title: Electrochemical organization of monolayer protected gold nanoclusters on single-walled carbon nanotubes: significantly enhanced double layer capacitance.
abstract: This paper reports a novel electrochemical route for anchoring monolayer protected gold nanoclusters (size 8 +/- 0.2 nm) on single-walled carbon nanotube bundles, resulting in the formation of hybrid materials. Monolayer protected gold nanoclusters prepared by modified Brust synthesis route were organized on SWNT bundles by cycling the potential in dichloromethane between -1 to +1 V at a scan rate of 50 mV/s. Monolayer protected nanoclusters in electrolyte solutions possess ionic space charge around them (double layer charging), making them suitable for organization on nanotube bundles, by tuning the electrostatic interactions. More significantly, analysis of the double layer capacitance of these hybrid materials shows almost ten times increase in capacitance compared to that of bare SWNT bundles. We believe that these hybrid materials are potentially useful in nanoelectronics.
authors.affiliation: Physical and Materials Chemistry Division, National Chemical Laboratory, Pune 411008, India.
authors.forename: S
authors.initials: S
authors.lastname: Mahima
authors.forename: N K
authors.initials: NK
authors.lastname: Chaki
authors.forename: J
authors.initials: J
authors.lastname: Sharma
authors.forename: B A
authors.initials: BA
authors.lastname: Kakade
authors.forename: R
authors.initials: R
authors.lastname: Pasricha
authors.forename: A M
authors.initials: AM
authors.lastname: Rao
authors.forename: K
authors.initials: K
authors.lastname: Vijayamohanan
mesh_terms: D003460:Crystallization / Q000379:methods*; D025802:Electric Capacitance; D004563:Electrochemistry / Q000295:instrumentation* / Q000379:methods*; D006046:Gold / Q000737:chemistry*; D017979:Gold Colloid / Q000737:chemistry*; D008422:Materials Testing; D008839:Microelectrodes; D008968:Molecular Conformation; D036103:Nanotechnology / Q000295:instrumentation / Q000379:methods*; D037742:Nanotubes, Carbon / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D013499:Surface Properties
chemical_list: D017979:Gold Colloid; D037742:Nanotubes, Carbon; D006046:Gold