title: The first structurally characterized nitrosyl heme thiolate model complex.
abstract: The NO ligand in the formally {FeNO}6 compound [Fe(oep)(NO)(thiolate)] is bent, and does not impart a significant structural trans effect to the Fe-S bond.
authors.affiliation: Department of Chemistry and Biochemistry, University of Oklahoma, 620 Parrington Oval, Norman, Oklahoma, USA.
authors.forename: Nan
authors.initials: N
authors.lastname: Xu
authors.forename: Douglas R
authors.initials: DR
authors.lastname: Powell
authors.forename: Lin
authors.initials: L
authors.lastname: Cheng
authors.forename: George B
authors.initials: GB
authors.lastname: Richter-Addo
mesh_terms: D006418:Heme / Q000737:chemistry*; D058085:Iron Compounds / Q000737:chemistry*; D008956:Models, Chemical; D009569:Nitric Oxide / Q000737:chemistry / Q000378:metabolism; D009603:Nitroso Compounds / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*
chemical_list: D058085:Iron Compounds; D009603:Nitroso Compounds; D013438:Sulfhydryl Compounds; D009569:Nitric Oxide; D006418:Heme