The unusual micelle micropolarity of partially fluorinated gemini surfactants sensed by pyrene fluorescence.
New gemini surfactants having two fluorocarbon chains were prepared by refluxing partially fluorinated alkyl bromide with N,N,N',N'-tetramethyl-1,6-diaminohexane in acetonitrile. The partially fluorinated gemini surfactants containing a six-methylene spacer chain are easily soluble in water. The critical micelle concentrations (cmc's) were determined by various fluorescent probe methods. The hydrophobicity of a CF2 group was estimated to be 1.5 times that of a CH2 group according to the cmc values. The micelle micropolarity of a fluorocarbon gemini sensed by pyrene fluorescence was unusually high, suggesting an apparent iceberg-like environment in the location of pyrene. The significantly small micelle aggregation numbers of fluorinated gemini surfactants were ascertained by the pyrene fluorescence quenching method. The micelle ionization degree estimated by fluorescence quenching of 6-methoxy-N-(3-sulfopropyl)quinolinium (SPQ) gave tendencies similar to those of the corresponding hydrocarbon geminis.
Asakawa
Tsuyoshi
T
Division of Material Sciences, Graduate School of Natural Science & Technology, Kanazawa University, Kanazawa 920-1192, Japan. asakawa@t.kanazawa-u.ac.jp
Okada
Tomohisa
T
Hayasaka
Tsutomu
T
Kuwamoto
Keiko
K
Ohta
Akio
A
Miyagishi
Shigeyoshi
S