Nitrogen-containing macrocycles as host molecules for the recognition of undissociated phenol derivatives: mechanism of potentiometric signal generation.
The mechanism of the generation of potentiometric signals of corrole- and calix[4]pyrrole-containing liquid membrane electrodes was elucidated and compared in the presence of the neutral forms of phenol derivatives. In addition, the influence of lipophilic, anionic or cationic salts on this phenomenon was explored. Finally, the relationship between the acid-base properties of the phenolic guests and the hydrogen bond donor activity of the calix[4]pyrrole and corrole hosts, and the influence on the molecular recognition phenomenon occurring at the organic/aqueous interface are discussed.
Radecki
Jerzy
J
Institute of Animal Reproduction and Food Research of Polish Academy of Sciences, Tuwima 10, 10-747 Olsztyn, Poland. radecki@pan.olsztyn.pl
Dehaen
Wim
W
D047250:Calixarenes / Q000737:chemistry*; D004566:Electrodes; D006860:Hydrogen Bonding; D007477:Ions; D047028:Macrocyclic Compounds / Q000737:chemistry* / Q000494:pharmacology; D008567:Membranes, Artificial; D009584:Nitrogen / Q000737:chemistry*; D010636:Phenols / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D011199:Potentiometry
D007477:Ions; D047028:Macrocyclic Compounds; D008567:Membranes, Artificial; D010636:Phenols; D011166:Porphyrins; C469811:calix(4)pyrrole; C431863:corrole; D047250:Calixarenes; D009584:Nitrogen