title: Gold-catalyzed synthesis of alkylidene 2-oxazolidinones and 1,3-oxazin-2-ones.
abstract: N-Boc-protected alkynylamines are converted into the corresponding alkylidene 2-oxazolidinones or 2-oxazinones under very mild reaction conditions in the presence of 1-5 mol % of a cationic Au(I) complex. The scope of the reaction is very general, providing the cyclic carbamates in high yield regardless of the substitution at nitrogen and alkyne terminus.
authors.affiliation: Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid, Spain.
authors.forename: Rocío
authors.initials: R
authors.lastname: Robles-Machín
authors.forename: Javier
authors.initials: J
authors.lastname: Adrio
authors.forename: Juan Carlos
authors.initials: JC
authors.lastname: Carretero