Characterization of sintered TCP sheets with various contents of binder prepared by tape-casting technique.
OBJECTIVE
The purpose of this study was to investigate the effect of binder content on the characterization of sintered tricalcium phosphate (TCP) sheets prepared by the tape-casting technique.


METHODS
Poly(acrylic acid)-based binder was added at four contents: 5, 10, 15, or 30 mass%, to a beta-TCP aqueous slurry. The TCP green sheets were fabricated with the prepared TCP slurry by the tape-casting technique, and were sintered at 1200 degrees C for 2h. The sintered TCP sheets were characterized by field-emission scanning electron microscope (FE-SEM) observation, X-ray diffraction (XRD) and Fourier transform infrared (FT-IR) spectrometry. Apatite precipitation on the sintered TCP sheet surface in Hanks' balanced salt (HBS) solution at pH 7.4 was monitored over 14 days at 37 degrees C.


RESULTS
A TCP green sheet with 5 mass% binder content had insufficient flexibility before sintering, and that with 30 mass% binder content had a problem in controlling the viscosity of slurry. FE-SEM observation showed that no differences in grain size existed in the various sintered TCP sheets. Measurement of XRD and FT-IR showed the presence of alpha-TCP phase in the various sintered TCP sheets, and same crystallographic structure was observed among various sintered TCP sheets. After 14 days immersion in HBS solution, the surfaces of sintered TCP sheets were completely covered with precipitated apatite crystals.


CONCLUSIONS
The binder content of 10 or 15 mass% is suitable for sintering TCP sheets. The sintered TCP sheet prepared by the tape-casting technique is a promising material as bone substitute.
Tanimoto
Yasuhiro
Y
Department of Dental Biomaterials, Research Institute of Oral Science, Nihon University School of Dentistry at Matsudo, 2-870-1 Sakaecho Nishi, Matsudo, Chiba 271-8587, Japan. tanimoto.yasuhiro@nihon-u.ac.jp
Hayakawa
Tohru
T
Nemoto
Kimiya
K
D000180:Acrylic Resins / Q000737:chemistry*; D001031:Apatites / Q000737:chemistry; D002130:Calcium Phosphates / Q000737:chemistry*; D003461:Crystallography; D003735:Dental Casting Technique; D003764:Dental Materials / Q000737:chemistry*; D006358:Hot Temperature; D006801:Humans; D006863:Hydrogen-Ion Concentration; D007101:Immersion; D007552:Isotonic Solutions / Q000737:chemistry; D008422:Materials Testing; D008855:Microscopy, Electron, Scanning; D010316:Particle Size; D010968:Plasticizers / Q000737:chemistry; D018583:Pliability; D012997:Solvents / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013499:Surface Properties; D013997:Time Factors; D014783:Viscosity; D014961:X-Ray Diffraction
D000180:Acrylic Resins; D001031:Apatites; D002130:Calcium Phosphates; D003764:Dental Materials; C072670:Hanks Balanced Salt Solution; D007552:Isotonic Solutions; D010968:Plasticizers; D012997:Solvents; C006903:carbopol 940; C018392:tricalcium phosphate