Oxidative N-dealkylation in cobalt-bispidine-H2O2 systems.
The reaction of the Co(II) complex with the rigid bispidine ligand L1 with two tertiary amine and two pyridine donors, [Co(II)(L1)(OH2)2]2+, with H2O2 and O2 produces [Co(II)(L2)(OH2)2]3+, where L2 is demethylated at one of the amine donors, and CH2O.
Comba
Peter
P
Universität Heidelberg, Anorganisch-Chemisches Institut, Im Neuenheimer Feld 270, D-69120, Heidelberg, Germany. peter.comba@aci.uni-heidelberg.de
Kuwata
Shigemasa
S
Linti
Gerald
G
Pritzkow
Hans
H
Tarnai
Máté
M
Wadepohl
Hubert
H
D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D003640:Dealkylation; D006861:Hydrogen Peroxide / Q000737:chemistry*; D008956:Models, Chemical; D016877:Oxidants / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*
D019086:Bridged Bicyclo Compounds, Heterocyclic; D016877:Oxidants; C495809:bispidine; D003035:Cobalt; D006861:Hydrogen Peroxide; D010100:Oxygen