Practical access to the polymer incarcerated platinum (PI Pt) catalyst and its application to hydrogenation.
Polymer incarcerated platinum catalysts (PI Pt) were conveniently prepared from PtCl(2)(COD) or H(2)PtCl(6).6H(2)O and styrene copolymers via reduction of the Pt sources with triethylamine, coacervation, and cross-linking. The Pt catalysts have been successfully applied to catalytic hydrogenation including saturation of heterocyclic compounds.
Miyazaki
Yoji
Y
Graduate School of Pharmaceutical Sciences, The University of Tokyo, Astellas Pharma Inc., Hongo, Bunkyo-ku, Japan.
Hagio
Hiroyuki
H
Sugiura
Masaharu
M
Kobayashi
Shū
S
D002384:Catalysis; D006859:Hydrogen / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*
D011108:Polymers; D010984:Platinum; D006859:Hydrogen