The application of cathodic reductions and anodic oxidations in the synthesis of complex molecules.
This tutorial review surveys the recent advances in electrochemical transformations as they pertain to the synthesis of complex organic molecules. Electrochemistry has emerged as a powerful tool to synthetic chemists, yet many have never considered electrochemical methodology as a means for synthesis. Here, an introduction to electrochemistry and voltammetry will be provided with descriptions of the four types of electrochemical cells. In addition, recent examples of both anodic oxidations and cathodic reductions will be discussed, along with the experimental setups for carrying out each reaction.
Sperry
Jeffrey B
JB
Department of Chemistry, Dartmouth College, Hanover, NH, USA.
Wright
Dennis L
DL
D004563:Electrochemistry; D004566:Electrodes; D015394:Molecular Structure; D009930:Organic Chemicals / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D013237:Stereoisomerism
D009930:Organic Chemicals