement conditions for the determination of cadmium by GFAAS, e.g., the ashing and atomizing temperature, were investigated. Quantitative recovery of cadmium onto zeolite A-4 from the sample solution over the pH range 2.0 - 9.0 was achieved by the batch method. After the solid-phase (cadmium-adsorbed zeolite A-4) was separated from the sample solution by a membrane filter, it was dissolved in 2.0 cm(3) of 2.0 mol dm(-3) nitric acid. An aliquot of the resulting solution was injected into the graphite furnace. In GFAAS measurements an alternate gas (Ar, 90%; O(2), 10%) was used as a sheath gas, and the ashing temperature and atomizing temperature were 400 degrees C and 1600 degrees C, respectively. The detection limit (3 sigma) for cadmium was 0.002 microg dm(-3). The relative standard deviation at 0.010 microg dm(-3) was 3.5 - 4.5% (n = 5). The proposed method has been successfully applied to the analysis of trace cadmium in environmental water samples.
authors.affiliation: Department of Basic Science and High Technology Research Center, College of Industrial Technology, Nihon University.
authors.forename: Hiroaki
authors.initials: H
authors.lastname: Minamisawa
authors.forename: Ryoko
authors.initials: R
authors.lastname: Okunugi
authors.forename: Mayumi
authors.initials: M
authors.lastname: Minamisawa
authors.forename: Satoshi
authors.initials: S
authors.lastname: Tanaka
authors.forename: Kazunori
authors.initials: K
authors.lastname: Saitoh
authors.forename: Nobumasa
authors.initials: N
authors.lastname: Arai
authors.forename: Masami
authors.initials: M
authors.lastname: Shibukawa
mesh_terms: D002104:Cadmium / Q000032:analysis*; D002138:Calibration; D006863:Hydrogen-Ion Concentration; D012680:Sensitivity and Specificity; D013054:Spectrophotometry, Atomic; D014874:Water Pollutants, Chemical / Q000032:analysis*; D017641:Zeolites / Q000737:chemistry*
chemical_list: D014874:Water Pollutants, Chemical; D002104:Cadmium; D017641:Zeolites