Synthesis of the spirastrellolide A trioxadispiroketal.
[reaction: see text] The core trioxadispiroketal system representing C26-C40 of spirastrellolide A was assembled using a sequenced double-intramolecular hetero-Michael addition process.
Wang
Ce
C
Department of Chemistry, University of Minnesota, Minneapolis, 55414, USA.
Forsyth
Craig J
CJ
D002384:Catalysis; D005663:Furans / Q000138:chemical synthesis*; D018942:Macrolides / Q000138:chemical synthesis*; D015394:Molecular Structure; D013141:Spiro Compounds / Q000138:chemical synthesis*
D005663:Furans; D018942:Macrolides; D013141:Spiro Compounds; C475125:spirastrellolide A; C507607:trioxadispiroketal