title: Oxidant enhancement in martian dust devils and storms: implications for life and habitability.
abstract: We investigate a new mechanism for producing oxidants, especially hydrogen peroxide (H2O2), on Mars. Large-scale electrostatic fields generated by charged sand and dust in the martian dust devils and storms, as well as during normal saltation, can induce chemical changes near and above the surface of Mars. The most dramatic effect is found in the production of H2O2 whose atmospheric abundance in the "vapor" phase can exceed 200 times that produced by photochemistry alone. With large electric fields, H2O2 abundance gets large enough for condensation to occur, followed by precipitation out of the atmosphere. Large quantities of H2O2 would then be adsorbed into the regolith, either as solid H2O2 "dust" or as re-evaporated vapor if the solid does not survive as it diffuses from its production region close to the surface. We suggest that this H2O2, or another superoxide processed from it in the surface, may be responsible for scavenging organic material from Mars. The presence of H2O2 in the surface could also accelerate the loss of methane from the atmosphere, thus requiring a larger source for maintaining a steady-state abundance of methane on Mars. The surface oxidants, together with storm electric fields and the harmful ultraviolet radiation that readily passes through the thin martian atmosphere, are likely to render the surface of Mars inhospitable to life as we know it.
authors.affiliation: Department of Atmospheric, Oceanic, and Space Sciences, University of Michigan, Ann Arbor, Michigan, USA.
authors.forename: Sushil K
authors.initials: SK
authors.lastname: Atreya
authors.forename: Ah-San
authors.initials: AS
authors.lastname: Wong
authors.forename: Nilton O
authors.initials: NO
authors.lastname: Renno
authors.forename: William M
authors.initials: WM
authors.lastname: Farrell
authors.forename: Gregory T
authors.initials: GT
authors.lastname: Delory
authors.forename: Davis D
authors.initials: DD
authors.lastname: Sentman
authors.forename: Steven A
authors.initials: SA
authors.lastname: Cummer
authors.forename: John R
authors.initials: JR
authors.lastname: Marshall
authors.forename: Scot C R
authors.initials: SC
authors.lastname: Rafkin
authors.forename: David C
authors.initials: DC
authors.lastname: Catling
mesh_terms: D018559:Exobiology; D006861:Hydrogen Peroxide / Q000138:chemical synthesis*; D018535:Mars; D014919:Wind
chemical_list: D006861:Hydrogen Peroxide