Adsorption and recovery of lead(II) from aqueous solutions by immobilized Pseudomonas Aeruginosa PU21 beads.
In this study, immobilized Pseudomonas aeruginosa PU21 beads were used as an adsorbent for lead(II). Different weight percentages of chitosan were added to polyethylene glycol (PEG, 0.5 wt.% in aqueous solution) and alginate (18 wt.% in aqueous solution), and then blended or cross-linked using different concentrations of epichlorohydrin (ECH) to prepare beads of different sizes and increased mechanical strength. Before blending or cross-linking, different weight percentages of P. aeruginosa PU21 were added to increase lead(II) adsorption. Subsequently the optimized bead composition (concentration of ECH, percentages of chitosan and P. aeruginosa PU21) and the optimum adsorption conditions (agitation rate and pH in the aqueous solution) were ascertained. Finally, the optimized beads adsorbing lead(II) were regenerated by 0.1M aqueous HCl solutions and the most effective desorption agitation rate was ascertained. The results indicate that the reuse of immobilized P. aeruginosa PU21 beads was feasible. In addition, the equilibrium adsorption, kinetics, changes in the thermodynamic properties of adsorption of lead(II) on optimized beads were also investigated.
Lin
Chuen-Chang
CC
Department of Chemical Engineering, National Yunlin University of Science and Technology, 123 University Road, Sec. 3, Touliu, Yunlin 64002, Taiwan, ROC. linchuen@yuntech.edu.tw
Lai
Yin-Tzu
YT
D000327:Adsorption; D048271:Chitosan / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007854:Lead / Q000737:chemistry*; D008956:Models, Chemical; D008962:Models, Theoretical; D011092:Polyethylene Glycols / Q000737:chemistry; D011550:Pseudomonas aeruginosa / Q000378:metabolism*; D013696:Temperature; D013816:Thermodynamics; D013997:Time Factors; D014867:Water / Q000737:chemistry*
D014867:Water; D007854:Lead; D011092:Polyethylene Glycols; D048271:Chitosan