title: First C-3 lithiation of DMAP: a new entry into chemical tuning of acylation catalysts.
abstract: A TMSCH2Li-based reagent promoted the first C-3 lithiation of DMAP opening a direct access to functional diversity in acylation catalysts.
authors.affiliation: Synthèse Organométallique et Réactivité, UMR CNRS-UHP 7565 Université Henri Poincaré, Faculté des Sciences, Boulevard des Aiguillettes, 54506 Vandoeuvre-lès-Nancy, France. philippe.gros@sor.uhp-nancy.fr
authors.forename: Philippe C
authors.initials: PC
authors.lastname: Gros
authors.forename: Abdelatif
authors.initials: A
authors.lastname: Doudouh
authors.forename: Christopher
authors.initials: C
authors.lastname: Woltermann