Reactive quenching of OH(A 2Sigma+) by D2 studied using crossed molecular beams.
Reactive quenching of OH(A 2Sigma+,v=0) by D2 forming HOD+D was studied in crossed molecular beams. The D atom products are primarily forward scattered relative to the incident D2. The dominant mechanism involves a direct reaction from relatively large impact parameters with approximately 88% of the available energy appearing in HOD internal excitation.
Ortiz-Suárez
Mariví
M
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853-1301, USA.
Witinski
Mark F
MF
Davis
H Floyd
HF