O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding.
Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2 activation.
Company
Anna
A
Departament de Química and Institut de Química Computacional, Universitat de Girona, Campus de Montilivi, E-17071 Girona, Catalonia, Spain.
Lamata
Diana
D
Poater
Albert
A
Solà
Miquel
M
Rybak-Akimova
Elena V
EV
Que
Lawrence
L
Fontrodona
Xavier
X
Parella
Teodor
T
Llobet
Antoni
A
Costas
Miquel
M
D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D047028:Macrocyclic Compounds / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D011437:Propylamines / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman
D008024:Ligands; D047028:Macrocyclic Compounds; D009942:Organometallic Compounds; D011437:Propylamines; D003300:Copper; D010100:Oxygen