title: Powerful preconcentration method for capillary electrophoresis and its application to analysis of ultratrace amounts of polycyclic aromatic hydrocarbons.
abstract: For environmental analyses, a high-performance and powerful preconcentration system exceeding 1 x 10(7)-fold was developed that was composed of a blue cotton method (solid extraction method)/homogeneous liquid-liquid extraction method/on-line concentration method for capillary electrophoresis (CE). This system was named the "triplex concentration system" and it was achieved by finding a new phase-separation phenomenon (homogeneous liquid-liquid extraction) from a water-miscible organic solvent. Parts per trillion levels of polycyclic aromatic hydrocarbons (PAHs) were used as model analytical targets in this study. With the proposed method, 20-L levels of environmental water could be preconcentrated up to 1 x 10(7)-fold within a maximum of 1 h. The parts per trillion levels of PAHs were easily determined even using UV/CE, which has a serious sensitivity problem, and the detection limit of benzo[a]pyrene was 3.60 ppt. This system was also used as a practical monitoring method for the Miyata River (in Japan).
authors.affiliation: Laboratory of Physical and Chemical Science, Fukushima University, 1 Kanayagawa, Fukushima 960-1296, Japan.
authors.forename: Yoshitaka
authors.initials: Y
authors.lastname: Takagai
authors.forename: Ryoutaro
authors.initials: R
authors.lastname: Akiyama
authors.forename: Shukuro
authors.initials: S
authors.lastname: Igarashi