title: Recyclable self-assembly-supported catalyst for chelation-assisted hydroacylation of an olefin with a primary alcohol.
abstract: [reaction: see text] A novel recyclable catalyst for chelation-assisted hydroacylation of an olefin with a primary alcohol was developed by utilizing a hydrogen-bonding self-assembly motif consisting of a barbiturate bearing 2-aminopyridin-4-yl group and 5-hexyl-2,4,6-triaminopyrimidine. This was further applied to a mixed catalyst system to recycle both organic and organometallic catalysts.
authors.affiliation: Department of Chemistry, Yonsei University, Seoul, South Korea.
authors.forename: Do-Won
authors.initials: DW
authors.lastname: Kim
authors.forename: Sung-Gon
authors.initials: SG
authors.lastname: Lim
authors.forename: Chul-Ho
authors.initials: CH
authors.lastname: Jun