Radical reactions of [60]fullerene with beta-enamino carbonyl compounds mediated by manganese(III) acetate.
Manganese(III) acetate dihydrate-mediated reactions of [60]fullerene with beta-enamino carbonyl compounds afforded [60]fullerene-fused pyrroline derivatives, of which the nitrogen atom is directly connected to the fullerene cage. A possible reaction mechanism is proposed.
Wang
Guan-Wu
GW
Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Anhui, PR China. gwang@ustc.edu.cn
Yang
Hai-Tao
HT
Miao
Chun-Bao
CB
Xu
Yu
Y
Liu
Fei
F