Grignard reagents in ionic liquids.
Grignard reagents were generated from magnesium and organic iodides in the ionic liquid n-butylpyridinium tetrafluoroborate, [bpy][BF4], and they showed different reactivity from classical Grignard reagents in organic solvents.
Law
Man Chun
MC
Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hong Hum, Hong Kong, China.
Wong
Kwok-Yin
KY
Chan
Tak Hang
TH
D001881:Borates / Q000737:chemistry*; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D008274:Magnesium / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011726:Pyridinium Compounds / Q000737:chemistry*
D001881:Borates; D006847:Hydrocarbons, Iodinated; D052578:Ionic Liquids; D009942:Organometallic Compounds; D011726:Pyridinium Compounds; C518932:n-butylpyridinium tetrafluoroborate; D008274:Magnesium