Mechanism of NO transfer from NO-donors (SNAP and G-MNBS) to ferrous tetraphenylporphyrin in CH3OH.
[reaction: see text] The mechanism of NO transfer from NO-donors (SNAP and G-MNBS) to ferrous tetraphenylporphyrin (TPPFe(II)) in CH(3)OH is discovered for the first time by using a laser flash technique. The results show that the NO transfer is completed by NO(+) transfer followed by electron transfer rather than direct NO transfer in one step.
Zhu
Xiao-Qing
XQ
Department of Chemistry, the State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, China. xqzhu@nankai.edu.cn
Zhang
Jian-Yu
JY
Mei
Lian-Rui
LR
Cheng
Jin-Pei
JP
D001557:Benzenesulfonates / Q000737:chemistry*; D000432:Methanol / Q000737:chemistry; D015394:Molecular Structure; D009569:Nitric Oxide / Q000737:chemistry*; D020030:Nitric Oxide Donors / Q000737:chemistry*; D010396:Penicillamine / Q000031:analogs & derivatives* / Q000737:chemistry; D011166:Porphyrins / Q000737:chemistry*
D001557:Benzenesulfonates; D020030:Nitric Oxide Donors; D011166:Porphyrins; C110881:S-nitro-N-acetylpenicillamine; C409084:tetraphenylporphyrin; D009569:Nitric Oxide; C010233:methyl-4-nitrobenzenesulfonate; D010396:Penicillamine; D000432:Methanol