title: Radical-polar crossover domino reactions involving organozinc and mixed organocopper/organozinc reagents.
abstract: A domino process involving Michael addition and carbocyclization has been developed starting from beta-N-allylamino enoates and various organometallic reagents (organozinc halides, diorganozinc reagents, and copper/zinc mixed species). In all cases the mechanism of this domino reaction has been evidenced to involve a radical-polar crossover mechanism.
authors.affiliation: Université Pierre et Marie Curie - Paris 6, Laboratoire de chimie organique (UMR CNRS 7611), Institut de chimie moléculaire (FR 2769) case 183, 4 place Jussieu, 75252 Paris cedex 05, France.
authors.forename: Fabrice
authors.initials: F
authors.lastname: Denes
authors.forename: Sabrina
authors.initials: S
authors.lastname: Cutri
authors.forename: Alejandro
authors.initials: A
authors.lastname: Perez-Luna
authors.forename: Fabrice
authors.initials: F
authors.lastname: Chemla