title: Most stable metallic phase of the mixed-valence MMX-chain, Pt2(dtp)4I (dtp = C2H5CS2-), in purely d-electronic conductors based on the transition-metal complex.
abstract: The electrical resistivity and X-ray oscillation photograph measurements for an MMX-chain complex, Pt2(dtp)4I (dtp = C2H5CS2-), under high pressure were performed. We observed the most stable metallic phase (TMI = 70 K, under 2.2 GPa) in the 1-D purely d-electronic conductors and pressure-induced metal-insulator transition including the structural phase transition at 3.0 GPa.
authors.affiliation: Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Fukuoka 812-8581, Japan.
authors.forename: Kazuya
authors.initials: K
authors.lastname: Otsubo
authors.forename: Atsushi
authors.initials: A
authors.lastname: Kobayashi
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Kitagawa
authors.forename: Masato
authors.initials: M
authors.lastname: Hedo
authors.forename: Yoshiya
authors.initials: Y
authors.lastname: Uwatoko
authors.forename: Hajime
authors.initials: H
authors.lastname: Sagayama
authors.forename: Yusuke
authors.initials: Y
authors.lastname: Wakabayashi
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Sawa