Sequential generation of one-dimensional networks based on a differentiated bischelate-type ligand bearing both 4,5-diazafluorene and dithiolene units.
A novel dithiolene ligand appended with a 4,5-diazafluorene moiety has been synthesized and used for the preparation of discrete nickel and mercury complexes and a one-dimensional polymer in the presence of sodium cations.
Baudron
Stéphane A
SA
Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université Louis Pasteur, F-67000 Strasbourg, France. sbaudron@chimie.u-strasbg.fr
Hosseini
Mir Wais
MW
D001372:Aza Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D005449:Fluorenes / Q000138:chemical synthesis* / Q000737:chemistry; D008024:Ligands; D008628:Mercury / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D013438:Sulfhydryl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D014961:X-Ray Diffraction
D001372:Aza Compounds; D005449:Fluorenes; D008024:Ligands; D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D009532:Nickel; D008628:Mercury