The cocrystal of 3-hydroxy-2-naphthoic acid and 4,4'-bipyridine.
4,4'-Bipyridine cocrystallizes with 3-hydroxy-2-naphthoic acid in a 1:2 ratio to give a centrosymmetric three-component supramolecular adduct, namely 3-hydroxy-2-naphthoic acid-4,4'-bipyridine (2/1), C11H8O3.0.5C10H8N2, in which 4,4'-bipyridine is located on an inversion center. The pyridine-carboxylic acid heterosynthon generates an infinite one-dimensional hydrogen-bonded chain via pi-pi interactions between naphthyl and 4,4'-bipyridine groups. The one-dimensional chains are further assembled into a three-dimensional network by weak C-H...pi interactions between pyridyl and naphthyl rings, and C-H...O interactions between 3-hydroxy-2-naphthoic acid molecules.
Lou
Ben-Yong
BY
Department of Chemistry and Chemical Engineering, Minjiang University, Fuzhou, Fujian 350108, People's Republic of China. loubenyong@163.com
Huang
Xiao-Dong
XD
Lin
Xiang-Chao
XC
D003460:Crystallization; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008958:Models, Molecular; D015394:Molecular Structure; D009281:Naphthalenes / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*
C520087:3-hydroxy-2-naphthoic acid-4,4'-bipyridine; D009281:Naphthalenes; D011725:Pyridines; C023666:pyridine