title: Confinement-driven translocation of a flexible polymer.
abstract: We consider the escape of a flexible, self-avoiding polymer chain out of a confined geometry. By means of simulations, we demonstrate that the translocation time can be described by a simple scaling law that exhibits a nonlinear dependence on the degree of polymerization and that is sensitive to the nature of the confining geometry. These results contradict earlier predictions but are in agreement with recently confirmed geometry-dependent expressions for the free energy of confinement.
authors.affiliation: Department of Materials Science and Engineering and Frederick Seitz Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA.
authors.forename: Angelo
authors.initials: A
authors.lastname: Cacciuto
authors.forename: Erik
authors.initials: E
authors.lastname: Luijten
mesh_terms: D003198:Computer Simulation; D004548:Elasticity; D008567:Membranes, Artificial; D008956:Models, Chemical; D008958:Models, Molecular; D008968:Molecular Conformation; D009038:Motion; D011108:Polymers / Q000737:chemistry*; D013314:Stress, Mechanical
chemical_list: D008567:Membranes, Artificial; D011108:Polymers