title: Geochemical modeling of leaching from MSWI air-pollution-control residues.
abstract: This paper provides an improved understanding of the leaching behavior of waste incineration air-pollution-control (APC) residues in a long-term perspective. Leaching was investigated by a series of batch experiments reflecting leaching conditions after initial washout of highly soluble salts from residues. Leaching experiments were performed at a range of pH-values using carbonated and noncarbonated versions of two APC residues. The leaching data were evaluated by geochemical speciation modeling and discussed with respect to possible solubility control. The leaching of major elements as well as trace elements was generally found to be strongly dependent on pH. As leaching characterization was performed in the absence of high salt levels, the presented results represent long-term leaching after initial washout from a disposal site, that is, liquid-to-solid ratios above 1-2 L/kg. The leaching of Al, Ba, Ca, Cr, Pb, S, Si, V, and Zn was found influenced by solubility control from A12O3, Al(OH)3, Ba(S,Cr)04 solid solutions, BaSO4, Ca6Al2(SO4)3(OH)12 x 26H2O, CaAl2Si4O12 x 2H2O, Ca(OH)2, CaSiO3, CaSO4 x 2H2O, CaZn2(OH)6 x 2H2O, KAlSi2O6, PbCO3, PbCrO4, Pb2O3, Pb2V2O7, Pb3(VO4)2, ZnO, Zn2SiO4, and ZnSiO3. The presented dataset and modeling results form a thorough contribution to the assessment of long-term leaching behavior of APC residues under a wide range of conditions.
authors.affiliation: Institute of Environment & Resources, Technical University of Denmark, Building 115, DK-2800 Lyngby, Denmark. tha@er.dtu.dk
authors.forename: Thomas
authors.initials: T
authors.lastname: Astrup
authors.forename: Joris J
authors.initials: JJ
authors.lastname: Dijkstra
authors.forename: Rob N J
authors.initials: RN
authors.lastname: Comans
authors.forename: Hans A
authors.initials: HA
authors.lastname: Van Der Sloot
authors.forename: Thomas H
authors.initials: TH
authors.lastname: Christensen
mesh_terms: D000393:Air Pollutants / Q000032:analysis / Q000737:chemistry*; D000397:Air Pollution / Q000032:analysis / Q000517:prevention & control*; D000535:Aluminum / Q000737:chemistry; D001464:Barium / Q000737:chemistry; D002118:Calcium / Q000737:chemistry; D002857:Chromium / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D017745:Incineration; D007854:Lead / Q000737:chemistry; D012822:Silicon Dioxide / Q000737:chemistry; D013431:Sulfates / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
chemical_list: D000393:Air Pollutants; D013431:Sulfates; D002857:Chromium; D001464:Barium; D007854:Lead; D012822:Silicon Dioxide; D000535:Aluminum; D015032:Zinc; D002118:Calcium