title: The formation of the stable radicals .CH2CN, CH3.CHCN and .CH2CH2CN from the anions -CH2CN, CH3-CHCN and -CH2CH2CN in the gas phase. A joint experimental and theoretical study.
abstract: Franck-Condon one-electron oxidation of the stable anions -CH2CN, CH3-CHCN and -CH2CH2CN (in the collision cell of a reverse-sector mass spectrometer) produce the radicals .CH2CN, CH3.CHCN and .CH2CH2CN, which neither rearrange nor decompose during the microsecond duration of the neutralisation-reionisation experiment. Acetonitrile (CH3CN) and propionitrile (CH3CH2CN) are known interstellar molecules and radical abstraction of these could produce energised .CH2CN and CH3.CHCN, which might react with NH2. (a known interstellar radical) on interstellar dust or ice surfaces to form NH2CH2CN and NH2CH(CH3)CN, precursors of the amino acids glycine and alanine.
authors.affiliation: Department of Chemistry, University of Adelaide, South Australia.
authors.forename: Hayley J
authors.initials: HJ
authors.lastname: Andreazza
authors.forename: Mark
authors.initials: M
authors.lastname: Fitzgerald
authors.forename: John H
authors.initials: JH
authors.lastname: Bowie
mesh_terms: D000097:Acetonitriles / Q000737:chemistry*; D005609:Free Radicals / Q000737:chemistry; D005740:Gases; D013058:Mass Spectrometry; D008968:Molecular Conformation; D009570:Nitriles / Q000737:chemistry*; D013816:Thermodynamics
chemical_list: D000097:Acetonitriles; D005609:Free Radicals; D005740:Gases; D009570:Nitriles; C005557:propionitrile; C032159:acetonitrile