title: Studies on photoinduced H-atom and electron transfer reactions of o-naphthoquinones by laser flash photolysis.
abstract: The quenching of the triplets of 1,2-naphthoquinone (NQ) and 1,2-naphthoquinone-4-sulfonic acid sodium salt (NQS) by various electron and H-atom donors was investigated by laser flash photolysis measurement in acetonitrile and benzene. The results showed that the reactivities and configurations of 3NQ* (3NQS*) are governed by solvent polarity. All the quenching rate constants (kq) measured in benzene are larger than those in acetonitrile. The SO3Na substituent at the C-4 position of NQS makes 3NQS* more reactive than 3NQ* in electron/H-atom transfer reactions. Large differences of kq values were discovered in H-atom transfer reactions for alcohols and phenols, which can be explained by different H-abstraction mechanisms. Detection of radical cations of amines/anilines in time-resolved transient absorption spectra confirms an electron transfer mechanism. Triplets are identified as precursors of formed radical anions of NQ and NQS in photoinduced reactions. The dependence of electron transfer rate constants on the free energy changes (DeltaG) was treated by using the Rehm-Weller equation. For the four anilines with different substituents on the para or meta position of amidocyanogen, good correlation between log kq values with Hammett sigma constants testifies the correctness of empirical Hammett equation. Charge density distributions, adiabatic ionization/affinity potentials and redox potentials of NQ (NQS) and some quenchers were studied by quantum chemistry calculation.
authors.affiliation: Department of Chemical Physics, Department of Chemistry, and Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei 230026, China.
authors.forename: Yang
authors.initials: Y
authors.lastname: Pan
authors.forename: Yao
authors.initials: Y
authors.lastname: Fu
authors.forename: Shaoxiong
authors.initials: S
authors.lastname: Liu
authors.forename: Haizhu
authors.initials: H
authors.lastname: Yu
authors.forename: Yuhe
authors.initials: Y
authors.lastname: Gao
authors.forename: Qingxiang
authors.initials: Q
authors.lastname: Guo
authors.forename: Shuqin
authors.initials: S
authors.lastname: Yu
mesh_terms: D004583:Electrons; D006859:Hydrogen / Q000737:chemistry; D007834:Lasers; D008956:Models, Chemical; D009285:Naphthoquinones / Q000737:chemistry* / Q000528:radiation effects; D010100:Oxygen / Q000737:chemistry; D010777:Photochemistry; D010782:Photolysis; D012680:Sensitivity and Specificity; D013053:Spectrophotometry / Q000379:methods; D014466:Ultraviolet Rays
chemical_list: D009285:Naphthoquinones; D006859:Hydrogen; C040756:1,2-naphthoquinone; D010100:Oxygen