Application of the statistical rate theory of interfacial transport to interpret the relaxation time of proton adsorption from solution onto oxides.
A new way to analyze the rate of hydrogen ion adsorption from solution onto oxides was described. The statistical rate theory of interfacial transport (SRT) was applied to interpret relaxation time of ion adsorption. The new procedure for determination of rate constants of surface reaction was compared with the classical theory of activated adsorption and desorption (TAAD). It was found that for adsorption of uncharged species, both models give the same result, but for ion adsorption, their predictions differ considerably. Influence of surface potential and total concentration of adsorption sites on calculated rate constants was also discussed.
Piasecki
Wojciech
W
Group for Theoretical Problems of Adsorption, Institute of Catalysis and Surface, Chemistry, Polish Academy of Sciences, Ul. Niezapominajek 8, Kraków, 30-239 Poland. piacho@hermes.umcs.lublin.pl