Highly efficient hydrazination of conjugated nitroalkenes via imidazole or DMAP mediated Morita-Baylis-Hillman reaction.
Novel alpha-hydrazino-alpha,beta-unsaturated nitroalkenes, which exhibit dynamic phenomenon on the NMR time scale, were synthesized in excellent yields via imidazole or DMAP mediated Morita-Baylis-Hillman (MBH) type reaction of nitroalkenes with azodicarboxylates.
Dadwal
Mamta
M
Department of Chemistry, Indian Institute of Technology, Bombay, Mumbai.
Mobin
Shaikh M
SM
Namboothiri
Irishi N N
IN