Recyclable self-assembly-supported catalyst for chelation-assisted hydroacylation of an olefin with a primary alcohol.
[reaction: see text] A novel recyclable catalyst for chelation-assisted hydroacylation of an olefin with a primary alcohol was developed by utilizing a hydrogen-bonding self-assembly motif consisting of a barbiturate bearing 2-aminopyridin-4-yl group and 5-hexyl-2,4,6-triaminopyrimidine. This was further applied to a mixed catalyst system to recycle both organic and organometallic catalysts.
Kim
Do-Won
DW
Department of Chemistry, Yonsei University, Seoul, South Korea.
Lim
Sung-Gon
SG
Jun
Chul-Ho
CH